#------------------------------------------------------------------------------
#$Date: 2017-02-03 11:14:05 +0200 (Fri, 03 Feb 2017) $
#$Revision: 191222 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/76/7227619.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7227619
loop_
_publ_author_name
'Ding, Bin'
'Wu, Jie'
'Wu, Xiang Xia'
'Huo, Jian Zhong'
'Zhu, Zhao Zhou'
'Liu, Yuan Yuan'
'Shi, Fang Xue'
_publ_section_title
;
 Syntheses, structural diversities and characterization of a series of
 coordination polymers with two isomeric oxadiazol-pyridine ligands
;
_journal_issue                   16
_journal_name_full               'RSC Adv.'
_journal_page_first              9704
_journal_paper_doi               10.1039/C6RA28153B
_journal_volume                  7
_journal_year                    2017
_chemical_formula_sum            'C24 H21 Ag2 F12 N9 O3 P2'
_chemical_formula_weight         989.18
_chemical_name_systematic
; 
 ? 
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2016-06-20 deposited with the CCDC.
2017-01-29 downloaded from the CCDC.
;
_cell_angle_alpha                104.313(3)
_cell_angle_beta                 91.093(3)
_cell_angle_gamma                112.549(3)
_cell_formula_units_Z            2
_cell_length_a                   9.0183(13)
_cell_length_b                   10.8981(17)
_cell_length_c                   19.524(3)
_cell_measurement_reflns_used    2966
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      24.46
_cell_measurement_theta_min      2.52
_cell_volume                     1703.2(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0283
_diffrn_reflns_av_unetI/netI     0.0591
_diffrn_reflns_Laue_measured_fraction_full 0.992
_diffrn_reflns_Laue_measured_fraction_max 0.985
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            12765
_diffrn_reflns_point_group_measured_fraction_full 0.992
_diffrn_reflns_point_group_measured_fraction_max 0.985
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.417
_diffrn_reflns_theta_min         1.085
_exptl_absorpt_coefficient_mu    1.353
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            COLOURLESS
_exptl_crystal_density_diffrn    1.929
_exptl_crystal_density_meas      ?
_exptl_crystal_description       BLOCK
_exptl_crystal_F_000             968
_exptl_crystal_size_max          0.220
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.170
_exptl_transmission_factor_max   0.803
_exptl_transmission_factor_min   0.755
_refine_diff_density_max         1.283
_refine_diff_density_min         -0.751
_refine_diff_density_rms         0.112
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     469
_refine_ls_number_reflns         8421
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.056
_refine_ls_R_factor_all          0.0858
_refine_ls_R_factor_gt           0.0549
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
; 
 w=1/[σ²(Fo²)+(0.0758P)²+0.5071P] 
 where P=(Fo²+2Fc²)/3 
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1389
_refine_ls_wR_factor_ref         0.1590
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5560
_reflns_number_total             8421
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6ra28153b2.cif
_cod_data_source_block           n160324b
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'MULTI-SCAN' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

'_exptl_crystal_density_meas' value 'NONE' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 
;
_cod_database_code               7227619
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.755
_shelx_estimated_absorpt_t_max   0.803
_shelxl_version_number           2013-2
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Ag1 Ag 1.45458(5) 0.72962(4) 0.76395(2) 0.04795(14) Uani 1 1 d . .
Ag2 Ag 0.91986(5) 0.89321(5) 0.78745(2) 0.05013(14) Uani 1 1 d . .
P1 P 0.7073(3) 0.36008(19) 0.87165(9) 0.0743(5) Uani 1 1 d . .
P2 P 0.3753(2) 0.23890(18) 0.48802(8) 0.0574(4) Uani 1 1 d . .
O1 O 0.6402(4) 0.4136(3) 0.67931(18) 0.0399(8) Uani 1 1 d . .
O2 O 0.7793(5) 1.2254(4) 1.0373(2) 0.0589(11) Uani 1 1 d . .
O3 O 0.6585(4) 1.0937(4) 0.6791(2) 0.0456(9) Uani 1 1 d . .
N1 N 0.7508(4) 0.6389(4) 0.7243(2) 0.0376(9) Uani 1 1 d . .
N2 N 0.5883(4) 0.5873(4) 0.7379(2) 0.0388(9) Uani 1 1 d . .
