#------------------------------------------------------------------------------
#$Date: 2019-08-26 09:35:46 +0300 (Mon, 26 Aug 2019) $
#$Revision: 217704 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/34/7233434.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7233434
loop_
_publ_author_name
'Jia Li'
'Jin-Yun Wang'
'Zhong-Ning Chen'
_publ_section_title
;
 Sensitized EuIII luminescence through energy transfer from PtM2 (M = Ag
 or Au) alkynyl chromophores in PtM2Eu2 heteropentanuclear complexes
;
_journal_name_full               'Journal of Materials Chemistry C'
_journal_page_first              3661
_journal_page_last               3668
_journal_paper_doi               10.1039/C3TC30474D
_journal_volume                  1
_journal_year                    2013
_chemical_formula_sum            'C148 H112 Ag2 Cl2 Eu2 F36 N6 O22 P6 Pt'
_chemical_formula_weight         3981.91
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                91.365(3)
_cell_angle_beta                 93.191(3)
_cell_angle_gamma                106.915(3)
_cell_formula_units_Z            1
_cell_length_a                   15.030(4)
_cell_length_b                   15.677(4)
_cell_length_c                   19.167(4)
_cell_measurement_temperature    293(2)
_cell_volume                     4310.4(18)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0431
_diffrn_reflns_av_sigmaI/netI    0.0629
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            32935
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.20
_exptl_absorpt_coefficient_mu    1.935
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.6542
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_density_diffrn    1.534
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1964
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_platon_squeeze_details
;
;
_refine_diff_density_max         1.184
_refine_diff_density_min         -1.285
_refine_diff_density_rms         0.103
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.064
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1079
_refine_ls_number_reflns         14953
_refine_ls_number_restraints     418
_refine_ls_restrained_S_all      1.143
_refine_ls_R_factor_all          0.0716
_refine_ls_R_factor_gt           0.0592
_refine_ls_shift/su_max          0.020
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0906P)²+0.6268P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1587
_refine_ls_wR_factor_ref         0.1701
_reflns_number_gt                12106
_reflns_number_total             14953
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            J-Mater-Chem-C-1-3661-1.cif
_cod_data_source_block           a
_cod_original_cell_volume        4310.2(17)
_cod_original_sg_symbol_H-M      p-1
_cod_database_code               7233434
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.0000 0.5000 0.5000 0.04510(12) Uani 1 2 d S . .
Ag1 Ag -0.06091(5) 0.63445(4) 0.42300(3) 0.07178(19) Uani 1 1 d . . .
O1 O 0.7462(5) 0.7599(4) 0.0794(3) 0.0875(17) Uani 1 1 d . . .
O2 O 0.7404(4) 0.6813(4) -0.0513(3) 0.0871(17) Uani 1 1 d . . .
O3 O 0.8052(4) 0.8726(4) -0.0557(3) 0.0897(18) Uani 1 1 d . . .
O4 O 0.6515(4) 0.7739(4) -0.1459(3) 0.0860(18) Uani 1 1 d . . .
O6 O 0.5004(5) 0.7896(5) -0.0609(3) 0.0917(19) Uani 1 1 d . . .
O5 O 0.6506(5) 0.9345(5) -0.0650(4) 0.099(2) Uani 1 1 d . . .
N1 N 0.5378(5) 0.6329(5) -0.0413(3) 0.0736(18) Uani 1 1 d . . .
N2 N 0.5410(4) 0.7373(4) 0.0741(3) 0.0642(16) Uani 1 1 d . . .
N3 N 0.6710(5) 0.8969(5) 0.0828(4) 0.0782(19) Uani 1 1 d . . .
C1 C 0.1442(5) 0.7189(4) 0.5257(4) 0.0566(16) Uani 1 1 d . . .
H1A H 0.1874 0.7076 0.4934 0.068 Uiso 1 1 calc R . .
H1B H 0.1796 0.7650 0.5595 0.068 Uiso 1 1 calc R . .
C2 C 0.1991(5) 0.5895(5) 0.6039(4) 0.0614(18) Uani 1 1 d . . .
H2A H 0.2340 0.6358 0.6378 0.074 Uiso 1 1 calc R . .
H2B H 0.2379 0.5897 0.5652 0.074 Uiso 1 1 calc R . .
C3 C 0.1264(6) 0.8306(5) 0.4139(4) 0.0652(18) Uani 1 1 d U . .
C4 C 0.0949(8) 0.8222(7) 0.3426(5) 0.093(3) Uani 1 1 d U . .
H4A H 0.0385 0.7811 0.3275 0.112 Uiso 1 1 calc R . .
C5 C 0.1485(11) 0.8754(8) 0.2967(6) 0.116(4) Uani 1 1 d U . .
H5A H 0.1270 0.8709 0.2499 0.140 Uiso 1 1 calc R . .
C6 C 0.2295(11) 0.9327(8) 0.3156(7) 0.121(4) Uani 1 1 d U . .
H6A H 0.2641 0.9674 0.2822 0.145 Uiso 1 1 calc R . .
C7 C 0.2634(9) 0.9422(7) 0.3837(7) 0.117(4) Uani 1 1 d U . .
H7A H 0.3207 0.9835 0.3965 0.140 Uiso 1 1 calc R . .
C8 C 0.2126(7) 0.8901(6) 0.4340(5) 0.088(3) Uani 1 1 d U . .
H8A H 0.2361 0.8952 0.4803 0.106 Uiso 1 1 calc R . .
C9 C 0.0213(6) 0.8349(5) 0.5338(4) 0.067(2) Uani 1 1 d . . .
C10 C 0.0759(8) 0.8821(7) 0.5904(6) 0.099(3) Uani 1 1 d . . .
H10A H 0.1350 0.8766 0.6017 0.119 Uiso 1 1 calc R . .
C11 C 0.0397(11) 0.9385(9) 0.6303(7) 0.127(5) Uani 1 1 d . . .
H11A H 0.0760 0.9686 0.6692 0.152 Uiso 1 1 calc R . .
C12 C -0.0394(13) 0.9517(10) 0.6174(8) 0.133(5) Uani 1 1 d . . .
H12A H -0.0576 0.9941 0.6430 0.159 Uiso 1 1 calc R . .
C13 C -0.0939(12) 0.9029(12) 0.5663(10) 0.157(6) Uani 1 1 d . . .
H13A H -0.1549 0.9051 0.5593 0.189 Uiso 1 1 calc R . .
C14 C -0.0616(9) 0.8477(9) 0.5225(7) 0.119(4) Uani 1 1 d . . .
H14A H -0.0996 0.8188 0.4838 0.142 Uiso 1 1 calc R . .
C15 C 0.0471(6) 0.6601(5) 0.6458(4) 0.066(2) Uani 1 1 d . . .
C16 C -0.0427(7) 0.6586(6) 0.6423(5) 0.085(3) Uani 1 1 d . . .
H16A H -0.0826 0.6290 0.6049 0.103 Uiso 1 1 calc R . .
C17 C -0.0765(10) 0.7019(7) 0.6956(8) 0.123(5) Uani 1 1 d . . .
H17A H -0.1380 0.7034 0.6923 0.148 Uiso 1 1 calc R . .
C18 C -0.0202(15) 0.7405(9) 0.7502(8) 0.147(7) Uani 1 1 d . . .
H18A H -0.0426 0.7696 0.7850 0.176 Uiso 1 1 calc R . .
C19 C 0.0699(13) 0.7384(8) 0.7564(6) 0.124(5) Uani 1 1 d . . .
H19A H 0.1067 0.7622 0.7969 0.149 Uiso 1 1 calc R . .
C20 C 0.1068(8) 0.7020(6) 0.7041(5) 0.092(3) Uani 1 1 d . . .
