#------------------------------------------------------------------------------
#$Date: 2017-05-09 04:35:02 +0300 (Tue, 09 May 2017) $
#$Revision: 196565 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/82/7228236.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7228236
loop_
_publ_author_name
'Fukushima, Misaki'
'Kikkawa, Shoko'
'hikawa, hidemasa'
'Azumaya, Isao'
_publ_section_title
;
 Synthesis and Solvent Vapor Induced Transformations of Crystals of 1D
 Coordination Polymer Assembled with Continuous Void Space
;
_journal_name_full               CrystEngComm
_journal_paper_doi               10.1039/C7CE00640C
_journal_year                    2017
_chemical_formula_moiety         'C30 H16 Ag2 F6 N2 O4'
_chemical_formula_sum            'C30 H16 Ag2 F6 N2 O4'
_chemical_formula_weight         798.19
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_update_record
;
2017-01-10 deposited with the CCDC.
2017-05-08 downloaded from the CCDC.
;
_cell_angle_alpha                90.0000
_cell_angle_beta                 109.182(4)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            8
_cell_length_a                   22.764(6)
_cell_length_b                   11.314(2)
_cell_length_c                   22.613(5)
_cell_measurement_reflns_used    5301
_cell_measurement_temperature    93
_cell_measurement_theta_max      27.49
_cell_measurement_theta_min      3.25
_cell_volume                     5501(2)
_computing_cell_refinement       'CrystalClear-SM Expert 2.1 b29'
_computing_data_collection
'CrystalClear-SM Expert 2.1 b29 (Rigaku, 2013)'
_computing_data_reduction        'CrystalClear-SM Expert 2.1 b29'
_computing_molecular_graphics    'CrystalStructure 4.1'
_computing_publication_material  'CrystalStructure 4.1 (Rigaku, 2014)'
_computing_structure_refinement  'SHELXL2013 (Sheldrick, 2008)'
_computing_structure_solution    'SIR92 (Altomare, et al., 1994)'
_diffrn_ambient_temperature      93
_diffrn_detector_area_resol_mean 5.811
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Rigaku XtaLAB P200'
_diffrn_measurement_method       ω
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0485
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            86524
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.516
_diffrn_reflns_theta_min         3.365
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.502
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  1.000
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'NUMABS (Rigaku, 1999)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.928
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             3120.00
_exptl_crystal_size_max          0.280
_exptl_crystal_size_mid          0.090
_exptl_crystal_size_min          0.010
_refine_diff_density_max         3.66
_refine_diff_density_min         -1.75
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     397
_refine_ls_number_reflns         6311
_refine_ls_number_restraints     36
_refine_ls_R_factor_all          0.0496
_refine_ls_R_factor_gt           0.0368
_refine_ls_shift/su_max          0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.0480P)²+51.7090P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0971
_refine_ls_wR_factor_ref         0.1047
_reflns_number_gt                5141
_reflns_number_total             6311
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            c7ce00640c2.cif
_cod_data_source_block           mfu105-3c-3
_cod_database_code               7228236
loop_
_symmetry_equiv_pos_site_id
_space_group_symop_operation_xyz
1 +X,+Y,+Z
2 -X,+Y,1/2-Z
3 -X,-Y,-Z
4 +X,-Y,1/2+Z
5 1/2+X,1/2+Y,+Z
6 1/2-X,1/2+Y,1/2-Z
7 1/2-X,1/2-Y,-Z
8 1/2+X,1/2-Y,1/2+Z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.44564(2) 0.86015(3) 0.48306(2) 0.01608(9) Uani 1 8 d .
Ag2 Ag 0.48270(2) 0.63789(3) 0.44058(2) 0.01742(9) Uani 1 8 d .
F1 F 0.46975(14) 0.5031(2) 0.65084(13) 0.0353(6) Uani 1 8 d .
F2 F 0.54621(12) 0.6249(3) 0.68416(11) 0.0291(6) Uani 1 8 d .
F3 F 0.45426(12) 0.6778(3) 0.68050(11) 0.0298(6) Uani 1 8 d .
F4 F 0.68294(13) 0.8369(3) 0.46627(15) 0.0383(6) Uani 1 8 d .
F5 F 0.6249(2) 0.9540(4) 0.3973(2) 0.0766(10) Uani 1 8 d .
F6 F 0.65390(19) 1.0103(4) 0.4869(3) 0.0806(11) Uani 1 8 d .
O1 O 0.48713(13) 0.5922(3) 0.54634(12) 0.0197(6) Uani 1 8 d .
O2 O 0.45542(14) 0.7664(3) 0.57396(13) 0.0246(6) Uani 1 8 d .
O3 O 0.56435(13) 0.7583(3) 0.43900(14) 0.0246(6) Uani 1 8 d .
O4 O 0.54893(12) 0.9170(3) 0.49233(13) 0.0211(6) Uani 1 8 d .
N1 N 0.36730(14) 0.8763(3) 0.39228(14) 0.0149(6) Uani 1 8 d .
N2 N 0.10518(14) 1.0859(3) 0.13984(14) 0.0153(6) Uani 1 8 d .
C1 C 0.44208(18) 1.0697(4) 0.3105(2) 0.0237(9) Uani 1 8 d .
C2 C 0.43347(18) 0.9971(4) 0.35449(18) 0.0200(8) Uani 1 8 d .
