#------------------------------------------------------------------------------
#$Date: 2019-09-25 16:01:09 +0300 (Wed, 25 Sep 2019) $
#$Revision: 218855 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/41/7234163.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7234163
loop_
_publ_author_name
'Makhmudiyarova, Nataliya N.'
'Shangaraev, Kamil R.'
'Dzhemileva, Lilya U.'
'Tyumkina, Tatyana V.'
'Mescheryakova, Ekaterina S.'
'D'yakonov, Vladimir A.'
'Ibragimov, Askhat G.'
'Dzhemilev, Usein M.'
_publ_section_title
;
 New synthesis of tetraoxaspirododecane-diamines and
 tetraoxazaspirobicycloalkanes
;
_journal_issue                   51
_journal_name_full               'RSC Advances'
_journal_page_first              29949
_journal_paper_doi               10.1039/C9RA06372B
_journal_volume                  9
_journal_year                    2019
_chemical_formula_moiety         'C20 H22 F2 N2 O4'
_chemical_formula_sum            'C20 H22 F2 N2 O4'
_chemical_formula_weight         392.40
_chemical_name_systematic
9-N,10-N-bis(2-fluorophenyl)-7,8,11,12-tetraoxaspiro[5.6]dodecane-9,10-diamine
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_audit_creation_date             2018-04-11
_audit_creation_method
;
Olex2 1.2
(compiled 2018.04.03 svn.r3497 for OlexSys, GUI svn.r5486)
;
_audit_update_record
;
2019-03-25 deposited with the CCDC.    2019-09-23 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 99.134(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   18.9061(6)
_cell_length_b                   11.4711(4)
_cell_length_c                   8.7831(3)
_cell_measurement_reflns_used    2196
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.2200
_cell_measurement_theta_min      2.1230
_cell_volume                     1880.67(11)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.1709
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_details
;
#__ type_ start__ end____ width___ exp.time_
  1 omega    1.00   86.00   1.0000    9.0250
omega____ theta____ kappa____ phi______ frames
    -       17.1042   38.0000    0.0000 85

#__ type_ start__ end____ width___ exp.time_
  2 omega   45.00   82.00   1.0000    9.0250
omega____ theta____ kappa____ phi______ frames
    -       17.1042   19.0000  -60.0000 37

#__ type_ start__ end____ width___ exp.time_
  3 omega  -16.00   16.00   1.0000    9.0250
omega____ theta____ kappa____ phi______ frames
    -       17.1042   92.0000   53.0000 32