H20A H 0.1695 0.7046 0.7067 0.111 Uiso 1 1 calc R . .
C21 C -0.2903(6) 0.5324(6) 0.3393(4) 0.070(2) Uani 1 1 d . . .
C22 C -0.2961(8) 0.6179(7) 0.3312(6) 0.099(3) Uani 1 1 d . . .
H22A H -0.2417 0.6653 0.3326 0.119 Uiso 1 1 calc R . .
C23 C -0.3824(10) 0.6347(10) 0.3209(7) 0.123(4) Uani 1 1 d . . .
H23A H -0.3861 0.6926 0.3165 0.147 Uiso 1 1 calc R . .
C24 C -0.4632(9) 0.5614(12) 0.3174(6) 0.116(4) Uani 1 1 d . . .
H24A H -0.5214 0.5700 0.3086 0.140 Uiso 1 1 calc R . .
C25 C -0.4565(7) 0.4810(10) 0.3265(5) 0.107(4) Uani 1 1 d . . .
H25A H -0.5114 0.4344 0.3269 0.128 Uiso 1 1 calc R . .
C26 C -0.3734(7) 0.4612(7) 0.3356(5) 0.091(3) Uani 1 1 d . . .
H26A H -0.3721 0.4025 0.3392 0.109 Uiso 1 1 calc R . .
C27 C -0.1360(6) 0.5046(6) 0.2687(4) 0.071(2) Uani 1 1 d . . .
C28 C -0.1964(7) 0.4641(7) 0.2123(5) 0.096(3) Uani 1 1 d . . .
H28A H -0.2601 0.4435 0.2177 0.115 Uiso 1 1 calc R . .
C29 C -0.1630(9) 0.4543(9) 0.1494(5) 0.110(4) Uani 1 1 d . . .
H29A H -0.2036 0.4241 0.1124 0.132 Uiso 1 1 calc R . .
C30 C -0.0679(9) 0.4894(10) 0.1397(6) 0.120(4) Uani 1 1 d . . .
H30A H -0.0458 0.4855 0.0957 0.144 Uiso 1 1 calc R . .
C31 C -0.0084(9) 0.5287(10) 0.1941(6) 0.121(4) Uani 1 1 d . . .
H31A H 0.0552 0.5499 0.1881 0.145 Uiso 1 1 calc R . .
C32 C -0.0420(7) 0.5379(8) 0.2595(5) 0.095(3) Uani 1 1 d . . .
H32A H -0.0011 0.5663 0.2968 0.114 Uiso 1 1 calc R . .
C33 C 0.0937(5) 0.5426(5) 0.4285(4) 0.0552(16) Uani 1 1 d . . .
C34 C 0.1497(5) 0.5705(5) 0.3867(4) 0.0594(18) Uani 1 1 d . . .
C35 C 0.2160(5) 0.5986(5) 0.3332(4) 0.0597(17) Uani 1 1 d . . .
C36 C 0.2370(6) 0.5368(5) 0.2881(4) 0.073(2) Uani 1 1 d . . .
H36A H 0.2074 0.4761 0.2913 0.088 Uiso 1 1 calc R . .
C37 C 0.3012(6) 0.5653(5) 0.2393(4) 0.072(2) Uani 1 1 d . . .
H37A H 0.3151 0.5229 0.2106 0.087 Uiso 1 1 calc R . .
C38 C 0.3457(5) 0.6535(5) 0.2310(4) 0.0590(17) Uani 1 1 d . . .
C39 C 0.3245(6) 0.7143(5) 0.2759(5) 0.080(3) Uani 1 1 d . . .
H39A H 0.3533 0.7748 0.2714 0.096 Uiso 1 1 calc R . .
C40 C 0.2628(6) 0.6887(6) 0.3264(4) 0.078(2) Uani 1 1 d . . .
H40A H 0.2520 0.7315 0.3565 0.094 Uiso 1 1 calc R . .
C41 C 0.5321(8) 0.5856(7) -0.1031(4) 0.086(3) Uani 1 1 d . . .
H41A H 0.5825 0.6015 -0.1310 0.103 Uiso 1 1 calc R . .
C42 C 0.4573(8) 0.5170(7) -0.1262(4) 0.087(3) Uani 1 1 d . . .
H42A H 0.4567 0.4861 -0.1683 0.104 Uiso 1 1 calc R . .
C43 C 0.3839(7) 0.4950(7) -0.0861(4) 0.089(3) Uani 1 1 d . . .
H43A H 0.3318 0.4480 -0.1009 0.107 Uiso 1 1 calc R . .
C44 C 0.3845(6) 0.5400(6) -0.0247(4) 0.079(2) Uani 1 1 d . . .
H44A H 0.3329 0.5252 0.0021 0.095 Uiso 1 1 calc R . .
C45 C 0.4637(6) 0.6086(6) -0.0026(4) 0.066(2) Uani 1 1 d . . .
C46 C 0.4705(5) 0.6618(5) 0.0644(4) 0.0601(18) Uani 1 1 d . . .
C47 C 0.4068(5) 0.6337(5) 0.1155(4) 0.0634(19) Uani 1 1 d . . .
H47A H 0.3595 0.5802 0.1080 0.076 Uiso 1 1 calc R . .
C48 C 0.4123(5) 0.6831(5) 0.1766(4) 0.0611(18) Uani 1 1 d . . .
C49 C 0.4878(5) 0.7612(5) 0.1858(4) 0.0623(18) Uani 1 1 d . . .
H49A H 0.4962 0.7955 0.2272 0.075 Uiso 1 1 calc R . .
C50 C 0.5497(5) 0.7878(5) 0.1344(4) 0.0622(18) Uani 1 1 d . . .
C51 C 0.6268(6) 0.8717(5) 0.1411(4) 0.069(2) Uani 1 1 d . . .
C52 C 0.6532(7) 0.9205(7) 0.2036(5) 0.094(3) Uani 1 1 d . . .
H52A H 0.6210 0.9019 0.2432 0.113 Uiso 1 1 calc R . .
C53 C 0.7283(8) 0.9978(8) 0.2069(6) 0.104(3) Uani 1 1 d . . .
H53A H 0.7466 1.0313 0.2487 0.125 Uiso 1 1 calc R . .
C54 C 0.7756(8) 1.0241(8) 0.1469(7) 0.112(4) Uani 1 1 d . . .
H54A H 0.8260 1.0753 0.1472 0.134 Uiso 1 1 calc R . .
C55 C 0.7449(7) 0.9721(6) 0.0883(6) 0.098(3) Uani 1 1 d . . .
H55A H 0.7768 0.9890 0.0483 0.117 Uiso 1 1 calc R . .
C56 C 0.8634(7) 0.7564(7) 0.1613(6) 0.115(3) Uani 1 1 d DU . .
C57 C 0.8171(7) 0.7362(6) 0.0894(5) 0.082(2) Uani 1 1 d . C .
C58 C 0.8550(7) 0.6923(7) 0.0404(6) 0.093(3) Uani 1 1 d . . .
H58A H 0.9105 0.6799 0.0525 0.112 Uiso 1 1 calc R C .
C59 C 0.8133(7) 0.6671(7) -0.0246(6) 0.087(3) Uani 1 1 d . A .
C60 C 0.8539(6) 0.6114(7) -0.0737(6) 0.119(3) Uani 1 1 d DU . .