C3 C 0.37301(17) 0.9526(4) 0.34858(17) 0.0162(7) Uani 1 8 d .
C4 C 0.32043(17) 0.9901(4) 0.29636(17) 0.0172(8) Uani 1 8 d .
C5 C 0.33164(19) 1.0690(4) 0.25170(19) 0.0228(9) Uani 1 8 d .
C6 C 0.3907(2) 1.1057(4) 0.2583(2) 0.0275(10) Uani 1 8 d .
C7 C 0.26074(17) 0.9486(4) 0.29216(16) 0.0152(7) Uani 1 8 d .
C8 C 0.25483(17) 0.8696(3) 0.33786(17) 0.0144(7) Uani 1 8 d .
C9 C 0.19620(17) 0.8252(4) 0.33858(17) 0.0165(7) Uani 1 8 d .
C10 C 0.19293(18) 0.7467(4) 0.38316(17) 0.0184(8) Uani 1 8 d .
C11 C 0.24830(19) 0.7059(4) 0.42910(18) 0.0190(8) Uani 1 8 d .
C12 C 0.30513(18) 0.7484(4) 0.43172(17) 0.0173(8) Uani 1 8 d .
C13 C 0.31030(17) 0.8327(3) 0.38687(16) 0.0142(7) Uani 1 8 d .
C14 C 0.20499(16) 0.9922(4) 0.24016(17) 0.0150(7) Uani 1 8 d .
C15 C 0.19387(16) 0.9516(4) 0.17871(16) 0.0142(7) Uani 1 8 d .
C16 C 0.14295(17) 1.0026(4) 0.12932(17) 0.0150(7) Uani 1 8 d .
C17 C 0.11489(17) 1.1219(3) 0.19940(17) 0.0149(7) Uani 1 8 d .
C18 C 0.16465(16) 1.0760(3) 0.25158(16) 0.0142(7) Uani 1 8 d .
C19 C 0.16982(18) 1.1160(4) 0.31332(17) 0.0180(8) Uani 1 8 d .
C20 C 0.12948(18) 1.1969(4) 0.32212(19) 0.0212(8) Uani 1 8 d .
C21 C 0.08195(18) 1.2462(4) 0.2701(2) 0.0224(9) Uani 1 8 d .
C22 C 0.07462(18) 1.2090(4) 0.21056(18) 0.0196(8) Uani 1 8 d .
C23 C 0.23069(18) 0.8626(4) 0.16313(19) 0.0209(8) Uani 1 8 d .
C24 C 0.21876(19) 0.8279(4) 0.10274(19) 0.0232(9) Uani 1 8 d .
C25 C 0.17019(19) 0.8822(4) 0.05358(19) 0.0224(9) Uani 1 8 d .
C26 C 0.13316(17) 0.9653(4) 0.06644(18) 0.0184(8) Uani 1 8 d .
C27 C 0.47431(17) 0.6633(4) 0.58269(17) 0.0157(7) Uani 1 8 d .
C28 C 0.4856(2) 0.6163(4) 0.65013(18) 0.0212(8) Uani 1 8 d .
C29 C 0.57715(18) 0.8561(4) 0.4653(2) 0.0211(8) Uani 1 8 d .
C30 C 0.6378(2) 0.9127(5) 0.4604(4) 0.0502(9) Uani 1 8 d .
H1 H 0.48187 1.09629 0.31448 0.0285 Uiso 1 8 calc R
H2 H 0.4673 0.97589 0.389 0.0241 Uiso 1 8 calc R
H5 H 0.29845 1.09558 0.21794 0.0274 Uiso 1 8 calc R
H6 H 0.3974 1.15487 0.22812 0.0330 Uiso 1 8 calc R
H9 H 0.15979 0.85018 0.30819 0.0197 Uiso 1 8 calc R
H10 H 0.15443 0.7199 0.38352 0.0221 Uiso 1 8 calc R
H11 H 0.2457 0.64915 0.4579 0.0228 Uiso 1 8 calc R
H12 H 0.34068 0.72221 0.46291 0.0207 Uiso 1 8 calc R
H19 H 0.2012 1.086 0.34772 0.0216 Uiso 1 8 calc R
H20 H 0.13288 1.22037 0.36253 0.0254 Uiso 1 8 calc R
H21 H 0.05575 1.30411 0.27667 0.0269 Uiso 1 8 calc R
H22 H 0.043 1.2409 0.17702 0.0235 Uiso 1 8 calc R
H23 H 0.26325 0.82785 0.19467 0.0251 Uiso 1 8 calc R
H24 H 0.24249 0.76827 0.09347 0.0278 Uiso 1 8 calc R
H25 H 0.1638 0.86053 0.01227 0.0269 Uiso 1 8 calc R
H26 H 0.10096 0.99841 0.03389 0.0221 Uiso 1 8 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Table 6.1.1.4)
;
Ag Ag -0.8971 1.1015
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
N N 0.0061 0.0033
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
F F 0.0171 0.0103
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
O O 0.0106 0.0060
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ag2 Ag1 O2 86.69(8) yes . .
Ag2 Ag1 O4 82.96(8) yes . .
Ag2 Ag1 N1 89.87(9) yes . .
O2 Ag1 O4 104.34(10) yes . .
O2 Ag1 N1 133.07(12) yes . .
O4 Ag1 N1 121.64(12) yes . .
Ag1 Ag2 O1 77.34(7) yes . .
