#------------------------------------------------------------------------------
#$Date: 2019-11-17 09:02:01 +0200 (Sun, 17 Nov 2019) $
#$Revision: 228993 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/97/7229750.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7229750
loop_
_publ_author_name
'Zhu, Mei'
'Jia, Lingjie'
'Li, Yang'
'Li, Yungai'
'Zhang, Li'
'Zhang, Wei'
'Lü, Yaohong'
_publ_section_title
;
 Nitronyl nitroxide bridged 3d--4f hetero-tri-spin chains: synthesis
 strategy, crystal structure and magnetic properties
;
_journal_issue                   4
_journal_name_full               CrystEngComm
_journal_page_first              420
_journal_paper_doi               10.1039/C7CE01962A
_journal_volume                  20
_journal_year                    2018
_chemical_formula_sum            'C135 H103 Cu Eu3 F66 N8 O34'
_chemical_formula_weight         4154.68
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2017-09-21 deposited with the CCDC.
2017-12-14 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 113.362(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   20.180(3)
_cell_length_b                   43.634(8)
_cell_length_c                   20.077(3)
_cell_measurement_reflns_used    37500
_cell_measurement_temperature    113(2)
_cell_measurement_theta_max      26.2
_cell_measurement_theta_min      1.2
_cell_volume                     16229(5)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      113(2)
_diffrn_detector_area_resol_mean 28.5714
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type
;
Rigaku Saturn724+ (2x2 bin mode)
;
_diffrn_measurement_method       'profile data from ω-scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0599
_diffrn_reflns_av_sigmaI/netI    0.0580
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       51
_diffrn_reflns_limit_k_min       -50
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            105760
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.78
_exptl_absorpt_coefficient_mu    1.421
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.705
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.700
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rectangle
_exptl_crystal_F_000             8211
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.1
_refine_diff_density_max         0.867
_refine_diff_density_min         -0.693
_refine_diff_density_rms         0.087
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     2240
_refine_ls_number_reflns         28428
_refine_ls_number_restraints     36
_refine_ls_restrained_S_all      1.057
_refine_ls_R_factor_all          0.0539
_refine_ls_R_factor_gt           0.0427
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0500P)²+2.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0938
_refine_ls_wR_factor_ref         0.0995
_reflns_number_gt                24494
_reflns_number_total             28428
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c7ce01962a2.cif
_cod_data_source_block           1_CCDC3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 7229746--7229753.cif.
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7229750
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu2 Eu 0.796999(12) 0.110045(5) 0.918307(11) 0.02344(6) Uani 1 1 d .
Eu3 Eu 1.061166(11) 0.099586(4) 0.678018(10) 0.01640(6) Uani 1 1 d .
Eu1 Eu 0.558773(11) 0.117288(4) 1.194767(10) 0.01833(6) Uani 1 1 d .
Cu1 Cu 0.31756(3) 0.137551(11) 1.45461(3) 0.02310(12) Uani 1 1 d .
O2 O 0.30794(16) 0.10360(6) 1.38828(15) 0.0260(7) Uani 1 1 d .
O30 O 1.17670(14) 0.08755(6) 0.76894(13) 0.0188(6) Uani 1 1 d .
O3 O 0.35189(16) 0.10908(6) 1.53526(14) 0.0250(7) Uani 1 1 d .
O10 O 0.62248(16) 0.07028(6) 1.23963(14) 0.0256(7) Uani 1 1 d .
O4 O 0.34826(16) 0.17325(6) 1.51780(14) 0.0236(6) Uani 1 1 d .
O1 O 0.25889(15) 0.16477(6) 1.37806(14) 0.0226(6) Uani 1 1 d .
C124 C 1.2083(2) 0.16338(9) 0.5705(2) 0.0193(8) Uani 1 1 d .
H124 H 1.1853 0.1683 0.5204 0.023 Uiso 1 1 calc R
O31 O 1.06157(14) 0.04588(6) 0.70091(13) 0.0210(6) Uani 1 1 d .
O9 O 0.45826(16) 0.13999(6) 1.10317(14) 0.0253(6) Uani 1 1 d .
O29 O 1.10773(15) 0.14948(6) 0.71959(14) 0.0226(6) Uani 1 1 d .
O34 O 1.30903(16) 0.20284(6) 0.73911(14) 0.0247(7) Uani 1 1 d .
O20 O 0.72579(17) 0.14165(7) 0.81858(15) 0.0313(7) Uani 1 1 d .
F61 F 1.31909(14) 0.04227(6) 0.88350(14) 0.0415(7) Uani 1 1 d .
N3 N 0.60507(19) 0.09818(8) 1.04783(17) 0.0231(8) Uani 1 1 d .
F2 F 0.19865(14) 0.20836(6) 1.27813(13) 0.0355(6) Uani 1 1 d .
F49 F 0.86958(15) 0.16872(6) 0.69265(13) 0.0395(7) Uani 1 1 d .
O13 O 0.66748(15) 0.13448(6) 1.28391(14) 0.0253(6) Uani 1 1 d .
F10 F 0.43169(17) 0.20238(6) 1.69214(13) 0.0430(7) Uani 1 1 d .
F56 F 0.94636(15) 0.14882(6) 0.44624(13) 0.0410(7) Uani 1 1 d .
F54 F 0.87831(16) 0.07578(7) 0.42519(13) 0.0449(7) Uani 1 1 d .
F7 F 0.35474(15) 0.06794(6) 1.63320(14) 0.0413(7) Uani 1 1 d .
N7 N 1.14009(18) 0.08412(7) 0.55894(16) 0.0189(7) Uani 1 1 d .
F6 F 0.34006(16) 0.06871(6) 1.29162(15) 0.0428(7) Uani 1 1 d .
F43 F 0.61073(16) 0.03205(7) 0.77163(14) 0.0505(8) Uani 1 1 d .
F8 F 0.46698(15) 0.07833(6) 1.66176(14) 0.0407(7) Uani 1 1 d .
O26 O 0.95823(15) 0.13020(6) 0.66673(13) 0.0219(6) Uani 1 1 d .
O19 O 0.81531(16) 0.16257(7) 0.95794(15) 0.0287(7) Uani 1 1 d .
O5 O 0.42880(15) 0.15051(6) 1.44086(14) 0.0243(6) Uani 1 1 d .
O24 O 0.72606(16) 0.04567(6) 0.59342(14) 0.0256(6) Uani 1 1 d .
F51 F 0.87402(17) 0.18533(6) 0.59374(16) 0.0495(8) Uani 1 1 d .
F50 F 0.78356(14) 0.15847(6) 0.59099(14) 0.0421(7) Uani 1 1 d .
F12 F 0.47676(15) 0.20929(6) 1.61316(14) 0.0397(7) Uani 1 1 d .
N8 N 1.16436(18) 0.10534(7) 0.47332(16) 0.0189(7) Uani 1 1 d .
O8 O 0.53576(16) 0.16491(6) 1.24039(15) 0.0258(7) Uani 1 1 d .
N2 N 0.50819(18) 0.11310(7) 1.34239(17) 0.0201(7) Uani 1 1 d .
O14 O 0.59625(15) 0.09242(6) 1.10684(14) 0.0234(6) Uani 1 1 d .
F9 F 0.40995(16) 0.09879(6) 1.72103(13) 0.0396(7) Uani 1 1 d .
O7 O 0.51507(16) 0.10356(6) 1.28399(14) 0.0245(6) Uani 1 1 d .
F11 F 0.37045(16) 0.22567(6) 1.59209(15) 0.0443(7) Uani 1 1 d .
O28 O 1.03864(15) 0.13103(6) 0.57378(13) 0.0212(6) Uani 1 1 d .
F14 F 0.46470(19) 0.23626(6) 1.24250(17) 0.0580(9) Uani 1 1 d .
O27 O 0.95903(15) 0.07842(6) 0.58297(14) 0.0217(6) Uani 1 1 d .
N5 N 0.93866(19) 0.12656(8) 0.86605(17) 0.0230(8) Uani 1 1 d .
O6 O 0.24368(16) 0.19024(6) 1.10853(14) 0.0268(7) Uani 1 1 d .
F5 F 0.24845(18) 0.05085(6) 1.30622(16) 0.0507(8) Uani 1 1 d .
N6 N 1.01828(19) 0.10780(8) 0.82979(17) 0.0217(8) Uani 1 1 d .
F58 F 1.18214(16) 0.19538(6) 0.79994(14) 0.0456(7) Uani 1 1 d .
F57 F 0.95919(17) 0.19591(6) 0.47859(14) 0.0478(8) Uani 1 1 d .
O21 O 0.72178(16) 0.07720(7) 0.82487(14) 0.0274(7) Uani 1 1 d .
C82 C 1.0636(2) 0.12291(10) 0.9009(2) 0.0266(10) Uani 1 1 d .
F53 F 0.86690(17) 0.03892(6) 0.49066(15) 0.0491(8) Uani 1 1 d .
O22 O 0.87002(16) 0.06891(7) 0.90523(15) 0.0302(7) Uani 1 1 d .
O23 O 0.87862(16) 0.13258(7) 0.87178(15) 0.0274(7) Uani 1 1 d .
O17 O 0.77515(17) 0.06787(7) 0.98238(15) 0.0339(7) Uani 1 1 d .
O15 O 0.91915(16) 0.14292(7) 1.27868(14) 0.0283(7) Uani 1 1 d .
F60 F 1.07351(17) 0.21115(7) 0.76632(16) 0.0528(8) Uani 1 1 d .
F55 F 1.04135(15) 0.17283(7) 0.45476(13) 0.0485(8) Uani 1 1 d .
N4 N 0.65206(19) 0.11234(8) 0.97262(18) 0.0261(8) Uani 1 1 d .
F52 F 0.78472(15) 0.07328(7) 0.45043(15) 0.0527(8) Uani 1 1 d .
F4 F 0.23490(18) 0.07642(6) 1.21017(14) 0.0535(8) Uani 1 1 d .
O11 O 0.47375(16) 0.07656(6) 1.14954(14) 0.0264(7) Uani 1 1 d .
O32 O 1.13327(15) 0.07895(6) 0.61987(13) 0.0191(6) Uani 1 1 d .
C20 C 0.3284(2) 0.19178(9) 1.2351(2) 0.0225(9) Uani 1 1 d .
H20 H 0.3159 0.2123 1.2412 0.027 Uiso 1 1 calc R
O33 O 1.18905(16) 0.12419(6) 0.43980(14) 0.0256(7) Uani 1 1 d .
F17 F 0.32360(17) 0.15107(8) 0.99841(15) 0.0585(9) Uani 1 1 d .
F3 F 0.11451(15) 0.18297(7) 1.29090(17) 0.0563(8) Uani 1 1 d .
C11 C 0.4569(2) 0.13156(9) 1.3451(2) 0.0206(9) Uani 1 1 d .
O25 O 1.04747(15) 0.09355(6) 0.79211(14) 0.0254(7) Uani 1 1 d .
F45 F 0.62684(16) 0.05881(7) 0.69101(14) 0.0520(8) Uani 1 1 d .
F59 F 1.13963(19) 0.22690(6) 0.71176(15) 0.0566(9) Uani 1 1 d .
C37 C 0.6074(3) 0.04279(10) 1.2217(2) 0.0285(10) Uani 1 1 d .
O16 O 0.69609(16) 0.12328(7) 0.94586(14) 0.0298(7) Uani 1 1 d .
F32 F 0.83538(19) -0.00045(7) 1.07720(17) 0.0596(9) Uani 1 1 d .
F19 F 0.72080(18) 0.02805(7) 1.31181(17) 0.0575(9) Uani 1 1 d .
F1 F 0.14055(18) 0.17493(7) 1.19802(14) 0.0556(9) Uani 1 1 d .
F20 F 0.65834(19) -0.00802(6) 1.24347(17) 0.0579(9) Uani 1 1 d .
F65 F 1.13000(17) -0.02603(6) 0.76919(15) 0.0500(8) Uani 1 1 d .
F21 F 0.70771(19) 0.02602(7) 1.20056(18) 0.0626(10) Uani 1 1 d .
C9 C 0.3859(2) 0.17188(9) 1.5852(2) 0.0223(9) Uani 1 1 d .
C2 C 0.2225(2) 0.15620(9) 1.3139(2) 0.0234(9) Uani 1 1 d .
F15 F 0.54098(19) 0.20996(6) 1.32805(16) 0.0590(9) Uani 1 1 d .
O12 O 0.60662(16) 0.15553(6) 1.13940(14) 0.0240(6) Uani 1 1 d .
O18 O 0.89584(16) 0.10703(7) 1.03311(15) 0.0298(7) Uani 1 1 d .
C18 C 0.3999(2) 0.14650(9) 1.2844(2) 0.0201(9) Uani 1 1 d .
F25 F 0.63923(18) 0.18909(7) 1.04638(14) 0.0508(8) Uani 1 1 d .
N1 N 0.46835(18) 0.13492(7) 1.41658(17) 0.0196(7) Uani 1 1 d .
F46 F 0.98043(16) 0.03489(7) 0.90505(18) 0.0602(9) Uani 1 1 d .
C23 C 0.3659(2) 0.13180(9) 1.2166(2) 0.0202(9) Uani 1 1 d .
H23 H 0.3795 0.1115 1.2101 0.024 Uiso 1 1 calc R
F18 F 0.40647(18) 0.16716(8) 0.96604(15) 0.0586(9) Uani 1 1 d .
C81 C 0.9475(2) 0.10771(9) 0.8166(2) 0.0230(9) Uani 1 1 d .
F30 F 0.71352(18) 0.16584(9) 1.41227(15) 0.0719(11) Uani 1 1 d .
C85 C 1.0063(2) 0.14469(10) 0.9078(2) 0.0259(10) Uani 1 1 d .
C12 C 0.5518(2) 0.09836(9) 1.4144(2) 0.0231(9) Uani 1 1 d .
C21 C 0.2948(2) 0.17698(9) 1.1682(2) 0.0219(9) Uani 1 1 d .
F26 F 0.71541(18) 0.21530(7) 1.13146(16) 0.0626(9) Uani 1 1 d .
F44 F 0.66791(17) 0.01298(7) 0.71171(16) 0.0598(9) Uani 1 1 d .
F63 F 1.29049(16) 0.08787(7) 0.90030(15) 0.0584(9) Uani 1 1 d .
F62 F 1.32529(15) 0.07839(8) 0.81449(15) 0.0552(9) Uani 1 1 d .
C126 C 1.2771(2) 0.17895(9) 0.6943(2) 0.0200(9) Uani 1 1 d .
C127 C 1.2793(2) 0.14875(9) 0.7173(2) 0.0211(9) Uani 1 1 d .
