#------------------------------------------------------------------------------
#$Date: 2019-01-29 04:57:35 +0200 (Tue, 29 Jan 2019) $
#$Revision: 213365 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/22/7232240.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7232240
loop_
_publ_author_name
'Zhang, Hang'
'Wang, Jia-Chen'
'Jiang, Wei'
'Zhao, Si-Si'
_publ_section_title
;
 Three resorcin[4]arene-based lanthanide-coordination polymers with
 multifunctional photoluminescence sensing properties
;
_journal_issue                   7
_journal_name_full               'RSC Advances'
_journal_page_first              3647
_journal_paper_doi               10.1039/C8RA09777A
_journal_volume                  9
_journal_year                    2019
_chemical_formula_moiety         'C66 H94 Eu2 N O33'
_chemical_formula_sum            'C66 H94 Eu2 N O33'
_chemical_formula_weight         1733.34
_chemical_name_common            Resorcin[4]arene-Eu
_chemical_name_systematic        2
_chemical_properties_physical    Light-sensitive
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2017-10-22 deposited with the CCDC.
2019-01-28 downloaded from the CCDC.
;
_cell_angle_alpha                97.853(6)
_cell_angle_beta                 92.450(5)
_cell_angle_gamma                98.272(6)
_cell_formula_units_Z            2
_cell_length_a                   11.6030(7)
_cell_length_b                   14.7990(10)
_cell_length_c                   22.0270(14)
_cell_measurement_reflns_used    3318
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.2168
_cell_measurement_theta_min      2.8605
_cell_volume                     3700.3(4)
_computing_cell_refinement       CrysAlis
_computing_data_collection       'CrysAlis (Oxford Diffraction, 2006)'
_computing_data_reduction        CrysAlis
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 10.0
_diffrn_measured_fraction_theta_full 0.977
_diffrn_measured_fraction_theta_max 0.829
_diffrn_measurement_device_type  'Oxford Diffraction Gemini R Ultra'
_diffrn_measurement_method       'ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0850
_diffrn_reflns_av_sigmaI/netI    0.2196
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            26682
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         29.28
_diffrn_reflns_theta_min         2.87
_exptl_absorpt_coefficient_mu    1.768
_exptl_absorpt_correction_T_max  0.8430
_exptl_absorpt_correction_T_min  0.6191
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis (Oxford Diffraction, 2006) 
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.556
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1774
_exptl_crystal_preparation       Luminescent
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_refine_diff_density_max         3.342
_refine_diff_density_min         -2.638
_refine_diff_density_rms         0.259
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.113
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     909
_refine_ls_number_reflns         16733
_refine_ls_number_restraints     210
_refine_ls_restrained_S_all      1.108
_refine_ls_R_factor_all          0.2251
_refine_ls_R_factor_gt           0.1390
_refine_ls_shift/su_max          0.014
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0001P)²+150.8087P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2549
_refine_ls_wR_factor_ref         0.2958
_reflns_number_gt                9079
_reflns_number_total             16733
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            c8ra09777a2.cif
_cod_data_source_block           Compound-2
_cod_database_code               7232240
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.69746(7) 0.15865(6) 0.47402(4) 0.0216(2) Uani 1 1 d .
Eu2 Eu 1.23066(7) 0.23313(6) 0.36287(4) 0.0251(2) Uani 1 1 d .
C1 C 0.419(2) -0.6612(18) 0.1318(11) 0.077(3) Uani 1 1 d DU
H1A H 0.3426 -0.6950 0.1342 0.115 Uiso 1 1 calc R
H1B H 0.4383 -0.6165 0.1681 0.115 Uiso 1 1 calc R
H1C H 0.4751 -0.7030 0.1288 0.115 Uiso 1 1 calc R
C2 C 0.4204(17) -0.6127(18) 0.0763(11) 0.074(3) Uani 1 1 d DU
H2A H 0.3607 -0.5729 0.0777 0.088 Uiso 1 1 calc R
H2B H 0.4052 -0.6573 0.0392 0.088 Uiso 1 1 calc R
C3 C 0.5390(18) -0.5566(19) 0.0766(13) 0.074(3) Uani 1 1 d DU
H3A H 0.5869 -0.5921 0.0506 0.088 Uiso 1 1 calc R
H3B H 0.5308 -0.5015 0.0586 0.088 Uiso 1 1 calc R
C4 C 0.599(2) -0.530(2) 0.1359(13) 0.079(6) Uani 1 1 d U
H4A H 0.5961 -0.5847 0.1554 0.094 Uiso 1 1 calc R
H4B H 0.5530 -0.4893 0.1597 0.094 Uiso 1 1 calc R
C5 C 0.723(2) -0.482(2) 0.1434(12) 0.070(3) Uani 1 1 d U
H5A H 0.7295 -0.4300 0.1209 0.084 Uiso 1 1 calc R
H5B H 0.7722 -0.5247 0.1251 0.084 Uiso 1 1 calc R
C6 C 0.768(2) -0.4485(19) 0.2094(12) 0.065(3) Uani 1 1 d U
H6 H 0.7509 -0.5001 0.2328 0.078 Uiso 1 1 calc R
C7 C 0.8979(18) -0.4194(13) 0.2135(8) 0.034(4) Uani 1 1 d U
C8 C 0.9719(14) -0.4820(11) 0.2257(8) 0.026(4) Uani 1 1 d .
C9 C 1.0954(14) -0.4546(12) 0.2276(9) 0.029(4) Uani 1 1 d .
H9 H 1.1471 -0.4947 0.2355 0.035 Uiso 1 1 calc R
C10 C 1.1338(15) -0.3665(15) 0.2174(9) 0.036(5) Uani 1 1 d .
C11 C 1.0682(13) -0.3068(11) 0.2019(8) 0.022(4) Uani 1 1 d .
C12 C 0.9490(13) -0.3342(11) 0.2025(8) 0.021(4) Uani 1 1 d .
H12 H 0.9002 -0.2918 0.1949 0.025 Uiso 1 1 calc R
C13 C 0.9935(15) -0.6373(13) 0.2382(8) 0.027(4) Uani 1 1 d U
H13A H 1.0520 -0.6307 0.2083 0.033 Uiso 1 1 calc R
H13B H 0.9451 -0.6968 0.2262 0.033 Uiso 1 1 calc R
C14 C 1.0544(14) -0.6375(12) 0.2997(9) 0.028(4) Uani 1 1 d .
C15 C 1.3324(18) -0.4066(15) 0.2169(12) 0.049(6) Uani 1 1 d .
H15A H 1.4068 -0.3822 0.2026 0.059 Uiso 1 1 calc R
H15B H 1.3009 -0.4616 0.1886 0.059 Uiso 1 1 calc R
C16 C 1.3539(18) -0.4341(18) 0.2767(13) 0.053(6) Uani 1 1 d .
