#------------------------------------------------------------------------------
#$Date: 2019-11-17 09:19:34 +0200 (Sun, 17 Nov 2019) $
#$Revision: 229065 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/02/7230260.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7230260
loop_
_publ_author_name
'Jin, Jun-Ling'
'Shen, Yang-Lin'
'Xie, Yun-Peng'
'Lu, Xing'
_publ_section_title
;
 Silver ethynide clusters constructed with fluorinated β-diketonate
 ligands
;
_journal_issue                   14
_journal_name_full               CrystEngComm
_journal_page_first              2036
_journal_paper_doi               10.1039/C8CE00243F
_journal_volume                  20
_journal_year                    2018
_chemical_formula_sum            'C172 H242 Ag40 F30 O33 P4 V2'
_chemical_formula_weight         7948.20
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2017-11-07 deposited with the CCDC.
2018-03-05 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 106.543(4)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   22.419(4)
_cell_length_b                   19.817(3)
_cell_length_c                   27.289(4)
_cell_measurement_reflns_used    9170
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      26.3635
_cell_measurement_theta_min      3.0077
_cell_volume                     11622(3)
_computing_cell_refinement       'SAINT (Bruker, 2014)'
_computing_data_collection       'Apex2 (Bruker, 2014)'
_computing_data_reduction        'SAINT (Bruker, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXTL XT-2014/4 (Sheldrick, 2014)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.973
_diffrn_measured_fraction_theta_max 0.973
_diffrn_measurement_device_type  'Bruker D8 Quest'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0590
_diffrn_reflns_av_unetI/netI     0.0591
_diffrn_reflns_Laue_measured_fraction_full 0.973
_diffrn_reflns_Laue_measured_fraction_max 0.973
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            56142
_diffrn_reflns_point_group_measured_fraction_full 0.973
_diffrn_reflns_point_group_measured_fraction_max 0.973
_diffrn_reflns_theta_full        23.256
_diffrn_reflns_theta_max         23.256
_diffrn_reflns_theta_min         2.897
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    3.462
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.271
_exptl_crystal_description       block
_exptl_crystal_F_000             7588
_exptl_crystal_size_max          0.084
_exptl_crystal_size_mid          0.063
_exptl_crystal_size_min          0.045
_exptl_transmission_factor_max   0.7454
_exptl_transmission_factor_min   0.3978
_refine_diff_density_max         2.062
_refine_diff_density_min         -2.057
_refine_diff_density_rms         0.330
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.090
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1257
_refine_ls_number_reflns         16257
_refine_ls_number_restraints     644
_refine_ls_restrained_S_all      1.071
_refine_ls_R_factor_all          0.1321
_refine_ls_R_factor_gt           0.1009
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+1217.8906P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2223
_refine_ls_wR_factor_ref         0.2440
_reflns_Friedel_coverage         0.000
_reflns_number_gt                12247
_reflns_number_total             16257
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c8ce00243f2.cif
_cod_data_source_block           Complex8
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 7230255--7230262.cif.
;
_cod_database_code               7230260
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.760
_shelx_estimated_absorpt_t_max   0.860
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.59553(9) -0.20260(11) 0.58924(10) 0.0558(6) Uani 1 1 d . . . . .
Ag2 Ag 0.47265(10) -0.15597(11) 0.59822(10) 0.0571(6) Uani 1 1 d . . . . .
Ag3 Ag 0.42606(8) -0.00896(9) 0.59005(7) 0.0355(4) Uani 1 1 d . . . . .
Ag4 Ag 0.16188(11) 0.24546(11) 0.35020(9) 0.0593(6) Uani 1 1 d . . . . .
Ag5 Ag 0.17213(8) 0.08147(10) 0.34851(8) 0.0443(5) Uani 1 1 d . . . . .
Ag6 Ag 0.67856(8) -0.04412(9) 0.64622(7) 0.0364(4) Uani 1 1 d . . . . .
Ag7 Ag 0.16910(11) 0.35899(15) 0.43488(10) 0.0700(7) Uani 1 1 d . . . . .
Ag8 Ag 0.14803(9) 0.04735(11) 0.45229(8) 0.0490(5) Uani 1 1 d . . . . .
Ag9 Ag 0.48541(9) -0.14450(11) 0.40927(8) 0.0504(5) Uani 1 1 d . . . . .
Ag10 Ag 0.37938(8) 0.12153(9) 0.55786(7) 0.0376(4) Uani 1 1 d . . . . .
Ag11 Ag 0.28882(8) 0.12574(9) 0.44342(6) 0.0325(4) Uani 1 1 d . . . . .
Ag12 Ag 0.31089(8) -0.01031(9) 0.50683(7) 0.0368(4) Uani 1 1 d . . . . .
Ag13 Ag 0.05653(8) 0.11690(10) 0.36887(7) 0.0437(5) Uani 1 1 d . . . . .
Ag14 Ag 0.39136(10) -0.12446(10) 0.48630(8) 0.0497(5) Uani 1 1 d . . . . .
Ag15 Ag 0.55842(8) 0.01732(10) 0.66023(7) 0.0421(5) Uani 1 1 d . . . . .
Ag16 Ag 0.48764(10) -0.22698(11) 0.49841(8) 0.0503(5) Uani 1 1 d . . . . .
Ag17 Ag 0.35431(8) -0.09852(9) 0.37566(7) 0.0392(4) Uani 1 1 d . . . . .
Ag18 Ag 0.11471(9) 0.20555(11) 0.46024(9) 0.0526(5) Uani 1 1 d . . . . .
Ag19 Ag 0.24394(9) 0.22293(11) 0.50858(8) 0.0489(5) Uani 1 1 d . . . . .
Ag20 Ag 0.28843(12) 0.28661(16) 0.42255(10) 0.0788(8) Uani 1 1 d . . . . .
V1 V 0.44158(17) 0.04886(19) 0.46197(15) 0.0320(9) Uani 1 1 d . . . . .
C1 C 0.5097(12) -0.2507(13) 0.5823(11) 0.047(6) Uani 1 1 d . U . . .
C2 C 0.4882(12) -0.3087(13) 0.5771(10) 0.045(5) Uani 1 1 d . U . . .
C3 C 0.4683(14) -0.3831(13) 0.5739(10) 0.054(5) Uani 1 1 d . U . . .
C4 C 0.4246(17) -0.3928(15) 0.6077(13) 0.074(8) Uani 1 1 d . U . . .
H4A H 0.3871 -0.3653 0.5944 0.111 Uiso 1 1 calc R U . . .
H4B H 0.4128 -0.4405 0.6075 0.111 Uiso 1 1 calc R U . . .
H4C H 0.4459 -0.3789 0.6428 0.111 Uiso 1 1 calc R U . . .
C5 C 0.4334(19) -0.3992(18) 0.5180(12) 0.090(11) Uani 1 1 d . U . . .
H5A H 0.3956 -0.3717 0.5073 0.135 Uiso 1 1 calc R U . . .
H5B H 0.4602 -0.3890 0.4962 0.135 Uiso 1 1 calc R U . . .
H5C H 0.4221 -0.4471 0.5149 0.135 Uiso 1 1 calc R U . . .
C6 C 0.5268(16) -0.4241(16) 0.5922(16) 0.085(10) Uani 1 1 d . U . . .
H6A H 0.5532 -0.4164 0.5696 0.127 Uiso 1 1 calc R U . . .
H6B H 0.5492 -0.4106 0.6271 0.127 Uiso 1 1 calc R U . . .
H6C H 0.5161 -0.4721 0.5918 0.127 Uiso 1 1 calc R U . . .
C7 C 0.0784(13) 0.1909(14) 0.2811(10) 0.054(6) Uani 1 1 d . U . . .
C8 C 0.1103(11) 0.1533(13) 0.3152(10) 0.047(6) Uani 1 1 d . U . . .
C9 C 0.0369(15) 0.2270(17) 0.2388(11) 0.068(7) Uani 1 1 d . U . . .
C10 C -0.0143(16) 0.176(2) 0.2096(14) 0.099(11) Uani 1 1 d . U . . .
H10A H -0.0432 0.1992 0.1806 0.149 Uiso 1 1 calc R U . . .
H10B H 0.0054 0.1384 0.1970 0.149 Uiso 1 1 calc R U . . .
H10C H -0.0371 0.1592 0.2327 0.149 Uiso 1 1 calc R U . . .
C11 C 0.0045(19) 0.2882(18) 0.2593(13) 0.088(10) Uani 1 1 d . U . . .
H11A H -0.0233 0.3121 0.2303 0.132 Uiso 1 1 calc R U . . .
H11B H -0.0195 0.2708 0.2815 0.132 Uiso 1 1 calc R U . . .
H11C H 0.0365 0.3194 0.2788 0.132 Uiso 1 1 calc R U . . .
C12 C 0.0758(18) 0.2539(18) 0.2050(12) 0.085(9) Uani 1 1 d . U . . .
H12A H 0.0487 0.2786 0.1760 0.127 Uiso 1 1 calc R U . . .
H12B H 0.1081 0.2842 0.2250 0.127 Uiso 1 1 calc R U . . .
H12C H 0.0952 0.2160 0.1923 0.127 Uiso 1 1 calc R U . . .
C13 C 0.1689(12) 0.2890(13) 0.5004(11) 0.051(6) Uani 1 1 d . U . . .
C14 C 0.1448(11) 0.3314(13) 0.5221(10) 0.046(5) Uani 1 1 d . U . . .
C15 C 0.1150(15) 0.3782(16) 0.5521(13) 0.065(6) Uani 1 1 d . U . . .
C16 C 0.1026(18) 0.337(2) 0.5931(14) 0.092(10) Uani 1 1 d . U . . .
H16A H 0.0831 0.3645 0.6138 0.137 Uiso 1 1 calc R U . . .
H16B H 0.0746 0.2994 0.5778 0.137 Uiso 1 1 calc R U . . .
H16C H 0.1418 0.3182 0.6147 0.137 Uiso 1 1 calc R U . . .
C17 C 0.0532(13) 0.4067(17) 0.5134(13) 0.071(8) Uani 1 1 d . U . . .
H17A H 0.0638 0.4338 0.4871 0.106 Uiso 1 1 calc R U . . .
H17B H 0.0265 0.3690 0.4973 0.106 Uiso 1 1 calc R U . . .
H17C H 0.0310 0.4349 0.5321 0.106 Uiso 1 1 calc R U . . .
C18 C 0.1597(17) 0.4370(19) 0.5714(15) 0.089(10) Uani 1 1 d . U . . .
H18A H 0.1656 0.4621 0.5422 0.134 Uiso 1 1 calc R U . . .
H18B H 0.1423 0.4671 0.5923 0.134 Uiso 1 1 calc R U . . .
H18C H 0.1999 0.4195 0.5921 0.134 Uiso 1 1 calc R U . . .
C19 C 0.2692(11) 0.1004(12) 0.5107(9) 0.036(5) Uani 1 1 d . U . . .
C20 C 0.2607(11) 0.0896(13) 0.5532(8) 0.043(5) Uani 1 1 d D U . . .
C21 C 0.2413(9) 0.0776(10) 0.6013(7) 0.038(5) Uani 1 1 d D U . . .
C22A C 0.2922(15) 0.0408(18) 0.6413(14) 0.062(12) Uiso 0.68(3) 1 d D U P A 1
H22A H 0.2788 0.0336 0.6720 0.093 Uiso 0.68(3) 1 calc R U P A 1
H22B H 0.3004 -0.0028 0.6276 0.093 Uiso 0.68(3) 1 calc R U P A 1
H22C H 0.3303 0.0680 0.6499 0.093 Uiso 0.68(3) 1 calc R U P A 1
C23A C 0.1807(12) 0.0370(17) 0.5873(15) 0.053(11) Uiso 0.68(3) 1 d D U P A 1
H23A H 0.1676 0.0289 0.6181 0.079 Uiso 0.68(3) 1 calc R U P A 1
H23B H 0.1483 0.0623 0.5624 0.079 Uiso 0.68(3) 1 calc R U P A 1
H23C H 0.1875 -0.0063 0.5723 0.079 Uiso 0.68(3) 1 calc R U P A 1
C24A C 0.230(2) 0.1478(17) 0.621(2) 0.111(19) Uiso 0.68(3) 1 d D U P A 1
H24A H 0.2172 0.1429 0.6524 0.166 Uiso 0.68(3) 1 calc R U P A 1
H24B H 0.2683 0.1744 0.6284 0.166 Uiso 0.68(3) 1 calc R U P A 1
H24C H 0.1970 0.1710 0.5950 0.166 Uiso 0.68(3) 1 calc R U P A 1
C22B C 0.237(3) 0.0021(17) 0.611(3) 0.07(2) Uiso 0.32(3) 1 d D U P A 2
H22D H 0.2239 -0.0049 0.6417 0.101 Uiso 0.32(3) 1 calc R U P A 2
H22E H 0.2055 -0.0181 0.5814 0.101 Uiso 0.32(3) 1 calc R U P A 2
H22F H 0.2771 -0.0192 0.6144 0.101 Uiso 0.32(3) 1 calc R U P A 2
C23B C 0.178(2) 0.111(4) 0.598(4) 0.08(2) Uiso 0.32(3) 1 d D U P A 2
H23D H 0.1669 0.1027 0.6293 0.120 Uiso 0.32(3) 1 calc R U P A 2
H23E H 0.1815 0.1600 0.5930 0.120 Uiso 0.32(3) 1 calc R U P A 2
H23F H 0.1463 0.0924 0.5686 0.120 Uiso 0.32(3) 1 calc R U P A 2
C24B C 0.291(3) 0.109(4) 0.647(3) 0.07(2) Uiso 0.32(3) 1 d D U P A 2
H24D H 0.2785 0.1013 0.6784 0.112 Uiso 0.32(3) 1 calc R U P A 2
H24E H 0.3310 0.0874 0.6503 0.112 Uiso 0.32(3) 1 calc R U P A 2
H24F H 0.2938 0.1573 0.6414 0.112 Uiso 0.32(3) 1 calc R U P A 2
C25 C 0.3712(10) -0.0957(12) 0.5587(9) 0.035(5) Uani 1 1 d . U . . .
