#------------------------------------------------------------------------------
#$Date: 2019-11-17 09:20:07 +0200 (Sun, 17 Nov 2019) $
#$Revision: 229066 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/02/7230233.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7230233
loop_
_publ_author_name
'An, Yan-Yan'
'Lu, Li-Ping'
'Feng, Si-Si'
'Zhu, Miao-Li'
_publ_section_title
;
 Efficient pure white light emission based on a three-component
 La:Eu,Tb-doped luminescent lanthanide metal--organic framework
;
_journal_issue                   14
_journal_name_full               CrystEngComm
_journal_page_first              2043
_journal_paper_doi               10.1039/C8CE00008E
_journal_volume                  20
_journal_year                    2018
_chemical_formula_moiety         '[Dy2(C16H9O7)2(C3H7ON)2(H2O)(CHOOH)]??3H2O'
_chemical_formula_sum            'C39 H42 Dy2 N2 O22'
_chemical_formula_weight         1215.74
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2018-02-11 deposited with the CCDC.
2018-03-02 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 98.2430(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   28.4551(16)
_cell_length_b                   14.2978(8)
_cell_length_c                   13.6672(8)
_cell_measurement_reflns_used    9782
_cell_measurement_temperature    300(2)
_cell_measurement_theta_max      28.40
_cell_measurement_theta_min      2.89
_cell_volume                     5503.0(5)
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      300(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0260
_diffrn_reflns_av_unetI/netI     0.0233
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.988
_diffrn_reflns_limit_h_max       37
_diffrn_reflns_limit_h_min       -37
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            26432
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.988
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.408
_diffrn_reflns_theta_min         2.841
_exptl_absorpt_coefficient_mu    2.764
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.467
_exptl_crystal_description       block
_exptl_crystal_F_000             2392
_refine_diff_density_max         1.493
_refine_diff_density_min         -1.365
_refine_diff_density_rms         0.143
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.126
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     313
_refine_ls_number_reflns         6846
_refine_ls_number_restraints     48
_refine_ls_restrained_S_all      1.135
_refine_ls_R_factor_all          0.0419
_refine_ls_R_factor_gt           0.0356
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0336P)²+53.8595P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0911
_refine_ls_wR_factor_ref         0.0963
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6014
_reflns_number_total             6846
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c8ce00008e2.cif
_cod_data_source_block           7R-Dy-RT
_cod_depositor_comments
'Adding full bibliography for 7230226--7230238.cif.'
_cod_database_code               7230233
_shelx_shelxl_version_number     2016/6
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.31742(2) 0.20892(2) 0.54025(2) 0.01872(7) Uani 1 1 d . . . . .
O1 O 0.26839(11) 0.3368(2) 0.5530(2) 0.0275(6) Uani 1 1 d . . . . .
O2 O 0.20652(11) 0.4244(2) 0.5646(3) 0.0345(7) Uani 1 1 d . . . . .
O3 O 0.23446(10) 0.6488(2) 0.8540(2) 0.0323(7) Uani 1 1 d . . . . .
O4 O 0.30455(11) 0.7223(2) 0.8824(2) 0.0294(7) Uani 1 1 d . . . . .
O5 O 0.42311(13) 0.6456(3) 0.6497(4) 0.0540(11) Uani 1 1 d . . . . .
O6 O 0.60888(12) 0.8239(2) 0.5219(3) 0.0396(8) Uani 1 1 d . . . . .
O7 O 0.61764(12) 0.6798(3) 0.4734(3) 0.0444(9) Uani 1 1 d . . . . .
C1 C 0.28189(14) 0.4799(3) 0.6409(3) 0.0243(8) Uani 1 1 d . . . . .
C2 C 0.26448(14) 0.5390(3) 0.7077(3) 0.0255(8) Uani 1 1 d . . . . .
H2 H 0.232535 0.536823 0.715290 0.031 Uiso 1 1 calc R U . . .