C17 C 0.954(5) -0.403(4) -0.073(3) 0.206(14) Uani 1 1 d U
H17A H 0.8824 -0.4457 -0.0804 0.309 Uiso 1 1 calc R
H17B H 1.0182 -0.4352 -0.0839 0.309 Uiso 1 1 calc R
H17C H 0.9515 -0.3546 -0.0977 0.309 Uiso 1 1 calc R
C18 C 0.971(3) -0.360(4) -0.001(2) 0.186(14) Uani 1 1 d DU
H18A H 0.9154 -0.3178 0.0093 0.224 Uiso 1 1 calc R
H18B H 0.9630 -0.4075 0.0249 0.224 Uiso 1 1 calc R
C19 C 1.091(3) -0.311(3) 0.0018(17) 0.123(10) Uani 1 1 d U
H19A H 1.0933 -0.2526 -0.0141 0.148 Uiso 1 1 calc R
H19B H 1.1407 -0.3479 -0.0219 0.148 Uiso 1 1 calc R
C20 C 1.136(3) -0.2928(19) 0.0754(12) 0.091(8) Uani 1 1 d DU
H20A H 1.1173 -0.3501 0.0922 0.109 Uiso 1 1 calc R
H20B H 1.2202 -0.2761 0.0789 0.109 Uiso 1 1 calc R
C21 C 1.0834(19) -0.2187(15) 0.1136(9) 0.043(5) Uani 1 1 d .
H21A H 0.9991 -0.2304 0.1067 0.052 Uiso 1 1 calc R
H21B H 1.1112 -0.1592 0.1015 0.052 Uiso 1 1 calc R
C22 C 1.1168(14) -0.2173(12) 0.1812(8) 0.024(4) Uani 1 1 d .
H22 H 1.2021 -0.2116 0.1856 0.029 Uiso 1 1 calc R
C23 C 1.0823(12) -0.1357(10) 0.2214(7) 0.016(3) Uani 1 1 d .
C24 C 1.1366(13) -0.1118(11) 0.2824(7) 0.018(3) Uani 1 1 d U
C25 C 1.1176(13) -0.0331(11) 0.3188(8) 0.021(4) Uani 1 1 d .
H25 H 1.1529 -0.0178 0.3583 0.025 Uiso 1 1 calc R
C26 C 1.0478(14) 0.0220(12) 0.2971(8) 0.024(4) Uani 1 1 d .
C27 C 0.9921(13) 0.0025(11) 0.2408(8) 0.020(3) Uani 1 1 d .
C28 C 1.0105(13) -0.0746(11) 0.2050(8) 0.021(4) Uani 1 1 d .
H28 H 0.9719 -0.0880 0.1662 0.026 Uiso 1 1 calc R
C29 C 1.3096(14) -0.1306(13) 0.3374(9) 0.032(4) Uani 1 1 d .
H29A H 1.3367 -0.0700 0.3267 0.038 Uiso 1 1 calc R
H29B H 1.3701 -0.1684 0.3281 0.038 Uiso 1 1 calc R
C30 C 1.2959(14) -0.1205(12) 0.4058(9) 0.026(4) Uani 1 1 d .
C31 C 0.9457(15) 0.1116(14) 0.3693(9) 0.032(4) Uani 1 1 d .
H31A H 0.9201 0.0519 0.3816 0.039 Uiso 1 1 calc R
H31B H 0.8826 0.1277 0.3445 0.039 Uiso 1 1 calc R
C32 C 0.9767(13) 0.1819(13) 0.4238(8) 0.026(4) Uani 1 1 d .
C33 C 1.204(3) 0.124(4) -0.019(2) 0.168(18) Uani 1 1 d U
H33A H 1.2852 0.1321 -0.0273 0.252 Uiso 1 1 calc R
H33B H 1.1686 0.1732 -0.0327 0.252 Uiso 1 1 calc R
H33C H 1.1659 0.0660 -0.0406 0.252 Uiso 1 1 calc R
C34 C 1.192(3) 0.126(3) 0.0481(17) 0.103(8) Uani 1 1 d U
H34A H 1.2348 0.1838 0.0690 0.123 Uiso 1 1 calc R
H34B H 1.2305 0.0768 0.0611 0.123 Uiso 1 1 calc R
C35 C 1.071(3) 0.115(3) 0.0694(15) 0.097(9) Uani 1 1 d U
H35A H 1.0337 0.1647 0.0564 0.117 Uiso 1 1 calc R
H35B H 1.0290 0.0577 0.0480 0.117 Uiso 1 1 calc R
C36 C 1.0568(19) 0.1162(17) 0.1363(12) 0.059(5) Uani 1 1 d U
H36A H 1.0810 0.1785 0.1573 0.071 Uiso 1 1 calc R
H36B H 1.1080 0.0771 0.1519 0.071 Uiso 1 1 calc R
C37 C 0.9341(15) 0.0837(15) 0.1511(9) 0.034(5) Uani 1 1 d .
H37A H 0.9067 0.0249 0.1258 0.041 Uiso 1 1 calc R
H37B H 0.8849 0.1273 0.1399 0.041 Uiso 1 1 calc R
C38 C 0.9182(14) 0.0720(12) 0.2184(9) 0.026(4) Uani 1 1 d .
H38 H 0.9445 0.1322 0.2434 0.032 Uiso 1 1 calc R
C39 C 0.7871(14) 0.0469(13) 0.2257(9) 0.031(4) Uani 1 1 d .
C40 C 0.7118(13) 0.1126(11) 0.2453(7) 0.019(3) Uani 1 1 d U
C41 C 0.6047(15) 0.0943(13) 0.2456(8) 0.028(4) Uani 1 1 d U
H41 H 0.5608 0.1415 0.2556 0.034 Uiso 1 1 calc R
C42 C 0.5482(13) 0.0026(11) 0.2309(8) 0.024(4) Uani 1 1 d .
C43 C 0.6104(14) -0.0670(12) 0.2161(8) 0.022(4) Uani 1 1 d .
C44 C 0.7311(13) -0.0427(11) 0.2115(8) 0.022(4) Uani 1 1 d .
H44 H 0.7748 -0.0889 0.1984 0.026 Uiso 1 1 calc R
C45 C 0.7120(15) 0.2716(11) 0.2853(8) 0.026(4) Uani 1 1 d .
H45A H 0.6483 0.2744 0.2559 0.031 Uiso 1 1 calc R
H45B H 0.7620 0.3309 0.2908 0.031 Uiso 1 1 calc R
C46 C 0.6614(14) 0.2559(12) 0.3469(9) 0.028(4) Uani 1 1 d .
C47 C 0.3568(13) 0.0423(11) 0.2199(8) 0.023(4) Uani 1 1 d .
H47A H 0.2842 0.0079 0.2002 0.027 Uiso 1 1 calc R
H47B H 0.3934 0.0783 0.1904 0.027 Uiso 1 1 calc R
C48 C 0.3272(14) 0.1103(12) 0.2757(9) 0.029(4) Uani 1 1 d .
C49 C 0.361(3) -0.138(3) -0.0700(17) 0.116(11) Uani 1 1 d U
H49A H 0.3144 -0.0977 -0.0867 0.174 Uiso 1 1 calc R
H49B H 0.3236 -0.2009 -0.0810 0.174 Uiso 1 1 calc R
H49C H 0.4366 -0.1310 -0.0862 0.174 Uiso 1 1 calc R
C50 C 0.374(3) -0.114(2) -0.0003(16) 0.106(11) Uani 1 1 d U
H50A H 0.4079 -0.0499 0.0103 0.127 Uiso 1 1 calc R
H50B H 0.2967 -0.1216 0.0156 0.127 Uiso 1 1 calc R
C51 C 0.447(2) -0.1722(19) 0.0298(11) 0.066(8) Uani 1 1 d .
H51A H 0.5234 -0.1661 0.0132 0.079 Uiso 1 1 calc R
H51B H 0.4116 -0.2363 0.0201 0.079 Uiso 1 1 calc R
C52 C 0.462(2) -0.1451(17) 0.1011(10) 0.052(6) Uani 1 1 d .