F4 F 0.7941(9) 0.5309(8) -0.0876(9) 0.132(4) Uani 0.50 1 d PDU A 1
F5 F 0.8735(13) 0.6488(11) -0.1323(8) 0.152(4) Uani 0.50 1 d PDU A 1
F6 F 0.9283(10) 0.5942(12) -0.0444(8) 0.140(4) Uani 0.50 1 d PDU A 1
F4' F 0.9422(8) 0.6540(11) -0.0840(8) 0.138(4) Uani 0.50 1 d PDU A 2
F5' F 0.8483(13) 0.5337(9) -0.0508(9) 0.148(4) Uani 0.50 1 d PDU A 2
F6' F 0.8148(11) 0.6026(12) -0.1390(6) 0.143(4) Uani 0.50 1 d PDU A 2
C61 C 0.9346(9) 0.9536(7) -0.1112(5) 0.126(4) Uani 1 1 d DU . .
C62 C 0.8354(7) 0.8929(6) -0.1154(5) 0.083(3) Uani 1 1 d U . .
C63 C 0.7943(7) 0.8652(7) -0.1805(5) 0.096(3) Uani 1 1 d . . .
H63A H 0.8268 0.8877 -0.2192 0.115 Uiso 1 1 calc R . .
C64 C 0.7066(8) 0.8052(7) -0.1914(5) 0.096(3) Uani 1 1 d . . .
C65 C 0.6720(10) 0.7704(12) -0.2659(6) 0.125(4) Uani 1 1 d U . .
C66 C 0.6257(11) 1.0550(9) -0.1261(9) 0.122(4) Uani 1 1 d U . .
C67 C 0.5926(9) 0.9574(8) -0.1029(7) 0.108(3) Uani 1 1 d U . .
C68 C 0.5017(10) 0.9111(9) -0.1265(8) 0.134(3) Uani 1 1 d U . .
H68A H 0.4679 0.9365 -0.1574 0.161 Uiso 1 1 calc R . .
C69 C 0.4635(9) 0.8281(8) -0.1035(7) 0.130(4) Uani 1 1 d DU B .
C70 C 0.3634(10) 0.7795(8) -0.1281(6) 0.147(4) Uani 1 1 d DU . .
F16 F 0.3513(14) 0.6954(8) -0.1433(12) 0.195(7) Uani 0.50 1 d PDU B 1
F17 F 0.3355(12) 0.8127(12) -0.1843(8) 0.163(6) Uani 0.50 1 d PDU B 1
F18 F 0.3077(11) 0.7864(16) -0.0793(10) 0.208(7) Uani 0.50 1 d PDU B 1
F16' F 0.3154(12) 0.8300(13) -0.1509(12) 0.202(7) Uani 0.50 1 d PDU B 2
F17' F 0.3180(10) 0.7332(12) -0.0772(9) 0.168(6) Uani 0.50 1 d PDU B 2
F18' F 0.3624(13) 0.7203(11) -0.1787(9) 0.185(6) Uani 0.50 1 d PDU B 2
Eu1 Eu 0.65430(3) 0.78971(3) -0.02193(2) 0.07078(16) Uani 1 1 d . . .
P1 P 0.05799(14) 0.76053(12) 0.47665(10) 0.0575(4) Uani 1 1 d . . .
P2 P 0.09412(12) 0.61700(12) 0.57175(9) 0.0514(4) Uani 1 1 d . . .
P3 P -0.17589(14) 0.51919(13) 0.35507(10) 0.0612(5) Uani 1 1 d . . .
F1 F 0.9539(10) 0.771(2) 0.1619(16) 0.175(10) Uani 0.50 1 d PDU C 1
F2 F 0.849(2) 0.8242(15) 0.1941(14) 0.180(12) Uani 0.50 1 d PDU C 1
F3 F 0.830(2) 0.6871(16) 0.1988(17) 0.193(11) Uani 0.50 1 d PDU C 1
F1' F 0.8970(19) 0.8419(9) 0.1756(17) 0.160(9) Uani 0.50 1 d PDU C 2
F2' F 0.9310(16) 0.7214(19) 0.1761(19) 0.188(11) Uani 0.50 1 d PDU C 2
F3' F 0.7999(16) 0.7253(19) 0.2061(13) 0.191(11) Uani 0.50 1 d PDU C 2
F7 F 0.9925(6) 0.9173(9) -0.0804(7) 0.234(5) Uani 1 1 d DU . .
F8 F 0.9445(9) 1.0272(7) -0.0750(7) 0.252(6) Uani 1 1 d DU . .
F9 F 0.9677(6) 0.9760(7) -0.1713(4) 0.222(5) Uani 1 1 d DU . .
F10 F 0.5859(7) 0.7547(11) -0.2824(4) 0.237(6) Uani 1 1 d U . .
F11 F 0.7199(9) 0.8115(8) -0.3140(4) 0.236(6) Uani 1 1 d U . .
F12 F 0.6756(7) 0.6888(7) -0.2748(5) 0.171(3) Uani 1 1 d U . .
F13 F 0.7168(8) 1.0767(7) -0.1385(7) 0.210(5) Uani 1 1 d . . .
F14 F 0.5901(8) 1.0712(6) -0.1856(6) 0.210(5) Uani 1 1 d . . .
F15 F 0.6165(10) 1.1105(6) -0.0813(6) 0.217(6) Uani 1 1 d . . .
Cl1 Cl -0.3768(3) 1.1425(3) 0.3604(2) 0.1220(15) Uani 0.588(8) 1 d PD D 1
O7 O -0.3570(9) 1.2316(7) 0.3338(7) 0.133(5) Uani 0.588(8) 1 d PDU D 1
O8 O -0.4511(8) 1.0781(8) 0.3151(6) 0.124(5) Uani 0.588(8) 1 d PDU D 1
O9 O -0.3017(7) 1.1139(8) 0.3817(6) 0.106(4) Uani 0.588(8) 1 d PDU D 1
O10 O -0.4300(7) 1.1516(7) 0.4315(5) 0.267(4) Uani 0.588(8) 1 d PDU D 1
Cl1' Cl -0.4300(7) 1.1516(7) 0.4315(5) 0.267(4) Uani 0.412(8) 1 d PD D 2
O7' O -0.4522(17) 1.0647(12) 0.4621(10) 0.221(8) Uani 0.412(8) 1 d PDU D 2
O8' O -0.5163(10) 1.1716(16) 0.4117(10) 0.163(6) Uani 0.412(8) 1 d PDU D 2
O9' O -0.3705(13) 1.2206(14) 0.4768(8) 0.171(7) Uani 0.412(8) 1 d PDU D 2
O10' O -0.3768(3) 1.1425(3) 0.3604(2) 0.1220(15) Uani 0.412(8) 1 d PDU D 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C33 Pt1 C33 180.000(1) 2_566 .
C33 Pt1 P2 94.2(2) 2_566 .
C33 Pt1 P2 85.8(2) . .
C33 Pt1 P2 85.8(2) 2_566 2_566
C33 Pt1 P2 94.2(2) . 2_566
P2 Pt1 P2 180.000(1) . 2_566
C33 Pt1 Ag1 74.2(2) 2_566 2_566
C33 Pt1 Ag1 105.8(2) . 2_566
P2 Pt1 Ag1 92.90(5) . 2_566
P2 Pt1 Ag1 87.10(5) 2_566 2_566
C33 Pt1 Ag1 105.8(2) 2_566 .
C33 Pt1 Ag1 74.2(2) . .
P2 Pt1 Ag1 87.10(5) . .
P2 Pt1 Ag1 92.90(5) 2_566 .
Ag1 Pt1 Ag1 180.00(2) 2_566 .
P3 Ag1 P1 172.26(7) . .
P3 Ag1 Pt1 90.54(5) . .
P1 Ag1 Pt1 95.37(5) . .
C57 O1 Eu1 136.7(6) . .
C59 O2 Eu1 133.1(7) . .
C62 O3 Eu1 131.2(6) . .
C64 O4 Eu1 135.4(7) . .
C69 O6 Eu1 138.0(7) . .
C67 O5 Eu1 132.4(7) . .
