#------------------------------------------------------------------------------
#$Date: 2019-11-17 09:36:46 +0200 (Sun, 17 Nov 2019) $
#$Revision: 229141 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/12/7231227.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7231227
loop_
_publ_author_name
'Li, Jing-Ming'
'Li, Rui'
'Li, Xia'
_publ_section_title
;
 Construction of metal--organic frameworks (MOFs) and highly luminescent
 Eu(iii)-MOF for the detection of inorganic ions and antibiotics in
 aqueous medium
;
_journal_issue                   34
_journal_name_full               CrystEngComm
_journal_page_first              4962
_journal_paper_doi               10.1039/C8CE00915E
_journal_volume                  20
_journal_year                    2018
_chemical_formula_sum            'C66 H40 Eu2 N4 O15'
_chemical_formula_weight         1432.94
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2018-06-02 deposited with the CCDC.
2018-07-24 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 90.9490(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.0373(12)
_cell_length_b                   22.5614(19)
_cell_length_c                   19.4320(17)
_cell_measurement_temperature    298(2)
_cell_volume                     5714.9(9)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0673
_diffrn_reflns_av_sigmaI/netI    0.1031
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            28935
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         2.28
_exptl_absorpt_coefficient_mu    2.250
_exptl_absorpt_correction_T_max  0.8405
_exptl_absorpt_correction_T_min  0.6494
_exptl_crystal_density_diffrn    1.665
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2840
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.279
_refine_diff_density_min         -0.700
_refine_diff_density_rms         0.105
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.869
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     784
_refine_ls_number_reflns         10068
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.869
_refine_ls_R_factor_all          0.0833
_refine_ls_R_factor_gt           0.0409
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0001P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0543
_refine_ls_wR_factor_ref         0.0613
_reflns_number_gt                6139
_reflns_number_total             10068
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c8ce00915e2.cif
_cod_data_source_block           160423e
_cod_depositor_comments
'Adding full bibliography for 7231226--7231229.cif.'
_cod_database_code               7231227
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.49092(2) 0.561477(12) 0.579000(14) 0.03486(9) Uani 1 1 d .
Eu2 Eu 0.13117(2) 0.957426(12) 0.505197(15) 0.03633(9) Uani 1 1 d .
N1 N 0.3349(4) 0.59072(19) 0.6579(2) 0.0384(12) Uani 1 1 d .
N2 N 0.4430(4) 0.6708(2) 0.5839(2) 0.0443(13) Uani 1 1 d .
N3 N 0.3200(4) 0.9420(2) 0.4771(3) 0.0422(13) Uani 1 1 d .
N4 N 0.2640(4) 0.9552(2) 0.6096(2) 0.0419(13) Uani 1 1 d .
O1 O 0.3317(3) 0.5622(2) 0.5193(2) 0.0716(14) Uani 1 1 d .
O2 O 0.3687(3) 0.50140(18) 0.4350(3) 0.0807(16) Uani 1 1 d .
O3 O 0.1551(3) 0.85072(15) 0.5208(2) 0.0442(11) Uani 1 1 d .
O4 O 0.1398(3) 0.88222(16) 0.41440(19) 0.0483(12) Uani 1 1 d .
O5 O 0.1536(3) 0.62665(17) 0.48901(19) 0.0522(12) Uani 1 1 d .
O6 O 0.6470(3) 0.62147(15) 0.60481(19) 0.0436(11) Uani 1 1 d .
O7 O 0.5611(3) 0.58249(17) 0.69133(18) 0.0501(11) Uani 1 1 d .
O8 O 0.0444(3) 1.06201(16) 0.52285(18) 0.0436(10) Uani 1 1 d .
O9 O 0.2115(3) 1.05566(16) 0.5243(2) 0.0515(11) Uani 1 1 d .
O10 O 0.2735(3) 1.15818(17) 0.5975(2) 0.0521(12) Uani 1 1 d .
O11 O 0.4378(3) 0.46911(16) 0.62288(19) 0.0474(11) Uani 1 1 d .
O12 O 0.4602(3) 0.41150(18) 0.5314(2) 0.0630(13) Uani 1 1 d .
O13 O 0.1163(3) 1.00969(15) 0.39802(18) 0.0456(11) Uani 1 1 d .
O14 O -0.0394(3) 1.05272(17) 0.39239(18) 0.0450(11) Uani 1 1 d .
O15 O 0.3112(3) 1.09656(17) 0.2077(2) 0.0641(14) Uani 1 1 d .
C1 C 0.3072(5) 0.5312(3) 0.4691(4) 0.0486(18) Uani 1 1 d .
C2 C 0.1960(5) 0.5284(3) 0.4472(3) 0.0437(16) Uani 1 1 d .
C3 C 0.1262(5) 0.5735(3) 0.4569(3) 0.0432(16) Uani 1 1 d .
C4 C 0.0251(5) 0.5677(3) 0.4360(3) 0.068(2) Uani 1 1 d .
H4 H -0.0206 0.5988 0.4424 0.081 Uiso 1 1 calc R
C5 C -0.0078(6) 0.5166(4) 0.4061(4) 0.085(3) Uani 1 1 d .
H5 H -0.0765 0.5126 0.3933 0.102 Uiso 1 1 calc R
C6 C 0.0578(7) 0.4718(3) 0.3948(4) 0.087(3) Uani 1 1 d .
H6 H 0.0346 0.4375 0.3731 0.104 Uiso 1 1 calc R
C7 C 0.1608(6) 0.4765(3) 0.4153(3) 0.062(2) Uani 1 1 d .
H7 H 0.2057 0.4452 0.4078 0.074 Uiso 1 1 calc R
C8 C 0.1541(4) 0.8410(3) 0.4561(3) 0.0419(16) Uani 1 1 d .
C9 C 0.1711(4) 0.7793(2) 0.4306(3) 0.0392(15) Uani 1 1 d .
C10 C 0.1561(4) 0.7299(2) 0.4711(3) 0.0416(16) Uani 1 1 d .
H10 H 0.1353 0.7346 0.5163 0.050 Uiso 1 1 calc R
C11 C 0.1715(4) 0.6740(3) 0.4457(3) 0.0397(16) Uani 1 1 d .
C12 C 0.2050(5) 0.6666(3) 0.3793(3) 0.0488(17) Uani 1 1 d .
H12 H 0.2166 0.6288 0.3620 0.059 Uiso 1 1 calc R
C13 C 0.2210(5) 0.7150(3) 0.3392(3) 0.061(2) Uani 1 1 d .
H13 H 0.2435 0.7102 0.2943 0.073 Uiso 1 1 calc R
C14 C 0.2041(5) 0.7712(3) 0.3645(3) 0.0542(19) Uani 1 1 d .
H14 H 0.2151 0.8039 0.3365 0.065 Uiso 1 1 calc R
C15 C 0.6360(5) 0.6125(2) 0.6686(3) 0.0418(16) Uani 1 1 d .
C16 C 0.2889(4) 1.1380(2) 0.7812(3) 0.0374(15) Uani 1 1 d .