H52A H 0.4937 -0.0801 0.1106 0.062 Uiso 1 1 calc R
H52B H 0.3858 -0.1538 0.1177 0.062 Uiso 1 1 calc R
C53 C 0.5388(17) -0.1985(13) 0.1321(10) 0.038(5) Uani 1 1 d .
H53A H 0.6149 -0.1911 0.1152 0.046 Uiso 1 1 calc R
H53B H 0.5063 -0.2634 0.1241 0.046 Uiso 1 1 calc R
C54 C 0.5533(13) -0.1676(11) 0.2018(7) 0.019(3) Uani 1 1 d U
H54 H 0.4742 -0.1698 0.2161 0.023 Uiso 1 1 calc R
C55 C 0.6121(12) -0.2321(11) 0.2365(8) 0.020(4) Uani 1 1 d .
C56 C 0.6152(13) -0.2223(12) 0.3004(8) 0.022(4) Uani 1 1 d .
C57 C 0.6529(13) -0.2861(12) 0.3327(8) 0.023(4) Uani 1 1 d U
H57 H 0.6490 -0.2798 0.3751 0.027 Uiso 1 1 calc R
C58 C 0.6972(14) -0.3609(12) 0.3015(8) 0.024(4) Uani 1 1 d U
C59 C 0.706(2) -0.3697(18) 0.2387(12) 0.059(3) Uani 1 1 d U
C60 C 0.6659(13) -0.3047(11) 0.2068(8) 0.021(4) Uani 1 1 d .
H60 H 0.6743 -0.3089 0.1648 0.025 Uiso 1 1 calc R
C61 C 0.6537(16) -0.0736(14) 0.3555(9) 0.035(5) Uani 1 1 d .
H61A H 0.6232 -0.0186 0.3472 0.042 Uiso 1 1 calc R
H61B H 0.7239 -0.0767 0.3334 0.042 Uiso 1 1 calc R
C62 C 0.6867(14) -0.0635(12) 0.4235(7) 0.022(4) Uani 1 1 d .
C63 C 0.6574(18) -0.4625(14) 0.3741(10) 0.043(5) Uani 1 1 d .
H63A H 0.6613 -0.5278 0.3722 0.051 Uiso 1 1 calc R
H63B H 0.5792 -0.4567 0.3593 0.051 Uiso 1 1 calc R
C64 C 0.6751(16) -0.4194(14) 0.4396(9) 0.034(4) Uani 1 1 d U
C65 C 1.034(2) -0.3546(17) 0.3793(11) 0.056(6) Uiso 1 1 d .
H65A H 1.0556 -0.4048 0.3982 0.084 Uiso 1 1 calc R
H65B H 1.1014 -0.3210 0.3647 0.084 Uiso 1 1 calc R
H65C H 0.9778 -0.3784 0.3454 0.084 Uiso 1 1 calc R
C66 C 0.948(2) -0.218(2) 0.3889(13) 0.076(8) Uani 1 1 d U
H66A H 0.9136 -0.1742 0.4158 0.114 Uiso 1 1 calc R
H66B H 0.8936 -0.2451 0.3553 0.114 Uiso 1 1 calc R
H66C H 1.0170 -0.1868 0.3735 0.114 Uiso 1 1 calc R
N1 N 0.9815(14) -0.2929(12) 0.4243(8) 0.041(4) Uiso 1 1 d .
O1 O 0.9213(10) -0.5660(8) 0.2354(5) 0.027(3) Uani 1 1 d U
O2 O 1.1161(12) -0.6978(10) 0.3001(7) 0.047(4) Uani 1 1 d .
O3 O 1.2564(9) -0.3409(8) 0.2132(6) 0.033(3) Uani 1 1 d .
O4 O 1.3918(18) -0.5037(13) 0.2822(11) 0.091(7) Uani 1 1 d .
O5 O 1.3336(13) -0.3754(13) 0.3228(9) 0.063(5) Uani 1 1 d .
O6 O 1.0402(12) -0.5809(10) 0.3431(7) 0.045(4) Uani 1 1 d .
O7 O 1.2089(10) -0.1695(8) 0.2996(5) 0.027(3) Uani 1 1 d .
O8 O 1.2123(10) -0.1699(9) 0.4256(6) 0.034(3) Uani 1 1 d .
O9 O 1.3750(9) -0.0739(8) 0.4413(6) 0.026(3) Uani 1 1 d .
O10 O 1.0468(9) 0.1082(7) 0.3348(5) 0.023(3) Uani 1 1 d .
O11 O 1.0689(11) 0.2378(9) 0.4268(6) 0.040(3) Uani 1 1 d .
O12 O 0.9003(9) 0.1920(8) 0.4637(6) 0.027(3) Uani 1 1 d .
O13 O 0.7778(9) 0.2020(8) 0.2601(6) 0.027(3) Uani 1 1 d .
O14 O 0.6993(12) 0.1988(10) 0.3758(7) 0.045(4) Uani 1 1 d .
O15 O 0.5878(11) 0.3051(10) 0.3626(7) 0.044(4) Uani 1 1 d .
O16 O 0.4293(9) -0.0205(8) 0.2333(6) 0.029(3) Uani 1 1 d .
O17 O 0.3762(11) 0.1204(10) 0.3271(6) 0.039(3) Uani 1 1 d .
O18 O 0.2435(10) 0.1509(9) 0.2619(6) 0.034(3) Uani 1 1 d .
O19 O 0.5716(9) -0.1505(8) 0.3319(6) 0.031(3) Uani 1 1 d .
O20 O 0.7453(9) 0.0130(8) 0.4446(6) 0.026(3) Uani 1 1 d .
O21 O 0.6617(13) -0.1273(10) 0.4518(6) 0.044(4) Uani 1 1 d .
O22 O 0.7368(11) -0.4262(10) 0.3333(6) 0.041(4) Uani 1 1 d .
O23 O 0.5914(11) -0.4187(11) 0.4727(7) 0.054(4) Uani 1 1 d .
H23 H 0.5315 -0.4441 0.4527 0.081 Uiso 1 1 calc R
O24 O 0.7807(12) -0.3944(11) 0.4607(7) 0.049(4) Uani 1 1 d U
O1W O 1.3798(11) 0.3276(10) 0.3120(7) 0.047(4) Uani 1 1 d .
O2W O 1.4029(11) 0.2843(10) 0.4349(6) 0.039(3) Uani 1 1 d .
O3W O 1.2234(10) 0.3915(9) 0.4164(6) 0.032(3) Uani 1 1 d .
O4W O 1.2408(12) 0.1202(11) 0.4348(7) 0.049(4) Uani 1 1 d .
O5W O 0.5471(11) 0.2368(10) 0.5300(6) 0.039(3) Uani 1 1 d U
O6W O 0.5146(10) 0.0788(9) 0.4222(6) 0.032(3) Uani 1 1 d .
O7W O 0.7583(13) 0.3234(11) 0.4939(7) 0.051(4) Uani 1 1 d U
O8W O 0.902(2) 0.4366(15) 0.4426(15) 0.142(12) Uani 1 1 d .
O9W O 1.3658(11) -0.4415(9) 0.4291(6) 0.039(3) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O20 Eu1 O14 94.7(5) . .
O20 Eu1 O12 78.1(4) . .
O14 Eu1 O12 79.4(5) . .
O20 Eu1 O8 92.7(4) . 2_756
O14 Eu1 O8 150.1(5) . 2_756
O12 Eu1 O8 73.9(4) . 2_756
O20 Eu1 O7W 148.6(4) . .
O14 Eu1 O7W 77.6(5) . .
O12 Eu1 O7W 70.5(5) . .