C26 C 0.3392(11) -0.1440(13) 0.5615(9) 0.041(5) Uani 1 1 d . U . . .
C27 C 0.2994(12) -0.1986(16) 0.5669(12) 0.060(6) Uani 1 1 d . U . . .
C28 C 0.2988(13) -0.2510(15) 0.5262(15) 0.074(8) Uani 1 1 d . U . . .
H28A H 0.2718 -0.2887 0.5294 0.112 Uiso 1 1 calc R U . . .
H28B H 0.2830 -0.2305 0.4923 0.112 Uiso 1 1 calc R U . . .
H28C H 0.3412 -0.2677 0.5307 0.112 Uiso 1 1 calc R U . . .
C29 C 0.3269(16) -0.228(2) 0.6219(15) 0.096(11) Uani 1 1 d . U . . .
H29A H 0.3010 -0.2652 0.6272 0.144 Uiso 1 1 calc R U . . .
H29B H 0.3694 -0.2438 0.6259 0.144 Uiso 1 1 calc R U . . .
H29C H 0.3276 -0.1922 0.6471 0.144 Uiso 1 1 calc R U . . .
C30 C 0.2323(13) -0.1713(19) 0.5565(15) 0.083(10) Uani 1 1 d . U . . .
H30A H 0.2046 -0.2080 0.5601 0.124 Uiso 1 1 calc R U . . .
H30B H 0.2316 -0.1355 0.5811 0.124 Uiso 1 1 calc R U . . .
H30C H 0.2184 -0.1530 0.5217 0.124 Uiso 1 1 calc R U . . .
C31 C 0.0721(11) 0.1033(11) 0.4528(10) 0.041(5) Uani 1 1 d . U . . .
C32 C 0.0317(10) 0.1196(13) 0.4717(9) 0.040(5) Uani 1 1 d . U . . .
C33 C -0.0204(12) 0.1364(14) 0.4977(12) 0.054(5) Uani 1 1 d . U . . .
C34 C -0.0453(15) 0.2048(16) 0.4849(17) 0.092(11) Uani 1 1 d . U . . .
H34A H -0.0640 0.2085 0.4479 0.138 Uiso 1 1 calc R U . . .
H34B H -0.0770 0.2139 0.5024 0.138 Uiso 1 1 calc R U . . .
H34C H -0.0115 0.2378 0.4959 0.138 Uiso 1 1 calc R U . . .
C35 C -0.0700(13) 0.0837(16) 0.4784(13) 0.068(8) Uani 1 1 d . U . . .
H35A H -0.0520 0.0387 0.4874 0.101 Uiso 1 1 calc R U . . .
H35B H -0.1038 0.0907 0.4940 0.101 Uiso 1 1 calc R U . . .
H35C H -0.0864 0.0873 0.4411 0.101 Uiso 1 1 calc R U . . .
C36 C 0.0077(15) 0.133(3) 0.5546(13) 0.105(12) Uani 1 1 d . U . . .
H36A H 0.0247 0.0877 0.5642 0.158 Uiso 1 1 calc R U . . .
H36B H 0.0412 0.1664 0.5651 0.158 Uiso 1 1 calc R U . . .
H36C H -0.0243 0.1426 0.5716 0.158 Uiso 1 1 calc R U . . .
C37 C 0.4569(10) 0.0823(13) 0.6300(8) 0.035(5) Uani 1 1 d . U . . .
C38 C 0.4709(9) 0.1151(10) 0.6663(7) 0.034(5) Uani 1 1 d D U . . .
C39 C 0.4825(9) 0.1547(11) 0.7161(8) 0.058(6) Uani 1 1 d D U . . .
C40 C 0.5528(10) 0.1529(17) 0.7451(12) 0.100(12) Uani 1 1 d D U . . .
H40A H 0.5765 0.1736 0.7240 0.150 Uiso 1 1 calc R U . . .
H40B H 0.5601 0.1779 0.7773 0.150 Uiso 1 1 calc R U . . .
H40C H 0.5661 0.1059 0.7525 0.150 Uiso 1 1 calc R U . . .
C41 C 0.4446(14) 0.1227(15) 0.7483(11) 0.084(9) Uani 1 1 d D U . . .
H41A H 0.4516 0.1476 0.7805 0.126 Uiso 1 1 calc R U . . .
H41B H 0.4003 0.1242 0.7295 0.126 Uiso 1 1 calc R U . . .
H41C H 0.4575 0.0756 0.7556 0.126 Uiso 1 1 calc R U . . .
C42 C 0.4624(15) 0.2278(11) 0.7020(13) 0.099(11) Uani 1 1 d D U . . .
H42A H 0.4875 0.2469 0.6814 0.149 Uiso 1 1 calc R U . . .
H42B H 0.4184 0.2287 0.6824 0.149 Uiso 1 1 calc R U . . .
H42C H 0.4684 0.2545 0.7333 0.149 Uiso 1 1 calc R U . . .
C43 C 0.6960(10) -0.1559(11) 0.6255(8) 0.032(5) Uani 1 1 d D U . . .
C44 C 0.6866(11) -0.1691(11) 0.6650(8) 0.040(5) Uani 1 1 d D U . . .
C45 C 0.6883(9) -0.1922(11) 0.7189(8) 0.058(6) Uani 1 1 d D U . . .
C46 C 0.6837(13) -0.2687(11) 0.7178(12) 0.078(8) Uani 1 1 d D U . . .
H46A H 0.6441 -0.2824 0.6939 0.117 Uiso 1 1 calc R U . . .
H46B H 0.7181 -0.2876 0.7068 0.117 Uiso 1 1 calc R U . . .
H46C H 0.6860 -0.2854 0.7521 0.117 Uiso 1 1 calc R U . . .
C47 C 0.7491(10) -0.1668(15) 0.7554(11) 0.079(9) Uani 1 1 d D U . . .
H47A H 0.7498 -0.1174 0.7548 0.118 Uiso 1 1 calc R U . . .
H47B H 0.7521 -0.1823 0.7902 0.118 Uiso 1 1 calc R U . . .
H47C H 0.7843 -0.1846 0.7448 0.118 Uiso 1 1 calc R U . . .
C48 C 0.6314(11) -0.1592(14) 0.7300(12) 0.077(9) Uani 1 1 d D U . . .
H48A H 0.6361 -0.1100 0.7304 0.115 Uiso 1 1 calc R U . . .
H48B H 0.5936 -0.1720 0.7034 0.115 Uiso 1 1 calc R U . . .
H48C H 0.6283 -0.1745 0.7634 0.115 Uiso 1 1 calc R U . . .
C49 C 0.4032(10) -0.1896(11) 0.4270(10) 0.036(5) Uani 1 1 d . U . . .
C50 C 0.3800(11) -0.2359(11) 0.3980(10) 0.042(5) Uani 1 1 d . U . . .
C51 C 0.3470(12) -0.2908(13) 0.3669(11) 0.050(5) Uani 1 1 d . U . . .
C52 C 0.3931(15) -0.3507(14) 0.3705(11) 0.063(7) Uani 1 1 d . U . . .
H52A H 0.3714 -0.3883 0.3496 0.094 Uiso 1 1 calc R U . . .
H52B H 0.4279 -0.3361 0.3580 0.094 Uiso 1 1 calc R U . . .
H52C H 0.4089 -0.3653 0.4062 0.094 Uiso 1 1 calc R U . . .
C53 C 0.2897(14) -0.3113(16) 0.3823(14) 0.072(8) Uani 1 1 d . U . . .
H53A H 0.2686 -0.3485 0.3605 0.109 Uiso 1 1 calc R U . . .
H53B H 0.3021 -0.3260 0.4181 0.109 Uiso 1 1 calc R U . . .
H53C H 0.2614 -0.2727 0.3783 0.109 Uiso 1 1 calc R U . . .
C54 C 0.3234(17) -0.2640(18) 0.3113(11) 0.078(9) Uani 1 1 d . U . . .
H54A H 0.3007 -0.2999 0.2889 0.117 Uiso 1 1 calc R U . . .
H54B H 0.2956 -0.2255 0.3102 0.117 Uiso 1 1 calc R U . . .
H54C H 0.3589 -0.2497 0.2997 0.117 Uiso 1 1 calc R U . . .
C55 C 0.2100(12) 0.3381(12) 0.3681(10) 0.047(6) Uani 1 1 d . U . . .
C56 C 0.2366(14) 0.3892(14) 0.3654(12) 0.057(6) Uani 1 1 d . U . . .
C57 C 0.2616(17) 0.4567(17) 0.3561(14) 0.078(7) Uani 1 1 d . U . . .
C58 C 0.213(2) 0.5042(15) 0.3327(14) 0.093(10) Uani 1 1 d . U . . .
H58A H 0.2318 0.5473 0.3275 0.139 Uiso 1 1 calc R U . . .
H58B H 0.1882 0.4865 0.2997 0.139 Uiso 1 1 calc R U . . .
H58C H 0.1862 0.5111 0.3550 0.139 Uiso 1 1 calc R U . . .
C59 C 0.3017(19) 0.4446(18) 0.3176(15) 0.092(10) Uani 1 1 d . U . . .
H59A H 0.3352 0.4125 0.3326 0.139 Uiso 1 1 calc R U . . .
H59B H 0.2751 0.4264 0.2854 0.139 Uiso 1 1 calc R U . . .
H59C H 0.3198 0.4875 0.3110 0.139 Uiso 1 1 calc R U . . .
C60 C 0.3050(18) 0.480(2) 0.4084(15) 0.098(11) Uani 1 1 d . U . . .
H60A H 0.3366 0.4458 0.4220 0.148 Uiso 1 1 calc R U . . .
H60B H 0.3254 0.5227 0.4037 0.148 Uiso 1 1 calc R U . . .
H60C H 0.2804 0.4875 0.4324 0.148 Uiso 1 1 calc R U . . .
C61 C 0.1565(11) -0.1149(15) 0.3690(10) 0.048(5) Uani 1 1 d . U . . .
C62 C 0.1723(12) -0.1409(16) 0.3202(11) 0.061(7) Uani 1 1 d . U . . .
H62A H 0.2106 -0.1679 0.3303 0.092 Uiso 1 1 calc R U . . .
H62B H 0.1380 -0.1689 0.3000 0.092 Uiso 1 1 calc R U . . .
H62C H 0.1784 -0.1024 0.2996 0.092 Uiso 1 1 calc R U . . .
C63 C 0.1490(13) -0.1748(13) 0.4025(13) 0.060(7) Uani 1 1 d . U . . .
H63A H 0.1877 -0.2008 0.4125 0.090 Uiso 1 1 calc R U . . .
H63B H 0.1394 -0.1580 0.4331 0.090 Uiso 1 1 calc R U . . .
H63C H 0.1150 -0.2038 0.3831 0.090 Uiso 1 1 calc R U . . .
C64 C 0.0969(10) -0.0732(15) 0.3526(10) 0.053(6) Uani 1 1 d . U . . .
H64A H 0.1029 -0.0353 0.3314 0.079 Uiso 1 1 calc R U . . .
H64B H 0.0626 -0.1016 0.3330 0.079 Uiso 1 1 calc R U . . .
H64C H 0.0870 -0.0557 0.3830 0.079 Uiso 1 1 calc R U . . .
C65 C 0.3823(11) 0.3628(14) 0.5630(11) 0.052(6) Uani 1 1 d . U . . .
C66 C 0.3178(13) 0.3918(16) 0.5376(13) 0.068(8) Uani 1 1 d . U . . .
H66A H 0.3098 0.3908 0.5004 0.101 Uiso 1 1 calc R U . . .
H66B H 0.2863 0.3647 0.5472 0.101 Uiso 1 1 calc R U . . .
H66C H 0.3159 0.4385 0.5489 0.101 Uiso 1 1 calc R U . . .
C67 C 0.4301(14) 0.4074(17) 0.5490(17) 0.088(10) Uani 1 1 d . U . . .
