#------------------------------------------------------------------------------
#$Date: 2017-02-04 15:45:16 +0200 (Sat, 04 Feb 2017) $
#$Revision: 191571 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/72/7227299.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7227299
loop_
_publ_author_name
'Gong, Peijun'
'Li, Yanyan'
'Zhai, Cuiping'
'Luo, Jie'
'Tian, Xuemeng'
'Chen, Lijuan'
'Zhao, Junwei'
_publ_section_title
;
 Syntheses, structural characterization and photophysical properties of
 two series of rare-earth-isonicotinic-acid containing Waugh-type
 manganomolybdates
;
_journal_issue                   5
_journal_name_full               CrystEngComm
_journal_page_first              834
_journal_paper_doi               10.1039/C6CE02428A
_journal_volume                  19
_journal_year                    2017
_chemical_formula_moiety         'Mn Mo9 O32, C12 H10 Eu N2 O10, 7(O), 3(N)'
_chemical_formula_sum            'C12 H48 Eu Mn Mo9 N5 O49'
_chemical_formula_weight         2116.91
_chemical_name_systematic
;
 ? 
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_Hall           '-P 2ac 2ab'
_space_group_name_H-M_alt        'P b c a'
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2016-12-13
_audit_creation_method
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_audit_update_record
;
2016-12-16 deposited with the CCDC.
2016-12-20 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   19.0464(6)
_cell_length_b                   22.8077(7)
_cell_length_c                   24.2799(7)
_cell_measurement_reflns_used    9296
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      25.00
_cell_measurement_theta_min      1.68
_cell_volume                     10547.3(6)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XH (Sheldrick, 2008)'
_computing_structure_solution    'SIR2004 (Burla et al., 2007)'
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean none
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker Apex II'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0479
_diffrn_reflns_av_unetI/netI     0.0336
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            52197
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.68
_diffrn_source                   'fine-focus sealed tube'
_diffrn_standards_decay_%        none
_diffrn_standards_interval_count none
_diffrn_standards_interval_time  none
_diffrn_standards_number         none
_exptl_absorpt_coefficient_mu    3.586
_exptl_absorpt_correction_T_max  0.5646
_exptl_absorpt_correction_T_min  0.3143
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            Orange
_exptl_crystal_density_diffrn    2.666
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle-like
_exptl_crystal_F_000             8104
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.874
_refine_diff_density_min         -0.907
_refine_diff_density_rms         0.150
_refine_ls_extinction_coef       0.000054(7)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.082
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     679
_refine_ls_number_reflns         9296
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.088
_refine_ls_R_factor_all          0.0464
_refine_ls_R_factor_gt           0.0325
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0438P)²+36.7001P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0863
_refine_ls_wR_factor_ref         0.0913
_reflns_number_gt                7532
_reflns_number_total             9296
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6ce02428a2.cif
_cod_data_source_block           5
_cod_depositor_comments
'Adding full bibliography for 7227298--7227310.cif.'
_cod_database_code               7227299
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H) groups
2. Restrained distances
 O13W-O13W_$2
 2.8 with sigma of 0.01
 O13W-O14W
 2.8 with sigma of 0.01
3. Others
 Fixed Sof: O13W(0.5) O14W(0.5)
4.a Aromatic/amide H refined with riding coordinates:
 C1(H1A), C2(H2A), C3(H3A), C4(H4A), C7(H7A), C8(H8A), C9(H9A), C10(H10A)
4.b Tetrahedral OH refined with riding coordinates:
 O34(H34A), O36(H36A)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x+1/2, -y, z+1/2'
3 '-x, y+1/2, -z+1/2'
4 'x+1/2, -y+1/2, -z'
5 '-x, -y, -z'
6 'x-1/2, y, -z-1/2'
7 'x, -y-1/2, z-1/2'
8 '-x-1/2, y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags_posn
Mn1 Mn 0.43286(5) 0.26347(4) 0.37756(4) 0.0173(2) Uani 1 d .
Eu1 Eu 0.281982(17) 0.291032(15) 0.632248(13) 0.02345(10) Uani 1 d .
Mo1 Mo 0.51466(3) 0.14655(3) 0.34502(2) 0.02490(14) Uani 1 d .
Mo2 Mo 0.33983(3) 0.15159(2) 0.34625(2) 0.02279(14) Uani 1 d .
Mo3 Mo 0.42864(3) 0.15965(3) 0.46463(2) 0.02498(14) Uani 1 d .
Mo4 Mo 0.26535(3) 0.27068(3) 0.38616(2) 0.02315(14) Uani 1 d .
Mo5 Mo 0.36124(3) 0.37929(3) 0.42481(3) 0.02657(15) Uani 1 d .