C17 C 0.3079(4) 1.1347(2) 0.7119(3) 0.0371(15) Uani 1 1 d .
H17 H 0.3655 1.1145 0.6969 0.045 Uiso 1 1 calc R
C18 C 0.2427(5) 1.1609(2) 0.6644(3) 0.0401(16) Uani 1 1 d .
C19 C 0.1563(5) 1.1891(3) 0.6857(3) 0.0538(19) Uani 1 1 d .
H19 H 0.1116 1.2064 0.6537 0.065 Uiso 1 1 calc R
C20 C 0.1355(5) 1.1919(3) 0.7550(3) 0.077(2) Uani 1 1 d .
H20 H 0.0758 1.2103 0.7697 0.092 Uiso 1 1 calc R
C21 C 0.2034(5) 1.1674(3) 0.8030(3) 0.063(2) Uani 1 1 d .
H21 H 0.1909 1.1710 0.8498 0.076 Uiso 1 1 calc R
C22 C 0.1325(5) 1.0860(2) 0.5211(3) 0.0356(15) Uani 1 1 d .
C23 C 0.1395(4) 1.1530(2) 0.5112(3) 0.0243(12) Uani 1 1 d .
C24 C 0.2122(5) 1.1852(3) 0.5475(3) 0.0419(16) Uani 1 1 d .
C25 C 0.2266(5) 1.2446(3) 0.5349(3) 0.0570(19) Uani 1 1 d .
H25 H 0.2763 1.2656 0.5596 0.068 Uiso 1 1 calc R
C26 C 0.1685(6) 1.2724(3) 0.4864(3) 0.063(2) Uani 1 1 d .
H26 H 0.1778 1.3126 0.4778 0.076 Uiso 1 1 calc R
C27 C 0.0962(5) 1.2409(3) 0.4503(3) 0.058(2) Uani 1 1 d .
H27 H 0.0561 1.2600 0.4171 0.070 Uiso 1 1 calc R
C28 C 0.0815(5) 1.1811(2) 0.4622(3) 0.0449(17) Uani 1 1 d .
H28 H 0.0322 1.1603 0.4370 0.054 Uiso 1 1 calc R
C29 C 0.4458(4) 0.4194(3) 0.5945(3) 0.0409(16) Uani 1 1 d .
C30 C 0.4429(5) 0.3650(2) 0.6390(3) 0.0376(15) Uani 1 1 d .
C31 C 0.3767(5) 0.3574(3) 0.6936(3) 0.0427(16) Uani 1 1 d .
C32 C 0.3781(5) 0.3077(3) 0.7336(3) 0.060(2) Uani 1 1 d .
H32 H 0.3315 0.3034 0.7690 0.072 Uiso 1 1 calc R
C33 C 0.4489(6) 0.2639(3) 0.7212(4) 0.080(3) Uani 1 1 d .
H33 H 0.4530 0.2311 0.7500 0.096 Uiso 1 1 calc R
C34 C 0.5143(6) 0.2687(3) 0.6658(5) 0.084(3) Uani 1 1 d .
H34 H 0.5595 0.2382 0.6557 0.101 Uiso 1 1 calc R
C35 C 0.5114(5) 0.3191(3) 0.6259(4) 0.064(2) Uani 1 1 d .
H35 H 0.5562 0.3226 0.5893 0.077 Uiso 1 1 calc R
C36 C 0.0514(5) 1.0449(2) 0.3713(3) 0.0369(15) Uani 1 1 d .
C37 C 0.0827(4) 1.0812(2) 0.3107(3) 0.0333(14) Uani 1 1 d .
C38 C 0.1829(5) 1.0766(2) 0.2878(3) 0.0387(15) Uani 1 1 d .
H38 H 0.2293 1.0518 0.3105 0.046 Uiso 1 1 calc R
C39 C 0.2130(5) 1.1087(2) 0.2317(3) 0.0427(16) Uani 1 1 d .
C40 C 0.1465(5) 1.1464(3) 0.1985(3) 0.0522(18) Uani 1 1 d .
H40 H 0.1676 1.1684 0.1609 0.063 Uiso 1 1 calc R
C41 C 0.0485(5) 1.1510(3) 0.2217(3) 0.0532(18) Uani 1 1 d .
H41 H 0.0028 1.1764 0.1991 0.064 Uiso 1 1 calc R
C42 C 0.0156(5) 1.1190(2) 0.2777(3) 0.0416(16) Uani 1 1 d .
H42 H -0.0512 1.1231 0.2929 0.050 Uiso 1 1 calc R
C43 C 0.2815(5) 0.5524(3) 0.6941(3) 0.0538(18) Uani 1 1 d .
H43 H 0.3063 0.5139 0.6981 0.065 Uiso 1 1 calc R
C44 C 0.1907(5) 0.5663(3) 0.7266(3) 0.065(2) Uani 1 1 d .
H44 H 0.1558 0.5376 0.7515 0.078 Uiso 1 1 calc R
C45 C 0.1537(5) 0.6221(3) 0.7215(3) 0.0596(19) Uani 1 1 d .
H45 H 0.0928 0.6321 0.7429 0.072 Uiso 1 1 calc R
C46 C 0.2071(5) 0.6652(3) 0.6839(3) 0.0425(16) Uani 1 1 d .
C47 C 0.2970(5) 0.6470(2) 0.6525(3) 0.0370(15) Uani 1 1 d .
C48 C 0.3552(5) 0.6893(2) 0.6141(3) 0.0393(16) Uani 1 1 d .
C49 C 0.3193(5) 0.7478(3) 0.6098(3) 0.0465(17) Uani 1 1 d .
C50 C 0.3778(6) 0.7882(3) 0.5720(3) 0.062(2) Uani 1 1 d .
H50 H 0.3557 0.8272 0.5671 0.075 Uiso 1 1 calc R
C51 C 0.4660(6) 0.7705(3) 0.5429(3) 0.071(2) Uani 1 1 d .
H51 H 0.5061 0.7975 0.5191 0.085 Uiso 1 1 calc R
C52 C 0.4967(5) 0.7107(3) 0.5490(3) 0.0578(19) Uani 1 1 d .
H52 H 0.5567 0.6987 0.5279 0.069 Uiso 1 1 calc R
C53 C 0.1726(5) 0.7245(3) 0.6772(3) 0.0545(19) Uani 1 1 d .
H53 H 0.1115 0.7359 0.6973 0.065 Uiso 1 1 calc R
C54 C 0.2274(5) 0.7643(3) 0.6421(3) 0.058(2) Uani 1 1 d .
H54 H 0.2045 0.8033 0.6389 0.070 Uiso 1 1 calc R
C55 C 0.3489(5) 0.9357(3) 0.4115(4) 0.0547(18) Uani 1 1 d .
H55 H 0.2991 0.9395 0.3770 0.066 Uiso 1 1 calc R
C56 C 0.4489(6) 0.9237(3) 0.3924(4) 0.064(2) Uani 1 1 d .