H67A H 0.4204 0.4103 0.5117 0.132 Uiso 1 1 calc R U . . .
H67B H 0.4290 0.4526 0.5632 0.132 Uiso 1 1 calc R U . . .
H67C H 0.4716 0.3879 0.5630 0.132 Uiso 1 1 calc R U . . .
C68 C 0.401(2) 0.361(2) 0.6205(14) 0.106(12) Uani 1 1 d . U . . .
H68A H 0.3714 0.3331 0.6319 0.158 Uiso 1 1 calc R U . . .
H68B H 0.4428 0.3425 0.6333 0.158 Uiso 1 1 calc R U . . .
H68C H 0.4002 0.4073 0.6336 0.158 Uiso 1 1 calc R U . . .
C69 C -0.0947(13) 0.1514(17) 0.3233(11) 0.058(6) Uani 1 1 d . U . . .
C70 C -0.1149(12) 0.0797(16) 0.3105(10) 0.054(6) Uani 1 1 d . U . . .
H70 H -0.1580 0.0691 0.2995 0.065 Uiso 1 1 calc R U . . .
C71 C -0.0710(11) 0.0285(15) 0.3148(10) 0.051(6) Uani 1 1 d . U . . .
C72 C -0.1515(16) 0.199(2) 0.3101(14) 0.073(8) Uani 1 1 d . U . . .
C73 C -0.0962(12) -0.0421(17) 0.2999(11) 0.058(7) Uani 1 1 d . U . . .
C74 C 0.0447(14) 0.4567(17) 0.3779(13) 0.065(7) Uani 1 1 d . U . . .
C75 C 0.0681(18) 0.519(2) 0.3991(16) 0.089(9) Uani 1 1 d . U . . .
H75 H 0.0437 0.5589 0.3901 0.107 Uiso 1 1 calc R U . . .
C76 C 0.129(2) 0.523(2) 0.434(2) 0.107(11) Uani 1 1 d . U . . .
C78 C 0.1470(15) 0.5942(19) 0.4562(14) 0.117(14) Uani 1 1 d D U . . .
C77 C -0.0158(13) 0.4613(13) 0.3454(12) 0.090(10) Uani 1 1 d D U . . .
C79 C 0.6604(11) 0.0422(13) 0.6950(8) 0.038(5) Uani 1 1 d . U . . .
C80 C 0.6904(11) 0.0479(14) 0.7355(9) 0.043(5) Uani 1 1 d . U . . .
C81 C 0.7279(13) 0.0588(15) 0.7898(10) 0.053(5) Uani 1 1 d . U . . .
C82 C 0.730(2) 0.1332(18) 0.8030(13) 0.099(12) Uani 1 1 d . U . . .
H82A H 0.7545 0.1397 0.8386 0.149 Uiso 1 1 calc R U . . .
H82B H 0.7489 0.1584 0.7805 0.149 Uiso 1 1 calc R U . . .
H82C H 0.6874 0.1497 0.7986 0.149 Uiso 1 1 calc R U . . .
C83 C 0.7947(14) 0.034(2) 0.7992(13) 0.082(9) Uani 1 1 d . U . . .
H83A H 0.8179 0.0421 0.8350 0.123 Uiso 1 1 calc R U . . .
H83B H 0.7945 -0.0142 0.7917 0.123 Uiso 1 1 calc R U . . .
H83C H 0.8145 0.0588 0.7769 0.123 Uiso 1 1 calc R U . . .
C84 C 0.6968(15) 0.019(2) 0.8252(11) 0.081(9) Uani 1 1 d . U . . .
H84A H 0.7209 0.0260 0.8610 0.121 Uiso 1 1 calc R U . . .
H84B H 0.6543 0.0359 0.8201 0.121 Uiso 1 1 calc R U . . .
H84C H 0.6957 -0.0289 0.8169 0.121 Uiso 1 1 calc R U . . .
C85 C 0.4764(17) -0.085(3) 0.7080(15) 0.090(11) Uani 1 1 d D U . . .
C86 C 0.4404(12) -0.0905(13) 0.7474(10) 0.103(12) Uani 1 1 d D U . . .
O1 O 0.2275(7) -0.0036(9) 0.3693(7) 0.044(4) Uani 1 1 d . . . . .
O2 O 0.2075(8) -0.0373(8) 0.4537(6) 0.043(4) Uani 1 1 d . . . . .
O3 O 0.2792(7) -0.1078(8) 0.4176(7) 0.042(4) Uani 1 1 d . . . . .
O4 O 0.3456(8) 0.2315(8) 0.5545(8) 0.056(5) Uani 1 1 d . . . . .
O5 O 0.4587(7) 0.2541(9) 0.5596(7) 0.049(5) Uani 1 1 d . . . . .
O6 O 0.3733(8) 0.2819(11) 0.4792(8) 0.068(6) Uani 1 1 d . . . . .
O7 O 0.0687(9) 0.4009(10) 0.3841(8) 0.061(5) Uani 1 1 d . . . . .
O8 O 0.1703(12) 0.4808(13) 0.4519(9) 0.085(8) Uani 1 1 d . . . . .
O9 O -0.0453(9) 0.1745(10) 0.3407(9) 0.073(5) Uani 1 1 d . . . . .
O10 O -0.0165(9) 0.0318(10) 0.3297(9) 0.073(5) Uani 1 1 d . . . . .
O11 O 0.5103(17) -0.0370(17) 0.7155(15) 0.133(14) Uani 1 1 d . . . . .
O12 O 0.4644(15) -0.131(3) 0.6786(11) 0.18(2) Uani 1 1 d . . . . .
O13 O 0.4584(9) 0.0657(9) 0.4076(8) 0.061(5) Uani 1 1 d . . . . .
O14 O 0.4345(11) 0.1223(11) 0.4903(9) 0.083(8) Uani 1 1 d . . . . .
O15 O 0.3747(8) 0.0090(11) 0.4483(7) 0.066(6) Uani 1 1 d . . . . .
O16 O 0.486(2) -0.0225(18) 0.4979(18) 0.075(14) Uani 0.5 1 d . . P B -1
P1 P 0.2212(2) -0.0623(3) 0.4047(2) 0.0310(13) Uani 1 1 d . . . . .
P2 P 0.3905(3) 0.2779(3) 0.5374(3) 0.0400(15) Uani 1 1 d . . . . .
F1 F 0.1568(17) 0.5968(19) 0.5070(13) 0.177(13) Uiso 1 1 d D . . . .
F2 F 0.1069(19) 0.6433(15) 0.4373(16) 0.33(4) Uani 1 1 d D . . . .
F3 F 0.2004(18) 0.6114(16) 0.4485(17) 0.25(3) Uani 1 1 d D . . . .
F4 F -0.0231(16) 0.453(2) 0.2953(12) 0.28(3) Uani 1 1 d D . . . .
F5 F -0.0518(12) 0.5148(10) 0.3420(11) 0.151(12) Uani 1 1 d D . . . .
F6 F -0.0556(12) 0.4141(13) 0.3503(18) 0.26(3) Uani 1 1 d D . . . .
F7 F -0.1562(15) 0.2331(18) 0.2742(14) 0.20(2) Uani 1 1 d . . . . .
F8 F -0.2056(11) 0.1734(15) 0.3107(13) 0.146(12) Uani 1 1 d . . . . .
F9 F -0.1441(16) 0.2420(18) 0.3498(13) 0.184(17) Uani 1 1 d . . . . .
F10 F -0.1560(8) -0.0499(10) 0.2900(7) 0.076(5) Uani 1 1 d . . . . .
F11 F -0.0801(9) -0.0633(10) 0.2593(8) 0.086(6) Uani 1 1 d . . . . .
F12 F -0.0686(12) -0.0848(11) 0.3379(8) 0.108(8) Uani 1 1 d . . . . .
F13 F 0.3875(10) -0.0571(15) 0.7337(9) 0.148(13) Uani 1 1 d D . . . .
F14 F 0.4231(15) -0.1522(11) 0.7566(10) 0.169(15) Uani 1 1 d D . . . .
F15 F 0.4677(13) -0.0672(14) 0.7939(9) 0.152(12) Uani 1 1 d D . . . .
O1W O 0.0352(10) 0.2714(10) 0.3969(9) 0.084(8) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
V V 0.3005 0.5294 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ag1 C43 161.3(9) . .
C1 Ag1 C44 133.8(9) . .
C43 Ag1 C44 27.6(4) . .
C1 Ag1 Ag16 49.1(8) . .
C43 Ag1 Ag16 149.6(5) . .
C44 Ag1 Ag16 174.2(5) . .
C1 Ag1 Ag2 46.1(7) . .
C43 Ag1 Ag2 129.3(5) . .
C44 Ag1 Ag2 113.5(5) . .
Ag16 Ag1 Ag2 64.33(8) . .
C1 Ag1 Ag20 120.4(7) . 3_656
C43 Ag1 Ag20 62.6(5) . 3_656
C44 Ag1 Ag20 74.3(5) . 3_656
Ag16 Ag1 Ag20 109.01(10) . 3_656
Ag2 Ag1 Ag20 166.41(11) . 3_656
C1 Ag1 Ag11 160.2(8) . 3_656
C43 Ag1 Ag11 38.5(5) . 3_656
C44 Ag1 Ag11 66.0(4) . 3_656
Ag16 Ag1 Ag11 111.18(9) . 3_656
Ag2 Ag1 Ag11 133.34(9) . 3_656
Ag20 Ag1 Ag11 59.49(7) 3_656 3_656
C1 Ag2 O12 121.4(16) . .
C1 Ag2 O13 110.2(8) . 3_656
O12 Ag2 O13 97.4(13) . 3_656
C1 Ag2 C25 132.9(9) . .
O12 Ag2 C25 89.9(12) . .
O13 Ag2 C25 98.0(7) 3_656 .
C1 Ag2 Ag1 45.0(7) . .
O12 Ag2 Ag1 118.1(9) . .
O13 Ag2 Ag1 66.3(5) 3_656 .
C25 Ag2 Ag1 148.6(5) . .
C1 Ag2 Ag3 162.7(7) . .
O12 Ag2 Ag3 75.4(14) . .
O13 Ag2 Ag3 60.1(5) 3_656 .
C25 Ag2 Ag3 43.6(5) . .
Ag1 Ag2 Ag3 126.10(9) . .
C1 Ag2 Ag14 97.4(8) . .
O12 Ag2 Ag14 134.4(11) . .
O13 Ag2 Ag14 89.7(5) 3_656 .
C25 Ag2 Ag14 44.6(5) . .
Ag1 Ag2 Ag14 106.00(9) . .
Ag3 Ag2 Ag14 69.57(7) . .
C1 Ag2 Ag16 45.2(7) . .
O12 Ag2 Ag16 166.0(15) . .
O13 Ag2 Ag16 92.7(5) 3_656 .
C25 Ag2 Ag16 98.4(5) . .
Ag1 Ag2 Ag16 57.65(7) . .
Ag3 Ag2 Ag16 118.34(9) . .
Ag14 Ag2 Ag16 55.01(7) . .
C37 Ag3 C25 162.5(8) . .
C37 Ag3 Ag10 54.5(6) . .
C25 Ag3 Ag10 119.3(6) . .
C37 Ag3 Ag12 119.7(6) . .
C25 Ag3 Ag12 53.2(6) . .
Ag10 Ag3 Ag12 66.39(6) . .
C37 Ag3 Ag2 135.6(6) . .
C25 Ag3 Ag2 54.2(6) . .
Ag10 Ag3 Ag2 166.61(9) . .
Ag12 Ag3 Ag2 104.75(8) . .
C37 Ag3 Ag15 54.7(6) . .
C25 Ag3 Ag15 136.4(6) . .
Ag10 Ag3 Ag15 104.10(7) . .
Ag12 Ag3 Ag15 165.55(9) . .
Ag2 Ag3 Ag15 82.43(7) . .
C55 Ag4 C8 168.5(10) . .
C55 Ag4 C7 140.8(9) . .
C8 Ag4 C7 29.9(9) . .
C55 Ag4 Ag20 45.9(6) . .
C8 Ag4 Ag20 140.0(6) . .
C7 Ag4 Ag20 163.5(7) . .
C55 Ag4 Ag7 45.9(8) . .
C8 Ag4 Ag7 143.2(8) . .
C7 Ag4 Ag7 136.4(7) . .
Ag20 Ag4 Ag7 60.04(8) . .
C55 Ag4 Ag5 146.7(7) . .
C8 Ag4 Ag5 37.4(6) . .
C7 Ag4 Ag5 66.3(6) . .
Ag20 Ag4 Ag5 102.59(10) . .
Ag7 Ag4 Ag5 136.29(10) . .
C8 Ag5 O1 168.3(9) . .
C8 Ag5 Ag13 51.3(8) . .
O1 Ag5 Ag13 130.2(4) . .
C8 Ag5 Ag8 106.8(8) . .
O1 Ag5 Ag8 79.6(5) . .
Ag13 Ag5 Ag8 58.58(6) . .
C8 Ag5 Ag11 117.7(7) . .