C3 C 0.29476(14) 0.6016(3) 0.7634(3) 0.0243(8) Uani 1 1 d . . . . .
C4 C 0.34229(14) 0.6061(3) 0.7498(3) 0.0276(9) Uani 1 1 d . . . . .
H4 H 0.362570 0.647999 0.786921 0.033 Uiso 1 1 calc R U . . .
C5 C 0.35965(15) 0.5485(3) 0.6813(4) 0.0296(9) Uani 1 1 d . . . . .
C6 C 0.32918(15) 0.4848(3) 0.6272(3) 0.0282(9) Uani 1 1 d . . . . .
H6 H 0.340609 0.445408 0.581801 0.034 Uiso 1 1 calc R U . . .
C7 C 0.25006(15) 0.4096(3) 0.5832(3) 0.0242(8) Uani 1 1 d . . . . .
C8 C 0.27647(14) 0.6627(3) 0.8396(3) 0.0237(8) Uani 1 1 d . . . . .
C9 C 0.41101(16) 0.5517(3) 0.6655(4) 0.0369(11) Uani 1 1 d . . . . .
H9A H 0.431075 0.526931 0.723037 0.044 Uiso 1 1 calc R U . . .
H9B H 0.415607 0.513964 0.608630 0.044 Uiso 1 1 calc R U . . .
C10 C 0.46624(17) 0.6623(4) 0.6201(4) 0.0424(12) Uani 1 1 d . . . . .
C11 C 0.4774(2) 0.7556(4) 0.6113(7) 0.066(2) Uani 1 1 d . . . . .
H11 H 0.456789 0.801375 0.628308 0.080 Uiso 1 1 calc R U . . .
C12 C 0.5192(2) 0.7813(4) 0.5771(6) 0.061(2) Uani 1 1 d . . . . .
H12 H 0.526451 0.844244 0.571109 0.073 Uiso 1 1 calc R U . . .
C13 C 0.55035(16) 0.7133(3) 0.5517(4) 0.0360(11) Uani 1 1 d . . . . .
C14 C 0.53915(16) 0.6207(4) 0.5635(4) 0.0384(11) Uani 1 1 d . . . . .
H14 H 0.560002 0.574728 0.548114 0.046 Uiso 1 1 calc R U . . .
C15 C 0.49709(17) 0.5942(4) 0.5980(4) 0.0404(12) Uani 1 1 d . . . . .
H15 H 0.490150 0.531311 0.605917 0.048 Uiso 1 1 calc R U . . .
C16 C 0.59475(14) 0.7401(3) 0.5133(4) 0.0313(9) Uani 1 1 d . . . . .
O8 O 0.35582(16) 0.0795(3) 0.6297(4) 0.0605(12) Uani 0.5 1 d . . P A 1
C17 C 0.3430(3) 0.0042(7) 0.6388(7) 0.077(2) Uani 0.5 1 d . U P A 1
H17 H 0.317225 -0.014770 0.593469 0.093 Uiso 0.5 1 calc R U P A 1
N1 N 0.3605(4) -0.0606(7) 0.7070(7) 0.129(3) Uani 0.5 1 d . U P A 1
C18 C 0.3452(6) -0.1475(10) 0.7170(12) 0.068(4) Uani 0.5 1 d . U P A 1
H18A H 0.367319 -0.190728 0.695109 0.101 Uiso 0.5 1 d R U P A 1
H18B H 0.314627 -0.155387 0.677961 0.101 Uiso 0.5 1 d R U P A 1
H18C H 0.342749 -0.159188 0.785265 0.101 Uiso 0.5 1 d R U P A 1
C19 C 0.3961(10) -0.042(2) 0.776(2) 0.135(9) Uani 0.5 1 d . U P A 1
H19A H 0.402833 -0.094605 0.818946 0.202 Uiso 0.5 1 d R U P A 1
H19B H 0.387541 0.010821 0.813986 0.202 Uiso 0.5 1 d R U P A 1