H56 H 0.4653 0.9193 0.3463 0.077 Uiso 1 1 calc R
C57 C 0.5213(5) 0.9187(3) 0.4419(4) 0.063(2) Uani 1 1 d .
H57 H 0.5888 0.9109 0.4298 0.075 Uiso 1 1 calc R
C58 C 0.4969(5) 0.9251(2) 0.5111(4) 0.0480(18) Uani 1 1 d .
C59 C 0.3939(5) 0.9368(2) 0.5254(3) 0.0396(15) Uani 1 1 d .
C60 C 0.3638(5) 0.9445(2) 0.5960(3) 0.0400(15) Uani 1 1 d .
C61 C 0.4401(5) 0.9402(3) 0.6480(4) 0.0499(17) Uani 1 1 d .
C62 C 0.4089(6) 0.9512(3) 0.7154(4) 0.064(2) Uani 1 1 d .
H62 H 0.4569 0.9493 0.7513 0.077 Uiso 1 1 calc R
C63 C 0.3100(6) 0.9645(3) 0.7292(3) 0.064(2) Uani 1 1 d .
H63 H 0.2900 0.9727 0.7739 0.077 Uiso 1 1 calc R
C64 C 0.2395(5) 0.9657(2) 0.6751(3) 0.0514(17) Uani 1 1 d .
H64 H 0.1715 0.9743 0.6848 0.062 Uiso 1 1 calc R
C65 C 0.5702(5) 0.9197(3) 0.5652(5) 0.068(2) Uani 1 1 d .
H65 H 0.6381 0.9109 0.5552 0.082 Uiso 1 1 calc R
C66 C 0.5424(5) 0.9271(3) 0.6306(4) 0.069(2) Uani 1 1 d .
H66 H 0.5916 0.9236 0.6656 0.083 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O12 Eu1 O2 79.94(17) 3_666 3_666
O12 Eu1 O11 130.56(13) 3_666 .
O2 Eu1 O11 74.97(14) 3_666 .
O12 Eu1 O1 78.29(15) 3_666 .
O2 Eu1 O1 129.13(16) 3_666 .
O11 Eu1 O1 85.55(15) . .
O12 Eu1 O7 132.87(14) 3_666 .
O2 Eu1 O7 86.45(16) 3_666 .
O11 Eu1 O7 87.45(13) . .
O1 Eu1 O7 139.85(15) . .
O12 Eu1 O6 78.94(13) 3_666 .
O2 Eu1 O6 73.39(13) 3_666 .
O11 Eu1 O6 130.66(12) . .
O1 Eu1 O6 143.60(14) . .
O7 Eu1 O6 53.93(12) . .
O12 Eu1 N2 81.48(15) 3_666 .
O2 Eu1 N2 141.82(16) 3_666 .
O11 Eu1 N2 140.20(15) . .
O1 Eu1 N2 78.34(16) . .
O7 Eu1 N2 82.23(14) . .
O6 Eu1 N2 70.48(14) . .
O12 Eu1 N1 133.75(15) 3_666 .
O2 Eu1 N1 145.99(16) 3_666 .
O11 Eu1 N1 77.19(13) . .
O1 Eu1 N1 66.78(14) . .
O7 Eu1 N1 73.10(13) . .
O6 Eu1 N1 112.39(13) . .
N2 Eu1 N1 63.02(15) . .
O12 Eu1 Eu1 58.22(10) 3_666 3_666
O2 Eu1 Eu1 56.85(12) 3_666 3_666
O11 Eu1 Eu1 72.40(9) . 3_666
O1 Eu1 Eu1 72.60(11) . 3_666
O7 Eu1 Eu1 141.25(9) . 3_666
O6 Eu1 Eu1 117.17(9) . 3_666
N2 Eu1 Eu1 133.82(10) . 3_666
N1 Eu1 Eu1 130.41(9) . 3_666
O14 Eu2 O8 71.07(12) 3_576 3_576
O14 Eu2 O13 138.45(12) 3_576 .
O8 Eu2 O13 80.14(12) 3_576 .
O14 Eu2 O3 82.24(13) 3_576 .
O8 Eu2 O3 88.11(12) 3_576 .
O13 Eu2 O3 126.85(13) . .
O14 Eu2 O4 124.90(13) 3_576 .
O8 Eu2 O4 76.34(13) 3_576 .
O13 Eu2 O4 73.70(12) . .
O3 Eu2 O4 53.17(12) . .
O14 Eu2 O9 100.37(13) 3_576 .
O8 Eu2 O9 126.91(12) 3_576 .
O13 Eu2 O9 73.63(12) . .
O3 Eu2 O9 144.07(13) . .
O4 Eu2 O9 134.66(13) . .
O14 Eu2 N3 132.36(14) 3_576 .
O8 Eu2 N3 148.29(14) 3_576 .
O13 Eu2 N3 86.87(14) . .
O3 Eu2 N3 76.75(14) . .
O4 Eu2 N3 72.27(15) . .
O9 Eu2 N3 75.39(14) . .
O14 Eu2 O8 75.63(12) 3_576 .
O8 Eu2 O8 77.43(13) 3_576 .
O13 Eu2 O8 69.21(11) . .
O3 Eu2 O8 156.51(12) . .
O4 Eu2 O8 137.44(11) . .
O9 Eu2 O8 50.36(11) . .
N3 Eu2 O8 124.48(13) . .
O14 Eu2 N4 71.62(14) 3_576 .
O8 Eu2 N4 141.75(13) 3_576 .
O13 Eu2 N4 135.84(14) . .
O3 Eu2 N4 78.82(13) . .
O4 Eu2 N4 120.09(14) . .
O9 Eu2 N4 68.42(13) . .
N3 Eu2 N4 62.65(15) . .
O8 Eu2 N4 101.16(13) . .
O14 Eu2 Eu2 68.65(9) 3_576 3_576
O8 Eu2 Eu2 41.06(9) 3_576 3_576
O13 Eu2 Eu2 69.95(9) . 3_576
O3 Eu2 Eu2 126.68(9) . 3_576
O4 Eu2 Eu2 110.62(9) . 3_576
O9 Eu2 Eu2 86.30(9) . 3_576
N3 Eu2 Eu2 153.88(10) . 3_576
O8 Eu2 Eu2 36.37(8) . 3_576
N4 Eu2 Eu2 127.40(11) . 3_576
C43 N1 C47 117.1(5) . .
C43 N1 Eu1 124.2(4) . .
C47 N1 Eu1 117.8(4) . .
C52 N2 C48 117.8(5) . .
C52 N2 Eu1 120.3(4) . .
C48 N2 Eu1 121.4(4) . .
C59 N3 C55 116.5(5) . .
C59 N3 Eu2 123.1(4) . .
C55 N3 Eu2 120.3(4) . .
C64 N4 C60 117.6(5) . .
C64 N4 Eu2 124.2(4) . .
C60 N4 Eu2 118.2(4) . .
C1 O1 Eu1 126.6(5) . .
C1 O2 Eu1 154.4(5) . 3_666
C8 O3 Eu2 92.8(3) . .