O1 Ag5 Ag11 73.6(5) . .
Ag13 Ag5 Ag11 110.22(8) . .
Ag8 Ag5 Ag11 68.89(7) . .
C8 Ag5 Ag4 42.2(7) . .
O1 Ag5 Ag4 147.7(5) . .
Ag13 Ag5 Ag4 71.58(7) . .
Ag8 Ag5 Ag4 99.96(8) . .
Ag11 Ag5 Ag4 76.26(7) . .
C79 Ag6 C43 157.0(7) . .
C79 Ag6 O1 96.7(8) . 3_656
C43 Ag6 O1 96.5(6) . 3_656
C79 Ag6 C44 129.3(7) . .
C43 Ag6 C44 27.8(4) . .
O1 Ag6 C44 113.5(6) 3_656 .
C79 Ag6 Ag17 47.1(6) . 3_656
C43 Ag6 Ag17 155.3(5) . 3_656
O1 Ag6 Ag17 76.8(4) 3_656 3_656
C44 Ag6 Ag17 169.7(5) . 3_656
C79 Ag6 Ag15 47.2(6) . .
C43 Ag6 Ag15 128.0(5) . .
O1 Ag6 Ag15 133.9(4) 3_656 .
C44 Ag6 Ag15 112.2(5) . .
Ag17 Ag6 Ag15 57.80(6) 3_656 .
C79 Ag6 Ag11 161.7(6) . 3_656
C43 Ag6 Ag11 41.0(5) . 3_656
O1 Ag6 Ag11 70.6(4) 3_656 3_656
C44 Ag6 Ag11 68.8(4) . 3_656
Ag17 Ag6 Ag11 115.55(8) 3_656 3_656
Ag15 Ag6 Ag11 134.15(8) . 3_656
C13 Ag7 C55 127.3(9) . .
C13 Ag7 O7 116.8(8) . .
C55 Ag7 O7 97.1(8) . .
C13 Ag7 O8 117.0(9) . .
C55 Ag7 O8 110.0(9) . .
O7 Ag7 O8 74.4(7) . .
C13 Ag7 C14 27.8(8) . .
C55 Ag7 C14 155.0(8) . .
O7 Ag7 C14 100.9(7) . .
O8 Ag7 C14 91.5(8) . .
C13 Ag7 Ag20 89.9(6) . .
C55 Ag7 Ag20 44.6(6) . .
O7 Ag7 Ag20 140.8(5) . .
O8 Ag7 Ag20 120.4(6) . .
C14 Ag7 Ag20 113.7(5) . .
C13 Ag7 Ag4 97.4(7) . .
C55 Ag7 Ag4 41.4(7) . .
O7 Ag7 Ag4 88.8(5) . .
O8 Ag7 Ag4 145.5(6) . .
C14 Ag7 Ag4 121.6(6) . .
Ag20 Ag7 Ag4 57.98(9) . .
C31 Ag8 O2 161.2(8) . .
C31 Ag8 Ag13 49.4(7) . .
O2 Ag8 Ag13 132.6(4) . .
C31 Ag8 Ag5 104.5(8) . .
O2 Ag8 Ag5 85.3(5) . .
Ag13 Ag8 Ag5 57.01(6) . .
C31 Ag8 Ag18 42.6(7) . .
O2 Ag8 Ag18 155.8(5) . .
Ag13 Ag8 Ag18 58.34(7) . .
Ag5 Ag8 Ag18 87.35(8) . .
C49 Ag9 C37 160.5(8) . 3_656
C49 Ag9 O5 86.8(7) . 3_656
C37 Ag9 O5 109.4(7) 3_656 3_656
C49 Ag9 C38 142.2(8) . 3_656
C37 Ag9 C38 26.4(7) 3_656 3_656
O5 Ag9 C38 101.4(6) 3_656 3_656
C49 Ag9 Ag16 54.0(6) . .
C37 Ag9 Ag16 145.3(6) 3_656 .
O5 Ag9 Ag16 49.5(4) 3_656 .
C38 Ag9 Ag16 150.4(5) 3_656 .
C49 Ag9 Ag10 147.4(6) . 3_656
C37 Ag9 Ag10 51.9(6) 3_656 3_656
O5 Ag9 Ag10 70.2(4) 3_656 3_656
C38 Ag9 Ag10 67.5(4) 3_656 3_656
Ag16 Ag9 Ag10 93.49(8) . 3_656
C49 Ag9 Ag17 51.7(6) . .
C37 Ag9 Ag17 109.6(6) 3_656 .
O5 Ag9 Ag17 136.1(4) 3_656 .
C38 Ag9 Ag17 104.6(5) 3_656 .
Ag16 Ag9 Ag17 102.14(8) . .
Ag10 Ag9 Ag17 153.16(10) 3_656 .
C49 Ag9 Ag15 108.6(6) . 3_656
C37 Ag9 Ag15 53.1(6) 3_656 3_656
O5 Ag9 Ag15 158.8(4) 3_656 3_656
C38 Ag9 Ag15 57.5(5) 3_656 3_656
Ag16 Ag9 Ag15 151.78(10) . 3_656
Ag10 Ag9 Ag15 100.26(7) 3_656 3_656
Ag17 Ag9 Ag15 56.88(6) . 3_656
O4 Ag10 C37 120.1(8) . .
O4 Ag10 C19 82.6(7) . .
C37 Ag10 C19 140.2(8) . .
O4 Ag10 O14 101.0(8) . .
C37 Ag10 O14 102.5(8) . .
C19 Ag10 O14 104.4(8) . .
O4 Ag10 C20 84.9(7) . .
C37 Ag10 C20 116.4(7) . .
C19 Ag10 C20 27.4(7) . .
O14 Ag10 C20 130.9(7) . .
O4 Ag10 Ag3 164.9(5) . .
C37 Ag10 Ag3 47.2(6) . .
C19 Ag10 Ag3 103.4(6) . .
O14 Ag10 Ag3 91.0(6) . .
C20 Ag10 Ag3 94.2(5) . .
O4 Ag10 Ag9 99.5(4) . 3_656
C37 Ag10 Ag9 49.1(5) . 3_656
C19 Ag10 Ag9 167.0(5) . 3_656
O14 Ag10 Ag9 62.6(6) . 3_656
C20 Ag10 Ag9 165.0(4) . 3_656
Ag3 Ag10 Ag9 77.83(7) . 3_656
O4 Ag10 Ag12 130.9(5) . .
C37 Ag10 Ag12 104.3(6) . .
C19 Ag10 Ag12 48.7(6) . .
O14 Ag10 Ag12 87.7(5) . .
C20 Ag10 Ag12 55.6(5) . .
Ag3 Ag10 Ag12 58.01(6) . .
Ag9 Ag10 Ag12 126.44(8) 3_656 .
O4 Ag10 Ag11 80.0(5) . .
C37 Ag10 Ag11 159.2(6) . .
C19 Ag10 Ag11 40.2(5) . .
O14 Ag10 Ag11 65.8(6) . .
C20 Ag10 Ag11 67.5(4) . .
Ag3 Ag10 Ag11 113.67(7) . .
Ag9 Ag10 Ag11 127.23(8) 3_656 .
Ag12 Ag10 Ag11 59.77(6) . .
C19 Ag11 C43 176.3(9) . 3_656
C19 Ag11 Ag19 55.6(7) . .
C43 Ag11 Ag19 121.3(6) 3_656 .
C19 Ag11 Ag12 49.3(7) . .
C43 Ag11 Ag12 134.0(6) 3_656 .
Ag19 Ag11 Ag12 104.52(7) . .
C19 Ag11 Ag6 135.4(7) . 3_656
C43 Ag11 Ag6 47.4(6) 3_656 3_656
Ag19 Ag11 Ag6 167.22(8) . 3_656
Ag12 Ag11 Ag6 87.31(6) . 3_656
C19 Ag11 Ag10 50.5(6) . .
C43 Ag11 Ag10 131.6(6) 3_656 .
Ag19 Ag11 Ag10 70.34(6) . .
Ag12 Ag11 Ag10 59.21(6) . .
Ag6 Ag11 Ag10 120.98(7) 3_656 .
C19 Ag11 Ag5 108.5(6) . .
C43 Ag11 Ag5 70.0(6) 3_656 .
Ag19 Ag11 Ag5 108.61(7) . .
Ag12 Ag11 Ag5 99.88(7) . .
Ag6 Ag11 Ag5 63.75(6) 3_656 .
Ag10 Ag11 Ag5 156.45(8) . .
C19 Ag11 Ag20 113.9(7) . .
C43 Ag11 Ag20 63.5(6) 3_656 .
Ag19 Ag11 Ag20 58.99(7) . .
Ag12 Ag11 Ag20 157.95(8) . .
Ag6 Ag11 Ag20 110.76(8) 3_656 .
Ag10 Ag11 Ag20 99.57(7) . .
Ag5 Ag11 Ag20 99.50(7) . .
C19 Ag11 Ag1 136.5(6) . 3_656
C43 Ag11 Ag1 45.0(6) 3_656 3_656
Ag19 Ag11 Ag1 106.49(8) . 3_656
Ag12 Ag11 Ag1 121.47(7) . 3_656
Ag6 Ag11 Ag1 70.21(6) 3_656 3_656
Ag10 Ag11 Ag1 86.98(7) . 3_656
Ag5 Ag11 Ag1 114.99(7) . 3_656
Ag20 Ag11 Ag1 57.82(7) . 3_656
C25 Ag12 C19 142.2(8) . .
C25 Ag12 O2 119.2(7) . .
C19 Ag12 O2 84.8(6) . .
C25 Ag12 O15 99.2(8) . .
C19 Ag12 O15 101.1(8) . .
O2 Ag12 O15 106.3(6) . .
C25 Ag12 Ag3 46.5(6) . .
C19 Ag12 Ag3 103.1(5) . .
O2 Ag12 Ag3 162.8(4) . .
O15 Ag12 Ag3 87.4(5) . .
C25 Ag12 Ag14 46.5(5) . .
C19 Ag12 Ag14 161.2(5) . .
O2 Ag12 Ag14 104.0(4) . .
O15 Ag12 Ag14 60.7(6) . .
Ag3 Ag12 Ag14 73.14(7) . .
C25 Ag12 Ag10 101.8(6) . .
C19 Ag12 Ag10 50.8(5) . .
O2 Ag12 Ag10 135.4(4) . .
O15 Ag12 Ag10 81.8(4) . .
Ag3 Ag12 Ag10 55.59(6) . .
Ag14 Ag12 Ag10 117.28(7) . .
C25 Ag12 Ag11 155.4(6) . .
C19 Ag12 Ag11 40.8(5) . .
O2 Ag12 Ag11 83.5(4) . .
O15 Ag12 Ag11 62.7(6) . .
Ag3 Ag12 Ag11 112.60(7) . .
Ag14 Ag12 Ag11 122.75(8) . .
Ag10 Ag12 Ag11 61.02(6) . .
C31 Ag13 C8 138.2(9) . .
C31 Ag13 O10 105.2(8) . .
C8 Ag13 O10 111.1(9) . .
C31 Ag13 O9 103.6(8) . .
C8 Ag13 O9 105.5(8) . .
O10 Ag13 O9 74.4(7) . .
C31 Ag13 Ag5 106.3(6) . .
C8 Ag13 Ag5 44.0(6) . .
O10 Ag13 Ag5 106.4(6) . .
O9 Ag13 Ag5 148.5(6) . .
C31 Ag13 Ag8 43.7(6) . .
C8 Ag13 Ag8 105.5(6) . .
O10 Ag13 Ag8 104.8(5) . .
O9 Ag13 Ag8 146.8(6) . .
Ag5 Ag13 Ag8 64.41(7) . .
C31 Ag13 Ag18 47.1(6) . .
C8 Ag13 Ag18 99.4(6) . .
O10 Ag13 Ag18 149.4(6) . .
O9 Ag13 Ag18 97.6(5) . .
Ag5 Ag13 Ag18 95.73(8) . .
Ag8 Ag13 Ag18 65.90(7) . .
C49 Ag14 C25 157.7(8) . .
C49 Ag14 C26 132.0(8) . .
C25 Ag14 C26 26.8(8) . .
C49 Ag14 Ag16 54.5(6) . .
C25 Ag14 Ag16 114.2(6) . .
C26 Ag14 Ag16 106.6(5) . .
C49 Ag14 Ag17 52.4(6) . .
C25 Ag14 Ag17 143.0(6) . .
C26 Ag14 Ag17 139.4(5) . .
Ag16 Ag14 Ag17 102.83(8) . .
C49 Ag14 Ag12 142.5(6) . .
C25 Ag14 Ag12 50.6(6) . .
C26 Ag14 Ag12 63.4(6) . .
Ag16 Ag14 Ag12 162.99(10) . .
Ag17 Ag14 Ag12 92.88(8) . .
C49 Ag14 Ag2 116.8(6) . .
C25 Ag14 Ag2 52.8(6) . .
C26 Ag14 Ag2 58.8(5) . .
Ag16 Ag14 Ag2 62.95(7) . .
