#------------------------------------------------------------------------------
#$Date: 2019-11-17 08:32:23 +0200 (Sun, 17 Nov 2019) $
#$Revision: 228875 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/09/7230980.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7230980
loop_
_publ_author_name
'Kyratzis, Nicholas'
'Cao, Winnie'
'Izgorodina, Ekaterina I.'
'Turner, David R.'
_publ_section_title
;
 Structural changes in coordination polymers in response to small changes
 in steric bulk (H vs. Me): an experimental and theoretical study
;
_journal_issue                   29
_journal_name_full               CrystEngComm
_journal_page_first              4115
_journal_paper_doi               10.1039/C8CE00744F
_journal_volume                  20
_journal_year                    2018
_chemical_formula_moiety         'C30 H18 N4 O8 Zn'
_chemical_formula_sum            'C30 H18 N4 O8 Zn'
_chemical_formula_weight         627.85
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_date             2018-02-14
_audit_creation_method
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_audit_update_record
;
2018-04-30 deposited with the CCDC.
2018-06-21 downloaded from the CCDC.
;
_cell_angle_alpha                109.91(3)
_cell_angle_beta                 106.20(3)
_cell_angle_gamma                99.92(3)
_cell_formula_units_Z            2
_cell_length_a                   9.6690(19)
_cell_length_b                   13.649(3)
_cell_length_c                   14.082(3)
_cell_measurement_reflns_used    60793
_cell_measurement_temperature    100
_cell_measurement_theta_max      32.233
_cell_measurement_theta_min      1.652
_cell_volume                     1602.8(9)
_computing_cell_refinement       'XDS (Kabsch, 1993)'
_computing_data_collection       'BluIce (McPhillips, 2002)'
_computing_data_reduction        'XDS (Kabsch, 1993)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SIR2004 (Burla et al., 2007)'
_diffrn_ambient_temperature      100.0
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'ADSC Quantum 210r'
_diffrn_measurement_method       'Phi Scan'
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.7108
_diffrn_reflns_av_R_equivalents  0.1879
_diffrn_reflns_av_unetI/netI     0.0866
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            51444
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        27.497
_diffrn_reflns_theta_max         27.497
_diffrn_reflns_theta_min         1.652
_diffrn_source                   'MX1 Beamline Australian Synchrotron'
_exptl_absorpt_coefficient_mu    0.818
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            'clear light yellow'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.301
_exptl_crystal_description       plate
_exptl_crystal_F_000             640
_exptl_crystal_recrystallization_method
'Crystallised at elevated temperature from synthesis'
_exptl_crystal_size_max          0.06
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.02
_refine_diff_density_max         2.292
_refine_diff_density_min         -1.071
_refine_diff_density_rms         0.142
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.058
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     391
_refine_ls_number_reflns         7354
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.058
_refine_ls_R_factor_all          0.1466
_refine_ls_R_factor_gt           0.0972
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1990P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2803
_refine_ls_wR_factor_ref         0.3216
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4111
_reflns_number_total             7354
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c8ce00744f2.cif
_cod_data_source_block           7
_cod_depositor_comments
'Adding full bibliography for 7230978--7230987.cif.'
_cod_database_code               7230980
_shelx_shelxl_version_number     2017/1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C17(H17A,H17B), C2(H2A,H2B)
2.b Aromatic/amide H refined with riding coordinates:
 C28(H28), C20(H20), C9(H9), C26(H26), C30(H30), C10(H10), C25(H25), C22(H22),
 C12(H12), C7(H7), C27(H27), C24(H24), C19(H19), C21(H21)
;
_platon_squeeze_void_probe_radius 1.20
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Zn2 Zn 1.000000 0.500000 1.000000 0.0402(3) Uani 1 2 d S T P
Zn1 Zn -0.500000 0.500000 0.000000 0.0415(3) Uani 1 2 d S T P
O8 O 0.5520(4) 0.4661(3) 0.8562(3) 0.0399(9) Uani 1 1 d . . .
O7 O 0.7679(4) 0.4274(4) 0.9086(3) 0.0455(10) Uani 1 1 d . . .