Mo6 Mo 0.41643(3) 0.37147(2) 0.29359(2) 0.02433(14) Uani 1 d .
Mo7 Mo 0.53365(3) 0.37406(2) 0.39506(2) 0.02187(14) Uani 1 d .
Mo8 Mo 0.50380(3) 0.25496(3) 0.25921(2) 0.02288(14) Uani 1 d .
Mo9 Mo 0.53151(3) 0.26887(3) 0.48393(2) 0.02213(14) Uani 1 d .
O1W O 0.2378(3) 0.2687(3) 0.5417(2) 0.0648(19) Uani 1 d .
O2W O 0.3757(3) 0.3106(2) 0.5667(2) 0.0451(14) Uani 1 d .
O3W O 0.2512(3) 0.3862(3) 0.5922(3) 0.0573(17) Uani 1 d .
O4W O 0.2991(2) 0.2432(2) 0.72092(18) 0.0282(11) Uani 1 d .
O5W O 0.3692(2) 0.3552(2) 0.6766(2) 0.0337(12) Uani 1 d .
O6W O 0.1717(2) 0.2426(2) 0.64433(19) 0.0297(11) Uani 1 d .
O7W O 0.3087(3) -0.0156(3) 0.2376(3) 0.069(2) Uani 1 d .
O8W O 0.5560(3) 0.5187(3) 0.2844(3) 0.0634(19) Uani 1 d .
O9W O 0.6959(7) 0.3687(5) 0.5010(5) 0.151(4) Uiso 1 d .
O10W O 0.7302(7) 0.4596(6) 0.4286(6) 0.180(5) Uiso 1 d .
O11W O 0.3215(4) -0.0327(4) 0.3497(4) 0.088(2) Uani 1 d .
O12W O 0.1986(3) 0.3607(3) 0.2329(3) 0.0578(17) Uani 1 d .
O13W O 0.4340(4) -0.0057(8) 0.4782(7) 0.114(6) Uiso 0.50 d D
O14W O 0.2941(5) 0.0140(6) 0.4645(6) 0.072(4) Uiso 0.50 d D
N3 N 0.4855(5) 0.5430(3) 0.4454(3) 0.062(2) Uani 1 d .
N4 N 0.1634(4) 0.3941(4) 0.4998(4) 0.081(3) Uani 1 d .
N5 N 0.6210(5) 0.5306(4) 0.3932(4) 0.082(3) Uiso 1 d .
O1 O 0.4998(3) 0.0964(2) 0.2942(2) 0.0405(13) Uani 1 d .
O2 O 0.5788(3) 0.1159(2) 0.3845(2) 0.0414(13) Uani 1 d .
O3 O 0.4317(2) 0.20942(18) 0.31863(17) 0.0195(9) Uani 1 d .
O4 O 0.5636(2) 0.2054(2) 0.30487(18) 0.0260(10) Uani 1 d .
O5 O 0.4981(2) 0.21345(18) 0.41194(17) 0.0198(9) Uani 1 d .
O6 O 0.4258(2) 0.12123(18) 0.38725(18) 0.0246(10) Uani 1 d .
O7 O 0.3451(3) 0.1154(2) 0.2851(2) 0.0346(12) Uani 1 d .
O8 O 0.2827(3) 0.1120(2) 0.3852(2) 0.0354(12) Uani 1 d .
O9 O 0.2820(2) 0.21615(19) 0.32601(18) 0.0240(10) Uani 1 d .
O10 O 0.3619(2) 0.21765(19) 0.41085(17) 0.0209(9) Uani 1 d .
O11 O 0.3532(3) 0.1334(2) 0.4933(2) 0.0406(13) Uani 1 d .
O12 O 0.4920(3) 0.1122(2) 0.4864(2) 0.0403(13) Uani 1 d .
O13 O 0.4498(2) 0.2259(2) 0.50943(18) 0.0269(10) Uani 1 d .
O14 O 0.2113(3) 0.3182(2) 0.3527(2) 0.0377(12) Uani 1 d .
O15 O 0.2119(2) 0.2284(2) 0.4260(2) 0.0350(12) Uani 1 d .
O16 O 0.3604(2) 0.31605(18) 0.35586(17) 0.0198(9) Uani 1 d .
O17 O 0.2983(2) 0.3208(2) 0.44780(18) 0.0277(10) Uani 1 d .
O18 O 0.3041(3) 0.4295(2) 0.3985(2) 0.0413(13) Uani 1 d .
O19 O 0.3870(3) 0.4094(2) 0.4858(2) 0.0447(14) Uani 1 d .
O20 O 0.4382(2) 0.40675(18) 0.37048(18) 0.0254(10) Uani 1 d .
