#------------------------------------------------------------------------------
#$Date: 2019-08-27 09:54:43 +0300 (Tue, 27 Aug 2019) $
#$Revision: 217738 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/34/7233478.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7233478
loop_
_publ_author_name
'Zhi-Fa Liu'
'Mei-Feng Wu'
'Shuai-Hua Wang'
'Fa-Kun Zheng'
'Guan-E. Wang'
'Jun Chen'
'Yu Xiao'
'A-Qing Wu'
'Guo-Cong Guo'
'Jin-Shun Huang'
_publ_section_title
;
 Eu3+-doped Tb3+ metal-organic frameworks emitting tunable three primary
 colors towards white light
;
_journal_name_full               'Journal of Materials Chemistry C'
_journal_page_first              4634
_journal_page_last               4639
_journal_paper_doi               10.1039/C3TC30733F
_journal_volume                  1
_journal_year                    2013
_chemical_formula_moiety         Eu5Zn2C140H135O47N40
_chemical_formula_sum            'C140 H135 Eu5 N40 O47 Zn2'
_chemical_formula_weight         4020.46
_chemical_melting_point          ?
_chemical_name_common            Eu5Zn2C140H135O47N40
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                94.2350(10)
_cell_angle_beta                 97.134(3)
_cell_angle_gamma                113.480(3)
_cell_formula_units_Z            1
_cell_length_a                   13.094(3)
_cell_length_b                   14.061(3)
_cell_length_c                   23.454(5)
_cell_measurement_reflns_used    9973
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.7713
_cell_measurement_theta_min      2.0371
_cell_volume                     3893.8(15)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 28.5714
_diffrn_measured_fraction_theta_full 0.965
_diffrn_measured_fraction_theta_max 0.965
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       CCD_Profile_fitting
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0303
_diffrn_reflns_av_sigmaI/netI    0.0421
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            28125
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.77
_exptl_absorpt_coefficient_mu    2.381
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.7590
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Sphere (Rigaku CrystalClear)'
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.715
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       sheet
_exptl_crystal_F_000             2006
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.784
_refine_diff_density_min         -1.107
_refine_diff_density_rms         0.118
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.038
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1193
_refine_ls_number_reflns         13255
_refine_ls_number_restraints     185
_refine_ls_restrained_S_all      1.060
_refine_ls_R_factor_all          0.0526
_refine_ls_R_factor_gt           0.0436
_refine_ls_shift/su_max          0.058
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0830P)²+1.9148P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1194
_refine_ls_wR_factor_ref         0.1283
_reflns_number_gt                11056
_reflns_number_total             13255
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            J-Mater-Chem-C-2013-1-4634-1.cif
_cod_data_source_block           a
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_chemical_melting_point' value 'not measured' was changed
to '?' -- the value is undefined or not given.

data item '_exptl_absorpt_correction_type' value 'Multi-scan' was
changed to 'multi-scan' in accordance with the built-in table derived
from the CIF Core dictionary named 'cif_core.dic' version 2.4.5 last
updated on 2014-11-21.

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

data item '_exptl_crystal_density_meas' value 'not measured' was
changed to '?' -- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7233478
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.411920(18) 0.445740(17) 0.789315(10) 0.03205(6) Uani 1 1 d U . .
Eu2 Eu 0.446255(18) 0.492787(16) 0.594593(9) 0.02897(6) Uani 1 1 d U . .
Eu3 Eu 0.01844(4) 1.02670(4) 1.04565(2) 0.03969(12) Uani 0.50 1 d PU . .
Zn1 Zn -0.29674(4) 0.30114(4) 0.01177(2) 0.03699(13) Uani 1 1 d . . .
O1W O -0.1546(4) 1.0262(4) 1.0003(2) 0.0911(10) Uani 1 1 d DU . .
H1WA H -0.176(3) 1.023(3) 1.0335(8) 0.109 Uiso 1 1 d D . .
H1WB H -0.128(6) 1.0910(11) 0.9967(19) 0.109 Uiso 1 1 d D . .
O2W O 0.1944(6) 1.1615(6) 1.0960(4) 0.1499(13) Uani 1 1 d DU . .
H2WA H 0.222(3) 1.130(2) 1.120(2) 0.180 Uiso 1 1 d D . .
H2WB H 0.253(2) 1.216(3) 1.093(3) 0.180 Uiso 1 1 d D . .
O3W O 0.0465(7) 0.9193(7) 1.1166(4) 0.0700(12) Uani 0.50 1 d PDU . .
H3WA H 0.011(3) 0.931(6) 1.086(2) 0.084 Uiso 0.50 1 d PD . .
O4W O -0.0437(5) 1.0655(5) 1.1366(3) 0.1235(12) Uani 1 1 d DU . .
H4WA H -0.1077(12) 1.065(3) 1.123(3) 0.148 Uiso 1 1 d D . .
H4WB H 0.006(2) 1.124(2) 1.130(3) 0.148 Uiso 1 1 d D . .
O5WA O 0.0981(8) 1.1486(7) 1.0008(4) 0.0825(18) Uani 0.50 1 d PDU . 1
H5WA H 0.097(9) 1.112(3) 1.0282(11) 0.099 Uiso 0.50 1 d PD A 1
H5WB H 0.084(8) 1.105(3) 0.9702(11) 0.099 Uiso 0.50 1 d PD B 1
O5WB O 0.0151(7) 1.2000(7) 1.0298(4) 0.0825(18) Uani 0.50 1 d PD . 2
H5WC H 0.035(3) 1.175(5) 1.0014(13) 0.099 Uiso 0.50 1 d PD C 2
H5WD H 0.062(3) 1.204(6) 1.0595(11) 0.099 Uiso 0.50 1 d PD D 2
O6W O 0.4968(3) 0.3520(3) 0.85449(18) 0.0581(11) Uani 1 1 d D . .
H6WA H 0.532(3) 0.359(3) 0.8887(7) 0.070 Uiso 1 1 d D . .
H6WB H 0.544(2) 0.397(3) 0.8382(13) 0.070 Uiso 1 1 d D . .
O7W O 0.2669(3) 0.3088(3) 0.82885(18) 0.0618(11) Uani 1 1 d D . .
H7WA H 0.2019(15) 0.268(2) 0.8104(16) 0.074 Uiso 1 1 d D . .
H7WB H 0.289(2) 0.270(2) 0.8487(18) 0.074 Uiso 1 1 d D . .
O8W O 0.5296(4) 0.5655(4) 0.8744(2) 0.0791(10) Uani 1 1 d DU . .
H8WA H 0.508(3) 0.5051(13) 0.8842(17) 0.095 Uiso 1 1 d D . .
H8WB H 0.5913(15) 0.583(4) 0.8619(15) 0.095 Uiso 1 1 d D . .
O9W O 0.3008(3) 0.5185(3) 0.8452(2) 0.0689(12) Uani 1 1 d D . .
H9WA H 0.2386(17) 0.4710(18) 0.849(2) 0.083 Uiso 1 1 d D . .
H9WB H 0.293(2) 0.5756(11) 0.850(3) 0.083 Uiso 1 1 d D . .
O10W O 0.2302(3) 0.4059(3) 0.71941(17) 0.0585(10) Uani 1 1 d DU . .
H10A H 0.234(5) 0.424(2) 0.6858(7) 0.070 Uiso 1 1 d D . .
H10B H 0.187(4) 0.3408(11) 0.7136(16) 0.070 Uiso 1 1 d D . .
O11 O 0.4386(3) 0.6075(3) 0.76479(16) 0.0535(9) Uani 1 1 d . . .
O11W O 0.6441(3) 0.6304(3) 0.58995(18) 0.0629(12) Uani 1 1 d D . .
H11D H 0.697(2) 0.683(2) 0.6121(13) 0.075 Uiso 1 1 d D . .
H11E H 0.676(2) 0.628(4) 0.5606(10) 0.075 Uiso 1 1 d D . .
O12 O 0.4471(4) 0.6024(3) 0.67287(17) 0.0651(11) Uani 1 1 d U . .
O12W O 0.2901(11) 0.2781(11) 0.9352(7) 0.3357(14) Uani 1 1 d DU . .
H12A H 0.228(2) 0.255(6) 0.948(2) 0.403 Uiso 1 1 d D . .
H12B H 0.330(5) 0.338(3) 0.955(3) 0.403 Uiso 1 1 d D . .
O13W O 0.2401(8) 1.2848(9) 1.1935(5) 0.2312(14) Uani 1 1 d DU . .
H13B H 0.2762(19) 1.250(3) 1.182(2) 0.277 Uiso 1 1 d D . .
H13C H 0.199(3) 1.289(5) 1.1636(16) 0.277 Uiso 1 1 d D . .
O14W O 0.2169(8) 0.2032(7) 0.2973(6) 0.2032(14) Uani 1 1 d DU . .
H14B H 0.151(2) 0.156(2) 0.296(5) 0.244 Uiso 1 1 d D . .
H14C H 0.208(3) 0.2601(14) 0.301(6) 0.244 Uiso 1 1 d D . .
O21 O 0.3783(3) 0.2983(3) 0.72492(15) 0.0422(8) Uani 1 1 d . . .
O22 O 0.3597(3) 0.3421(3) 0.63672(16) 0.0543(10) Uani 1 1 d . . .
O31 O 0.2428(3) 0.4577(3) 0.59325(15) 0.0502(9) Uani 1 1 d . . .
O32 O 0.2851(3) 0.3997(3) 0.51378(14) 0.0428(8) Uani 1 1 d . . .
O41 O 0.5181(3) 0.4020(3) 0.53723(14) 0.0427(8) Uani 1 1 d . . .
O42 O 0.5695(3) 0.3708(3) 0.45484(15) 0.0506(9) Uani 1 1 d . . .
O51 O 0.5850(3) 0.4890(4) 0.66814(19) 0.0704(12) Uani 1 1 d U . .
O52 O 0.5910(3) 0.4948(3) 0.76269(16) 0.0473(9) Uani 1 1 d . . .
N11 N 0.5377(3) 1.2313(3) 1.01360(18) 0.0409(10) Uani 1 1 d . . .
N12 N 0.4993(4) 1.2682(4) 1.0575(2) 0.0567(12) Uani 1 1 d . . .