Ag1 Ag2 O3 79.52(8) yes . .
Ag1 Ag2 N2 102.19(9) yes . 6_545
O1 Ag2 O3 111.64(10) yes . .
O1 Ag2 N2 118.13(11) yes . 6_545
O3 Ag2 N2 129.37(12) yes . 6_545
Ag2 O1 C27 124.7(3) yes . .
Ag1 O2 C27 120.9(3) yes . .
Ag2 O3 C29 125.4(3) yes . .
Ag1 O4 C29 117.8(3) yes . .
Ag1 N1 C3 118.9(2) yes . .
Ag1 N1 C13 120.2(2) yes . .
C3 N1 C13 119.1(3) yes . .
Ag2 N2 C16 118.7(2) yes 6_555 .
Ag2 N2 C17 121.7(3) yes 6_555 .
C16 N2 C17 118.7(3) yes . .
C2 C1 C6 120.4(4) yes . .
C1 C2 C3 120.8(3) yes . .
N1 C3 C2 118.6(3) yes . .
N1 C3 C4 122.3(4) yes . .
C2 C3 C4 119.2(4) yes . .
C3 C4 C5 118.0(4) yes . .
C3 C4 C7 118.6(4) yes . .
C5 C4 C7 123.4(3) yes . .
C4 C5 C6 120.6(3) yes . .
C1 C6 C5 120.9(4) yes . .
C4 C7 C8 119.0(3) yes . .
C4 C7 C14 119.4(3) yes . .
C8 C7 C14 121.6(3) yes . .
C7 C8 C9 123.1(3) yes . .
C7 C8 C13 118.6(4) yes . .
C9 C8 C13 118.3(4) yes . .
C8 C9 C10 121.0(3) yes . .
C9 C10 C11 120.1(4) yes . .
C10 C11 C12 121.2(4) yes . .
C11 C12 C13 120.3(3) yes . .
N1 C13 C8 122.3(3) yes . .
N1 C13 C12 118.7(3) yes . .
C8 C13 C12 119.0(4) yes . .
C7 C14 C15 119.9(3) yes . .
C7 C14 C18 120.9(3) yes . .
C15 C14 C18 119.2(3) yes . .
C14 C15 C16 118.2(4) yes . .
C14 C15 C23 123.1(3) yes . .
C16 C15 C23 118.7(3) yes . .
N2 C16 C15 122.7(3) yes . .
N2 C16 C26 118.8(3) yes . .
C15 C16 C26 118.4(4) yes . .
N2 C17 C18 122.3(4) yes . .
N2 C17 C22 118.7(3) yes . .
C18 C17 C22 119.0(3) yes . .
C14 C18 C17 118.7(3) yes . .
C14 C18 C19 122.9(3) yes . .
C17 C18 C19 118.4(4) yes . .
C18 C19 C20 120.8(3) yes . .
C19 C20 C21 120.7(4) yes . .
C20 C21 C22 120.4(4) yes . .
C17 C22 C21 120.7(3) yes . .
C15 C23 C24 120.8(3) yes . .
C23 C24 C25 120.5(4) yes . .
C24 C25 C26 120.6(4) yes . .
C16 C26 C25 120.9(3) yes . .
O1 C27 O2 130.2(4) yes . .
O1 C27 C28 115.2(3) yes . .
O2 C27 C28 114.6(4) yes . .
F1 C28 F2 107.1(3) yes . .
F1 C28 F3 107.6(4) yes . .
F1 C28 C27 112.5(3) yes . .
F2 C28 F3 106.8(3) yes . .
F2 C28 C27 110.1(4) yes . .
F3 C28 C27 112.5(3) yes . .
O3 C29 O4 130.9(4) yes . .
O3 C29 C30 113.9(5) yes . .
O4 C29 C30 115.1(4) yes . .
F4 C30 F5 102.2(6) yes . .
F4 C30 F6 115.5(4) yes . .
F4 C30 C29 114.1(5) yes . .
F5 C30 F6 97.0(5) yes . .
F5 C30 C29 107.9(4) yes . .
F6 C30 C29 117.1(6) yes . .
C2 C1 H1 119.775 no . .
C6 C1 H1 119.784 no . .
C1 C2 H2 119.581 no . .
C3 C2 H2 119.584 no . .
C4 C5 H5 119.685 no . .
C6 C5 H5 119.716 no . .
C1 C6 H6 119.529 no . .
C5 C6 H6 119.535 no . .
C8 C9 H9 119.514 no . .
C10 C9 H9 119.504 no . .
C9 C10 H10 119.962 no . .
C11 C10 H10 119.962 no . .
C10 C11 H11 119.396 no . .
C12 C11 H11 119.391 no . .
C11 C12 H12 119.858 no . .
C13 C12 H12 119.863 no . .
C18 C19 H19 119.603 no . .
C20 C19 H19 119.603 no . .
C19 C20 H20 119.669 no . .
C21 C20 H20 119.655 no . .
C20 C21 H21 119.780 no . .
C22 C21 H21 119.805 no . .
C17 C22 H22 119.662 no . .
C21 C22 H22 119.660 no . .
C15 C23 H23 119.588 no . .
C24 C23 H23 119.603 no . .
C23 C24 H24 119.773 no . .
C25 C24 H24 119.771 no . .
C24 C25 H25 119.685 no . .
C26 C25 H25 119.680 no . .