O2 O -0.0417(4) 0.5537(3) 0.1509(3) 0.0418(9) Uani 1 1 d . . .
O4 O -0.1732(4) 0.3822(4) 0.2665(3) 0.0467(10) Uani 1 1 d . . .
O5 O 0.6933(4) 0.6307(4) 0.7458(4) 0.0558(12) Uani 1 1 d . . .
N4 N 0.9983(4) 0.6483(3) 0.9839(4) 0.0314(9) Uani 1 1 d . . .
O6 O 0.4338(5) 0.2721(4) 0.5907(4) 0.0622(13) Uani 1 1 d . . .
N3 N -0.5071(4) 0.3420(3) -0.0062(4) 0.0342(10) Uani 1 1 d . . .
O1 O -0.2747(4) 0.5695(4) 0.1033(4) 0.0508(11) Uani 1 1 d . . .
O3 O 0.0878(5) 0.7429(4) 0.4276(4) 0.0583(12) Uani 1 1 d . . .
N1 N -0.0439(5) 0.5618(4) 0.3496(4) 0.0450(11) Uani 1 1 d . . .
C6 C 0.0715(5) 0.4293(4) 0.3981(4) 0.0331(11) Uani 1 1 d . . .
N2 N 0.5667(5) 0.4520(5) 0.6623(4) 0.0473(12) Uani 1 1 d . . .
C8 C 0.1996(5) 0.5171(4) 0.4738(4) 0.0326(11) Uani 1 1 d . . .
C13 C 0.4499(6) 0.5811(5) 0.6124(4) 0.0363(12) Uani 1 1 d . . .
C4 C -0.0578(5) 0.4521(5) 0.3321(4) 0.0393(13) Uani 1 1 d . . .
C3 C 0.0829(6) 0.6502(5) 0.4203(5) 0.0469(14) Uani 1 1 d . . .
C18 C 0.6667(6) 0.4440(4) 0.8439(5) 0.0363(12) Uani 1 1 d . . .
C11 C 0.3215(5) 0.4937(4) 0.5377(4) 0.0334(11) Uani 1 1 d . . .
C28 C 1.1061(6) 0.7946(4) 0.9420(5) 0.0464(14) Uani 1 1 d . . .
H28 H 1.176367 0.822429 0.915086 0.056 Uiso 1 1 calc R . .
C15 C 0.5813(6) 0.5600(5) 0.6801(5) 0.0421(13) Uani 1 1 d . . .
C5 C 0.2108(6) 0.6267(5) 0.4890(5) 0.0431(13) Uani 1 1 d . . .
C14 C 0.3119(6) 0.3852(5) 0.5237(5) 0.0439(13) Uani 1 1 d . . .
C20 C -0.4808(6) 0.3169(5) 0.0774(5) 0.0420(13) Uani 1 1 d . . .
H20 H -0.457365 0.373710 0.146490 0.050 Uiso 1 1 calc R . .
C9 C 0.0649(6) 0.3236(5) 0.3839(4) 0.0373(12) Uani 1 1 d . . .
H9 H -0.020969 0.265427 0.330589 0.045 Uiso 1 1 calc R . .
C26 C 1.0967(6) 0.6946(4) 0.9482(5) 0.0415(13) Uani 1 1 d . . .
H26 H 1.163350 0.656286 0.926090 0.050 Uiso 1 1 calc R . .
C30 C 1.0267(7) 0.9628(5) 0.9741(6) 0.0481(15) Uani 1 1 d . . .
H30 H 1.079659 0.980739 0.931834 0.058 Uiso 1 1 calc R . .
C1 C -0.1587(6) 0.5664(5) 0.1680(5) 0.0395(12) Uani 1 1 d . . .
C29 C 1.0126(6) 0.8538(5) 0.9752(5) 0.0424(14) Uani 1 1 d . . .
C10 C 0.4570(6) 0.6880(5) 0.6264(5) 0.0413(13) Uani 1 1 d . . .
H10 H 0.542911 0.746260 0.679568 0.050 Uiso 1 1 calc R . .
C25 C 0.9001(6) 0.7035(4) 1.0081(5) 0.0469(15) Uani 1 1 d . . .