H127 H 1.3045 0.1437 0.7671 0.025 Uiso 1 1 calc R
C112 C 1.2077(2) 0.06326(9) 0.79665(19) 0.0196(9) Uani 1 1 d .
C53 C 0.7319(2) 0.11808(9) 1.1043(2) 0.0210(9) Uani 1 1 d .
F24 F 0.4090(2) 0.00182(7) 1.11657(19) 0.0688(10) Uani 1 1 d .
C5 C 0.2721(3) 0.07480(10) 1.2812(2) 0.0321(11) Uani 1 1 d .
C46 C 0.6659(2) 0.10986(9) 1.0442(2) 0.0211(9) Uani 1 1 d .
C108 C 1.0575(2) 0.18235(9) 0.6171(2) 0.0261(10) Uani 1 1 d .
H108 H 1.0483 0.2032 0.6027 0.031 Uiso 1 1 calc R
F37 F 0.8125(2) 0.21383(7) 1.03661(17) 0.0759(12) Uani 1 1 d .
C49 C 0.4754(2) 0.09397(13) 0.9702(3) 0.0418(13) Uani 1 1 d .
H49A H 0.4645 0.0811 1.0045 0.063 Uiso 1 1 calc R
H49B H 0.4407 0.0897 0.9207 0.063 Uiso 1 1 calc R
H49C H 0.4719 0.1156 0.9816 0.063 Uiso 1 1 calc R
C117 C 1.1227(2) 0.05907(9) 0.5027(2) 0.0196(9) Uani 1 1 d .
C4 C 0.2683(2) 0.10446(9) 1.3213(2) 0.0256(10) Uani 1 1 d .
C13 C 0.6300(2) 0.09442(10) 1.4234(2) 0.0294(10) Uani 1 1 d .
H13A H 0.6321 0.0798 1.3872 0.044 Uiso 1 1 calc R
H13B H 0.6588 0.0867 1.4722 0.044 Uiso 1 1 calc R
H13C H 0.6492 0.1142 1.4166 0.044 Uiso 1 1 calc R
C103 C 0.8619(2) 0.11363(9) 0.5583(2) 0.0242(9) Uani 1 1 d .
H103 H 0.8140 0.1182 0.5258 0.029 Uiso 1 1 calc R
C101 C 0.8550(2) 0.16138(10) 0.6243(2) 0.0286(10) Uani 1 1 d .
C14 C 0.5168(2) 0.06734(9) 1.4132(2) 0.0300(10) Uani 1 1 d .
H14A H 0.4685 0.0704 1.4126 0.045 Uiso 1 1 calc R
H14B H 0.5464 0.0557 1.4565 0.045 Uiso 1 1 calc R
H14C H 0.5131 0.0560 1.3697 0.045 Uiso 1 1 calc R
F29 F 0.78363(17) 0.19305(7) 1.38094(14) 0.0550(9) Uani 1 1 d .
C57 C 0.8376(2) 0.15060(10) 1.1523(2) 0.0252(9) Uani 1 1 d .
H57 H 0.8663 0.1667 1.1458 0.030 Uiso 1 1 calc R
C22 C 0.3135(2) 0.14670(9) 1.1604(2) 0.0235(9) Uani 1 1 d .
H22 H 0.2894 0.1364 1.1155 0.028 Uiso 1 1 calc R
C56 C 0.8584(2) 0.13569(9) 1.2192(2) 0.0232(9) Uani 1 1 d .
C19 C 0.3803(2) 0.17615(9) 1.2925(2) 0.0200(9) Uani 1 1 d .
H19 H 0.4026 0.1860 1.3382 0.024 Uiso 1 1 calc R
F27 F 0.6026(2) 0.22179(7) 1.10292(18) 0.0666(10) Uani 1 1 d .
C36 C 0.6738(3) 0.02189(11) 1.2448(3) 0.0419(13) Uani 1 1 d .
C106 C 0.9943(3) 0.16941(10) 0.4856(2) 0.0301(10) Uani 1 1 d .
C114 C 1.1090(2) 0.02732(9) 0.7377(2) 0.0229(9) Uani 1 1 d .
C16 C 0.5398(2) 0.12213(10) 1.4659(2) 0.0259(10) Uani 1 1 d .
C47 C 0.5512(2) 0.08719(11) 0.9761(2) 0.0308(11) Uani 1 1 d .
C7 C 0.3839(2) 0.11691(9) 1.6010(2) 0.0238(9) Uani 1 1 d .
F40 F 0.5962(3) 0.16626(12) 0.7205(2) 0.1187(18) Uani 1 1 d .
C77 C 0.7283(2) 0.05121(10) 0.8020(2) 0.0255(10) Uani 1 1 d .
C43 C 0.6983(2) 0.18074(10) 1.2388(2) 0.0289(10) Uani 1 1 d .
H43 H 0.7286 0.1983 1.2524 0.035 Uiso 1 1 calc R
F28 F 0.8004(2) 0.14478(9) 1.39581(18) 0.0799(12) Uani 1 1 d .
C118 C 1.0550(2) 0.04224(10) 0.4964(2) 0.0295(10) Uani 1 1 d .
H11A H 1.0638 0.0314 0.5419 0.044 Uiso 1 1 calc R
H11B H 1.0417 0.0275 0.4565 0.044 Uiso 1 1 calc R
H11C H 1.0156 0.0570 0.4868 0.044 Uiso 1 1 calc R
C8 C 0.4048(2) 0.14603(9) 1.6293(2) 0.0249(9) Uani 1 1 d .
H8 H 0.4325 0.1484 1.6799 0.030 Uiso 1 1 calc R
C55 C 0.8168(2) 0.11209(9) 1.2283(2) 0.0252(9) Uani 1 1 d .
H55 H 0.8316 0.1019 1.2738 0.030 Uiso 1 1 calc R
C93 C 0.9061(2) 0.06341(9) 0.7331(2) 0.0246(9) Uani 1 1 d .
H93 H 0.9538 0.0554 0.7532 0.030 Uiso 1 1 calc R
C107 C 1.0329(2) 0.15952(9) 0.5651(2) 0.0231(9) Uani 1 1 d .
C116 C 1.1712(2) 0.10852(8) 0.5437(2) 0.0177(8) Uani 1 1 d .
C105 C 0.8557(2) 0.06892(10) 0.4776(2) 0.0284(10) Uani 1 1 d .
C123 C 1.2083(2) 0.13306(9) 0.59349(19) 0.0177(8) Uani 1 1 d .
C50 C 0.5756(2) 0.10562(11) 0.9242(2) 0.0319(11) Uani 1 1 d .
C113 C 1.1801(2) 0.03330(9) 0.7845(2) 0.0234(9) Uani 1 1 d .
H113 H 1.2106 0.0167 0.8088 0.028 Uiso 1 1 calc R
C3 C 0.2241(2) 0.12821(10) 1.2815(2) 0.0256(9) Uani 1 1 d .
H3 H 0.1946 0.1252 1.2316 0.031 Uiso 1 1 calc R
C88 C 0.8905(2) 0.09127(9) 0.7588(2) 0.0203(9) Uani 1 1 d .
C119 C 1.1881(2) 0.03777(9) 0.5296(2) 0.0296(10) Uani 1 1 d .
H11D H 1.2311 0.0492 0.5327 0.044 Uiso 1 1 calc R
H11E H 1.1798 0.0207 0.4956 0.044 Uiso 1 1 calc R
H11F H 1.1953 0.0298 0.5776 0.044 Uiso 1 1 calc R
C111 C 1.2860(2) 0.06749(10) 0.8500(2) 0.0291(10) Uani 1 1 d .
C131 C 1.4580(3) 0.22715(10) 0.8893(2) 0.0346(11) Uani 1 1 d .
H131 H 1.4892 0.2130 0.8802 0.041 Uiso 1 1 calc R
F34 F 1.00845(19) 0.12060(9) 1.15295(19) 0.0815(12) Uani 1 1 d .
F33 F 0.73926(19) 0.02287(8) 1.06931(19) 0.0737(11) Uani 1 1 d .
C98 C 0.5436(3) -0.01367(10) 0.3985(3) 0.0357(11) Uani 1 1 d .
H98 H 0.5001 -0.0197 0.3599 0.043 Uiso 1 1 calc R
C44 C 0.7004(2) 0.15951(10) 1.2914(2) 0.0253(9) Uani 1 1 d .
C125 C 1.2418(2) 0.18612(9) 0.6207(2) 0.0217(9) Uani 1 1 d .
H125 H 1.2409 0.2067 0.6050 0.026 Uiso 1 1 calc R
C134 C 1.3680(3) 0.26885(10) 0.9147(2) 0.0403(13) Uani 1 1 d .
H134 H 1.3369 0.2832 0.9233 0.048 Uiso 1 1 calc R
F31 F 0.7508(2) 0.00766(8) 0.97325(17) 0.0853(13) Uani 1 1 d .
C45 C 0.7504(3) 0.16609(12) 1.3705(2) 0.0384(12) Uani 1 1 d .
C17 C 0.5331(3) 0.10836(11) 1.5334(2) 0.0346(11) Uani 1 1 d .
H17A H 0.5312 0.1249 1.5656 0.052 Uiso 1 1 calc R
H17B H 0.5750 0.0953 1.5590 0.052 Uiso 1 1 calc R
H17C H 0.4889 0.0961 1.5186 0.052 Uiso 1 1 calc R
C102 C 0.8964(2) 0.13269(9) 0.6178(2) 0.0214(9) Uani 1 1 d .
C128 C 1.2446(2) 0.12604(9) 0.6674(2) 0.0204(9) Uani 1 1 d .
H128 H 1.2455 0.1055 0.6833 0.024 Uiso 1 1 calc R
C96 C 0.6173(3) -0.01072(11) 0.5258(3) 0.0395(12) Uani 1 1 d .
H96 H 0.6238 -0.0150 0.5744 0.047 Uiso 1 1 calc R
F48 F 0.9269(2) 0.00771(10) 0.9580(2) 0.0954(15) Uani 1 1 d .
C75 C 0.6605(4) 0.17774(15) 0.7315(3) 0.0645(18) Uani 1 1 d .
C104 C 0.8964(2) 0.08802(9) 0.5457(2) 0.0207(9) Uani 1 1 d .
C69 C 0.9202(3) 0.08570(11) 1.0785(2) 0.0325(11) Uani 1 1 d .
C120 C 1.1162(2) 0.07903(9) 0.4356(2) 0.0216(9) Uani 1 1 d .
C109 C 1.0954(2) 0.17537(9) 0.6899(2) 0.0227(9) Uani 1 1 d .
F16 F 0.34736(19) 0.19906(8) 1.00199(16) 0.0657(10) Uani 1 1 d .
C84 C 1.1286(3) 0.13865(12) 0.8959(2) 0.0374(12) Uani 1 1 d .
H84A H 1.1608 0.1232 0.8895 0.056 Uiso 1 1 calc R
H84B H 1.1545 0.1502 0.9405 0.056 Uiso 1 1 calc R
H84C H 1.1123 0.1527 0.8544 0.056 Uiso 1 1 calc R
C133 C 1.4409(3) 0.27278(11) 0.9473(2) 0.0438(14) Uani 1 1 d .
H133 H 1.4604 0.2898 0.9784 0.053 Uiso 1 1 calc R
C130 C 1.3836(2) 0.22312(9) 0.8565(2) 0.0256(10) Uani 1 1 d .
C91 C 0.7829(2) 0.05925(9) 0.6477(2) 0.0224(9) Uani 1 1 d .
C76 C 0.6579(3) 0.03857(11) 0.7436(2) 0.0347(11) Uani 1 1 d .
C42 C 0.6521(2) 0.17651(9) 1.1664(2) 0.0245(9) Uani 1 1 d .
C100 C 0.6602(3) 0.01038(9) 0.4407(2) 0.0298(10) Uani 1 1 d .
H100 H 0.6967 0.0206 0.4305 0.036 Uiso 1 1 calc R
C132 C 1.4867(3) 0.25185(11) 0.9350(3) 0.0444(13) Uani 1 1 d .
H132 H 1.5375 0.2544 0.9580 0.053 Uiso 1 1 calc R
C74 C 0.7153(3) 0.16984(12) 0.8079(3) 0.0405(12) Uani 1 1 d .
C38 C 0.5399(3) 0.03004(10) 1.1821(2) 0.0336(11) Uani 1 1 d .
H38 H 0.5358 0.0084 1.1763 0.040 Uiso 1 1 calc R
F13 F 0.5733(2) 0.23284(7) 1.2508(2) 0.0824(13) Uani 1 1 d .
C80 C 0.9193(3) 0.02122(12) 0.8967(3) 0.0468(13) Uani 1 1 d .
C90 C 0.7667(2) 0.08720(9) 0.6727(2) 0.0210(9) Uani 1 1 d .
H90 H 0.7191 0.0953 0.6518 0.025 Uiso 1 1 calc R
F47 F 0.9111(2) -0.00121(8) 0.8489(2) 0.0837(12) Uani 1 1 d .
C34 C 0.4342(2) 0.16689(10) 1.0913(2) 0.0272(10) Uani 1 1 d .
C60 C 0.9334(2) 0.19823(10) 1.2628(2) 0.0281(10) Uani 1 1 d .
C94 C 0.7386(3) 0.01520(9) 0.5730(2) 0.0324(11) Uani 1 1 d .
H94A H 0.7512 0.0011 0.6149 0.039 Uiso 1 1 calc R
H94B H 0.7791 0.0154 0.5570 0.039 Uiso 1 1 calc R
C6 C 0.4036(3) 0.09030(10) 1.6546(2) 0.0296(10) Uani 1 1 d .
C92 C 0.8521(2) 0.04746(9) 0.6783(2) 0.0251(9) Uani 1 1 d .
H92 H 0.8627 0.0284 0.6618 0.030 Uiso 1 1 calc R
F42 F 0.6521(3) 0.20705(9) 0.71717(19) 0.1059(17) Uani 1 1 d .
C110 C 1.1232(3) 0.20252(10) 0.7424(2) 0.0318(11) Uani 1 1 d .
C10 C 0.4156(3) 0.20297(10) 1.6209(2) 0.0289(10) Uani 1 1 d .
C58 C 0.7749(2) 0.14157(10) 1.0959(2) 0.0250(9) Uani 1 1 d .
H58 H 0.7606 0.1516 1.0503 0.030 Uiso 1 1 calc R
C89 C 0.8202(2) 0.10287(9) 0.7279(2) 0.0220(9) Uani 1 1 d .
H89 H 0.8091 0.1217 0.7450 0.026 Uiso 1 1 calc R
C52 C 0.5732(3) 0.08746(14) 0.8581(2) 0.0511(15) Uani 1 1 d .
