#------------------------------------------------------------------------------
#$Date: 2017-05-09 04:35:02 +0300 (Tue, 09 May 2017) $
#$Revision: 196565 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/82/7228232.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7228232
loop_
_publ_author_name
'Fukushima, Misaki'
'Kikkawa, Shoko'
'hikawa, hidemasa'
'Azumaya, Isao'
_publ_section_title
;
 Synthesis and Solvent Vapor Induced Transformations of Crystals of 1D
 Coordination Polymer Assembled with Continuous Void Space
;
_journal_name_full               CrystEngComm
_journal_paper_doi               10.1039/C7CE00640C
_journal_year                    2017
_chemical_absolute_configuration ad
_chemical_formula_moiety         'C27 H18 Ag B Cl2 F4 N2'
_chemical_formula_sum            'C27 H18 Ag B Cl2 F4 N2'
_chemical_formula_weight         636.03
_space_group_crystal_system      orthorhombic
_space_group_IT_number           18
_space_group_name_Hall           'P 2 2ab'
_space_group_name_H-M_alt        'P 21 21 2'
_symmetry_space_group_name_Hall  'P 2 2ab'
_symmetry_space_group_name_H-M   'P 21 21 2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_update_record
;
2017-01-26 deposited with the CCDC.
2017-05-08 downloaded from the CCDC.
;
_cell_angle_alpha                90.0000
_cell_angle_beta                 90.0000
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   16.4929(16)
_cell_length_b                   12.6770(11)
_cell_length_c                   11.4596(10)
_cell_measurement_reflns_used    8459
_cell_measurement_temperature    93
_cell_measurement_theta_max      27.50
_cell_measurement_theta_min      3.00
_cell_volume                     2396.0(4)
_computing_cell_refinement       'CrystalClear-SM Expert 2.1 b29'
_computing_data_collection
'CrystalClear-SM Expert 2.1 b29 (Rigaku, 2013)'
_computing_data_reduction        'CrystalClear-SM Expert 2.1 b29'
_computing_molecular_graphics    'CrystalStructure 4.2.2'
_computing_publication_material  'CrystalStructure 4.2.2 (Rigaku, 2016)'
_computing_structure_refinement  'SHELXL Version 2014/7 (Sheldrick, 2008)'
_computing_structure_solution    'SIR92 (Altomare, et al., 1994)'
_diffrn_ambient_temperature      93
_diffrn_detector_area_resol_mean 5.814
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Rigaku XtaLAB P200'
_diffrn_measurement_method       ω
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0280
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            77808
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.491
_diffrn_reflns_theta_min         3.442
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.114
_exptl_absorpt_correction_T_max  0.956
_exptl_absorpt_correction_T_min  0.772
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'NUMABS (Rigaku, 1999)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.763
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1264.00
_exptl_crystal_size_max          0.420
_exptl_crystal_size_mid          0.280
_exptl_crystal_size_min          0.040
_refine_diff_density_max         0.51
_refine_diff_density_min         -0.50
_refine_ls_abs_structure_details
;
 Flack x determined using 2284 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.022(4)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    refxyz
_refine_ls_number_parameters     375
_refine_ls_number_reflns         5490
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0191
_refine_ls_R_factor_gt           0.0183
_refine_ls_shift/su_max          0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.0317P)²+0.8538P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0500
_refine_ls_wR_factor_ref         0.0504
_reflns_Friedel_coverage         0.776
_reflns_Friedel_fraction_full    0.999
_reflns_Friedel_fraction_max     1.000
_reflns_number_gt                5314
_reflns_number_total             5490
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            c7ce00640c2.cif
_cod_data_source_block           mfu106-3b-2
_cod_database_code               7228232
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 +X,+Y,+Z
2 -X,-Y,+Z
3 1/2+X,1/2-Y,-Z
4 1/2-X,1/2+Y,-Z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.5000 0.5000 0.97327(2) 0.02203(7) Uani 1 2 d S T P . .
Ag2 Ag 0.0000 0.5000 1.13729(2) 0.02309(7) Uani 1 2 d S T P . .