C45 N1 C41 116.5(8) . .
C45 N1 Eu1 119.7(6) . .
C41 N1 Eu1 120.4(6) . .
C46 N2 C50 119.4(6) . .
C46 N2 Eu1 120.3(5) . .
C50 N2 Eu1 120.3(5) . .
C51 N3 C55 116.9(8) . .
C51 N3 Eu1 121.9(5) . .
C55 N3 Eu1 118.6(6) . .
P2 C1 P1 114.3(4) . .
P2 C2 P3 114.2(4) . 2_566
C8 C3 C4 118.8(8) . .
C8 C3 P1 120.9(7) . .
C4 C3 P1 120.2(7) . .
C5 C4 C3 118.7(11) . .
C6 C5 C4 122.6(12) . .
C5 C6 C7 120.7(11) . .
C6 C7 C8 120.1(12) . .
C3 C8 C7 118.9(10) . .
C14 C9 C10 116.1(9) . .
C14 C9 P1 120.3(8) . .
C10 C9 P1 123.5(7) . .
C9 C10 C11 117.9(11) . .
C12 C11 C10 125.0(13) . .
C11 C12 C13 117.2(13) . .
C12 C13 C14 120.9(14) . .
C9 C14 C13 122.4(13) . .
C16 C15 C20 120.1(8) . .
C16 C15 P2 119.7(7) . .
C20 C15 P2 120.0(7) . .
C15 C16 C17 119.8(11) . .
C18 C17 C16 119.7(13) . .
C17 C18 C19 121.2(11) . .
C18 C19 C20 120.9(13) . .
C19 C20 C15 118.1(12) . .
C22 C21 C26 118.6(9) . .
C22 C21 P3 117.4(7) . .
C26 C21 P3 124.0(7) . .
C21 C22 C23 121.3(11) . .
C22 C23 C24 117.9(12) . .
C25 C24 C23 119.9(11) . .
C24 C25 C26 124.1(12) . .
C25 C26 C21 118.1(11) . .
C32 C27 C28 119.4(9) . .
C32 C27 P3 117.9(7) . .
C28 C27 P3 122.7(7) . .
C29 C28 C27 120.3(10) . .
C28 C29 C30 120.3(10) . .
C31 C30 C29 120.0(10) . .
C30 C31 C32 120.0(11) . .
C27 C32 C31 119.9(10) . .
C34 C33 Pt1 178.0(7) . .
C33 C34 C35 176.1(8) . .
C40 C35 C36 117.6(6) . .
C40 C35 C34 120.8(7) . .
C36 C35 C34 121.6(7) . .
C37 C36 C35 120.1(7) . .
C38 C37 C36 122.8(7) . .
C37 C38 C39 116.7(7) . .
C37 C38 C48 122.0(7) . .
C39 C38 C48 121.3(7) . .
C40 C39 C38 122.5(7) . .
C39 C40 C35 120.3(8) . .
C42 C41 N1 124.0(9) . .
C43 C42 C41 117.8(9) . .
C42 C43 C44 121.3(10) . .
C43 C44 C45 118.6(9) . .
N1 C45 C44 121.8(8) . .
N1 C45 C46 115.9(7) . .
C44 C45 C46 122.3(7) . .
N2 C46 C47 120.9(7) . .
N2 C46 C45 117.5(6) . .
C47 C46 C45 121.6(7) . .
C48 C47 C46 121.6(8) . .
C47 C48 C49 116.2(6) . .
C47 C48 C38 121.9(7) . .
C49 C48 C38 121.9(7) . .
C50 C49 C48 121.2(7) . .
N2 C50 C49 120.7(7) . .
N2 C50 C51 116.9(6) . .
C49 C50 C51 122.4(7) . .
N3 C51 C52 121.9(8) . .
N3 C51 C50 115.8(7) . .
C52 C51 C50 122.3(7) . .
C51 C52 C53 119.6(9) . .
C52 C53 C54 119.1(10) . .
C55 C54 C53 117.0(10) . .
C54 C55 N3 125.4(9) . .
F2 C56 F1' 35.9(17) . .
F2 C56 F3 106.5(13) . .
F1' C56 F3 134(3) . .
F2 C56 F2' 126(2) . .
F1' C56 F2' 106.6(13) . .
F3 C56 F2' 72.5(15) . .
F2 C56 F1 107.0(13) . .
F1' C56 F1 75.9(16) . .
F3 C56 F1 107.8(13) . .
F2' C56 F1 36.4(16) . .
F2 C56 F3' 72.1(17) . .
F1' C56 F3' 106.6(13) . .
F3 C56 F3' 38.5(15) . .
F2' C56 F3' 106.5(13) . .
F1 C56 F3' 135(2) . .
F2 C56 C57 114.6(14) . .
F1' C56 C57 112.3(18) . .
F3 C56 C57 108.0(18) . .
F2' C56 C57 116.4(18) . .
F1 C56 C57 112.5(16) . .
F3' C56 C57 107.8(16) . .
O1 C57 C58 125.7(10) . .
O1 C57 C56 115.3(9) . .
C58 C57 C56 119.0(9) . .
C59 C58 C57 122.1(10) . .
O2 C59 C58 128.1(10) . .
O2 C59 C60 112.5(10) . .
C58 C59 C60 119.4(9) . .
F5' C60 F5 134.7(15) . .
F5' C60 F6 59.4(9) . .
F5 C60 F6 109.9(10) . .
F5' C60 F4' 109.5(10) . .
F5 C60 F4' 61.1(9) . .
F6 C60 F4' 53.7(8) . .
F5' C60 F4 46.7(8) . .
F5 C60 F4 107.9(11) . .
F6 C60 F4 103.6(10) . .
F4' C60 F4 138.0(13) . .
F5' C60 F6' 109.4(11) . .
F5 C60 F6' 43.1(8) . .
F6 C60 F6' 134.2(13) . .
F4' C60 F6' 101.5(10) . .
F4 C60 F6' 67.8(9) . .
F5' C60 C59 112.5(11) . .
F5 C60 C59 111.9(12) . .
F6 C60 C59 112.1(11) . .
F4' C60 C59 110.5(10) . .
F4 C60 C59 110.9(10) . .
F6' C60 C59 112.8(11) . .
F7 C61 F9 105.1(10) . .
F7 C61 F8 104.8(11) . .
F9 C61 F8 106.8(10) . .
F7 C61 C62 112.3(9) . .
F9 C61 C62 114.5(10) . .
F8 C61 C62 112.6(10) . .
O3 C62 C63 130.2(9) . .
O3 C62 C61 112.8(9) . .
C63 C62 C61 116.9(8) . .
C62 C63 C64 122.6(8) . .
O4 C64 C63 126.8(10) . .
O4 C64 C65 114.8(10) . .
C63 C64 C65 118.3(10) . .
F10 C65 F11 110.4(13) . .
F10 C65 F12 97.0(15) . .
F11 C65 F12 103.4(13) . .
F10 C65 C64 117.6(11) . .
F11 C65 C64 115.8(13) . .
F12 C65 C64 110.1(12) . .
F15 C66 F14 108.1(14) . .
F15 C66 F13 107.3(14) . .
F14 C66 F13 101.0(14) . .
F15 C66 C67 113.3(14) . .
F14 C66 C67 116.4(13) . .
F13 C66 C67 109.7(12) . .
O5 C67 C68 130.9(11) . .
O5 C67 C66 114.7(11) . .
C68 C67 C66 114.4(11) . .
C69 C68 C67 118.7(12) . .
O6 C69 C68 126.1(13) . .
O6 C69 C70 115.8(9) . .
C68 C69 C70 118.0(11) . .
F16' C70 F16 128.7(19) . .
F16' C70 F17 35.7(13) . .