N13 N 0.3929(4) 1.2109(4) 1.0532(2) 0.0663(15) Uani 1 1 d . . .
N14 N 0.3579(4) 1.1358(4) 1.0071(2) 0.0636(14) Uani 1 1 d . . .
N21 N -0.0612(4) -0.1706(4) 0.2918(2) 0.0590(13) Uani 1 1 d . . .
N22 N -0.0803(5) -0.1575(5) 0.2363(3) 0.0709(16) Uani 1 1 d . . .
N23 N -0.0177(5) -0.0610(6) 0.2300(3) 0.093(2) Uani 1 1 d . . .
H23B H -0.0180 -0.0345 0.1981 0.112 Uiso 1 1 calc R . .
N24 N 0.0475(5) -0.0090(5) 0.2815(3) 0.0761(17) Uani 1 1 d . . .
N31 N -0.2238(3) 0.3130(3) 0.14183(17) 0.0380(9) Uani 1 1 d . . .
N32 N -0.2281(3) 0.2758(3) 0.08673(17) 0.0397(10) Uani 1 1 d . . .
N33 N -0.1730(4) 0.2154(4) 0.08451(19) 0.0587(12) Uani 1 1 d . . .
N34 N -0.1283(4) 0.2141(4) 0.13915(19) 0.0519(11) Uani 1 1 d . . .
N41 N 0.7971(4) 0.1568(4) 0.88254(18) 0.0546(12) Uani 1 1 d . . .
N42 N 0.8036(4) 0.1856(4) 0.93908(18) 0.0507(11) Uani 1 1 d . . .
N43 N 0.7435(4) 0.2406(3) 0.94309(18) 0.0466(11) Uani 1 1 d . . .
N44 N 0.6977(3) 0.2497(3) 0.89007(17) 0.0433(10) Uani 1 1 d . . .
N51 N 1.1841(4) 0.3869(4) 1.0152(2) 0.0629(14) Uani 1 1 d . . .
N52 N 1.2779(4) 0.4371(4) 1.0562(3) 0.0701(16) Uani 1 1 d . . .
N53 N 1.3214(4) 0.5351(4) 1.0510(2) 0.0585(13) Uani 1 1 d . . .
N54 N 1.2570(3) 0.5526(3) 1.00686(19) 0.0446(10) Uani 1 1 d . . .
C11 C 0.4494(4) 1.1508(4) 0.9836(2) 0.0408(12) Uani 1 1 d . . .
C12 C 0.4480(4) 1.0855(4) 0.9315(2) 0.0400(12) Uani 1 1 d . . .
C13 C 0.5242(4) 1.0384(4) 0.9315(2) 0.0388(11) Uani 1 1 d . . .
H13A H 0.5750 1.0469 0.9650 0.063(18) Uiso 1 1 d R . .
C14 C 0.5234(4) 0.9784(4) 0.8811(2) 0.0401(11) Uani 1 1 d . . .
H14A H 0.5731 0.9461 0.8815 0.061(17) Uiso 1 1 d R . .
C15 C 0.4509(4) 0.9672(4) 0.8309(2) 0.0411(12) Uani 1 1 d . . .
C16 C 0.3735(5) 1.0127(4) 0.8323(2) 0.0532(14) Uani 1 1 d . . .
H16A H 0.3213 1.0032 0.7993 0.067(19) Uiso 1 1 d R . .
C17 C 0.3726(5) 1.0702(4) 0.8814(2) 0.0492(14) Uani 1 1 d . . .
H17A H 0.3205 1.0999 0.8813 0.048(15) Uiso 1 1 d R . .
C18 C 0.4565(5) 0.9100(4) 0.7763(2) 0.0423(12) Uani 1 1 d . . .
C19 C 0.4598(4) 0.8122(3) 0.7749(2) 0.0351(11) Uani 1 1 d . . .
H19A H 0.4603 0.7821 0.8088 0.023(11) Uiso 1 1 d R . .
C21 C 0.0171(5) -0.0789(5) 0.3178(3) 0.0561(15) Uani 1 1 d . . .
C22 C 0.0649(5) -0.0535(5) 0.3808(3) 0.0546(15) Uani 1 1 d . . .
C23 C 0.1550(8) 0.0402(6) 0.4022(3) 0.096(3) Uani 1 1 d . . .
H23A H 0.1850 0.0881 0.3769 0.07(2) Uiso 1 1 d R . .
C24 C 0.2007(7) 0.0651(6) 0.4607(3) 0.084(2) Uani 1 1 d . . .
H24A H 0.2640 0.1278 0.4737 0.07(2) Uiso 1 1 d R . .
C25 C 0.1542(5) -0.0009(4) 0.4999(2) 0.0479(13) Uani 1 1 d . . .
C26 C 0.0683(6) -0.0974(5) 0.4766(3) 0.070(2) Uani 1 1 d . . .
H26A H 0.0385 -0.1463 0.5013 0.11(3) Uiso 1 1 d R . .
C27 C 0.0260(6) -0.1246(5) 0.4190(3) 0.070(2) Uani 1 1 d . . .
H27A H -0.0292 -0.1914 0.4056 0.09(2) Uiso 1 1 d R . .
C28 C 0.1975(5) 0.0297(4) 0.5630(2) 0.0481(13) Uani 1 1 d . . .
C29 C 0.2543(4) 0.1344(4) 0.5874(2) 0.0400(11) Uani 1 1 d . . .
H29A H 0.2687 0.1862 0.5632 0.026(11) Uiso 1 1 d R . .
C31 C -0.1616(4) 0.2736(4) 0.1728(2) 0.0351(11) Uani 1 1 d . . .
C32 C -0.1304(4) 0.2923(4) 0.2367(2) 0.0367(11) Uani 1 1 d . . .
C33 C -0.0514(4) 0.2608(4) 0.2641(2) 0.0430(12) Uani 1 1 d . . .
H33A H -0.0176 0.2278 0.2421 0.040(13) Uiso 1 1 d R . .
C34 C -0.0234(4) 0.2772(4) 0.3234(2) 0.0408(12) Uani 1 1 d . . .
H34A H 0.0307 0.2563 0.3409 0.041(14) Uiso 1 1 d R . .
C35 C -0.0726(4) 0.3252(4) 0.3584(2) 0.0335(11) Uani 1 1 d . . .
C36 C -0.1522(4) 0.3576(4) 0.3307(2) 0.0396(12) Uani 1 1 d . . .
H36A H -0.1863 0.3906 0.3525 0.09(2) Uiso 1 1 d R . .
C37 C -0.1797(4) 0.3418(4) 0.2709(2) 0.0378(11) Uani 1 1 d . . .
H37A H -0.2324 0.3639 0.2532 0.030(12) Uiso 1 1 d R . .
C38 C -0.0418(4) 0.3432(3) 0.4230(2) 0.0336(10) Uani 1 1 d . . .
C39 C 0.0668(4) 0.3648(4) 0.4508(2) 0.0335(10) Uani 1 1 d . . .
H39A H 0.1214 0.3660 0.4287 0.059(17) Uiso 1 1 d R . .
C41 C 0.7319(4) 0.1964(4) 0.8536(2) 0.0408(12) Uani 1 1 d . . .
C42 C 0.7037(4) 0.1869(4) 0.7912(2) 0.0383(11) Uani 1 1 d . . .
C43 C 0.6254(4) 0.2217(4) 0.7668(2) 0.0438(12) Uani 1 1 d . . .
H43A H 0.5893 0.2485 0.7910 0.062(18) Uiso 1 1 d R . .
C44 C 0.5996(4) 0.2177(4) 0.7072(2) 0.0394(11) Uani 1 1 d . . .
H44A H 0.5460 0.2412 0.6923 0.055(16) Uiso 1 1 d R . .
C45 C 0.6522(4) 0.1799(4) 0.6696(2) 0.0347(10) Uani 1 1 d . . .
C46 C 0.7309(4) 0.1447(4) 0.6941(2) 0.0462(12) Uani 1 1 d . . .
H46A H 0.7679 0.1190 0.6699 0.10(2) Uiso 1 1 d R . .
C47 C 0.7550(4) 0.1468(4) 0.7534(2) 0.0471(12) Uani 1 1 d . . .
H47A H 0.8061 0.1204 0.7682 0.043(14) Uiso 1 1 d R . .
C48 C 0.6285(4) 0.1814(3) 0.6065(2) 0.0325(10) Uani 1 1 d . . .
C49 C 0.5929(4) 0.2569(3) 0.58520(19) 0.0316(10) Uani 1 1 d . . .
H49A H 0.5789 0.3021 0.6109 0.035(13) Uiso 1 1 d R . .
C51 C 1.1739(4) 0.4612(4) 0.9865(2) 0.0426(12) Uani 1 1 d . . .
C52 C 1.0867(4) 0.4469(4) 0.9360(2) 0.0386(12) Uani 1 1 d . . .
C53 C 1.0364(4) 0.5177(4) 0.9325(2) 0.0411(12) Uani 1 1 d . . .
H53A H 1.0483 0.5665 0.9645 0.023(11) Uiso 1 1 d R . .
C54 C 0.9686(4) 0.5143(4) 0.8816(2) 0.0393(11) Uani 1 1 d . . .
H54A H 0.9335 0.5601 0.8801 0.028(12) Uiso 1 1 d R . .
C55 C 0.9519(4) 0.4443(4) 0.8331(2) 0.0407(12) Uani 1 1 d . . .
C56 C 0.9973(4) 0.3705(4) 0.8382(3) 0.0490(14) Uani 1 1 d . . .
H56A H 0.9840 0.3202 0.8069 0.060(18) Uiso 1 1 d R . .
C57 C 1.0635(4) 0.3717(4) 0.8899(3) 0.0483(14) Uani 1 1 d . . .
H57A H 1.0916 0.3207 0.8935 0.037(13) Uiso 1 1 d R . .
C58 C 0.8906(4) 0.4503(4) 0.7769(2) 0.0396(12) Uani 1 1 d . . .
C59 C 0.7948(4) 0.4703(4) 0.7739(2) 0.0378(11) Uani 1 1 d . . .