O8 Eu1 O7W 81.0(5) 2_756 .
O20 Eu1 O6W 79.0(4) . .
O14 Eu1 O6W 75.0(4) . .
O12 Eu1 O6W 143.9(4) . .
O8 Eu1 O6W 134.8(4) 2_756 .
O7W Eu1 O6W 126.5(5) . .
O20 Eu1 O9 77.7(4) . 2_756
O14 Eu1 O9 156.8(4) . 2_756
O12 Eu1 O9 119.4(4) . 2_756
O8 Eu1 O9 53.0(4) 2_756 2_756
O7W Eu1 O9 119.9(5) . 2_756
O6W Eu1 O9 82.0(4) . 2_756
O20 Eu1 O5W 140.9(4) . .
O14 Eu1 O5W 107.9(5) . .
O12 Eu1 O5W 136.2(4) . .
O8 Eu1 O5W 83.3(4) 2_756 .
O7W Eu1 O5W 69.3(5) . .
O6W Eu1 O5W 76.8(4) . .
O9 Eu1 O5W 69.0(4) 2_756 .
O20 Eu1 C30 87.5(5) . 2_756
O14 Eu1 C30 176.5(5) . 2_756
O12 Eu1 C30 98.5(4) . 2_756
O8 Eu1 C30 26.8(4) 2_756 2_756
O7W Eu1 C30 99.1(5) . 2_756
O6W Eu1 C30 108.1(5) . 2_756
O9 Eu1 C30 26.5(4) 2_756 2_756
O5W Eu1 C30 71.6(4) . 2_756
O2 Eu2 O11 82.8(5) 1_565 .
O2 Eu2 O18 76.1(5) 1_565 1_655
O11 Eu2 O18 130.7(4) . 1_655
O2 Eu2 O2W 136.1(5) 1_565 .
O11 Eu2 O2W 104.1(4) . .
O18 Eu2 O2W 122.1(4) 1_655 .
O2 Eu2 O4W 148.0(5) 1_565 .
O11 Eu2 O4W 71.6(5) . .
O18 Eu2 O4W 106.2(5) 1_655 .
O2W Eu2 O4W 70.7(5) . .
O2 Eu2 O1W 78.4(5) 1_565 .
O11 Eu2 O1W 144.5(5) . .
O18 Eu2 O1W 73.1(5) 1_655 .
O2W Eu2 O1W 71.4(5) . .
O4W Eu2 O1W 133.4(5) . .
O2 Eu2 O3W 73.0(5) 1_565 .
O11 Eu2 O3W 67.8(4) . .
O18 Eu2 O3W 141.1(4) 1_655 .
O2W Eu2 O3W 70.1(4) . .
O4W Eu2 O3W 112.6(5) . .
O1W Eu2 O3W 77.9(5) . .
O2 Eu2 O17 126.4(5) 1_565 1_655
O11 Eu2 O17 138.6(5) . 1_655
O18 Eu2 O17 51.7(4) 1_655 1_655
O2W Eu2 O17 76.0(4) . 1_655
O4W Eu2 O17 69.6(5) . 1_655
O1W Eu2 O17 75.8(4) . 1_655
O3W Eu2 O17 142.2(4) . 1_655
O2 Eu2 O10 77.2(4) 1_565 .
O11 Eu2 O10 61.6(4) . .
O18 Eu2 O10 70.3(4) 1_655 .
O2W Eu2 O10 144.5(4) . .
O4W Eu2 O10 73.9(4) . .
O1W Eu2 O10 139.8(4) . .
O3W Eu2 O10 123.5(4) . .
O17 Eu2 O10 93.9(4) 1_655 .
O2 Eu2 C48 101.6(5) 1_565 1_655
O11 Eu2 C48 141.0(5) . 1_655
O18 Eu2 C48 26.2(4) 1_655 1_655
O2W Eu2 C48 99.1(5) . 1_655
O4W Eu2 C48 87.4(5) . 1_655
O1W Eu2 C48 72.9(5) . 1_655
O3W Eu2 C48 150.9(5) . 1_655
O17 Eu2 C48 25.5(4) 1_655 1_655
O10 Eu2 C48 81.3(4) . 1_655
C2 C1 H1A 109.5 . .
C2 C1 H1B 109.5 . .
H1A C1 H1B 109.5 . .
C2 C1 H1C 109.5 . .
H1A C1 H1C 109.5 . .
H1B C1 H1C 109.5 . .
C1 C2 C3 107(2) . .
C1 C2 H2A 110.2 . .
C3 C2 H2A 110.2 . .
C1 C2 H2B 110.2 . .
C3 C2 H2B 110.2 . .
H2A C2 H2B 108.5 . .
C4 C3 C2 115(2) . .
C4 C3 H3A 108.5 . .
C2 C3 H3A 108.5 . .
C4 C3 H3B 108.5 . .
C2 C3 H3B 108.5 . .
H3A C3 H3B 107.5 . .
C3 C4 C5 122(2) . .
C3 C4 H4A 106.9 . .
C5 C4 H4A 106.9 . .
C3 C4 H4B 106.9 . .
C5 C4 H4B 106.9 . .
H4A C4 H4B 106.7 . .
C4 C5 C6 114(2) . .
C4 C5 H5A 108.7 . .
C6 C5 H5A 108.7 . .
C4 C5 H5B 108.7 . .
C6 C5 H5B 108.7 . .
H5A C5 H5B 107.6 . .
C7 C6 C5 111(2) . .
C7 C6 C59 111(2) . .
C5 C6 C59 112(2) . .
C7 C6 H6 107.8 . .
C5 C6 H6 107.8 . .
C59 C6 H6 107.8 . .
C12 C7 C8 117.2(18) . .
C12 C7 C6 122.8(18) . .
C8 C7 C6 119.9(19) . .
O1 C8 C7 117.0(16) . .
O1 C8 C9 123.6(14) . .
C7 C8 C9 119.4(16) . .
C10 C9 C8 116.8(15) . .
C10 C9 H9 121.6 . .
C8 C9 H9 121.6 . .
C11 C10 C9 126.2(17) . .
C11 C10 O3 115.5(18) . .
C9 C10 O3 117.5(16) . .
C10 C11 C12 115.4(16) . .
C10 C11 C22 123.2(16) . .
C12 C11 C22 121.3(14) . .
C7 C12 C11 124.6(16) . .
C7 C12 H12 117.7 . .
C11 C12 H12 117.7 . .
O1 C13 C14 115.4(14) . .
O1 C13 H13A 108.4 . .
C14 C13 H13A 108.4 . .
O1 C13 H13B 108.4 . .
C14 C13 H13B 108.4 . .
H13A C13 H13B 107.5 . .
O6 C14 O2 126.2(19) . .
O6 C14 C13 120.2(16) . .
O2 C14 C13 113.6(17) . .
O3 C15 C16 117.3(19) . .
O3 C15 H15A 108.0 . .
C16 C15 H15A 108.0 . .
O3 C15 H15B 108.0 . .
C16 C15 H15B 108.0 . .
H15A C15 H15B 107.2 . .
O4 C16 O5 123(3) . .
O4 C16 C15 122(3) . .
O5 C16 C15 115(2) . .
C18 C17 H17A 109.5 . .
C18 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C18 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C19 C18 C17 101(4) . .
C19 C18 H18A 111.6 . .
C17 C18 H18A 111.6 . .
C19 C18 H18B 111.6 . .
C17 C18 H18B 111.6 . .
H18A C18 H18B 109.4 . .