Cl1 Cl 0.29738(6) 0.70536(9) 0.66700(8) 0.0580(3) Uani 1 1 d . . . . .
Cl2 Cl 0.41326(4) 0.75991(6) 0.84969(8) 0.04156(19) Uani 1 1 d . . . . .
F1 F 0.31907(11) 0.51484(18) 0.95807(18) 0.0483(5) Uani 1 1 d . . . . .
F2 F 0.25031(16) 0.3594(2) 0.9670(3) 0.0322(6) Uani 0.75 1 d . . P A 1
F3 F 0.20373(14) 0.4927(3) 0.85561(17) 0.0400(5) Uani 0.75 1 d . . P A 1
F4 F 0.19648(18) 0.5056(4) 1.0525(2) 0.0441(6) Uani 0.75 1 d . . P A 1
N1 N 0.5000 0.5000 0.78507(19) 0.0152(4) Uani 1 2 d S T P . .
N2 N 0.5000 0.5000 0.16163(19) 0.0146(4) Uani 1 2 d S T P . .
N3 N 0.0000 0.5000 0.3253(2) 0.0170(4) Uani 1 2 d S T P . .
N4 N 0.0000 0.5000 0.9503(2) 0.0151(4) Uani 1 2 d S T P . .
C1 C 0.40600(15) 0.35571(19) 0.7882(2) 0.0186(5) Uani 1 1 d . . . . .
H1 H 0.4045 0.3588 0.8710 0.022 Uiso 1 1 calc R U . . .
C2 C 0.36172(15) 0.2810(2) 0.7312(2) 0.0202(5) Uani 1 1 d . . . . .
H2 H 0.3305 0.2318 0.7748 0.024 Uiso 1 1 calc R U . . .
C3 C 0.36164(14) 0.27573(19) 0.6074(2) 0.0186(5) Uani 1 1 d . . . . .
H3 H 0.3311 0.2227 0.5687 0.022 Uiso 1 1 calc R U . . .
C4 C 0.40558(14) 0.34707(18) 0.5439(2) 0.0152(4) Uani 1 1 d . . . . .
H4 H 0.4042 0.3441 0.4611 0.018 Uiso 1 1 calc R U . . .
C5 C 0.45357(13) 0.42605(18) 0.60052(19) 0.0128(4) Uani 1 1 d . . . . .
C6 C 0.45455(13) 0.42939(18) 0.72499(19) 0.0146(4) Uani 1 1 d . . . . .
C7 C 0.5000 0.5000 0.5384(2) 0.0122(5) Uani 1 2 d S T P . .
C8 C 0.5000 0.5000 0.4081(2) 0.0114(5) Uani 1 2 d S T P . .
C9 C 0.45265(12) 0.57336(17) 0.34630(19) 0.0120(4) Uani 1 1 d . . . . .
C10 C 0.45390(13) 0.57032(18) 0.22146(19) 0.0141(4) Uani 1 1 d . . . . .
C11 C 0.40658(15) 0.64511(19) 0.1581(2) 0.0204(5) Uani 1 1 d . . . . .
H11 H 0.4062 0.6432 0.0752 0.024 Uiso 1 1 calc R U . . .
C12 C 0.36194(15) 0.7193(2) 0.2155(2) 0.0247(5) Uani 1 1 d . . . . .
H12 H 0.3314 0.7693 0.1722 0.030 Uiso 1 1 calc R U . . .
C13 C 0.36061(14) 0.72248(19) 0.3393(2) 0.0222(5) Uani 1 1 d . . . . .
H13 H 0.3290 0.7744 0.3780 0.027 Uiso 1 1 calc R U . . .
C14 C 0.40445(14) 0.65157(18) 0.4033(2) 0.0162(4) Uani 1 1 d . . . . .
H14 H 0.4029 0.6543 0.4862 0.019 Uiso 1 1 calc R U . . .
C15 C 0.0000 0.5000 0.5727(2) 0.0126(5) Uani 1 2 d S T P . .
C16 C 0.07369(12) 0.4956(2) 0.51017(16) 0.0140(4) Uani 1 1 d . . . . .
