#------------------------------------------------------------------------------
#$Date: 2018-12-19 04:34:32 +0200 (Wed, 19 Dec 2018) $
#$Revision: 212651 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/20/7232024.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7232024
loop_
_publ_author_name
'Wang, Wenbo'
'Wang, Ruiying'
'Ge, Yafang'
'Wu, Benlai'
_publ_section_title
;
 Color tuning and white light emission by codoping in isostructural
 homochiral lanthanide metal--organic frameworks
;
_journal_issue                   73
_journal_name_full               'RSC Advances'
_journal_page_first              42100
_journal_paper_doi               10.1039/C8RA06793G
_journal_volume                  8
_journal_year                    2018
_chemical_absolute_configuration rm
_chemical_formula_moiety         'C24 H30 Eu2 N2 O16, 2(Cl), 5(H2 O)'
_chemical_formula_sum            'C24 H40 Cl2 Eu2 N2 O21'
_chemical_formula_weight         1067.40
_chemical_name_common            'C24 H40 Cl2 Eu2 N2 O21'
_space_group_crystal_system      triclinic
_space_group_IT_number           1
_space_group_name_Hall           'P 1'
_space_group_name_H-M_alt        'P 1'
_symmetry_space_group_name_Hall  'P 1'
_symmetry_space_group_name_H-M   'P 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2018-07-01 deposited with the CCDC.
2018-12-13 downloaded from the CCDC.
;
_cell_angle_alpha                104.824(3)
_cell_angle_beta                 93.710(5)
_cell_angle_gamma                109.569(5)
_cell_formula_units_Z            1
_cell_length_a                   9.6686(6)
_cell_length_b                   10.0202(4)
_cell_length_c                   10.8727(4)
_cell_measurement_reflns_used    5232
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.5850
_cell_measurement_theta_min      3.9140
_cell_volume                     946.31(9)
_computing_structure_refinement  'SHELXL-2017/1 (Sheldrick, 2017)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0542
_diffrn_reflns_av_unetI/netI     0.0913
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            14889
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.371
_diffrn_reflns_theta_min         3.394
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    3.506
_exptl_absorpt_correction_T_max  0.841
_exptl_absorpt_correction_T_min  0.673
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   CrysAlisPro
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.873
_exptl_crystal_description       block
_exptl_crystal_F_000             526
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.06
_refine_diff_density_max         3.370
_refine_diff_density_min         -2.031
_refine_diff_density_rms         0.193
_refine_ls_abs_structure_details
;
 Flack x determined using 2492 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.20(3)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     486
_refine_ls_number_reflns         7672
_refine_ls_number_restraints     194
_refine_ls_restrained_S_all      1.041
_refine_ls_R_factor_all          0.0723
_refine_ls_R_factor_gt           0.0603
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0500P)²+6.3484P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1298
_refine_ls_wR_factor_ref         0.1427
_reflns_Friedel_coverage         0.988
_reflns_Friedel_fraction_full    0.990
_reflns_Friedel_fraction_max     0.986
_reflns_number_gt                6514
_reflns_number_total             7672
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c8ra06793g2.cif
_cod_data_source_block           II
_cod_original_cell_volume        946.31(8)
_cod_database_code               7232024
_shelx_shelxl_version_number     2017/1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Eu1 Eu 0.69640(7) 0.39466(7) 0.47663(7) 0.0260(4) Uani 1 1 d D .
Eu2 Eu 1.02998(7) 0.24809(7) 0.55522(7) 0.0266(4) Uani 1 1 d D .
Cl1 Cl 0.3338(16) 0.0455(14) 0.0862(11) 0.064(4) Uani 1 1 d . .
Cl2 Cl 0.3741(14) 0.5917(13) 0.9587(11) 0.055(3) Uani 1 1 d . .
O1 O 0.548(2) 0.516(2) 0.605(2) 0.028(5) Uani 1 1 d . U
O2 O 0.7281(17) 0.6596(17) 0.5345(16) 0.031(4) Uani 1 1 d . U
O3 O 0.7750(17) 1.1880(17) 0.5654(16) 0.025(4) Uani 1 1 d . U
O4 O 0.568(2) 1.224(2) 0.589(2) 0.031(5) Uani 1 1 d . .