H25 H 0.823979 0.671072 1.027968 0.056 Uiso 1 1 calc R . .
C22 C -0.4845(7) 0.2126(5) 0.0726(5) 0.0496(15) Uani 1 1 d . . .
H22 H -0.462917 0.200416 0.137009 0.059 Uiso 1 1 calc R . .
C12 C 0.1853(6) 0.3011(5) 0.4482(5) 0.0403(12) Uani 1 1 d . . .
H12 H 0.179148 0.228125 0.439453 0.048 Uiso 1 1 calc R . .
C7 C 0.3379(6) 0.7098(5) 0.5623(5) 0.0449(13) Uani 1 1 d . . .
H7 H 0.345110 0.782423 0.569401 0.054 Uiso 1 1 calc R . .
C16 C 0.4392(6) 0.3628(5) 0.5937(5) 0.0474(15) Uani 1 1 d . . .
C27 C 0.9044(6) 0.8032(5) 1.0057(6) 0.0543(17) Uani 1 1 d . . .
H27 H 0.833461 0.838456 1.024896 0.065 Uiso 1 1 calc R . .
C23 C -0.5191(6) 0.1288(5) -0.0245(5) 0.0438(13) Uani 1 1 d . . .
C17 C 0.6898(7) 0.4325(6) 0.7367(5) 0.0535(17) Uani 1 1 d . . .
H17A H 0.786746 0.485201 0.753467 0.064 Uiso 1 1 calc R . .
H17B H 0.695902 0.358205 0.700057 0.064 Uiso 1 1 calc R . .
C24 C -0.5226(7) 0.0164(5) -0.0378(6) 0.0538(16) Uani 1 1 d . . .
H24 H -0.562727 -0.037777 -0.110149 0.065 Uiso 1 1 calc R . .
C19 C -0.5439(8) 0.2586(5) -0.1035(6) 0.0599(17) Uani 1 1 d . . .
H19 H -0.565461 0.272989 -0.166612 0.072 Uiso 1 1 calc R . .
C2 C -0.1647(7) 0.5853(6) 0.2808(5) 0.0520(16) Uani 1 1 d . . .
H2A H -0.160515 0.662322 0.318136 0.062 Uiso 1 1 calc R . .
H2B H -0.262522 0.538919 0.271448 0.062 Uiso 1 1 calc R . .
C21 C -0.5512(8) 0.1535(5) -0.1145(6) 0.0661(19) Uani 1 1 d . . .
H21 H -0.578680 0.097116 -0.184556 0.079 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0030 0.0020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0070 0.0030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0120 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.3120 1.4670 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O7 Zn2 O7 180.0 2_767 .
O7 Zn2 O2 91.48(15) 2_767 2_666
O7 Zn2 O2 88.52(15) . 2_666
O7 Zn2 O2 88.52(15) 2_767 1_656
O7 Zn2 O2 91.48(15) . 1_656
O7 Zn2 N4 93.00(16) 2_767 2_767
O7 Zn2 N4 87.00(16) 2_767 .
O7 Zn2 N4 87.00(16) . 2_767
O7 Zn2 N4 93.00(16) . .
O2 Zn2 O2 180.0 1_656 2_666
N4 Zn2 O2 93.39(15) 2_767 2_666
N4 Zn2 O2 86.61(15) 2_767 1_656
N4 Zn2 O2 93.39(15) . 1_656
N4 Zn2 O2 86.61(15) . 2_666
N4 Zn2 N4 180.0(2) 2_767 .
O8 Zn1 O8 180.0(2) 1_454 2_566
N3 Zn1 O8 87.42(16) . 2_566
N3 Zn1 O8 87.42(16) 2_465 1_454
N3 Zn1 O8 92.58(16) 2_465 2_566
N3 Zn1 O8 92.58(16) . 1_454
N3 Zn1 N3 180.0 . 2_465
O1 Zn1 O8 86.30(15) 2_465 1_454
O1 Zn1 O8 93.70(15) 2_465 2_566
O1 Zn1 O8 86.30(15) . 2_566
O1 Zn1 O8 93.70(15) . 1_454
O1 Zn1 N3 94.22(17) 2_465 2_465
O1 Zn1 N3 94.22(17) . .