F16 C70 F17 106.4(12) . .
F16' C70 F18 72.9(13) . .
F16 C70 F18 108.9(13) . .
F17 C70 F18 106.8(12) . .
F16' C70 F18' 107.9(13) . .
F16 C70 F18' 35.2(12) . .
F17 C70 F18' 75.9(12) . .
F18 C70 F18' 135.7(18) . .
F16' C70 F17' 107.3(12) . .
F16 C70 F17' 72.5(12) . .
F17 C70 F17' 132.6(18) . .
F18 C70 F17' 39.5(11) . .
F18' C70 F17' 105.9(12) . .
F16' C70 C69 114.8(12) . .
F16 C70 C69 112.3(12) . .
F17 C70 C69 112.6(12) . .
F18 C70 C69 109.6(12) . .
F18' C70 C69 109.5(12) . .
F17' C70 C69 111.0(11) . .
O4 Eu1 O6 75.8(2) . .
O4 Eu1 O3 73.0(2) . .
O6 Eu1 O3 132.3(2) . .
O4 Eu1 O5 74.7(2) . .
O6 Eu1 O5 67.9(2) . .
O3 Eu1 O5 69.6(2) . .
O4 Eu1 O1 137.3(2) . .
O6 Eu1 O1 142.6(2) . .
O3 Eu1 O1 82.3(2) . .
O5 Eu1 O1 128.1(3) . .
O4 Eu1 O2 71.8(2) . .
O6 Eu1 O2 129.2(2) . .
O3 Eu1 O2 72.1(2) . .
O5 Eu1 O2 134.8(2) . .
O1 Eu1 O2 67.6(2) . .
O4 Eu1 N3 146.0(2) . .
O6 Eu1 N3 96.2(2) . .
O3 Eu1 N3 90.3(2) . .
O5 Eu1 N3 71.8(2) . .
O1 Eu1 N3 65.5(2) . .
O2 Eu1 N3 131.6(2) . .
O4 Eu1 N2 137.4(2) . .
O6 Eu1 N2 69.3(2) . .
O3 Eu1 N2 149.6(2) . .
O5 Eu1 N2 112.2(2) . .
O1 Eu1 N2 73.3(2) . .
O2 Eu1 N2 113.1(2) . .
N3 Eu1 N2 63.5(2) . .
O4 Eu1 N1 80.3(2) . .
O6 Eu1 N1 65.9(2) . .
O3 Eu1 N1 139.4(2) . .
O5 Eu1 N1 131.4(2) . .
O1 Eu1 N1 98.3(2) . .
O2 Eu1 N1 70.8(2) . .
N3 Eu1 N1 127.13(19) . .
N2 Eu1 N1 63.7(2) . .
C9 P1 C3 105.6(4) . .
C9 P1 C1 108.5(4) . .
C3 P1 C1 102.9(4) . .
C9 P1 Ag1 117.5(3) . .
C3 P1 Ag1 113.0(3) . .
C1 P1 Ag1 108.3(2) . .
C15 P2 C1 101.5(3) . .
C15 P2 C2 107.9(4) . .
C1 P2 C2 101.4(3) . .
C15 P2 Pt1 120.5(3) . .
C1 P2 Pt1 113.9(2) . .
C2 P2 Pt1 109.8(3) . .
C21 P3 C27 105.3(4) . .
C21 P3 C2 103.4(4) . 2_566
C27 P3 C2 106.7(4) . 2_566
C21 P3 Ag1 118.0(3) . .
C27 P3 Ag1 110.6(3) . .
C2 P3 Ag1 111.9(3) 2_566 .
O9 Cl1 O7 117.1(7) . .
O9 Cl1 O8 115.9(7) . .
O7 Cl1 O8 110.7(7) . .
O9 Cl1 O10 105.8(6) . .
O7 Cl1 O10 102.3(7) . .
O8 Cl1 O10 102.8(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C33 2.005(6) 2_566
Pt1 C33 2.005(6) .
Pt1 P2 2.3260(19) .
Pt1 P2 2.3260(19) 2_566
Pt1 Ag1 2.9291(7) 2_566
Pt1 Ag1 2.9291(8) .
Ag1 P3 2.402(2) .
Ag1 P1 2.409(2) .
O1 C57 1.234(10) .
O1 Eu1 2.452(6) .
O2 C59 1.264(11) .
O2 Eu1 2.489(6) .
O3 C62 1.267(10) .
O3 Eu1 2.396(6) .
O4 C64 1.244(11) .
O4 Eu1 2.381(6) .
O6 C69 1.227(12) .
O6 Eu1 2.390(7) .
O5 C67 1.241(12) .
O5 Eu1 2.449(6) .
N1 C45 1.340(9) .
N1 C41 1.368(11) .
N1 Eu1 2.574(7) .
N2 C46 1.340(10) .
N2 C50 1.363(10) .
N2 Eu1 2.564(5) .
N3 C51 1.340(9) .
N3 C55 1.361(11) .
N3 Eu1 2.540(8) .
C1 P2 1.827(7) .
C1 P1 1.837(7) .
C2 P2 1.831(7) .
C2 P3 1.842(7) 2_566
C3 C8 1.386(13) .
C3 C4 1.411(12) .
C3 P1 1.804(7) .
C4 C5 1.358(14) .
C5 C6 1.311(17) .
C6 C7 1.363(17) .
C7 C8 1.391(13) .
C9 C14 1.326(13) .
C9 C10 1.381(13) .
C9 P1 1.801(8) .
C10 C11 1.398(14) .
C11 C12 1.277(18) .
C12 C13 1.314(19) .
C13 C14 1.395(17) .
C15 C16 1.341(12) .
C15 C20 1.412(13) .
C15 P2 1.821(8) .
C16 C17 1.409(13) .
C17 C18 1.32(2) .
C18 C19 1.36(2) .
C19 C20 1.363(14) .
C21 C22 1.381(12) .
C21 C26 1.409(12) .
C21 P3 1.801(8) .
C22 C23 1.401(14) .
C23 C24 1.406(18) .
C24 C25 1.308(17) .
C25 C26 1.375(14) .
C27 C32 1.380(12) .
C27 C28 1.383(12) .
C27 P3 1.824(9) .
C28 C29 1.354(14) .
C29 C30 1.399(16) .
C30 C31 1.346(16) .
C31 C32 1.397(14) .
C33 C34 1.191(9) .
C34 C35 1.456(9) .
C35 C40 1.396(11) .
C35 C36 1.399(11) .
C36 C37 1.368(10) .
C37 C38 1.367(10) .
C38 C39 1.384(10) .
C38 C48 1.475(9) .
C39 C40 1.363(10) .
C41 C42 1.354(14) .
C42 C43 1.345(13) .
C43 C44 1.357(12) .
C44 C45 1.390(12) .
C45 C46 1.497(11) .
C46 C47 1.397(9) .
C47 C48 1.374(11) .
C48 C49 1.406(10) .
C49 C50 1.380(9) .
C50 C51 1.476(11) .
C51 C52 1.380(12) .
C52 C53 1.391(13) .
C53 C54 1.394(14) .
C54 C55 1.349(15) .
C56 F2 1.301(10) .
C56 F1' 1.304(10) .
C56 F3 1.307(10) .
C56 F2' 1.309(10) .
C56 F1 1.311(10) .
C56 F3' 1.312(10) .
C56 C57 1.493(15) .
C57 C58 1.392(13) .
C58 C59 1.358(14) .
C59 C60 1.535(14) .
C60 F5' 1.286(9) .
C60 F5 1.288(9) .
C60 F6 1.324(9) .
C60 F4' 1.329(9) .
C60 F4 1.330(9) .
C60 F6' 1.339(9) .
C61 F7 1.295(9) .