H59A H 0.7666 0.4777 0.8077 0.027(11) Uiso 1 1 d R . .
C110 C 0.4617(4) 0.7590(3) 0.72278(19) 0.0337(10) Uani 1 1 d . . .
C111 C 0.4641(6) 0.8042(4) 0.6720(2) 0.0579(16) Uani 1 1 d . . .
H11A H 0.4669 0.7695 0.6374 0.065(18) Uiso 1 1 d R . .
C112 C 0.4620(7) 0.9013(5) 0.6734(3) 0.074(2) Uani 1 1 d . . .
H11B H 0.4658 0.9329 0.6398 0.09(2) Uiso 1 1 d R . .
C113 C 0.4547(6) 0.9526(4) 0.7247(3) 0.0683(19) Uani 1 1 d . . .
H11C H 0.4488 1.0163 0.7242 0.07(2) Uiso 1 1 d R . .
C114 C 0.4508(4) 0.6501(4) 0.7205(2) 0.0386(11) Uani 1 1 d U . .
C159 C 0.5532(4) 0.3511(3) 0.5050(2) 0.0338(11) Uani 1 1 d . . .
C210 C 0.2908(4) 0.1630(3) 0.6465(2) 0.0359(11) Uani 1 1 d . . .
C211 C 0.2713(5) 0.0874(4) 0.6824(3) 0.0537(15) Uani 1 1 d . . .
H21A H 0.2918 0.1060 0.7224 0.056(16) Uiso 1 1 d R . .
C212 C 0.2169(7) -0.0183(5) 0.6584(3) 0.082(2) Uani 1 1 d . . .
H21B H 0.2063 -0.0702 0.6823 0.10(3) Uiso 1 1 d R . .
C213 C 0.1806(6) -0.0459(5) 0.6000(3) 0.069(2) Uani 1 1 d . . .
H21C H 0.1443 -0.1164 0.5849 0.069(19) Uiso 1 1 d R . .
C214 C 0.3475(4) 0.2756(4) 0.6710(2) 0.0358(11) Uani 1 1 d . . .
C310 C 0.0950(4) 0.3854(4) 0.51095(19) 0.0337(10) Uani 1 1 d . . .
C311 C 0.0140(4) 0.3840(4) 0.5442(2) 0.0396(11) Uani 1 1 d . . .
H31A H 0.0323 0.3988 0.5844 0.036(13) Uiso 1 1 d R . .
C312 C -0.0947(4) 0.3599(4) 0.5170(2) 0.0465(13) Uani 1 1 d . . .
H31B H -0.1502 0.3566 0.5389 0.035(13) Uiso 1 1 d R . .
C313 C -0.1231(4) 0.3395(4) 0.4570(2) 0.0397(12) Uani 1 1 d . . .
H31C H -0.1965 0.3242 0.4393 0.11(3) Uiso 1 1 d R . .
C314 C 0.2144(4) 0.4157(4) 0.54036(19) 0.0367(11) Uani 1 1 d . . .
C410 C 0.5797(3) 0.2647(3) 0.52621(18) 0.0287(9) Uani 1 1 d . . .
C411 C 0.5947(4) 0.1941(4) 0.4875(2) 0.0385(11) Uani 1 1 d . . .
H41A H 0.5854 0.1990 0.4480 0.035(13) Uiso 1 1 d R . .
C412 C 0.6248(4) 0.1160(4) 0.5074(2) 0.0445(12) Uani 1 1 d . . .
H41B H 0.6321 0.0669 0.4813 0.050(15) Uiso 1 1 d R . .
C413 C 0.6430(4) 0.1118(4) 0.5662(2) 0.0409(11) Uani 1 1 d . . .
H41C H 0.6658 0.0613 0.5792 0.053(16) Uiso 1 1 d R . .
C510 C 0.7398(4) 0.4786(4) 0.7214(2) 0.0352(11) Uani 1 1 d . . .
C511 C 0.7843(4) 0.4712(4) 0.6715(2) 0.0469(14) Uani 1 1 d . . .
H51A H 0.7499 0.4795 0.6363 0.059(17) Uiso 1 1 d R . .
C512 C 0.8797(4) 0.4505(5) 0.6740(2) 0.0524(14) Uani 1 1 d . . .
H51B H 0.9085 0.4442 0.6403 0.09(2) Uiso 1 1 d R . .
C513 C 0.9321(4) 0.4398(4) 0.7264(3) 0.0515(14) Uani 1 1 d . . .
H51C H 0.9960 0.4259 0.7278 0.09(2) Uiso 1 1 d R . .
C514 C 0.6304(4) 0.4887(4) 0.7171(2) 0.0399(12) Uani 1 1 d U . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O11 Eu1 O21 125.77(13) . .
O11 Eu1 O52 80.84(13) . .
O21 Eu1 O52 80.24(13) . .
O11 Eu1 O8W 75.93(15) . .
O21 Eu1 O8W 146.91(14) . .
O52 Eu1 O8W 79.39(15) . .
O11 Eu1 O7W 135.75(15) . .
O21 Eu1 O7W 78.39(13) . .
O52 Eu1 O7W 143.30(14) . .
O8W Eu1 O7W 103.68(16) . .
O11 Eu1 O6W 143.10(13) . .
O21 Eu1 O6W 80.18(13) . .
O52 Eu1 O6W 78.57(13) . .
O8W Eu1 O6W 70.41(15) . .
O7W Eu1 O6W 68.65(14) . .
O11 Eu1 O9W 70.71(14) . .
O21 Eu1 O9W 138.16(13) . .
O52 Eu1 O9W 141.06(13) . .
O8W Eu1 O9W 68.48(16) . .
O7W Eu1 O9W 68.45(14) . .
O6W Eu1 O9W 109.07(15) . .
O11 Eu1 O10W 77.90(14) . .
O21 Eu1 O10W 72.61(13) . .
O52 Eu1 O10W 124.83(13) . .
O8W Eu1 O10W 140.36(15) . .
O7W Eu1 O10W 75.85(14) . .
O6W Eu1 O10W 138.77(13) . .
O9W Eu1 O10W 75.05(14) . .
O11 Eu1 H6WB 127.5(6) . .
O21 Eu1 H6WB 82.4(11) . .
O52 Eu1 H6WB 59.5(4) . .
O8W Eu1 H6WB 64.8(11) . .
O7W Eu1 H6WB 88.2(3) . .
O6W Eu1 H6WB 19.6(3) . .
O9W Eu1 H6WB 120.1(10) . .
O10W Eu1 H6WB 152.5(9) . .
O11 Eu1 H8WA 95.9(4) . .
O21 Eu1 H8WA 132.5(7) . .
O52 Eu1 H8WA 85.9(11) . .
O8W Eu1 H8WA 20.2(2) . .
O7W Eu1 H8WA 87.0(7) . .
O6W Eu1 H8WA 52.5(6) . .
O9W Eu1 H8WA 71.6(11) . .
O10W Eu1 H8WA 146.3(11) . .
H6WB Eu1 H8WA 52.0(14) . .
O11 Eu1 H8WB 73.4(10) . .
O21 Eu1 H8WB 134.4(8) . .
O52 Eu1 H8WB 61.1(5) . .
O8W Eu1 H8WB 18.3(5) . .
O7W Eu1 H8WB 118.6(7) . .
O6W Eu1 H8WB 69.9(10) . .
O9W Eu1 H8WB 85.1(7) . .
O10W Eu1 H8WB 149.2(10) . .
H6WB Eu1 H8WB 58.3(14) . .
H8WA Eu1 H8WB 31.6(6) . .
O12 Eu2 O41 156.52(14) . .
O12 Eu2 O22 93.48(15) . .
O41 Eu2 O22 88.90(13) . .
O12 Eu2 O51 75.26(16) . .
O41 Eu2 O51 83.08(14) . .
O22 Eu2 O51 73.54(15) . .
O12 Eu2 O42 80.93(14) . 2_666
O41 Eu2 O42 108.30(12) . 2_666
O22 Eu2 O42 148.94(14) . 2_666
O51 Eu2 O42 132.71(15) . 2_666
O12 Eu2 O32 125.64(14) . .
O41 Eu2 O32 77.84(11) . .
O22 Eu2 O32 82.95(13) . .
O51 Eu2 O32 149.89(15) . .
O42 Eu2 O32 76.01(12) 2_666 .
O12 Eu2 O31 75.28(14) . .
O41 Eu2 O31 127.17(12) . .
O22 Eu2 O31 70.81(14) . .
O51 Eu2 O31 131.54(14) . .
O42 Eu2 O31 78.24(13) 2_666 .
O32 Eu2 O31 52.25(11) . .
O12 Eu2 O11W 86.39(15) . .
O41 Eu2 O11W 76.99(13) . .
O22 Eu2 O11W 140.00(15) . .
O51 Eu2 O11W 67.77(15) . .
O42 Eu2 O11W 70.52(14) 2_666 .
O32 Eu2 O11W 128.51(12) . .
O31 Eu2 O11W 145.89(14) . .
O12 Eu2 C314 100.34(15) . .
O41 Eu2 C314 102.95(13) . .
O22 Eu2 C314 77.00(14) . .
O51 Eu2 C314 149.82(15) . .
O42 Eu2 C314 74.07(13) 2_666 .
O32 Eu2 C314 25.96(12) . .
O31 Eu2 C314 26.38(12) . .
O11W Eu2 C314 142.37(14) . .
O5WA Eu3 Eu3 69.7(3) . 2_577
O5WA Eu3 O1W 86.8(3) . .
Eu3 Eu3 O1W 67.25(14) 2_577 .
O5WA Eu3 O5WA 123.2(2) . 2_577
Eu3 Eu3 O5WA 53.5(2) 2_577 2_577
O1W Eu3 O5WA 72.7(3) . 2_577
O5WA Eu3 O2W 63.8(3) . .
Eu3 Eu3 O2W 125.0(2) 2_577 .
O1W Eu3 O2W 134.0(2) . .
O5WA Eu3 O2W 152.8(3) 2_577 .
O5WA Eu3 O3W 144.9(3) . .
Eu3 Eu3 O3W 121.9(2) 2_577 .
O1W Eu3 O3W 128.2(2) . .