O5 O -0.164(2) 0.4997(19) 0.6939(17) 0.026(4) Uani 1 1 d . U
O6 O 0.058(2) 0.481(2) 0.713(2) 0.033(6) Uani 1 1 d . .
O7 O 0.444(3) 0.298(3) 0.349(2) 0.046(6) Uani 1 1 d D U
O8 O 0.704(4) 0.454(3) 0.266(3) 0.078(10) Uani 1 1 d D .
O9 O 0.183(2) 0.130(3) 0.430(3) 0.038(7) Uani 1 1 d . .
O10 O 0.0248(18) -0.0002(18) 0.5316(16) 0.036(4) Uani 1 1 d . U
O11 O -0.0601(18) -0.5427(19) 0.4402(16) 0.031(4) Uani 1 1 d . U
O12 O 0.149(3) -0.590(3) 0.435(3) 0.043(6) Uani 1 1 d . U
O13 O 0.889(2) 0.120(2) 0.339(2) 0.037(5) Uani 1 1 d . U
O14 O 0.676(3) 0.166(3) 0.320(3) 0.039(6) Uani 1 1 d . U
O15 O 1.027(3) 0.205(4) 0.764(2) 0.065(9) Uani 1 1 d D .
O16 O 1.283(2) 0.359(2) 0.667(2) 0.029(5) Uani 1 1 d D U
O17 O 0.434(3) 0.442(3) 0.145(3) 0.142(12) Uani 1 1 d . .
O18 O 0.652(4) 0.283(3) 0.016(3) 0.151(12) Uani 1 1 d . .
O19 O 1.009(6) -0.068(6) 0.168(5) 0.25(2) Uani 1 1 d . U
O20 O 1.115(4) 0.233(4) 1.156(4) 0.143(12) Uani 1 1 d . U
O21 O -0.353(3) 0.492(3) 0.895(3) 0.104(8) Uani 1 1 d . U
N1 N 0.192(3) 0.767(3) 0.845(2) 0.031(6) Uani 1 1 d D U
H1A H 0.237329 0.844035 0.917926 0.038 Uiso 1 1 calc R U
H1B H 0.240733 0.702362 0.839979 0.038 Uiso 1 1 calc R U
N2 N 0.534(3) -0.117(3) 0.179(2) 0.023(5) Uani 1 1 d D U
H2A H 0.488542 -0.191135 0.103883 0.028 Uiso 1 1 calc R U
H2B H 0.491632 -0.047739 0.185508 0.028 Uiso 1 1 calc R U
C1 C 0.618(3) 0.640(3) 0.586(3) 0.024(7) Uani 1 1 d D U
C2 C 0.558(3) 0.762(2) 0.627(2) 0.013(5) Uani 1 1 d D .
C3 C 0.645(3) 0.902(2) 0.619(3) 0.018(6) Uani 1 1 d D U
H3 H 0.740952 0.921397 0.596121 0.022 Uiso 1 1 calc R U
C4 C 0.584(3) 1.013(3) 0.646(3) 0.028(7) Uani 1 1 d D U
C5 C 0.643(4) 1.151(4) 0.601(4) 0.034(8) Uani 1 1 d . U
C6 C 0.447(3) 0.987(3) 0.690(3) 0.030(8) Uani 1 1 d D .
H6 H 0.407341 1.063939 0.709228 0.036 Uiso 1 1 calc R U
C7 C 0.368(2) 0.850(3) 0.707(3) 0.023(6) Uani 1 1 d D .
H7A H 0.392(18) 0.224(12) 0.37(2) 0.035 Uiso 1 1 d D U
H15A H 1.04(2) 0.256(10) 0.841(7) 0.035 Uiso 1 1 d D U
H8B H 0.69(3) 0.423(16) 0.185(4) 0.035 Uiso 1 1 d D U
H15B H 0.97(2) 0.121(8) 0.767(4) 0.035 Uiso 1 1 d D U
H16A H 1.364(13) 0.40(2) 0.64(2) 0.035 Uiso 1 1 d D U
H7B H 0.398(6) 0.356(8) 0.371(11) 0.035 Uiso 1 1 d D U
H16B H 1.29(2) 0.40(2) 0.746(5) 0.035 Uiso 1 1 d D U
H8A H 0.69(2) 0.532(12) 0.274(6) 0.035 Uiso 1 1 d D U
C8 C 0.429(4) 0.739(3) 0.679(3) 0.027(7) Uani 1 1 d D .