C61 F9 1.295(8) .
C61 F8 1.299(9) .
C61 C62 1.515(14) .
C62 C63 1.364(14) .
C63 C64 1.381(14) .
C64 C65 1.525(16) .
C65 F10 1.264(15) .
C65 F11 1.271(14) .
C65 F12 1.304(17) .
C66 F15 1.249(17) .
C66 F14 1.294(15) .
C66 F13 1.348(16) .
C66 C67 1.549(16) .
C67 C68 1.391(16) .
C68 C69 1.355(15) .
C69 C70 1.518(18) .
C70 F16' 1.286(9) .
C70 F16 1.300(10) .
C70 F17 1.308(9) .
C70 F18 1.313(10) .
C70 F18' 1.322(10) .
C70 F17' 1.328(9) .
P3 C2 1.842(7) 2_566
Cl1 O9 1.376(9) .
Cl1 O7 1.452(10) .
Cl1 O8 1.488(9) .
Cl1 O10 1.642(9) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
C33 Pt1 Ag1 P3 -79.3(2) 2_566 . . .
C33 Pt1 Ag1 P3 100.7(2) . . . .
P2 Pt1 Ag1 P3 -172.88(7) . . . .
P2 Pt1 Ag1 P3 7.12(7) 2_566 . . .
Ag1 Pt1 Ag1 P3 -56(100) 2_566 . . .
C33 Pt1 Ag1 P1 105.7(2) 2_566 . . .
C33 Pt1 Ag1 P1 -74.3(2) . . . .
P2 Pt1 Ag1 P1 12.11(6) . . . .
P2 Pt1 Ag1 P1 -167.89(6) 2_566 . . .
Ag1 Pt1 Ag1 P1 129(100) 2_566 . . .
C8 C3 C4 C5 -2.5(14) . . . .
P1 C3 C4 C5 -179.4(8) . . . .
C3 C4 C5 C6 1.6(19) . . . .
C4 C5 C6 C7 -1(2) . . . .
C5 C6 C7 C8 1(2) . . . .
C4 C3 C8 C7 2.6(14) . . . .
P1 C3 C8 C7 179.4(8) . . . .
C6 C7 C8 C3 -1.6(18) . . . .
C14 C9 C10 C11 0.0(16) . . . .
P1 C9 C10 C11 179.3(9) . . . .
C9 C10 C11 C12 -2(2) . . . .
C10 C11 C12 C13 6(3) . . . .
C11 C12 C13 C14 -8(3) . . . .
C10 C9 C14 C13 -2.4(19) . . . .
P1 C9 C14 C13 178.3(12) . . . .
C12 C13 C14 C9 7(3) . . . .
C20 C15 C16 C17 2.5(13) . . . .
P2 C15 C16 C17 -171.9(7) . . . .
C15 C16 C17 C18 -2.9(16) . . . .
C16 C17 C18 C19 -1(2) . . . .
C17 C18 C19 C20 5(2) . . . .
C18 C19 C20 C15 -5.0(18) . . . .
C16 C15 C20 C19 1.4(14) . . . .
P2 C15 C20 C19 175.8(8) . . . .
C26 C21 C22 C23 1.2(16) . . . .
P3 C21 C22 C23 -178.0(9) . . . .
C21 C22 C23 C24 -1.4(18) . . . .
C22 C23 C24 C25 2.7(19) . . . .
C23 C24 C25 C26 -4.0(19) . . . .
C24 C25 C26 C21 3.8(17) . . . .
C22 C21 C26 C25 -2.2(14) . . . .
P3 C21 C26 C25 177.0(7) . . . .
C32 C27 C28 C29 2.4(16) . . . .
P3 C27 C28 C29 -179.5(9) . . . .
C27 C28 C29 C30 -3.6(18) . . . .
C28 C29 C30 C31 4(2) . . . .
C29 C30 C31 C32 -3(2) . . . .
C28 C27 C32 C31 -1.4(16) . . . .
P3 C27 C32 C31 -179.6(9) . . . .
C30 C31 C32 C27 1.5(19) . . . .
C33 Pt1 C33 C34 -132(100) 2_566 . . .
P2 Pt1 C33 C34 -34(20) . . . .
P2 Pt1 C33 C34 146(20) 2_566 . . .
Ag1 Pt1 C33 C34 -126(20) 2_566 . . .
Ag1 Pt1 C33 C34 54(20) . . . .
Pt1 C33 C34 C35 -166(13) . . . .
C33 C34 C35 C40 165(12) . . . .
C33 C34 C35 C36 -17(13) . . . .
C40 C35 C36 C37 -0.4(13) . . . .
C34 C35 C36 C37 -178.5(8) . . . .
C35 C36 C37 C38 -1.4(14) . . . .
C36 C37 C38 C39 1.3(13) . . . .
C36 C37 C38 C48 -178.0(8) . . . .
C37 C38 C39 C40 0.4(14) . . . .
C48 C38 C39 C40 179.7(9) . . . .
C38 C39 C40 C35 -2.1(16) . . . .
C36 C35 C40 C39 2.0(14) . . . .
C34 C35 C40 C39 -179.8(9) . . . .
C45 N1 C41 C42 -0.4(13) . . . .
Eu1 N1 C41 C42 -159.6(7) . . . .
N1 C41 C42 C43 0.9(15) . . . .
C41 C42 C43 C44 0.1(15) . . . .
C42 C43 C44 C45 -1.5(15) . . . .
C41 N1 C45 C44 -1.1(12) . . . .
Eu1 N1 C45 C44 158.3(6) . . . .
C41 N1 C45 C46 -179.2(7) . . . .
Eu1 N1 C45 C46 -19.9(9) . . . .
C43 C44 C45 N1 2.0(13) . . . .
C43 C44 C45 C46 -180.0(8) . . . .
C50 N2 C46 C47 -0.9(11) . . . .
Eu1 N2 C46 C47 -178.3(5) . . . .
C50 N2 C46 C45 179.9(6) . . . .
Eu1 N2 C46 C45 2.5(9) . . . .
N1 C45 C46 N2 11.4(10) . . . .
C44 C45 C46 N2 -166.7(7) . . . .
N1 C45 C46 C47 -167.8(7) . . . .
C44 C45 C46 C47 14.1(12) . . . .
N2 C46 C47 C48 1.8(12) . . . .
C45 C46 C47 C48 -179.1(7) . . . .
C46 C47 C48 C49 -2.6(11) . . . .
C46 C47 C48 C38 -179.6(7) . . . .
C37 C38 C48 C47 27.1(12) . . . .
C39 C38 C48 C47 -152.1(8) . . . .
C37 C38 C48 C49 -149.6(8) . . . .
C39 C38 C48 C49 31.1(12) . . . .
C47 C48 C49 C50 2.9(11) . . . .
C38 C48 C49 C50 179.8(7) . . . .
C46 N2 C50 C49 1.2(11) . . . .
Eu1 N2 C50 C49 178.5(5) . . . .
C46 N2 C50 C51 -178.0(7) . . . .
Eu1 N2 C50 C51 -0.6(9) . . . .
C48 C49 C50 N2 -2.2(11) . . . .
C48 C49 C50 C51 176.9(7) . . . .
C55 N3 C51 C52 1.4(14) . . . .
Eu1 N3 C51 C52 163.0(7) . . . .
C55 N3 C51 C50 -177.4(8) . . . .
Eu1 N3 C51 C50 -15.8(10) . . . .
N2 C50 C51 N3 10.4(11) . . . .
C49 C50 C51 N3 -168.7(8) . . . .
N2 C50 C51 C52 -168.3(8) . . . .
C49 C50 C51 C52 12.6(13) . . . .
N3 C51 C52 C53 -0.6(16) . . . .