O5WA Eu3 O3W 76.7(3) 2_577 .
O2W Eu3 O3W 85.8(3) . .
O5WA Eu3 O4W 118.6(3) . .
Eu3 Eu3 O4W 150.25(16) 2_577 .
O1W Eu3 O4W 84.2(2) . .
O5WA Eu3 O4W 111.4(3) 2_577 .
O2W Eu3 O4W 80.8(3) . .
O3W Eu3 O4W 69.4(3) . .
O5WA Eu3 O5WB 42.4(4) . .
Eu3 Eu3 O5WB 92.4(2) 2_577 .
O1W Eu3 O5WB 62.4(2) . .
O5WA Eu3 O5WB 132.1(3) 2_577 .
O2W Eu3 O5WB 72.4(3) . .
O3W Eu3 O5WB 145.7(3) . .
O4W Eu3 O5WB 80.9(3) . .
O5WA Eu3 O1W 75.9(3) . 2_577
Eu3 Eu3 O1W 60.80(13) 2_577 2_577
O1W Eu3 O1W 128.06(12) . 2_577
O5WA Eu3 O1W 76.9(3) 2_577 2_577
O2W Eu3 O1W 80.3(2) . 2_577
O3W Eu3 O1W 82.3(3) . 2_577
O4W Eu3 O1W 146.9(2) . 2_577
O5WB Eu3 O1W 118.3(3) . 2_577
O5WA Eu3 H1WA 100.6(8) . .
Eu3 Eu3 H1WA 85.8(4) 2_577 .
O1W Eu3 H1WA 20.0(4) . .
O5WA Eu3 H1WA 77.1(10) 2_577 .
O2W Eu3 H1WA 129.4(9) . .
O3W Eu3 H1WA 112.7(7) . .
O4W Eu3 H1WA 64.9(4) . .
O5WB Eu3 H1WA 66.7(10) . .
O1W Eu3 H1WA 145.8(6) 2_577 .
O5WA Eu3 H1WB 70.4(9) . .
Eu3 Eu3 H1WB 71.2(9) 2_577 .
O1W Eu3 H1WB 18.9(7) . .
O5WA Eu3 H1WB 90.0(7) 2_577 .
O2W Eu3 H1WB 115.9(7) . .
O3W Eu3 H1WB 143.2(10) . .
O4W Eu3 H1WB 84.5(10) . .
O5WB Eu3 H1WB 43.7(7) . .
O1W Eu3 H1WB 128.3(10) 2_577 .
H1WA Eu3 H1WB 30.6(7) . .
O5WA Eu3 H2WA 79.6(7) . .
Eu3 Eu3 H2WA 131.0(12) 2_577 .
O1W Eu3 H2WA 148.9(9) . .
O5WA Eu3 H2WA 137.8(7) 2_577 .
O2W Eu3 H2WA 17.7(4) . .
O3W Eu3 H2WA 68.4(5) . .
O4W Eu3 H2WA 78.2(12) . .
O5WB Eu3 H2WA 89.4(6) . .
O1W Eu3 H2WA 75.5(12) 2_577 .
H1WA Eu3 H2WA 138.1(14) . .
H1WB Eu3 H2WA 132.2(9) . .
O5WA Eu3 H3WA 154.9(17) . .
Eu3 Eu3 H3WA 113(3) 2_577 .
O1W Eu3 H3WA 117.6(14) . .
O5WA Eu3 H3WA 65(2) 2_577 .
O2W Eu3 H3WA 98.6(16) . .
O3W Eu3 H3WA 12.8(16) . .
O4W Eu3 H3WA 72(3) . .
O5WB Eu3 H3WA 153(3) . .
O1W Eu3 H3WA 84(3) 2_577 .
H1WA Eu3 H3WA 104.4(19) . .
H1WB Eu3 H3WA 134.6(18) . .
H2WA Eu3 H3WA 81.1(16) . .
O5WA Eu3 H4WA 115.6(8) . .
Eu3 Eu3 H4WA 133.0(9) 2_577 .
O1W Eu3 H4WA 66.6(9) . .
O5WA Eu3 H4WA 103.8(9) 2_577 .
O2W Eu3 H4WA 94.0(9) . .
O3W Eu3 H4WA 81.8(8) . .
O4W Eu3 H4WA 17.6(9) . .
O5WB Eu3 H4WA 73.9(7) . .
O1W Eu3 H4WA 163.4(8) 2_577 .
H1WA Eu3 H4WA 47.3(10) . .
H1WB Eu3 H4WA 68.1(13) . .
H2WA Eu3 H4WA 94.3(15) . .
H3WA Eu3 H4WA 82(3) . .
O5WA Eu3 H4WB 99.3(6) . .
Eu3 Eu3 H4WB 153.7(9) 2_577 .
O1W Eu3 H4WB 88.8(9) . .
O5WA Eu3 H4WB 131.4(4) 2_577 .
O2W Eu3 H4WB 64.2(6) . .
O3W Eu3 H4WB 81.2(9) . .
O4W Eu3 H4WB 20.3(3) . .
O5WB Eu3 H4WB 65.7(8) . .
O1W Eu3 H4WB 141.7(8) 2_577 .
H1WA Eu3 H4WB 72.5(10) . .
H1WB Eu3 H4WB 82.6(13) . .
H2WA Eu3 H4WB 66.3(14) . .
H3WA Eu3 H4WB 87(3) . .
H4WA Eu3 H4WB 29.7(10) . .
O5WA Eu3 H5WA 17(3) . .
Eu3 Eu3 H5WA 81.5(13) 2_577 .
O1W Eu3 H5WA 103(4) . .
O5WA Eu3 H5WA 133.5(17) 2_577 .
O2W Eu3 H5WA 48(2) . .
O3W Eu3 H5WA 129(3) . .
O4W Eu3 H5WA 114(2) . .
O5WB Eu3 H5WA 50(4) . .
O1W Eu3 H5WA 71(4) 2_577 .
H1WA Eu3 H5WA 114(4) . .
H1WB Eu3 H5WA 85(4) . .
H2WA Eu3 H5WA 63(3) . .
H3WA Eu3 H5WA 140(4) . .
H4WA Eu3 H5WA 117(3) . .
H4WB Eu3 H5WA 94(2) . .
O5WA Eu3 H5WB 22.7(6) . .
Eu3 Eu3 H5WB 47.8(11) 2_577 .
O1W Eu3 H5WB 83(2) . .
O5WA Eu3 H5WB 101.0(9) 2_577 .
O2W Eu3 H5WB 80.9(18) . .
O3W Eu3 H5WB 144(2) . .
O4W Eu3 H5WB 139.8(10) . .
O5WB Eu3 H5WB 59.4(14) . .
O1W Eu3 H5WB 62.4(19) 2_577 .
H1WA Eu3 H5WB 102(2) . .
H1WB Eu3 H5WB 72(2) . .
H2WA Eu3 H5WB 94(2) . .
H3WA Eu3 H5WB 146(3) . .
H4WA Eu3 H5WB 132.4(18) . .
H4WB Eu3 H5WB 121.5(9) . .
H5WA Eu3 H5WB 34.0(19) . .
O5WA Eu3 H5WC 26.0(7) . .
Eu3 Eu3 H5WC 75.2(5) 2_577 .
O1W Eu3 H5WC 64.8(9) . .
O5WA Eu3 H5WC 122.8(8) 2_577 .
O2W Eu3 H5WC 75.8(9) . .
O3W Eu3 H5WC 160.5(8) . .
O4W Eu3 H5WC 100.7(4) . .
O5WB Eu3 H5WC 19.8(3) . .
O1W Eu3 H5WC 100.7(5) 2_577 .
H1WA Eu3 H5WC 75.6(12) . .
H1WB Eu3 H5WC 46.6(12) . .
H2WA Eu3 H5WC 93.4(10) . .
H3WA Eu3 H5WC 172(3) . .
H4WA Eu3 H5WC 92.9(8) . .
H4WB Eu3 H5WC 84.9(8) . .
H5WA Eu3 H5WC 39(4) . .
H5WB Eu3 H5WC 39.8(15) . .
O5WA Eu3 H5WD 46.4(9) . .
Eu3 Eu3 H5WD 109.0(6) 2_577 .
O1W Eu3 H5WD 80.0(5) . .
O5WA Eu3 H5WD 151.7(4) 2_577 .
O2W Eu3 H5WD 54.1(6) . .
O3W Eu3 H5WD 127.9(5) . .
O4W Eu3 H5WD 72.2(9) . .
O5WB Eu3 H5WD 19.8(3) . .
O1W Eu3 H5WD 116.3(10) 2_577 .
H1WA Eu3 H5WD 79.7(12) . .
H1WB Eu3 H5WD 62.0(8) . .
H2WA Eu3 H5WD 70.3(7) . .
H3WA Eu3 H5WD 138(3) . .
H4WA Eu3 H5WD 70.9(12) . .
H4WB Eu3 H5WD 53.5(10) . .
H5WA Eu3 H5WD 46(3) . .
H5WB Eu3 H5WD 68.0(11) . .
H5WC Eu3 H5WD 33.8(6) . .
N43 Zn1 N32 112.82(18) 1_454 .
N43 Zn1 N11 111.43(17) 1_454 1_444
N32 Zn1 N11 102.78(17) . 1_444
N43 Zn1 N54 99.80(18) 1_454 2_666
N32 Zn1 N54 120.63(16) . 2_666
N11 Zn1 N54 109.57(17) 1_444 2_666
Eu3 O1W Eu3 51.94(12) . 2_577
Eu3 O1W H1WA 88(3) . .
Eu3 O1W H1WA 135(3) 2_577 .
Eu3 O1W H1WB 96(5) . .
Eu3 O1W H1WB 100(4) 2_577 .
H1WA O1W H1WB 105(2) . .
Eu3 O2W H2WA 105(2) . .
Eu3 O2W H2WB 145(4) . .
H2WA O2W H2WB 103(2) . .
Eu3 O3W H3WA 26(4) . .
Eu3 O4W H4WA 101(6) . .
Eu3 O4W H4WB 74(5) . .
H4WA O4W H4WB 106(2) . .
Eu3 O5WA Eu3 56.8(2) . 2_577
Eu3 O5WA H5WA 27(6) . .
