#------------------------------------------------------------------------------
#$Date: 2019-11-17 09:32:04 +0200 (Sun, 17 Nov 2019) $
#$Revision: 229120 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/12/7231284.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7231284
loop_
_publ_author_name
'Li, Shaodong'
'Lu, Liping'
'Zhu, Miaoli'
'Feng, Sisi'
'Su, Feng'
'Zhao, Xuefeng'
_publ_section_title
;
 Exploring the syntheses, structures, topologies, luminescence sensing and
 magnetism of Zn(ii) and Mn(ii) coordination polymers based on a semirigid
 tricarboxylate ligand
;
_journal_issue                   36
_journal_name_full               CrystEngComm
_journal_page_first              5442
_journal_paper_doi               10.1039/C8CE00947C
_journal_volume                  20
_journal_year                    2018
_chemical_formula_moiety         'C25 H16 N2 O8 Zn2, H2 O'
_chemical_formula_sum            'C25 H18 N2 O9 Zn2'
_chemical_formula_weight         621.15
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2018-05-02 deposited with the CCDC.
2018-08-03 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 120.16(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   12.390(3)
_cell_length_b                   16.177(3)
_cell_length_c                   13.367(6)
_cell_measurement_reflns_used    6215
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      29.10
_cell_measurement_theta_min      1.83
_cell_volume                     2316.5(13)
_computing_cell_refinement       'HKL 2000'
_computing_data_collection       mar555
_computing_data_reduction        'HKL 2000'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.953
_diffrn_measurement_device_type  mar555
_diffrn_measurement_method       'oscillation mode'
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.7100
_diffrn_reflns_av_R_equivalents  0.000
_diffrn_reflns_av_unetI/netI     0.0245
_diffrn_reflns_Laue_measured_fraction_full 0.991
_diffrn_reflns_Laue_measured_fraction_max 0.953
_diffrn_reflns_number            6026
_diffrn_reflns_point_group_measured_fraction_full 0.991
_diffrn_reflns_point_group_measured_fraction_max 0.953
_diffrn_reflns_theta_full        25.214
_diffrn_reflns_theta_max         29.258
_diffrn_reflns_theta_min         2.163
_diffrn_source                   'synchrotron, 3W1A at BSRF'
_exptl_absorpt_coefficient_mu    2.133
_exptl_absorpt_correction_T_max  0.809
_exptl_absorpt_correction_T_min  0.808
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.781
_exptl_crystal_description       block
_exptl_crystal_F_000             1256
_exptl_crystal_size_max          0.100
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.100
_refine_diff_density_max         1.739
_refine_diff_density_min         -1.690
_refine_diff_density_rms         0.198
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     334
_refine_ls_number_reflns         6026
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.068
_refine_ls_R_factor_all          0.0804
_refine_ls_R_factor_gt           0.0762
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1067P)²+26.8107P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2339
_refine_ls_wR_factor_ref         0.2364
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5405
_reflns_number_total             6026
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c8ce00947c2.cif
_cod_data_source_block           complex4
_cod_depositor_comments
'Adding full bibliography for 7231282--7231285.cif.'
_cod_database_code               7231284
_shelx_shelxl_version_number     2016/6
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.815
_shelx_estimated_absorpt_t_max   0.815
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Zn1 Zn 0.48978(6) 0.59706(4) 0.52422(6) 0.02188(19) Uani 1 1 d . .
Zn2 Zn 0.28737(6) 0.55333(4) 0.24956(6) 0.02349(19) Uani 1 1 d . .
O1 O 0.3835(4) 0.5077(2) 0.4060(3) 0.0215(7) Uani 1 1 d . .
H1A H 0.347253 0.484644 0.436113 0.032 Uiso 1 1 d R U
O2 O -0.1228(5) 1.0091(3) 0.1778(5) 0.0413(12) Uani 1 1 d . .
O3 O -0.1510(4) 0.9697(3) 0.3220(4) 0.0322(10) Uani 1 1 d . .
O4 O 0.2546(5) 0.6703(3) 0.2604(4) 0.0304(9) Uani 1 1 d . .
O5 O 0.3432(4) 0.6841(3) 0.4539(4) 0.0319(10) Uani 1 1 d . .
O6 O 0.0277(4) 0.8667(3) 0.4839(4) 0.0288(9) Uani 1 1 d . .