Ag17 Ag14 Ag2 161.68(9) . .
Ag12 Ag14 Ag2 100.31(8) . .
C79 Ag15 O11 115.1(12) . .
C79 Ag15 O13 112.7(7) . 3_656
O11 Ag15 O13 100.3(11) . 3_656
C79 Ag15 C37 136.8(8) . .
O11 Ag15 C37 84.7(9) . .
O13 Ag15 C37 99.5(7) 3_656 .
C79 Ag15 Ag17 47.6(6) . 3_656
O11 Ag15 Ag17 160.9(11) . 3_656
O13 Ag15 Ag17 95.3(4) 3_656 3_656
C37 Ag15 Ag17 103.6(5) . 3_656
C79 Ag15 Ag6 47.4(6) . .
O11 Ag15 Ag6 118.5(7) . .
O13 Ag15 Ag6 65.7(5) 3_656 .
C37 Ag15 Ag6 153.5(5) . .
Ag17 Ag15 Ag6 58.72(6) 3_656 .
C79 Ag15 Ag3 167.0(5) . .
O11 Ag15 Ag3 77.5(11) . .
O13 Ag15 Ag3 59.9(5) 3_656 .
C37 Ag15 Ag3 43.0(6) . .
Ag17 Ag15 Ag3 120.31(8) 3_656 .
Ag6 Ag15 Ag3 125.28(8) . .
C79 Ag15 Ag9 100.6(6) . 3_656
O11 Ag15 Ag9 129.3(7) . 3_656
O13 Ag15 Ag9 97.4(5) 3_656 3_656
C37 Ag15 Ag9 45.5(5) . 3_656
Ag17 Ag15 Ag9 58.50(6) 3_656 3_656
Ag6 Ag15 Ag9 112.15(7) . 3_656
Ag3 Ag15 Ag9 71.34(6) . 3_656
C1 Ag16 O5 130.0(8) . 3_656
C1 Ag16 C49 141.3(9) . .
O5 Ag16 C49 87.7(7) 3_656 .
C1 Ag16 C2 27.2(8) . .
O5 Ag16 C2 121.6(7) 3_656 .
C49 Ag16 C2 130.8(7) . .
C1 Ag16 Ag14 101.7(6) . .
O5 Ag16 Ag14 126.8(5) 3_656 .
C49 Ag16 Ag14 46.3(6) . .
C2 Ag16 Ag14 110.2(6) . .
C1 Ag16 Ag9 155.7(7) . .
O5 Ag16 Ag9 56.5(5) 3_656 .
C49 Ag16 Ag9 48.1(5) . .
C2 Ag16 Ag9 176.9(5) . .
Ag14 Ag16 Ag9 71.26(8) . .
C1 Ag16 Ag1 45.1(7) . .
O5 Ag16 Ag1 98.6(4) 3_656 .
C49 Ag16 Ag1 152.7(5) . .
C2 Ag16 Ag1 67.3(5) . .
Ag14 Ag16 Ag1 112.48(9) . .
Ag9 Ag16 Ag1 114.90(9) . .
C1 Ag16 Ag2 42.7(6) . .
O5 Ag16 Ag2 153.7(4) 3_656 .
C49 Ag16 Ag2 107.8(6) . .
C2 Ag16 Ag2 63.7(5) . .
Ag14 Ag16 Ag2 62.04(7) . .
Ag9 Ag16 Ag2 119.14(9) . .
Ag1 Ag16 Ag2 58.03(7) . .
C79 Ag17 O3 122.5(7) 3_656 .
C79 Ag17 C49 148.2(8) 3_656 .
O3 Ag17 C49 85.7(7) . .
C79 Ag17 Ag15 50.4(7) 3_656 3_656
O3 Ag17 Ag15 150.5(4) . 3_656
C49 Ag17 Ag15 112.3(5) . 3_656
C79 Ag17 Ag6 50.1(6) 3_656 3_656
O3 Ag17 Ag6 90.1(4) . 3_656
C49 Ag17 Ag6 154.8(6) . 3_656
Ag15 Ag17 Ag6 63.49(6) 3_656 3_656
C79 Ag17 Ag14 158.3(7) 3_656 .
O3 Ag17 Ag14 60.4(4) . .
C49 Ag17 Ag14 46.1(6) . .
Ag15 Ag17 Ag14 114.96(8) 3_656 .
Ag6 Ag17 Ag14 110.98(8) 3_656 .
C79 Ag17 Ag9 108.6(6) 3_656 .
O3 Ag17 Ag9 128.6(4) . .
C49 Ag17 Ag9 47.7(5) . .
Ag15 Ag17 Ag9 64.62(7) 3_656 .
Ag6 Ag17 Ag9 121.87(8) 3_656 .
Ag14 Ag17 Ag9 70.30(7) . .
C13 Ag18 C31 155.4(10) . .
C13 Ag18 O1W 98.1(9) . .
C31 Ag18 O1W 102.2(8) . .
C13 Ag18 C32 139.3(10) . .
C31 Ag18 C32 27.5(8) . .
O1W Ag18 C32 91.8(8) . .
C13 Ag18 Ag19 47.1(7) . .
C31 Ag18 Ag19 120.5(6) . .
O1W Ag18 Ag19 134.2(6) . .
C32 Ag18 Ag19 133.8(5) . .
C13 Ag18 Ag13 155.8(8) . .
C31 Ag18 Ag13 47.4(7) . .
O1W Ag18 Ag13 71.0(5) . .
C32 Ag18 Ag13 64.1(6) . .
Ag19 Ag18 Ag13 126.60(9) . .
C13 Ag18 Ag8 131.9(7) . .
C31 Ag18 Ag8 38.2(6) . .
O1W Ag18 Ag8 126.7(5) . .
C32 Ag18 Ag8 64.0(6) . .
Ag19 Ag18 Ag8 85.67(8) . .
Ag13 Ag18 Ag8 55.75(6) . .
C13 Ag19 O4 131.4(9) . .
C13 Ag19 C19 141.6(9) . .
O4 Ag19 C19 82.7(7) . .
C13 Ag19 Ag18 49.0(7) . .
O4 Ag19 Ag18 174.0(5) . .
C19 Ag19 Ag18 95.1(5) . .
C13 Ag19 Ag11 137.5(8) . .
O4 Ag19 Ag11 85.5(5) . .
C19 Ag19 Ag11 43.2(5) . .
Ag18 Ag19 Ag11 96.74(8) . .
C13 Ag19 Ag20 95.0(8) . .
O4 Ag19 Ag20 84.1(5) . .
C19 Ag19 Ag20 107.3(5) . .
Ag18 Ag19 Ag20 101.83(9) . .
Ag11 Ag19 Ag20 64.64(8) . .
O6 Ag20 C55 154.9(9) . .
O6 Ag20 C56 129.2(9) . .
C55 Ag20 C56 26.8(9) . .
O6 Ag20 Ag4 161.2(7) . .
C55 Ag20 Ag4 43.5(7) . .
C56 Ag20 Ag4 69.6(6) . .
O6 Ag20 Ag19 80.8(6) . .
C55 Ag20 Ag19 109.6(7) . .
C56 Ag20 Ag19 126.0(7) . .
Ag4 Ag20 Ag19 86.60(10) . .
O6 Ag20 Ag7 124.5(6) . .
C55 Ag20 Ag7 47.1(8) . .
C56 Ag20 Ag7 57.5(7) . .
Ag4 Ag20 Ag7 61.98(8) . .
Ag19 Ag20 Ag7 68.50(8) . .
O6 Ag20 Ag1 56.8(6) . 3_656
C55 Ag20 Ag1 133.9(8) . 3_656
C56 Ag20 Ag1 125.6(7) . 3_656
Ag4 Ag20 Ag1 115.38(11) . 3_656
Ag19 Ag20 Ag1 108.37(10) . 3_656
Ag7 Ag20 Ag1 175.66(13) . 3_656
O6 Ag20 Ag11 82.5(6) . .
C55 Ag20 Ag11 122.4(7) . .
C56 Ag20 Ag11 147.8(6) . .
Ag4 Ag20 Ag11 78.89(9) . .
Ag19 Ag20 Ag11 56.37(7) . .
Ag7 Ag20 Ag11 113.02(11) . .
Ag1 Ag20 Ag11 62.69(7) 3_656 .
O15 V1 O13 108.6(9) . .
O15 V1 O14 108.7(10) . .
O13 V1 O14 108.3(10) . .
O15 V1 O16 94.2(17) . .
O13 V1 O16 113.6(18) . .
O14 V1 O16 121.9(18) . .
C2 C1 Ag1 138(2) . .
C2 C1 Ag2 132(2) . .
Ag1 C1 Ag2 89.0(10) . .
C2 C1 Ag16 96(2) . .
Ag1 C1 Ag16 85.8(9) . .
Ag2 C1 Ag16 92.1(10) . .
C1 C2 C3 174(3) . .
C1 C2 Ag16 56.3(17) . .
C3 C2 Ag16 126.7(17) . .
C6 C3 C4 112(3) . .
C6 C3 C5 112(3) . .
C4 C3 C5 110(3) . .
C6 C3 C2 107(2) . .
C4 C3 C2 108(2) . .
C5 C3 C2 108(2) . .
C3 C4 H4A 109.5 . .
C3 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
C3 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
C3 C5 H5A 109.5 . .
C3 C5 H5B 109.5 . .
H5A C5 H5B 109.5 . .
C3 C5 H5C 109.5 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
C3 C6 H6A 109.5 . .
C3 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C3 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C8 C7 C9 173(3) . .
C8 C7 Ag4 63.1(16) . .
C9 C7 Ag4 124(2) . .
C7 C8 Ag5 159(3) . .
C7 C8 Ag4 87.0(19) . .
Ag5 C8 Ag4 100.3(10) . .
C7 C8 Ag13 112(2) . .
Ag5 C8 Ag13 84.8(9) . .
Ag4 C8 Ag13 107.0(12) . .
C7 C9 C12 108(3) . .
C7 C9 C10 107(3) . .
C12 C9 C10 112(3) . .
C7 C9 C11 110(3) . .
C12 C9 C11 110(3) . .
C10 C9 C11 109(3) . .
C9 C10 H10A 109.5 . .
C9 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C9 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C9 C11 H11A 109.5 . .
C9 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C9 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C9 C12 H12A 109.5 . .
C9 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C9 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C14 C13 Ag19 145(2) . .
C14 C13 Ag18 120(2) . .
Ag19 C13 Ag18 83.9(9) . .
C14 C13 Ag7 93(2) . .
Ag19 C13 Ag7 106.6(12) . .
Ag18 C13 Ag7 101.3(12) . .
C13 C14 C15 175(3) . .
C13 C14 Ag7 58.7(18) . .
C15 C14 Ag7 126.6(19) . .
C16 C15 C14 106(3) . .
C16 C15 C18 114(3) . .
C14 C15 C18 108(2) . .
C16 C15 C17 113(3) . .
C14 C15 C17 107(2) . .
C18 C15 C17 109(3) . .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C15 C17 H17A 109.5 . .
C15 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C15 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C15 C18 H18A 109.5 . .
C15 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C15 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C20 C19 Ag11 175(2) . .
C20 C19 Ag12 92.8(18) . .
Ag11 C19 Ag12 89.9(8) . .
C20 C19 Ag10 86.6(17) . .
Ag11 C19 Ag10 89.3(8) . .
Ag12 C19 Ag10 80.5(7) . .
C20 C19 Ag19 95.5(17) . .
Ag11 C19 Ag19 81.2(8) . .
Ag12 C19 Ag19 168.4(10) . .
Ag10 C19 Ag19 92.0(7) . .
C19 C20 C21 172(2) . .
C19 C20 Ag10 66.0(15) . .
C21 C20 Ag10 121.2(15) . .
C20 C21 C22A 111(2) . .
C20 C21 C22B 110(4) . .
C20 C21 C23A 109(2) . .
C22A C21 C23A 111.0(17) . .
C20 C21 C24A 106(3) . .
C22A C21 C24A 110.3(17) . .
C23A C21 C24A 109.9(17) . .
C20 C21 C23B 111(4) . .
C22B C21 C23B 109(3) . .
C20 C21 C24B 109(4) . .
C22B C21 C24B 109(3) . .
C23B C21 C24B 108(3) . .
C21 C22A H22A 109.5 . .
C21 C22A H22B 109.5 . .
H22A C22A H22B 109.5 . .
C21 C22A H22C 109.5 . .
H22A C22A H22C 109.5 . .
H22B C22A H22C 109.5 . .
C21 C23A H23A 109.5 . .
C21 C23A H23B 109.5 . .
H23A C23A H23B 109.5 . .
C21 C23A H23C 109.5 . .
H23A C23A H23C 109.5 . .
H23B C23A H23C 109.5 . .
C21 C24A H24A 109.5 . .
C21 C24A H24B 109.5 . .
H24A C24A H24B 109.5 . .
C21 C24A H24C 109.5 . .
H24A C24A H24C 109.5 . .
H24B C24A H24C 109.5 . .