H8 H 0.380474 0.647190 0.695460 0.033 Uiso 1 1 calc R U
C9 C 0.210(3) 0.824(4) 0.732(3) 0.035(8) Uani 1 1 d D .
H9A H 0.192297 0.918593 0.749303 0.042 Uiso 1 1 calc R U
H9B H 0.138379 0.751856 0.655275 0.042 Uiso 1 1 calc R U
C10 C 0.034(4) 0.690(3) 0.860(2) 0.024(7) Uani 1 1 d D U
H10 H 0.033129 0.664845 0.942970 0.029 Uiso 1 1 calc R U
C11 C -0.057(2) 0.792(2) 0.858(3) 0.060(7) Uani 1 1 d . .
H11A H -0.017578 0.879567 0.934297 0.090 Uiso 1 1 calc R U
H11B H -0.161759 0.737442 0.859820 0.090 Uiso 1 1 calc R U
H11C H -0.049154 0.823612 0.779959 0.090 Uiso 1 1 calc R U
C12 C -0.033(3) 0.545(3) 0.746(3) 0.021(6) Uani 1 1 d D U
C13 C 0.124(3) 0.013(3) 0.457(3) 0.032(8) Uani 1 1 d D .
C14 C 0.165(4) -0.124(3) 0.404(4) 0.051(10) Uani 1 1 d D U
C15 C 0.090(3) -0.258(3) 0.425(3) 0.034(8) Uani 1 1 d D .
H15 H 0.000291 -0.273383 0.459501 0.040 Uiso 1 1 calc R U
C16 C 0.149(3) -0.370(3) 0.396(3) 0.025(7) Uani 1 1 d D .
C17 C 0.072(3) -0.512(3) 0.425(3) 0.024(7) Uani 1 1 d D .
C18 C 0.284(3) -0.345(3) 0.351(3) 0.027(7) Uani 1 1 d D U
H18 H 0.321625 -0.422617 0.330490 0.033 Uiso 1 1 calc R U
C19 C 0.363(3) -0.213(3) 0.336(3) 0.034(8) Uani 1 1 d D U
C20 C 0.309(4) -0.096(3) 0.366(3) 0.024(6) Uani 1 1 d . U
H20 H 0.366920 -0.000769 0.362023 0.029 Uiso 1 1 calc R U
C21 C 0.511(3) -0.179(4) 0.290(3) 0.029(7) Uani 1 1 d D U
H21A H 0.587218 -0.108585 0.364558 0.035 Uiso 1 1 calc R U
H21B H 0.531222 -0.272169 0.268190 0.035 Uiso 1 1 calc R U
C22 C 0.695(4) -0.049(3) 0.174(2) 0.047(12) Uani 1 1 d D .
H22 H 0.747910 -0.118775 0.177948 0.057 Uiso 1 1 calc R U
C23 C 0.699(3) -0.010(3) 0.044(2) 0.064(8) Uani 1 1 d D .
H23A H 0.663199 -0.102027 -0.027717 0.096 Uiso 1 1 calc R U
H23B H 0.801932 0.048255 0.040064 0.096 Uiso 1 1 calc R U
H23C H 0.635918 0.047016 0.039078 0.096 Uiso 1 1 calc R U
C24 C 0.755(4) 0.092(3) 0.291(3) 0.038(9) Uani 1 1 d D .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O11 Eu1 O4 128.3(7) 1_665 1_545
O11 Eu1 O14 80.6(8) 1_665 .
O4 Eu1 O14 81.5(9) 1_545 .
O11 Eu1 O5 77.6(6) 1_665 1_655
O4 Eu1 O5 76.1(7) 1_545 1_655
O14 Eu1 O5 127.6(7) . 1_655
O11 Eu1 O1 137.2(7) 1_665 .
O4 Eu1 O1 74.9(8) 1_545 .
O14 Eu1 O1 142.1(8) . .
O5 Eu1 O1 74.7(7) 1_655 .
O11 Eu1 O7 138.2(7) 1_665 .
O4 Eu1 O7 80.7(7) 1_545 .
O14 Eu1 O7 74.5(8) . .
O5 Eu1 O7 143.9(7) 1_655 .
O1 Eu1 O7 72.8(7) . .
O11 Eu1 O2 89.4(5) 1_665 .