O7 O 0.5861(5) 0.6335(3) 0.4355(5) 0.0379(11) Uani 1 1 d . .
O8 O 0.6365(5) 0.6951(3) 0.5989(5) 0.0392(11) Uani 1 1 d . .
N1 N 0.3398(5) 0.5587(3) 1.1291(4) 0.0240(9) Uani 1 1 d . .
N2 N 0.4559(5) 0.5909(3) 0.6622(4) 0.0227(9) Uani 1 1 d . .
C1 C -0.0994(6) 0.9619(4) 0.2619(6) 0.0287(12) Uani 1 1 d . .
C2 C -0.0037(5) 0.8944(4) 0.2909(6) 0.0257(11) Uani 1 1 d . .
C3 C 0.0301(6) 0.8761(4) 0.2086(5) 0.0275(12) Uani 1 1 d . .
H3 H -0.005685 0.906705 0.138515 0.033 Uiso 1 1 calc R U
C4 C 0.1151(6) 0.8137(4) 0.2272(6) 0.0290(12) Uani 1 1 d . .
H4 H 0.134610 0.800542 0.168800 0.035 Uiso 1 1 calc R U
C5 C 0.1720(5) 0.7702(4) 0.3317(6) 0.0261(11) Uani 1 1 d . .
C6 C 0.1417(5) 0.7889(4) 0.4160(5) 0.0258(11) Uani 1 1 d . .
H6 H 0.181932 0.760594 0.488061 0.031 Uiso 1 1 calc R U
C7 C 0.0516(5) 0.8497(4) 0.3949(5) 0.0259(11) Uani 1 1 d . .
C8 C 0.2646(5) 0.7027(4) 0.3522(5) 0.0256(11) Uani 1 1 d . .
C9 C -0.0649(5) 0.8221(4) 0.4874(5) 0.0258(11) Uani 1 1 d . .
C10 C -0.1378(6) 0.7631(4) 0.4025(6) 0.0327(13) Uani 1 1 d . .
H10 H -0.125359 0.753300 0.338910 0.039 Uiso 1 1 calc R U
C11 C -0.2286(7) 0.7194(4) 0.4132(7) 0.0350(14) Uani 1 1 d . .
H11 H -0.278014 0.679446 0.356315 0.042 Uiso 1 1 calc R U
C12 C -0.2481(6) 0.7333(4) 0.5068(6) 0.0314(13) Uani 1 1 d . .
C13 C -0.1767(6) 0.7929(4) 0.5881(6) 0.0322(13) Uani 1 1 d . .
H13 H -0.190536 0.803954 0.650587 0.039 Uiso 1 1 calc R U
C14 C -0.0840(6) 0.8371(4) 0.5794(6) 0.0302(12) Uani 1 1 d . .
H14 H -0.034796 0.877142 0.636235 0.036 Uiso 1 1 calc R U
C15 C 0.6540(6) 0.6853(4) 0.5152(6) 0.0326(14) Uani 1 1 d . .
C16 C 0.2790(6) 0.5120(4) 1.0352(6) 0.0310(13) Uani 1 1 d . .
H16 H 0.219995 0.473018 1.032036 0.037 Uiso 1 1 calc R U
C17 C 0.2979(6) 0.5175(4) 0.9412(6) 0.0307(13) Uani 1 1 d . .
H17 H 0.253025 0.482626 0.875832 0.037 Uiso 1 1 calc R U
C18 C 0.3836(5) 0.5750(4) 0.9439(5) 0.0239(11) Uani 1 1 d . .
C19 C 0.4475(6) 0.6243(4) 1.0430(6) 0.0291(12) Uani 1 1 d . .
H19 H 0.506337 0.664220 1.048311 0.035 Uiso 1 1 calc R U
C20 C 0.4238(6) 0.6139(4) 1.1338(6) 0.0294(12) Uani 1 1 d . .
H20 H 0.468284 0.646952 1.201234 0.035 Uiso 1 1 calc R U
C21 C 0.4053(5) 0.5820(4) 0.8444(5) 0.0232(11) Uani 1 1 d . .
C22 C 0.3363(9) 0.5380(6) 0.7436(7) 0.050(2) Uani 1 1 d . .