N3 N 1.2089(5) 0.6037(4) 0.6822(2) 0.0425(10) Uani 1 1 d . .
N4 N 0.6596(6) 1.2298(5) 1.1326(2) 0.0549(12) Uani 1 1 d . .
N5 N 0.6579(7) 1.0964(5) 1.1061(3) 0.0662(14) Uani 1 1 d . .
N6 N 0.8426(5) 0.8916(4) 0.8949(2) 0.0456(10) Uani 1 1 d . .
N7 N 0.7631(5) 0.9999(4) 0.7420(2) 0.0453(10) Uani 1 1 d . .
N8 N 0.5934(4) 0.9354(4) 0.7369(2) 0.0400(9) Uani 1 1 d . .
N9 N 0.1068(5) 0.9221(5) 0.7129(2) 0.0422(10) Uani 1 1 d . .
F1 F 0.8327(6) 0.4819(5) 0.9324(2) 0.0997(15) Uani 1 1 d . .
F2 F 0.6133(8) 0.2992(8) 0.9285(4) 0.173(3) Uani 1 1 d . .
F3 F 0.6038(8) 0.4459(6) 0.8690(3) 0.145(3) Uani 1 1 d . .
F4 F 0.5789(8) 0.2384(6) 0.8109(3) 0.153(3) Uani 1 1 d . .
F5 F 0.8143(9) 0.2782(6) 0.8732(4) 0.146(2) Uani 1 1 d . .
F6 F 0.8039(9) 0.4241(8) 0.8149(3) 0.170(3) Uani 1 1 d . .
F7 F 0.2805(8) 0.3050(6) 0.4517(4) 0.145(3) Uani 1 1 d . .
F8 F 0.2692(8) 0.0911(5) 0.4386(3) 0.133(2) Uani 1 1 d . .
F9 F 0.5012(10) 0.2630(8) 0.4370(4) 0.183(3) Uani 1 1 d . .
F10 F 0.4608(7) 0.1750(6) 0.5288(3) 0.134(2) Uani 1 1 d . .
F11 F 0.4745(7) 0.3848(5) 0.5391(3) 0.123(2) Uani 1 1 d . .
F12 F 0.2401(9) 0.2136(7) 0.5376(4) 0.176(3) Uani 1 1 d . .
C1 C 1.2029(7) 0.5263(6) 0.6160(3) 0.0516(14) Uani 1 1 d . .
H1 H 1.2994 0.5287 0.5991 0.062 Uiso 1 1 calc R U
C2 C 1.0593(7) 0.4433(7) 0.5718(3) 0.0573(15) Uani 1 1 d . .
H2 H 1.0594 0.3880 0.5271 0.069 Uiso 1 1 calc R U
C3 C 0.9167(7) 0.4438(6) 0.5948(3) 0.0518(13) Uani 1 1 d . .
H3 H 0.8187 0.3898 0.5657 0.062 Uiso 1 1 calc R U
C4 C 0.9213(5) 0.5263(5) 0.6622(3) 0.0344(10) Uani 1 1 d . .
C5 C 1.0692(5) 0.6022(5) 0.7034(3) 0.0384(11) Uani 1 1 d . .
H5 H 1.0715 0.6557 0.7490 0.046 Uiso 1 1 calc R U
C6 C 0.7753(5) 0.5335(5) 0.6896(2) 0.0348(10) Uani 1 1 d . .
C7 C 0.5294(5) 0.4556(5) 0.7103(3) 0.0400(11) Uani 1 1 d . .
C8 C 0.3676(6) 0.3521(6) 0.7119(3) 0.0556(15) Uani 1 1 d . .
H8A H 0.3715 0.3111 0.7497 0.083 Uiso 1 1 d R U
H8B H 0.3329 0.2818 0.6672 0.083 Uiso 1 1 d R U
H8C H 0.2928 0.3960 0.7197 0.083 Uiso 1 1 d R U
C9 C 0.8153(7) 0.9966(6) 0.9391(3) 0.0467(12) Uani 1 1 d . .
H9 H 0.8382 1.0780 0.9261 0.056 Uiso 1 1 calc R U
C10 C 0.7547(7) 0.9856(6) 1.0024(3) 0.0487(13) Uani 1 1 d . .