H52A H 0.5878 0.1007 0.8269 0.077 Uiso 1 1 calc R
H52B H 0.5240 0.0800 0.8308 0.077 Uiso 1 1 calc R
H52C H 0.6063 0.0700 0.8743 0.077 Uiso 1 1 calc R
C97 C 0.5544(3) -0.01979(11) 0.4688(3) 0.0428(13) Uani 1 1 d .
H97 H 0.5183 -0.0304 0.4788 0.051 Uiso 1 1 calc R
C72 C 0.7940(3) 0.18800(11) 0.9280(3) 0.0365(12) Uani 1 1 d .
C30 C 0.1039(3) 0.23510(10) 1.0297(2) 0.0349(11) Uani 1 1 d .
H30 H 0.0885 0.2288 1.0666 0.042 Uiso 1 1 calc R
C54 C 0.7538(2) 0.10330(9) 1.1714(2) 0.0240(9) Uani 1 1 d .
H54 H 0.7253 0.0872 1.1780 0.029 Uiso 1 1 calc R
C29 C 0.0540(3) 0.24573(11) 0.9643(3) 0.0438(13) Uani 1 1 d .
H29 H 0.0044 0.2467 0.9562 0.053 Uiso 1 1 calc R
F41 F 0.6794(3) 0.16470(11) 0.68183(17) 0.1085(17) Uani 1 1 d .
C63 C 0.8775(3) 0.25739(12) 1.2515(3) 0.0507(14) Uani 1 1 d .
H63 H 0.8576 0.2774 1.2468 0.061 Uiso 1 1 calc R
C135 C 1.3394(3) 0.24449(10) 0.8698(2) 0.0324(11) Uani 1 1 d .
H135 H 1.2885 0.2421 0.8472 0.039 Uiso 1 1 calc R
F35 F 1.0082(2) 0.07691(12) 1.19698(19) 0.124(2) Uani 1 1 d U
F36 F 1.04499(19) 0.08332(11) 1.1141(2) 0.0887(13) Uani 1 1 d .
F38 F 0.8970(2) 0.21571(10) 1.0011(3) 0.1166(18) Uani 1 1 d .
C61 C 0.8936(2) 0.20695(10) 1.3028(2) 0.0318(11) Uani 1 1 d .
H61 H 0.8848 0.1925 1.3338 0.038 Uiso 1 1 calc R
C65 C 0.9450(3) 0.21977(11) 1.2176(2) 0.0401(12) Uani 1 1 d .
H65 H 0.9722 0.2143 1.1900 0.048 Uiso 1 1 calc R
C1 C 0.1690(2) 0.18081(10) 1.2694(2) 0.0326(11) Uani 1 1 d .
C78 C 0.7896(2) 0.03304(10) 0.8234(2) 0.0305(10) Uani 1 1 d .
H78 H 0.7865 0.0131 0.8032 0.037 Uiso 1 1 calc R
C26 C 0.1985(3) 0.24260(10) 0.9878(2) 0.0364(11) Uani 1 1 d .
H26 H 0.2480 0.2414 0.9955 0.044 Uiso 1 1 calc R
C70 C 0.9953(3) 0.09140(13) 1.1374(3) 0.0434(13) Uani 1 1 d U
C33 C 0.4529(3) 0.19162(10) 1.1385(2) 0.0332(11) Uani 1 1 d .
H33 H 0.4317 0.2111 1.1216 0.040 Uiso 1 1 calc R
C31 C 0.5204(3) 0.21727(11) 1.2591(3) 0.0434(13) Uani 1 1 d .
C95 C 0.6703(2) 0.00452(9) 0.5119(2) 0.0252(9) Uani 1 1 d .
C83 C 1.0869(3) 0.09726(11) 0.9572(2) 0.0400(12) Uani 1 1 d .
H83A H 1.0441 0.0880 0.9606 0.060 Uiso 1 1 calc R
H83B H 1.1181 0.1057 1.0045 0.060 Uiso 1 1 calc R
H83C H 1.1134 0.0816 0.9426 0.060 Uiso 1 1 calc R
C41 C 0.6526(3) 0.20100(11) 1.1114(3) 0.0354(11) Uani 1 1 d .
C99 C 0.5969(3) 0.00145(10) 0.3843(2) 0.0345(11) Uani 1 1 d .
H99 H 0.5900 0.0057 0.3355 0.041 Uiso 1 1 calc R
C79 C 0.8553(3) 0.04337(10) 0.8735(2) 0.0309(10) Uani 1 1 d .
C28 C 0.0764(3) 0.25494(11) 0.9105(3) 0.0452(14) Uani 1 1 d .
H28 H 0.0422 0.2623 0.8655 0.054 Uiso 1 1 calc R
C66 C 0.7852(3) 0.01983(13) 1.0376(3) 0.0487(14) Uani 1 1 d .
C40 C 0.4044(3) 0.03217(12) 1.1117(3) 0.0482(15) Uani 1 1 d .
C59 C 0.9653(2) 0.16631(10) 1.2708(2) 0.0316(10) Uani 1 1 d .
H59A H 0.9757 0.1617 1.2276 0.038 Uiso 1 1 calc R
H59B H 1.0117 0.1659 1.3137 0.038 Uiso 1 1 calc R
C129 C 1.3527(2) 0.19482(9) 0.8129(2) 0.0269(10) Uani 1 1 d .
H12A H 1.3924 0.1811 0.8144 0.032 Uiso 1 1 calc R
H12B H 1.3230 0.1837 0.8341 0.032 Uiso 1 1 calc R
C67 C 0.8178(3) 0.05118(11) 1.0318(2) 0.0355(11) Uani 1 1 d .
C71 C 0.8256(4) 0.21529(12) 0.9782(3) 0.0488(14) Uani 1 1 d .
F66 F 1.0242(2) -0.00946(8) 0.7381(3) 0.1085(16) Uani 1 1 d U
F39 F 0.8033(3) 0.24199(7) 0.94824(18) 0.0942(14) Uani 1 1 d U
C25 C 0.1766(2) 0.23356(9) 1.0420(2) 0.0275(10) Uani 1 1 d .
F23 F 0.3601(2) 0.03919(10) 1.1438(3) 0.1013(15) Uani 1 1 d .
C35 C 0.3767(3) 0.17148(12) 1.0142(3) 0.0410(12) Uani 1 1 d .
C24 C 0.2306(3) 0.22283(9) 1.1141(2) 0.0302(10) Uani 1 1 d .
H24A H 0.2762 0.2344 1.1273 0.036 Uiso 1 1 calc R
H24B H 0.2118 0.2263 1.1522 0.036 Uiso 1 1 calc R
C87 C 1.0128(3) 0.15065(12) 0.9850(2) 0.0377(12) Uani 1 1 d .
H87A H 0.9739 0.1644 0.9837 0.057 Uiso 1 1 calc R
H87B H 1.0596 0.1602 1.0131 0.057 Uiso 1 1 calc R
H87C H 1.0091 0.1312 1.0077 0.057 Uiso 1 1 calc R
C73 C 0.7455(3) 0.19361(11) 0.8566(3) 0.0449(13) Uani 1 1 d .
H73 H 0.7330 0.2142 0.8411 0.054 Uiso 1 1 calc R
C32 C 0.5020(3) 0.18854(9) 1.2100(2) 0.0287(10) Uani 1 1 d .
F64 F 1.0694(3) -0.01475(7) 0.65920(18) 0.1008(16) Uani 1 1 d U
C51 C 0.5389(3) 0.13670(13) 0.9025(3) 0.0473(14) Uani 1 1 d .
H51A H 0.5410 0.1476 0.9460 0.071 Uiso 1 1 calc R
H51B H 0.4883 0.1337 0.8695 0.071 Uiso 1 1 calc R
H51C H 0.5636 0.1488 0.8782 0.071 Uiso 1 1 calc R
C121 C 1.1446(3) 0.06366(10) 0.3841(2) 0.0326(11) Uani 1 1 d .
H12C H 1.1385 0.0775 0.3437 0.049 Uiso 1 1 calc R
H12D H 1.1177 0.0447 0.3653 0.049 Uiso 1 1 calc R
H12E H 1.1960 0.0589 0.4102 0.049 Uiso 1 1 calc R
C122 C 1.0408(2) 0.09216(10) 0.3947(2) 0.0314(10) Uani 1 1 d .
H12F H 1.0236 0.1015 0.4293 0.047 Uiso 1 1 calc R
H12G H 1.0079 0.0757 0.3684 0.047 Uiso 1 1 calc R
H12H H 1.0426 0.1077 0.3602 0.047 Uiso 1 1 calc R
C115 C 1.0833(3) -0.00603(11) 0.7267(3) 0.0427(13) Uani 1 1 d .
C86 C 0.9978(3) 0.17478(10) 0.8663(2) 0.0362(11) Uani 1 1 d .
H86A H 0.9933 0.1705 0.8168 0.054 Uiso 1 1 calc R
H86B H 1.0402 0.1877 0.8909 0.054 Uiso 1 1 calc R
H86C H 0.9544 0.1854 0.8646 0.054 Uiso 1 1 calc R
C27 C 0.1482(3) 0.25347(11) 0.9223(3) 0.0464(14) Uani 1 1 d .
H27 H 0.1635 0.2599 0.8855 0.056 Uiso 1 1 calc R
C64 C 0.9174(3) 0.24904(13) 1.2123(3) 0.0545(16) Uani 1 1 d .
H64 H 0.9259 0.2636 1.1813 0.065 Uiso 1 1 calc R
F22 F 0.3753(3) 0.03982(11) 1.0463(2) 0.134(2) Uani 1 1 d U
C15 C 0.5924(3) 0.14894(11) 1.4864(2) 0.0355(11) Uani 1 1 d .
H15A H 0.5949 0.1576 1.4425 0.053 Uiso 1 1 calc R
H15B H 0.6403 0.1418 1.5190 0.053 Uiso 1 1 calc R
H15C H 0.5757 0.1647 1.5110 0.053 Uiso 1 1 calc R
C62 C 0.8668(3) 0.23631(11) 1.2978(3) 0.0415(12) Uani 1 1 d .
H62 H 0.8408 0.2421 1.3263 0.050 Uiso 1 1 calc R
C68 C 0.8873(3) 0.05806(11) 1.0807(2) 0.0393(12) Uani 1 1 d .
H68 H 0.9130 0.0434 1.1167 0.047 Uiso 1 1 calc R
C39 C 0.4783(3) 0.04800(10) 1.1507(2) 0.0296(10) Uani 1 1 d .
C48 C 0.5628(3) 0.05256(12) 0.9751(3) 0.0491(14) Uani 1 1 d .
H48A H 0.6130 0.0484 0.9825 0.074 Uiso 1 1 calc R
H48B H 0.5304 0.0442 0.9283 0.074 Uiso 1 1 calc R
H48C H 0.5526 0.0429 1.0141 0.074 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
O21 Eu2 O18 139.54(10) .
O21 Eu2 O16 89.56(10) .
O18 Eu2 O16 104.70(10) .
O21 Eu2 O20 72.65(10) .
O18 Eu2 O20 147.06(10) .
O16 Eu2 O20 76.65(10) .
O21 Eu2 O17 76.29(10) .
O18 Eu2 O17 72.43(10) .
O16 Eu2 O17 72.78(11) .
O20 Eu2 O17 136.06(11) .
O21 Eu2 O23 105.21(9) .
O18 Eu2 O23 87.63(10) .
O16 Eu2 O23 140.50(10) .
O20 Eu2 O23 73.43(10) .
O17 Eu2 O23 145.85(10) .
O21 Eu2 O22 71.93(10) .
O18 Eu2 O22 75.50(10) .
O16 Eu2 O22 145.51(10) .
O20 Eu2 O22 122.11(9) .
O17 Eu2 O22 74.63(10) .
O23 Eu2 O22 73.65(10) .
O21 Eu2 O19 143.49(10) .
O18 Eu2 O19 76.85(10) .
O16 Eu2 O19 74.08(10) .
O20 Eu2 O19 71.90(10) .
O17 Eu2 O19 126.42(10) .
O23 Eu2 O19 72.52(9) .
O22 Eu2 O19 136.68(10) .
O27 Eu3 O32 87.89(9) .
O27 Eu3 O30 143.66(9) .
O32 Eu3 O30 71.86(9) .
O27 Eu3 O29 137.11(9) .
O32 Eu3 O29 106.54(9) .
O30 Eu3 O29 78.64(9) .
O27 Eu3 O31 73.04(9) .
O32 Eu3 O31 76.50(9) .
O30 Eu3 O31 73.04(9) .
O29 Eu3 O31 149.00(9) .
O27 Eu3 O28 73.50(9) .
O32 Eu3 O28 74.21(9) .
O30 Eu3 O28 125.90(9) .
O29 Eu3 O28 72.21(9) .
O31 Eu3 O28 135.79(8) .
O27 Eu3 O26 72.40(9) .
O32 Eu3 O26 147.09(8) .
O30 Eu3 O26 137.89(8) .
O29 Eu3 O26 74.44(9) .
O31 Eu3 O26 120.03(9) .
O28 Eu3 O26 75.01(9) .
O27 Eu3 O25 109.22(9) .
O32 Eu3 O25 138.07(9) .
O30 Eu3 O25 72.30(9) .
O29 Eu3 O25 86.87(9) .
O31 Eu3 O25 72.84(9) .
O28 Eu3 O25 146.61(9) .
O26 Eu3 O25 74.44(9) .
O13 Eu1 O9 136.12(10) .
O13 Eu1 O7 91.15(10) .
O9 Eu1 O7 103.54(10) .
O13 Eu1 O11 147.72(9) .
O9 Eu1 O11 75.44(10) .
O7 Eu1 O11 70.84(9) .
O13 Eu1 O8 72.15(10) .
O9 Eu1 O8 72.22(10) .
O7 Eu1 O8 75.08(9) .
O11 Eu1 O8 125.02(10) .
O13 Eu1 O10 77.67(10) .
O9 Eu1 O10 145.32(10) .
O7 Eu1 O10 78.72(9) .
O11 Eu1 O10 72.75(10) .
O8 Eu1 O10 139.15(9) .
O13 Eu1 O12 72.83(9) .
O9 Eu1 O12 74.12(10) .
O7 Eu1 O12 149.61(9) .
O11 Eu1 O12 134.41(9) .
O8 Eu1 O12 75.46(9) .
O10 Eu1 O12 120.82(10) .
O13 Eu1 O14 103.37(9) .
O9 Eu1 O14 92.31(9) .
O7 Eu1 O14 138.81(9) .
O11 Eu1 O14 77.02(9) .
O8 Eu1 O14 146.01(9) .
O10 Eu1 O14 67.46(9) .
O12 Eu1 O14 71.18(9) .
O1 Cu1 O3 164.19(12) .
O1 Cu1 O2 93.45(12) .
O3 Cu1 O2 89.40(11) .