C18 C19 C20 106(2) . .
C18 C19 H19A 110.6 . .
C20 C19 H19A 110.6 . .
C18 C19 H19B 110.6 . .
C20 C19 H19B 110.6 . .
H19A C19 H19B 108.7 . .
C21 C20 C19 114(2) . .
C21 C20 H20A 108.7 . .
C19 C20 H20A 108.7 . .
C21 C20 H20B 108.7 . .
C19 C20 H20B 108.7 . .
H20A C20 H20B 107.6 . .
C20 C21 C22 109.9(17) . .
C20 C21 H21A 109.7 . .
C22 C21 H21A 109.7 . .
C20 C21 H21B 109.7 . .
C22 C21 H21B 109.7 . .
H21A C21 H21B 108.2 . .
C11 C22 C23 111.6(14) . .
C11 C22 C21 110.7(15) . .
C23 C22 C21 112.7(14) . .
C11 C22 H22 107.2 . .
C23 C22 H22 107.2 . .
C21 C22 H22 107.2 . .
C28 C23 C24 114.3(14) . .
C28 C23 C22 127.7(15) . .
C24 C23 C22 117.8(13) . .
O7 C24 C25 123.8(14) . .
O7 C24 C23 115.8(13) . .
C25 C24 C23 120.3(14) . .
C26 C25 C24 119.8(15) . .
C26 C25 H25 120.1 . .
C24 C25 H25 120.1 . .
C25 C26 C27 122.9(16) . .
C25 C26 O10 115.3(14) . .
C27 C26 O10 121.4(15) . .
C28 C27 C26 117.5(15) . .
C28 C27 C38 123.0(15) . .
C26 C27 C38 119.3(15) . .
C27 C28 C23 125.2(15) . .
C27 C28 H28 117.4 . .
C23 C28 H28 117.4 . .
O7 C29 C30 116.1(14) . .
O7 C29 H29A 108.3 . .
C30 C29 H29A 108.3 . .
O7 C29 H29B 108.3 . .
C30 C29 H29B 108.3 . .
H29A C29 H29B 107.4 . .
O9 C30 O8 121.2(17) . .
O9 C30 C29 119.3(15) . .
O8 C30 C29 118.7(15) . .
O9 C30 Eu1 63.8(10) . 2_756
O8 C30 Eu1 58.5(9) . 2_756
C29 C30 Eu1 160.1(12) . 2_756
O10 C31 C32 107.9(14) . .
O10 C31 H31A 110.1 . .
C32 C31 H31A 110.1 . .
O10 C31 H31B 110.1 . .
C32 C31 H31B 110.1 . .
H31A C31 H31B 108.4 . .
O11 C32 O12 120.9(17) . .
O11 C32 C31 120.0(15) . .
O12 C32 C31 118.4(15) . .
C34 C33 H33A 109.5 . .
C34 C33 H33B 109.5 . .
H33A C33 H33B 109.5 . .
C34 C33 H33C 109.5 . .
H33A C33 H33C 109.5 . .
H33B C33 H33C 109.5 . .
C33 C34 C35 117(3) . .
C33 C34 H34A 108.1 . .
C35 C34 H34A 108.1 . .
C33 C34 H34B 108.1 . .
C35 C34 H34B 108.1 . .
H34A C34 H34B 107.3 . .
C36 C35 C34 118(3) . .
C36 C35 H35A 107.8 . .
C34 C35 H35A 107.8 . .
C36 C35 H35B 107.8 . .
C34 C35 H35B 107.8 . .
H35A C35 H35B 107.1 . .
C35 C36 C37 114(2) . .
C35 C36 H36A 108.9 . .
C37 C36 H36A 108.9 . .
C35 C36 H36B 108.9 . .
C37 C36 H36B 108.9 . .
H36A C36 H36B 107.7 . .
C36 C37 C38 115.2(16) . .
C36 C37 H37A 108.5 . .
C38 C37 H37A 108.5 . .
C36 C37 H37B 108.5 . .
C38 C37 H37B 108.5 . .
H37A C37 H37B 107.5 . .
C39 C38 C37 107.6(14) . .
C39 C38 C27 113.6(14) . .
C37 C38 C27 112.6(14) . .
C39 C38 H38 107.6 . .
C37 C38 H38 107.6 . .
C27 C38 H38 107.6 . .
C44 C39 C40 114.3(14) . .
C44 C39 C38 121.4(16) . .
C40 C39 C38 124.3(16) . .
C41 C40 O13 125.4(16) . .
C41 C40 C39 124.6(17) . .
O13 C40 C39 109.9(13) . .
C40 C41 C42 120.6(17) . .
C40 C41 H41 119.7 . .
C42 C41 H41 119.7 . .
C43 C42 O16 117.4(15) . .
C43 C42 C41 120.6(15) . .
O16 C42 C41 121.9(15) . .
C42 C43 C44 117.2(15) . .
C42 C43 C54 122.4(15) . .
C44 C43 C54 120.4(15) . .
C39 C44 C43 122.4(15) . .
C39 C44 H44 118.8 . .
C43 C44 H44 118.8 . .
O13 C45 C46 114.4(14) . .
O13 C45 H45A 108.7 . .
C46 C45 H45A 108.7 . .
O13 C45 H45B 108.7 . .
C46 C45 H45B 108.7 . .
H45A C45 H45B 107.6 . .
O15 C46 O14 127.2(19) . .
O15 C46 C45 114.0(16) . .
O14 C46 C45 118.7(16) . .
O16 C47 C48 116.0(14) . .
O16 C47 H47A 108.3 . .
C48 C47 H47A 108.3 . .
O16 C47 H47B 108.3 . .
C48 C47 H47B 108.3 . .
H47A C47 H47B 107.4 . .
O17 C48 O18 124.0(17) . .
O17 C48 C47 124.3(15) . .
O18 C48 C47 111.6(15) . .
O17 C48 Eu2 66.7(10) . 1_455
O18 C48 Eu2 57.3(9) . 1_455
C47 C48 Eu2 168.4(11) . 1_455
C50 C49 H49A 109.5 . .
C50 C49 H49B 109.5 . .
H49A C49 H49B 109.5 . .
C50 C49 H49C 109.5 . .
H49A C49 H49C 109.5 . .
H49B C49 H49C 109.5 . .
C51 C50 C49 113(3) . .
C51 C50 H50A 108.9 . .
C49 C50 H50A 108.9 . .
C51 C50 H50B 108.9 . .
C49 C50 H50B 108.9 . .
H50A C50 H50B 107.7 . .
C50 C51 C52 113(2) . .
C50 C51 H51A 109.0 . .
C52 C51 H51A 109.0 . .
C50 C51 H51B 109.0 . .
C52 C51 H51B 109.0 . .
H51A C51 H51B 107.8 . .
C53 C52 C51 114(2) . .
C53 C52 H52A 108.7 . .
C51 C52 H52A 108.7 . .
C53 C52 H52B 108.7 . .
C51 C52 H52B 108.7 . .
H52A C52 H52B 107.6 . .
C52 C53 C54 112.3(17) . .
C52 C53 H53A 109.2 . .
C54 C53 H53A 109.2 . .
C52 C53 H53B 109.2 . .
C54 C53 H53B 109.2 . .
H53A C53 H53B 107.9 . .
C55 C54 C43 113.7(13) . .
C55 C54 C53 113.6(14) . .
C43 C54 C53 110.4(14) . .
C55 C54 H54 106.2 . .
C43 C54 H54 106.2 . .
C53 C54 H54 106.2 . .