C16 C26 H26 119.552 no . .
C25 C26 H26 119.553 no . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
_geom_bond_site_symmetry_2
Ag1 Ag2 2.9138(7) yes .
Ag1 O2 2.258(3) yes .
Ag1 O4 2.379(3) yes .
Ag1 N1 2.241(3) yes .
Ag2 O1 2.416(3) yes .
Ag2 O3 2.314(3) yes .
Ag2 N2 2.294(3) yes 6_545
F1 C28 1.333(5) yes .
F2 C28 1.345(5) yes .
F3 C28 1.336(6) yes .
F4 C30 1.312(7) yes .
F5 C30 1.437(9) yes .
F6 C30 1.253(7) yes .
O1 C27 1.251(5) yes .
O2 C27 1.237(5) yes .
O3 C29 1.245(5) yes .
O4 C29 1.233(6) yes .
N1 C3 1.351(5) yes .
N1 C13 1.355(5) yes .
N2 C16 1.348(5) yes .
N2 C17 1.354(5) yes .
C1 C2 1.353(6) yes .
C1 C6 1.421(5) yes .
C2 C3 1.430(6) yes .
C3 C4 1.442(5) yes .
C4 C5 1.432(6) yes .
C4 C7 1.411(6) yes .
C5 C6 1.369(6) yes .
C7 C8 1.406(6) yes .
C7 C14 1.502(5) yes .
C8 C9 1.431(6) yes .
C8 C13 1.441(5) yes .
C9 C10 1.363(6) yes .
C10 C11 1.422(5) yes .
C11 C12 1.363(6) yes .
C12 C13 1.425(6) yes .
C14 C15 1.405(5) yes .
C14 C18 1.402(6) yes .
C15 C16 1.440(5) yes .
C15 C23 1.427(6) yes .
C16 C26 1.429(6) yes .
C17 C18 1.438(5) yes .
C17 C22 1.424(6) yes .
C18 C19 1.435(5) yes .
C19 C20 1.357(6) yes .
C20 C21 1.425(5) yes .
C21 C22 1.367(6) yes .
C23 C24 1.360(6) yes .
C24 C25 1.424(5) yes .
C25 C26 1.356(6) yes .
C27 C28 1.555(6) yes .
C29 C30 1.557(8) yes .
C1 H1 0.930 no .
C2 H2 0.930 no .
C5 H5 0.930 no .
C6 H6 0.930 no .
C9 H9 0.930 no .
C10 H10 0.930 no .
C11 H11 0.930 no .
C12 H12 0.930 no .
C19 H19 0.930 no .
C20 H20 0.930 no .
C21 H21 0.930 no .
C22 H22 0.930 no .
C23 H23 0.930 no .
C24 H24 0.930 no .
C25 H25 0.930 no .
C26 H26 0.930 no .
loop_
_geom_contact_atom_site_label_1
_geom_contact_atom_site_label_2
_geom_contact_distance
_geom_contact_publ_flag
_geom_contact_site_symmetry_2
Ag1 C2 3.225(4) no .
Ag1 C12 3.277(4) no .
Ag2 C22 3.332(4) no 6_545
Ag2 C26 3.243(4) no 6_545
F1 O1 2.715(4) no .
F1 O2 3.411(4) no .
F2 O1 2.984(3) no .
F2 O2 3.108(4) no .
F3 O1 3.492(4) no .
F3 O2 2.618(4) no .
F4 O3 2.714(4) no .
F4 O4 3.414(5) no .
F5 O3 2.923(6) no .
F5 O4 3.198(7) no .
F6 O3 3.465(5) no .
F6 O4 2.651(6) no .
O1 C26 3.387(4) no 6_545
O4 C2 3.473(4) no .
N1 N2 3.466(5) no 6_545
N1 C7 2.841(4) no .
N1 C22 3.572(6) no 6_545
N2 C12 3.512(6) no 6_555
N2 C13 3.554(5) no 6_555
N2 C14 2.836(4) no .
C1 C4 2.829(6) no .
C2 C5 2.810(5) no .
C2 C22 3.556(6) no 6_545
C3 C6 2.806(7) no .
C3 C8 2.784(6) no .
C3 C22 3.443(6) no 6_545
C4 C13 2.779(6) no .
C4 C15 3.245(4) no .
C4 C18 3.491(5) no .
C4 C23 3.360(5) no .
C5 C9 3.481(6) no 6_555
C5 C10 3.540(6) no 6_555
C5 C14 2.939(6) no .
C5 C15 3.305(5) no .
C5 C23 3.424(6) no .
C6 C9 3.468(6) no 6_555
C6 C10 3.521(6) no 6_555
C7 C19 2.957(6) no .
C7 C23 2.936(6) no .
C8 C11 2.813(6) no .
C8 C15 3.529(5) no .
C8 C18 3.293(5) no .
C8 C19 3.334(6) no .
C9 C12 2.812(5) no .
C9 C14 2.976(6) no .
C9 C18 3.393(5) no .
C9 C19 3.359(6) no .
C10 C13 2.819(6) no .
C12 C16 3.479(6) no 6_545
C12 C26 3.492(6) no 6_545
C15 C17 2.778(6) no .
C15 C25 2.813(6) no .
C16 C18 2.771(5) no .
C16 C24 2.816(6) no .
C17 C20 2.815(6) no .
C18 C21 2.819(6) no .
C19 C22 2.810(5) no .