O1 Cu1 O4 87.87(12) .
O3 Cu1 O4 93.00(11) .
O2 Cu1 O4 166.43(12) .
O1 Cu1 O5 93.94(10) .
O3 Cu1 O5 101.74(11) .
O2 Cu1 O5 86.88(11) .
O4 Cu1 O5 79.55(10) .
O1 Cu1 O33 76.96(10) 1_456
O3 Cu1 O33 87.76(11) 1_456
O2 Cu1 O33 85.73(11) 1_456
O4 Cu1 O33 107.69(10) 1_456
O5 Cu1 O33 167.89(9) 1_456
C4 O2 Cu1 123.7(3) .
C112 O30 Eu3 134.2(3) .
C7 O3 Cu1 124.3(3) .
C37 O10 Eu1 132.6(3) .
C9 O4 Cu1 124.1(3) .
C2 O1 Cu1 123.7(3) .
C125 C124 C123 120.1(4) .
C125 C124 H124 120.0 .
C123 C124 H124 120.0 .
C114 O31 Eu3 134.0(3) .
C34 O9 Eu1 133.7(3) .
C109 O29 Eu3 132.7(3) .
C126 O34 C129 115.6(3) .
C74 O20 Eu2 135.7(3) .
O14 N3 C46 125.4(3) .
O14 N3 C47 120.6(3) .
C46 N3 C47 113.3(3) .
C44 O13 Eu1 131.5(3) .
O32 N7 C116 126.1(3) .
O32 N7 C117 119.8(3) .
C116 N7 C117 113.4(3) .
C102 O26 Eu3 132.7(2) .
C72 O19 Eu2 134.9(3) .
N1 O5 Cu1 131.3(2) .
C91 O24 C94 116.2(3) .
O33 N8 C116 125.1(3) .
O33 N8 C120 122.3(3) .
C116 N8 C120 112.2(3) .
C32 O8 Eu1 132.8(3) .
O7 N2 C11 126.3(3) .
O7 N2 C12 119.8(3) .
C11 N2 C12 112.8(3) .
N3 O14 Eu1 140.8(2) .
N2 O7 Eu1 143.6(2) .
C107 O28 Eu3 131.7(2) .
C104 O27 Eu3 134.2(2) .
O23 N5 C81 126.2(4) .
O23 N5 C85 121.2(3) .
C81 N5 C85 111.8(3) .
C21 O6 C24 116.3(3) .
O25 N6 C81 125.5(3) .
O25 N6 C82 121.3(3) .
C81 N6 C82 112.7(3) .
C77 O21 Eu2 135.4(3) .
N6 C82 C84 110.5(3) .
N6 C82 C83 105.9(3) .
C84 C82 C83 111.2(4) .
N6 C82 C85 99.1(3) .
C84 C82 C85 115.1(4) .
C83 C82 C85 114.0(3) .
C79 O22 Eu2 133.2(3) .
N5 O23 Eu2 139.9(2) .
C67 O17 Eu2 131.2(3) .
C56 O15 C59 117.7(3) .
O16 N4 C46 125.5(3) .
O16 N4 C50 120.2(3) .
C46 N4 C50 113.7(3) .
C39 O11 Eu1 134.4(3) .
N7 O32 Eu3 135.2(2) .
C19 C20 C21 119.3(4) .
C19 C20 H20 120.4 .
C21 C20 H20 120.4 .
N8 O33 Cu1 132.3(2) 1_654
N2 C11 N1 107.3(3) .
N2 C11 C18 127.4(3) .
N1 C11 C18 125.4(3) .
N6 O25 Eu3 138.7(2) .
O10 C37 C38 128.1(4) .
O10 C37 C36 113.5(4) .
C38 C37 C36 118.3(4) .
N4 O16 Eu2 142.7(3) .
O4 C9 C8 128.1(4) .
O4 C9 C10 114.5(3) .
C8 C9 C10 117.4(4) .
O1 C2 C3 128.8(4) .
O1 C2 C1 112.2(4) .
C3 C2 C1 118.9(4) .
C42 O12 Eu1 131.5(2) .
C69 O18 Eu2 132.8(3) .
C19 C18 C23 119.2(4) .
C19 C18 C11 119.2(4) .
C23 C18 C11 121.5(3) .
O5 N1 C11 125.7(3) .
O5 N1 C16 121.8(3) .
C11 N1 C16 111.9(3) .
C22 C23 C18 120.0(4) .
C22 C23 H23 120.0 .
C18 C23 H23 120.0 .
N6 C81 N5 107.0(4) .
N6 C81 C88 126.8(4) .
N5 C81 C88 126.1(4) .
N5 C85 C87 110.3(3) .
N5 C85 C86 105.4(3) .
C87 C85 C86 110.7(4) .
N5 C85 C82 99.9(3) .
C87 C85 C82 115.5(4) .
C86 C85 C82 114.0(3) .
N2 C12 C14 105.9(3) .
N2 C12 C13 110.2(3) .
C14 C12 C13 110.7(3) .
N2 C12 C16 99.7(3) .
C14 C12 C16 114.2(3) .
C13 C12 C16 115.1(4) .
O6 C21 C20 123.9(4) .
O6 C21 C22 116.5(3) .
C20 C21 C22 119.6(4) .
O34 C126 C125 115.9(3) .
O34 C126 C127 124.1(3) .
C125 C126 C127 120.0(4) .
C128 C127 C126 119.7(4) .
C128 C127 H127 120.1 .
C126 C127 H127 120.1 .
O30 C112 C113 128.4(4) .
O30 C112 C111 114.0(4) .
C113 C112 C111 117.6(4) .
C58 C53 C54 118.8(4) .
C58 C53 C46 119.6(4) .
C54 C53 C46 121.6(4) .
F5 C5 F4 108.3(4) .
F5 C5 F6 106.6(4) .
F4 C5 F6 106.8(3) .
F5 C5 C4 111.3(3) .
F4 C5 C4 113.2(4) .
F6 C5 C4 110.3(4) .
N4 C46 N3 106.0(3) .
N4 C46 C53 126.9(4) .
N3 C46 C53 127.1(3) .
C109 C108 C107 121.3(4) .
C109 C108 H108 119.4 .
C107 C108 H108 119.4 .
C47 C49 H49A 109.5 .
C47 C49 H49B 109.5 .
H49A C49 H49B 109.5 .
C47 C49 H49C 109.5 .
H49A C49 H49C 109.5 .
H49B C49 H49C 109.5 .
N7 C117 C118 110.4(3) .
N7 C117 C119 105.4(3) .
C118 C117 C119 111.1(3) .
N7 C117 C120 99.0(3) .
C118 C117 C120 115.7(3) .
C119 C117 C120 114.1(3) .
O2 C4 C3 128.5(4) .
O2 C4 C5 112.9(4) .
C3 C4 C5 118.5(4) .
C12 C13 H13A 109.5 .
C12 C13 H13B 109.5 .
H13A C13 H13B 109.5 .
C12 C13 H13C 109.5 .
H13A C13 H13C 109.5 .
H13B C13 H13C 109.5 .
C102 C103 C104 121.3(4) .
C102 C103 H103 119.3 .
C104 C103 H103 119.3 .
F49 C101 F50 107.1(3) .
F49 C101 F51 107.4(4) .
F50 C101 F51 107.1(4) .
F49 C101 C102 112.3(3) .
F50 C101 C102 113.3(4) .
F51 C101 C102 109.3(3) .
C12 C14 H14A 109.5 .
C12 C14 H14B 109.5 .
H14A C14 H14B 109.5 .
C12 C14 H14C 109.5 .
H14A C14 H14C 109.5 .
H14B C14 H14C 109.5 .
C58 C57 C56 118.9(4) .
C58 C57 H57 120.6 .
C56 C57 H57 120.6 .
C23 C22 C21 120.7(4) .
C23 C22 H22 119.6 .
C21 C22 H22 119.6 .
O15 C56 C55 115.8(3) .
O15 C56 C57 123.8(4) .
C55 C56 C57 120.4(4) .
C18 C19 C20 121.2(4) .
C18 C19 H19 119.4 .
C20 C19 H19 119.4 .
F21 C36 F19 107.4(5) .
F21 C36 F20 107.2(4) .
F19 C36 F20 106.5(4) .
F21 C36 C37 109.7(4) .
F19 C36 C37 111.8(4) .
F20 C36 C37 113.9(5) .
F56 C106 F57 107.0(4) .
F56 C106 F55 106.5(4) .
F57 C106 F55 107.5(3) .
F56 C106 C107 112.3(3) .
F57 C106 C107 112.5(3) .
F55 C106 C107 110.7(4) .
O31 C114 C113 128.4(4) .
O31 C114 C115 113.3(4) .
C113 C114 C115 118.3(4) .
N1 C16 C15 106.1(3) .
N1 C16 C17 109.4(3) .
C15 C16 C17 111.0(4) .
N1 C16 C12 99.9(3) .
C15 C16 C12 114.7(4) .
C17 C16 C12 114.7(3) .
N3 C47 C49 109.7(3) .
N3 C47 C48 105.8(4) .
C49 C47 C48 110.3(4) .
N3 C47 C50 100.3(3) .
C49 C47 C50 115.3(4) .
C48 C47 C50 114.5(4) .
O3 C7 C8 128.4(4) .
O3 C7 C6 114.4(4) .
C8 C7 C6 117.2(4) .
O21 C77 C78 128.0(4) .
O21 C77 C76 113.9(4) .
C78 C77 C76 118.1(4) .
C42 C43 C44 120.6(4) .
C42 C43 H43 119.7 .
C44 C43 H43 119.7 .
C117 C118 H11A 109.5 .
C117 C118 H11B 109.5 .
H11A C118 H11B 109.5 .
C117 C118 H11C 109.5 .
H11A C118 H11C 109.5 .
H11B C118 H11C 109.5 .
C9 C8 C7 121.3(4) .
C9 C8 H8 119.4 .
C7 C8 H8 119.4 .
C54 C55 C56 120.2(4) .
C54 C55 H55 119.9 .
C56 C55 H55 119.9 .
C92 C93 C88 120.3(4) .
C92 C93 H93 119.8 .
C88 C93 H93 119.8 .
O28 C107 C108 128.5(4) .
O28 C107 C106 113.8(4) .
C108 C107 C106 117.7(4) .
N7 C116 N8 107.0(3) .
N7 C116 C123 126.3(3) .
N8 C116 C123 126.7(3) .
F52 C105 F54 107.1(4) .
F52 C105 F53 106.9(4) .
F54 C105 F53 106.9(3) .
F52 C105 C104 113.4(3) .
F54 C105 C104 110.6(3) .
F53 C105 C104 111.6(3) .
C124 C123 C128 119.1(3) .
C124 C123 C116 122.4(3) .
C128 C123 C116 118.5(3) .
N4 C50 C51 105.8(4) .
N4 C50 C52 109.7(4) .
C51 C50 C52 111.7(4) .
N4 C50 C47 100.8(3) .
C51 C50 C47 114.0(4) .
C52 C50 C47 114.0(4) .
C114 C113 C112 121.5(4) .
C114 C113 H113 119.2 .
C112 C113 H113 119.2 .
C2 C3 C4 120.9(4) .
C2 C3 H3 119.6 .
C4 C3 H3 119.6 .
C89 C88 C93 119.1(4) .
C89 C88 C81 121.1(4) .
C93 C88 C81 119.8(4) .
C117 C119 H11D 109.5 .
C117 C119 H11E 109.5 .
H11D C119 H11E 109.5 .
C117 C119 H11F 109.5 .
H11D C119 H11F 109.5 .
H11E C119 H11F 109.5 .
F61 C111 F63 107.7(3) .
F61 C111 F62 106.2(4) .
F63 C111 F62 106.9(4) .
F61 C111 C112 115.3(4) .
F63 C111 C112 110.8(4) .
F62 C111 C112 109.5(3) .
C132 C131 C130 120.0(5) .
C132 C131 H131 120.0 .
C130 C131 H131 120.0 .
C97 C98 C99 119.2(4) .
C97 C98 H98 120.4 .
C99 C98 H98 120.4 .
O13 C44 C43 129.2(4) .
O13 C44 C45 112.7(4) .
C43 C44 C45 118.1(4) .
C124 C125 C126 120.4(4) .
C124 C125 H125 119.8 .
C126 C125 H125 119.8 .
C133 C134 C135 120.5(5) .
C133 C134 H134 119.7 .
C135 C134 H134 119.7 .
F28 C45 F30 106.6(4) .
F28 C45 F29 107.6(4) .
F30 C45 F29 106.4(4) .
F28 C45 C44 110.9(4) .
F30 C45 C44 110.5(4) .
F29 C45 C44 114.4(4) .
C16 C17 H17A 109.5 .
C16 C17 H17B 109.5 .
H17A C17 H17B 109.5 .
C16 C17 H17C 109.5 .
H17A C17 H17C 109.5 .
H17B C17 H17C 109.5 .
O26 C102 C103 128.7(4) .
O26 C102 C101 114.2(3) .
C103 C102 C101 117.0(4) .
C127 C128 C123 120.7(4) .
C127 C128 H128 119.6 .
C123 C128 H128 119.6 .
C95 C96 C97 120.0(4) .
C95 C96 H96 120.0 .
C97 C96 H96 120.0 .
F42 C75 F40 107.4(6) .
F42 C75 F41 107.7(5) .
F40 C75 F41 105.5(6) .
F42 C75 C74 114.8(5) .
F40 C75 C74 110.6(5) .
F41 C75 C74 110.3(5) .
O27 C104 C103 128.0(4) .
O27 C104 C105 114.0(3) .
C103 C104 C105 118.0(4) .
O18 C69 C68 127.7(4) .
O18 C69 C70 115.0(4) .
C68 C69 C70 117.3(4) .
N8 C120 C121 109.6(3) .
N8 C120 C122 107.0(3) .
C121 C120 C122 111.3(3) .
N8 C120 C117 100.1(3) .
C121 C120 C117 114.4(3) .
C122 C120 C117 113.5(3) .
O29 C109 C108 128.3(4) .
O29 C109 C110 114.8(4) .
C108 C109 C110 116.9(4) .
C82 C84 H84A 109.5 .
C82 C84 H84B 109.5 .
H84A C84 H84B 109.5 .
C82 C84 H84C 109.5 .
H84A C84 H84C 109.5 .
H84B C84 H84C 109.5 .
C134 C133 C132 119.9(4) .
C134 C133 H133 120.1 .
C132 C133 H133 120.1 .
C135 C130 C131 118.7(4) .
C135 C130 C129 121.0(4) .
C131 C130 C129 120.1(4) .
O24 C91 C92 125.0(4) .
O24 C91 C90 114.9(4) .
C92 C91 C90 120.1(4) .
F43 C76 F45 106.8(4) .