C11 C 0.7181(9) 0.8674(7) 1.0214(3) 0.0656(17) Uani 1 1 d . .
H11 H 0.6755 0.8584 1.0638 0.079 Uiso 1 1 calc R U
C12 C 0.7447(10) 0.7603(7) 0.9770(3) 0.076(2) Uani 1 1 d . .
H12 H 0.7204 0.6780 0.9891 0.091 Uiso 1 1 calc R U
C13 C 0.8074(8) 0.7759(6) 0.9145(3) 0.0559(14) Uani 1 1 d . .
H13 H 0.8260 0.7033 0.8850 0.067 Uiso 1 1 calc R U
C14 C 0.7273(7) 1.1013(6) 1.0501(3) 0.0463(12) Uani 1 1 d . .
C15 C 0.7298(8) 1.3009(6) 1.0907(3) 0.0520(14) Uani 1 1 d . .
C16 C 0.7661(11) 1.4474(7) 1.0964(4) 0.085(2) Uani 1 1 d . .
H16A H 0.7075 1.4535 1.0568 0.128 Uiso 1 1 d R U
H16B H 0.8802 1.4960 1.0963 0.128 Uiso 1 1 d R U
H16C H 0.7344 1.4878 1.1400 0.128 Uiso 1 1 d R U
C17 C 0.0526(7) 0.9013(6) 0.6456(3) 0.0520(14) Uani 1 1 d . .
H17 H -0.0579 0.8739 0.6337 0.062 Uiso 1 1 calc R U
C18 C 0.1518(7) 0.9183(7) 0.5914(3) 0.0619(16) Uani 1 1 d . .
H18 H 0.1097 0.9078 0.5455 0.074 Uiso 1 1 calc R U
C19 C 0.3147(7) 0.9512(7) 0.6086(3) 0.0545(14) Uani 1 1 d . .
H19 H 0.3851 0.9627 0.5743 0.065 Uiso 1 1 calc R U
C20 C 0.3704(6) 0.9665(5) 0.6781(3) 0.0380(10) Uani 1 1 d . .
C21 C 0.2641(5) 0.9523(5) 0.7283(3) 0.0372(10) Uani 1 1 d . .
H21 H 0.3035 0.9643 0.7749 0.045 Uiso 1 1 calc R U
C22 C 0.5395(5) 0.9950(5) 0.6996(2) 0.0363(10) Uani 1 1 d . .
C23 C 0.7947(6) 1.0919(6) 0.7083(3) 0.0473(13) Uani 1 1 d . .
C24 C 0.9537(7) 1.1911(7) 0.6988(5) 0.077(2) Uani 1 1 d . .
H24A H 1.0382 1.1765 0.7218 0.115 Uiso 1 1 d R U
H24B H 0.9628 1.2836 0.7197 0.115 Uiso 1 1 d R U
H24C H 0.9634 1.1777 0.6489 0.115 Uiso 1 1 d R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag1 N4 124.79(16) 1_655 2_777
N2 Ag1 N8 111.05(14) 1_655 1_655
N4 Ag1 N8 109.87(16) 2_777 1_655
N2 Ag1 N3 102.49(14) 1_655 .
N4 Ag1 N3 98.30(17) 2_777 .
N8 Ag1 N3 108.07(14) 1_655 .
N6 Ag2 N9 152.34(16) . 1_655
N6 Ag2 N7 102.44(15) . .
N9 Ag2 N7 98.82(15) 1_655 .
N6 Ag2 N1 97.59(15) . .
N9 Ag2 N1 95.79(14) 1_655 .
N7 Ag2 N1 100.30(14) . .
F2 P1 F5 90.2(4) . .
F2 P1 F6 179.1(4) . .
F5 P1 F6 90.1(4) . .
F2 P1 F3 91.6(5) . .
F5 P1 F3 178.1(5) . .
F6 P1 F3 88.1(4) . .
F2 P1 F1 89.5(3) . .
F5 P1 F1 88.4(3) . .
F6 P1 F1 89.7(4) . .
F3 P1 F1 91.0(3) . .
F2 P1 F4 90.2(4) . .
F5 P1 F4 92.4(4) . .
F6 P1 F4 90.7(4) . .
F3 P1 F4 88.2(3) . .
F1 P1 F4 179.1(4) . .