Eu3 O5WA H5WA 77(3) 2_577 .
Eu3 O5WA H5WB 90(4) . .
Eu3 O5WA H5WB 35(5) 2_577 .
H5WA O5WA H5WB 103(2) . .
Eu3 O5WA H5WC 92(4) . .
Eu3 O5WA H5WC 98(3) 2_577 .
H5WA O5WA H5WC 109(8) . .
H5WB O5WA H5WC 111(6) . .
Eu3 O5WB H5WC 69(4) . .
Eu3 O5WB H5WD 67(5) . .
H5WC O5WB H5WD 105(3) . .
Eu1 O6W H6WA 141(3) . .
Eu1 O6W H6WB 66(3) . .
H6WA O6W H6WB 104(2) . .
Eu1 O7W H7WA 126(3) . .
Eu1 O7W H7WB 117(2) . .
H7WA O7W H7WB 105(2) . .
Eu1 O8W H8WA 74(3) . .
Eu1 O8W H8WB 97(3) . .
H8WA O8W H8WB 112(3) . .
Eu1 O9W H9WA 111(3) . .
Eu1 O9W H9WB 137(3) . .
H9WA O9W H9WB 106(2) . .
Eu1 O10W H10A 120(4) . .
Eu1 O10W H10B 112(3) . .
H10A O10W H10B 105(2) . .
C114 O11 Eu1 136.4(3) . .
Eu2 O11W H11D 138(2) . .
Eu2 O11W H11E 121(2) . .
H11D O11W H11E 101(2) . .
C114 O12 Eu2 169.6(4) . .
H12A O12W H12B 106(3) . .
H13B O13W H13C 107(3) . .
H14B O14W H14C 104(2) . .
C214 O21 Eu1 132.8(3) . .
C214 O22 Eu2 159.1(3) . .
C314 O31 Eu2 92.9(3) . .
C314 O32 Eu2 94.0(3) . .
C159 O41 Eu2 177.7(3) . .
C159 O42 Eu2 129.6(3) . 2_666
C514 O51 Eu2 158.3(4) . .
C514 O52 Eu1 137.1(3) . .
C11 N11 N12 106.2(4) . .
C11 N11 Zn1 136.8(3) . 1_666
N12 N11 Zn1 116.9(3) . 1_666
N13 N12 N11 108.1(4) . .
N12 N13 N14 110.3(4) . .
C11 N14 N13 105.2(4) . .
C21 N21 N22 104.9(5) . .
N23 N22 N21 109.2(5) . .
N22 N23 N24 109.5(6) . .
N22 N23 H23B 125.3 . .
N24 N23 H23B 125.3 . .
C21 N24 N23 103.9(6) . .
C31 N31 N32 103.8(4) . .
N33 N32 N31 111.0(4) . .
N33 N32 Zn1 117.7(3) . .
N31 N32 Zn1 131.2(3) . .
N32 N33 N34 107.8(4) . .
C31 N34 N33 105.3(4) . .
C41 N41 N42 106.7(4) . .
N43 N42 N41 107.2(4) . .
N42 N43 N44 111.0(4) . .
N42 N43 Zn1 131.2(3) . 1_656
N44 N43 Zn1 117.6(4) . 1_656
C41 N44 N43 104.3(4) . .
C51 N51 N52 105.1(5) . .
N53 N52 N51 109.4(5) . .
N52 N53 N54 108.8(4) . .
C51 N54 N53 106.0(4) . .
C51 N54 Zn1 134.2(4) . 2_666
N53 N54 Zn1 119.7(3) . 2_666
N11 C11 N14 110.3(5) . .
N11 C11 C12 126.8(4) . .
N14 C11 C12 122.9(5) . .
C17 C12 C13 118.7(5) . .
C17 C12 C11 120.8(5) . .
C13 C12 C11 120.4(5) . .
C14 C13 C12 119.7(5) . .
C14 C13 H13A 120.2 . .
C12 C13 H13A 120.1 . .
C15 C14 C13 120.9(5) . .
C15 C14 H14A 119.6 . .
C13 C14 H14A 119.4 . .
C14 C15 C16 118.4(5) . .
C14 C15 C18 120.6(5) . .
C16 C15 C18 120.9(5) . .
C17 C16 C15 121.1(5) . .
C17 C16 H16A 119.2 . .
C15 C16 H16A 119.8 . .
C16 C17 C12 121.1(5) . .
C16 C17 H17A 119.7 . .
C12 C17 H17A 119.2 . .
C113 C18 C19 118.5(5) . .
C113 C18 C15 120.0(5) . .
C19 C18 C15 121.4(4) . .
C18 C19 C110 120.2(4) . .
C18 C19 H19A 119.9 . .
C110 C19 H19A 119.9 . .
N24 C21 N21 112.4(6) . .
N24 C21 C22 122.3(6) . .
N21 C21 C22 125.3(6) . .
C23 C22 C27 117.6(6) . .
C23 C22 C21 120.5(6) . .
C27 C22 C21 121.8(5) . .
C22 C23 C24 121.4(7) . .
C22 C23 H23A 119.2 . .
C24 C23 H23A 119.4 . .
C25 C24 C23 121.1(7) . .
C25 C24 H24A 119.5 . .
C23 C24 H24A 119.4 . .
C24 C25 C26 116.0(6) . .
C24 C25 C28 121.0(5) . .
C26 C25 C28 123.0(5) . .
C27 C26 C25 123.2(6) . .
C27 C26 H26A 118.0 . .
C25 C26 H26A 118.8 . .
C26 C27 C22 120.2(6) . .
C26 C27 H27A 119.5 . .
C22 C27 H27A 120.3 . .
C213 C28 C29 117.7(5) . .
C213 C28 C25 120.6(5) . .
C29 C28 C25 121.7(5) . .
C210 C29 C28 121.6(5) . .
C210 C29 H29A 119.3 . .
C28 C29 H29A 119.1 . .
N31 C31 N34 111.9(4) . .
N31 C31 C32 125.5(4) . .
N34 C31 C32 122.6(4) . .
C33 C32 C37 118.3(4) . .
C33 C32 C31 120.7(5) . .
C37 C32 C31 121.0(4) . .
C34 C33 C32 120.6(5) . .
C34 C33 H33A 119.8 . .
C32 C33 H33A 119.5 . .
C33 C34 C35 121.9(5) . .
C33 C34 H34A 119.1 . .
C35 C34 H34A 119.0 . .
C34 C35 C36 117.5(4) . .
C34 C35 C38 121.9(4) . .
C36 C35 C38 120.6(4) . .
C37 C36 C35 120.5(5) . .
C37 C36 H36A 119.4 . .
C35 C36 H36A 120.1 . .
C36 C37 C32 121.1(4) . .
C36 C37 H37A 119.5 . .
C32 C37 H37A 119.4 . .
C39 C38 C313 118.3(4) . .
C39 C38 C35 121.9(4) . .
C313 C38 C35 119.8(4) . .
C310 C39 C38 121.1(4) . .
C310 C39 H39A 119.7 . .
C38 C39 H39A 119.3 . .
N44 C41 N41 110.8(4) . .
N44 C41 C42 123.3(5) . .
N41 C41 C42 125.9(5) . .
C43 C42 C47 117.2(4) . .
C43 C42 C41 120.0(5) . .
C47 C42 C41 122.9(5) . .
C42 C43 C44 121.6(5) . .
C42 C43 H43A 119.1 . .
C44 C43 H43A 119.3 . .
C45 C44 C43 121.4(5) . .
C45 C44 H44A 119.3 . .
C43 C44 H44A 119.3 . .
C44 C45 C46 117.0(4) . .
C44 C45 C48 120.8(4) . .
C46 C45 C48 122.2(4) . .
C47 C46 C45 121.7(5) . .
C47 C46 H46A 119.3 . .
C45 C46 H46A 119.0 . .
C46 C47 C42 121.2(5) . .
C46 C47 H47A 119.5 . .
C42 C47 H47A 119.3 . .
C413 C48 C49 117.8(4) . .
C413 C48 C45 121.9(4) . .
C49 C48 C45 120.3(4) . .
C410 C49 C48 120.6(4) . .
C410 C49 H49A 119.6 . .
C48 C49 H49A 119.7 . .
N54 C51 N51 110.7(5) . .
N54 C51 C52 122.5(5) . .
N51 C51 C52 126.7(5) . .
C57 C52 C53 119.5(5) . .
C57 C52 C51 120.4(5) . .
C53 C52 C51 119.8(5) . .
C54 C53 C52 119.7(5) . .
C54 C53 H53A 120.4 . .
C52 C53 H53A 119.9 . .
C53 C54 C55 121.5(5) . .
C53 C54 H54A 119.1 . .
C55 C54 H54A 119.4 . .
C54 C55 C56 118.1(5) . .
C54 C55 C58 120.8(5) . .
C56 C55 C58 121.1(5) . .
C55 C56 C57 120.5(5) . .
C55 C56 H56A 120.0 . .
C57 C56 H56A 119.5 . .
C52 C57 C56 120.4(5) . .
C52 C57 H57A 119.4 . .
C56 C57 H57A 120.2 . .
C513 C58 C59 119.1(5) . .
C513 C58 C55 119.5(5) . .
C59 C58 C55 121.4(5) . .
C510 C59 C58 121.1(5) . .
C510 C59 H59A 119.4 . .
C58 C59 H59A 119.5 . .
C111 C110 C19 120.6(5) . .
C111 C110 C114 119.5(4) . .
C19 C110 C114 119.6(4) . .
C112 C111 C110 119.2(5) . .
C112 C111 H11A 120.0 . .
C110 C111 H11A 120.7 . .
C111 C112 C113 120.4(5) . .
C111 C112 H11B 119.7 . .
C113 C112 H11B 119.9 . .
C18 C113 C112 120.9(5) . .
C18 C113 H11C 120.1 . .
C112 C113 H11C 119.0 . .
O11 C114 O12 122.2(5) . .
O11 C114 C110 119.1(4) . .
O12 C114 C110 118.5(5) . .
O41 C159 O42 122.4(4) . .
O41 C159 C410 120.2(4) . .