C8 O4 Eu2 93.2(4) . .
C11 O5 C3 115.9(4) . .
C15 O6 Eu1 90.3(4) . .
C15 O7 Eu1 94.2(4) . .
C22 O8 Eu2 159.5(4) . 3_576
C22 O8 Eu2 89.3(3) . .
Eu2 O8 Eu2 102.57(13) 3_576 .
C22 O9 Eu2 97.9(3) . .
C18 O10 C24 118.1(5) . .
C29 O11 Eu1 127.2(4) . .
C29 O12 Eu1 155.5(4) . 3_666
C36 O13 Eu2 135.1(4) . .
C36 O14 Eu2 138.5(4) . 3_576
C31 O15 C39 119.6(5) 4_575 .
O1 C1 O2 124.4(7) . .
O1 C1 C2 118.7(6) . .
O2 C1 C2 116.8(6) . .
C3 C2 C7 117.8(6) . .
C3 C2 C1 124.4(6) . .
C7 C2 C1 117.8(6) . .
C2 C3 C4 121.3(6) . .
C2 C3 O5 122.0(6) . .
C4 C3 O5 116.7(6) . .
C5 C4 C3 120.1(7) . .
C5 C4 H4 120.0 . .
C3 C4 H4 120.0 . .
C6 C5 C4 120.7(8) . .
C6 C5 H5 119.6 . .
C4 C5 H5 119.6 . .
C5 C6 C7 120.5(7) . .
C5 C6 H6 119.8 . .
C7 C6 H6 119.8 . .
C6 C7 C2 119.7(7) . .
C6 C7 H7 120.1 . .
C2 C7 H7 120.1 . .
O4 C8 O3 120.8(5) . .
O4 C8 C9 120.0(6) . .
O3 C8 C9 119.2(5) . .
C14 C9 C10 118.3(5) . .
C14 C9 C8 119.0(6) . .
C10 C9 C8 122.7(6) . .
C11 C10 C9 121.0(6) . .
C11 C10 H10 119.5 . .
C9 C10 H10 119.5 . .
C10 C11 C12 119.8(6) . .
C10 C11 O5 117.7(5) . .
C12 C11 O5 122.5(5) . .
C13 C12 C11 119.6(6) . .
C13 C12 H12 120.2 . .
C11 C12 H12 120.2 . .
C12 C13 C14 120.4(6) . .
C12 C13 H13 119.8 . .
C14 C13 H13 119.8 . .
C9 C14 C13 120.8(6) . .
C9 C14 H14 119.6 . .
C13 C14 H14 119.6 . .
O6 C15 O7 121.6(6) . .
O6 C15 C16 119.8(6) . 2_646
O7 C15 C16 118.6(6) . 2_646
C21 C16 C17 119.3(5) . .
C21 C16 C15 121.0(6) . 2_656
C17 C16 C15 119.7(6) . 2_656
C16 C17 C18 120.9(6) . .
C16 C17 H17 119.5 . .
C18 C17 H17 119.5 . .
C19 C18 O10 124.4(6) . .
C19 C18 C17 120.0(6) . .
O10 C18 C17 115.5(5) . .
C18 C19 C20 119.6(6) . .
C18 C19 H19 120.2 . .
C20 C19 H19 120.2 . .
C19 C20 C21 120.2(6) . .
C19 C20 H20 119.9 . .
C21 C20 H20 119.9 . .
C16 C21 C20 119.9(6) . .
C16 C21 H21 120.1 . .
C20 C21 H21 120.1 . .
O9 C22 O8 121.0(5) . .
O9 C22 C23 120.2(5) . .
O8 C22 C23 118.7(5) . .
C28 C23 C24 118.7(5) . .
C28 C23 C22 121.0(5) . .
C24 C23 C22 120.0(5) . .
C25 C24 C23 121.1(5) . .
C25 C24 O10 118.3(6) . .
C23 C24 O10 120.6(5) . .
C26 C25 C24 120.0(6) . .
C26 C25 H25 120.0 . .
C24 C25 H25 120.0 . .
C25 C26 C27 119.3(6) . .
C25 C26 H26 120.4 . .
C27 C26 H26 120.4 . .
C26 C27 C28 121.3(6) . .
C26 C27 H27 119.4 . .
C28 C27 H27 119.4 . .
C23 C28 C27 119.6(6) . .
C23 C28 H28 120.2 . .
C27 C28 H28 120.2 . .
O11 C29 O12 124.7(6) . .
O11 C29 C30 118.4(5) . .
O12 C29 C30 116.8(6) . .
C31 C30 C35 117.1(6) . .
C31 C30 C29 124.2(6) . .
C35 C30 C29 118.6(6) . .
C32 C31 O15 120.7(6) . 4_576
C32 C31 C30 122.3(6) . .
O15 C31 C30 117.0(5) 4_576 .
C31 C32 C33 119.5(7) . .
C31 C32 H32 120.2 . .
C33 C32 H32 120.2 . .
C32 C33 C34 120.2(7) . .
C32 C33 H33 119.9 . .
C34 C33 H33 119.9 . .
C35 C34 C33 119.3(7) . .
C35 C34 H34 120.3 . .
C33 C34 H34 120.3 . .
C34 C35 C30 121.5(7) . .
C34 C35 H35 119.3 . .
C30 C35 H35 119.3 . .
O13 C36 O14 125.1(5) . .
O13 C36 C37 118.5(5) . .
O14 C36 C37 116.4(5) . .
C42 C37 C38 119.4(5) . .
C42 C37 C36 121.8(5) . .
C38 C37 C36 118.7(5) . .
C39 C38 C37 119.8(6) . .
C39 C38 H38 120.1 . .
C37 C38 H38 120.1 . .
C40 C39 C38 121.1(6) . .
C40 C39 O15 122.7(6) . .
C38 C39 O15 116.0(6) . .
C41 C40 C39 118.8(6) . .
C41 C40 H40 120.6 . .
C39 C40 H40 120.6 . .
C40 C41 C42 121.6(6) . .
C40 C41 H41 119.2 . .
C42 C41 H41 119.2 . .
C37 C42 C41 119.3(6) . .
C37 C42 H42 120.3 . .
C41 C42 H42 120.3 . .
N1 C43 C44 123.9(6) . .
N1 C43 H43 118.1 . .
C44 C43 H43 118.1 . .
C45 C44 C43 118.8(7) . .
C45 C44 H44 120.6 . .
C43 C44 H44 120.6 . .
C44 C45 C46 120.2(6) . .
C44 C45 H45 119.9 . .
C46 C45 H45 119.9 . .
C47 C46 C45 116.8(6) . .
C47 C46 C53 120.4(6) . .
C45 C46 C53 122.8(6) . .
N1 C47 C46 123.1(6) . .
N1 C47 C48 117.7(6) . .
C46 C47 C48 119.2(6) . .
N2 C48 C49 123.0(6) . .
N2 C48 C47 118.4(5) . .
C49 C48 C47 118.6(6) . .
C48 C49 C50 117.4(6) . .
C48 C49 C54 120.5(6) . .