O1 Zn1 N3 85.78(17) . 2_465
O1 Zn1 N3 85.78(17) 2_465 .
O1 Zn1 O1 180.0 2_465 .
C18 O8 Zn1 126.5(4) . 1_656
C18 O7 Zn2 137.4(3) . .
C1 O2 Zn2 130.4(4) . 1_454
C26 N4 Zn2 121.6(3) . .
C26 N4 C25 115.4(4) . .
C25 N4 Zn2 123.0(3) . .
C20 N3 Zn1 125.2(4) . .
C20 N3 C19 115.9(5) . .
C19 N3 Zn1 118.9(4) . .
C1 O1 Zn1 151.0(4) . .
C4 N1 C2 118.0(5) . .
C3 N1 C4 125.6(5) . .
C3 N1 C2 116.0(5) . .
C8 C6 C4 119.0(5) . .
C9 C6 C8 121.2(5) . .
C9 C6 C4 119.7(5) . .
C15 N2 C16 126.7(5) . .
C15 N2 C17 115.6(5) . .
C16 N2 C17 116.9(5) . .
C6 C8 C11 118.2(5) . .
C6 C8 C5 122.6(5) . .
C5 C8 C11 119.3(5) . .
C11 C13 C15 119.9(5) . .
C10 C13 C11 121.3(5) . .
C10 C13 C15 118.8(5) . .
O4 C4 N1 119.3(5) . .
O4 C4 C6 123.6(5) . .
N1 C4 C6 117.1(5) . .
O3 C3 N1 121.5(5) . .
O3 C3 C5 121.8(6) . .
N1 C3 C5 116.7(5) . .
O8 C18 O7 127.2(5) . .
O8 C18 C17 118.4(5) . .
O7 C18 C17 114.4(4) . .
C13 C11 C8 118.1(5) . .
C13 C11 C14 121.9(5) . .
C14 C11 C8 119.9(5) . .
C26 C28 H28 120.1 . .
C29 C28 H28 120.1 . .
C29 C28 C26 119.8(4) . .
O5 C15 N2 120.9(5) . .
O5 C15 C13 123.3(6) . .
N2 C15 C13 115.8(5) . .
C8 C5 C3 118.8(5) . .
C7 C5 C8 121.0(5) . .
C7 C5 C3 120.1(5) . .
C11 C14 C16 119.1(5) . .
C12 C14 C11 120.4(5) . .
C12 C14 C16 120.5(5) . .
N3 C20 H20 117.6 . .
N3 C20 C22 124.8(6) . .
C22 C20 H20 117.6 . .
C6 C9 H9 119.9 . .
C6 C9 C12 120.3(5) . .
C12 C9 H9 119.9 . .
N4 C26 C28 123.9(5) . .
N4 C26 H26 118.1 . .
C28 C26 H26 118.1 . .
C30 C30 H30 116.9 2_777 .
C30 C30 C29 126.3(6) 2_777 .
C29 C30 H30 116.9 . .
O2 C1 O1 126.9(5) . .
O2 C1 C2 119.1(5) . .
O1 C1 C2 113.9(5) . .
C28 C29 C30 120.2(4) . .
C28 C29 C27 116.5(5) . .
C27 C29 C30 123.3(5) . .
C13 C10 H10 120.0 . .
C13 C10 C7 120.0(5) . .
C7 C10 H10 120.0 . .
N4 C25 H25 118.1 . .
N4 C25 C27 123.7(4) . .
C27 C25 H25 118.1 . .
C20 C22 H22 120.2 . .
C23 C22 C20 119.5(5) . .
C23 C22 H22 120.2 . .
C14 C12 C9 120.0(5) . .
C14 C12 H12 120.0 . .
C9 C12 H12 120.0 . .
C5 C7 C10 120.2(5) . .
C5 C7 H7 119.9 . .
C10 C7 H7 119.9 . .
O6 C16 N2 121.4(5) . .