H22 H 0.269435 0.503878 0.734156 0.060 Uiso 1 1 calc R U
C23 C 0.3649(9) 0.5436(6) 0.6557(7) 0.051(2) Uani 1 1 d . .
H23 H 0.316902 0.512069 0.587384 0.062 Uiso 1 1 calc R U
C24 C 0.5187(9) 0.6338(6) 0.7560(7) 0.051(2) Uani 1 1 d . .
H24 H 0.583377 0.668618 0.761858 0.062 Uiso 1 1 calc R U
C25 C 0.4972(9) 0.6319(6) 0.8484(7) 0.055(3) Uani 1 1 d . .
H25 H 0.546281 0.665192 0.914584 0.065 Uiso 1 1 calc R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Zn1 N2 108.06(19) . .
O1 Zn1 O5 92.94(17) . .
N2 Zn1 O5 85.15(19) . .
O1 Zn1 O7 95.00(19) . .
N2 Zn1 O7 156.3(2) . .
O5 Zn1 O7 99.4(2) . .
O1 Zn1 O1 80.08(17) . 3_666
N2 Zn1 O1 90.32(17) . 3_666
O5 Zn1 O1 170.09(17) . 3_666
O7 Zn1 O1 88.24(17) . 3_666
O1 Zn1 O8 154.83(17) . .
N2 Zn1 O8 96.8(2) . .
O5 Zn1 O8 92.9(2) . .
O7 Zn1 O8 59.9(2) . .
O1 Zn1 O8 96.43(18) 3_666 .
O1 Zn1 C15 125.3(2) . .
N2 Zn1 C15 126.2(2) . .
O5 Zn1 C15 97.7(2) . .
O7 Zn1 C15 30.3(2) . .
O1 Zn1 C15 92.05(18) 3_666 .
O8 Zn1 C15 29.6(2) . .
O4 Zn2 O1 108.85(18) . .
O4 Zn2 O3 122.3(2) . 2_545
O1 Zn2 O3 99.85(18) . 2_545
O4 Zn2 N1 100.3(2) . 1_554
O1 Zn2 N1 126.96(19) . 1_554
O3 Zn2 N1 100.4(2) 2_545 1_554
Zn2 O1 Zn1 111.55(19) . .
Zn2 O1 Zn1 132.2(2) . 3_666
Zn1 O1 Zn1 99.92(16) . 3_666
Zn2 O1 H1A 120.1 . .
Zn1 O1 H1A 103.7 . .
Zn1 O1 H1A 83.7 3_666 .
C1 O3 Zn2 109.9(4) . 2
C8 O4 Zn2 122.9(4) . .
C8 O5 Zn1 132.2(4) . .
C9 O6 C7 117.7(5) . .
C15 O7 Zn1 92.0(4) . .
C15 O8 Zn1 88.7(4) . .
C16 N1 C20 118.6(5) . .
C16 N1 Zn2 118.2(4) . 1_556
C20 N1 Zn2 122.8(4) . 1_556
C24 N2 C23 116.7(6) . .
C24 N2 Zn1 122.6(5) . .
C23 N2 Zn1 120.6(4) . .
O3 C1 O2 122.8(6) . .
O3 C1 C2 119.5(6) . .
O2 C1 C2 117.7(6) . .
C3 C2 C7 118.8(6) . .
C3 C2 C1 117.4(6) . .
C7 C2 C1 123.8(6) . .
C4 C3 C2 121.1(6) . .
C4 C3 H3 119.5 . .
C2 C3 H3 119.5 . .
C3 C4 C5 120.1(6) . .
C3 C4 H4 120.0 . .
C5 C4 H4 120.0 . .
C6 C5 C4 119.7(6) . .
C6 C5 C8 120.2(6) . .
C4 C5 C8 120.2(6) . .
C5 C6 C7 120.1(6) . .
C5 C6 H6 120.0 . .
C7 C6 H6 120.0 . .
O6 C7 C2 122.5(6) . .
O6 C7 C6 117.1(5) . .
C2 C7 C6 120.2(6) . .
O5 C8 O4 126.3(6) . .
O5 C8 C5 118.6(5) . .
O4 C8 C5 115.1(5) . .
O6 C9 C14 117.0(6) . .
O6 C9 C10 122.4(6) . .
C14 C9 C10 120.6(6) . .
C11 C10 C9 118.9(6) . .
C11 C10 H10 120.5 . .