C17 C 0.07093(12) 0.4977(2) 0.38473(16) 0.0156(4) Uani 1 1 d . . . . .
C18 C 0.14512(13) 0.4974(2) 0.32068(17) 0.0206(4) Uani 1 1 d . . . . .
H18 H 0.1439 0.4984 0.2378 0.025 Uiso 1 1 calc R U . . .
C19 C 0.21774(13) 0.4956(3) 0.37735(19) 0.0235(4) Uani 1 1 d . . . . .
H19 H 0.2667 0.4964 0.3336 0.028 Uiso 1 1 calc R U . . .
C20 C 0.22103(13) 0.4925(3) 0.5011(2) 0.0213(4) Uani 1 1 d . . . . .
H20 H 0.2721 0.4904 0.5393 0.026 Uiso 1 1 calc R U . . .
C21 C 0.15124(12) 0.4925(2) 0.56596(18) 0.0167(4) Uani 1 1 d . . . . .
H21 H 0.1544 0.4904 0.6487 0.020 Uiso 1 1 calc R U . . .
C22 C 0.0000 0.5000 0.7030(2) 0.0137(5) Uani 1 2 d S T P . .
C23 C 0.03039(13) 0.58720(18) 0.76529(18) 0.0130(4) Uani 1 1 d . . . . .
C24 C 0.03125(13) 0.58271(18) 0.89067(19) 0.0144(4) Uani 1 1 d . . . . .
C25 C 0.06741(14) 0.6673(2) 0.9541(2) 0.0173(4) Uani 1 1 d . . . . .
H25 H 0.0689 0.6648 1.0369 0.021 Uiso 1 1 calc R U . . .
C26 C 0.09968(14) 0.7514(2) 0.8973(2) 0.0190(5) Uani 1 1 d . . . . .
H26 H 0.1246 0.8064 0.9407 0.023 Uiso 1 1 calc R U . . .
C27 C 0.09651(14) 0.75795(18) 0.7740(2) 0.0166(4) Uani 1 1 d . . . . .
H27 H 0.1185 0.8179 0.7356 0.020 Uiso 1 1 calc R U . . .
C28 C 0.06221(13) 0.67886(18) 0.7096(2) 0.0157(4) Uani 1 1 d . . . . .
H28 H 0.0595 0.6850 0.6270 0.019 Uiso 1 1 calc R U . . .
C29 C 0.31004(16) 0.7396(3) 0.8151(2) 0.0311(6) Uani 1 1 d . . . . .
H29A H 0.2880 0.6827 0.8649 0.037 Uiso 1 1 calc R U . . .
H29B H 0.2791 0.8049 0.8318 0.037 Uiso 1 1 calc R U . . .
B1 B 0.2422(3) 0.4681(4) 0.9596(4) 0.0216(9) Uani 0.75 1 d . . P A 1
B2 B 0.2553(9) 0.4859(15) 1.023(2) 0.040(4) Uani 0.25 1 d . . P A 2
F6 F 0.2938(5) 0.4491(6) 1.1271(7) 0.0403(17) Uani 0.25 1 d . . P A 2
F7 F 0.2102(12) 0.4128(18) 0.9814(15) 0.124(8) Uani 0.25 1 d . . P A 2
F8 F 0.2142(9) 0.5779(13) 1.0576(11) 0.085(4) Uani 0.25 1 d . . P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Table 6.1.1.4)
;
Ag Ag -0.8971 1.1015
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
B B 0.0013 0.0007
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
F F 0.0171 0.0103
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Cl Cl 0.1484 0.1585
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
N N 0.0061 0.0033
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N2 180.0 . 1_556
N4 Ag2 N3 180.0 . 1_556
C6 N1 C6 118.9(2) . 2_665
C6 N1 Ag1 120.53(12) . .
C6 N1 Ag1 120.53(12) 2_665 .
C10 N2 C10 119.3(2) . 2_665
C10 N2 Ag1 120.34(12) . 1_554
C10 N2 Ag1 120.34(12) 2_665 1_554
C17 N3 C17 119.6(2) 2_565 .