C56 C55 C60 116.3(15) . .
C56 C55 C54 120.7(14) . .
C60 C55 C54 123.0(15) . .
O19 C56 C57 118.2(16) . .
O19 C56 C55 119.3(14) . .
C57 C56 C55 122.3(16) . .
C56 C57 C58 119.4(16) . .
C56 C57 H57 120.3 . .
C58 C57 H57 120.3 . .
C59 C58 O22 118.6(17) . .
C59 C58 C57 120.8(18) . .
O22 C58 C57 120.5(15) . .
C58 C59 C60 119(2) . .
C58 C59 C6 117(2) . .
C60 C59 C6 124(2) . .
C59 C60 C55 121.9(18) . .
C59 C60 H60 119.0 . .
C55 C60 H60 119.0 . .
O19 C61 C62 115.7(17) . .
O19 C61 H61A 108.4 . .
C62 C61 H61A 108.4 . .
O19 C61 H61B 108.4 . .
C62 C61 H61B 108.4 . .
H61A C61 H61B 107.4 . .
O21 C62 O20 125.8(17) . .
O21 C62 C61 120.5(17) . .
O20 C62 C61 113.6(15) . .
O22 C63 C64 116.6(17) . .
O22 C63 H63A 108.2 . .
C64 C63 H63A 108.2 . .
O22 C63 H63B 108.2 . .
C64 C63 H63B 108.2 . .
H63A C63 H63B 107.3 . .
O23 C64 O24 122.6(18) . .
O23 C64 C63 120.5(17) . .
O24 C64 C63 116.3(17) . .
N1 C65 H65A 109.5 . .
N1 C65 H65B 109.5 . .
H65A C65 H65B 109.5 . .
N1 C65 H65C 109.5 . .
H65A C65 H65C 109.5 . .
H65B C65 H65C 109.5 . .
N1 C66 H66A 109.5 . .
N1 C66 H66B 109.5 . .
H66A C66 H66B 109.5 . .
N1 C66 H66C 109.5 . .
H66A C66 H66C 109.5 . .
H66B C66 H66C 109.5 . .
C65 N1 C66 104.7(18) . .
C8 O1 C13 118.6(13) . .
C14 O2 Eu2 143.8(14) . 1_545
C15 O3 C10 120.1(15) . .
C24 O7 C29 118.0(13) . .
C30 O8 Eu1 94.7(10) . 2_756
C30 O9 Eu1 89.7(11) . 2_756
C26 O10 C31 114.0(12) . .
C26 O10 Eu2 123.8(8) . .
C31 O10 Eu2 120.3(10) . .
C32 O11 Eu2 128.6(12) . .
C32 O12 Eu1 140.8(11) . .
C40 O13 C45 114.3(12) . .
C46 O14 Eu1 138.8(13) . .
C42 O16 C47 119.1(13) . .
C48 O17 Eu2 87.7(11) . 1_455
C48 O18 Eu2 96.5(11) . 1_455
C56 O19 C61 115.6(13) . .
C62 O20 Eu1 133.6(11) . .
C58 O22 C63 114.4(14) . .
C64 O23 H23 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O20 2.316(12) .
Eu1 O14 2.320(15) .
Eu1 O12 2.361(10) .
Eu1 O8 2.380(13) 2_756
Eu1 O7W 2.412(16) .
Eu1 O6W 2.429(11) .
Eu1 O9 2.497(12) 2_756
Eu1 O5W 2.506(13) .
Eu1 C30 2.782(19) 2_756
Eu2 O2 2.311(14) 1_565
Eu2 O11 2.398(12) .
Eu2 O18 2.406(12) 1_655
Eu2 O2W 2.460(13) .
Eu2 O4W 2.466(15) .
Eu2 O1W 2.471(14) .
Eu2 O3W 2.491(12) .
Eu2 O17 2.611(14) 1_655
Eu2 O10 2.606(11) .
Eu2 C48 2.840(18) 1_655
C1 C2 1.5001(10) .
C1 H1A 0.9600 .
C1 H1B 0.9600 .
C1 H1C 0.9600 .
C2 C3 1.5001(10) .
C2 H2A 0.9700 .
C2 H2B 0.9700 .
C3 C4 1.43(3) .
C3 H3A 0.9700 .
C3 H3B 0.9700 .
C4 C5 1.50(3) .
C4 H4A 0.9700 .
C4 H4B 0.9700 .
C5 C6 1.52(3) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C6 C7 1.51(3) .
C6 C59 1.53(3) .
C6 H6 0.9800 .
C7 C12 1.37(2) .
C7 C8 1.39(2) .
C8 O1 1.345(19) .
C8 C9 1.43(2) .
C9 C10 1.37(3) .
C9 H9 0.9300 .
C10 C11 1.32(2) .
C10 O3 1.43(2) .
C11 C12 1.39(2) .
C11 C22 1.50(2) .
C12 H12 0.9300 .
C13 O1 1.45(2) .
C13 C14 1.50(3) .
C13 H13A 0.9700 .
C13 H13B 0.9700 .
C14 O6 1.22(2) .
C14 O2 1.22(2) .
C15 O3 1.41(2) .
C15 C16 1.45(3) .
C15 H15A 0.9700 .
C15 H15B 0.9700 .
C16 O4 1.19(3) .
C16 O5 1.30(3) .
C17 C18 1.61(6) .
C17 H17A 0.9600 .
C17 H17B 0.9600 .
C17 H17C 0.9600 .
C18 C19 1.48(5) .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C19 C20 1.65(4) .
C19 H19A 0.9700 .
C19 H19B 0.9700 .
C20 C21 1.51(3) .
C20 H20A 0.9700 .
C20 H20B 0.9700 .
C21 C22 1.52(2) .
C21 H21A 0.9700 .
C21 H21B 0.9700 .
C22 C23 1.51(2) .
C22 H22 0.9800 .
C23 C28 1.39(2) .
C23 C24 1.44(2) .
C24 O7 1.358(18) .
C24 C25 1.37(2) .
C25 C26 1.35(2) .
C25 H25 0.9300 .
C26 C27 1.35(2) .
C26 O10 1.43(2) .
C27 C28 1.34(2) .
C27 C38 1.55(2) .
C28 H28 0.9300 .
C29 O7 1.408(19) .
C29 C30 1.51(3) .
C29 H29A 0.9700 .
C29 H29B 0.9700 .
C30 O9 1.241(19) .
C30 O8 1.26(2) .
C30 Eu1 2.782(19) 2_756
C31 O10 1.428(19) .
C31 C32 1.47(3) .
C31 H31A 0.9700 .
C31 H31B 0.9700 .
C32 O11 1.25(2) .
C32 O12 1.28(2) .
C33 C34 1.49(5) .
C33 H33A 0.9600 .
C33 H33B 0.9600 .
C33 H33C 0.9600 .
C34 C35 1.50(4) .
C34 H34A 0.9700 .
C34 H34B 0.9700 .
C35 C36 1.49(4) .
C35 H35A 0.9700 .
C35 H35B 0.9700 .
C36 C37 1.50(3) .
C36 H36A 0.9700 .
C36 H36B 0.9700 .
C37 C38 1.53(2) .
C37 H37A 0.9700 .
C37 H37B 0.9700 .
C38 C39 1.53(2) .
C38 H38 0.9800 .
C39 C44 1.38(2) .
C39 C40 1.43(2) .
C40 C41 1.23(2) .
C40 O13 1.420(19) .
C41 C42 1.41(2) .
C41 H41 0.9300 .