H19C H 0.423787 -0.026068 0.746766 0.202 Uiso 0.5 1 d R U P A 1
O9 O 0.34626(18) 0.2666(4) 0.7052(3) 0.0627(13) Uani 0.5 1 d . . P A 1
C20 C 0.3394(5) 0.2391(10) 0.7843(9) 0.052(3) Uani 0.5 1 d . U P A 1
H20 H 0.328188 0.178165 0.786022 0.063 Uiso 0.5 1 calc R U P A 1
N2 N 0.3455(5) 0.2833(11) 0.8685(8) 0.076(4) Uani 0.5 1 d . U P A 1
C21 C 0.3604(9) 0.3674(17) 0.8782(18) 0.115(7) Uani 0.5 1 d . U P A 1
H21A H 0.393694 0.368838 0.873504 0.173 Uiso 0.5 1 d R U P A 1
H21B H 0.355168 0.391477 0.941340 0.173 Uiso 0.5 1 d R U P A 1
H21C H 0.343515 0.405228 0.826624 0.173 Uiso 0.5 1 d R U P A 1
C22 C 0.3442(11) 0.224(2) 0.964(2) 0.143(10) Uani 0.5 1 d . U P A 1
H22A H 0.341480 0.158997 0.944732 0.214 Uiso 0.5 1 d R U P A 1
H22B H 0.317019 0.241591 0.993560 0.214 Uiso 0.5 1 d R U P A 1
H22C H 0.372499 0.232582 1.010077 0.214 Uiso 0.5 1 d R U P A 1
O8A O 0.35582(16) 0.0795(3) 0.6297(4) 0.0605(12) Uani 0.5 1 d . . P A 2
C17A C 0.3430(3) 0.0042(7) 0.6388(7) 0.077(2) Uani 0.5 1 d . . P A 2
H17A H 0.317225 -0.014770 0.593469 0.093 Uiso 0.5 1 calc R U P A 2
O10 O 0.3605(4) -0.0606(7) 0.7070(7) 0.129(3) Uani 0.5 1 d . . P A 2
O9A O 0.34626(18) 0.2666(4) 0.7052(3) 0.0627(13) Uani 0.5 1 d . . P A 2
O11 O 0.500000 0.772(2) 0.250000 0.324(9) Uiso 1 2 d S . P . .
O12 O 0.5593(7) 0.0051(15) 0.4744(15) 0.312(9) Uiso 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Dy1 O4 73.94(11) . 6_565
O1 Dy1 O3 78.81(11) . 4_546
O4 Dy1 O3 133.03(11) 6_565 4_546
O1 Dy1 O8 143.66(14) . .
O4 Dy1 O8 142.34(14) 6_565 .
O3 Dy1 O8 71.76(13) 4_546 .
O1 Dy1 O8A 143.66(14) . .
O4 Dy1 O8A 142.34(14) 6_565 .
O3 Dy1 O8A 71.76(13) 4_546 .
O1 Dy1 O6 137.71(11) . 5_666
O4 Dy1 O6 77.74(12) 6_565 5_666
O3 Dy1 O6 142.29(12) 4_546 5_666
O8 Dy1 O6 70.99(14) . 5_666
O1 Dy1 O2 122.90(11) . 7_556
O4 Dy1 O2 78.06(12) 6_565 7_556
O3 Dy1 O2 85.91(12) 4_546 7_556
O8 Dy1 O2 76.29(16) . 7_556
O6 Dy1 O2 79.87(11) 5_666 7_556
O1 Dy1 O9A 77.85(15) . .
O4 Dy1 O9A 134.14(14) 6_565 .
O3 Dy1 O9A 73.41(14) 4_546 .
O8A Dy1 O9A 73.73(18) . .
O6 Dy1 O9A 101.37(16) 5_666 .
O2 Dy1 O9A 147.62(15) 7_556 .
O1 Dy1 O9 77.85(15) . .
O4 Dy1 O9 134.14(14) 6_565 .
O3 Dy1 O9 73.41(14) 4_546 .