O4 Eu1 O2 124.8(7) 1_545 .
O14 Eu1 O2 151.1(7) . .
O5 Eu1 O2 75.4(6) 1_655 .
O1 Eu1 O2 52.4(6) . .
O7 Eu1 O2 96.5(7) . .
O11 Eu1 O8 72.5(10) 1_665 .
O4 Eu1 O8 145.8(10) 1_545 .
O14 Eu1 O8 75.6(9) . .
O5 Eu1 O8 138.2(9) 1_655 .
O1 Eu1 O8 109.1(9) . .
O7 Eu1 O8 69.0(10) . .
O2 Eu1 O8 75.6(7) . .
O11 Eu1 O3 80.3(5) 1_665 1_545
O4 Eu1 O3 48.6(6) 1_545 1_545
O14 Eu1 O3 62.1(7) . 1_545
O5 Eu1 O3 67.5(5) 1_655 1_545
O1 Eu1 O3 117.0(6) . 1_545
O7 Eu1 O3 115.0(6) . 1_545
O2 Eu1 O3 142.8(5) . 1_545
O8 Eu1 O3 132.7(8) . 1_545
O11 Eu1 C1 113.9(8) 1_665 .
O4 Eu1 C1 101.2(9) 1_545 .
O14 Eu1 C1 156.3(8) . .
O5 Eu1 C1 75.4(8) 1_655 .
O1 Eu1 C1 26.9(8) . .
O7 Eu1 C1 82.6(9) . .
O2 Eu1 C1 25.6(7) . .
O8 Eu1 C1 90.6(10) . .
O3 Eu1 C1 136.2(7) 1_545 .
O11 Eu1 C5 106.1(8) 1_665 1_545
O4 Eu1 C5 22.7(9) 1_545 1_545
O14 Eu1 C5 69.7(10) . 1_545
O5 Eu1 C5 71.6(8) 1_655 1_545
O1 Eu1 C5 95.4(9) . 1_545
O7 Eu1 C5 96.1(9) . 1_545
O2 Eu1 C5 139.1(8) . 1_545
O8 Eu1 C5 144.9(10) . 1_545
O3 Eu1 C5 26.0(8) 1_545 1_545
C1 Eu1 C5 119.9(10) . 1_545
O11 Eu1 Eu2 46.8(4) 1_665 .
O4 Eu1 Eu2 81.6(5) 1_545 .
O14 Eu1 Eu2 67.0(6) . .
O5 Eu1 Eu2 63.3(4) 1_655 .
O1 Eu1 Eu2 135.7(5) . .
O7 Eu1 Eu2 139.4(6) . .
O2 Eu1 Eu2 123.5(4) . .
O8 Eu1 Eu2 111.3(9) . .
O3 Eu1 Eu2 33.7(3) 1_545 .
C1 Eu1 Eu2 136.7(6) . .
C5 Eu1 Eu2 59.3(7) 1_545 .
O3 Eu2 O12 120.4(8) 1_545 1_665
O3 Eu2 O16 148.4(6) 1_545 .
O12 Eu2 O16 77.6(8) 1_665 .
O3 Eu2 O15 80.4(8) 1_545 .
O12 Eu2 O15 146.1(9) 1_665 .
O16 Eu2 O15 73.0(8) . .
O3 Eu2 O10 94.9(5) 1_545 1_655
O12 Eu2 O10 127.1(8) 1_665 1_655
O16 Eu2 O10 92.4(6) . 1_655
O15 Eu2 O10 71.2(9) . 1_655
O3 Eu2 O13 71.0(6) 1_545 .
O12 Eu2 O13 77.3(8) 1_665 .
O16 Eu2 O13 140.6(7) . .
O15 Eu2 O13 136.6(8) . .
O10 Eu2 O13 79.3(6) 1_655 .