F43 C76 F44 107.2(4) .
F45 C76 F44 106.7(4) .
F43 C76 C77 110.9(3) .
F45 C76 C77 111.6(4) .
F44 C76 C77 113.2(4) .
O12 C42 C43 128.2(4) .
O12 C42 C41 114.0(4) .
C43 C42 C41 117.7(4) .
C99 C100 C95 120.2(4) .
C99 C100 H100 119.9 .
C95 C100 H100 119.9 .
C131 C132 C133 119.8(5) .
C131 C132 H132 120.1 .
C133 C132 H132 120.1 .
O20 C74 C73 128.0(5) .
O20 C74 C75 113.4(5) .
C73 C74 C75 118.5(5) .
C37 C38 C39 122.0(4) .
C37 C38 H38 119.0 .
C39 C38 H38 119.0 .
F48 C80 F46 109.0(5) .
F48 C80 F47 106.2(5) .
F46 C80 F47 105.5(4) .
F48 C80 C79 109.7(4) .
F46 C80 C79 112.7(4) .
F47 C80 C79 113.3(5) .
C89 C90 C91 119.8(4) .
C89 C90 H90 120.1 .
C91 C90 H90 120.1 .
O9 C34 C33 128.1(4) .
O9 C34 C35 113.2(4) .
C33 C34 C35 118.6(4) .
C65 C60 C61 118.5(4) .
C65 C60 C59 121.0(4) .
C61 C60 C59 120.5(4) .
O24 C94 C95 108.0(4) .
O24 C94 H94A 110.1 .
C95 C94 H94A 110.1 .
O24 C94 H94B 110.1 .
C95 C94 H94B 110.1 .
H94A C94 H94B 108.4 .
F8 C6 F7 107.7(3) .
F8 C6 F9 106.9(3) .
F7 C6 F9 106.8(3) .
F8 C6 C7 110.2(4) .
F7 C6 C7 112.2(4) .
F9 C6 C7 112.8(3) .
C91 C92 C93 120.1(4) .
C91 C92 H92 119.9 .
C93 C92 H92 119.9 .
F58 C110 F60 107.2(4) .
F58 C110 F59 106.8(4) .
F60 C110 F59 107.6(4) .
F58 C110 C109 112.0(4) .
F60 C110 C109 110.1(4) .
F59 C110 C109 112.9(4) .
F11 C10 F10 108.6(3) .
F11 C10 F12 107.7(3) .
F10 C10 F12 106.6(4) .
F11 C10 C9 112.6(4) .
F10 C10 C9 111.5(3) .
F12 C10 C9 109.6(3) .
C57 C58 C53 121.5(4) .
C57 C58 H58 119.2 .
C53 C58 H58 119.2 .
C90 C89 C88 120.6(4) .
C90 C89 H89 119.7 .
C88 C89 H89 119.7 .
C50 C52 H52A 109.5 .
C50 C52 H52B 109.5 .
H52A C52 H52B 109.5 .
C50 C52 H52C 109.5 .
H52A C52 H52C 109.5 .
H52B C52 H52C 109.5 .
C98 C97 C96 121.0(5) .
C98 C97 H97 119.5 .
C96 C97 H97 119.5 .
O19 C72 C73 127.8(5) .
O19 C72 C71 113.5(4) .
C73 C72 C71 118.6(4) .
C29 C30 C25 120.4(5) .
C29 C30 H30 119.8 .
C25 C30 H30 119.8 .
C55 C54 C53 120.2(4) .
C55 C54 H54 119.9 .
C53 C54 H54 119.9 .
C30 C29 C28 119.9(5) .
C30 C29 H29 120.1 .
C28 C29 H29 120.1 .
C64 C63 C62 119.3(5) .
C64 C63 H63 120.4 .
C62 C63 H63 120.4 .
C134 C135 C130 121.0(5) .
C134 C135 H135 119.5 .
C130 C135 H135 119.5 .
C62 C61 C60 120.6(4) .
C62 C61 H61 119.7 .
C60 C61 H61 119.7 .
C64 C65 C60 120.5(5) .
C64 C65 H65 119.7 .
C60 C65 H65 119.7 .
F2 C1 F3 106.3(4) .
F2 C1 F1 107.1(3) .
F3 C1 F1 107.6(4) .
F2 C1 C2 112.4(4) .
F3 C1 C2 110.0(3) .
F1 C1 C2 113.1(4) .
C79 C78 C77 121.3(4) .
C79 C78 H78 119.4 .
C77 C78 H78 119.4 .
C25 C26 C27 120.0(5) .
C25 C26 H26 120.0 .
C27 C26 H26 120.0 .
F35 C70 F34 108.0(5) .
F35 C70 F36 107.3(5) .
F34 C70 F36 103.5(5) .
F35 C70 C69 114.4(4) .
F34 C70 C69 112.8(5) .
F36 C70 C69 110.1(4) .
C34 C33 C32 121.3(4) .
C34 C33 H33 119.3 .
C32 C33 H33 119.3 .
F15 C31 F13 108.8(5) .
F15 C31 F14 107.4(4) .
F13 C31 F14 106.9(4) .
F15 C31 C32 111.7(4) .
F13 C31 C32 109.6(4) .
F14 C31 C32 112.4(5) .
C96 C95 C100 119.3(4) .
C96 C95 C94 121.0(4) .
C100 C95 C94 119.7(4) .
C82 C83 H83A 109.5 .
C82 C83 H83B 109.5 .
H83A C83 H83B 109.5 .
C82 C83 H83C 109.5 .
H83A C83 H83C 109.5 .
H83B C83 H83C 109.5 .
F27 C41 F25 107.2(4) .
F27 C41 F26 107.8(4) .
F25 C41 F26 106.3(4) .
F27 C41 C42 110.3(4) .
F25 C41 C42 112.1(4) .
F26 C41 C42 112.7(4) .
C100 C99 C98 120.3(4) .
C100 C99 H99 119.8 .
C98 C99 H99 119.8 .
O22 C79 C78 128.4(4) .
O22 C79 C80 113.8(4) .
C78 C79 C80 117.7(4) .
C27 C28 C29 120.0(5) .
C27 C28 H28 120.0 .
C29 C28 H28 120.0 .
F31 C66 F33 108.4(5) .
F31 C66 F32 107.3(5) .
F33 C66 F32 106.7(4) .
F31 C66 C67 111.1(4) .
F33 C66 C67 110.4(5) .
F32 C66 C67 112.7(4) .
F22 C40 F24 109.4(5) .
F22 C40 F23 108.8(6) .
F24 C40 F23 103.6(4) .
F22 C40 C39 111.6(4) .
F24 C40 C39 112.5(5) .
F23 C40 C39 110.6(4) .
O15 C59 C60 113.5(4) .
O15 C59 H59A 108.9 .
C60 C59 H59A 108.9 .
O15 C59 H59B 108.9 .
C60 C59 H59B 108.9 .
H59A C59 H59B 107.7 .
O34 C129 C130 110.2(3) .
O34 C129 H12A 109.6 .
C130 C129 H12A 109.6 .
O34 C129 H12B 109.6 .
C130 C129 H12B 109.6 .
H12A C129 H12B 108.1 .
O17 C67 C68 128.0(4) .
O17 C67 C66 113.3(4) .
C68 C67 C66 118.7(4) .
F37 C71 F39 107.6(5) .
F37 C71 F38 105.6(5) .
F39 C71 F38 106.0(5) .
F37 C71 C72 112.0(4) .
F39 C71 C72 114.5(5) .
F38 C71 C72 110.6(4) .
C26 C25 C30 119.4(4) .
C26 C25 C24 120.7(4) .
C30 C25 C24 120.0(4) .
F16 C35 F17 107.9(4) .
F16 C35 F18 106.9(4) .
F17 C35 F18 106.5(4) .
F16 C35 C34 114.2(4) .
F17 C35 C34 111.6(4) .
F18 C35 C34 109.4(4) .
O6 C24 C25 108.4(3) .
O6 C24 H24A 110.0 .
C25 C24 H24A 110.0 .
O6 C24 H24B 110.0 .
C25 C24 H24B 110.0 .
H24A C24 H24B 108.4 .
C85 C87 H87A 109.5 .
C85 C87 H87B 109.5 .
H87A C87 H87B 109.5 .
C85 C87 H87C 109.5 .
H87A C87 H87C 109.5 .
H87B C87 H87C 109.5 .
C74 C73 C72 121.6(5) .
C74 C73 H73 119.2 .
C72 C73 H73 119.2 .
O8 C32 C33 127.5(4) .
O8 C32 C31 114.2(4) .
C33 C32 C31 118.2(4) .
C50 C51 H51A 109.5 .
C50 C51 H51B 109.5 .
H51A C51 H51B 109.5 .
C50 C51 H51C 109.5 .
H51A C51 H51C 109.5 .
H51B C51 H51C 109.5 .
C120 C121 H12C 109.5 .
C120 C121 H12D 109.5 .
H12C C121 H12D 109.5 .
C120 C121 H12E 109.5 .
H12C C121 H12E 109.5 .
H12D C121 H12E 109.5 .
C120 C122 H12F 109.5 .
C120 C122 H12G 109.5 .
H12F C122 H12G 109.5 .
C120 C122 H12H 109.5 .
H12F C122 H12H 109.5 .
H12G C122 H12H 109.5 .
F66 C115 F65 106.1(4) .
F66 C115 F64 107.9(5) .
F65 C115 F64 106.2(4) .
F66 C115 C114 111.3(4) .
F65 C115 C114 114.9(4) .
F64 C115 C114 110.1(4) .
C85 C86 H86A 109.5 .
C85 C86 H86B 109.5 .
H86A C86 H86B 109.5 .
C85 C86 H86C 109.5 .
H86A C86 H86C 109.5 .
H86B C86 H86C 109.5 .
C28 C27 C26 120.3(5) .
C28 C27 H27 119.8 .
C26 C27 H27 119.8 .
C65 C64 C63 120.6(5) .
C65 C64 H64 119.7 .
C63 C64 H64 119.7 .
C16 C15 H15A 109.5 .
C16 C15 H15B 109.5 .
H15A C15 H15B 109.5 .
C16 C15 H15C 109.5 .
H15A C15 H15C 109.5 .
H15B C15 H15C 109.5 .
C61 C62 C63 120.4(5) .
C61 C62 H62 119.8 .
C63 C62 H62 119.8 .
C69 C68 C67 121.9(4) .
C69 C68 H68 119.1 .
C67 C68 H68 119.1 .
O11 C39 C38 128.1(4) .
O11 C39 C40 112.7(4) .
C38 C39 C40 119.2(4) .
C47 C48 H48A 109.5 .
C47 C48 H48B 109.5 .
H48A C48 H48B 109.5 .
C47 C48 H48C 109.5 .
H48A C48 H48C 109.5 .
H48B C48 H48C 109.5 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu2 O21 2.370(3) .
Eu2 O18 2.380(3) .
Eu2 O16 2.383(3) .
Eu2 O20 2.386(3) .
Eu2 O17 2.385(3) .
Eu2 O23 2.403(3) .
Eu2 O22 2.402(3) .
Eu2 O19 2.406(3) .
Eu3 O27 2.371(3) .
Eu3 O32 2.374(2) .
Eu3 O30 2.381(3) .
Eu3 O29 2.387(3) .
Eu3 O31 2.387(3) .
Eu3 O28 2.390(2) .
Eu3 O26 2.404(3) .
Eu3 O25 2.428(2) .
Eu1 O13 2.338(3) .
Eu1 O9 2.349(3) .
Eu1 O7 2.366(2) .
Eu1 O11 2.385(3) .
Eu1 O8 2.390(3) .
Eu1 O10 2.398(3) .
Eu1 O12 2.409(3) .
Eu1 O14 2.434(2) .
Cu1 O1 1.932(3) .
Cu1 O3 1.938(3) .
Cu1 O2 1.950(3) .
Cu1 O4 1.948(3) .
Cu1 O5 2.435(3) .
Cu1 O33 2.558(3) 1_456
O2 C4 1.264(5) .
O30 C112 1.244(5) .
O3 C7 1.265(5) .
O10 C37 1.255(5) .
O4 C9 1.263(5) .
O1 C2 1.260(5) .
C124 C125 1.385(5) .
C124 C123 1.401(5) .
C124 H124 0.9500 .
O31 C114 1.247(5) .
O9 C34 1.256(5) .
O29 C109 1.255(5) .
O34 C126 1.361(5) .
O34 C129 1.435(5) .
O20 C74 1.252(6) .
F61 C111 1.324(5) .
N3 O14 1.291(4) .
N3 C46 1.358(5) .
N3 C47 1.498(5) .
F2 C1 1.323(5) .
F49 C101 1.324(5) .
O13 C44 1.256(5) .
F10 C10 1.335(5) .
F56 C106 1.327(5) .
F54 C105 1.336(5) .
F7 C6 1.332(5) .
N7 O32 1.304(4) .
N7 C116 1.332(5) .
N7 C117 1.509(5) .
F6 C5 1.330(5) .
F43 C76 1.316(5) .
F8 C6 1.335(5) .
O26 C102 1.250(5) .
O19 C72 1.254(5) .
O5 N1 1.283(4) .
O24 C91 1.364(5) .
O24 C94 1.443(5) .
F51 C101 1.342(5) .
F50 C101 1.333(5) .
F12 C10 1.333(5) .
N8 O33 1.282(4) .
N8 C116 1.371(5) .
N8 C120 1.501(5) .
O8 C32 1.253(5) .
N2 O7 1.303(4) .
N2 C11 1.329(5) .
N2 C12 1.506(5) .
F9 C6 1.341(5) .
F11 C10 1.314(5) .
O28 C107 1.254(5) .
F14 C31 1.328(6) .
O27 C104 1.258(5) .
N5 O23 1.289(4) .
N5 C81 1.354(5) .
N5 C85 1.512(5) .
O6 C21 1.361(5) .
O6 C24 1.458(5) .
F5 C5 1.327(5) .
N6 O25 1.288(4) .
N6 C81 1.345(5) .
N6 C82 1.509(5) .
F58 C110 1.325(5) .
F57 C106 1.334(5) .
O21 C77 1.250(5) .
C82 C84 1.518(6) .
C82 C83 1.526(6) .
C82 C85 1.545(6) .
F53 C105 1.337(5) .
O22 C79 1.260(5) .
O17 C67 1.256(5) .
O15 C56 1.367(5) .
O15 C59 1.432(5) .
F60 C110 1.327(5) .
F55 C106 1.332(5) .
N4 O16 1.298(4) .
N4 C46 1.355(5) .
N4 C50 1.490(5) .
F52 C105 1.329(5) .
F4 C5 1.324(5) .
O11 C39 1.249(5) .
C20 C19 1.391(5) .
C20 C21 1.399(6) .