C17 N3 Ag2 120.22(11) 2_565 1_554
C17 N3 Ag2 120.22(11) . 1_554
C24 N4 C24 119.4(3) . 2_565
C24 N4 Ag2 120.32(13) . .
C24 N4 Ag2 120.32(13) 2_565 .
C2 C1 C6 120.8(2) . .
C2 C1 H1 119.6 . .
C6 C1 H1 119.6 . .
C1 C2 C3 120.8(2) . .
C1 C2 H2 119.6 . .
C3 C2 H2 119.6 . .
C4 C3 C2 120.0(2) . .
C4 C3 H3 120.0 . .
C2 C3 H3 120.0 . .
C3 C4 C5 120.9(2) . .
C3 C4 H4 119.5 . .
C5 C4 H4 119.5 . .
C7 C5 C6 118.7(2) . .
C7 C5 C4 122.61(19) . .
C6 C5 C4 118.7(2) . .
N1 C6 C5 122.2(2) . .
N1 C6 C1 119.0(2) . .
C5 C6 C1 118.8(2) . .
C5 C7 C5 119.1(2) 2_665 .
C5 C7 C8 120.45(12) 2_665 .
C5 C7 C8 120.45(12) . .
C9 C8 C9 119.5(2) . 2_665
C9 C8 C7 120.25(12) . .
C9 C8 C7 120.26(12) 2_665 .
C8 C9 C14 122.51(19) . .
C8 C9 C10 118.54(19) . .
C14 C9 C10 118.9(2) . .
N2 C10 C11 119.1(2) . .
N2 C10 C9 122.0(2) . .
C11 C10 C9 118.9(2) . .
C12 C11 C10 120.5(2) . .
C12 C11 H11 119.7 . .
C10 C11 H11 119.7 . .
C11 C12 C13 120.7(2) . .
C11 C12 H12 119.7 . .
C13 C12 H12 119.7 . .
C14 C13 C12 120.6(2) . .
C14 C13 H13 119.7 . .
C12 C13 H13 119.7 . .
C13 C14 C9 120.3(2) . .
C13 C14 H14 119.8 . .
C9 C14 H14 119.8 . .
C16 C15 C16 119.0(2) 2_565 .
C16 C15 C22 120.50(12) 2_565 .
C16 C15 C22 120.50(12) . .
C15 C16 C21 122.94(18) . .
C15 C16 C17 118.64(18) . .
C21 C16 C17 118.39(17) . .
N3 C17 C18 118.81(18) . .
N3 C17 C16 122.06(18) . .
C18 C17 C16 119.14(18) . .
C19 C18 C17 120.57(18) . .
C19 C18 H18 119.7 . .
C17 C18 H18 119.7 . .
C18 C19 C20 120.66(19) . .
C18 C19 H19 119.7 . .
C20 C19 H19 119.7 . .
C21 C20 C19 120.7(2) . .
C21 C20 H20 119.7 . .
C19 C20 H20 119.7 . .
C20 C21 C16 120.58(19) . .
C20 C21 H21 119.7 . .
C16 C21 H21 119.7 . .
C23 C22 C23 119.1(2) . 2_565
C23 C22 C15 120.44(12) . .
C23 C22 C15 120.44(12) 2_565 .
C22 C23 C28 123.0(2) . .
C22 C23 C24 118.6(2) . .
C28 C23 C24 118.4(2) . .
N4 C24 C25 119.0(2) . .
N4 C24 C23 122.1(2) . .
C25 C24 C23 118.9(2) . .
C26 C25 C24 120.7(2) . .
C26 C25 H25 119.7 . .
C24 C25 H25 119.7 . .
C25 C26 C27 120.7(2) . .
C25 C26 H26 119.7 . .
C27 C26 H26 119.7 . .
C28 C27 C26 120.7(2) . .
C28 C27 H27 119.6 . .
C26 C27 H27 119.6 . .
C27 C28 C23 120.5(2) . .
C27 C28 H28 119.7 . .
C23 C28 H28 119.7 . .
Cl1 C29 Cl2 111.47(15) . .
Cl1 C29 H29A 109.3 . .
Cl2 C29 H29A 109.3 . .
Cl1 C29 H29B 109.3 . .