C21 C22B H22D 109.5 . .
C21 C22B H22E 109.5 . .
H22D C22B H22E 109.5 . .
C21 C22B H22F 109.5 . .
H22D C22B H22F 109.5 . .
H22E C22B H22F 109.5 . .
C21 C23B H23D 109.5 . .
C21 C23B H23E 109.5 . .
H23D C23B H23E 109.5 . .
C21 C23B H23F 109.5 . .
H23D C23B H23F 109.5 . .
H23E C23B H23F 109.5 . .
C21 C24B H24D 109.5 . .
C21 C24B H24E 109.5 . .
H24D C24B H24E 109.5 . .
C21 C24B H24F 109.5 . .
H24D C24B H24F 109.5 . .
H24E C24B H24F 109.5 . .
C26 C25 Ag3 153(2) . .
C26 C25 Ag14 97.3(18) . .
Ag3 C25 Ag14 108.7(10) . .
C26 C25 Ag12 110.7(18) . .
Ag3 C25 Ag12 80.2(8) . .
Ag14 C25 Ag12 83.0(8) . .
C26 C25 Ag2 94.5(17) . .
Ag3 C25 Ag2 82.2(8) . .
Ag14 C25 Ag2 82.6(7) . .
Ag12 C25 Ag2 152.3(10) . .
C25 C26 C27 176(3) . .
C25 C26 Ag14 55.9(14) . .
C27 C26 Ag14 128(2) . .
C26 C27 C28 108(3) . .
C26 C27 C30 108(3) . .
C28 C27 C30 107(3) . .
C26 C27 C29 107(2) . .
C28 C27 C29 112(3) . .
C30 C27 C29 114(3) . .
C27 C28 H28A 109.5 . .
C27 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C27 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
C27 C29 H29A 109.5 . .
C27 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
C27 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
C27 C30 H30A 109.5 . .
C27 C30 H30B 109.5 . .
H30A C30 H30B 109.5 . .
C27 C30 H30C 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
C32 C31 Ag8 152(2) . .
C32 C31 Ag18 94.2(17) . .
Ag8 C31 Ag18 99.2(10) . .
C32 C31 Ag13 119(2) . .
Ag8 C31 Ag13 86.9(9) . .
Ag18 C31 Ag13 85.5(9) . .
C31 C32 C33 176(3) . .
C31 C32 Ag18 58.3(15) . .
C33 C32 Ag18 124.5(17) . .
C34 C33 C36 108(3) . .
C34 C33 C35 111(3) . .
C36 C33 C35 112(3) . .
C34 C33 C32 112(2) . .
C36 C33 C32 108(2) . .
C35 C33 C32 105(2) . .
C33 C34 H34A 109.5 . .
C33 C34 H34B 109.5 . .
H34A C34 H34B 109.5 . .
C33 C34 H34C 109.5 . .
H34A C34 H34C 109.5 . .
H34B C34 H34C 109.5 . .
C33 C35 H35A 109.5 . .
C33 C35 H35B 109.5 . .
H35A C35 H35B 109.5 . .
C33 C35 H35C 109.5 . .
H35A C35 H35C 109.5 . .
H35B C35 H35C 109.5 . .
C33 C36 H36A 109.5 . .
C33 C36 H36B 109.5 . .
H36A C36 H36B 109.5 . .
C33 C36 H36C 109.5 . .
H36A C36 H36C 109.5 . .
H36B C36 H36C 109.5 . .
C38 C37 Ag3 153(2) . .
C38 C37 Ag9 92.8(16) . 3_656
Ag3 C37 Ag9 111.6(10) . 3_656
C38 C37 Ag10 119(2) . .
Ag3 C37 Ag10 78.3(8) . .
Ag9 C37 Ag10 79.1(7) 3_656 .
C38 C37 Ag15 90.5(17) . .
Ag3 C37 Ag15 82.3(8) . .
Ag9 C37 Ag15 81.4(7) 3_656 .
Ag10 C37 Ag15 144.9(10) . .
C37 C38 C39 173(2) . .
C37 C38 Ag9 60.8(13) . 3_656
C39 C38 Ag9 126.0(12) . 3_656
C41 C39 C38 108.6(17) . .
C41 C39 C42 111.5(14) . .
C38 C39 C42 107.3(18) . .
C41 C39 C40 110.4(15) . .
C38 C39 C40 109.5(17) . .
C42 C39 C40 109.5(14) . .
C39 C40 H40A 109.5 . .
C39 C40 H40B 109.5 . .
H40A C40 H40B 109.5 . .
C39 C40 H40C 109.5 . .
H40A C40 H40C 109.5 . .
H40B C40 H40C 109.5 . .
C39 C41 H41A 109.5 . .
C39 C41 H41B 109.5 . .
H41A C41 H41B 109.5 . .
C39 C41 H41C 109.5 . .
H41A C41 H41C 109.5 . .
H41B C41 H41C 109.5 . .
C39 C42 H42A 109.5 . .
C39 C42 H42B 109.5 . .
H42A C42 H42B 109.5 . .
C39 C42 H42C 109.5 . .
H42A C42 H42C 109.5 . .
H42B C42 H42C 109.5 . .
C44 C43 Ag11 176(2) . 3_656
C44 C43 Ag6 84.5(15) . .
Ag11 C43 Ag6 91.6(8) 3_656 .
C44 C43 Ag1 84.3(16) . .
Ag11 C43 Ag1 96.5(8) 3_656 .
Ag6 C43 Ag1 105.3(8) . .
C43 C44 C45 168(2) . .
C43 C44 Ag6 67.7(14) . .
C45 C44 Ag6 118.0(14) . .
C43 C44 Ag1 68.2(15) . .
C45 C44 Ag1 119.8(14) . .
Ag6 C44 Ag1 95.5(7) . .
C46 C45 C47 112.5(14) . .
C46 C45 C44 107(2) . .
C47 C45 C44 108(2) . .
C46 C45 C48 111.9(14) . .
C47 C45 C48 111.5(15) . .
C44 C45 C48 105.5(18) . .
C45 C46 H46A 109.5 . .
C45 C46 H46B 109.5 . .
H46A C46 H46B 109.5 . .
C45 C46 H46C 109.5 . .
H46A C46 H46C 109.5 . .
H46B C46 H46C 109.5 . .
C45 C47 H47A 109.5 . .
C45 C47 H47B 109.5 . .
H47A C47 H47B 109.5 . .
C45 C47 H47C 109.5 . .
H47A C47 H47C 109.5 . .
H47B C47 H47C 109.5 . .
C45 C48 H48A 109.5 . .
C45 C48 H48B 109.5 . .
H48A C48 H48B 109.5 . .
C45 C48 H48C 109.5 . .
H48A C48 H48C 109.5 . .
H48B C48 H48C 109.5 . .
C50 C49 Ag14 145(2) . .
C50 C49 Ag9 113(2) . .
Ag14 C49 Ag9 102.2(9) . .
C50 C49 Ag17 98.6(17) . .
Ag14 C49 Ag17 81.4(7) . .
Ag9 C49 Ag17 80.6(7) . .
C50 C49 Ag16 112.5(17) . .
Ag14 C49 Ag16 79.3(8) . .
Ag9 C49 Ag16 77.9(7) . .
Ag17 C49 Ag16 147.2(10) . .
C49 C50 C51 173(3) . .
C50 C51 C53 112(2) . .
C50 C51 C54 107(2) . .
C53 C51 C54 106(3) . .
C50 C51 C52 108(2) . .
C53 C51 C52 112(2) . .
C54 C51 C52 111(2) . .
C51 C52 H52A 109.5 . .
C51 C52 H52B 109.5 . .
H52A C52 H52B 109.5 . .
C51 C52 H52C 109.5 . .
H52A C52 H52C 109.5 . .
H52B C52 H52C 109.5 . .
C51 C53 H53A 109.5 . .
C51 C53 H53B 109.5 . .
H53A C53 H53B 109.5 . .
C51 C53 H53C 109.5 . .
H53A C53 H53C 109.5 . .
H53B C53 H53C 109.5 . .
C51 C54 H54A 109.5 . .
C51 C54 H54B 109.5 . .
H54A C54 H54B 109.5 . .
C51 C54 H54C 109.5 . .
H54A C54 H54C 109.5 . .
H54B C54 H54C 109.5 . .
C56 C55 Ag4 163(3) . .
C56 C55 Ag20 97(2) . .
Ag4 C55 Ag20 90.6(9) . .
C56 C55 Ag7 102(2) . .
Ag4 C55 Ag7 92.7(10) . .
Ag20 C55 Ag7 88.3(9) . .
C55 C56 C57 172(3) . .
C55 C56 Ag20 56.5(17) . .
C57 C56 Ag20 132(2) . .
C58 C57 C56 113(3) . .
C58 C57 C60 114(3) . .
C56 C57 C60 106(3) . .
C58 C57 C59 108(3) . .
C56 C57 C59 107(3) . .
C60 C57 C59 109(3) . .
C57 C58 H58A 109.5 . .
C57 C58 H58B 109.5 . .
H58A C58 H58B 109.5 . .
C57 C58 H58C 109.5 . .
H58A C58 H58C 109.5 . .
H58B C58 H58C 109.5 . .
C57 C59 H59A 109.5 . .
C57 C59 H59B 109.5 . .
H59A C59 H59B 109.5 . .
C57 C59 H59C 109.5 . .
H59A C59 H59C 109.5 . .
H59B C59 H59C 109.5 . .
C57 C60 H60A 109.5 . .
C57 C60 H60B 109.5 . .
H60A C60 H60B 109.5 . .
C57 C60 H60C 109.5 . .
H60A C60 H60C 109.5 . .
H60B C60 H60C 109.5 . .
C64 C61 C63 111(2) . .
C64 C61 C62 109(2) . .
C63 C61 C62 110(2) . .
C64 C61 P1 110.0(19) . .
C63 C61 P1 109.2(18) . .
C62 C61 P1 107.7(17) . .
C61 C62 H62A 109.5 . .
C61 C62 H62B 109.5 . .
H62A C62 H62B 109.5 . .
C61 C62 H62C 109.5 . .
H62A C62 H62C 109.5 . .
H62B C62 H62C 109.5 . .
C61 C63 H63A 109.5 . .
C61 C63 H63B 109.5 . .
H63A C63 H63B 109.5 . .
C61 C63 H63C 109.5 . .
H63A C63 H63C 109.5 . .
H63B C63 H63C 109.5 . .
C61 C64 H64A 109.5 . .
C61 C64 H64B 109.5 . .
H64A C64 H64B 109.5 . .
C61 C64 H64C 109.5 . .
H64A C64 H64C 109.5 . .
H64B C64 H64C 109.5 . .
C68 C65 C67 106(3) . .
C68 C65 C66 115(3) . .
C67 C65 C66 108(3) . .
C68 C65 P2 110(2) . .
C67 C65 P2 106(2) . .
C66 C65 P2 110.7(18) . .
C65 C66 H66A 109.5 . .
C65 C66 H66B 109.5 . .
H66A C66 H66B 109.5 . .
C65 C66 H66C 109.5 . .
H66A C66 H66C 109.5 . .
H66B C66 H66C 109.5 . .
C65 C67 H67A 109.5 . .
C65 C67 H67B 109.5 . .
H67A C67 H67B 109.5 . .
C65 C67 H67C 109.5 . .
H67A C67 H67C 109.5 . .
H67B C67 H67C 109.5 . .
C65 C68 H68A 109.5 . .
C65 C68 H68B 109.5 . .
H68A C68 H68B 109.5 . .
C65 C68 H68C 109.5 . .
H68A C68 H68C 109.5 . .
H68B C68 H68C 109.5 . .
O9 C69 C70 131(3) . .
O9 C69 C72 119(3) . .
C70 C69 C72 111(3) . .
C71 C70 C69 121(2) . .
C71 C70 H70 119.7 . .
C69 C70 H70 119.7 . .
O10 C71 C70 129(3) . .
O10 C71 C73 114(3) . .
C70 C71 C73 117(2) . .
F7 C72 F8 112(4) . .
F7 C72 F9 106(4) . .
F8 C72 F9 98(3) . .
F7 C72 C69 115(3) . .
F8 C72 C69 117(3) . .
F9 C72 C69 107(3) . .
F10 C73 F11 107(2) . .
F10 C73 F12 108(3) . .
F11 C73 F12 106(3) . .
F10 C73 C71 117(3) . .
F11 C73 C71 110(2) . .
F12 C73 C71 109(2) . .
O7 C74 C77 117(3) . .
O7 C74 C75 130(3) . .
C77 C74 C75 113(3) . .
C74 C75 C76 120(4) . .
C74 C75 H75 120.2 . .
C76 C75 H75 120.2 . .
O8 C76 C75 134(4) . .
O8 C76 C78 112(4) . .
C75 C76 C78 114(4) . .
F3 C78 F2 107(2) . .
F3 C78 F1 105(2) . .
F2 C78 F1 106(2) . .
F3 C78 C76 109(3) . .
F2 C78 C76 116(3) . .