C20 H20 0.9500 .
O33 Cu1 2.558(3) 1_654
F17 C35 1.331(6) .
F3 C1 1.333(5) .
C11 N1 1.369(5) .
C11 C18 1.456(6) .
F45 C76 1.328(5) .
F59 C110 1.334(5) .
C37 C38 1.392(7) .
C37 C36 1.532(6) .
F32 C66 1.342(6) .
F19 C36 1.331(6) .
F1 C1 1.341(5) .
F20 C36 1.340(6) .
F65 C115 1.319(5) .
F21 C36 1.330(5) .
C9 C8 1.391(6) .
C9 C10 1.540(6) .
C2 C3 1.390(6) .
C2 C1 1.534(6) .
F15 C31 1.316(6) .
O12 C42 1.257(5) .
O18 C69 1.259(5) .
C18 C19 1.382(5) .
C18 C23 1.411(5) .
F25 C41 1.329(5) .
N1 C16 1.496(5) .
F46 C80 1.320(6) .
C23 C22 1.368(6) .
C23 H23 0.9500 .
F18 C35 1.339(5) .
C81 C88 1.459(6) .
F30 C45 1.324(5) .
C85 C87 1.524(5) .
C85 C86 1.528(6) .
C12 C14 1.523(6) .
C12 C13 1.524(6) .
C12 C16 1.551(6) .
C21 C22 1.400(6) .
F26 C41 1.324(5) .
F44 C76 1.341(5) .
F63 C111 1.321(5) .
F62 C111 1.345(5) .
C126 C125 1.397(5) .
C126 C127 1.391(5) .
C127 C128 1.386(5) .
C127 H127 0.9500 .
C112 C113 1.404(6) .
C112 C111 1.529(6) .
C53 C58 1.395(6) .
C53 C54 1.399(5) .
C53 C46 1.443(6) .
F24 C40 1.329(6) .
C5 C4 1.541(6) .
C108 C109 1.388(6) .
C108 C107 1.385(6) .
C108 H108 0.9500 .
F37 C71 1.302(6) .
C49 C47 1.516(6) .
C49 H49A 0.9800 .
C49 H49B 0.9800 .
C49 H49C 0.9800 .
C117 C118 1.511(6) .
C117 C119 1.526(6) .
C117 C120 1.565(5) .
C4 C3 1.395(6) .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C103 C102 1.393(6) .
C103 C104 1.392(6) .
C103 H103 0.9500 .
C101 C102 1.539(6) .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
F29 C45 1.329(5) .
C57 C58 1.380(6) .
C57 C56 1.399(5) .
C57 H57 0.9500 .
C22 H22 0.9500 .
C56 C55 1.386(6) .
C19 H19 0.9500 .
F27 C41 1.317(6) .
C106 C107 1.534(6) .
C114 C113 1.394(6) .
C114 C115 1.531(6) .
C16 C15 1.523(6) .
C16 C17 1.535(5) .
C47 C48 1.530(7) .
C47 C50 1.544(6) .
C7 C8 1.387(6) .
C7 C6 1.525(6) .
F40 C75 1.325(8) .
C77 C78 1.387(6) .
C77 C76 1.541(6) .
C43 C42 1.393(6) .
C43 C44 1.392(6) .
C43 H43 0.9500 .
F28 C45 1.317(6) .
C118 H11A 0.9800 .
C118 H11B 0.9800 .
C118 H11C 0.9800 .
C8 H8 0.9500 .
C55 C54 1.385(6) .
C55 H55 0.9500 .
C93 C92 1.390(6) .
C93 C88 1.405(5) .
C93 H93 0.9500 .
C116 C123 1.453(5) .
C105 C104 1.533(6) .
C123 C128 1.404(5) .
C50 C51 1.524(7) .
C50 C52 1.529(6) .
C113 H113 0.9500 .
C3 H3 0.9500 .
C88 C89 1.398(6) .
C119 H11D 0.9800 .
C119 H11E 0.9800 .
C119 H11F 0.9800 .
C131 C132 1.385(6) .
C131 C130 1.391(6) .
C131 H131 0.9500 .
F34 C70 1.313(6) .
F33 C66 1.325(6) .
C98 C97 1.366(6) .
C98 C99 1.385(6) .
C98 H98 0.9500 .
C44 C45 1.533(6) .
C125 H125 0.9500 .
C134 C133 1.364(7) .
C134 C135 1.365(6) .
C134 H134 0.9500 .
F31 C66 1.312(6) .
C17 H17A 0.9800 .
C17 H17B 0.9800 .
C17 H17C 0.9800 .
C128 H128 0.9500 .
C96 C95 1.379(6) .
C96 C97 1.387(7) .
C96 H96 0.9500 .
F48 C80 1.319(6) .
C75 F42 1.307(7) .
C75 F41 1.329(7) .
C75 C74 1.533(7) .
C69 C68 1.386(6) .
C69 C70 1.528(7) .
C120 C121 1.523(5) .
C120 C122 1.524(6) .
C109 C110 1.536(6) .
F16 C35 1.320(5) .
C84 H84A 0.9800 .
C84 H84B 0.9800 .
C84 H84C 0.9800 .
C133 C132 1.388(7) .
C133 H133 0.9500 .
C130 C135 1.386(6) .
C130 C129 1.499(5) .
C91 C92 1.383(6) .
C91 C90 1.406(5) .
C42 C41 1.541(6) .
C100 C99 1.385(6) .
C100 C95 1.385(6) .
C100 H100 0.9500 .
C132 H132 0.9500 .
C74 C73 1.389(7) .
C38 C39 1.391(7) .
C38 H38 0.9500 .
F13 C31 1.331(6) .
C80 F47 1.334(6) .
C80 C79 1.530(7) .
C90 C89 1.383(6) .
C90 H90 0.9500 .
C34 C33 1.386(6) .
C34 C35 1.536(6) .
C60 C65 1.390(6) .
C60 C61 1.395(6) .
C60 C59 1.517(6) .
C94 C95 1.510(6) .
C94 H94A 0.9900 .
C94 H94B 0.9900 .
C92 H92 0.9500 .
C58 H58 0.9500 .
C89 H89 0.9500 .
C52 H52A 0.9800 .
C52 H52B 0.9800 .
C52 H52C 0.9800 .
C97 H97 0.9500 .
C72 C73 1.399(7) .
C72 C71 1.527(7) .
C30 C29 1.381(6) .
C30 C25 1.389(7) .
C30 H30 0.9500 .
C54 H54 0.9500 .
C29 C28 1.386(8) .
C29 H29 0.9500 .
C63 C64 1.381(8) .
C63 C62 1.383(7) .
C63 H63 0.9500 .
C135 H135 0.9500 .
F35 C70 1.284(6) .
F36 C70 1.312(6) .
F38 C71 1.328(7) .
C61 C62 1.378(7) .
C61 H61 0.9500 .
C65 C64 1.381(8) .
C65 H65 0.9500 .
C78 C79 1.384(6) .
C78 H78 0.9500 .
C26 C25 1.385(6) .
C26 C27 1.388(7) .
C26 H26 0.9500 .
C33 C32 1.391(6) .
C33 H33 0.9500 .
C31 C32 1.546(6) .
C83 H83A 0.9800 .
C83 H83B 0.9800 .
C83 H83C 0.9800 .
C99 H99 0.9500 .
C28 C27 1.372(8) .
C28 H28 0.9500 .
C66 C67 1.541(7) .
C40 F22 1.253(6) .
C40 F23 1.327(7) .
C40 C39 1.547(7) .
C59 H59A 0.9900 .
C59 H59B 0.9900 .
C129 H12A 0.9900 .
C129 H12B 0.9900 .
C67 C68 1.389(7) .
C71 F39 1.306(6) .
F66 C115 1.310(7) .
C25 C24 1.500(6) .
C24 H24A 0.9900 .
C24 H24B 0.9900 .
C87 H87A 0.9800 .
C87 H87B 0.9800 .
C87 H87C 0.9800 .
C73 H73 0.9500 .
F64 C115 1.325(6) .
C51 H51A 0.9800 .
C51 H51B 0.9800 .
C51 H51C 0.9800 .
C121 H12C 0.9800 .
C121 H12D 0.9800 .
C121 H12E 0.9800 .
C122 H12F 0.9800 .
C122 H12G 0.9800 .
C122 H12H 0.9800 .
C86 H86A 0.9800 .
C86 H86B 0.9800 .
C86 H86C 0.9800 .
C27 H27 0.9500 .
C64 H64 0.9500 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C62 H62 0.9500 .
C68 H68 0.9500 .
C48 H48A 0.9800 .
C48 H48B 0.9800 .
C48 H48C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 Cu1 O2 C4 -4.9(3) . .
O3 Cu1 O2 C4 159.6(3) . .
O4 Cu1 O2 C4 -100.1(6) . .
O5 Cu1 O2 C4 -98.6(3) . .
O33 Cu1 O2 C4 71.8(3) 1_456 .
O27 Eu3 O30 C112 -15.1(4) . .
O32 Eu3 O30 C112 -74.4(3) . .
O29 Eu3 O30 C112 173.8(3) . .
O31 Eu3 O30 C112 6.6(3) . .
O28 Eu3 O30 C112 -128.2(3) . .
O26 Eu3 O30 C112 122.9(3) . .
O25 Eu3 O30 C112 83.5(3) . .
O1 Cu1 O3 C7 -95.0(5) . .
O2 Cu1 O3 C7 164.4(3) . .
O4 Cu1 O3 C7 -2.3(3) . .
O5 Cu1 O3 C7 77.7(3) . .
O33 Cu1 O3 C7 -109.9(3) 1_456 .
O13 Eu1 O10 C37 -177.4(3) . .
O9 Eu1 O10 C37 -8.6(4) . .
O7 Eu1 O10 C37 88.9(3) . .
O11 Eu1 O10 C37 15.7(3) . .
O8 Eu1 O10 C37 139.7(3) . .
O12 Eu1 O10 C37 -116.2(3) . .
O14 Eu1 O10 C37 -67.1(3) . .
O1 Cu1 O4 C9 172.4(3) . .
O3 Cu1 O4 C9 8.2(3) . .
O2 Cu1 O4 C9 -91.7(5) . .
O5 Cu1 O4 C9 -93.2(3) . .
O33 Cu1 O4 C9 96.8(3) 1_456 .
O3 Cu1 O1 C2 -89.8(5) . .
O2 Cu1 O1 C2 10.2(3) . .
O4 Cu1 O1 C2 176.7(3) . .
O5 Cu1 O1 C2 97.3(3) . .
O33 Cu1 O1 C2 -74.6(3) 1_456 .
O27 Eu3 O31 C114 159.4(3) . .
O32 Eu3 O31 C114 67.4(3) . .
O30 Eu3 O31 C114 -7.4(3) . .
O29 Eu3 O31 C114 -32.3(4) . .
O28 Eu3 O31 C114 117.0(3) . .
O26 Eu3 O31 C114 -143.4(3) . .
O25 Eu3 O31 C114 -83.6(3) . .
O13 Eu1 O9 C34 -17.3(4) . .
O7 Eu1 O9 C34 89.0(4) . .
O11 Eu1 O9 C34 154.7(4) . .
O8 Eu1 O9 C34 19.8(3) . .
O10 Eu1 O9 C34 178.7(3) . .
O12 Eu1 O9 C34 -59.7(3) . .
O14 Eu1 O9 C34 -129.4(3) . .
O27 Eu3 O29 C109 -18.6(4) . .
O32 Eu3 O29 C109 86.7(3) . .
O30 Eu3 O29 C109 153.7(3) . .
O31 Eu3 O29 C109 177.9(3) . .
O28 Eu3 O29 C109 19.8(3) . .
O26 Eu3 O29 C109 -59.1(3) . .
O25 Eu3 O29 C109 -133.8(3) . .
O21 Eu2 O20 C74 172.2(4) . .
O18 Eu2 O20 C74 -18.0(5) . .
O16 Eu2 O20 C74 78.5(4) . .
O17 Eu2 O20 C74 125.2(4) . .
O23 Eu2 O20 C74 -75.5(4) . .
O22 Eu2 O20 C74 -133.2(4) . .
O19 Eu2 O20 C74 1.1(4) . .
O9 Eu1 O13 C44 -16.4(4) . .
O7 Eu1 O13 C44 -127.4(3) . .
O11 Eu1 O13 C44 178.3(3) . .
O8 Eu1 O13 C44 -53.4(3) . .
O10 Eu1 O13 C44 154.4(3) . .
O12 Eu1 O13 C44 26.4(3) . .
O14 Eu1 O13 C44 91.5(3) . .
O27 Eu3 O26 C102 -16.4(3) . .
O32 Eu3 O26 C102 39.5(4) . .
O30 Eu3 O26 C102 -171.8(3) . .
O29 Eu3 O26 C102 136.0(3) . .
O31 Eu3 O26 C102 -73.9(3) . .
O28 Eu3 O26 C102 60.7(3) . .
O25 Eu3 O26 C102 -132.9(4) . .
O21 Eu2 O19 C72 -17.4(5) . .
O18 Eu2 O19 C72 166.4(4) . .
O16 Eu2 O19 C72 -83.9(4) . .
O20 Eu2 O19 C72 -3.1(4) . .
O17 Eu2 O19 C72 -137.5(4) . .
O23 Eu2 O19 C72 74.7(4) . .
O22 Eu2 O19 C72 114.9(4) . .
O1 Cu1 O5 N1 -110.0(3) . .
O3 Cu1 O5 N1 72.0(3) . .
O2 Cu1 O5 N1 -16.7(3) . .
O4 Cu1 O5 N1 162.9(3) . .
O33 Cu1 O5 N1 -69.2(6) 1_456 .
O13 Eu1 O8 C32 133.6(4) . .
O9 Eu1 O8 C32 -20.4(4) . .
O7 Eu1 O8 C32 -130.3(4) . .
O11 Eu1 O8 C32 -77.2(4) . .
O10 Eu1 O8 C32 177.9(3) . .
O12 Eu1 O8 C32 57.3(4) . .
O14 Eu1 O8 C32 46.0(4) . .
C46 N3 O14 Eu1 86.8(5) . .
C47 N3 O14 Eu1 -103.9(4) . .
O13 Eu1 O14 N3 -93.0(4) . .
O9 Eu1 O14 N3 45.7(4) . .
O7 Eu1 O14 N3 159.4(3) . .
O11 Eu1 O14 N3 120.2(4) . .
O8 Eu1 O14 N3 -15.2(5) . .
O10 Eu1 O14 N3 -163.3(4) . .
O12 Eu1 O14 N3 -26.7(4) . .
C11 N2 O7 Eu1 81.6(6) . .
C12 N2 O7 Eu1 -110.8(4) . .