O3 Eu2 O6 84.3(6) 1_545 1_655
O12 Eu2 O6 82.4(9) 1_665 1_655
O16 Eu2 O6 72.0(7) . 1_655
O15 Eu2 O6 72.8(10) . 1_655
O10 Eu2 O6 143.6(8) 1_655 1_655
O13 Eu2 O6 133.2(8) . 1_655
O3 Eu2 O9 136.1(7) 1_545 1_655
O12 Eu2 O9 74.1(9) 1_665 1_655
O16 Eu2 O9 71.0(7) . 1_655
O15 Eu2 O9 110.8(10) . 1_655
O10 Eu2 O9 53.9(7) 1_655 1_655
O13 Eu2 O9 73.1(8) . 1_655
O6 Eu2 O9 139.5(7) 1_655 1_655
O3 Eu2 C13 117.0(8) 1_545 1_655
O12 Eu2 C13 100.0(10) 1_665 1_655
O16 Eu2 C13 81.0(8) . 1_655
O15 Eu2 C13 91.8(11) . 1_655
O10 Eu2 C13 27.5(8) 1_655 1_655
O13 Eu2 C13 74.0(8) . 1_655
O6 Eu2 C13 151.8(8) 1_655 1_655
O9 Eu2 C13 26.3(9) 1_655 1_655
O3 Eu2 C17 98.6(7) 1_545 1_665
O12 Eu2 C17 23.5(9) 1_665 1_665
O16 Eu2 C17 92.6(7) . 1_665
O15 Eu2 C17 142.5(10) . 1_665
O10 Eu2 C17 145.4(7) 1_655 1_665
O13 Eu2 C17 75.2(7) . 1_665
O6 Eu2 C17 69.8(9) 1_655 1_665
O9 Eu2 C17 96.0(8) 1_655 1_665
C13 Eu2 C17 120.6(10) 1_655 1_665
O3 Eu2 O11 74.9(5) 1_545 1_665
O12 Eu2 O11 46.7(7) 1_665 1_665
O16 Eu2 O11 112.2(6) . 1_665
O15 Eu2 O11 133.7(9) . 1_665
O10 Eu2 O11 148.3(5) 1_655 1_665
O13 Eu2 O11 69.0(6) . 1_665
O6 Eu2 O11 66.4(7) 1_655 1_665
O9 Eu2 O11 114.2(7) 1_655 1_665
C13 Eu2 O11 134.3(8) 1_655 1_665
C17 Eu2 O11 23.8(7) 1_665 1_665
O3 Eu2 Eu1 41.1(4) 1_545 .
O12 Eu2 Eu1 80.4(7) 1_665 .
O16 Eu2 Eu1 136.4(5) . .
O15 Eu2 Eu1 110.1(8) . .
O10 Eu2 Eu1 130.6(4) 1_655 .
O13 Eu2 Eu1 67.1(5) . .
O6 Eu2 Eu1 68.1(5) 1_655 .
O9 Eu2 Eu1 136.5(6) 1_655 .
C13 Eu2 Eu1 140.1(6) 1_655 .
C17 Eu2 Eu1 57.7(6) 1_665 .
O11 Eu2 Eu1 33.9(3) 1_665 .
C1 O1 Eu1 92.2(17) . .
C1 O2 Eu1 93.0(14) . .
C5 O3 Eu2 165(2) . 1_565
C5 O3 Eu1 86.1(17) . 1_565
Eu2 O3 Eu1 105.2(6) 1_565 1_565
C5 O4 Eu1 107(2) . 1_565
C12 O5 Eu1 137.6(18) . 1_455
C12 O6 Eu2 132.7(17) . 1_455
Eu1 O7 H7A 108(10) . .
Eu1 O7 H7B 113(3) . .
H7A O7 H7B 102(2) . .
Eu1 O8 H8B 147(9) . .
Eu1 O8 H8A 109(3) . .
H8B O8 H8A 101(2) . .
C13 O9 Eu2 91.8(18) . 1_455
C13 O10 Eu2 92.6(16) . 1_455
C17 O11 Eu1 177.0(19) . 1_445
C17 O11 Eu2 78.0(15) . 1_445
Eu1 O11 Eu2 99.3(6) 1_445 1_445
C17 O12 Eu2 108(2) . 1_445
C24 O13 Eu2 133(2) . .
C24 O14 Eu1 137(2) . .
Eu2 O15 H15A 137(10) . .
Eu2 O15 H15B 118(3) . .
H15A O15 H15B 101(2) . .
Eu2 O16 H16A 132(10) . .
Eu2 O16 H16B 113(10) . .
H16A O16 H16B 108(10) . .
C9 N1 C10 115(2) . .
C9 N1 H1A 108.5 . .
C10 N1 H1A 108.5 . .
C9 N1 H1B 108.5 . .