C50 C49 C54 122.2(6) . .
C51 C50 C49 120.0(6) . .
C51 C50 H50 120.0 . .
C49 C50 H50 120.0 . .
C50 C51 C52 119.3(7) . .
C50 C51 H51 120.4 . .
C52 C51 H51 120.4 . .
N2 C52 C51 122.6(7) . .
N2 C52 H52 118.7 . .
C51 C52 H52 118.7 . .
C54 C53 C46 120.6(6) . .
C54 C53 H53 119.7 . .
C46 C53 H53 119.7 . .
C53 C54 C49 120.8(6) . .
C53 C54 H54 119.6 . .
C49 C54 H54 119.6 . .
N3 C55 C56 123.7(6) . .
N3 C55 H55 118.2 . .
C56 C55 H55 118.2 . .
C57 C56 C55 118.5(7) . .
C57 C56 H56 120.7 . .
C55 C56 H56 120.7 . .
C56 C57 C58 120.9(7) . .
C56 C57 H57 119.6 . .
C58 C57 H57 119.6 . .
C57 C58 C59 116.4(6) . .
C57 C58 C65 123.1(7) . .
C59 C58 C65 120.5(7) . .
N3 C59 C58 123.9(6) . .
N3 C59 C60 116.9(5) . .
C58 C59 C60 119.2(6) . .
N4 C60 C61 122.8(6) . .
N4 C60 C59 119.0(5) . .
C61 C60 C59 118.2(6) . .
C62 C61 C60 116.5(6) . .
C62 C61 C66 123.4(7) . .
C60 C61 C66 120.1(7) . .
C63 C62 C61 121.1(6) . .
C63 C62 H62 119.4 . .
C61 C62 H62 119.4 . .
C62 C63 C64 118.4(7) . .
C62 C63 H63 120.8 . .
C64 C63 H63 120.8 . .
N4 C64 C63 123.5(6) . .
N4 C64 H64 118.2 . .
C63 C64 H64 118.2 . .
C66 C65 C58 120.3(7) . .
C66 C65 H65 119.9 . .
C58 C65 H65 119.9 . .
C65 C66 C61 121.7(7) . .
C65 C66 H66 119.2 . .
C61 C66 H66 119.2 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O12 2.330(4) 3_666
Eu1 O2 2.335(4) 3_666
Eu1 O11 2.360(4) .
Eu1 O1 2.362(4) .
Eu1 O7 2.400(3) .
Eu1 O6 2.488(4) .
Eu1 N2 2.547(5) .
Eu1 N1 2.650(5) .
Eu1 Eu1 4.1475(6) 3_666
Eu2 O14 2.350(4) 3_576
Eu2 O8 2.385(4) 3_576
Eu2 O13 2.398(3) .
Eu2 O3 2.446(3) .
Eu2 O4 2.452(4) .
Eu2 O9 2.476(4) .
Eu2 N3 2.555(5) .
Eu2 O8 2.642(4) .
Eu2 N4 2.647(4) .
Eu2 Eu2 3.9250(6) 3_576
N1 C43 1.320(6) .
N1 C47 1.366(6) .
N2 C52 1.332(7) .
N2 C48 1.361(7) .
N3 C59 1.339(6) .
N3 C55 1.342(7) .
N4 C64 1.338(6) .
N4 C60 1.353(7) .
O1 C1 1.236(7) .
O2 C1 1.247(7) .
O2 Eu1 2.335(4) 3_666
O3 C8 1.275(6) .
O4 C8 1.246(6) .
O5 C11 1.381(6) .
O5 C3 1.395(6) .
O6 C15 1.267(6) .
O7 C15 1.274(6) .
O8 C22 1.271(6) .
O8 Eu2 2.385(4) 3_576
O9 C22 1.237(6) .
O10 C18 1.369(6) .
O10 C24 1.390(6) .
O11 C29 1.255(6) .
O12 C29 1.256(6) .
O12 Eu1 2.330(4) 3_666
O13 C36 1.266(6) .
O14 C36 1.271(6) .
O14 Eu2 2.350(4) 3_576
O15 C31 1.375(6) 4_575
O15 C39 1.398(7) .
C1 C2 1.506(8) .
C2 C3 1.379(7) .
C2 C7 1.400(7) .
C3 C4 1.380(8) .
C4 C5 1.356(8) .
C4 H4 0.9300 .
C5 C6 1.346(9) .
C5 H5 0.9300 .
C6 C7 1.398(8) .
C6 H6 0.9300 .
C7 H7 0.9300 .
C8 C9 1.494(7) .
C9 C14 1.374(7) .
C9 C10 1.381(7) .
C10 C11 1.371(7) .
C10 H10 0.9300 .
C11 C12 1.380(7) .
C12 C13 1.359(7) .
C12 H12 0.9300 .
C13 C14 1.378(7) .
C13 H13 0.9300 .
C14 H14 0.9300 .
C15 C16 1.486(7) 2_646
C16 C21 1.371(7) .
C16 C17 1.374(7) .
C16 C15 1.486(7) 2_656
C17 C18 1.377(7) .
C17 H17 0.9300 .
C18 C19 1.365(7) .
C19 C20 1.380(7) .
C19 H19 0.9300 .
C20 C21 1.390(7) .
C20 H20 0.9300 .
C21 H21 0.9300 .
C22 C23 1.527(7) .
C23 C28 1.362(6) .
C23 C24 1.379(7) .
C24 C25 1.374(7) .
C25 C26 1.353(7) .
C25 H25 0.9300 .
C26 C27 1.366(8) .
C26 H26 0.9300 .
C27 C28 1.381(7) .
C27 H27 0.9300 .
C28 H28 0.9300 .
C29 C30 1.501(7) .
C30 C31 1.389(7) .
C30 C35 1.394(7) .
C31 C32 1.364(7) .
C31 O15 1.375(6) 4_576
C32 C33 1.375(8) .
C32 H32 0.9300 .
C33 C34 1.389(9) .
C33 H33 0.9300 .
C34 C35 1.376(8) .
C34 H34 0.9300 .
C35 H35 0.9300 .
C36 C37 1.497(7) .
C37 C42 1.373(7) .
C37 C38 1.390(7) .
C38 C39 1.371(7) .
C38 H38 0.9300 .
C39 C40 1.369(7) .
C40 C41 1.366(8) .
C40 H40 0.9300 .
C41 C42 1.380(7) .
C41 H41 0.9300 .
C42 H42 0.9300 .
C43 C44 1.387(8) .
C43 H43 0.9300 .
C44 C45 1.352(7) .
C44 H44 0.9300 .
C45 C46 1.407(7) .
C45 H45 0.9300 .
C46 C47 1.393(7) .
C46 C53 1.416(7) .
C47 C48 1.435(7) .
C48 C49 1.402(7) .
C49 C50 1.404(8) .
C49 C54 1.412(8) .
C50 C51 1.351(8) .
C50 H50 0.9300 .
C51 C52 1.412(7) .
C51 H51 0.9300 .
C52 H52 0.9300 .