F1 C78 C76 113(4) . .
F5 C77 F6 99(2) . .
F5 C77 F4 97(2) . .
F6 C77 F4 97(2) . .
F5 C77 C74 124(3) . .
F6 C77 C74 117(3) . .
F4 C77 C74 117(3) . .
C80 C79 Ag17 136(2) . 3_656
C80 C79 Ag15 133(2) . .
Ag17 C79 Ag15 82.0(8) 3_656 .
C80 C79 Ag6 120(2) . .
Ag17 C79 Ag6 82.8(7) 3_656 .
Ag15 C79 Ag6 85.4(9) . .
C79 C80 C81 177(3) . .
C80 C81 C82 110(2) . .
C80 C81 C83 112(2) . .
C82 C81 C83 108(3) . .
C80 C81 C84 109(2) . .
C82 C81 C84 109(3) . .
C83 C81 C84 109(3) . .
C81 C82 H82A 109.5 . .
C81 C82 H82B 109.5 . .
H82A C82 H82B 109.5 . .
C81 C82 H82C 109.5 . .
H82A C82 H82C 109.5 . .
H82B C82 H82C 109.5 . .
C81 C83 H83A 109.5 . .
C81 C83 H83B 109.5 . .
H83A C83 H83B 109.5 . .
C81 C83 H83C 109.5 . .
H83A C83 H83C 109.5 . .
H83B C83 H83C 109.5 . .
C81 C84 H84A 109.5 . .
C81 C84 H84B 109.5 . .
H84A C84 H84B 109.5 . .
C81 C84 H84C 109.5 . .
H84A C84 H84C 109.5 . .
H84B C84 H84C 109.5 . .
O11 C85 O12 137(4) . .
O11 C85 C86 112(4) . .
O12 C85 C86 111(4) . .
F13 C86 F15 103(2) . .
F13 C86 F14 103.2(19) . .
F15 C86 F14 102.7(19) . .
F13 C86 C85 112(2) . .
F15 C86 C85 117(3) . .
F14 C86 C85 116(3) . .
P1 O1 Ag5 128.9(9) . .
P1 O1 Ag6 129.4(8) . 3_656
Ag5 O1 Ag6 96.7(6) . 3_656
P1 O2 Ag8 121.1(9) . .
P1 O2 Ag12 101.4(8) . .
Ag8 O2 Ag12 108.9(6) . .
P1 O3 Ag17 122.0(9) . .
P2 O4 Ag19 121.4(11) . .
P2 O4 Ag10 110.1(9) . .
Ag19 O4 Ag10 102.6(7) . .
P2 O5 Ag16 116.9(10) . 3_656
P2 O5 Ag9 137.1(10) . 3_656
Ag16 O5 Ag9 74.1(5) 3_656 3_656
P2 O6 Ag20 133.0(12) . .
C74 O7 Ag7 134(2) . .
C76 O8 Ag7 128(2) . .
C69 O9 Ag13 129(2) . .
C71 O10 Ag13 135(2) . .
C85 O11 Ag15 130(3) . .
C85 O12 Ag2 138(4) . .
V1 O13 Ag2 121.4(10) . 3_656
V1 O13 Ag15 121.3(9) . 3_656
Ag2 O13 Ag15 114.8(8) 3_656 3_656
V1 O14 Ag10 117.9(10) . .
V1 O15 Ag12 126.2(9) . .
O2 P1 O3 110.8(10) . .
O2 P1 O1 112.3(10) . .
O3 P1 O1 111.2(9) . .
O2 P1 C61 108.9(11) . .
O3 P1 C61 106.2(11) . .
O1 P1 C61 107.3(11) . .
O6 P2 O4 110.7(12) . .
O6 P2 O5 110.7(10) . .
O4 P2 O5 111.1(10) . .
O6 P2 C65 108.8(13) . .
O4 P2 C65 106.6(12) . .
O5 P2 C65 108.9(11) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C1 2.11(3) .
Ag1 C43 2.38(2) .
Ag1 C44 2.55(2) .
Ag1 Ag16 2.969(3) .
Ag1 Ag2 2.981(3) .
Ag1 Ag20 3.181(3) 3_656
Ag1 Ag11 3.340(3) 3_656
Ag2 C1 2.15(2) .
Ag2 O12 2.31(3) .
Ag2 O13 2.399(17) 3_656
Ag2 C25 2.52(2) .
Ag2 Ag3 3.081(3) .
Ag2 Ag14 3.142(3) .
Ag2 Ag16 3.167(3) .
Ag3 C37 2.12(2) .
Ag3 C25 2.15(2) .
Ag3 Ag10 2.834(3) .
Ag3 Ag12 2.913(2) .
Ag3 Ag15 3.084(2) .
Ag4 C55 2.11(3) .
Ag4 C8 2.23(2) .
Ag4 C7 2.49(3) .
Ag4 Ag20 3.070(4) .
Ag4 Ag7 3.196(4) .
Ag4 Ag5 3.259(3) .
Ag5 C8 2.01(2) .
Ag5 O1 2.076(16) .
Ag5 Ag13 2.888(3) .
Ag5 Ag8 3.105(3) .
Ag5 Ag11 3.235(3) .
Ag6 C79 2.27(2) .
Ag6 C43 2.35(2) .
Ag6 O1 2.452(15) 3_656
Ag6 C44 2.52(2) .
Ag6 Ag17 2.939(3) 3_656
Ag6 Ag15 3.077(2) .
Ag6 Ag11 3.186(2) 3_656
Ag7 C13 2.26(3) .
Ag7 C55 2.30(3) .
Ag7 O7 2.428(19) .
Ag7 O8 2.46(3) .
Ag7 C14 2.64(3) .
Ag7 Ag20 3.137(4) .
Ag8 C31 2.03(2) .
Ag8 O2 2.136(15) .
Ag8 Ag13 2.938(3) .
Ag8 Ag18 3.244(3) .
Ag9 C49 2.22(2) .
Ag9 C37 2.26(2) 3_656
Ag9 O5 2.530(18) 3_656
Ag9 C38 2.589(18) 3_656
Ag9 Ag16 2.919(3) .
Ag9 Ag10 2.941(3) 3_656
Ag9 Ag17 2.962(3) .
Ag9 Ag15 3.139(3) 3_656
Ag10 O4 2.299(17) .
Ag10 C37 2.36(2) .
Ag10 C19 2.47(2) .
Ag10 O14 2.493(18) .
Ag10 C20 2.70(2) .
Ag10 Ag9 2.941(3) 3_656
Ag10 Ag12 3.147(3) .
Ag10 Ag11 3.205(3) .
Ag11 C19 2.07(2) .
Ag11 C43 2.092(19) 3_656
Ag11 Ag19 2.984(3) .
Ag11 Ag12 3.165(3) .
Ag11 Ag6 3.186(2) 3_656
Ag11 Ag20 3.238(4) .
Ag11 Ag1 3.340(3) 3_656
Ag12 C25 2.37(2) .
Ag12 C19 2.40(2) .
Ag12 O2 2.418(16) .
Ag12 O15 2.458(16) .
Ag12 Ag14 3.043(3) .
Ag13 C31 2.23(3) .
Ag13 C8 2.26(3) .
Ag13 O10 2.381(19) .
Ag13 O9 2.47(2) .
Ag13 Ag18 3.025(3) .
Ag14 C49 2.14(2) .
Ag14 C25 2.22(2) .
Ag14 C26 2.66(2) .
Ag14 Ag16 2.914(3) .
Ag14 Ag17 2.940(3) .
Ag15 C79 2.27(2) .
Ag15 O11 2.35(3) .
Ag15 O13 2.42(2) 3_656
Ag15 C37 2.54(2) .
Ag15 Ag17 2.910(3) 3_656
Ag15 Ag9 3.139(3) 3_656
Ag16 C1 2.25(3) .
Ag16 O5 2.307(17) 3_656
Ag16 C49 2.41(2) .
Ag16 C2 2.69(3) .
Ag17 C79 2.17(2) 3_656
Ag17 O3 2.298(15) .
Ag17 C49 2.36(2) .
Ag17 Ag15 2.910(3) 3_656
Ag17 Ag6 2.939(3) 3_656
Ag18 C13 2.16(3) .
Ag18 C31 2.22(2) .
Ag18 O1W 2.473(18) .
Ag18 C32 2.61(2) .
Ag18 Ag19 2.842(3) .
Ag19 C13 2.09(3) .
Ag19 O4 2.273(18) .
Ag19 C19 2.49(2) .
Ag19 Ag20 3.071(4) .
Ag20 O6 2.084(17) .
Ag20 C55 2.20(2) .
Ag20 C56 2.62(3) .
Ag20 Ag1 3.181(3) 3_656
V1 O15 1.642(16) .
V1 O13 1.67(2) .
V1 O14 1.68(2) .
V1 O16 1.84(4) .
C1 C2 1.24(4) .
C2 C3 1.54(4) .
C3 C6 1.50(4) .
C3 C4 1.54(4) .
C3 C5 1.54(4) .
C4 H4A 0.9800 .
C4 H4B 0.9800 .
C4 H4C 0.9800 .
C5 H5A 0.9800 .
C5 H5B 0.9800 .
C5 H5C 0.9800 .
C6 H6A 0.9800 .
C6 H6B 0.9800 .
C6 H6C 0.9800 .
C7 C8 1.25(3) .
C7 C9 1.45(3) .
C9 C12 1.54(5) .
C9 C10 1.56(5) .
C9 C11 1.59(4) .
C10 H10A 0.9800 .
C10 H10B 0.9800 .
C10 H10C 0.9800 .
C11 H11A 0.9800 .
C11 H11B 0.9800 .
C11 H11C 0.9800 .
C12 H12A 0.9800 .
C12 H12B 0.9800 .
C12 H12C 0.9800 .
C13 C14 1.24(3) .
C14 C15 1.51(4) .
C15 C16 1.48(5) .
C15 C18 1.53(5) .
C15 C17 1.59(4) .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C17 H17A 0.9800 .
C17 H17B 0.9800 .
C17 H17C 0.9800 .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 C20 1.24(3) .
C20 C21 1.515(17) .
C21 C22A 1.522(19) .
C21 C22B 1.53(2) .
C21 C23A 1.531(19) .
C21 C24A 1.540(19) .
C21 C23B 1.54(2) .
C21 C24B 1.54(2) .
C22A H22A 0.9800 .
C22A H22B 0.9800 .
C22A H22C 0.9800 .
C23A H23A 0.9800 .
C23A H23B 0.9800 .
C23A H23C 0.9800 .
C24A H24A 0.9800 .
C24A H24B 0.9800 .
C24A H24C 0.9800 .
C22B H22D 0.9800 .
C22B H22E 0.9800 .
C22B H22F 0.9800 .
C23B H23D 0.9800 .
C23B H23E 0.9800 .
C23B H23F 0.9800 .
C24B H24D 0.9800 .
C24B H24E 0.9800 .
C24B H24F 0.9800 .
C25 C26 1.21(3) .
C26 C27 1.44(4) .
C27 C28 1.52(4) .
C27 C30 1.55(4) .
C27 C29 1.56(4) .
C28 H28A 0.9800 .
C28 H28B 0.9800 .
C28 H28C 0.9800 .
C29 H29A 0.9800 .
C29 H29B 0.9800 .
C29 H29C 0.9800 .
C30 H30A 0.9800 .
C30 H30B 0.9800 .
C30 H30C 0.9800 .
C31 C32 1.21(3) .
C32 C33 1.57(4) .
C33 C34 1.47(4) .
C33 C36 1.50(4) .
C33 C35 1.51(4) .
C34 H34A 0.9800 .
C34 H34B 0.9800 .
C34 H34C 0.9800 .
C35 H35A 0.9800 .
C35 H35B 0.9800 .
C35 H35C 0.9800 .
C36 H36A 0.9800 .
C36 H36B 0.9800 .
C36 H36C 0.9800 .
C37 C38 1.15(3) .
C37 Ag9 2.26(2) 3_656
C38 C39 1.526(17) .
C38 Ag9 2.589(18) 3_656
C39 C41 1.522(18) .
C39 C42 1.534(18) .
C39 C40 1.549(18) .
C40 H40A 0.9800 .
C40 H40B 0.9800 .
C40 H40C 0.9800 .
C41 H41A 0.9800 .
C41 H41B 0.9800 .
C41 H41C 0.9800 .
C42 H42A 0.9800 .
C42 H42B 0.9800 .
C42 H42C 0.9800 .
C43 C44 1.184(17) .
C43 Ag11 2.092(19) 3_656
C44 C45 1.530(17) .
C45 C46 1.519(18) .
C45 C47 1.527(18) .
C45 C48 1.538(18) .
C46 H46A 0.9800 .
C46 H46B 0.9800 .
C46 H46C 0.9800 .
C47 H47A 0.9800 .
C47 H47B 0.9800 .
C47 H47C 0.9800 .
C48 H48A 0.9800 .
C48 H48B 0.9800 .
C48 H48C 0.9800 .
C49 C50 1.23(3) .
C50 C51 1.45(3) .