C19 C23 3.522(6) no 6_555
C19 C24 3.553(6) no 6_555
C23 C26 2.805(5) no .
Ag1 F6 2.959(5) no 3_676
Ag1 O4 2.577(3) no 3_676
Ag1 C29 3.512(4) no 3_676
Ag2 F1 3.075(3) no 3_666
Ag2 O1 2.684(3) no 3_666
F1 Ag2 3.075(3) no 3_666
F1 O3 3.526(4) no 3_666
F1 N2 3.329(5) no 8_565
F1 C17 3.426(5) no 8_565
F1 C20 3.391(6) no 7_566
F1 C22 3.341(5) no 8_565
F2 F3 3.122(4) no 2_656
F2 N2 3.063(5) no 8_565
F2 C1 3.464(5) no 3_676
F2 C6 3.437(5) no 3_676
F2 C15 3.512(5) no 8_565
F2 C16 3.204(5) no 8_565
F2 C17 3.164(5) no 8_565
F2 C18 3.473(4) no 8_565
F3 F2 3.122(4) no 2_656
F3 F3 3.149(3) no 2_656
F3 C6 3.585(6) no 4_575
F3 C9 3.309(5) no 7_566
F3 C10 3.295(5) no 7_566
F4 F4 3.530(4) no 7_666
F4 C20 3.466(5) no 5_545
F4 C24 3.122(6) no 2_655
F4 C24 3.466(5) no 8_565
F4 C25 3.554(6) no 2_655
F4 C25 3.241(6) no 8_565
F5 C20 3.388(7) no 5_545
F5 C21 3.593(6) no 5_545
F6 Ag1 2.959(5) no 3_676
F6 O2 3.496(5) no 3_676
F6 N1 3.195(7) no 3_676
F6 C12 3.253(6) no 3_676
F6 C13 3.230(6) no 3_676
O1 Ag2 2.684(3) no 3_666
O1 O1 3.145(4) no 3_666
O1 N2 3.467(4) no 8_565
O1 C16 3.589(4) no 8_565
O1 C26 3.269(5) no 8_565
O2 F6 3.496(5) no 3_676
O2 C1 3.420(5) no 3_676
O3 F1 3.526(4) no 3_666
O3 C20 3.499(6) no 5_545
O3 C25 3.308(5) no 8_565
O4 Ag1 2.577(3) no 3_676
O4 O4 3.020(4) no 3_676
O4 N1 3.556(4) no 3_676
O4 C2 3.492(5) no 3_676
N1 F6 3.195(7) no 3_676
N1 O4 3.556(4) no 3_676
N2 F1 3.329(5) no 8_464
N2 F2 3.063(5) no 8_464
N2 O1 3.467(4) no 8_464
C1 F2 3.464(5) no 3_676
C1 O2 3.420(5) no 3_676
C2 O4 3.492(5) no 3_676
C6 F2 3.437(5) no 3_676
C6 F3 3.585(6) no 4_574
C9 F3 3.309(5) no 7_566
C10 F3 3.295(5) no 7_566
C11 C11 3.335(6) no 7_566
C12 F6 3.253(6) no 3_676
C13 F6 3.230(6) no 3_676
C15 F2 3.512(5) no 8_464
C16 F2 3.204(5) no 8_464
C16 O1 3.589(4) no 8_464
C17 F1 3.426(5) no 8_464
C17 F2 3.164(5) no 8_464
C18 F2 3.473(4) no 8_464
C20 F1 3.391(6) no 7_566
C20 F4 3.466(5) no 5_455
C20 F5 3.388(7) no 5_455
C20 O3 3.499(6) no 5_455
C21 F5 3.593(6) no 5_455
C21 C21 3.538(6) no 2_555
C22 F1 3.341(5) no 8_464
C24 F4 3.122(6) no 2_655
C24 F4 3.466(5) no 8_464
C25 F4 3.554(6) no 2_655
C25 F4 3.241(6) no 8_464
C25 O3 3.308(5) no 8_464
C26 O1 3.269(5) no 8_464
C29 Ag1 3.512(4) no 3_676
Ag1 H2 2.6779 no .
Ag1 H12 2.7635 no .
Ag2 H12 3.5623 no .
Ag2 H22 2.7838 no 6_545
Ag2 H26 2.6782 no 6_545
F5 H1 3.5621 no .
F5 H2 3.5385 no .
O1 H12 3.5644 no .
O1 H26 2.4591 no 6_545
O2 H12 3.0114 no .
O3 H2 3.2527 no .
O3 H22 2.9462 no 6_545
O4 H2 2.5502 no .
N1 H2 2.5630 no .
N1 H12 2.5675 no .
N1 H22 3.3277 no 6_545
N2 H12 3.3433 no 6_555
N2 H22 2.5628 no .
N2 H26 2.5647 no .
C1 H5 3.2649 no .
C2 H6 3.2378 no .
C2 H22 3.0739 no 6_545
C3 H1 3.2610 no .
C3 H5 3.3059 no .
C3 H22 3.2335 no 6_545
C4 H2 3.3151 no .
C4 H6 3.2714 no .
C4 H19 3.4589 no .
C4 H23 2.8958 no .
C5 H1 3.2581 no .
C5 H9 3.4877 no 6_555
C5 H23 3.1958 no .
C6 H2 3.2478 no .