O8 Dy1 O9 73.73(18) . .
O6 Dy1 O9 101.37(16) 5_666 .
O2 Dy1 O9 147.62(15) 7_556 .
O1 Dy1 O7 87.87(11) . 5_666
O4 Dy1 O7 71.36(13) 6_565 5_666
O3 Dy1 O7 144.99(12) 4_546 5_666
O8 Dy1 O7 104.18(16) . 5_666
O6 Dy1 O7 53.23(11) 5_666 5_666
O2 Dy1 O7 127.80(11) 7_556 5_666
O9 Dy1 O7 72.19(14) . 5_666
O1 Dy1 O1 73.16(11) . 7_556
O4 Dy1 O1 69.67(10) 6_565 7_556
O3 Dy1 O1 66.14(10) 4_546 7_556
O8 Dy1 O1 111.98(14) . 7_556
O6 Dy1 O1 124.38(11) 5_666 7_556
O2 Dy1 O1 50.54(9) 7_556 7_556
O9 Dy1 O1 133.67(14) . 7_556
O7 Dy1 O1 140.01(13) 5_666 7_556
O1 Dy1 C16 112.55(12) . 5_666
O4 Dy1 C16 71.26(13) 6_565 5_666
O3 Dy1 C16 155.66(13) 4_546 5_666
O8 Dy1 C16 88.58(15) . 5_666
O8A Dy1 C16 88.58(15) . 5_666
O6 Dy1 C16 26.76(13) 5_666 5_666
O2 Dy1 C16 103.64(12) 7_556 5_666
O9A Dy1 C16 87.63(15) . 5_666
O9 Dy1 C16 87.63(15) . 5_666
O7 Dy1 C16 26.55(13) 5_666 5_666
O1 Dy1 C16 136.78(12) 7_556 5_666
C7 O1 Dy1 163.1(3) . .
C7 O1 Dy1 88.0(2) . 7_556
Dy1 O1 Dy1 106.84(10) . 7_556
C7 O2 Dy1 100.0(3) . 7_556
C8 O3 Dy1 136.8(3) . 4_556
C8 O4 Dy1 135.8(3) . 6_566
C10 O5 C9 117.4(4) . .
C16 O6 Dy1 93.7(3) . 5_666
C16 O7 Dy1 91.8(3) . 5_666
C6 C1 C2 120.2(4) . .
C6 C1 C7 119.2(3) . .
C2 C1 C7 120.6(3) . .
C1 C2 C3 120.0(4) . .
C1 C2 H2 120.0 . .
C3 C2 H2 120.0 . .
C2 C3 C4 119.6(4) . .
C2 C3 C8 120.2(3) . .
C4 C3 C8 120.2(4) . .
C5 C4 C3 120.5(4) . .
C5 C4 H4 119.7 . .
C3 C4 H4 119.7 . .
C4 C5 C6 119.4(4) . .
C4 C5 C9 121.6(4) . .
C6 C5 C9 119.0(4) . .
C1 C6 C5 120.2(4) . .
C1 C6 H6 119.9 . .
C5 C6 H6 119.9 . .
O2 C7 O1 121.3(4) . .
O2 C7 C1 120.1(4) . .
O1 C7 C1 118.6(4) . .
O2 C7 Dy1 55.0(2) . 7_556
O1 C7 Dy1 66.4(2) . 7_556
C1 C7 Dy1 173.5(3) . 7_556
O4 C8 O3 126.3(4) . .
O4 C8 C3 117.1(3) . .
O3 C8 C3 116.6(4) . .
O5 C9 C5 108.3(4) . .
O5 C9 H9A 110.0 . .
C5 C9 H9A 110.0 . .
O5 C9 H9B 110.0 . .
C5 C9 H9B 110.0 . .
H9A C9 H9B 108.4 . .
O5 C10 C15 124.7(5) . .
O5 C10 C11 115.0(5) . .
C15 C10 C11 120.3(4) . .
C10 C11 C12 120.2(5) . .