C10 N1 H1B 108.5 . .
H1A N1 H1B 107.5 . .
C22 N2 C21 111(2) . .
C22 N2 H2A 109.4 . .
C21 N2 H2A 109.4 . .
C22 N2 H2B 109.4 . .
C21 N2 H2B 109.4 . .
H2A N2 H2B 108.0 . .
O2 C1 O1 122(2) . .
O2 C1 C2 120(2) . .
O1 C1 C2 118(3) . .
O2 C1 Eu1 61.4(12) . .
O1 C1 Eu1 60.9(13) . .
C2 C1 Eu1 172(2) . .
C8 C2 C3 122(2) . .
C8 C2 C1 121(2) . .
C3 C2 C1 117(2) . .
C4 C3 C2 118(2) . .
C4 C3 H3 121.2 . .
C2 C3 H3 121.2 . .
C3 C4 C6 121(3) . .
C3 C4 C5 122(3) . .
C6 C4 C5 116(2) . .
O4 C5 O3 118(3) . .
O4 C5 C4 122(3) . .
O3 C5 C4 120(3) . .
O4 C5 Eu1 50.1(16) . 1_565
O3 C5 Eu1 67.9(15) . 1_565
C4 C5 Eu1 168(2) . 1_565
C7 C6 C4 120(2) . .
C7 C6 H6 119.8 . .
C4 C6 H6 119.8 . .
C8 C7 C6 119(2) . .
C8 C7 C9 124(2) . .
C6 C7 C9 116(2) . .
C2 C8 C7 120(2) . .
C2 C8 H8 119.9 . .
C7 C8 H8 119.9 . .
N1 C9 C7 108(2) . .
N1 C9 H9A 110.2 . .
C7 C9 H9A 110.2 . .
N1 C9 H9B 110.2 . .
C7 C9 H9B 110.2 . .
H9A C9 H9B 108.5 . .
N1 C10 C12 108(2) . .
N1 C10 C11 110(2) . .
C12 C10 C11 111(2) . .
N1 C10 H10 109.4 . .
C12 C10 H10 109.4 . .
C11 C10 H10 109.4 . .
C10 C11 H11A 109.5 . .
C10 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C10 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
O5 C12 O6 125(2) . .
O5 C12 C10 121(3) . .
O6 C12 C10 114(3) . .
O9 C13 O10 122(2) . .
O9 C13 C14 122(3) . .
O10 C13 C14 116(3) . .
O9 C13 Eu2 61.9(15) . 1_455
O10 C13 Eu2 59.8(12) . 1_455
C14 C13 Eu2 176(2) . 1_455
C15 C14 C20 120(3) . .
C15 C14 C13 122(3) . .
C20 C14 C13 116(3) . .
C14 C15 C16 119(3) . .
C14 C15 H15 120.3 . .
C16 C15 H15 120.3 . .
C18 C16 C15 120(3) . .
C18 C16 C17 120(2) . .
C15 C16 C17 119(2) . .
O11 C17 O12 125(3) . .
O11 C17 C16 118(2) . .
O12 C17 C16 117(2) . .
O11 C17 Eu2 78.3(15) . 1_445
O12 C17 Eu2 48.9(15) . 1_445
C16 C17 Eu2 158(2) . 1_445
C19 C18 C16 121(3) . .
C19 C18 H18 119.3 . .
C16 C18 H18 119.3 . .
C18 C19 C20 120(3) . .
C18 C19 C21 124(2) . .
C20 C19 C21 116(3) . .
C19 C20 C14 119(3) . .
C19 C20 H20 120.6 . .
C14 C20 H20 120.6 . .
N2 C21 C19 120(2) . .
N2 C21 H21A 107.4 . .
C19 C21 H21A 107.4 . .
N2 C21 H21B 107.4 . .
C19 C21 H21B 107.4 . .
H21A C21 H21B 106.9 . .
N2 C22 C24 105(3) . .
N2 C22 C23 105(2) . .
C24 C22 C23 111(3) . .
N2 C22 H22 111.7 . .
C24 C22 H22 111.7 . .
C23 C22 H22 111.7 . .
C22 C23 H23A 109.5 . .
C22 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C22 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
O14 C24 O13 129(3) . .
O14 C24 C22 119(3) . .