C53 C54 1.342(8) .
C53 H53 0.9300 .
C54 H54 0.9300 .
C55 C56 1.388(8) .
C55 H55 0.9300 .
C56 C57 1.341(8) .
C56 H56 0.9300 .
C57 C58 1.395(8) .
C57 H57 0.9300 .
C58 C59 1.402(7) .
C58 C65 1.413(8) .
C59 C60 1.444(7) .
C60 C61 1.409(7) .
C61 C62 1.399(8) .
C61 C66 1.412(8) .
C62 C63 1.355(8) .
C62 H62 0.9300 .
C63 C64 1.385(7) .
C63 H63 0.9300 .
C64 H64 0.9300 .
C65 C66 1.340(8) .
C65 H65 0.9300 .
C66 H66 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O12 Eu1 N1 C43 135.8(4) 3_666 .
O2 Eu1 N1 C43 -34.7(6) 3_666 .
O11 Eu1 N1 C43 1.0(4) . .
O1 Eu1 N1 C43 91.6(5) . .
O7 Eu1 N1 C43 -90.2(5) . .
O6 Eu1 N1 C43 -128.0(4) . .
N2 Eu1 N1 C43 180.0(5) . .
Eu1 Eu1 N1 C43 54.0(5) 3_666 .
O12 Eu1 N1 C47 -33.4(4) 3_666 .
O2 Eu1 N1 C47 156.0(3) 3_666 .
O11 Eu1 N1 C47 -168.3(4) . .
O1 Eu1 N1 C47 -77.7(4) . .
O7 Eu1 N1 C47 100.5(4) . .
O6 Eu1 N1 C47 62.7(4) . .
N2 Eu1 N1 C47 10.7(3) . .
Eu1 Eu1 N1 C47 -115.2(3) 3_666 .
O12 Eu1 N2 C52 -32.0(4) 3_666 .
O2 Eu1 N2 C52 29.6(6) 3_666 .
O11 Eu1 N2 C52 -179.9(4) . .
O1 Eu1 N2 C52 -111.7(5) . .
O7 Eu1 N2 C52 103.7(5) . .
O6 Eu1 N2 C52 49.3(4) . .
N1 Eu1 N2 C52 178.6(5) . .
Eu1 Eu1 N2 C52 -60.1(5) 3_666 .
O12 Eu1 N2 C48 139.3(4) 3_666 .
O2 Eu1 N2 C48 -159.2(4) 3_666 .
O11 Eu1 N2 C48 -8.6(5) . .
O1 Eu1 N2 C48 59.6(4) . .
O7 Eu1 N2 C48 -85.1(4) . .
O6 Eu1 N2 C48 -139.5(4) . .
N1 Eu1 N2 C48 -10.1(4) . .
Eu1 Eu1 N2 C48 111.2(4) 3_666 .
O14 Eu2 N3 C59 -14.2(5) 3_576 .
O8 Eu2 N3 C59 -144.0(4) 3_576 .
O13 Eu2 N3 C59 150.5(4) . .
O3 Eu2 N3 C59 -80.4(4) . .
O4 Eu2 N3 C59 -135.6(5) . .
O9 Eu2 N3 C59 76.6(4) . .
O8 Eu2 N3 C59 88.5(4) . .
N4 Eu2 N3 C59 3.7(4) . .
Eu2 Eu2 N3 C59 123.6(4) 3_576 .
O14 Eu2 N3 C55 162.5(4) 3_576 .
O8 Eu2 N3 C55 32.7(6) 3_576 .
O13 Eu2 N3 C55 -32.8(4) . .
O3 Eu2 N3 C55 96.2(4) . .
O4 Eu2 N3 C55 41.1(4) . .
O9 Eu2 N3 C55 -106.7(4) . .
O8 Eu2 N3 C55 -94.9(4) . .
N4 Eu2 N3 C55 -179.6(5) . .
Eu2 Eu2 N3 C55 -59.8(5) 3_576 .
O14 Eu2 N4 C64 -18.6(4) 3_576 .
O8 Eu2 N4 C64 -31.8(5) 3_576 .
O13 Eu2 N4 C64 123.5(4) . .
O3 Eu2 N4 C64 -104.1(4) . .
O4 Eu2 N4 C64 -138.9(4) . .
O9 Eu2 N4 C64 90.9(4) . .
N3 Eu2 N4 C64 175.2(5) . .
O8 Eu2 N4 C64 52.0(4) . .
Eu2 Eu2 N4 C64 23.9(5) 3_576 .
O14 Eu2 N4 C60 163.3(4) 3_576 .
O8 Eu2 N4 C60 150.1(3) 3_576 .
O13 Eu2 N4 C60 -54.5(5) . .
O3 Eu2 N4 C60 77.9(4) . .
O4 Eu2 N4 C60 43.0(4) . .
O9 Eu2 N4 C60 -87.1(4) . .
N3 Eu2 N4 C60 -2.9(4) . .
O8 Eu2 N4 C60 -126.1(4) . .
Eu2 Eu2 N4 C60 -154.2(3) 3_576 .
O12 Eu1 O1 C1 60.6(5) 3_666 .
O2 Eu1 O1 C1 -6.0(6) 3_666 .
O11 Eu1 O1 C1 -72.5(5) . .
O7 Eu1 O1 C1 -153.2(5) . .
O6 Eu1 O1 C1 112.9(5) . .
N2 Eu1 O1 C1 144.1(5) . .
N1 Eu1 O1 C1 -150.4(6) . .
Eu1 Eu1 O1 C1 0.5(5) 3_666 .
O14 Eu2 O3 C8 146.7(3) 3_576 .
O8 Eu2 O3 C8 75.6(3) 3_576 .
O13 Eu2 O3 C8 -0.6(4) . .
O4 Eu2 O3 C8 1.3(3) . .
O9 Eu2 O3 C8 -116.3(4) . .
N3 Eu2 O3 C8 -76.3(3) . .
O8 Eu2 O3 C8 127.1(4) . .
N4 Eu2 O3 C8 -140.6(4) . .
Eu2 Eu2 O3 C8 90.7(3) 3_576 .
O14 Eu2 O4 C8 -44.6(4) 3_576 .
O8 Eu2 O4 C8 -99.3(4) 3_576 .
O13 Eu2 O4 C8 177.1(4) . .
O3 Eu2 O4 C8 -1.3(3) . .
O9 Eu2 O4 C8 131.7(3) . .
N3 Eu2 O4 C8 85.2(4) . .
O8 Eu2 O4 C8 -152.8(3) . .
N4 Eu2 O4 C8 43.2(4) . .
Eu2 Eu2 O4 C8 -122.3(3) 3_576 .
O12 Eu1 O6 C15 -179.8(3) 3_666 .
O2 Eu1 O6 C15 -97.1(3) 3_666 .
O11 Eu1 O6 C15 -45.0(4) . .
O1 Eu1 O6 C15 128.0(3) . .
O7 Eu1 O6 C15 0.8(3) . .
N2 Eu1 O6 C15 95.4(3) . .