C10 C11 H11 119.9 . .
C12 C11 H11 119.9 . .
C11 C12 C13 120.4(5) . .
C11 C12 H12 119.8 . .
C13 C12 H12 119.8 . .
C14 C13 C12 118.4(4) . .
C14 C13 C16 120.8(4) . .
C12 C13 C16 120.7(4) . .
C13 C14 C15 121.6(4) . .
C13 C14 H14 119.2 . .
C15 C14 H14 119.2 . .
C10 C15 C14 119.1(5) . .
C10 C15 H15 120.5 . .
C14 C15 H15 120.5 . .
O7 C16 O6 121.0(4) . .
O7 C16 C13 119.8(4) . .
O6 C16 C13 119.1(4) . .
O7 C16 Dy1 61.7(2) . 5_666
O6 C16 Dy1 59.6(2) . 5_666
C13 C16 Dy1 174.5(4) . 5_666
C17 O8 Dy1 130.6(6) . .
O8 C17 N1 128.5(10) . .
O8 C17 H17 115.7 . .
N1 C17 H17 115.7 . .
C19 N1 C18 110.5(16) . .
C19 N1 C17 121.5(16) . .
C18 N1 C17 128.0(13) . .
N1 C18 H18A 109.3 . .
N1 C18 H18B 109.7 . .
H18A C18 H18B 109.5 . .
N1 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
N1 C19 H19A 109.9 . .
N1 C19 H19B 108.7 . .
H19A C19 H19B 109.5 . .
N1 C19 H19C 109.9 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
C20 O9 Dy1 130.7(7) . .
O9 C20 N2 128.6(13) . .
O9 C20 H20 115.7 . .
N2 C20 H20 115.7 . .
C21 N2 C20 123.3(16) . .
C21 N2 C22 118.5(18) . .
C20 N2 C22 117.1(16) . .
N2 C21 H21A 109.1 . .
N2 C21 H21B 109.9 . .
H21A C21 H21B 109.5 . .
N2 C21 H21C 109.4 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
N2 C22 H22A 108.2 . .
N2 C22 H22B 109.1 . .
H22A C22 H22B 109.5 . .
N2 C22 H22C 111.1 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C17A O8A Dy1 130.6(6) . .
O8A C17A O10 128.5(10) . .
O8A C17A H17A 115.7 . .
O10 C17A H17A 115.7 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O1 2.321(3) .
Dy1 O4 2.351(3) 6_565
Dy1 O3 2.371(3) 4_546
Dy1 O8 2.394(4) .
Dy1 O8A 2.394(4) .
Dy1 O6 2.419(3) 5_666
Dy1 O2 2.423(3) 7_556
Dy1 O9A 2.430(4) .
Dy1 O9 2.430(4) .
Dy1 O7 2.466(3) 5_666
Dy1 O1 2.669(3) 7_556
Dy1 C16 2.799(4) 5_666
O1 C7 1.260(5) .
O2 C7 1.247(5) .
O3 C8 1.254(5) .
O4 C8 1.254(5) .
O5 C10 1.367(5) .
O5 C9 1.411(6) .
O6 C16 1.263(6) .
O7 C16 1.252(6) .
C1 C6 1.387(5) .
C1 C2 1.387(5) .
C1 C7 1.499(5) .
C2 C3 1.390(5) .
C2 H2 0.9300 .
C3 C4 1.393(5) .
C3 C8 1.508(5) .
C4 C5 1.390(5) .
C4 H4 0.9300 .
C5 C6 1.395(6) .
C5 C9 1.508(5) .
C6 H6 0.9300 .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C10 C15 1.374(7) .
C10 C11 1.379(8) .
C11 C12 1.390(7) .
C11 H11 0.9300 .
C12 C13 1.392(7) .
C12 H12 0.9300 .
C13 C14 1.376(7) .
C13 C16 1.487(6) .
C14 C15 1.401(6) .
C14 H14 0.9300 .
C15 H15 0.9300 .