C6 H9 3.1774 no 6_555
C6 H10 3.2924 no 6_555
C7 H5 2.6952 no .
C7 H9 2.6835 no .
C7 H19 2.6362 no .
C7 H23 2.6103 no .
C8 H5 3.4162 no 6_545
C8 H10 3.2726 no .
C8 H12 3.3114 no .
C8 H19 2.7771 no .
C8 H23 3.3394 no .
C9 H5 2.9151 no 6_545
C9 H6 2.9009 no 6_545
C9 H11 3.2431 no .
C9 H19 2.9578 no .
C10 H5 2.9127 no 6_545
C10 H6 2.8705 no 6_545
C10 H12 3.2643 no .
C11 H5 3.3794 no 6_545
C11 H9 3.2527 no .
C12 H10 3.2563 no .
C12 H26 3.4756 no 6_545
C13 H9 3.3072 no .
C13 H11 3.2569 no .
C14 H5 2.6169 no .
C14 H9 2.6550 no .
C14 H19 2.6807 no .
C14 H23 2.6783 no .
C15 H5 2.7785 no .
C15 H9 3.4618 no .
C15 H24 3.2627 no .
C15 H26 3.3055 no .
C16 H12 3.3423 no 6_555
C16 H23 3.3067 no .
C16 H25 3.2621 no .
C17 H19 3.3082 no .
C17 H21 3.2648 no .
C18 H5 3.3804 no .
C18 H9 2.8763 no .
C18 H20 3.2675 no .
C18 H22 3.3049 no .
C18 H23 3.3132 no 6_555
C19 H9 3.0149 no .
C19 H21 3.2477 no .
C19 H23 2.8780 no 6_555
C19 H24 2.9381 no 6_555
C20 H22 3.2626 no .
C20 H23 2.9853 no 6_555
C20 H24 3.0223 no 6_555
C21 H19 3.2566 no .
C21 H23 3.4728 no 6_555
C22 H20 3.2542 no .
C23 H5 3.0997 no .
C23 H19 3.5364 no 6_545
C23 H25 3.2470 no .
C24 H19 3.2745 no 6_545
C24 H20 3.4292 no 6_545
C24 H26 3.2548 no .
C25 H23 3.2563 no .
C26 H12 3.0828 no 6_555
C26 H24 3.2461 no .
C27 H12 3.4088 no .
C27 H26 3.2244 no 6_545
C29 H2 2.8685 no .
H1 H2 2.2743 no .
H1 H6 2.3415 no .
H2 H22 3.0203 no 6_545
H5 H6 2.2882 no .
H5 H9 3.1495 no 6_555
H5 H10 3.1638 no 6_555
H5 H23 3.1333 no .
H6 H9 2.5592 no 6_555
H6 H10 2.5197 no 6_555
H9 H10 2.2860 no .
H9 H19 2.8727 no .
H10 H11 2.3431 no .
H11 H12 2.2825 no .
H12 H26 2.8493 no 6_545
H19 H20 2.2769 no .
H19 H23 3.0937 no 6_555
H19 H24 2.5581 no 6_555
H20 H21 2.3473 no .
H20 H23 3.2791 no 6_555
H20 H24 2.7345 no 6_555
H21 H22 2.2899 no .
H23 H24 2.2812 no .
H24 H25 2.3470 no .
H25 H26 2.2756 no .
Ag1 H2 3.4599 no 3_676
Ag2 H26 3.2163 no 8_565
F1 H20 3.3875 no 7_566
F1 H22 3.1781 no 8_565
F2 H1 3.2205 no 3_676
F2 H6 3.1806 no 3_676
F2 H9 3.1409 no 8_565
F3 H1 2.9243 no 3_676
F3 H6 2.7084 no 4_575
F3 H9 2.7097 no 7_566
F3 H10 2.6840 no 7_566
F4 H20 2.6047 no 5_545
F4 H24 2.6109 no 2_655
F4 H24 2.9942 no 8_565
F4 H25 3.3714 no 2_655
F4 H25 2.5615 no 8_565
F5 H6 3.5381 no 2_655
F5 H10 3.1205 no 5_555
F5 H11 3.4412 no 5_555
F5 H20 2.7806 no 5_545
F5 H21 3.1575 no 5_545
F6 H10 3.3337 no 5_555
F6 H11 2.8582 no 5_555
F6 H12 3.2204 no 3_676
O1 H26 2.8851 no 8_565
O2 H1 2.9064 no 3_676
O2 H2 3.3655 no 3_676
O2 H10 2.9634 no 7_566
O3 H20 2.7167 no 5_545
O3 H25 2.6855 no 8_565
O3 H26 3.5436 no 8_565
O4 H2 3.0754 no 3_676
C10 H11 3.5996 no 7_566
C11 H11 3.0014 no 7_566
C12 H11 3.2881 no 7_566
C21 H21 3.0323 no 2_555
C21 H22 3.4293 no 2_555
C22 H21 3.2576 no 2_555
C27 H1 3.5038 no 3_676
C27 H10 3.5200 no 7_566
C28 H1 3.3725 no 3_676
C28 H10 3.5466 no 7_566
C29 H20 3.3617 no 5_545
C29 H25 3.1068 no 8_565
C30 H20 3.0791 no 5_545
C30 H25 3.2906 no 8_565
H1 F2 3.2205 no 3_676