O13 Eu1 O7 N2 46.9(4) . .
O9 Eu1 O7 N2 -91.4(4) . .
O11 Eu1 O7 N2 -160.5(4) . .
O8 Eu1 O7 N2 -24.3(4) . .
O10 Eu1 O7 N2 124.0(4) . .
O12 Eu1 O7 N2 -9.8(5) . .
O14 Eu1 O7 N2 158.8(4) . .
O27 Eu3 O28 C107 130.0(4) . .
O32 Eu3 O28 C107 -137.5(4) . .
O30 Eu3 O28 C107 -84.6(4) . .
O29 Eu3 O28 C107 -23.8(3) . .
O31 Eu3 O28 C107 172.2(3) . .
O26 Eu3 O28 C107 54.3(3) . .
O25 Eu3 O28 C107 30.0(4) . .
O32 Eu3 O27 C104 -137.2(3) . .
O30 Eu3 O27 C104 167.9(3) . .
O29 Eu3 O27 C104 -24.9(4) . .
O31 Eu3 O27 C104 146.3(3) . .
O28 Eu3 O27 C104 -63.1(3) . .
O26 Eu3 O27 C104 16.0(3) . .
O25 Eu3 O27 C104 81.9(3) . .
O18 Eu2 O21 C77 -27.1(4) . .
O16 Eu2 O21 C77 -139.6(4) . .
O20 Eu2 O21 C77 144.3(4) . .
O17 Eu2 O21 C77 -67.2(4) . .
O23 Eu2 O21 C77 77.5(4) . .
O22 Eu2 O21 C77 10.8(3) . .
O19 Eu2 O21 C77 158.5(3) . .
O25 N6 C82 C84 40.2(5) . .
C81 N6 C82 C84 -147.7(4) . .
O25 N6 C82 C83 -80.2(4) . .
C81 N6 C82 C83 91.9(4) . .
O25 N6 C82 C85 161.5(3) . .
C81 N6 C82 C85 -26.4(4) . .
O21 Eu2 O22 C79 -14.2(3) . .
O18 Eu2 O22 C79 141.4(4) . .
O16 Eu2 O22 C79 46.5(4) . .
O20 Eu2 O22 C79 -69.1(4) . .
O17 Eu2 O22 C79 66.0(4) . .
O23 Eu2 O22 C79 -126.8(4) . .
O19 Eu2 O22 C79 -166.7(3) . .
C81 N5 O23 Eu2 78.2(5) . .
C85 N5 O23 Eu2 -112.4(4) . .
O21 Eu2 O23 N5 -84.0(4) . .
O18 Eu2 O23 N5 57.1(4) . .
O16 Eu2 O23 N5 167.5(3) . .
O20 Eu2 O23 N5 -150.2(4) . .
O17 Eu2 O23 N5 3.9(5) . .
O22 Eu2 O23 N5 -18.5(4) . .
O19 Eu2 O23 N5 134.0(4) . .
O21 Eu2 O17 C67 128.3(4) . .
O18 Eu2 O17 C67 -25.7(4) . .
O16 Eu2 O17 C67 -137.8(4) . .
O20 Eu2 O17 C67 174.3(4) . .
O23 Eu2 O17 C67 31.3(5) . .
O22 Eu2 O17 C67 53.6(4) . .
O19 Eu2 O17 C67 -83.7(4) . .
O13 Eu1 O11 C39 -31.5(4) . .
O9 Eu1 O11 C39 158.9(4) . .
O7 Eu1 O11 C39 -90.8(3) . .
O8 Eu1 O11 C39 -145.6(3) . .
O10 Eu1 O11 C39 -7.1(3) . .
O12 Eu1 O11 C39 109.5(3) . .
O14 Eu1 O11 C39 63.0(3) . .
C116 N7 O32 Eu3 72.6(5) . .
C117 N7 O32 Eu3 -117.7(3) . .
O27 Eu3 O32 N7 66.6(3) . .
O30 Eu3 O32 N7 -144.1(3) . .
O29 Eu3 O32 N7 -72.4(3) . .
O31 Eu3 O32 N7 139.6(3) . .
O28 Eu3 O32 N7 -6.9(3) . .
O26 Eu3 O32 N7 14.4(4) . .
O25 Eu3 O32 N7 -176.6(3) . .
C116 N8 O33 Cu1 69.4(5) . 1_654
C120 N8 O33 Cu1 -118.4(3) . 1_654
O7 N2 C11 N1 178.0(3) . .
C12 N2 C11 N1 9.7(4) . .
O7 N2 C11 C18 -3.8(7) . .
C12 N2 C11 C18 -172.1(4) . .
C81 N6 O25 Eu3 78.0(5) . .
C82 N6 O25 Eu3 -111.0(4) . .
O27 Eu3 O25 N6 -86.2(4) . .
O32 Eu3 O25 N6 164.5(3) . .
O30 Eu3 O25 N6 132.1(4) . .
O29 Eu3 O25 N6 53.0(4) . .
O31 Eu3 O25 N6 -150.7(4) . .
O28 Eu3 O25 N6 2.8(5) . .
O26 Eu3 O25 N6 -21.7(4) . .
Eu1 O10 C37 C38 -18.9(6) . .
Eu1 O10 C37 C36 158.1(3) . .
C46 N4 O16 Eu2 81.7(5) . .
C50 N4 O16 Eu2 -107.6(4) . .
O21 Eu2 O16 N4 69.0(4) . .
O18 Eu2 O16 N4 -72.7(4) . .
O20 Eu2 O16 N4 141.3(4) . .
O17 Eu2 O16 N4 -6.8(4) . .
O23 Eu2 O16 N4 -177.2(3) . .
O22 Eu2 O16 N4 13.0(5) . .
O19 Eu2 O16 N4 -144.1(4) . .
Cu1 O4 C9 C8 -9.2(6) . .
Cu1 O4 C9 C10 168.8(3) . .
Cu1 O1 C2 C3 -10.7(6) . .
Cu1 O1 C2 C1 167.6(3) . .
O13 Eu1 O12 C42 -20.2(3) . .
O9 Eu1 O12 C42 130.6(4) . .
O7 Eu1 O12 C42 40.8(4) . .
O11 Eu1 O12 C42 -179.6(3) . .
O8 Eu1 O12 C42 55.3(3) . .
O10 Eu1 O12 C42 -83.8(4) . .
O14 Eu1 O12 C42 -131.3(4) . .
O21 Eu2 O18 C69 -20.2(4) . .
O16 Eu2 O18 C69 87.0(4) . .
O20 Eu2 O18 C69 175.0(3) . .
O17 Eu2 O18 C69 20.8(4) . .
O23 Eu2 O18 C69 -131.0(4) . .
O22 Eu2 O18 C69 -57.3(4) . .
O19 Eu2 O18 C69 156.4(4) . .
N2 C11 C18 C19 -141.2(4) . .
N1 C11 C18 C19 36.7(6) . .
N2 C11 C18 C23 36.7(6) . .
N1 C11 C18 C23 -145.4(4) . .
Cu1 O5 N1 C11 83.3(4) . .
Cu1 O5 N1 C16 -106.3(4) . .
N2 C11 N1 O5 -178.2(3) . .
C18 C11 N1 O5 3.6(6) . .
N2 C11 N1 C16 10.6(4) . .
C18 C11 N1 C16 -167.6(4) . .
C19 C18 C23 C22 -1.0(6) . .
C11 C18 C23 C22 -178.9(4) . .
O25 N6 C81 N5 -177.0(3) . .
C82 N6 C81 N5 11.3(4) . .
O25 N6 C81 C88 1.2(6) . .
C82 N6 C81 C88 -170.5(4) . .
O23 N5 C81 N6 -179.7(3) . .
C85 N5 C81 N6 10.0(4) . .
O23 N5 C81 C88 2.0(6) . .
C85 N5 C81 C88 -168.2(4) . .
O23 N5 C85 C87 41.5(5) . .
C81 N5 C85 C87 -147.7(4) . .
O23 N5 C85 C86 -78.1(4) . .
C81 N5 C85 C86 92.7(4) . .
O23 N5 C85 C82 163.5(3) . .
C81 N5 C85 C82 -25.7(4) . .
N6 C82 C85 N5 28.3(3) . .
C84 C82 C85 N5 146.1(3) . .
C83 C82 C85 N5 -83.7(4) . .
N6 C82 C85 C87 146.6(4) . .
C84 C82 C85 C87 -95.6(4) . .
C83 C82 C85 C87 34.6(5) . .
N6 C82 C85 C86 -83.6(4) . .
C84 C82 C85 C86 34.2(5) . .
C83 C82 C85 C86 164.4(4) . .
O7 N2 C12 C14 -74.7(4) . .
C11 N2 C12 C14 94.5(4) . .
O7 N2 C12 C13 45.0(5) . .
C11 N2 C12 C13 -145.8(4) . .
O7 N2 C12 C16 166.5(3) . .
C11 N2 C12 C16 -24.3(4) . .
C24 O6 C21 C20 7.3(6) . .
C24 O6 C21 C22 -172.8(4) . .
C19 C20 C21 O6 -179.6(4) . .
C19 C20 C21 C22 0.4(6) . .
C129 O34 C126 C125 -172.5(3) . .
C129 O34 C126 C127 6.0(6) . .
O34 C126 C127 C128 179.6(4) . .
C125 C126 C127 C128 -2.0(6) . .
Eu3 O30 C112 C113 -4.2(6) . .
Eu3 O30 C112 C111 175.2(2) . .
O16 N4 C46 N3 178.3(4) . .
C50 N4 C46 N3 7.1(5) . .
O16 N4 C46 C53 -1.5(7) . .
C50 N4 C46 C53 -172.7(4) . .
O14 N3 C46 N4 -179.8(3) . .
C47 N3 C46 N4 10.1(5) . .
O14 N3 C46 C53 0.0(6) . .
C47 N3 C46 C53 -170.1(4) . .
C58 C53 C46 N4 29.4(6) . .
C54 C53 C46 N4 -151.4(4) . .
C58 C53 C46 N3 -150.3(4) . .
C54 C53 C46 N3 28.9(6) . .
O32 N7 C117 C118 41.7(5) . .
C116 N7 C117 C118 -147.3(4) . .
O32 N7 C117 C119 -78.3(4) . .
C116 N7 C117 C119 92.7(4) . .
O32 N7 C117 C120 163.5(3) . .
C116 N7 C117 C120 -25.5(4) . .
Cu1 O2 C4 C3 -1.0(6) . .
Cu1 O2 C4 C5 178.7(3) . .
F5 C5 C4 O2 62.4(5) . .
F4 C5 C4 O2 -175.3(4) . .
F6 C5 C4 O2 -55.8(5) . .
F5 C5 C4 C3 -117.9(4) . .
F4 C5 C4 C3 4.4(6) . .
F6 C5 C4 C3 123.9(4) . .
C18 C23 C22 C21 2.5(6) . .
O6 C21 C22 C23 177.8(4) . .
C20 C21 C22 C23 -2.2(6) . .
C59 O15 C56 C55 177.5(4) . .
C59 O15 C56 C57 -2.5(6) . .
C58 C57 C56 O15 -179.5(4) . .
C58 C57 C56 C55 0.5(6) . .
C23 C18 C19 C20 -0.7(6) . .
C11 C18 C19 C20 177.1(4) . .
C21 C20 C19 C18 1.0(6) . .
O10 C37 C36 F21 -76.4(5) . .
C38 C37 C36 F21 101.0(5) . .
O10 C37 C36 F19 42.7(5) . .
C38 C37 C36 F19 -140.0(4) . .
O10 C37 C36 F20 163.4(4) . .
C38 C37 C36 F20 -19.2(6) . .
Eu3 O31 C114 C113 6.0(6) . .
Eu3 O31 C114 C115 -172.6(3) . .
O5 N1 C16 C15 -76.9(4) . .
C11 N1 C16 C15 94.7(4) . .
O5 N1 C16 C17 42.8(5) . .
C11 N1 C16 C17 -145.6(4) . .
O5 N1 C16 C12 163.6(3) . .
C11 N1 C16 C12 -24.8(4) . .
N2 C12 C16 N1 26.8(4) . .
C14 C12 C16 N1 -85.6(4) . .
C13 C12 C16 N1 144.6(3) . .
N2 C12 C16 C15 -86.2(4) . .
C14 C12 C16 C15 161.4(4) . .
C13 C12 C16 C15 31.6(5) . .
N2 C12 C16 C17 143.7(4) . .
C14 C12 C16 C17 31.2(5) . .
C13 C12 C16 C17 -98.5(4) . .
O14 N3 C47 C49 45.9(5) . .
C46 N3 C47 C49 -143.5(4) . .
O14 N3 C47 C48 -73.1(5) . .
C46 N3 C47 C48 97.5(4) . .
O14 N3 C47 C50 167.7(3) . .
C46 N3 C47 C50 -21.7(5) . .
Cu1 O3 C7 C8 -3.8(6) . .
Cu1 O3 C7 C6 178.3(3) . .
Eu2 O21 C77 C78 -5.8(6) . .
Eu2 O21 C77 C76 173.4(2) . .
O4 C9 C8 C7 1.7(7) . .
C10 C9 C8 C7 -176.2(4) . .
O3 C7 C8 C9 5.6(7) . .
C6 C7 C8 C9 -176.5(4) . .
O15 C56 C55 C54 179.3(4) . .
C57 C56 C55 C54 -0.7(6) . .
Eu3 O28 C107 C108 20.2(6) . .
Eu3 O28 C107 C106 -160.9(3) . .
C109 C108 C107 O28 1.5(7) . .
C109 C108 C107 C106 -177.5(4) . .
F56 C106 C107 O28 29.6(5) . .
F57 C106 C107 O28 150.4(4) . .
F55 C106 C107 O28 -89.3(4) . .
F56 C106 C107 C108 -151.3(4) . .
F57 C106 C107 C108 -30.5(5) . .
F55 C106 C107 C108 89.8(5) . .
O32 N7 C116 N8 -177.8(3) . .
C117 N7 C116 N8 11.9(4) . .
O32 N7 C116 C123 4.8(6) . .
C117 N7 C116 C123 -165.6(4) . .
O33 N8 C116 N7 -178.7(3) . .
C120 N8 C116 N7 8.5(4) . .
O33 N8 C116 C123 -1.2(6) . .
C120 N8 C116 C123 -174.1(4) . .
C125 C124 C123 C128 -2.1(6) . .
C125 C124 C123 C116 177.2(4) . .
N7 C116 C123 C124 -147.6(4) . .
N8 C116 C123 C124 35.4(6) . .
N7 C116 C123 C128 31.7(6) . .
N8 C116 C123 C128 -145.2(4) . .
O16 N4 C50 C51 -72.8(4) . .
C46 N4 C50 C51 98.9(4) . .