F9 P2 F10 92.5(4) . .
F9 P2 F11 90.5(4) . .
F10 P2 F11 90.6(3) . .
F9 P2 F12 177.3(5) . .
F10 P2 F12 89.9(4) . .
F11 P2 F12 90.8(4) . .
F9 P2 F8 92.0(4) . .
F10 P2 F8 89.6(3) . .
F11 P2 F8 177.5(4) . .
F12 P2 F8 86.8(4) . .
F9 P2 F7 91.9(4) . .
F10 P2 F7 175.5(4) . .
F11 P2 F7 88.2(3) . .
F12 P2 F7 85.7(4) . .
F8 P2 F7 91.4(3) . .
C7 O1 C6 103.8(4) . .
C14 O2 C15 103.3(4) . .
C22 O3 C23 103.2(4) . .
C6 N1 N2 105.9(4) . .
C6 N1 Ag2 137.5(3) . .
N2 N1 Ag2 115.7(3) . .
C7 N2 N1 106.9(4) . .
C7 N2 Ag1 128.6(3) . 1_455
N1 N2 Ag1 120.5(3) . 1_455
C5 N3 C1 117.0(4) . .
C5 N3 Ag1 119.8(3) . .
C1 N3 Ag1 123.2(3) . .
C15 N4 N5 107.6(4) . .
C15 N4 Ag1 135.6(4) . 2_777
N5 N4 Ag1 116.9(3) . 2_777
C14 N5 N4 104.4(5) . .
C13 N6 C9 117.8(5) . .
C13 N6 Ag2 117.8(3) . .
C9 N6 Ag2 124.1(4) . .
C23 N7 N8 106.8(4) . .
C23 N7 Ag2 134.3(3) . .
N8 N7 Ag2 117.6(3) . .
C22 N8 N7 105.2(4) . .
C22 N8 Ag1 128.3(3) . 1_455
N7 N8 Ag1 124.4(3) . 1_455
C17 N9 C21 117.4(4) . .
C17 N9 Ag2 115.4(3) . 1_455
C21 N9 Ag2 127.1(3) . 1_455
N3 C1 C2 122.9(5) . .
N3 C1 H1 118.6 . .
C2 C1 H1 118.6 . .
C3 C2 C1 119.1(5) . .
C3 C2 H2 120.5 . .
C1 C2 H2 120.5 . .
C2 C3 C4 118.8(5) . .
C2 C3 H3 120.6 . .
C4 C3 H3 120.6 . .
C5 C4 C3 118.2(4) . .
C5 C4 C6 120.1(4) . .
C3 C4 C6 121.7(4) . .
N3 C5 C4 124.1(5) . .
N3 C5 H5 118.0 . .
C4 C5 H5 118.0 . .
N1 C6 O1 111.7(4) . .
N1 C6 C4 129.5(4) . .
O1 C6 C4 118.7(4) . .
N2 C7 O1 111.6(4) . .
N2 C7 C8 129.1(5) . .
O1 C7 C8 119.2(5) . .
C7 C8 H8A 109.5 . .
C7 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C7 C8 H8C 109.4 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
N6 C9 C10 121.7(5) . .
N6 C9 H9 119.1 . .
C10 C9 H9 119.1 . .
C11 C10 C9 119.9(5) . .
C11 C10 C14 119.2(5) . .
C9 C10 C14 120.9(5) . .
C10 C11 C12 118.9(5) . .
C10 C11 H11 120.6 . .
C12 C11 H11 120.6 . .
C13 C12 C11 119.5(6) . .
C13 C12 H12 120.2 . .
C11 C12 H12 120.2 . .
N6 C13 C12 122.1(5) . .
N6 C13 H13 118.9 . .
C12 C13 H13 118.9 . .
N5 C14 O2 113.7(5) . .
N5 C14 C10 125.4(5) . .
O2 C14 C10 120.9(4) . .
N4 C15 O2 110.9(5) . .
N4 C15 C16 128.6(5) . .
O2 C15 C16 120.4(5) . .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 C16 H16C 109.4 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
N9 C17 C18 123.9(5) . .
N9 C17 H17 118.1 . .
C18 C17 H17 118.1 . .
C19 C18 C17 117.7(5) . .
C19 C18 H18 121.2 . .
C17 C18 H18 121.2 . .