C42 C43 1.35(2) .
C42 O16 1.378(18) .
C43 C44 1.41(2) .
C43 C54 1.53(2) .
C44 H44 0.9300 .
C45 O13 1.43(2) .
C45 C46 1.53(2) .
C45 H45A 0.9700 .
C45 H45B 0.9700 .
C46 O15 1.23(2) .
C46 O14 1.24(2) .
C47 O16 1.392(18) .
C47 C48 1.56(2) .
C47 H47A 0.9700 .
C47 H47B 0.9700 .
C48 O17 1.23(2) .
C48 O18 1.26(2) .
C48 Eu2 2.840(18) 1_455
C49 C50 1.52(5) .
C49 H49A 0.9600 .
C49 H49B 0.9600 .
C49 H49C 0.9600 .
C50 C51 1.49(4) .
C50 H50A 0.9700 .
C50 H50B 0.9700 .
C51 C52 1.56(3) .
C51 H51A 0.9700 .
C51 H51B 0.9700 .
C52 C53 1.48(3) .
C52 H52A 0.9700 .
C52 H52B 0.9700 .
C53 C54 1.54(3) .
C53 H53A 0.9700 .
C53 H53B 0.9700 .
C54 C55 1.52(2) .
C54 H54 0.9800 .
C55 C56 1.39(2) .
C55 C60 1.42(2) .
C56 O19 1.36(2) .
C56 C57 1.37(2) .
C57 C58 1.40(2) .
C57 H57 0.9300 .
C58 C59 1.38(3) .
C58 O22 1.39(2) .
C59 C60 1.39(3) .
C60 H60 0.9300 .
C61 O19 1.40(2) .
C61 C62 1.51(2) .
C61 H61A 0.9700 .
C61 H61B 0.9700 .
C62 O21 1.21(2) .
C62 O20 1.252(19) .
C63 O22 1.42(2) .
C63 C64 1.49(3) .
C63 H63A 0.9700 .
C63 H63B 0.9700 .
C64 O23 1.24(2) .
C64 O24 1.28(2) .
C65 N1 1.46(3) .
C65 H65A 0.9600 .
C65 H65B 0.9600 .
C65 H65C 0.9600 .
C66 N1 1.52(3) .
C66 H66A 0.9600 .
C66 H66B 0.9600 .
C66 H66C 0.9600 .
O2 Eu2 2.311(14) 1_545
O8 Eu1 2.380(13) 2_756
O9 Eu1 2.497(12) 2_756
O17 Eu2 2.611(14) 1_455
O18 Eu2 2.406(12) 1_455
O23 H23 0.8200 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C1 C2 C3 C4 -26(4) . .
C2 C3 C4 C5 173(3) . .
C3 C4 C5 C6 173(3) . .
C4 C5 C6 C7 169(2) . .
C4 C5 C6 C59 -67(3) . .
C5 C6 C7 C12 83(3) . .
C59 C6 C7 C12 -42(3) . .
C5 C6 C7 C8 -94(3) . .
C59 C6 C7 C8 141(2) . .
C12 C7 C8 O1 -178.9(16) . .
C6 C7 C8 O1 -2(3) . .
C12 C7 C8 C9 2(3) . .
C6 C7 C8 C9 178.1(19) . .
O1 C8 C9 C10 -179.4(17) . .
C7 C8 C9 C10 0(3) . .
C8 C9 C10 C11 -5(3) . .
C8 C9 C10 O3 -174.0(16) . .
C9 C10 C11 C12 7(3) . .
O3 C10 C11 C12 176.4(15) . .
C9 C10 C11 C22 -169.4(18) . .
O3 C10 C11 C22 0(3) . .
C8 C7 C12 C11 1(3) . .
C6 C7 C12 C11 -175.7(19) . .
C10 C11 C12 C7 -5(3) . .
C22 C11 C12 C7 171.6(17) . .
O1 C13 C14 O6 1(2) . .
O1 C13 C14 O2 -178.9(15) . .
O3 C15 C16 O4 161(2) . .
O3 C15 C16 O5 -22(3) . .
C17 C18 C19 C20 -161(3) . .
C18 C19 C20 C21 -74(4) . .
C19 C20 C21 C22 172(2) . .
C10 C11 C22 C23 -122.3(19) . .
C12 C11 C22 C23 62(2) . .
C10 C11 C22 C21 111(2) . .
C12 C11 C22 C21 -65(2) . .
C20 C21 C22 C11 -63(2) . .
C20 C21 C22 C23 171.4(18) . .
C11 C22 C23 C28 -114.0(18) . .
C21 C22 C23 C28 11(2) . .
C11 C22 C23 C24 71.9(18) . .
C21 C22 C23 C24 -162.8(15) . .
C28 C23 C24 O7 -179.0(14) . .
C22 C23 C24 O7 -4(2) . .
C28 C23 C24 C25 -1(2) . .
C22 C23 C24 C25 173.4(14) . .
O7 C24 C25 C26 177.4(15) . .
C23 C24 C25 C26 0(2) . .
C24 C25 C26 C27 2(3) . .
C24 C25 C26 O10 -171.5(14) . .
C25 C26 C27 C28 -2(3) . .
O10 C26 C27 C28 171.1(14) . .
C25 C26 C27 C38 -177.2(15) . .
O10 C26 C27 C38 -4(2) . .
C26 C27 C28 C23 0(3) . .
C38 C27 C28 C23 175.3(15) . .
C24 C23 C28 C27 2(2) . .
C22 C23 C28 C27 -172.7(16) . .
O7 C29 C30 O9 -168.6(14) . .
O7 C29 C30 O8 21(2) . .
O7 C29 C30 Eu1 98(3) . 2_756
O10 C31 C32 O11 14(2) . .
O10 C31 C32 O12 -175.3(14) . .
C33 C34 C35 C36 180(4) . .
C34 C35 C36 C37 -167(3) . .
C35 C36 C37 C38 173(2) . .
C36 C37 C38 C39 175.1(17) . .
C36 C37 C38 C27 -59(2) . .
C28 C27 C38 C39 86(2) . .
C26 C27 C38 C39 -98.9(19) . .
C28 C27 C38 C37 -37(2) . .
C26 C27 C38 C37 138.4(16) . .
C37 C38 C39 C44 83(2) . .
C27 C38 C39 C44 -42(2) . .
C37 C38 C39 C40 -94(2) . .
C27 C38 C39 C40 140.2(17) . .
C44 C39 C40 C41 -5(3) . .
C38 C39 C40 C41 172.7(18) . .
C44 C39 C40 O13 178.7(15) . .
C38 C39 C40 O13 -3(2) . .
O13 C40 C41 C42 -179.1(16) . .
C39 C40 C41 C42 5(3) . .
C40 C41 C42 C43 0(3) . .
C40 C41 C42 O16 177.2(17) . .
O16 C42 C43 C44 177.7(15) . .
C41 C42 C43 C44 -5(3) . .
O16 C42 C43 C54 1(3) . .
C41 C42 C43 C54 178.1(16) . .
C40 C39 C44 C43 0(3) . .
C38 C39 C44 C43 -178.1(16) . .
C42 C43 C44 C39 5(3) . .
C54 C43 C44 C39 -178.0(16) . .
O13 C45 C46 O15 -167.0(15) . .
O13 C45 C46 O14 15(2) . .
O16 C47 C48 O17 11(2) . .
O16 C47 C48 O18 -166.3(14) . .
O16 C47 C48 Eu2 -150(5) . 1_455
C49 C50 C51 C52 178(3) . .