O42 C159 C410 117.4(4) . .
C211 C210 C29 119.8(5) . .
C211 C210 C214 120.2(5) . .
C29 C210 C214 120.0(4) . .
C210 C211 C212 119.3(5) . .
C210 C211 H21A 120.4 . .
C212 C211 H21A 120.3 . .
C213 C212 C211 120.5(6) . .
C213 C212 H21B 119.6 . .
C211 C212 H21B 119.9 . .
C212 C213 C28 121.0(5) . .
C212 C213 H21C 119.3 . .
C28 C213 H21C 119.6 . .
O21 C214 O22 123.9(4) . .
O21 C214 C210 118.0(4) . .
O22 C214 C210 118.0(4) . .
C311 C310 C39 120.0(4) . .
C311 C310 C314 119.3(4) . .
C39 C310 C314 120.6(4) . .
C312 C311 C310 119.3(4) . .
C312 C311 H31A 120.1 . .
C310 C311 H31A 120.6 . .
C311 C312 C313 120.9(5) . .
C311 C312 H31B 120.0 . .
C313 C312 H31B 119.1 . .
C312 C313 C38 120.4(4) . .
C312 C313 H31C 119.9 . .
C38 C313 H31C 119.7 . .
O32 C314 O31 120.4(4) . .
O32 C314 C310 121.1(4) . .
O31 C314 C310 118.5(4) . .
O32 C314 Eu2 60.0(2) . .
O31 C314 Eu2 60.7(2) . .
C310 C314 Eu2 174.8(3) . .
C411 C410 C49 119.8(4) . .
C411 C410 C159 120.1(4) . .
C49 C410 C159 120.0(4) . .
C410 C411 C412 120.3(4) . .
C410 C411 H41A 119.9 . .
C412 C411 H41A 119.8 . .
C413 C412 C411 119.5(5) . .
C413 C412 H41B 120.1 . .
C411 C412 H41B 120.4 . .
C412 C413 C48 121.8(4) . .
C412 C413 H41C 118.9 . .
C48 C413 H41C 119.2 . .
C59 C510 C511 119.2(5) . .
C59 C510 C514 121.3(4) . .
C511 C510 C514 119.4(5) . .
C510 C511 C512 120.0(5) . .
C510 C511 H51A 120.1 . .
C512 C511 H51A 119.9 . .
C513 C512 C511 120.1(5) . .
C513 C512 H51B 120.1 . .
C511 C512 H51B 119.8 . .
C512 C513 C58 120.5(5) . .
C512 C513 H51C 119.7 . .
C58 C513 H51C 119.9 . .
O51 C514 O52 125.2(5) . .
O51 C514 C510 116.3(5) . .
O52 C514 C510 118.6(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O11 2.288(3) .
Eu1 O21 2.328(3) .
Eu1 O52 2.346(3) .
Eu1 O8W 2.422(5) .
Eu1 O7W 2.441(4) .
Eu1 O6W 2.521(4) .
Eu1 O9W 2.519(4) .
Eu1 O10W 2.549(4) .
Eu1 H6WB 2.31(4) .
Eu1 H8WA 2.33(4) .
Eu1 H8WB 2.66(3) .
Eu2 O12 2.304(4) .
Eu2 O41 2.311(3) .
Eu2 O22 2.328(3) .
Eu2 O51 2.364(4) .
Eu2 O42 2.377(3) 2_666
Eu2 O32 2.490(3) .
Eu2 O31 2.504(3) .
Eu2 O11W 2.564(4) .
Eu2 C314 2.867(5) .
Eu3 O5WA 2.061(9) .
Eu3 Eu3 2.1445(11) 2_577
Eu3 O1W 2.378(6) .
Eu3 O5WA 2.405(9) 2_577
Eu3 O2W 2.410(7) .
Eu3 O3W 2.418(9) .
Eu3 O4W 2.475(8) .
Eu3 O5WB 2.508(9) .
Eu3 O1W 2.512(6) 2_577
Eu3 H1WA 2.50(4) .
Eu3 H1WB 2.61(7) .
Eu3 H2WA 2.76(3) .
Eu3 H3WA 1.69(4) .
Eu3 H4WA 2.77(7) .
Eu3 H4WB 2.39(7) .
Eu3 H5WA 1.36(7) .
Eu3 H5WB 2.23(5) .
Eu3 H5WC 2.34(7) .
Eu3 H5WD 2.31(7) .
Zn1 N43 1.991(4) 1_454
Zn1 N32 1.995(4) .
Zn1 N11 1.999(4) 1_444
Zn1 N54 2.007(4) 2_666
O1W Eu3 2.512(6) 2_577
O1W H1WA 0.855(10) .
O1W H1WB 0.851(10) .
O2W H2WA 0.865(10) .
O2W H2WB 0.858(10) .
O3W H3WA 0.859(11) .
O4W H4WA 0.851(10) .
O4W H4WB 0.861(11) .
O5WA Eu3 2.405(8) 2_577
O5WA H5WA 0.851(10) .
O5WA H5WB 0.861(11) .
O5WA H5WC 1.03(4) .
O5WB H5WC 0.849(11) .
O5WB H5WD 0.853(11) .
O6W H6WA 0.850(10) .
O6W H6WB 0.849(10) .
O7W H7WA 0.851(10) .
O7W H7WB 0.850(10) .
O8W H8WA 0.840(10) .
O8W H8WB 0.842(10) .
O9W H9WA 0.843(10) .
O9W H9WB 0.846(10) .
O10W H10A 0.848(10) .
O10W H10B 0.850(10) .
O11 C114 1.233(6) .
O11W H11D 0.860(10) .
O11W H11E 0.856(10) .
O12 C114 1.245(6) .
O12W H12A 0.848(11) .
O12W H12B 0.850(11) .
O13W H13B 0.850(11) .
O13W H13C 0.848(11) .
O14W H14B 0.851(10) .
O14W H14C 0.851(10) .
O21 C214 1.254(6) .
O22 C214 1.254(6) .
O31 C314 1.276(6) .
O32 C314 1.258(6) .
O41 C159 1.250(6) .
O42 C159 1.253(6) .
O42 Eu2 2.377(3) 2_666
O51 C514 1.226(6) .
O52 C514 1.256(6) .
N11 C11 1.322(6) .
N11 N12 1.356(6) .
N11 Zn1 1.999(4) 1_666
N12 N13 1.288(7) .
N13 N14 1.347(7) .
N14 C11 1.328(7) .
N21 C21 1.327(7) .
N21 N22 1.335(7) .
N22 N23 1.307(8) .
N23 N24 1.356(8) .
N23 H23B 0.8600 .
N24 C21 1.321(8) .
N31 C31 1.330(6) .
N31 N32 1.344(5) .
N32 N33 1.317(6) .
N33 N34 1.346(6) .
N34 C31 1.339(7) .
N41 C41 1.338(7) .
N41 N42 1.340(6) .
N42 N43 1.311(6) .
N43 N44 1.350(6) .
N43 Zn1 1.991(4) 1_656
N44 C41 1.327(7) .
N51 C51 1.325(7) .
N51 N52 1.358(7) .
N52 N53 1.286(7) .
N53 N54 1.352(6) .
N54 C51 1.315(6) .
N54 Zn1 2.007(4) 2_666
C11 C12 1.467(7) .
C12 C17 1.382(7) .
C12 C13 1.400(7) .
C13 C14 1.397(7) .
C13 H13A 0.9305 .
C14 C15 1.374(7) .
C14 H14A 0.9297 .
C15 C16 1.399(8) .
C15 C18 1.489(7) .
C16 C17 1.362(8) .
C16 H16A 0.9300 .
C17 H17A 0.9312 .
C18 C113 1.390(8) .
C18 C19 1.392(7) .
C19 C110 1.393(6) .
C19 H19A 0.9281 .
C21 C22 1.489(8) .
C22 C23 1.378(9) .
C22 C27 1.379(9) .
C23 C24 1.385(10) .
C23 H23A 0.9307 .
C24 C25 1.377(9) .
C24 H24A 0.9341 .
C25 C26 1.388(8) .
C25 C28 1.482(8) .
C26 C27 1.359(9) .
C26 H26A 0.9283 .
C27 H27A 0.9287 .
C28 C213 1.390(8) .
C28 C29 1.395(7) .
C29 C210 1.383(7) .
C29 H29A 0.9311 .
C31 C32 1.479(6) .
C32 C33 1.386(7) .
C32 C37 1.395(7) .
C33 C34 1.371(7) .
C33 H33A 0.9299 .
C34 C35 1.392(7) .
C34 H34A 0.9312 .
C35 C36 1.403(7) .
C35 C38 1.494(6) .
C36 C37 1.381(7) .
C36 H36A 0.9289 .
C37 H37A 0.9302 .
C38 C39 1.392(6) .
C38 C313 1.395(7) .
C39 C310 1.392(6) .
C39 H39A 0.9297 .
C41 C42 1.448(6) .
C42 C43 1.383(7) .
C42 C47 1.389(7) .
C43 C44 1.389(7) .
C43 H43A 0.9301 .
C44 C45 1.382(7) .
C44 H44A 0.9300 .
C45 C46 1.392(7) .
C45 C48 1.476(6) .
C46 C47 1.382(7) .
C46 H46A 0.9300 .
C47 H47A 0.9307 .
C48 C413 1.395(7) .
C48 C49 1.417(6) .
C49 C410 1.391(6) .
C49 H49A 0.9299 .
C51 C52 1.482(7) .
C52 C57 1.368(8) .
C52 C53 1.396(7) .
C53 C54 1.382(7) .
C53 H53A 0.9317 .
C54 C55 1.383(7) .
C54 H54A 0.9287 .
C55 C56 1.392(7) .
C55 C58 1.483(7) .
C56 C57 1.397(8) .
C56 H56A 0.9286 .
C57 H57A 0.9318 .
C58 C513 1.383(8) .
C58 C59 1.385(7) .
C59 C510 1.383(7) .
C59 H59A 0.9311 .
C110 C111 1.389(7) .
C110 C114 1.478(7) .
C111 C112 1.374(8) .
C111 H11A 0.9282 .
C112 C113 1.391(9) .
C112 H11B 0.9299 .