O21 O 0.4526(2) 0.31782(18) 0.43520(17) 0.0209(9) Uani 1 d .
O22 O 0.4764(3) 0.4171(2) 0.2641(2) 0.0404(13) Uani 1 d .
O23 O 0.3369(3) 0.4010(2) 0.2777(2) 0.0375(12) Uani 1 d .
O24 O 0.4219(2) 0.30611(19) 0.24593(18) 0.0250(10) Uani 1 d .
O25 O 0.4938(2) 0.31070(18) 0.33405(17) 0.0202(9) Uani 1 d .
O26 O 0.5378(3) 0.4249(2) 0.4471(2) 0.0347(12) Uani 1 d .
O27 O 0.5901(2) 0.3999(2) 0.3467(2) 0.0349(12) Uani 1 d .
O28 O 0.5865(2) 0.31263(19) 0.42770(18) 0.0243(10) Uani 1 d .
O29 O 0.4853(3) 0.2078(2) 0.2066(2) 0.0363(12) Uani 1 d .
O30 O 0.5696(2) 0.2978(2) 0.2347(2) 0.0371(12) Uani 1 d .
O31 O 0.5974(3) 0.2202(2) 0.4986(2) 0.0356(12) Uani 1 d .
O32 O 0.5345(3) 0.3199(2) 0.53524(19) 0.0358(12) Uani 1 d .
O33 O 0.3473(3) 0.2074(3) 0.6188(2) 0.0511(16) Uani 1 d .
O34 O 0.2939(4) 0.1237(4) 0.6321(4) 0.092(3) Uani 1 d .
H34A H 0.2895 0.1013 0.6059 0.137 Uiso 1 calc R
O35 O 0.2183(2) 0.3412(2) 0.7004(2) 0.0322(12) Uani 1 d .
O36 O 0.2145(3) 0.4379(2) 0.6886(2) 0.0542(16) Uani 1 d .
H36A H 0.2268 0.4298 0.6572 0.081 Uiso 1 calc R
N1 N 0.5468(5) 0.0723(4) 0.6324(4) 0.070(2) Uani 1 d .
N2 N 0.0916(4) 0.4088(3) 0.8647(3) 0.0477(18) Uani 1 d .
C1 C 0.4913(7) 0.0407(5) 0.6355(5) 0.085(4) Uani 1 d .
H1A H 0.4964 0.0004 0.6397 0.102 Uiso 1 calc R
C2 C 0.4243(6) 0.0636(4) 0.6327(4) 0.066(3) Uani 1 d .
H2A H 0.3849 0.0395 0.6346 0.079 Uiso 1 calc R
C3 C 0.5426(5) 0.1295(5) 0.6272(4) 0.063(3) Uani 1 d .
H3A H 0.5835 0.1518 0.6258 0.076 Uiso 1 calc R
C4 C 0.4783(5) 0.1568(4) 0.6238(3) 0.047(2) Uani 1 d .
H4A H 0.4757 0.1972 0.6194 0.057 Uiso 1 calc R
C5 C 0.4179(5) 0.1240(4) 0.6270(3) 0.042(2) Uani 1 d .
C6 C 0.3467(5) 0.1542(4) 0.6254(3) 0.050(2) Uani 1 d .
C7 C 0.1087(5) 0.4564(4) 0.8372(4) 0.060(3) Uani 1 d .
H7A H 0.0970 0.4931 0.8513 0.072 Uiso 1 calc R
C8 C 0.1437(5) 0.4525(4) 0.7878(4) 0.049(2) Uani 1 d .
H8A H 0.1548 0.4862 0.7681 0.059 Uiso 1 calc R
C9 C 0.1092(4) 0.3560(4) 0.8466(3) 0.044(2) Uani 1 d .
H9A H 0.0976 0.3231 0.8673 0.053 Uiso 1 calc R
C10 C 0.1441(4) 0.3491(3) 0.7979(3) 0.0302(16) Uani 1 d .
H10A H 0.1555 0.3119 0.7851 0.036 Uiso 1 calc R
C11 C 0.1622(3) 0.3981(3) 0.7677(3) 0.0297(16) Uani 1 d .