O13 C24 C22 112(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O11 2.313(17) 1_665
Eu1 O4 2.41(2) 1_545
Eu1 O14 2.41(3) .
Eu1 O5 2.425(18) 1_655
Eu1 O1 2.46(2) .
Eu1 O7 2.47(2) .
Eu1 O2 2.472(15) .
Eu1 O8 2.51(3) .
Eu1 O3 2.789(16) 1_545
Eu1 C1 2.81(2) .
Eu1 C5 3.00(3) 1_545
Eu1 Eu2 4.0925(9) .
Eu2 O3 2.351(16) 1_545
Eu2 O12 2.39(3) 1_665
Eu2 O16 2.413(19) .
Eu2 O15 2.41(2) .
Eu2 O10 2.417(16) 1_655
Eu2 O13 2.43(2) .
Eu2 O6 2.44(2) 1_655
Eu2 O9 2.46(2) 1_655
Eu2 C13 2.79(3) 1_655
Eu2 C17 3.02(3) 1_665
Eu2 O11 3.023(17) 1_665
O1 C1 1.27(4) .
O2 C1 1.22(3) .
O3 C5 1.32(4) .
O4 C5 1.21(4) .
O5 C12 1.23(3) .
O6 C12 1.27(4) .
O7 H7A 0.841(15) .
O7 H7B 0.838(15) .
O8 H8B 0.843(15) .
O8 H8A 0.843(15) .
O9 C13 1.24(4) .
O10 C13 1.29(4) .
O11 C17 1.24(3) .
O12 C17 1.26(4) .
O13 C24 1.27(4) .
O14 C24 1.24(4) .
O15 H15A 0.843(15) .
O15 H15B 0.840(15) .
O16 H16A 0.842(15) .
O16 H16B 0.840(15) .
N1 C9 1.489(13) .
N1 C10 1.50(4) .
N1 H1A 0.9100 .
N1 H1B 0.9100 .
N2 C22 1.48(4) .
N2 C21 1.497(13) .
N2 H2A 0.9100 .
N2 H2B 0.9100 .
C1 C2 1.503(13) .
C2 C8 1.38(4) .
C2 C3 1.401(14) .
C3 C4 1.399(13) .
C3 H3 0.9500 .
C4 C6 1.40(3) .
C4 C5 1.52(3) .
C6 C7 1.401(14) .
C6 H6 0.9500 .
C7 C8 1.396(14) .
C7 C9 1.52(2) .
C8 H8 0.9500 .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C10 C12 1.552(13) .
C10 C11 1.56(4) .
C10 H10 1.0000 .
C11 H11A 0.9800 .
C11 H11B 0.9800 .
C11 H11C 0.9800 .
C13 C14 1.534(14) .
C14 C15 1.37(3) .
C14 C20 1.44(5) .
C15 C16 1.395(13) .
C15 H15 0.9500 .
C16 C18 1.393(14) .
C16 C17 1.491(14) .
C18 C19 1.34(3) .
C18 H18 0.9500 .
C19 C20 1.41(3) .
C19 C21 1.505(14) .
C20 H20 0.9500 .
C21 H21A 0.9900 .
C21 H21B 0.9900 .
C22 C24 1.551(14) .
C22 C23 1.555(14) .
C22 H22 1.0000 .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
N1 H1B Cl2 0.91 2.46 3.25(3) 146.4 . yes
N2 H2B Cl1 0.91 2.37 3.18(3) 148.1 . yes
O7 H7A O9 0.841(15) 2.14(10) 2.86(3) 143(13) . yes
N1 H1A Cl1 0.91 2.22 3.12(3) 173.7 1_566 yes
N2 H2A Cl2 0.91 2.20 3.09(3) 164.2 1_544 yes
O16 H16B Cl2 0.840(15) 2.47(7) 3.28(2) 160(18) 1_655 yes
O16 H16A O1 0.842(15) 1.91(4) 2.75(3) 172(20) 1_655 yes
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Eu1 O2 C1 O1 8(3) . .
Eu1 O2 C1 C2 -170(2) . .
Eu1 O1 C1 O2 -8(3) . .
Eu1 O1 C1 C2 170(2) . .
O2 C1 C2 C8 176(3) . .
O1 C1 C2 C8 -3(4) . .
O2 C1 C2 C3 -8(4) . .
O1 C1 C2 C3 173(3) . .
C8 C2 C3 C4 -10(4) . .