C9 C10 H10 120.5 . .
C10 C11 C12 121.2(6) . .
C10 C11 H11 119.4 . .
C12 C11 H11 119.4 . .
C13 C12 C11 118.7(6) . .
C13 C12 C15 121.7(6) . 1_455
C11 C12 C15 119.6(6) . 1_455
C12 C13 C14 120.9(6) . .
C12 C13 H13 119.5 . .
C14 C13 H13 119.5 . .
C9 C14 C13 119.6(6) . .
C9 C14 H14 120.2 . .
C13 C14 H14 120.2 . .
O8 C15 O7 119.3(6) . .
O8 C15 C12 120.9(7) . 1_655
O7 C15 C12 119.8(6) . 1_655
O8 C15 Zn1 61.7(4) . .
O7 C15 Zn1 57.6(3) . .
C12 C15 Zn1 176.9(5) 1_655 .
N1 C16 C17 122.9(6) . .
N1 C16 H16 118.5 . .
C17 C16 H16 118.5 . .
C16 C17 C18 119.3(6) . .
C16 C17 H17 120.3 . .
C18 C17 H17 120.3 . .
C17 C18 C19 117.6(6) . .
C17 C18 C21 120.2(5) . .
C19 C18 C21 122.2(5) . .
C20 C19 C18 119.3(6) . .
C20 C19 H19 120.4 . .
C18 C19 H19 120.4 . .
N1 C20 C19 122.2(6) . .
N1 C20 H20 118.9 . .
C19 C20 H20 118.9 . .
C25 C21 C22 115.9(6) . .
C25 C21 C18 121.9(6) . .
C22 C21 C18 122.2(6) . .
C21 C22 C23 119.8(7) . .
C21 C22 H22 120.1 . .
C23 C22 H22 120.1 . .
N2 C23 C22 123.4(7) . .
N2 C23 H23 118.3 . .
C22 C23 H23 118.3 . .
N2 C24 C25 124.0(7) . .
N2 C24 H24 118.0 . .
C25 C24 H24 118.0 . .
C21 C25 C24 120.2(7) . .
C21 C25 H25 119.9 . .
C24 C25 H25 119.9 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 O1 2.057(4) .
Zn1 N2 2.089(5) .
Zn1 O5 2.110(4) .
Zn1 O7 2.145(5) .
Zn1 O1 2.177(4) 3_666
Zn1 O8 2.235(6) .
Zn1 C15 2.537(7) .
Zn2 O4 1.956(4) .
Zn2 O1 1.957(4) .
Zn2 O3 1.994(5) 2_545
Zn2 N1 2.018(5) 1_554
O1 H1A 0.8282 .
O2 C1 1.266(8) .
O3 C1 1.261(8) .
O4 C8 1.282(8) .
O5 C8 1.248(8) .
O6 C9 1.376(7) .
O6 C7 1.390(7) .
O7 C15 1.283(9) .
O8 C15 1.252(9) .
N1 C16 1.328(8) .
N1 C20 1.349(8) .
N2 C24 1.295(9) .
N2 C23 1.328(9) .
C1 C2 1.512(8) .
C2 C3 1.392(9) .
C2 C7 1.403(9) .
C3 C4 1.388(9) .
C3 H3 0.9500 .
C4 C5 1.398(9) .
C4 H4 0.9500 .
C5 C6 1.389(9) .
C5 C8 1.505(8) .
C6 C7 1.406(8) .
C6 H6 0.9500 .
C9 C14 1.386(9) .
C9 C10 1.408(9) .
C10 C11 1.396(9) .
C10 H10 0.9500 .
C11 C12 1.407(10) .
C11 H11 0.9500 .
C12 C13 1.389(10) .
C12 C15 1.491(9) 1_455
C13 C14 1.407(9) .
C13 H13 0.9500 .
C14 H14 0.9500 .
C16 C17 1.392(9) .
C16 H16 0.9500 .
C17 C18 1.398(8) .
C17 H17 0.9500 .
C18 C19 1.401(9) .
C18 C21 1.488(8) .
C19 C20 1.395(9) .
C19 H19 0.9500 .
C20 H20 0.9500 .
C21 C25 1.375(9) .
C21 C22 1.377(9) .
C22 C23 1.391(10) .
C22 H22 0.9500 .