H1 F3 2.9243 no 3_676
H1 O2 2.9064 no 3_676
H1 C27 3.5038 no 3_676
H1 C28 3.3725 no 3_676
H1 H1 3.2813 no 2_655
H1 H6 3.2650 no 2_655
H2 Ag1 3.4599 no 3_676
H2 O2 3.3655 no 3_676
H2 O4 3.0754 no 3_676
H6 F2 3.1806 no 3_676
H6 F3 2.7084 no 4_574
H6 F5 3.5381 no 2_655
H6 H1 3.2650 no 2_655
H9 F2 3.1409 no 8_464
H9 F3 2.7097 no 7_566
H10 F3 2.6840 no 7_566
H10 F5 3.1205 no 5_445
H10 F6 3.3337 no 5_445
H10 O2 2.9634 no 7_566
H10 C27 3.5200 no 7_566
H10 C28 3.5466 no 7_566
H10 H12 3.4995 no 7_566
H11 F5 3.4412 no 5_445
H11 F6 2.8582 no 5_445
H11 C10 3.5996 no 7_566
H11 C11 3.0014 no 7_566
H11 C12 3.2881 no 7_566
H11 H11 2.9370 no 7_566
H11 H12 3.3920 no 7_566
H12 F6 3.2204 no 3_676
H12 H10 3.4995 no 7_566
H12 H11 3.3920 no 7_566
H20 F1 3.3875 no 7_566
H20 F4 2.6047 no 5_455
H20 F5 2.7806 no 5_455
H20 O3 2.7167 no 5_455
H20 C29 3.3617 no 5_455
H20 C30 3.0791 no 5_455
H20 H25 3.3514 no 4_575
H21 F5 3.1575 no 5_455
H21 C21 3.0323 no 2_555
H21 C22 3.2576 no 2_555
H21 H21 2.4260 no 2_555
H21 H22 2.8650 no 2_555
H22 F1 3.1781 no 8_464
H22 C21 3.4293 no 2_555
H22 H21 2.8650 no 2_555
H24 F4 2.6109 no 2_655
H24 F4 2.9942 no 8_464
H25 F4 3.3714 no 2_655
H25 F4 2.5615 no 8_464
H25 O3 2.6855 no 8_464
H25 C29 3.1068 no 8_464
H25 C30 3.2906 no 8_464
H25 H20 3.3514 no 4_574
H26 Ag2 3.2163 no 8_464
H26 O1 2.8851 no 8_464
H26 O3 3.5436 no 8_464
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_publ_flag
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
Ag2 Ag1 O2 C27 3.5(2) no . . .
O2 Ag1 Ag2 O1 -1.46(8) no . . .
O2 Ag1 Ag2 O3 -116.66(8) no . . .
O2 Ag1 Ag2 N2 115.03(8) no . . 6_545
Ag2 Ag1 O4 C29 16.22(18) no . . .
O4 Ag1 Ag2 O1 103.44(7) no . . .
O4 Ag1 Ag2 O3 -11.76(7) no . . .
O4 Ag1 Ag2 N2 -140.08(7) no . . 6_545
Ag2 Ag1 N1 C3 -103.5(2) no . . .
Ag2 Ag1 N1 C13 92.0(2) no . . .
N1 Ag1 Ag2 O1 -134.63(9) no . . .
N1 Ag1 Ag2 O3 110.17(9) no . . .
N1 Ag1 Ag2 N2 -18.14(9) no . . 6_545
O2 Ag1 O4 C29 101.0(2) no . . .
O4 Ag1 O2 C27 -78.3(2) no . . .
O2 Ag1 N1 C3 171.18(18) no . . .
O2 Ag1 N1 C13 6.6(3) no . . .
N1 Ag1 O2 C27 90.2(3) no . . .
O4 Ag1 N1 C3 -21.8(3) no . . .
O4 Ag1 N1 C13 173.62(19) no . . .
N1 Ag1 O4 C29 -69.3(2) no . . .
Ag1 Ag2 O1 C27 0.37(19) no . . .
Ag1 Ag2 O3 C29 15.64(19) no . . .
Ag1 Ag2 N2 C16 -101.6(2) no . 6_545 6_545
Ag1 Ag2 N2 C17 89.1(2) no . 6_545 6_545
O1 Ag2 O3 C29 -56.1(2) no . . .
O3 Ag2 O1 C27 73.5(2) no . . .
O1 Ag2 N2 C16 -19.6(3) no . 6_545 6_545
O1 Ag2 N2 C17 171.1(2) no . 6_545 6_545
N2 Ag2 O1 C27 -96.8(2) no 6_545 . .
O3 Ag2 N2 C16 172.00(18) no . 6_545 6_545
O3 Ag2 N2 C17 2.7(3) no . 6_545 6_545
N2 Ag2 O3 C29 112.9(2) no 6_545 . .
Ag2 O1 C27 O2 2.6(6) no . . .
Ag2 O1 C27 C28 -175.44(16) no . . .
Ag1 O2 C27 O1 -4.7(5) no . . .
Ag1 O2 C27 C28 173.37(17) no . . .
Ag2 O3 C29 O4 -7.3(6) no . . .
Ag2 O3 C29 C30 175.56(16) no . . .
Ag1 O4 C29 O3 -10.4(6) no . . .
Ag1 O4 C29 C30 166.76(17) no . . .
Ag1 N1 C3 C2 15.8(5) no . . .
Ag1 N1 C3 C4 -164.4(2) no . . .