C20 C19 C18 118.5(5) . .
C20 C19 H19 120.7 . .
C18 C19 H19 120.7 . .
C21 C20 C19 119.4(4) . .
C21 C20 C22 118.9(4) . .
C19 C20 C22 121.7(4) . .
N9 C21 C20 122.9(5) . .
N9 C21 H21 118.6 . .
C20 C21 H21 118.6 . .
N8 C22 O3 112.8(4) . .
N8 C22 C20 127.7(4) . .
O3 C22 C20 119.5(4) . .
N7 C23 O3 112.0(4) . .
N7 C23 C24 128.9(5) . .
O3 C23 C24 119.1(5) . .
C23 C24 H24A 109.5 . .
C23 C24 H24B 109.4 . .
H24A C24 H24B 109.5 . .
C23 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N2 2.277(4) 1_655
Ag1 N4 2.307(4) 2_777
Ag1 N8 2.309(4) 1_655
Ag1 N3 2.406(4) .
Ag2 N6 2.225(4) .
Ag2 N9 2.231(4) 1_655
Ag2 N7 2.421(4) .
Ag2 N1 2.554(4) .
P1 F2 1.536(6) .
P1 F5 1.549(5) .
P1 F6 1.558(6) .
P1 F3 1.563(5) .
P1 F1 1.571(5) .
P1 F4 1.581(5) .
P2 F9 1.515(6) .
P2 F10 1.542(5) .
P2 F11 1.553(5) .
P2 F12 1.555(6) .
P2 F8 1.567(5) .
P2 F7 1.567(5) .
O1 C7 1.346(6) .
O1 C6 1.369(6) .
O2 C14 1.339(6) .
O2 C15 1.356(6) .
O3 C22 1.346(5) .
O3 C23 1.354(6) .
N1 C6 1.282(6) .
N1 N2 1.411(5) .
N2 C7 1.286(6) .
N2 Ag1 2.277(4) 1_455
N3 C5 1.330(6) .
N3 C1 1.345(7) .
N4 C15 1.275(7) .
N4 N5 1.412(7) .
N4 Ag1 2.307(4) 2_777
N5 C14 1.273(7) .
N6 C13 1.332(7) .
N6 C9 1.361(6) .
N7 C23 1.278(7) .
N7 N8 1.408(5) .
N8 C22 1.286(6) .
N8 Ag1 2.309(4) 1_455
N9 C17 1.326(7) .
N9 C21 1.337(6) .
N9 Ag2 2.231(4) 1_455
C1 C2 1.383(8) .
C1 H1 0.9300 .
C2 C3 1.372(7) .
C2 H2 0.9300 .
C3 C4 1.389(7) .
C3 H3 0.9300 .
C4 C5 1.376(6) .
C4 C6 1.452(6) .
C5 H5 0.9300 .
C7 C8 1.469(7) .
C8 H8A 0.9600 .
C8 H8B 0.9600 .
C8 H8C 0.9600 .
C9 C10 1.375(7) .
C9 H9 0.9300 .
C10 C11 1.349(8) .
C10 C14 1.478(7) .
C11 C12 1.377(9) .
C11 H11 0.9300 .
C12 C13 1.375(8) .
C12 H12 0.9300 .
C13 H13 0.9300 .
C15 C16 1.476(8) .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C17 C18 1.400(8) .
C17 H17 0.9300 .
C18 C19 1.385(8) .
C18 H18 0.9300 .
C19 C20 1.385(7) .
C19 H19 0.9300 .
C20 C21 1.379(6) .
C20 C22 1.464(6) .
C21 H21 0.9300 .
C23 C24 1.476(7) .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C6 N1 N2 C7 0.0(5) . .
Ag2 N1 N2 C7 -171.2(3) . .
C6 N1 N2 Ag1 -159.3(3) . 1_455
Ag2 N1 N2 Ag1 29.5(4) . 1_455
C15 N4 N5 C14 -0.4(7) . .
Ag1 N4 N5 C14 -179.7(4) 2_777 .
C23 N7 N8 C22 0.7(6) . .
Ag2 N7 N8 C22 -168.1(3) . .
C23 N7 N8 Ag1 165.7(4) . 1_455
Ag2 N7 N8 Ag1 -3.1(5) . 1_455
C5 N3 C1 C2 -2.7(8) . .