C113 H11C 0.9300 .
C159 C410 1.492(6) .
C210 C211 1.369(7) .
C210 C214 1.487(6) .
C211 C212 1.403(8) .
C211 H21A 0.9305 .
C212 C213 1.366(9) .
C212 H21B 0.9300 .
C213 H21C 0.9301 .
C310 C311 1.387(7) .
C310 C314 1.504(6) .
C311 C312 1.381(7) .
C311 H31A 0.9291 .
C312 C313 1.387(7) .
C312 H31B 0.9293 .
C313 H31C 0.9303 .
C410 C411 1.385(6) .
C411 C412 1.399(7) .
C411 H41A 0.9303 .
C412 C413 1.379(7) .
C412 H41B 0.9299 .
C413 H41C 0.9298 .
C510 C511 1.386(7) .
C510 C514 1.486(7) .
C511 C512 1.386(8) .
C511 H51A 0.9301 .
C512 C513 1.380(8) .
C512 H51B 0.9301 .
C513 H51C 0.9294 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
O5WA Eu3 O1W Eu3 69.3(3) . . . 2_577
O5WA Eu3 O1W Eu3 -57.0(3) 2_577 . . 2_577
O2W Eu3 O1W Eu3 117.3(3) . . . 2_577
O3W Eu3 O1W Eu3 -113.5(3) . . . 2_577
O4W Eu3 O1W Eu3 -171.50(17) . . . 2_577
O5WB Eu3 O1W Eu3 105.7(3) . . . 2_577
O1W Eu3 O1W Eu3 0.0 2_577 . . 2_577
O1W Eu3 O5WA Eu3 -66.90(16) . . . 2_577
O5WA Eu3 O5WA Eu3 0.000(1) 2_577 . . 2_577
O2W Eu3 O5WA Eu3 149.6(3) . . . 2_577
O3W Eu3 O5WA Eu3 117.0(5) . . . 2_577
O4W Eu3 O5WA Eu3 -148.51(19) . . . 2_577
O5WB Eu3 O5WA Eu3 -118.1(4) . . . 2_577
O1W Eu3 O5WA Eu3 63.67(16) 2_577 . . 2_577
O21 Eu1 O11 C114 -7.9(6) . . . .
O52 Eu1 O11 C114 63.0(5) . . . .
O8W Eu1 O11 C114 144.3(5) . . . .
O7W Eu1 O11 C114 -120.5(5) . . . .
O6W Eu1 O11 C114 119.7(5) . . . .
O9W Eu1 O11 C114 -144.0(5) . . . .
O10W Eu1 O11 C114 -65.8(5) . . . .
O41 Eu2 O12 C114 -59(2) . . . .
O22 Eu2 O12 C114 36(2) . . . .
O51 Eu2 O12 C114 -36(2) . . . .
O42 Eu2 O12 C114 -175(2) 2_666 . . .
O32 Eu2 O12 C114 120(2) . . . .
O31 Eu2 O12 C114 105(2) . . . .
O11W Eu2 O12 C114 -104(2) . . . .
C314 Eu2 O12 C114 113(2) . . . .
O11 Eu1 O21 C214 -16.7(5) . . . .
O52 Eu1 O21 C214 -87.9(4) . . . .
O8W Eu1 O21 C214 -140.5(4) . . . .
O7W Eu1 O21 C214 122.2(4) . . . .
O6W Eu1 O21 C214 -167.8(4) . . . .
O9W Eu1 O21 C214 84.5(5) . . . .
O10W Eu1 O21 C214 43.5(4) . . . .
O12 Eu2 O22 C214 -68.8(10) . . . .
O41 Eu2 O22 C214 87.8(10) . . . .
O51 Eu2 O22 C214 4.7(10) . . . .
O42 Eu2 O22 C214 -147.0(9) 2_666 . . .
O32 Eu2 O22 C214 165.7(10) . . . .
O31 Eu2 O22 C214 -141.9(10) . . . .
O11W Eu2 O22 C214 19.7(11) . . . .
C314 Eu2 O22 C214 -168.6(10) . . . .
O12 Eu2 O31 C314 161.4(3) . . . .
O41 Eu2 O31 C314 -26.4(4) . . . .
O22 Eu2 O31 C314 -99.5(3) . . . .
O51 Eu2 O31 C314 -144.4(3) . . . .
O42 Eu2 O31 C314 77.8(3) 2_666 . . .
O32 Eu2 O31 C314 -3.5(3) . . . .
O11W Eu2 O31 C314 101.6(3) . . . .
O12 Eu2 O32 C314 -14.5(3) . . . .
O41 Eu2 O32 C314 165.1(3) . . . .
O22 Eu2 O32 C314 74.7(3) . . . .
O51 Eu2 O32 C314 113.2(4) . . . .
O42 Eu2 O32 C314 -82.3(3) 2_666 . . .
O31 Eu2 O32 C314 3.6(3) . . . .
O11W Eu2 O32 C314 -132.7(3) . . . .
O12 Eu2 O51 C514 37.0(11) . . . .
O41 Eu2 O51 C514 -152.1(11) . . . .
O22 Eu2 O51 C514 -61.2(11) . . . .
O42 Eu2 O51 C514 99.3(11) 2_666 . . .
O32 Eu2 O51 C514 -101.3(11) . . . .
O31 Eu2 O51 C514 -17.2(12) . . . .
O11W Eu2 O51 C514 129.2(12) . . . .
C314 Eu2 O51 C514 -48.2(13) . . . .
O11 Eu1 O52 C514 -87.9(5) . . . .
O21 Eu1 O52 C514 41.0(5) . . . .
O8W Eu1 O52 C514 -165.2(5) . . . .
O7W Eu1 O52 C514 96.1(5) . . . .
O6W Eu1 O52 C514 122.9(5) . . . .
O9W Eu1 O52 C514 -130.9(5) . . . .
O10W Eu1 O52 C514 -19.7(6) . . . .
C11 N11 N12 N13 0.2(6) . . . .
Zn1 N11 N12 N13 -176.9(4) 1_666 . . .
N11 N12 N13 N14 -0.1(7) . . . .
N12 N13 N14 C11 -0.1(7) . . . .
C21 N21 N22 N23 -1.5(7) . . . .
N21 N22 N23 N24 2.1(8) . . . .
N22 N23 N24 C21 -1.9(8) . . . .
C31 N31 N32 N33 1.1(5) . . . .
C31 N31 N32 Zn1 -176.5(3) . . . .
N43 Zn1 N32 N33 -6.0(4) 1_454 . . .
N11 Zn1 N32 N33 114.1(4) 1_444 . . .
N54 Zn1 N32 N33 -123.6(4) 2_666 . . .
N43 Zn1 N32 N31 171.4(4) 1_454 . . .
N11 Zn1 N32 N31 -68.4(4) 1_444 . . .
N54 Zn1 N32 N31 53.8(5) 2_666 . . .
N31 N32 N33 N34 -1.6(6) . . . .
Zn1 N32 N33 N34 176.3(3) . . . .
N32 N33 N34 C31 1.4(6) . . . .
C41 N41 N42 N43 0.1(6) . . . .
N41 N42 N43 N44 -0.5(6) . . . .
N41 N42 N43 Zn1 175.0(4) . . . 1_656
N42 N43 N44 C41 0.7(5) . . . .
Zn1 N43 N44 C41 -175.5(3) 1_656 . . .
C51 N51 N52 N53 -1.1(7) . . . .
N51 N52 N53 N54 0.6(7) . . . .
N52 N53 N54 C51 0.2(7) . . . .
N52 N53 N54 Zn1 177.7(4) . . . 2_666
N12 N11 C11 N14 -0.3(6) . . . .
Zn1 N11 C11 N14 176.0(4) 1_666 . . .
N12 N11 C11 C12 179.4(5) . . . .
Zn1 N11 C11 C12 -4.3(9) 1_666 . . .
N13 N14 C11 N11 0.2(7) . . . .
N13 N14 C11 C12 -179.4(5) . . . .
N11 C11 C12 C17 -126.2(6) . . . .
N14 C11 C12 C17 53.4(8) . . . .
N11 C11 C12 C13 53.1(8) . . . .
N14 C11 C12 C13 -127.3(6) . . . .
C17 C12 C13 C14 0.8(7) . . . .
C11 C12 C13 C14 -178.6(5) . . . .
C12 C13 C14 C15 1.8(7) . . . .
C13 C14 C15 C16 -3.4(7) . . . .
C13 C14 C15 C18 175.3(5) . . . .
C14 C15 C16 C17 2.5(8) . . . .
C18 C15 C16 C17 -176.2(5) . . . .
C15 C16 C17 C12 0.0(9) . . . .
C13 C12 C17 C16 -1.7(8) . . . .
C11 C12 C17 C16 177.7(5) . . . .
C14 C15 C18 C113 -133.6(6) . . . .
C16 C15 C18 C113 45.1(8) . . . .
C14 C15 C18 C19 48.5(7) . . . .
C16 C15 C18 C19 -132.8(6) . . . .
C113 C18 C19 C110 0.2(8) . . . .
C15 C18 C19 C110 178.1(5) . . . .
N23 N24 C21 N21 1.0(8) . . . .
N23 N24 C21 C22 -177.4(6) . . . .
N22 N21 C21 N24 0.3(7) . . . .
N22 N21 C21 C22 178.6(6) . . . .
N24 C21 C22 C23 -9.3(10) . . . .
N21 C21 C22 C23 172.5(7) . . . .
N24 C21 C22 C27 174.7(7) . . . .
N21 C21 C22 C27 -3.4(10) . . . .
C27 C22 C23 C24 -3.8(13) . . . .
C21 C22 C23 C24 -179.9(8) . . . .
C22 C23 C24 C25 -3.1(14) . . . .
C23 C24 C25 C26 6.9(12) . . . .
C23 C24 C25 C28 -175.0(7) . . . .
C24 C25 C26 C27 -4.1(11) . . . .
C28 C25 C26 C27 177.9(7) . . . .
C25 C26 C27 C22 -2.7(12) . . . .
C23 C22 C27 C26 6.6(11) . . . .
C21 C22 C27 C26 -177.4(6) . . . .