C1 C2 C3 C4 174(3) . .
C2 C3 C4 C6 5(4) . .
C2 C3 C4 C5 -161(3) . .
Eu1 O4 C5 O3 6(4) 1_565 .
Eu1 O4 C5 C4 -169(3) 1_565 .
Eu2 O3 C5 O4 133(6) 1_565 .
Eu1 O3 C5 O4 -5(3) 1_565 .
Eu2 O3 C5 C4 -52(9) 1_565 .
Eu1 O3 C5 C4 170(3) 1_565 .
Eu2 O3 C5 Eu1 138(7) 1_565 1_565
C3 C4 C5 O4 157(4) . .
C6 C4 C5 O4 -9(5) . .
C3 C4 C5 O3 -17(5) . .
C6 C4 C5 O3 176(3) . .
C3 C4 C5 Eu1 112(11) . 1_565
C6 C4 C5 Eu1 -54(13) . 1_565
C3 C4 C6 C7 -1(5) . .
C5 C4 C6 C7 166(3) . .
C4 C6 C7 C8 0(5) . .
C4 C6 C7 C9 -169(3) . .
C3 C2 C8 C7 10(4) . .
C1 C2 C8 C7 -175(3) . .
C6 C7 C8 C2 -5(4) . .
C9 C7 C8 C2 164(3) . .
C10 N1 C9 C7 -161(2) . .
C8 C7 C9 N1 60(4) . .
C6 C7 C9 N1 -131(3) . .
C9 N1 C10 C12 67(3) . .
C9 N1 C10 C11 -54(3) . .
Eu1 O5 C12 O6 -43(5) 1_455 .
Eu1 O5 C12 C10 137(2) 1_455 .
Eu2 O6 C12 O5 -4(5) 1_455 .
Eu2 O6 C12 C10 176.1(19) 1_455 .
N1 C10 C12 O5 -143(3) . .
C11 C10 C12 O5 -22(4) . .
N1 C10 C12 O6 36(3) . .
C11 C10 C12 O6 157(3) . .
Eu2 O9 C13 O10 -2(3) 1_455 .
Eu2 O9 C13 C14 178(3) 1_455 .
Eu2 O10 C13 O9 2(3) 1_455 .
Eu2 O10 C13 C14 -178(2) 1_455 .
O9 C13 C14 C15 -174(3) . .
O10 C13 C14 C15 6(5) . .
O9 C13 C14 C20 24(5) . .
O10 C13 C14 C20 -156(3) . .
C20 C14 C15 C16 -7(5) . .
C13 C14 C15 C16 -168(3) . .
C14 C15 C16 C18 3(5) . .
C14 C15 C16 C17 177(3) . .
Eu2 O11 C17 O12 15(3) 1_445 .
Eu2 O11 C17 C16 -164(3) 1_445 .
Eu2 O12 C17 O11 -20(4) 1_445 .
Eu2 O12 C17 C16 159(2) 1_445 .
C18 C16 C17 O11 -166(3) . .
C15 C16 C17 O11 20(4) . .
C18 C16 C17 O12 15(4) . .
C15 C16 C17 O12 -159(3) . .
C18 C16 C17 Eu2 60(6) . 1_445
C15 C16 C17 Eu2 -114(5) . 1_445
C15 C16 C18 C19 1(5) . .
C17 C16 C18 C19 -173(3) . .
C16 C18 C19 C20 0(5) . .
C16 C18 C19 C21 179(3) . .
C18 C19 C20 C14 -4(5) . .
C21 C19 C20 C14 177(3) . .
C15 C14 C20 C19 8(5) . .
C13 C14 C20 C19 170(3) . .
C22 N2 C21 C19 162(3) . .
C18 C19 C21 N2 127(4) . .
C20 C19 C21 N2 -54(4) . .
C21 N2 C22 C24 -70(3) . .
C21 N2 C22 C23 173(2) . .
Eu1 O14 C24 O13 -3(7) . .
Eu1 O14 C24 C22 -177(2) . .
Eu2 O13 C24 O14 33(6) . .
Eu2 O13 C24 C22 -152(2) . .
N2 C22 C24 O14 -38(4) . .
C23 C22 C24 O14 75(4) . .
N2 C22 C24 O13 147(3) . .
C23 C22 C24 O13 -100(4) . .