Ag1 N3 C1 C2 173.4(4) . .
N3 C1 C2 C3 2.9(9) . .
C1 C2 C3 C4 -0.9(9) . .
C2 C3 C4 C5 -1.1(8) . .
C2 C3 C4 C6 179.0(5) . .
C1 N3 C5 C4 0.5(7) . .
Ag1 N3 C5 C4 -175.7(4) . .
C3 C4 C5 N3 1.4(8) . .
C6 C4 C5 N3 -178.7(4) . .
N2 N1 C6 O1 -0.4(5) . .
Ag2 N1 C6 O1 167.7(3) . .
N2 N1 C6 C4 -179.7(5) . .
Ag2 N1 C6 C4 -11.5(8) . .
C7 O1 C6 N1 0.7(5) . .
C7 O1 C6 C4 -180.0(4) . .
C5 C4 C6 N1 42.9(8) . .
C3 C4 C6 N1 -137.3(6) . .
C5 C4 C6 O1 -136.3(5) . .
C3 C4 C6 O1 43.5(7) . .
N1 N2 C7 O1 0.4(5) . .
Ag1 N2 C7 O1 157.5(3) 1_455 .
N1 N2 C7 C8 177.3(5) . .
Ag1 N2 C7 C8 -25.6(8) 1_455 .
C6 O1 C7 N2 -0.7(5) . .
C6 O1 C7 C8 -177.9(5) . .
C13 N6 C9 C10 0.5(8) . .
Ag2 N6 C9 C10 174.5(4) . .
N6 C9 C10 C11 -1.2(9) . .
N6 C9 C10 C14 179.4(5) . .
C9 C10 C11 C12 0.9(10) . .
C14 C10 C11 C12 -179.6(6) . .
C10 C11 C12 C13 -0.1(12) . .
C9 N6 C13 C12 0.3(9) . .
Ag2 N6 C13 C12 -174.0(5) . .
C11 C12 C13 N6 -0.6(12) . .
N4 N5 C14 O2 1.7(7) . .
N4 N5 C14 C10 -179.6(5) . .
C15 O2 C14 N5 -2.3(7) . .
C15 O2 C14 C10 179.0(5) . .
C11 C10 C14 N5 -6.4(10) . .
C9 C10 C14 N5 173.0(6) . .
C11 C10 C14 O2 172.2(6) . .
C9 C10 C14 O2 -8.4(8) . .
N5 N4 C15 O2 -1.0(7) . .
Ag1 N4 C15 O2 178.2(4) 2_777 .
N5 N4 C15 C16 -178.0(7) . .
Ag1 N4 C15 C16 1.2(11) 2_777 .
C14 O2 C15 N4 1.9(7) . .
C14 O2 C15 C16 179.2(6) . .
C21 N9 C17 C18 -4.4(9) . .
Ag2 N9 C17 C18 178.1(5) 1_455 .
N9 C17 C18 C19 3.7(10) . .
C17 C18 C19 C20 -0.5(9) . .
C18 C19 C20 C21 -1.7(9) . .
C18 C19 C20 C22 177.2(5) . .
C17 N9 C21 C20 2.0(8) . .
Ag2 N9 C21 C20 179.1(4) 1_455 .
C19 C20 C21 N9 1.0(8) . .
C22 C20 C21 N9 -177.9(4) . .
N7 N8 C22 O3 0.1(5) . .
Ag1 N8 C22 O3 -164.1(3) 1_455 .
N7 N8 C22 C20 179.6(5) . .
Ag1 N8 C22 C20 15.4(7) 1_455 .
C23 O3 C22 N8 -0.8(6) . .
C23 O3 C22 C20 179.6(5) . .
C21 C20 C22 N8 46.1(8) . .
C19 C20 C22 N8 -132.8(6) . .
C21 C20 C22 O3 -134.4(5) . .
C19 C20 C22 O3 46.6(7) . .
N8 N7 C23 O3 -1.2(6) . .
Ag2 N7 C23 O3 164.8(3) . .
N8 N7 C23 C24 178.3(6) . .
Ag2 N7 C23 C24 -15.6(10) . .
C22 O3 C23 N7 1.3(6) . .
C22 O3 C23 C24 -178.3(6) . .