C23 H23 0.9500 .
C24 C25 1.388(10) .
C24 H24 0.9500 .
C25 H25 0.9500 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1 H1A O2 0.83 2.44 2.838(6) 110.5 2_545
O1 H1A O7 0.83 2.42 3.008(6) 128.8 3_666
C16 H16 O3 0.95 2.49 3.109(8) 122.6 2_546
C24 H24 O8 0.95 2.61 3.256(9) 125.8 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Zn2 O3 C1 O2 8.3(8) 2 .
Zn2 O3 C1 C2 -172.6(4) 2 .
O3 C1 C2 C3 166.0(6) . .
O2 C1 C2 C3 -14.9(9) . .
O3 C1 C2 C7 -13.6(9) . .
O2 C1 C2 C7 165.5(6) . .
C7 C2 C3 C4 1.2(9) . .
C1 C2 C3 C4 -178.5(6) . .
C2 C3 C4 C5 -2.4(9) . .
C3 C4 C5 C6 0.9(9) . .
C3 C4 C5 C8 -179.8(5) . .
C4 C5 C6 C7 1.8(9) . .
C8 C5 C6 C7 -177.4(5) . .
C9 O6 C7 C2 94.1(7) . .
C9 O6 C7 C6 -90.5(7) . .
C3 C2 C7 O6 176.8(5) . .
C1 C2 C7 O6 -3.5(9) . .
C3 C2 C7 C6 1.6(9) . .
C1 C2 C7 C6 -178.8(5) . .
C5 C6 C7 O6 -178.6(5) . .
C5 C6 C7 C2 -3.1(9) . .
Zn1 O5 C8 O4 0.0(10) . .
Zn1 O5 C8 C5 -179.0(4) . .
Zn2 O4 C8 O5 35.6(9) . .
Zn2 O4 C8 C5 -145.3(4) . .
C6 C5 C8 O5 -24.4(8) . .
C4 C5 C8 O5 156.3(6) . .
C6 C5 C8 O4 156.4(6) . .
C4 C5 C8 O4 -22.8(8) . .
C7 O6 C9 C14 177.3(5) . .
C7 O6 C9 C10 -2.4(9) . .
O6 C9 C10 C11 178.9(6) . .
C14 C9 C10 C11 -0.8(10) . .
C9 C10 C11 C12 0.1(11) . .
C10 C11 C12 C13 1.2(10) . .
C10 C11 C12 C15 180.0(6) . 1_455
C11 C12 C13 C14 -1.7(9) . .
C15 C12 C13 C14 179.5(6) 1_455 .
O6 C9 C14 C13 -179.4(5) . .
C10 C9 C14 C13 0.3(9) . .
C12 C13 C14 C9 1.0(10) . .
Zn1 O8 C15 O7 2.3(6) . .
Zn1 O8 C15 C12 -178.0(5) . 1_655
Zn1 O7 C15 O8 -2.4(6) . .
Zn1 O7 C15 C12 177.9(5) . 1_655
C20 N1 C16 C17 -0.1(10) . .
Zn2 N1 C16 C17 172.7(5) 1_556 .
N1 C16 C17 C18 -0.6(10) . .
C16 C17 C18 C19 0.5(9) . .
C16 C17 C18 C21 180.0(6) . .
C17 C18 C19 C20 0.2(9) . .
C21 C18 C19 C20 -179.3(6) . .
C16 N1 C20 C19 0.9(10) . .
Zn2 N1 C20 C19 -171.6(5) 1_556 .
C18 C19 C20 N1 -0.9(10) . .
C17 C18 C21 C25 -173.5(8) . .
C19 C18 C21 C25 6.0(10) . .
C17 C18 C21 C22 5.3(10) . .
C19 C18 C21 C22 -175.3(7) . .
C25 C21 C22 C23 2.2(14) . .
C18 C21 C22 C23 -176.6(8) . .
C24 N2 C23 C22 -0.7(15) . .
Zn1 N2 C23 C22 -178.8(8) . .
C21 C22 C23 N2 -0.9(16) . .
C23 N2 C24 C25 1.0(15) . .
Zn1 N2 C24 C25 179.0(8) . .
C22 C21 C25 C24 -2.0(14) . .
C18 C21 C25 C24 176.8(8) . .
N2 C24 C25 C21 0.4(17) . .