N1 Eu1 O6 C15 47.2(3) . .
Eu1 Eu1 O6 C15 -134.5(3) 3_666 .
O12 Eu1 O7 C15 -1.5(4) 3_666 .
O2 Eu1 O7 C15 71.2(3) 3_666 .
O11 Eu1 O7 C15 146.3(3) . .
O1 Eu1 O7 C15 -133.7(3) . .
O6 Eu1 O7 C15 -0.8(3) . .
N2 Eu1 O7 C15 -72.2(3) . .
N1 Eu1 O7 C15 -136.3(4) . .
Eu1 Eu1 O7 C15 88.9(3) 3_666 .
O14 Eu2 O8 C22 123.5(3) 3_576 .
O8 Eu2 O8 C22 -163.1(4) 3_576 .
O13 Eu2 O8 C22 -79.0(3) . .
O3 Eu2 O8 C22 143.6(3) . .
O4 Eu2 O8 C22 -110.0(3) . .
O9 Eu2 O8 C22 6.5(3) . .
N3 Eu2 O8 C22 -8.4(4) . .
N4 Eu2 O8 C22 56.0(3) . .
Eu2 Eu2 O8 C22 -163.1(4) 3_576 .
O14 Eu2 O8 Eu2 -73.38(13) 3_576 3_576
O8 Eu2 O8 Eu2 0.0 3_576 3_576
O13 Eu2 O8 Eu2 84.08(14) . 3_576
O3 Eu2 O8 Eu2 -53.3(3) . 3_576
O4 Eu2 O8 Eu2 53.1(2) . 3_576
O9 Eu2 O8 Eu2 169.7(2) . 3_576
N3 Eu2 O8 Eu2 154.73(15) . 3_576
N4 Eu2 O8 Eu2 -140.91(14) . 3_576
O14 Eu2 O9 C22 -68.2(3) 3_576 .
O8 Eu2 O9 C22 5.9(4) 3_576 .
O13 Eu2 O9 C22 69.5(3) . .
O3 Eu2 O9 C22 -159.2(3) . .
O4 Eu2 O9 C22 115.0(3) . .
N3 Eu2 O9 C22 160.5(4) . .
O8 Eu2 O9 C22 -6.8(3) . .
N4 Eu2 O9 C22 -133.5(4) . .
Eu2 Eu2 O9 C22 -0.7(3) 3_576 .
O12 Eu1 O11 C29 13.5(5) 3_666 .
O2 Eu1 O11 C29 -48.6(5) 3_666 .
O1 Eu1 O11 C29 83.9(5) . .
O7 Eu1 O11 C29 -135.7(5) . .
O6 Eu1 O11 C29 -100.3(5) . .
N2 Eu1 O11 C29 149.7(4) . .
N1 Eu1 O11 C29 151.1(5) . .
Eu1 Eu1 O11 C29 10.8(4) 3_666 .
O14 Eu2 O13 C36 -1.0(6) 3_576 .
O8 Eu2 O13 C36 45.2(5) 3_576 .
O3 Eu2 O13 C36 125.3(5) . .
O4 Eu2 O13 C36 123.7(5) . .
O9 Eu2 O13 C36 -88.2(5) . .
N3 Eu2 O13 C36 -163.9(5) . .
O8 Eu2 O13 C36 -35.0(5) . .
N4 Eu2 O13 C36 -119.6(5) . .
Eu2 Eu2 O13 C36 3.9(5) 3_576 .
Eu1 O1 C1 O2 -12.4(9) . .
Eu1 O1 C1 C2 167.3(4) . .
Eu1 O2 C1 O1 41.4(14) 3_666 .
Eu1 O2 C1 C2 -138.3(8) 3_666 .
O1 C1 C2 C3 28.9(9) . .
O2 C1 C2 C3 -151.5(6) . .
O1 C1 C2 C7 -150.7(6) . .
O2 C1 C2 C7 29.0(8) . .
C7 C2 C3 C4 0.1(9) . .
C1 C2 C3 C4 -179.5(6) . .
C7 C2 C3 O5 179.2(5) . .
C1 C2 C3 O5 -0.4(9) . .
C11 O5 C3 C2 100.3(6) . .
C11 O5 C3 C4 -80.5(7) . .
C2 C3 C4 C5 0.9(10) . .
O5 C3 C4 C5 -178.2(6) . .
C3 C4 C5 C6 -1.8(12) . .
C4 C5 C6 C7 1.7(13) . .
C5 C6 C7 C2 -0.7(12) . .
C3 C2 C7 C6 -0.2(10) . .
C1 C2 C7 C6 179.4(6) . .
Eu2 O4 C8 O3 2.3(6) . .
Eu2 O4 C8 C9 -177.3(5) . .
Eu2 O3 C8 O4 -2.3(6) . .
Eu2 O3 C8 C9 177.3(5) . .
O4 C8 C9 C14 21.2(9) . .
O3 C8 C9 C14 -158.4(6) . .
O4 C8 C9 C10 -159.5(6) . .
O3 C8 C9 C10 20.9(9) . .
C14 C9 C10 C11 -1.4(9) . .
C8 C9 C10 C11 179.4(5) . .
C9 C10 C11 C12 1.6(9) . .
C9 C10 C11 O5 -179.1(5) . .
C3 O5 C11 C10 153.2(5) . .
C3 O5 C11 C12 -27.6(8) . .
C10 C11 C12 C13 -1.0(9) . .
O5 C11 C12 C13 179.9(6) . .
C11 C12 C13 C14 0.1(10) . .
C10 C9 C14 C13 0.5(9) . .
C8 C9 C14 C13 179.8(6) . .
C12 C13 C14 C9 0.2(10) . .
Eu1 O6 C15 O7 -1.4(6) . .
Eu1 O6 C15 C16 179.5(4) . 2_646
Eu1 O7 C15 O6 1.4(6) . .
Eu1 O7 C15 C16 -179.5(4) . 2_646
C21 C16 C17 C18 0.5(9) . .
C15 C16 C17 C18 -176.3(5) 2_656 .
C24 O10 C18 C19 -1.0(8) . .
C24 O10 C18 C17 -178.3(5) . .
C16 C17 C18 C19 -1.9(9) . .
C16 C17 C18 O10 175.5(5) . .
O10 C18 C19 C20 -176.4(6) . .
C17 C18 C19 C20 0.9(9) . .
C18 C19 C20 C21 1.6(11) . .
C17 C16 C21 C20 1.9(10) . .
C15 C16 C21 C20 178.7(6) 2_656 .
C19 C20 C21 C16 -3.0(11) . .
Eu2 O9 C22 O8 12.7(6) . .
Eu2 O9 C22 C23 -164.2(4) . .
Eu2 O8 C22 O9 -137.8(8) 3_576 .
Eu2 O8 C22 O9 -11.8(5) . .
Eu2 O8 C22 C23 39.2(13) 3_576 .
Eu2 O8 C22 C23 165.2(4) . .
O9 C22 C23 C28 131.1(6) . .
O8 C22 C23 C28 -45.9(8) . .