C12 C 0.2019(4) 0.3927(3) 0.7140(3) 0.0304(16) Uani 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
Mo1 Mn1 Mo7 113.54(3)
Mo1 Mn1 Mo9 86.86(3)
Mo3 Mn1 Mo1 63.48(2)
Mo3 Mn1 Mo5 111.56(3)
Mo3 Mn1 Mo7 120.99(3)
Mo3 Mn1 Mo8 124.52(3)
Mo3 Mn1 Mo9 60.37(2)
Mo5 Mn1 Mo1 172.67(4)
Mo5 Mn1 Mo7 63.60(2)
Mo5 Mn1 Mo9 85.91(3)
Mo8 Mn1 Mo1 61.16(2)
Mo8 Mn1 Mo5 123.89(3)
Mo8 Mn1 Mo7 85.02(3)
Mo8 Mn1 Mo9 118.85(3)
Mo9 Mn1 Mo7 60.62(2)
O3 Mn1 Mo1 43.30(12)
O3 Mn1 Mo3 90.99(13)
O3 Mn1 Mo5 143.96(13)
O3 Mn1 Mo7 128.52(13)
O3 Mn1 Mo8 44.03(12)
O3 Mn1 Mo9 130.12(13)
O3 Mn1 O10 87.38(18)
O3 Mn1 O16 101.12(18)
O3 Mn1 O21 169.29(18)
O3 Mn1 O25 87.50(18)
O5 Mn1 Mo1 43.96(13)
O5 Mn1 Mo3 43.07(13)
O5 Mn1 Mo5 128.71(13)
O5 Mn1 Mo7 91.30(13)
O5 Mn1 Mo8 94.77(13)
O5 Mn1 Mo9 43.69(13)
O5 Mn1 O3 87.04(18)
O5 Mn1 O10 87.00(18)
O5 Mn1 O16 169.64(19)
O5 Mn1 O21 86.45(18)
O5 Mn1 O25 100.74(19)
O10 Mn1 Mo1 89.60(13)
O10 Mn1 Mo3 44.36(13)
O10 Mn1 Mo5 89.89(13)
O10 Mn1 Mo7 143.95(13)
O10 Mn1 Mo8 131.01(13)
O10 Mn1 Mo9 95.53(13)
O10 Mn1 O16 87.01(18)
O10 Mn1 O21 100.76(18)
O10 Mn1 O25 170.49(18)
O16 Mn1 Mo1 144.40(13)
O16 Mn1 Mo3 129.48(13)
O16 Mn1 Mo5 42.84(12)
O16 Mn1 Mo7 88.58(13)
O16 Mn1 Mo8 95.54(13)
O16 Mn1 Mo9 128.74(13)
O16 Mn1 O21 86.37(18)
O16 Mn1 O25 86.12(18)
O21 Mn1 Mo1 128.98(13)
O21 Mn1 Mo3 90.06(13)
O21 Mn1 Mo5 44.07(13)
O21 Mn1 Mo7 43.23(12)
O21 Mn1 Mo8 128.23(13)
O21 Mn1 Mo9 42.77(13)
O25 Mn1 Mo1 92.17(13)
O25 Mn1 Mo3 143.78(13)
O25 Mn1 Mo5 89.53(13)
O25 Mn1 Mo7 42.39(12)
O25 Mn1 Mo8 43.48(12)
O25 Mn1 Mo9 93.90(13)
O25 Mn1 O21 85.36(18)
O1W Eu1 O2W 72.4(2)
O1W Eu1 O3W 75.1(2)
O1W Eu1 O4W 139.4(2)
O1W Eu1 O5W 139.55(19)
O2W Eu1 O3W 75.71(19)
O2W Eu1 O4W 124.25(18)
O2W Eu1 O5W 71.48(18)
O3W Eu1 O5W 78.9(2)
O4W Eu1 O3W 141.21(19)
O4W Eu1 O5W 77.83(16)
O6W Eu1 O1W 72.98(18)
O6W Eu1 O2W 144.03(17)
O6W Eu1 O3W 104.38(19)
O6W Eu1 O4W 78.58(16)
O6W Eu1 O5W 144.45(16)
O33 Eu1 O1W 83.3(2)
O33 Eu1 O2W 70.3(2)
O33 Eu1 O3W 143.9(2)
O33 Eu1 O4W 71.44(17)
O33 Eu1 O5W 101.0(2)
O33 Eu1 O6W 96.2(2)
O33 Eu1 O35 141.50(18)
O35 Eu1 O1W 124.5(2)
O35 Eu1 O2W 138.64(17)
O35 Eu1 O3W 74.02(18)
O35 Eu1 O4W 70.36(16)
O35 Eu1 O5W 75.57(16)
O35 Eu1 O6W 71.64(16)