C51 C53 1.52(4) .
C51 C54 1.55(4) .
C51 C52 1.56(4) .
C52 H52A 0.9800 .
C52 H52B 0.9800 .
C52 H52C 0.9800 .
C53 H53A 0.9800 .
C53 H53B 0.9800 .
C53 H53C 0.9800 .
C54 H54A 0.9800 .
C54 H54B 0.9800 .
C54 H54C 0.9800 .
C55 C56 1.19(4) .
C56 C57 1.50(4) .
C57 C58 1.44(5) .
C57 C60 1.55(5) .
C57 C59 1.59(5) .
C58 H58A 0.9800 .
C58 H58B 0.9800 .
C58 H58C 0.9800 .
C59 H59A 0.9800 .
C59 H59B 0.9800 .
C59 H59C 0.9800 .
C60 H60A 0.9800 .
C60 H60B 0.9800 .
C60 H60C 0.9800 .
C61 C64 1.53(4) .
C61 C63 1.54(4) .
C61 C62 1.56(4) .
C61 P1 1.83(2) .
C62 H62A 0.9800 .
C62 H62B 0.9800 .
C62 H62C 0.9800 .
C63 H63A 0.9800 .
C63 H63B 0.9800 .
C63 H63C 0.9800 .
C64 H64A 0.9800 .
C64 H64B 0.9800 .
C64 H64C 0.9800 .
C65 C68 1.50(4) .
C65 C67 1.52(4) .
C65 C66 1.53(4) .
C65 P2 1.85(3) .
C66 H66A 0.9800 .
C66 H66B 0.9800 .
C66 H66C 0.9800 .
C67 H67A 0.9800 .
C67 H67B 0.9800 .
C67 H67C 0.9800 .
C68 H68A 0.9800 .
C68 H68B 0.9800 .
C68 H68C 0.9800 .
C69 O9 1.17(3) .
C69 C70 1.50(4) .
C69 C72 1.55(4) .
C70 C71 1.40(4) .
C70 H70 0.9500 .
C71 O10 1.17(3) .
C71 C73 1.52(4) .
C72 F7 1.17(4) .
C72 F8 1.32(4) .
C72 F9 1.35(4) .
C73 F10 1.30(3) .
C73 F11 1.33(3) .
C73 F12 1.34(3) .
C74 O7 1.22(4) .
C74 C77 1.40(4) .
C74 C75 1.40(5) .
C75 C76 1.42(6) .
C75 H75 0.9500 .
C76 O8 1.24(5) .
C76 C78 1.55(6) .
C78 F3 1.319(19) .
C78 F2 1.33(2) .
C78 F1 1.342(19) .
C77 F5 1.319(19) .
C77 F6 1.327(19) .
C77 F4 1.339(19) .
C79 C80 1.12(3) .
C79 Ag17 2.17(2) 3_656
C80 C81 1.50(3) .
C81 C82 1.51(4) .
C81 C83 1.53(4) .
C81 C84 1.55(4) .
C82 H82A 0.9800 .
C82 H82B 0.9800 .
C82 H82C 0.9800 .
C83 H83A 0.9800 .
C83 H83B 0.9800 .
C83 H83C 0.9800 .
C84 H84A 0.9800 .
C84 H84B 0.9800 .
C84 H84C 0.9800 .
C85 O11 1.19(5) .
C85 O12 1.20(6) .
C85 C86 1.523(19) .
C86 F13 1.317(19) .
C86 F15 1.325(19) .
C86 F14 1.328(19) .
O1 P1 1.545(17) .
O1 Ag6 2.452(15) 3_656
O2 P1 1.537(17) .
O3 P1 1.539(16) .
O4 P2 1.532(19) .
O5 P2 1.548(17) .
O5 Ag16 2.307(17) 3_656
O5 Ag9 2.530(18) 3_656
O6 P2 1.53(2) .
O13 Ag2 2.399(17) 3_656
O13 Ag15 2.42(2) 3_656
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Ag1 C1 C2 Ag16 -91(3) . .
Ag2 C1 C2 Ag16 99(3) . .
Ag16 C2 C3 C6 107(3) . .
Ag16 C2 C3 C4 -132(2) . .
Ag16 C2 C3 C5 -13(4) . .
Ag4 C7 C8 Ag5 -111(6) . .
Ag4 C7 C8 Ag13 107.1(17) . .
Ag4 C7 C9 C12 68(3) . .
Ag4 C7 C9 C10 -171(2) . .
Ag4 C7 C9 C11 -52(4) . .
Ag19 C13 C14 Ag7 126(4) . .
Ag18 C13 C14 Ag7 -105(2) . .
Ag7 C14 C15 C16 171(2) . .
Ag7 C14 C15 C18 -66(3) . .
Ag7 C14 C15 C17 51(3) . .
Ag12 C19 C20 Ag10 80.3(7) . .
Ag19 C19 C20 Ag10 -91.6(8) . .
Ag10 C20 C21 C22A -38(2) . .
Ag10 C20 C21 C22B -101(3) . .
Ag10 C20 C21 C23A -159.8(17) . .
Ag10 C20 C21 C24A 82(2) . .
Ag10 C20 C21 C23B 137(3) . .
Ag10 C20 C21 C24B 18(3) . .
Ag3 C25 C26 Ag14 -165(5) . .
Ag12 C25 C26 Ag14 85.2(13) . .
Ag2 C25 C26 Ag14 -83.1(9) . .
Ag14 C26 C27 C28 8(3) . .
Ag14 C26 C27 C30 -108(3) . .
Ag14 C26 C27 C29 129(3) . .
Ag8 C31 C32 Ag18 118(4) . .
Ag13 C31 C32 Ag18 -87.1(16) . .
Ag18 C32 C33 C34 38(3) . .
Ag18 C32 C33 C36 -81(3) . .
Ag18 C32 C33 C35 158.9(18) . .
Ag3 C37 C38 Ag9 155(5) . 3_656
Ag10 C37 C38 Ag9 -79.0(14) . 3_656
Ag15 C37 C38 Ag9 81.4(7) . 3_656
Ag9 C38 C39 C41 176.2(16) 3_656 .
Ag9 C38 C39 C42 56(2) 3_656 .
Ag9 C38 C39 C40 -63(2) 3_656 .
Ag6 C43 C44 C45 -121(12) . .
Ag1 C43 C44 C45 133(12) . .
Ag1 C43 C44 Ag6 -106.1(7) . .
Ag6 C43 C44 Ag1 106.1(7) . .
C43 C44 C45 C46 -72(12) . .
Ag6 C44 C45 C46 172.0(14) . .
Ag1 C44 C45 C46 56.5(19) . .
C43 C44 C45 C47 49(12) . .
Ag6 C44 C45 C47 -66.7(19) . .
Ag1 C44 C45 C47 177.8(14) . .
C43 C44 C45 C48 168(11) . .
Ag6 C44 C45 C48 52.5(19) . .
Ag1 C44 C45 C48 -63.0(19) . .
Ag4 C55 C56 Ag20 -116(8) . .
Ag7 C55 C56 Ag20 89.8(13) . .
Ag20 C56 C57 C58 -165(2) . .
Ag20 C56 C57 C60 -39(4) . .
Ag20 C56 C57 C59 77(4) . .
O9 C69 C70 C71 -6(5) . .
C72 C69 C70 C71 174(3) . .
C69 C70 C71 O10 4(5) . .
C69 C70 C71 C73 -179(2) . .
O9 C69 C72 F7 73(5) . .
C70 C69 C72 F7 -107(4) . .
O9 C69 C72 F8 -153(3) . .
C70 C69 C72 F8 27(4) . .
O9 C69 C72 F9 -44(5) . .
C70 C69 C72 F9 135(3) . .
O10 C71 C73 F10 171(3) . .
C70 C71 C73 F10 -7(4) . .
O10 C71 C73 F11 -67(3) . .
C70 C71 C73 F11 115(3) . .
O10 C71 C73 F12 49(4) . .
C70 C71 C73 F12 -129(3) . .
O7 C74 C75 C76 -1(6) . .
C77 C74 C75 C76 178(3) . .
C74 C75 C76 O8 1(8) . .
C74 C75 C76 C78 -177(3) . .
O8 C76 C78 F3 55(5) . .
C75 C76 C78 F3 -126(4) . .
O8 C76 C78 F2 176(4) . .
C75 C76 C78 F2 -5(5) . .
O8 C76 C78 F1 -62(5) . .
C75 C76 C78 F1 117(4) . .
O7 C74 C77 F5 167(3) . .
C75 C74 C77 F5 -12(5) . .
O7 C74 C77 F6 43(4) . .
C75 C74 C77 F6 -136(3) . .
O7 C74 C77 F4 -71(4) . .
C75 C74 C77 F4 109(4) . .
O11 C85 C86 F13 89(4) . .
O12 C85 C86 F13 -93(4) . .
O11 C85 C86 F15 -30(5) . .
O12 C85 C86 F15 147(4) . .
O11 C85 C86 F14 -152(3) . .
O12 C85 C86 F14 25(5) . .
C77 C74 O7 Ag7 -179(2) . .
C75 C74 O7 Ag7 0(5) . .
C75 C76 O8 Ag7 -1(8) . .
C78 C76 O8 Ag7 178(2) . .
C70 C69 O9 Ag13 -1(5) . .
C72 C69 O9 Ag13 178(2) . .
C70 C71 O10 Ag13 7(5) . .
C73 C71 O10 Ag13 -171(2) . .
O12 C85 O11 Ag15 21(9) . .
C86 C85 O11 Ag15 -163(2) . .
O11 C85 O12 Ag2 -22(10) . .
C86 C85 O12 Ag2 161(3) . .
O15 V1 O13 Ag2 156.6(12) . 3_656
O14 V1 O13 Ag2 38.7(16) . 3_656
O16 V1 O13 Ag2 -100.0(18) . 3_656
O15 V1 O13 Ag15 -42.4(15) . 3_656
O14 V1 O13 Ag15 -160.3(12) . 3_656
O16 V1 O13 Ag15 61(2) . 3_656
O15 V1 O14 Ag10 44.3(17) . .
O13 V1 O14 Ag10 162.1(12) . .
O16 V1 O14 Ag10 -63(2) . .
O13 V1 O15 Ag12 -166.3(13) . .
O14 V1 O15 Ag12 -48.7(19) . .
O16 V1 O15 Ag12 77(2) . .
Ag8 O2 P1 O3 162.5(9) . .
Ag12 O2 P1 O3 42.0(10) . .
Ag8 O2 P1 O1 37.4(14) . .
Ag12 O2 P1 O1 -83.1(9) . .
Ag8 O2 P1 C61 -81.1(14) . .
Ag12 O2 P1 C61 158.3(10) . .
Ag17 O3 P1 O2 -136.6(11) . .
Ag17 O3 P1 O1 -11.0(15) . .
Ag17 O3 P1 C61 105.4(13) . .
Ag5 O1 P1 O2 -44.4(15) . .
Ag6 O1 P1 O2 104.5(13) 3_656 .
Ag5 O1 P1 O3 -169.2(12) . .
Ag6 O1 P1 O3 -20.3(16) 3_656 .
Ag5 O1 P1 C61 75.2(16) . .
Ag6 O1 P1 C61 -136.0(13) 3_656 .
C64 C61 P1 O2 63(2) . .
C63 C61 P1 O2 -59(2) . .
C62 C61 P1 O2 -178.7(18) . .
C64 C61 P1 O3 -177.9(18) . .
C63 C61 P1 O3 60(2) . .
C62 C61 P1 O3 -59(2) . .
C64 C61 P1 O1 -59(2) . .
C63 C61 P1 O1 179.1(17) . .
C62 C61 P1 O1 60(2) . .
Ag20 O6 P2 O4 39(2) . .
Ag20 O6 P2 O5 162.8(15) . .
Ag20 O6 P2 C65 -78(2) . .
Ag19 O4 P2 O6 -32.8(15) . .
Ag10 O4 P2 O6 86.9(12) . .
Ag19 O4 P2 O5 -156.2(10) . .
Ag10 O4 P2 O5 -36.4(14) . .
Ag19 O4 P2 C65 85.4(14) . .
Ag10 O4 P2 C65 -154.9(11) . .
Ag16 O5 P2 O6 -2.9(15) 3_656 .
Ag9 O5 P2 O6 -98.3(17) 3_656 .
Ag16 O5 P2 O4 120.5(12) 3_656 .
Ag9 O5 P2 O4 25.2(19) 3_656 .
Ag16 O5 P2 C65 -122.4(13) 3_656 .
Ag9 O5 P2 C65 142.2(16) 3_656 .
C68 C65 P2 O6 -178(2) . .
C67 C65 P2 O6 -64(2) . .
C66 C65 P2 O6 53(2) . .
C68 C65 P2 O4 62(3) . .
C67 C65 P2 O4 176(2) . .
C66 C65 P2 O4 -67(2) . .
C68 C65 P2 O5 -58(3) . .
C67 C65 P2 O5 56(2) . .
C66 C65 P2 O5 174(2) . .