C50 C51 C52 C53 178.1(9) . . . .
C51 C52 C53 C54 -0.2(18) . . . .
C52 C53 C54 C55 0.0(19) . . . .
C53 C54 C55 N3 0.9(19) . . . .
C51 N3 C55 C54 -1.6(16) . . . .
Eu1 N3 C55 C54 -163.8(10) . . . .
Eu1 O1 C57 C58 -20.6(16) . . . .
Eu1 O1 C57 C56 160.3(7) . . . .
F2 C56 C57 O1 -26.4(19) . . . .
F1' C56 C57 O1 -65.6(16) . . . .
F3 C56 C57 O1 92.1(16) . . . .
F2' C56 C57 O1 171.1(16) . . . .
F1 C56 C57 O1 -149.0(15) . . . .
F3' C56 C57 O1 51.6(17) . . . .
F2 C56 C57 C58 154.4(17) . . . .
F1' C56 C57 C58 115.2(16) . . . .
F3 C56 C57 C58 -87.1(17) . . . .
F2' C56 C57 C58 -8.1(19) . . . .
F1 C56 C57 C58 31.8(17) . . . .
F3' C56 C57 C58 -127.6(16) . . . .
O1 C57 C58 C59 -3.1(17) . . . .
C56 C57 C58 C59 176.0(10) . . . .
Eu1 O2 C59 C58 18.9(15) . . . .
Eu1 O2 C59 C60 -163.5(6) . . . .
C57 C58 C59 O2 3.1(18) . . . .
C57 C58 C59 C60 -174.3(9) . . . .
O2 C59 C60 F5' -112.9(12) . . . .
C58 C59 C60 F5' 64.9(14) . . . .
O2 C59 C60 F5 58.1(13) . . . .
C58 C59 C60 F5 -124.0(13) . . . .
O2 C59 C60 F6 -177.8(11) . . . .
C58 C59 C60 F6 0.1(15) . . . .
O2 C59 C60 F4' 124.3(11) . . . .
C58 C59 C60 F4' -57.9(14) . . . .
O2 C59 C60 F4 -62.5(13) . . . .
C58 C59 C60 F4 115.4(12) . . . .
O2 C59 C60 F6' 11.4(13) . . . .
C58 C59 C60 F6' -170.8(11) . . . .
Eu1 O3 C62 C63 -8.6(17) . . . .
Eu1 O3 C62 C61 175.0(6) . . . .
F7 C61 C62 O3 60.5(13) . . . .
F9 C61 C62 O3 -179.8(10) . . . .
F8 C61 C62 O3 -57.4(13) . . . .
F7 C61 C62 C63 -116.4(12) . . . .
F9 C61 C62 C63 3.3(15) . . . .
F8 C61 C62 C63 125.6(12) . . . .
O3 C62 C63 C64 -1(2) . . . .
C61 C62 C63 C64 175.6(10) . . . .
Eu1 O4 C64 C63 -0.6(18) . . . .
Eu1 O4 C64 C65 177.9(9) . . . .
C62 C63 C64 O4 5.6(19) . . . .
C62 C63 C64 C65 -172.8(12) . . . .
O4 C64 C65 F10 36(2) . . . .
C63 C64 C65 F10 -145.7(16) . . . .
O4 C64 C65 F11 169.2(14) . . . .
C63 C64 C65 F11 -12(2) . . . .
O4 C64 C65 F12 -74.0(15) . . . .
C63 C64 C65 F12 104.6(14) . . . .
Eu1 O5 C67 C68 11(2) . . . .
Eu1 O5 C67 C66 -171.2(9) . . . .
F15 C66 C67 O5 -82.6(18) . . . .
F14 C66 C67 O5 151.1(15) . . . .
F13 C66 C67 O5 37.2(19) . . . .
F15 C66 C67 C68 95.7(18) . . . .
F14 C66 C67 C68 -31(2) . . . .
F13 C66 C67 C68 -144.5(15) . . . .
O5 C67 C68 C69 4(3) . . . .
C66 C67 C68 C69 -173.9(14) . . . .
Eu1 O6 C69 C68 -28(2) . . . .
Eu1 O6 C69 C70 156.8(7) . . . .
C67 C68 C69 O6 3(2) . . . .
C67 C68 C69 C70 178.3(12) . . . .
O6 C69 C70 F16' 155.9(15) . . . .
C68 C69 C70 F16' -20.1(18) . . . .
O6 C69 C70 F16 -45.0(16) . . . .
C68 C69 C70 F16 139.0(16) . . . .
O6 C69 C70 F17 -165.1(14) . . . .
C68 C69 C70 F17 18.9(17) . . . .
O6 C69 C70 F18 76.2(16) . . . .
C68 C69 C70 F18 -99.8(17) . . . .
O6 C69 C70 F18' -82.6(15) . . . .
C68 C69 C70 F18' 101.3(16) . . . .
O6 C69 C70 F17' 34.0(15) . . . .
C68 C69 C70 F17' -142.1(15) . . . .
C64 O4 Eu1 O6 138.7(10) . . . .
C64 O4 Eu1 O3 -4.7(10) . . . .
C64 O4 Eu1 O5 68.2(10) . . . .
C64 O4 Eu1 O1 -62.1(11) . . . .
C64 O4 Eu1 O2 -81.0(10) . . . .
C64 O4 Eu1 N3 58.9(11) . . . .
C64 O4 Eu1 N2 174.4(9) . . . .
C64 O4 Eu1 N1 -153.8(10) . . . .
C69 O6 Eu1 O4 -50.6(12) . . . .
C69 O6 Eu1 O3 -0.2(13) . . . .
C69 O6 Eu1 O5 28.4(12) . . . .
C69 O6 Eu1 O1 152.8(11) . . . .
C69 O6 Eu1 O2 -102.1(12) . . . .
C69 O6 Eu1 N3 95.9(12) . . . .
C69 O6 Eu1 N2 154.4(13) . . . .
C69 O6 Eu1 N1 -136.1(13) . . . .
C62 O3 Eu1 O4 8.8(8) . . . .
C62 O3 Eu1 O6 -42.6(10) . . . .
C62 O3 Eu1 O5 -70.8(9) . . . .
C62 O3 Eu1 O1 153.6(9) . . . .
C62 O3 Eu1 O2 84.6(9) . . . .
C62 O3 Eu1 N3 -141.2(9) . . . .
C62 O3 Eu1 N2 -170.1(8) . . . .
C62 O3 Eu1 N1 59.8(10) . . . .
C67 O5 Eu1 O4 62.1(10) . . . .
C67 O5 Eu1 O6 -18.6(10) . . . .
C67 O5 Eu1 O3 139.2(11) . . . .
C67 O5 Eu1 O1 -159.1(10) . . . .
C67 O5 Eu1 O2 105.4(10) . . . .
C67 O5 Eu1 N3 -123.4(11) . . . .
C67 O5 Eu1 N2 -73.4(11) . . . .
C67 O5 Eu1 N1 0.4(11) . . . .
C57 O1 Eu1 O4 7.1(11) . . . .
C57 O1 Eu1 O6 152.6(8) . . . .
C57 O1 Eu1 O3 -47.2(9) . . . .
C57 O1 Eu1 O5 -103.6(9) . . . .
C57 O1 Eu1 O2 26.5(9) . . . .
C57 O1 Eu1 N3 -141.1(10) . . . .
C57 O1 Eu1 N2 151.0(10) . . . .
C57 O1 Eu1 N1 91.8(9) . . . .
C59 O2 Eu1 O4 141.6(8) . . . .
C59 O2 Eu1 O6 -165.3(7) . . . .
C59 O2 Eu1 O3 64.2(8) . . . .
C59 O2 Eu1 O5 97.4(8) . . . .