O1 Mo1 Mn1 131.21(18)
O1 Mo1 O3 96.1(2)
O1 Mo1 O4 100.6(2)
O1 Mo1 O5 162.4(2)
O1 Mo1 O6 92.0(2)
O2 Mo1 Mn1 123.65(18)
O2 Mo1 O1 104.6(3)
O2 Mo1 O3 159.2(2)
O2 Mo1 O4 103.1(2)
O2 Mo1 O5 88.4(2)
O2 Mo1 O6 101.2(2)
O3 Mo1 Mn1 35.54(11)
O3 Mo1 O5 70.85(15)
O4 Mo1 Mn1 77.05(13)
O4 Mo1 O3 75.28(17)
O4 Mo1 O5 87.70(17)
O4 Mo1 O6 148.70(18)
O5 Mo1 Mn1 35.48(10)
O6 Mo1 Mn1 73.14(12)
O6 Mo1 O3 74.99(16)
O6 Mo1 O5 73.50(16)
Mn1 Mo2 Mo4 59.91(2)
O3 Mo2 Mn1 35.63(10)
O3 Mo2 Mo4 86.48(11)
O6 Mo2 Mn1 73.13(12)
O6 Mo2 Mo4 119.65(13)
O6 Mo2 O3 74.04(16)
O6 Mo2 O10 74.52(16)
O7 Mo2 Mn1 124.20(17)
O7 Mo2 Mo4 134.38(17)
O7 Mo2 O3 88.8(2)
O7 Mo2 O6 102.3(2)
O7 Mo2 O9 100.6(2)
O7 Mo2 O10 159.5(2)
O8 Mo2 Mn1 130.26(17)
O8 Mo2 Mo4 89.96(18)
O8 Mo2 O3 163.1(2)
O8 Mo2 O6 93.6(2)
O8 Mo2 O7 105.3(2)
O8 Mo2 O9 100.6(2)
O8 Mo2 O10 95.1(2)
O9 Mo2 Mn1 76.41(13)
O9 Mo2 Mo4 33.76(13)
O9 Mo2 O3 85.47(16)
O9 Mo2 O6 148.67(18)
O9 Mo2 O10 76.49(17)
O10 Mo2 Mn1 35.32(11)
O10 Mo2 Mo4 45.19(11)
O10 Mo2 O3 70.79(15)
Mn1 Mo3 Mo9 60.13(2)
O5 Mo3 Mn1 35.53(11)
O5 Mo3 Mo9 44.56(11)
O5 Mo3 O10 71.14(15)
O6 Mo3 Mn1 73.30(12)
O6 Mo3 Mo9 118.48(12)
O6 Mo3 O5 74.09(16)
O6 Mo3 O10 73.04(16)
O10 Mo3 Mn1 35.93(11)
O10 Mo3 Mo9 88.48(11)
O11 Mo3 Mn1 123.74(18)
O11 Mo3 Mo9 136.80(19)
O11 Mo3 O5 159.2(2)
O11 Mo3 O6 101.5(2)
O11 Mo3 O10 88.1(2)
O11 Mo3 O12 104.3(3)
O11 Mo3 O13 102.9(2)
O12 Mo3 Mn1 131.44(19)
O12 Mo3 Mo9 90.88(18)
O12 Mo3 O5 96.2(2)
O12 Mo3 O6 91.8(2)
O12 Mo3 O10 162.2(2)
O12 Mo3 O13 100.2(2)
O13 Mo3 Mn1 77.49(13)
O13 Mo3 Mo9 33.95(13)
O13 Mo3 O5 76.34(17)
O13 Mo3 O6 149.10(18)
O13 Mo3 O10 89.11(17)
Mn1 Mo4 Mo2 59.81(2)
Mn1 Mo4 Mo5 59.53(2)
Mo2 Mo4 Mo5 119.21(2)
O9 Mo4 Mn1 75.87(13)
O9 Mo4 Mo2 32.97(13)
O9 Mo4 Mo5 128.26(13)
O9 Mo4 O10 74.16(17)
O9 Mo4 O16 85.19(16)
O9 Mo4 O17 152.04(18)
O10 Mo4 Mn1 35.58(10)
O10 Mo4 Mo2 43.55(11)
O10 Mo4 Mo5 82.77(11)
O14 Mo4 Mn1 127.18(18)
O14 Mo4 Mo2 131.38(18)
O14 Mo4 Mo5 89.57(18)
O14 Mo4 O9 98.4(2)
O14 Mo4 O10 162.0(2)
O14 Mo4 O15 105.7(3)
O14 Mo4 O16 92.2(2)
O14 Mo4 O17 100.7(2)
O15 Mo4 Mn1 127.13(17)
O15 Mo4 Mo2 87.49(17)
O15 Mo4 Mo5 127.58(17)
O15 Mo4 O9 99.3(2)
O15 Mo4 O10 91.8(2)
O15 Mo4 O16 160.6(2)
O15 Mo4 O17 95.0(2)