O9 C22 C23 C24 -42.7(8) . .
O8 C22 C23 C24 140.3(5) . .
C28 C23 C24 C25 -0.1(9) . .
C22 C23 C24 C25 173.8(6) . .
C28 C23 C24 O10 -179.6(5) . .
C22 C23 C24 O10 -5.6(8) . .
C18 O10 C24 C25 86.0(7) . .
C18 O10 C24 C23 -94.5(6) . .
C23 C24 C25 C26 0.4(10) . .
O10 C24 C25 C26 179.8(6) . .
C24 C25 C26 C27 -0.2(10) . .
C25 C26 C27 C28 -0.2(11) . .
C24 C23 C28 C27 -0.3(9) . .
C22 C23 C28 C27 -174.1(5) . .
C26 C27 C28 C23 0.4(10) . .
Eu1 O11 C29 O12 -18.5(9) . .
Eu1 O11 C29 C30 158.6(4) . .
Eu1 O12 C29 O11 19.4(14) 3_666 .
Eu1 O12 C29 C30 -157.8(7) 3_666 .
O11 C29 C30 C31 40.9(9) . .
O12 C29 C30 C31 -141.7(6) . .
O11 C29 C30 C35 -138.1(6) . .
O12 C29 C30 C35 39.2(8) . .
C35 C30 C31 C32 0.4(9) . .
C29 C30 C31 C32 -178.6(6) . .
C35 C30 C31 O15 178.2(5) . 4_576
C29 C30 C31 O15 -0.9(9) . 4_576
O15 C31 C32 C33 -175.8(6) 4_576 .
C30 C31 C32 C33 1.9(10) . .
C31 C32 C33 C34 -4.0(11) . .
C32 C33 C34 C35 3.7(12) . .
C33 C34 C35 C30 -1.3(11) . .
C31 C30 C35 C34 -0.7(9) . .
C29 C30 C35 C34 178.4(6) . .
Eu2 O13 C36 O14 -15.4(9) . .
Eu2 O13 C36 C37 163.7(3) . .
Eu2 O14 C36 O13 24.5(9) 3_576 .
Eu2 O14 C36 C37 -154.5(4) 3_576 .
O13 C36 C37 C42 178.1(5) . .
O14 C36 C37 C42 -2.7(8) . .
O13 C36 C37 C38 -2.5(8) . .
O14 C36 C37 C38 176.7(5) . .
C42 C37 C38 C39 -1.6(8) . .
C36 C37 C38 C39 179.0(5) . .
C37 C38 C39 C40 1.4(9) . .
C37 C38 C39 O15 -173.2(5) . .
C31 O15 C39 C40 53.1(8) 4_575 .
C31 O15 C39 C38 -132.4(5) 4_575 .
C38 C39 C40 C41 -0.8(9) . .
O15 C39 C40 C41 173.4(6) . .
C39 C40 C41 C42 0.4(10) . .
C38 C37 C42 C41 1.2(8) . .
C36 C37 C42 C41 -179.5(5) . .
C40 C41 C42 C37 -0.6(9) . .
C47 N1 C43 C44 -0.2(9) . .
Eu1 N1 C43 C44 -169.5(5) . .
N1 C43 C44 C45 -0.2(10) . .
C43 C44 C45 C46 -0.1(10) . .
C44 C45 C46 C47 0.8(9) . .
C44 C45 C46 C53 -179.5(6) . .
C43 N1 C47 C46 0.9(8) . .
Eu1 N1 C47 C46 170.9(4) . .
C43 N1 C47 C48 179.0(5) . .
Eu1 N1 C47 C48 -10.9(6) . .
C45 C46 C47 N1 -1.2(9) . .
C53 C46 C47 N1 179.0(5) . .
C45 C46 C47 C48 -179.3(5) . .
C53 C46 C47 C48 1.0(8) . .
C52 N2 C48 C49 0.3(9) . .
Eu1 N2 C48 C49 -171.2(4) . .
C52 N2 C48 C47 -179.4(5) . .
Eu1 N2 C48 C47 9.2(7) . .
N1 C47 C48 N2 1.7(8) . .
C46 C47 C48 N2 179.9(5) . .
N1 C47 C48 C49 -178.0(5) . .
C46 C47 C48 C49 0.2(8) . .
N2 C48 C49 C50 0.3(9) . .
C47 C48 C49 C50 179.9(5) . .
N2 C48 C49 C54 179.8(5) . .
C47 C48 C49 C54 -0.6(9) . .
C48 C49 C50 C51 -1.4(10) . .
C54 C49 C50 C51 179.1(6) . .
C49 C50 C51 C52 2.1(11) . .
C48 N2 C52 C51 0.3(9) . .
Eu1 N2 C52 C51 171.9(5) . .
C50 C51 C52 N2 -1.5(10) . .
C47 C46 C53 C54 -1.7(9) . .
C45 C46 C53 C54 178.5(6) . .
C46 C53 C54 C49 1.3(10) . .
C48 C49 C54 C53 -0.2(10) . .
C50 C49 C54 C53 179.3(6) . .
C59 N3 C55 C56 0.7(9) . .
Eu2 N3 C55 C56 -176.2(5) . .
N3 C55 C56 C57 -0.7(10) . .
C55 C56 C57 C58 0.3(10) . .
C56 C57 C58 C59 0.0(9) . .
C56 C57 C58 C65 179.3(6) . .
C55 N3 C59 C58 -0.4(9) . .
Eu2 N3 C59 C58 176.4(4) . .
C55 N3 C59 C60 179.1(5) . .
Eu2 N3 C59 C60 -4.1(7) . .
C57 C58 C59 N3 0.1(9) . .
C65 C58 C59 N3 -179.3(5) . .
C57 C58 C59 C60 -179.4(5) . .
C65 C58 C59 C60 1.2(9) . .
C64 N4 C60 C61 4.1(8) . .
Eu2 N4 C60 C61 -177.7(4) . .
C64 N4 C60 C59 -176.0(5) . .
Eu2 N4 C60 C59 2.2(7) . .
N3 C59 C60 N4 1.1(8) . .
C58 C59 C60 N4 -179.4(5) . .
N3 C59 C60 C61 -179.0(5) . .
C58 C59 C60 C61 0.5(8) . .
N4 C60 C61 C62 -3.6(9) . .
C59 C60 C61 C62 176.5(5) . .
N4 C60 C61 C66 178.1(6) . .
C59 C60 C61 C66 -1.8(9) . .
C60 C61 C62 C63 0.7(10) . .
C66 C61 C62 C63 178.9(7) . .
C61 C62 C63 C64 1.5(10) . .
C60 N4 C64 C63 -1.8(9) . .
Eu2 N4 C64 C63 -179.9(4) . .
C62 C63 C64 N4 -0.9(10) . .
C57 C58 C65 C66 179.0(6) . .
C59 C58 C65 C66 -1.6(10) . .
C58 C65 C66 C61 0.3(11) . .
C62 C61 C66 C65 -176.8(7) . .
C60 C61 C66 C65 1.5(10) . .