O6 C16 C14 122.3(6) . .
N2 C16 C14 116.3(5) . .
C29 C27 H27 119.8 . .
C25 C27 C29 120.4(5) . .
C25 C27 H27 119.8 . .
C22 C23 C24 123.7(6) . .
C22 C23 C21 116.5(5) . .
C21 C23 C24 119.8(6) . .
N2 C17 C18 112.5(4) . .
N2 C17 H17A 109.1 . .
N2 C17 H17B 109.1 . .
C18 C17 H17A 109.1 . .
C18 C17 H17B 109.1 . .
H17A C17 H17B 107.8 . .
C23 C24 H24 116.4 . .
C24 C24 C23 127.2(9) 2_455 .
C24 C24 H24 116.4 2_455 .
N3 C19 H19 118.8 . .
N3 C19 C21 122.4(6) . .
C21 C19 H19 118.8 . .
N1 C2 C1 114.2(5) . .
N1 C2 H2A 108.7 . .
N1 C2 H2B 108.7 . .
C1 C2 H2A 108.7 . .
C1 C2 H2B 108.7 . .
H2A C2 H2B 107.6 . .
C23 C21 H21 119.6 . .
C19 C21 C23 120.8(7) . .
C19 C21 H21 119.6 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn2 O7 2.104(4) 2_767
Zn2 O7 2.104(4) .
Zn2 O2 2.176(4) 2_666
Zn2 O2 2.176(4) 1_656
Zn2 N4 2.115(4) .
Zn2 N4 2.115(4) 2_767
Zn1 O8 2.139(4) 2_566
Zn1 O8 2.139(4) 1_454
Zn1 N3 2.116(4) 2_465
Zn1 N3 2.116(4) .
Zn1 O1 2.083(4) .
Zn1 O1 2.083(4) 2_465
O8 C18 1.240(6) .
O7 C18 1.248(6) .
O2 C1 1.248(6) .
O4 C4 1.211(7) .
O5 C15 1.196(7) .
N4 C26 1.354(6) .
N4 C25 1.355(6) .
O6 C16 1.216(7) .
N3 C20 1.307(6) .
N3 C19 1.351(8) .
O1 C1 1.251(7) .
O3 C3 1.225(7) .
N1 C4 1.408(8) .
N1 C3 1.393(8) .
N1 C2 1.454(7) .
C6 C8 1.410(8) .
C6 C4 1.485(7) .
C6 C9 1.375(8) .
N2 C15 1.383(8) .
N2 C16 1.398(8) .
N2 C17 1.479(7) .
C8 C11 1.425(7) .
C8 C5 1.417(8) .
C13 C11 1.406(8) .
C13 C15 1.499(7) .
C13 C10 1.391(8) .
C3 C5 1.501(8) .
C18 C17 1.546(8) .
C11 C14 1.409(8) .
C28 H28 0.9500 .
C28 C26 1.386(7) .
C28 C29 1.385(7) .
C5 C7 1.370(8) .
C14 C12 1.380(8) .
C14 C16 1.495(8) .
C20 H20 0.9500 .
C20 C22 1.395(8) .
C9 H9 0.9500 .
C9 C12 1.412(8) .
C26 H26 0.9500 .
C30 C30 1.310(12) 2_777
C30 H30 0.9500 .
C30 C29 1.476(7) .
C1 C2 1.540(8) .
C29 C27 1.400(7) .
C10 H10 0.9500 .
C10 C7 1.396(8) .
C25 H25 0.9500 .
C25 C27 1.366(7) .
C22 H22 0.9500 .
C22 C23 1.356(9) .
C12 H12 0.9500 .
C7 H7 0.9500 .
C27 H27 0.9500 .
C23 C24 1.474(8) .
C23 C21 1.385(8) .
C17 H17A 0.9900 .
C17 H17B 0.9900 .
C24 C24 1.289(12) 2_455
C24 H24 0.9500 .
C19 H19 0.9500 .
C19 C21 1.377(8) .
C2 H2A 0.9900 .
C2 H2B 0.9900 .
C21 H21 0.9500 .
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.119 0.000 0.500 458 167 ' '