O16 Mo4 Mn1 35.56(11)
O16 Mo4 Mo2 86.21(11)
O16 Mo4 Mo5 43.28(11)
O16 Mo4 O10 71.08(15)
O17 Mo4 Mn1 76.34(13)
O17 Mo4 Mo2 125.06(13)
O17 Mo4 Mo5 32.58(13)
O17 Mo4 O10 81.51(17)
O17 Mo4 O16 73.89(17)
Mn1 Mo5 Mo4 59.99(2)
O16 Mo5 Mn1 35.84(11)
O16 Mo5 Mo4 43.31(11)
O16 Mo5 O21 71.57(15)
O17 Mo5 Mn1 77.96(14)
O17 Mo5 Mo4 34.67(13)
O17 Mo5 O16 75.93(17)
O17 Mo5 O20 148.93(18)
O17 Mo5 O21 91.03(17)
O18 Mo5 Mn1 134.05(19)
O18 Mo5 Mo4 92.60(18)
O18 Mo5 O16 98.6(2)
O18 Mo5 O17 100.4(2)
O18 Mo5 O19 103.8(3)
O18 Mo5 O20 90.6(2)
O18 Mo5 O21 162.8(2)
O19 Mo5 Mn1 121.58(18)
O19 Mo5 Mo4 136.7(2)
O19 Mo5 O16 157.4(2)
O19 Mo5 O17 102.3(2)
O19 Mo5 O20 103.2(2)
O19 Mo5 O21 86.0(2)
O20 Mo5 Mn1 73.63(12)
O20 Mo5 Mo4 116.69(12)
O20 Mo5 O16 73.73(16)
O20 Mo5 O21 73.27(16)
O21 Mo5 Mn1 36.14(11)
O21 Mo5 Mo4 89.55(11)
O16 Mo6 Mn1 35.50(10)
O16 Mo6 O25 70.73(14)
O20 Mo6 Mn1 72.96(12)
O20 Mo6 O16 72.95(16)
O20 Mo6 O25 73.44(16)
O22 Mo6 Mn1 132.07(18)
O22 Mo6 O16 161.4(2)
O22 Mo6 O20 90.4(2)
O22 Mo6 O24 100.8(2)
O22 Mo6 O25 96.9(2)
O23 Mo6 Mn1 122.26(17)
O23 Mo6 O16 87.3(2)
O23 Mo6 O20 103.2(2)
O23 Mo6 O22 105.1(2)
O23 Mo6 O24 102.8(2)
O23 Mo6 O25 157.8(2)
O24 Mo6 Mn1 77.20(13)
O24 Mo6 O16 89.68(17)
O24 Mo6 O20 147.76(18)
O24 Mo6 O25 75.25(17)
O25 Mo6 Mn1 35.57(10)
O20 Mo7 Mn1 73.52(12)
O20 Mo7 O21 73.94(16)
O20 Mo7 O25 74.81(16)
O21 Mo7 Mn1 35.84(11)
O25 Mo7 Mn1 35.61(11)
O25 Mo7 O21 71.25(15)
O26 Mo7 Mn1 131.16(17)
O26 Mo7 O20 90.5(2)
O26 Mo7 O21 95.7(2)
O26 Mo7 O25 162.42(19)
O26 Mo7 O28 99.6(2)
O27 Mo7 Mn1 124.19(17)
O27 Mo7 O20 103.5(2)
O27 Mo7 O21 160.0(2)
O27 Mo7 O25 88.9(2)
O27 Mo7 O26 104.2(2)
O27 Mo7 O28 102.1(2)
O28 Mo7 Mn1 77.99(13)
O28 Mo7 O20 149.18(18)
O28 Mo7 O21 76.14(17)
O28 Mo7 O25 88.81(17)
O3 Mo8 Mn1 35.75(11)
O4 Mo8 Mn1 76.69(13)
O4 Mo8 O3 73.98(16)
O4 Mo8 O24 153.70(18)
O4 Mo8 O25 85.21(17)
O24 Mo8 Mn1 77.05(13)
O24 Mo8 O3 83.96(16)
O24 Mo8 O25 74.24(17)
O25 Mo8 Mn1 36.05(11)
O25 Mo8 O3 71.79(15)
O29 Mo8 Mn1 128.81(17)
O29 Mo8 O3 93.6(2)
O29 Mo8 O4 100.5(2)
O29 Mo8 O24 95.0(2)
O29 Mo8 O25 162.4(2)
O30 Mo8 Mn1 126.55(17)
O30 Mo8 O3 160.6(2)
O30 Mo8 O4 95.9(2)
O30 Mo8 O24 100.7(2)
O30 Mo8 O25 91.2(2)
O30 Mo8 O29 104.6(2)
Mn1 Mo9 Mo3 59.49(2)