Cl2 C29 H29B 109.3 . .
H29A C29 H29B 108.0 . .
F3 B1 F2 108.7(4) . .
F3 B1 F4 109.5(3) . .
F2 B1 F4 110.2(4) . .
F3 B1 F1 108.0(3) . .
F2 B1 F1 109.5(3) . .
F4 B1 F1 110.9(4) . .
F7 B2 F1 117(2) . .
F7 B2 F8 115.2(18) . .
F1 B2 F8 108.0(14) . .
F7 B2 F6 109.3(15) . .
F1 B2 F6 101.7(11) . .
F8 B2 F6 104.2(18) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.157(2) .
Ag1 N2 2.159(2) 1_556
Ag2 N4 2.143(2) .
Ag2 N3 2.154(2) 1_556
Cl1 C29 1.764(3) .
Cl2 C29 1.767(3) .
F1 B2 1.337(17) .
F1 B1 1.400(5) .
F2 B1 1.388(6) .
F3 B1 1.385(5) .
F4 B1 1.389(5) .
N1 C6 1.355(3) .
N1 C6 1.355(3) 2_665
N2 C10 1.358(3) .
N2 C10 1.358(3) 2_665
N2 Ag1 2.159(2) 1_554
N3 C17 1.354(2) 2_565
N3 C17 1.354(2) .
N3 Ag2 2.154(2) 1_554
N4 C24 1.353(3) .
N4 C24 1.353(3) 2_565
C1 C2 1.363(4) .
C1 C6 1.428(3) .
C1 H1 0.9500 .
C2 C3 1.420(3) .
C2 H2 0.9500 .
C3 C4 1.369(3) .
C3 H3 0.9500 .
C4 C5 1.432(3) .
C4 H4 0.9500 .
C5 C7 1.404(2) .
C5 C6 1.427(3) .
C7 C5 1.404(2) 2_665
C7 C8 1.493(3) .
C8 C9 1.406(2) .
C8 C9 1.406(2) 2_665
C9 C14 1.429(3) .
C9 C10 1.431(3) .
C10 C11 1.427(3) .
C11 C12 1.363(4) .
C11 H11 0.9500 .
C12 C13 1.419(4) .
C12 H12 0.9500 .
C13 C14 1.367(3) .
C13 H13 0.9500 .
C14 H14 0.9500 .
C15 C16 1.412(2) 2_565
C15 C16 1.412(2) .
C15 C22 1.494(3) .
C16 C21 1.430(3) .
C16 C17 1.438(2) .
C17 C18 1.427(3) .
C18 C19 1.363(3) .
C18 H18 0.9500 .
C19 C20 1.420(3) .
C19 H19 0.9500 .
C20 C21 1.370(3) .
C20 H20 0.9500 .
C21 H21 0.9500 .
C22 C23 1.408(2) .
C22 C23 1.408(2) 2_565
C23 C28 1.426(3) .
C23 C24 1.438(3) .
C24 C25 1.426(3) .
C25 C26 1.357(4) .
C25 H25 0.9500 .
C26 C27 1.416(3) .
C26 H26 0.9500 .
C27 C28 1.368(3) .
C27 H27 0.9500 .
C28 H28 0.9500 .
C29 H29A 0.9900 .
C29 H29B 0.9900 .
B2 F7 1.28(3) .
B2 F8 1.41(2) .
B2 F6 1.43(2) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C6 C1 C2 C3 -1.1(4) . .
C1 C2 C3 C4 -0.8(4) . .
C2 C3 C4 C5 1.5(4) . .
C3 C4 C5 C7 179.44(19) . .
C3 C4 C5 C6 -0.2(3) . .
C6 N1 C6 C5 0.70(16) 2_665 .
Ag1 N1 C6 C5 -179.30(16) . .
C6 N1 C6 C1 -179.3(2) 2_665 .
Ag1 N1 C6 C1 0.7(2) . .
C7 C5 C6 N1 -1.4(3) . .
C4 C5 C6 N1 178.31(18) . .
C7 C5 C6 C1 178.66(18) . .
C4 C5 C6 C1 -1.6(3) . .