O16 N4 C50 C52 47.8(6) . .
C46 N4 C50 C52 -140.5(4) . .
O16 N4 C50 C47 168.3(3) . .
C46 N4 C50 C47 -20.0(5) . .
N3 C47 C50 N4 22.6(4) . .
C49 C47 C50 N4 140.4(4) . .
C48 C47 C50 N4 -90.1(4) . .
N3 C47 C50 C51 -90.2(4) . .
C49 C47 C50 C51 27.6(5) . .
C48 C47 C50 C51 157.2(4) . .
N3 C47 C50 C52 140.0(4) . .
C49 C47 C50 C52 -102.3(5) . .
C48 C47 C50 C52 27.3(6) . .
O31 C114 C113 C112 0.8(7) . .
C115 C114 C113 C112 179.3(4) . .
O30 C112 C113 C114 -1.7(6) . .
C111 C112 C113 C114 179.0(4) . .
O1 C2 C3 C4 2.5(7) . .
C1 C2 C3 C4 -175.6(4) . .
O2 C4 C3 C2 4.0(7) . .
C5 C4 C3 C2 -175.6(4) . .
C92 C93 C88 C89 -0.9(6) . .
C92 C93 C88 C81 179.7(3) . .
N6 C81 C88 C89 -149.0(4) . .
N5 C81 C88 C89 28.9(6) . .
N6 C81 C88 C93 30.5(6) . .
N5 C81 C88 C93 -151.6(4) . .
O30 C112 C111 F61 176.3(3) . .
C113 C112 C111 F61 -4.3(5) . .
O30 C112 C111 F63 53.7(5) . .
C113 C112 C111 F63 -126.9(4) . .
O30 C112 C111 F62 -64.0(4) . .
C113 C112 C111 F62 115.4(4) . .
Eu1 O13 C44 C43 -25.8(7) . .
Eu1 O13 C44 C45 155.6(3) . .
C42 C43 C44 O13 3.6(7) . .
C42 C43 C44 C45 -177.8(4) . .
C123 C124 C125 C126 1.3(6) . .
O34 C126 C125 C124 179.3(4) . .
C127 C126 C125 C124 0.8(6) . .
O13 C44 C45 F28 61.0(5) . .
C43 C44 C45 F28 -117.8(5) . .
O13 C44 C45 F30 -57.0(6) . .
C43 C44 C45 F30 124.2(5) . .
O13 C44 C45 F29 -177.1(4) . .
C43 C44 C45 F29 4.2(6) . .
Eu3 O26 C102 C103 14.2(6) . .
Eu3 O26 C102 C101 -163.9(2) . .
C104 C103 C102 O26 -1.4(7) . .
C104 C103 C102 C101 176.6(4) . .
F49 C101 C102 O26 -34.9(5) . .
F50 C101 C102 O26 -156.4(3) . .
F51 C101 C102 O26 84.2(4) . .
F49 C101 C102 C103 146.9(4) . .
F50 C101 C102 C103 25.3(5) . .
F51 C101 C102 C103 -94.0(4) . .
C126 C127 C128 C123 1.1(6) . .
C124 C123 C128 C127 0.9(6) . .
C116 C123 C128 C127 -178.4(4) . .
Eu3 O27 C104 C103 -13.2(6) . .
Eu3 O27 C104 C105 165.3(2) . .
C102 C103 C104 O27 0.6(6) . .
C102 C103 C104 C105 -177.8(4) . .
F52 C105 C104 O27 161.5(4) . .
F54 C105 C104 O27 -78.1(4) . .
F53 C105 C104 O27 40.7(5) . .
F52 C105 C104 C103 -19.8(5) . .
F54 C105 C104 C103 100.5(4) . .
F53 C105 C104 C103 -140.7(4) . .
Eu2 O18 C69 C68 -13.2(7) . .
Eu2 O18 C69 C70 166.4(3) . .
O33 N8 C120 C121 42.9(5) . .
C116 N8 C120 C121 -144.1(3) . .
O33 N8 C120 C122 -78.0(4) . .
C116 N8 C120 C122 95.1(4) . .
O33 N8 C120 C117 163.5(3) . .
C116 N8 C120 C117 -23.5(4) . .
N7 C117 C120 N8 26.5(3) . .
C118 C117 C120 N8 144.4(3) . .
C119 C117 C120 N8 -84.9(4) . .
N7 C117 C120 C121 143.6(4) . .
C118 C117 C120 C121 -98.5(4) . .
C119 C117 C120 C121 32.2(5) . .
N7 C117 C120 C122 -87.2(4) . .
C118 C117 C120 C122 30.7(5) . .
C119 C117 C120 C122 161.5(3) . .
Eu3 O29 C109 C108 -11.5(6) . .
Eu3 O29 C109 C110 165.3(3) . .
C107 C108 C109 O29 -6.1(7) . .
C107 C108 C109 C110 177.2(4) . .
C135 C134 C133 C132 -0.2(7) . .
C132 C131 C130 C135 1.1(6) . .
C132 C131 C130 C129 -174.0(4) . .
C94 O24 C91 C92 7.2(5) . .
C94 O24 C91 C90 -172.4(3) . .
O21 C77 C76 F43 -69.0(5) . .
C78 C77 C76 F43 110.2(4) . .
O21 C77 C76 F45 50.0(5) . .
C78 C77 C76 F45 -130.7(4) . .
O21 C77 C76 F44 170.4(4) . .
C78 C77 C76 F44 -10.3(5) . .
Eu1 O12 C42 C43 12.1(7) . .
Eu1 O12 C42 C41 -164.8(3) . .
C44 C43 C42 O12 3.2(7) . .
C44 C43 C42 C41 179.9(4) . .
C130 C131 C132 C133 -0.9(7) . .
C134 C133 C132 C131 0.5(7) . .
Eu2 O20 C74 C73 0.1(8) . .
Eu2 O20 C74 C75 -178.4(4) . .
F42 C75 C74 O20 -175.6(5) . .
F40 C75 C74 O20 62.7(7) . .
F41 C75 C74 O20 -53.6(7) . .
F42 C75 C74 C73 5.8(9) . .
F40 C75 C74 C73 -116.0(6) . .
F41 C75 C74 C73 127.8(6) . .
O10 C37 C38 C39 5.8(7) . .
C36 C37 C38 C39 -171.1(4) . .
O24 C91 C90 C89 179.7(3) . .
C92 C91 C90 C89 0.1(6) . .
Eu1 O9 C34 C33 -14.7(7) . .
Eu1 O9 C34 C35 166.1(3) . .
C91 O24 C94 C95 -179.0(3) . .
O3 C7 C6 F8 85.7(4) . .
C8 C7 C6 F8 -92.4(4) . .
O3 C7 C6 F7 -34.2(5) . .
C8 C7 C6 F7 147.6(4) . .
O3 C7 C6 F9 -154.9(4) . .
C8 C7 C6 F9 27.0(6) . .
O24 C91 C92 C93 179.5(4) . .
C90 C91 C92 C93 -1.0(6) . .
C88 C93 C92 C91 1.4(6) . .
O29 C109 C110 F58 30.9(5) . .
C108 C109 C110 F58 -151.9(4) . .
O29 C109 C110 F60 -88.3(5) . .
C108 C109 C110 F60 88.9(5) . .
O29 C109 C110 F59 151.4(4) . .
C108 C109 C110 F59 -31.4(6) . .
O4 C9 C10 F11 35.5(5) . .
C8 C9 C10 F11 -146.3(4) . .
O4 C9 C10 F10 157.8(4) . .
C8 C9 C10 F10 -24.0(5) . .
O4 C9 C10 F12 -84.4(4) . .
C8 C9 C10 F12 93.8(4) . .
C56 C57 C58 C53 0.2(6) . .
C54 C53 C58 C57 -0.5(6) . .
C46 C53 C58 C57 178.7(4) . .
C91 C90 C89 C88 0.4(6) . .
C93 C88 C89 C90 0.0(6) . .
C81 C88 C89 C90 179.5(3) . .
C99 C98 C97 C96 0.9(7) . .
C95 C96 C97 C98 -0.5(8) . .
Eu2 O19 C72 C73 4.0(8) . .
Eu2 O19 C72 C71 -176.8(3) . .
C56 C55 C54 C53 0.3(6) . .
C58 C53 C54 C55 0.3(6) . .
C46 C53 C54 C55 -178.9(4) . .
C25 C30 C29 C28 0.0(7) . .
C133 C134 C135 C130 0.4(7) . .
C131 C130 C135 C134 -0.8(6) . .
C129 C130 C135 C134 174.2(4) . .
C65 C60 C61 C62 -0.4(7) . .
C59 C60 C61 C62 177.5(4) . .
C61 C60 C65 C64 -0.3(7) . .
C59 C60 C65 C64 -178.1(4) . .
O1 C2 C1 F2 45.6(5) . .
C3 C2 C1 F2 -136.0(4) . .
O1 C2 C1 F3 -72.7(5) . .
C3 C2 C1 F3 105.8(4) . .
O1 C2 C1 F1 167.1(4) . .
C3 C2 C1 F1 -14.5(6) . .
O21 C77 C78 C79 -3.3(7) . .
C76 C77 C78 C79 177.5(4) . .
O18 C69 C70 F35 153.8(5) . .
C68 C69 C70 F35 -26.6(7) . .
O18 C69 C70 F34 29.8(6) . .
C68 C69 C70 F34 -150.6(5) . .
O18 C69 C70 F36 -85.2(6) . .
C68 C69 C70 F36 94.4(5) . .
O9 C34 C33 C32 -2.5(7) . .
C35 C34 C33 C32 176.8(4) . .
C97 C96 C95 C100 -0.5(7) . .
C97 C96 C95 C94 178.7(4) . .
C99 C100 C95 C96 1.0(6) . .
C99 C100 C95 C94 -178.2(4) . .
O24 C94 C95 C96 -89.3(5) . .
O24 C94 C95 C100 89.9(5) . .
O12 C42 C41 F27 84.2(5) . .
C43 C42 C41 F27 -93.0(5) . .
O12 C42 C41 F25 -35.2(5) . .
C43 C42 C41 F25 147.6(4) . .
O12 C42 C41 F26 -155.2(4) . .
C43 C42 C41 F26 27.6(6) . .
C95 C100 C99 C98 -0.7(7) . .
C97 C98 C99 C100 -0.3(7) . .
Eu2 O22 C79 C78 13.4(7) . .
Eu2 O22 C79 C80 -164.5(3) . .
C77 C78 C79 O22 -0.8(7) . .
C77 C78 C79 C80 177.1(4) . .
F48 C80 C79 O22 81.3(6) . .
F46 C80 C79 O22 -40.5(6) . .
F47 C80 C79 O22 -160.2(4) . .
F48 C80 C79 C78 -96.9(5) . .
F46 C80 C79 C78 141.3(4) . .
F47 C80 C79 C78 21.6(6) . .
C30 C29 C28 C27 0.1(7) . .
C56 O15 C59 C60 71.2(5) . .
C65 C60 C59 O15 -143.8(4) . .
C61 C60 C59 O15 38.4(5) . .
C126 O34 C129 C130 -179.1(3) . .
C135 C130 C129 O34 66.3(5) . .
C131 C130 C129 O34 -118.7(4) . .
Eu2 O17 C67 C68 23.9(7) . .
Eu2 O17 C67 C66 -157.9(3) . .
F31 C66 C67 O17 44.2(7) . .
F33 C66 C67 O17 -76.1(5) . .
F32 C66 C67 O17 164.7(4) . .
F31 C66 C67 C68 -137.5(5) . .
F33 C66 C67 C68 102.3(6) . .
F32 C66 C67 C68 -17.0(7) . .
O19 C72 C71 F37 -56.3(6) . .
C73 C72 C71 F37 123.0(5) . .
O19 C72 C71 F39 -179.2(5) . .
C73 C72 C71 F39 0.1(7) . .
O19 C72 C71 F38 61.2(6) . .
C73 C72 C71 F38 -119.6(6) . .
C27 C26 C25 C30 0.9(7) . .
C27 C26 C25 C24 -177.8(4) . .
C29 C30 C25 C26 -0.4(7) . .
C29 C30 C25 C24 178.3(4) . .
O9 C34 C35 F16 175.9(4) . .
C33 C34 C35 F16 -3.5(6) . .
O9 C34 C35 F17 53.2(5) . .
C33 C34 C35 F17 -126.2(4) . .
O9 C34 C35 F18 -64.4(5) . .
C33 C34 C35 F18 116.3(5) . .
C21 O6 C24 C25 176.4(3) . .
C26 C25 C24 O6 -85.3(5) . .
C30 C25 C24 O6 96.0(5) . .
O20 C74 C73 C72 -0.6(9) . .
C75 C74 C73 C72 177.8(5) . .
O19 C72 C73 C74 -1.4(8) . .
C71 C72 C73 C74 179.4(5) . .
Eu1 O8 C32 C33 16.0(7) . .
Eu1 O8 C32 C31 -162.2(3) . .
C34 C33 C32 O8 1.5(7) . .
C34 C33 C32 C31 179.6(4) . .
F15 C31 C32 O8 -28.2(6) . .
F13 C31 C32 O8 92.4(5) . .
F14 C31 C32 O8 -148.9(4) . .
F15 C31 C32 C33 153.5(4) . .
F13 C31 C32 C33 -85.9(6) . .
F14 C31 C32 C33 32.7(6) . .
O31 C114 C115 F66 -54.0(5) . .
C113 C114 C115 F66 127.3(5) . .
O31 C114 C115 F65 -174.6(4) . .
C113 C114 C115 F65 6.7(6) . .
O31 C114 C115 F64 65.6(6) . .
C113 C114 C115 F64 -113.1(5) . .
C29 C28 C27 C26 0.4(7) . .
C25 C26 C27 C28 -0.9(7) . .
C60 C65 C64 C63 -0.3(8) . .
C62 C63 C64 C65 1.6(8) . .
C60 C61 C62 C63 1.6(7) . .
C64 C63 C62 C61 -2.2(8) . .
O18 C69 C68 C67 -3.5(8) . .
C70 C69 C68 C67 177.0(4) . .
O17 C67 C68 C69 -2.3(8) . .
C66 C67 C68 C69 179.6(4) . .
Eu1 O11 C39 C38 0.6(6) . .
Eu1 O11 C39 C40 -179.6(3) . .
C37 C38 C39 O11 3.7(7) . .
C37 C38 C39 C40 -176.0(4) . .
F22 C40 C39 O11 60.0(6) . .
F24 C40 C39 O11 -176.5(4) . .
F23 C40 C39 O11 -61.2(5) . .
F22 C40 C39 C38 -120.2(6) . .
F24 C40 C39 C38 3.3(6) . .
F23 C40 C39 C38 118.6(5) . .