C59 O2 Eu1 O1 -24.7(8) . . . .
C59 O2 Eu1 N3 -9.6(9) . . . .
C59 O2 Eu1 N2 -83.8(8) . . . .
C59 O2 Eu1 N1 -132.6(8) . . . .
C51 N3 Eu1 O4 148.1(6) . . . .
C55 N3 Eu1 O4 -50.6(9) . . . .
C51 N3 Eu1 O6 74.3(7) . . . .
C55 N3 Eu1 O6 -124.4(7) . . . .
C51 N3 Eu1 O3 -153.0(7) . . . .
C55 N3 Eu1 O3 8.3(7) . . . .
C51 N3 Eu1 O5 138.6(7) . . . .
C55 N3 Eu1 O5 -60.1(7) . . . .
C51 N3 Eu1 O1 -71.7(7) . . . .
C55 N3 Eu1 O1 89.6(8) . . . .
C51 N3 Eu1 O2 -87.0(7) . . . .
C55 N3 Eu1 O2 74.2(8) . . . .
C51 N3 Eu1 N2 11.1(6) . . . .
C55 N3 Eu1 N2 172.4(8) . . . .
C51 N3 Eu1 N1 10.0(8) . . . .
C55 N3 Eu1 N1 171.3(7) . . . .
C46 N2 Eu1 O4 26.8(7) . . . .
C50 N2 Eu1 O4 -150.6(5) . . . .
C46 N2 Eu1 O6 64.0(6) . . . .
C50 N2 Eu1 O6 -113.4(6) . . . .
C46 N2 Eu1 O3 -154.8(5) . . . .
C50 N2 Eu1 O3 27.8(8) . . . .
C46 N2 Eu1 O5 118.0(6) . . . .
C50 N2 Eu1 O5 -59.4(6) . . . .
C46 N2 Eu1 O1 -117.0(6) . . . .
C50 N2 Eu1 O1 65.6(5) . . . .
C46 N2 Eu1 O2 -61.1(6) . . . .
C50 N2 Eu1 O2 121.6(5) . . . .
C46 N2 Eu1 N3 172.5(6) . . . .
C50 N2 Eu1 N3 -4.9(5) . . . .
C46 N2 Eu1 N1 -8.6(5) . . . .
C50 N2 Eu1 N1 174.1(6) . . . .
C45 N1 Eu1 O4 -141.5(6) . . . .
C41 N1 Eu1 O4 17.0(7) . . . .
C45 N1 Eu1 O6 -62.8(6) . . . .
C41 N1 Eu1 O6 95.8(7) . . . .
C45 N1 Eu1 O3 169.5(5) . . . .
C41 N1 Eu1 O3 -32.0(8) . . . .
C45 N1 Eu1 O5 -82.1(6) . . . .
C41 N1 Eu1 O5 76.4(7) . . . .
C45 N1 Eu1 O1 81.7(6) . . . .
C41 N1 Eu1 O1 -119.8(7) . . . .
C45 N1 Eu1 O2 144.5(6) . . . .
C41 N1 Eu1 O2 -57.0(7) . . . .
C45 N1 Eu1 N3 16.3(7) . . . .
C41 N1 Eu1 N3 174.8(6) . . . .
C45 N1 Eu1 N2 15.1(5) . . . .
C41 N1 Eu1 N2 173.6(7) . . . .
C14 C9 P1 C3 95.7(9) . . . .
C10 C9 P1 C3 -83.6(8) . . . .
C14 C9 P1 C1 -154.5(9) . . . .
C10 C9 P1 C1 26.2(9) . . . .
C14 C9 P1 Ag1 -31.4(10) . . . .
C10 C9 P1 Ag1 149.4(7) . . . .
C8 C3 P1 C9 68.7(8) . . . .
C4 C3 P1 C9 -114.5(7) . . . .
C8 C3 P1 C1 -45.0(8) . . . .
C4 C3 P1 C1 131.8(7) . . . .
C8 C3 P1 Ag1 -161.6(6) . . . .
C4 C3 P1 Ag1 15.2(8) . . . .
P2 C1 P1 C9 89.2(5) . . . .
P2 C1 P1 C3 -159.2(4) . . . .
P2 C1 P1 Ag1 -39.3(4) . . . .
P3 Ag1 P1 C9 108.1(6) . . . .
Pt1 Ag1 P1 C9 -112.2(3) . . . .
P3 Ag1 P1 C3 -15.3(7) . . . .
Pt1 Ag1 P1 C3 124.4(3) . . . .
P3 Ag1 P1 C1 -128.7(6) . . . .
Pt1 Ag1 P1 C1 11.0(2) . . . .
C16 C15 P2 C1 95.0(7) . . . .
C20 C15 P2 C1 -79.4(7) . . . .
C16 C15 P2 C2 -158.8(7) . . . .
C20 C15 P2 C2 26.8(8) . . . .
C16 C15 P2 Pt1 -31.7(8) . . . .
C20 C15 P2 Pt1 153.8(6) . . . .
P1 C1 P2 C15 -75.6(5) . . . .
P1 C1 P2 C2 173.3(4) . . . .
P1 C1 P2 Pt1 55.4(4) . . . .
P3 C2 P2 C15 81.0(5) 2_566 . . .
P3 C2 P2 C1 -172.8(4) 2_566 . . .
P3 C2 P2 Pt1 -52.0(5) 2_566 . . .
C33 Pt1 P2 C15 -20.8(4) 2_566 . . .
C33 Pt1 P2 C15 159.2(4) . . . .
P2 Pt1 P2 C15 -125(100) 2_566 . . .
Ag1 Pt1 P2 C15 -95.2(3) 2_566 . . .
Ag1 Pt1 P2 C15 84.8(3) . . . .
C33 Pt1 P2 C1 -141.7(3) 2_566 . . .
C33 Pt1 P2 C1 38.3(3) . . . .
P2 Pt1 P2 C1 114(100) 2_566 . . .
Ag1 Pt1 P2 C1 143.9(3) 2_566 . . .
Ag1 Pt1 P2 C1 -36.1(3) . . . .
C33 Pt1 P2 C2 105.4(3) 2_566 . . .
C33 Pt1 P2 C2 -74.6(3) . . . .
P2 Pt1 P2 C2 2(100) 2_566 . . .
Ag1 Pt1 P2 C2 31.0(2) 2_566 . . .
Ag1 Pt1 P2 C2 -149.0(2) . . . .
C22 C21 P3 C27 -89.6(8) . . . .
C26 C21 P3 C27 91.2(8) . . . .
C22 C21 P3 C2 158.5(7) . . . 2_566
C26 C21 P3 C2 -20.7(9) . . . 2_566
C22 C21 P3 Ag1 34.4(8) . . . .
C26 C21 P3 Ag1 -144.8(7) . . . .
C32 C27 P3 C21 146.9(7) . . . .
C28 C27 P3 C21 -31.2(9) . . . .
C32 C27 P3 C2 -103.6(8) . . . 2_566
C28 C27 P3 C2 78.3(8) . . . 2_566
C32 C27 P3 Ag1 18.3(8) . . . .
C28 C27 P3 Ag1 -159.8(7) . . . .
P1 Ag1 P3 C21 -83.0(6) . . . .
Pt1 Ag1 P3 C21 137.1(3) . . . .
P1 Ag1 P3 C27 38.3(7) . . . .
Pt1 Ag1 P3 C27 -101.6(3) . . . .
P1 Ag1 P3 C2 157.1(6) . . . 2_566
Pt1 Ag1 P3 C2 17.2(3) . . . 2_566
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.144 0.733 0.055 115 18 ' '
2 0.500 0.500 0.500 549 90 ' '
3 0.855 0.267 0.945 115 18 ' '