C24 C25 C28 C213 -157.5(7) . . . .
C26 C25 C28 C213 20.4(9) . . . .
C24 C25 C28 C29 23.8(9) . . . .
C26 C25 C28 C29 -158.3(6) . . . .
C213 C28 C29 C210 -1.3(8) . . . .
C25 C28 C29 C210 177.5(5) . . . .
N32 N31 C31 N34 -0.2(5) . . . .
N32 N31 C31 C32 179.3(4) . . . .
N33 N34 C31 N31 -0.8(6) . . . .
N33 N34 C31 C32 179.7(4) . . . .
N31 C31 C32 C33 -170.1(5) . . . .
N34 C31 C32 C33 9.3(7) . . . .
N31 C31 C32 C37 10.0(7) . . . .
N34 C31 C32 C37 -170.6(5) . . . .
C37 C32 C33 C34 0.6(7) . . . .
C31 C32 C33 C34 -179.3(4) . . . .
C32 C33 C34 C35 0.3(8) . . . .
C33 C34 C35 C36 -0.6(7) . . . .
C33 C34 C35 C38 -179.8(4) . . . .
C34 C35 C36 C37 0.0(7) . . . .
C38 C35 C36 C37 179.3(4) . . . .
C35 C36 C37 C32 0.8(7) . . . .
C33 C32 C37 C36 -1.1(7) . . . .
C31 C32 C37 C36 178.8(4) . . . .
C34 C35 C38 C39 33.3(7) . . . .
C36 C35 C38 C39 -146.0(5) . . . .
C34 C35 C38 C313 -147.3(5) . . . .
C36 C35 C38 C313 33.5(6) . . . .
C313 C38 C39 C310 -2.0(7) . . . .
C35 C38 C39 C310 177.5(4) . . . .
N43 N44 C41 N41 -0.7(6) . . . .
N43 N44 C41 C42 -178.9(4) . . . .
N42 N41 C41 N44 0.3(6) . . . .
N42 N41 C41 C42 178.5(5) . . . .
N44 C41 C42 C43 -9.2(7) . . . .
N41 C41 C42 C43 172.8(5) . . . .
N44 C41 C42 C47 168.6(5) . . . .
N41 C41 C42 C47 -9.3(8) . . . .
C47 C42 C43 C44 -0.6(7) . . . .
C41 C42 C43 C44 177.4(5) . . . .
C42 C43 C44 C45 -0.8(8) . . . .
C43 C44 C45 C46 0.9(7) . . . .
C43 C44 C45 C48 -176.6(4) . . . .
C44 C45 C46 C47 0.4(8) . . . .
C48 C45 C46 C47 177.9(5) . . . .
C45 C46 C47 C42 -1.8(8) . . . .
C43 C42 C47 C46 1.8(8) . . . .
C41 C42 C47 C46 -176.1(5) . . . .
C44 C45 C48 C413 -155.1(5) . . . .
C46 C45 C48 C413 27.6(7) . . . .
C44 C45 C48 C49 26.7(7) . . . .
C46 C45 C48 C49 -150.6(5) . . . .
C413 C48 C49 C410 -3.8(6) . . . .
C45 C48 C49 C410 174.5(4) . . . .
N53 N54 C51 N51 -1.0(6) . . . .
Zn1 N54 C51 N51 -177.9(4) 2_666 . . .
N53 N54 C51 C52 -177.8(5) . . . .
Zn1 N54 C51 C52 5.3(8) 2_666 . . .
N52 N51 C51 N54 1.3(7) . . . .
N52 N51 C51 C52 177.9(5) . . . .
N54 C51 C52 C57 127.7(6) . . . .
N51 C51 C52 C57 -48.6(8) . . . .
N54 C51 C52 C53 -45.6(7) . . . .
N51 C51 C52 C53 138.2(6) . . . .
C57 C52 C53 C54 -3.4(7) . . . .
C51 C52 C53 C54 169.9(4) . . . .
C52 C53 C54 C55 -2.1(7) . . . .
C53 C54 C55 C56 5.6(7) . . . .
C53 C54 C55 C58 -172.5(4) . . . .
C54 C55 C56 C57 -3.8(8) . . . .
C58 C55 C56 C57 174.2(5) . . . .
C53 C52 C57 C56 5.1(8) . . . .
C51 C52 C57 C56 -168.1(5) . . . .
C55 C56 C57 C52 -1.5(8) . . . .
C54 C55 C58 C513 136.4(5) . . . .
C56 C55 C58 C513 -41.5(7) . . . .
C54 C55 C58 C59 -40.9(7) . . . .
C56 C55 C58 C59 141.1(5) . . . .
C513 C58 C59 C510 0.8(7) . . . .
C55 C58 C59 C510 178.2(4) . . . .
C18 C19 C110 C111 2.2(8) . . . .
C18 C19 C110 C114 -172.4(4) . . . .
C19 C110 C111 C112 -1.5(9) . . . .
C114 C110 C111 C112 173.1(6) . . . .
C110 C111 C112 C113 -1.6(11) . . . .
C19 C18 C113 C112 -3.3(10) . . . .
C15 C18 C113 C112 178.8(6) . . . .
C111 C112 C113 C18 4.1(11) . . . .
Eu1 O11 C114 O12 2.2(8) . . . .
Eu1 O11 C114 C110 177.5(3) . . . .
Eu2 O12 C114 O11 -19(3) . . . .
Eu2 O12 C114 C110 165.8(19) . . . .
C111 C110 C114 O11 -173.6(5) . . . .
C19 C110 C114 O11 1.1(7) . . . .
C111 C110 C114 O12 1.9(7) . . . .
C19 C110 C114 O12 176.5(5) . . . .
Eu2 O42 C159 O41 3.9(7) 2_666 . . .
Eu2 O42 C159 C410 -174.8(3) 2_666 . . .
C28 C29 C210 C211 0.0(8) . . . .
C28 C29 C210 C214 -177.9(5) . . . .
C29 C210 C211 C212 1.7(9) . . . .
C214 C210 C211 C212 179.5(6) . . . .
C210 C211 C212 C213 -2.0(12) . . . .
C211 C212 C213 C28 0.7(12) . . . .
C29 C28 C213 C212 0.9(11) . . . .
C25 C28 C213 C212 -177.8(7) . . . .
Eu1 O21 C214 O22 22.7(7) . . . .
Eu1 O21 C214 C210 -156.0(3) . . . .
Eu2 O22 C214 O21 44.1(13) . . . .
Eu2 O22 C214 C210 -137.2(8) . . . .
C211 C210 C214 O21 1.4(7) . . . .
C29 C210 C214 O21 179.3(4) . . . .
C211 C210 C214 O22 -177.3(5) . . . .
C29 C210 C214 O22 0.5(7) . . . .
C38 C39 C310 C311 0.4(7) . . . .
C38 C39 C310 C314 -175.8(4) . . . .
C39 C310 C311 C312 1.3(7) . . . .
C314 C310 C311 C312 177.6(5) . . . .
C310 C311 C312 C313 -1.4(8) . . . .
C311 C312 C313 C38 -0.2(8) . . . .
C39 C38 C313 C312 1.9(7) . . . .
C35 C38 C313 C312 -177.6(5) . . . .
Eu2 O32 C314 O31 -6.4(5) . . . .
Eu2 O32 C314 C310 174.1(4) . . . .
Eu2 O31 C314 O32 6.4(5) . . . .
Eu2 O31 C314 C310 -174.1(4) . . . .
C311 C310 C314 O32 166.8(5) . . . .
C39 C310 C314 O32 -17.0(7) . . . .
C311 C310 C314 O31 -12.7(7) . . . .
C39 C310 C314 O31 163.5(5) . . . .
O12 Eu2 C314 O32 168.0(3) . . . .
O41 Eu2 C314 O32 -14.9(3) . . . .
O22 Eu2 C314 O32 -100.7(3) . . . .
O51 Eu2 C314 O32 -113.5(4) . . . .
O42 Eu2 C314 O32 90.7(3) 2_666 . . .
O31 Eu2 C314 O32 -173.6(5) . . . .
O11W Eu2 C314 O32 70.5(4) . . . .
O12 Eu2 C314 O31 -18.3(3) . . . .
O41 Eu2 C314 O31 158.7(3) . . . .
O22 Eu2 C314 O31 72.9(3) . . . .
O51 Eu2 C314 O31 60.1(5) . . . .
O42 Eu2 C314 O31 -95.7(3) 2_666 . . .
O32 Eu2 C314 O31 173.6(5) . . . .
O11W Eu2 C314 O31 -115.9(3) . . . .
C48 C49 C410 C411 4.0(6) . . . .
C48 C49 C410 C159 -174.0(4) . . . .
O41 C159 C410 C411 166.0(4) . . . .
O42 C159 C410 C411 -15.3(6) . . . .
O41 C159 C410 C49 -16.0(6) . . . .
O42 C159 C410 C49 162.7(4) . . . .
C49 C410 C411 C412 -1.0(7) . . . .
C159 C410 C411 C412 177.0(4) . . . .
C410 C411 C412 C413 -2.1(7) . . . .
C411 C412 C413 C48 2.2(8) . . . .
C49 C48 C413 C412 0.7(7) . . . .
C45 C48 C413 C412 -177.6(4) . . . .
C58 C59 C510 C511 -2.9(7) . . . .
C58 C59 C510 C514 173.4(4) . . . .
C59 C510 C511 C512 3.3(8) . . . .
C514 C510 C511 C512 -173.0(5) . . . .
C510 C511 C512 C513 -1.7(8) . . . .
C511 C512 C513 C58 -0.4(9) . . . .
C59 C58 C513 C512 0.8(8) . . . .
C55 C58 C513 C512 -176.6(5) . . . .
Eu2 O51 C514 O52 -1.9(15) . . . .
Eu2 O51 C514 C510 177.1(9) . . . .
Eu1 O52 C514 O51 30.2(9) . . . .
Eu1 O52 C514 C510 -148.9(4) . . . .
C59 C510 C514 O51 -175.7(5) . . . .
C511 C510 C514 O51 0.6(7) . . . .
C59 C510 C514 O52 3.4(7) . . . .
C511 C510 C514 O52 179.7(5) . . . .