O5 Mo9 Mn1 35.32(10)
O5 Mo9 Mo3 43.64(11)
O13 Mo9 Mn1 76.51(13)
O13 Mo9 Mo3 33.22(13)
O13 Mo9 O5 74.76(17)
O13 Mo9 O21 83.15(17)
O13 Mo9 O28 153.46(18)
O21 Mo9 Mn1 35.79(11)
O21 Mo9 Mo3 84.20(11)
O21 Mo9 O5 71.11(15)
O28 Mo9 Mn1 76.97(13)
O28 Mo9 Mo3 127.72(13)
O28 Mo9 O5 84.12(17)
O28 Mo9 O21 74.81(16)
O31 Mo9 Mn1 125.01(18)
O31 Mo9 Mo3 88.58(17)
O31 Mo9 O5 90.3(2)
O31 Mo9 O13 101.2(2)
O31 Mo9 O21 159.2(2)
O31 Mo9 O28 94.6(2)
O32 Mo9 Mn1 129.53(17)
O32 Mo9 Mo3 131.12(17)
O32 Mo9 O5 163.9(2)
O32 Mo9 O13 97.9(2)
O32 Mo9 O21 94.0(2)
O32 Mo9 O28 98.1(2)
O32 Mo9 O31 105.4(2)
Mn1 O3 Mo1 101.17(18)
Mn1 O3 Mo2 99.40(18)
Mn1 O3 Mo8 100.22(18)
Mo1 O3 Mo2 94.99(15)
Mo1 O3 Mo8 92.77(15)
Mo8 O3 Mo2 157.1(2)
Mo1 O4 Mo8 114.5(2)
Mn1 O5 Mo1 100.56(17)
Mn1 O5 Mo3 101.40(18)
Mn1 O5 Mo9 101.00(18)
Mo3 O5 Mo1 97.19(16)
Mo3 O5 Mo9 91.80(15)
Mo9 O5 Mo1 154.5(2)
Mo1 O6 Mo3 108.12(19)
Mo2 O6 Mo1 108.8(2)
Mo2 O6 Mo3 108.6(2)
Mo2 O9 Mo4 113.3(2)
Mn1 O10 Mo2 102.05(18)
Mn1 O10 Mo3 99.71(18)
Mn1 O10 Mo4 99.85(18)
Mo2 O10 Mo3 96.78(16)
Mo2 O10 Mo4 91.26(15)
Mo3 O10 Mo4 156.8(2)
Mo3 O13 Mo9 112.8(2)
Mn1 O16 Mo4 101.93(18)
Mn1 O16 Mo5 101.31(18)
Mn1 O16 Mo6 101.34(18)
Mo4 O16 Mo6 151.4(2)
Mo5 O16 Mo4 93.41(16)
Mo5 O16 Mo6 98.02(16)
Mo5 O17 Mo4 112.8(2)
Mo5 O20 Mo6 108.35(19)
Mo7 O20 Mo5 109.4(2)
Mo7 O20 Mo6 107.3(2)
Mn1 O21 Mo5 99.79(18)
Mn1 O21 Mo7 100.93(18)
Mn1 O21 Mo9 101.44(18)
Mo7 O21 Mo5 97.35(16)
Mo9 O21 Mo5 154.1(2)
Mo9 O21 Mo7 93.09(15)
Mo6 O24 Mo8 114.2(2)
Mn1 O25 Mo6 101.03(18)
Mn1 O25 Mo7 102.00(18)
Mn1 O25 Mo8 100.47(18)
Mo7 O25 Mo6 96.61(16)
Mo7 O25 Mo8 153.4(2)
Mo8 O25 Mo6 92.94(15)
Mo7 O28 Mo9 112.2(2)
C6 O33 Eu1 143.0(6)
C6 O34 H34A 109.5
C12 O35 Eu1 140.0(5)
C12 O36 H36A 109.5
C1 N1 C3 120.9(10)
C7 N2 C9 121.2(7)
N1 C1 H1A 118.4
N1 C1 C2 123.2(10)
C2 C1 H1A 118.4
C1 C2 H2A 121.3
C1 C2 C5 117.3(11)
C5 C2 H2A 121.3
N1 C3 H3A 119.7
N1 C3 C4 120.6(10)
C4 C3 H3A 119.7
C3 C4 H4A 120.1
C5 C4 C3 119.8(9)
C5 C4 H4A 120.1
C2 C5 C6 121.9(9)
C4 C5 C2 118.2(9)
C4 C5 C6 119.9(8)
O33 C6 O34 125.8(9)
O33 C6 C5 116.3(9)
O34 C6 C5 117.9(9)
N2 C7 H7A 119.7
N2 C7 C8 120.6(8)
C8 C7 H7A 119.7
C7 C8 H8A 120.3
C7 C8 C11 119.4(8)
C11 C8 H8A 120.3
N2 C9 H9A 119.5