Ag1 N1 C13 C8 161.2(2) no . . .
Ag1 N1 C13 C12 -18.1(4) no . . .
C3 N1 C13 C8 -3.3(5) no . . .
C3 N1 C13 C12 177.4(3) no . . .
C13 N1 C3 C2 -179.4(3) no . . .
C13 N1 C3 C4 0.3(6) no . . .
Ag2 N2 C16 C15 -170.6(2) no 6_555 . .
Ag2 N2 C16 C26 11.0(5) no 6_555 . .
Ag2 N2 C17 C18 170.4(2) no 6_555 . .
Ag2 N2 C17 C22 -10.1(5) no 6_555 . .
C16 N2 C17 C18 1.1(6) no . . .
C16 N2 C17 C22 -179.4(3) no . . .
C17 N2 C16 C15 -1.0(6) no . . .
C17 N2 C16 C26 -179.4(3) no . . .
C2 C1 C6 C5 0.8(7) no . . .
C6 C1 C2 C3 1.7(7) no . . .
C1 C2 C3 N1 177.1(4) no . . .
C1 C2 C3 C4 -2.7(6) no . . .
N1 C3 C4 C5 -178.4(3) no . . .
N1 C3 C4 C7 2.3(6) no . . .
C2 C3 C4 C5 1.3(6) no . . .
C2 C3 C4 C7 -177.9(3) no . . .
C3 C4 C5 C6 1.0(6) no . . .
C3 C4 C7 C8 -1.9(6) no . . .
C3 C4 C7 C14 176.5(3) no . . .
C5 C4 C7 C8 178.9(4) no . . .
C5 C4 C7 C14 -2.7(6) no . . .
C7 C4 C5 C6 -179.7(4) no . . .
C4 C5 C6 C1 -2.1(7) no . . .
C4 C7 C8 C9 178.3(3) no . . .
C4 C7 C8 C13 -0.9(5) no . . .
C4 C7 C14 C15 73.7(5) no . . .
C4 C7 C14 C18 -104.3(4) no . . .
C8 C7 C14 C15 -108.0(4) no . . .
C8 C7 C14 C18 74.0(5) no . . .
C14 C7 C8 C9 -0.1(6) no . . .
C14 C7 C8 C13 -179.2(3) no . . .
C7 C8 C9 C10 178.6(3) no . . .
C7 C8 C13 N1 3.6(6) no . . .
C7 C8 C13 C12 -177.1(3) no . . .
C9 C8 C13 N1 -175.6(3) no . . .
C9 C8 C13 C12 3.7(5) no . . .
C13 C8 C9 C10 -2.2(6) no . . .
C8 C9 C10 C11 -1.3(6) no . . .
C9 C10 C11 C12 3.5(6) no . . .
C10 C11 C12 C13 -1.9(6) no . . .
C11 C12 C13 N1 177.6(3) no . . .
C11 C12 C13 C8 -1.7(6) no . . .
C7 C14 C15 C16 -175.0(3) no . . .
C7 C14 C15 C23 4.9(6) no . . .
C7 C14 C18 C17 175.0(3) no . . .
C7 C14 C18 C19 -6.6(6) no . . .
C15 C14 C18 C17 -3.0(5) no . . .
C15 C14 C18 C19 175.4(3) no . . .
C18 C14 C15 C16 3.1(5) no . . .
C18 C14 C15 C23 -177.0(3) no . . .
C14 C15 C16 N2 -1.1(6) no . . .
C14 C15 C16 C26 177.3(3) no . . .
C14 C15 C23 C24 -178.7(3) no . . .
C16 C15 C23 C24 1.2(6) no . . .
C23 C15 C16 N2 179.0(3) no . . .
C23 C15 C16 C26 -2.6(5) no . . .
N2 C16 C26 C25 179.7(3) no . . .
C15 C16 C26 C25 1.2(6) no . . .
N2 C17 C18 C14 0.9(6) no . . .
N2 C17 C18 C19 -177.5(3) no . . .
N2 C17 C22 C21 178.7(3) no . . .
C18 C17 C22 C21 -1.8(6) no . . .
C22 C17 C18 C14 -178.6(3) no . . .
C22 C17 C18 C19 3.0(5) no . . .
C14 C18 C19 C20 -179.7(3) no . . .
C17 C18 C19 C20 -1.3(6) no . . .
C18 C19 C20 C21 -1.5(6) no . . .
C19 C20 C21 C22 2.8(6) no . . .
C20 C21 C22 C17 -1.1(6) no . . .
C15 C23 C24 C25 1.7(6) no . . .
C23 C24 C25 C26 -3.2(7) no . . .
C24 C25 C26 C16 1.7(6) no . . .
O1 C27 C28 F1 -38.9(5) no . . .
O1 C27 C28 F2 80.5(4) no . . .
O1 C27 C28 F3 -160.6(3) no . . .
O2 C27 C28 F1 142.7(3) no . . .
O2 C27 C28 F2 -97.9(4) no . . .
O2 C27 C28 F3 21.1(5) no . . .
O3 C29 C30 F4 -39.4(7) no . . .
O3 C29 C30 F5 73.4(5) no . . .
O3 C29 C30 F6 -178.6(4) no . . .
O4 C29 C30 F4 143.0(5) no . . .
O4 C29 C30 F5 -104.2(5) no . . .
O4 C29 C30 F6 3.8(7) no . . .