C50 C51 C52 C53 -177(2) . .
C51 C52 C53 C54 178.5(19) . .
C42 C43 C54 C55 -130.8(17) . .
C44 C43 C54 C55 52(2) . .
C42 C43 C54 C53 100.2(19) . .
C44 C43 C54 C53 -76.8(19) . .
C52 C53 C54 C55 169.0(16) . .
C52 C53 C54 C43 -62(2) . .
C43 C54 C55 C56 62.9(19) . .
C53 C54 C55 C56 -169.7(14) . .
C43 C54 C55 C60 -117.3(16) . .
C53 C54 C55 C60 10(2) . .
C60 C55 C56 O19 176.0(13) . .
C54 C55 C56 O19 -4(2) . .
C60 C55 C56 C57 -9(2) . .
C54 C55 C56 C57 170.9(15) . .
O19 C56 C57 C58 179.5(14) . .
C55 C56 C57 C58 4(2) . .
C56 C57 C58 C59 2(3) . .
C56 C57 C58 O22 179.5(15) . .
O22 C58 C59 C60 179.5(18) . .
C57 C58 C59 C60 -3(3) . .
O22 C58 C59 C6 -4(3) . .
C57 C58 C59 C6 173.8(19) . .
C7 C6 C59 C58 -85(3) . .
C5 C6 C59 C58 151(2) . .
C7 C6 C59 C60 92(3) . .
C5 C6 C59 C60 -32(4) . .
C58 C59 C60 C55 -2(3) . .
C6 C59 C60 C55 -179(2) . .
C56 C55 C60 C59 8(2) . .
C54 C55 C60 C59 -171.9(17) . .
O19 C61 C62 O21 14(2) . .
O19 C61 C62 O20 -169.1(14) . .
O22 C63 C64 O23 151.8(19) . .
O22 C63 C64 O24 -37(3) . .
C7 C8 O1 C13 170.1(15) . .
C9 C8 O1 C13 -10(2) . .
C14 C13 O1 C8 84.6(19) . .
O6 C14 O2 Eu2 6(4) . 1_545
C13 C14 O2 Eu2 -174.0(15) . 1_545
C16 C15 O3 C10 -73(2) . .
C11 C10 O3 C15 -167.5(18) . .
C9 C10 O3 C15 3(3) . .
C25 C24 O7 C29 -34(2) . .
C23 C24 O7 C29 143.8(15) . .
C30 C29 O7 C24 88.7(18) . .
O9 C30 O8 Eu1 -12.8(17) . 2_756
C29 C30 O8 Eu1 157.2(13) . 2_756
O8 C30 O9 Eu1 12.2(16) . 2_756
C29 C30 O9 Eu1 -157.8(14) . 2_756
C25 C26 O10 C31 -103.0(17) . .
C27 C26 O10 C31 83.8(19) . .
C25 C26 O10 Eu2 61.2(17) . .
C27 C26 O10 Eu2 -112.0(14) . .
C32 C31 O10 C26 155.0(14) . .
C32 C31 O10 Eu2 -9.9(18) . .
O2 Eu2 O10 C26 111.9(12) 1_565 .
O11 Eu2 O10 C26 -159.4(13) . .
O18 Eu2 O10 C26 32.3(11) 1_655 .
O2W Eu2 O10 C26 -85.8(13) . .
O4W Eu2 O10 C26 -82.0(12) . .
O1W Eu2 O10 C26 58.0(13) . .
O3W Eu2 O10 C26 171.2(11) . .
O17 Eu2 O10 C26 -14.6(12) 1_655 .
C48 Eu2 O10 C26 7.8(12) 1_655 .
O2 Eu2 O10 C31 -84.8(12) 1_565 .
O11 Eu2 O10 C31 3.9(11) . .
O18 Eu2 O10 C31 -164.4(12) 1_655 .
O2W Eu2 O10 C31 77.5(13) . .
O4W Eu2 O10 C31 81.3(12) . .
O1W Eu2 O10 C31 -138.7(12) . .
O3W Eu2 O10 C31 -25.5(13) . .
O17 Eu2 O10 C31 148.7(12) 1_655 .
C48 Eu2 O10 C31 171.0(12) 1_655 .
O12 C32 O11 Eu2 176.6(11) . .
C31 C32 O11 Eu2 -13(2) . .
O2 Eu2 O11 C32 84.2(16) 1_565 .
O18 Eu2 O11 C32 19.5(18) 1_655 .
O2W Eu2 O11 C32 -140.0(15) . .
O4W Eu2 O11 C32 -76.3(16) . .
O1W Eu2 O11 C32 142.4(14) . .
O3W Eu2 O11 C32 158.8(17) . .
O17 Eu2 O11 C32 -55.3(18) 1_655 .
O10 Eu2 O11 C32 4.9(14) . .
C48 Eu2 O11 C32 -15(2) 1_655 .
O11 C32 O12 Eu1 151.7(14) . .
C31 C32 O12 Eu1 -19(3) . .
O20 Eu1 O12 C32 58.3(18) . .
O14 Eu1 O12 C32 -38.9(18) . .
O8 Eu1 O12 C32 154.6(19) 2_756 .
O7W Eu1 O12 C32 -119.4(19) . .
O6W Eu1 O12 C32 6(2) . .
O9 Eu1 O12 C32 126.6(18) 2_756 .
O5W Eu1 O12 C32 -143.8(17) . .
C30 Eu1 O12 C32 143.9(18) 2_756 .
C41 C40 O13 C45 9(2) . .
C39 C40 O13 C45 -174.8(14) . .
C46 C45 O13 C40 63.1(18) . .
O15 C46 O14 Eu1 -13(3) . .
C45 C46 O14 Eu1 164.5(12) . .
O20 Eu1 O14 C46 161.1(18) . .
O12 Eu1 O14 C46 -122.0(19) . .
O8 Eu1 O14 C46 -95(2) 2_756 .
O7W Eu1 O14 C46 -49.8(18) . .
O6W Eu1 O14 C46 83.8(18) . .
O9 Eu1 O14 C46 92(2) 2_756 .
O5W Eu1 O14 C46 13.3(19) . .
C30 Eu1 O14 C46 -69(9) 2_756 .
C43 C42 O16 C47 -150.4(16) . .
C41 C42 O16 C47 32(2) . .
C48 C47 O16 C42 -91.4(18) . .
O18 C48 O17 Eu2 1.1(19) . 1_455
C47 C48 O17 Eu2 -176.0(16) . 1_455
O17 C48 O18 Eu2 -1(2) . 1_455
C47 C48 O18 Eu2 176.3(11) . 1_455
C57 C56 O19 C61 87.1(19) . .
C55 C56 O19 C61 -97.6(18) . .
C62 C61 O19 C56 -102.5(18) . .
O21 C62 O20 Eu1 -104(2) . .
C61 C62 O20 Eu1 79.6(18) . .
O14 Eu1 O20 C62 -85.0(15) . .
O12 Eu1 O20 C62 -163.1(16) . .
O8 Eu1 O20 C62 124.0(15) 2_756 .
O7W Eu1 O20 C62 -158.9(14) . .
O6W Eu1 O20 C62 -11.2(15) . .
O9 Eu1 O20 C62 72.9(15) 2_756 .
O5W Eu1 O20 C62 41.3(18) . .
C30 Eu1 O20 C62 97.7(15) 2_756 .
C59 C58 O22 C63 -131.5(19) . .
C57 C58 O22 C63 51(2) . .
C64 C63 O22 C58 -96(2) . .