N2 C9 C10 121.0(8)
C10 C9 H9A 119.5
C9 C10 H10A 120.4
C9 C10 C11 119.3(7)
C11 C10 H10A 120.4
C8 C11 C12 120.4(7)
C10 C11 C8 118.5(7)
C10 C11 C12 121.1(6)
O35 C12 C11 115.2(6)
O36 C12 O35 127.3(7)
O36 C12 C11 117.5(7)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Mn1 Mo1 3.1879(11)
Mn1 Mo3 3.1754(11)
Mn1 Mo5 3.1866(11)
Mn1 Mo7 3.1980(11)
Mn1 Mo8 3.1812(11)
Mn1 Mo9 3.1962(11)
Mn1 O3 1.889(4)
Mn1 O5 1.882(4)
Mn1 O10 1.891(4)
Mn1 O16 1.903(4)
Mn1 O21 1.907(4)
Mn1 O25 1.904(4)
Eu1 O1W 2.408(5)
Eu1 O2W 2.433(5)
Eu1 O3W 2.450(6)
Eu1 O4W 2.435(4)
Eu1 O5W 2.462(5)
Eu1 O6W 2.392(4)
Eu1 O33 2.301(5)
Eu1 O35 2.349(5)
Mo1 O1 1.705(5)
Mo1 O2 1.702(5)
Mo1 O3 2.228(4)
Mo1 O4 1.903(4)
Mo1 O5 2.251(4)
Mo1 O6 2.061(4)
Mo2 Mo4 3.2137(8)
Mo2 O3 2.291(4)
Mo2 O6 2.038(4)
Mo2 O7 1.702(5)
Mo2 O8 1.701(5)
Mo2 O9 1.904(4)
Mo2 O10 2.215(4)
Mo3 Mo9 3.2038(8)
Mo3 O5 2.212(4)
Mo3 O6 2.074(5)
Mo3 O10 2.252(4)
Mo3 O11 1.704(5)
Mo3 O12 1.705(5)
Mo3 O13 1.904(5)
Mo4 Mo5 3.2175(8)
Mo4 O9 1.944(4)
Mo4 O10 2.280(4)
Mo4 O14 1.702(5)
Mo4 O15 1.704(5)
Mo4 O16 2.211(4)
Mo4 O17 1.985(4)
Mo5 O16 2.210(4)
Mo5 O17 1.879(5)
Mo5 O18 1.703(5)
Mo5 O19 1.706(5)
Mo5 O20 2.069(5)
Mo5 O21 2.249(4)
Mo6 O16 2.241(4)
Mo6 O20 2.075(4)
Mo6 O22 1.703(5)
Mo6 O23 1.701(5)
Mo6 O24 1.890(4)
Mo6 O25 2.249(4)
Mo7 O20 2.054(4)
Mo7 O21 2.231(4)
Mo7 O25 2.204(4)
Mo7 O26 1.717(5)
Mo7 O27 1.697(5)
Mo7 O28 1.899(4)
Mo8 O3 2.247(4)
Mo8 O4 1.950(4)
Mo8 O24 1.974(4)
Mo8 O25 2.226(4)
Mo8 O29 1.706(5)
Mo8 O30 1.697(5)
Mo9 O5 2.249(4)
Mo9 O13 1.941(5)
Mo9 O21 2.214(4)
Mo9 O28 1.990(4)
Mo9 O31 1.713(5)
Mo9 O32 1.705(5)
O33 C6 1.223(11)
O34 H34A 0.8200
O34 C6 1.233(11)
O35 C12 1.259(8)
O36 H36A 0.8200
O36 C12 1.226(9)
N1 C1 1.282(15)
N1 C3 1.312(13)
N2 C7 1.317(12)
N2 C9 1.326(11)
C1 H1A 0.9300
C1 C2 1.381(15)
C2 H2A 0.9300
C2 C5 1.391(12)
C3 H3A 0.9300
C3 C4 1.377(13)
C4 H4A 0.9300
C4 C5 1.373(12)
C5 C6 1.523(12)
C7 H7A 0.9300
C7 C8 1.374(12)
C8 H8A 0.9300
C8 C11 1.379(10)
C9 H9A 0.9300
C9 C10 1.365(11)
C10 H10A 0.9300
C10 C11 1.379(10)
C11 C12 1.514(10)
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O34 H34A O10W 0.82 1.98 2.692(16) 145.5 4_456
O36 H36A O3W 0.82 1.92 2.712(8) 161.9 .