O8 C17 1.149(10) .
C17 N1 1.358(12) .
C17 H17 0.9300 .
N1 C19 1.31(3) .
N1 C18 1.331(16) .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
O9 C20 1.192(13) .
C20 N2 1.303(17) .
C20 H20 0.9300 .
N2 C21 1.28(2) .
N2 C22 1.56(3) .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
O8A C17A 1.149(10) .
C17A O10 1.358(12) .
C17A H17A 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C6 C1 C2 C3 -1.9(7) . .
C7 C1 C2 C3 177.7(4) . .
C1 C2 C3 C4 1.6(7) . .
C1 C2 C3 C8 -177.0(4) . .
C2 C3 C4 C5 -0.1(7) . .
C8 C3 C4 C5 178.5(4) . .
C3 C4 C5 C6 -1.1(7) . .
C3 C4 C5 C9 -179.7(5) . .
C2 C1 C6 C5 0.7(7) . .
C7 C1 C6 C5 -178.9(4) . .
C4 C5 C6 C1 0.8(7) . .
C9 C5 C6 C1 179.5(5) . .
Dy1 O2 C7 O1 -4.0(5) 7_556 .
Dy1 O2 C7 C1 174.9(3) 7_556 .
Dy1 O1 C7 O2 -148.5(7) . .
Dy1 O1 C7 O2 3.6(4) 7_556 .
Dy1 O1 C7 C1 32.6(12) . .
Dy1 O1 C7 C1 -175.3(3) 7_556 .
Dy1 O1 C7 Dy1 -152.1(10) . 7_556
C6 C1 C7 O2 -153.3(4) . .
C2 C1 C7 O2 27.1(6) . .
C6 C1 C7 O1 25.6(6) . .
C2 C1 C7 O1 -153.9(4) . .
Dy1 O4 C8 O3 32.2(7) 6_566 .
Dy1 O4 C8 C3 -147.9(3) 6_566 .
Dy1 O3 C8 O4 -2.5(8) 4_556 .
Dy1 O3 C8 C3 177.5(3) 4_556 .
C2 C3 C8 O4 -175.0(4) . .
C4 C3 C8 O4 6.3(6) . .
C2 C3 C8 O3 4.9(6) . .
C4 C3 C8 O3 -173.8(4) . .
C10 O5 C9 C5 -171.0(5) . .
C4 C5 C9 O5 -51.2(7) . .
C6 C5 C9 O5 130.2(5) . .
C9 O5 C10 C15 4.8(9) . .
C9 O5 C10 C11 -176.5(6) . .
O5 C10 C11 C12 -176.8(7) . .
C15 C10 C11 C12 2.0(12) . .
C10 C11 C12 C13 -0.2(13) . .
C11 C12 C13 C14 -1.4(11) . .
C11 C12 C13 C16 178.8(7) . .
C12 C13 C14 C15 1.4(9) . .
C16 C13 C14 C15 -178.9(5) . .
O5 C10 C15 C14 176.7(6) . .
C11 C10 C15 C14 -2.1(10) . .
C13 C14 C15 C10 0.4(9) . .
Dy1 O7 C16 O6 5.7(5) 5_666 .
Dy1 O7 C16 C13 -174.0(4) 5_666 .
Dy1 O6 C16 O7 -5.9(5) 5_666 .
Dy1 O6 C16 C13 173.8(4) 5_666 .
C14 C13 C16 O7 13.9(8) . .
C12 C13 C16 O7 -166.4(6) . .
C14 C13 C16 O6 -165.8(5) . .
C12 C13 C16 O6 13.9(9) . .
Dy1 O8 C17 N1 -163.3(7) . .
O8 C17 N1 C19 2(2) . .
O8 C17 N1 C18 179.7(12) . .
Dy1 O9 C20 N2 -161.6(12) . .
O9 C20 N2 C21 1(3) . .
O9 C20 N2 C22 -167.1(17) . .
Dy1 O8A C17A O10 -163.3(7) . .