C2 C1 C6 N1 -177.6(2) . .
C2 C1 C6 C5 2.3(4) . .
C6 C5 C7 C5 0.65(15) . 2_665
C4 C5 C7 C5 -179.0(2) . 2_665
C6 C5 C7 C8 -179.35(15) . .
C4 C5 C7 C8 1.0(2) . .
C5 C7 C8 C9 -79.26(15) 2_665 .
C5 C7 C8 C9 100.74(15) . .
C5 C7 C8 C9 100.74(15) 2_665 2_665
C5 C7 C8 C9 -79.26(15) . 2_665
C9 C8 C9 C14 -178.6(2) 2_665 .
C7 C8 C9 C14 1.4(2) . .
C9 C8 C9 C10 0.41(14) 2_665 .
C7 C8 C9 C10 -179.59(14) . .
C10 N2 C10 C11 179.0(2) 2_665 .
Ag1 N2 C10 C11 -1.0(2) 1_554 .
C10 N2 C10 C9 0.44(15) 2_665 .
Ag1 N2 C10 C9 -179.56(15) 1_554 .
C8 C9 C10 N2 -0.9(3) . .
C14 C9 C10 N2 178.21(17) . .
C8 C9 C10 C11 -179.44(17) . .
C14 C9 C10 C11 -0.4(3) . .
N2 C10 C11 C12 -177.6(2) . .
C9 C10 C11 C12 1.0(3) . .
C10 C11 C12 C13 -1.0(4) . .
C11 C12 C13 C14 0.4(4) . .
C12 C13 C14 C9 0.3(4) . .
C8 C9 C14 C13 178.75(19) . .
C10 C9 C14 C13 -0.3(3) . .
C16 C15 C16 C21 179.1(3) 2_565 .
C22 C15 C16 C21 -0.9(3) . .
C16 C15 C16 C17 1.1(2) 2_565 .
C22 C15 C16 C17 -178.9(2) . .
C17 N3 C17 C18 -178.7(3) 2_565 .
Ag2 N3 C17 C18 1.2(3) 1_554 .
C17 N3 C17 C16 1.2(2) 2_565 .
Ag2 N3 C17 C16 -178.8(2) 1_554 .
C15 C16 C17 N3 -2.3(4) . .
C21 C16 C17 N3 179.6(2) . .
C15 C16 C17 C18 177.6(2) . .
C21 C16 C17 C18 -0.5(5) . .
N3 C17 C18 C19 179.7(3) . .
C16 C17 C18 C19 -0.3(5) . .
C17 C18 C19 C20 0.9(5) . .
C18 C19 C20 C21 -0.8(5) . .
C19 C20 C21 C16 0.0(5) . .
C15 C16 C21 C20 -177.4(2) . .
C17 C16 C21 C20 0.6(5) . .
C16 C15 C22 C23 -111.77(17) 2_565 .
C16 C15 C22 C23 68.23(17) . .
C16 C15 C22 C23 68.23(17) 2_565 2_565
C16 C15 C22 C23 -111.77(17) . 2_565
C23 C22 C23 C28 -179.9(2) 2_565 .
C15 C22 C23 C28 0.1(2) . .
C23 C22 C23 C24 1.65(14) 2_565 .
C15 C22 C23 C24 -178.35(14) . .
C24 N4 C24 C25 -177.1(2) 2_565 .
Ag2 N4 C24 C25 2.9(2) . .
C24 N4 C24 C23 1.78(16) 2_565 .
Ag2 N4 C24 C23 -178.22(16) . .
C22 C23 C24 N4 -3.5(3) . .
C28 C23 C24 N4 177.97(17) . .
C22 C23 C24 C25 175.41(17) . .
C28 C23 C24 C25 -3.1(3) . .
N4 C24 C25 C26 179.73(19) . .
C23 C24 C25 C26 0.8(3) . .
C24 C25 C26 C27 1.4(4) . .
C25 C26 C27 C28 -1.2(4) . .
C26 C27 C28 C23 -1.3(4) . .
C22 C23 C28 C27 -175.07(19) . .
C24 C23 C28 C27 3.4(3) . .