#__ type_ start__ end____ width___ exp.time_
  4 omega  -21.00   54.00   1.0000    9.0250
omega____ theta____ kappa____ phi______ frames
    -       17.1042  -99.0000 -180.0000 75
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      0.0348733000
_diffrn_orient_matrix_UB_12      0.0042847000
_diffrn_orient_matrix_UB_13      0.0436012000
_diffrn_orient_matrix_UB_21      -0.0021914000
_diffrn_orient_matrix_UB_22      0.0616315000
_diffrn_orient_matrix_UB_23      -0.0042018000
_diffrn_orient_matrix_UB_31      -0.0149653000
_diffrn_orient_matrix_UB_32      0.0010212000
_diffrn_orient_matrix_UB_33      0.0691219000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0159
_diffrn_reflns_av_unetI/netI     0.0320
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.869
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            9078
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.869
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.151
_diffrn_reflns_theta_min         2.084
_diffrn_source                   'Enhance (Mo) X-ray Source'
_diffrn_source_type              'XCalibur E'
_exptl_absorpt_coefficient_mu    0.110
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.59284
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.386
_exptl_crystal_description       prizm
_exptl_crystal_F_000             824.0
_exptl_crystal_recrystallization_method hexane/Et2O
_exptl_crystal_size_max          0.52
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.29
_refine_diff_density_max         0.214
_refine_diff_density_min         -0.177
_refine_diff_density_rms         0.046
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     261
_refine_ls_number_reflns         4395
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.030
_refine_ls_R_factor_all          0.0985
_refine_ls_R_factor_gt           0.0544
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0672P)²+0.4802P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1313
_refine_ls_wR_factor_ref         0.1617
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2719
_reflns_number_total             4395
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9ra06372b2.cif
_cod_data_source_block           iir-288-1
_cod_original_cell_volume        1880.66(11)
_cod_database_code               7234163
_shelxl_version_number           2013-4
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2.a Ternary CH refined with riding coordinates:
 C10(H10), C9(H9)
2.b Secondary CH2 refined with riding coordinates:
 C6(H6A,H6B), C2(H2A,H2B), C5(H5A,H5B), C3(H3A,H3B), C4(H4A,H4B)
2.c Aromatic/amide H refined with riding coordinates:
 C26(H26), C19(H19), C16(H16), C17(H17), C25(H25), C18(H18), C23(H23), C24(H24)
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
O12 O 0.30160(7) 0.60592(12) 0.13077(14) 0.0440(4) Uani 1 1 d .
O7 O 0.21925(7) 0.59431(11) -0.09484(14) 0.0412(3) Uani 1 1 d .
O11 O 0.33354(7) 0.69510(11) 0.04342(15) 0.0433(4) Uani 1 1 d .
O8 O 0.18094(7) 0.68243(11) -0.01813(15) 0.0427(4) Uani 1 1 d .
C1 C 0.26223(10) 0.52798(17) 0.0225(2) 0.0369(4) Uani 1 1 d .
N20 N 0.32905(9) 0.89167(16) -0.0026(2) 0.0455(4) Uani 1 1 d .
F1 F 0.12300(8) 1.08683(12) 0.09048(16) 0.0698(4) Uani 1 1 d .
C6 C 0.31080(11) 0.45363(19) -0.0589(2) 0.0486(5) Uani 1 1 d .
H6A H 0.3476 0.4191 0.0173 0.058 Uiso 1 1 calc R
H6B H 0.3343 0.5030 -0.1253 0.058 Uiso 1 1 calc R
C26 C 0.42837(11) 0.8989(2) 0.2146(2) 0.0478(5) Uani 1 1 d .
H26 H 0.4169 0.8254 0.2482 0.057 Uiso 1 1 calc R
F2 F 0.37087(8) 1.10095(12) -0.09316(17) 0.0742(4) Uani 1 1 d .
C21 C 0.38837(10) 0.94631(17) 0.0831(2) 0.0392(5) Uani 1 1 d .
C10 C 0.29208(10) 0.79987(16) 0.0555(2) 0.0378(4) Uani 1 1 d .
H10 H 0.2891 0.8148 0.1642 0.045 Uiso 1 1 calc R
N13 N 0.17254(10) 0.87810(16) 0.0150(2) 0.0463(4) Uani 1 1 d .
C2 C 0.21789(11) 0.45548(18) 0.1160(2) 0.0457(5) Uani 1 1 d .
H2A H 0.1845 0.5055 0.1586 0.055 Uiso 1 1 calc R
H2B H 0.2490 0.4190 0.2011 0.055 Uiso 1 1 calc R
C9 C 0.21593(10) 0.79235(16) -0.0374(2) 0.0379(4) Uani 1 1 d .
H9 H 0.2179 0.8050 -0.1470 0.045 Uiso 1 1 calc R
C19 C 0.07913(11) 0.8775(2) -0.2138(2) 0.0505(5) Uani 1 1 d .
H19 H 0.0932 0.8040 -0.2425 0.061 Uiso 1 1 calc R
C22 C 0.40887(11) 1.0549(2) 0.0374(3) 0.0501(5) Uani 1 1 d .
C14 C 0.11449(10) 0.92913(17) -0.0805(2) 0.0404(5) Uani 1 1 d .
C15 C 0.08986(11) 1.03715(19) -0.0425(3) 0.0482(5) Uani 1 1 d .
C5 C 0.27090(13) 0.3575(2) -0.1548(2) 0.0563(6) Uani 1 1 d .
H5A H 0.2401 0.3915 -0.2424 0.068 Uiso 1 1 calc R
H5B H 0.3050 0.3070 -0.1941 0.068 Uiso 1 1 calc R
C16 C 0.03443(13) 1.0942(2) -0.1310(3) 0.0621(6) Uani 1 1 d .
H16 H 0.0197 1.1670 -0.1018 0.075 Uiso 1 1 calc R
C17 C 0.00096(13) 1.0420(3) -0.2635(3) 0.0696(7) Uani 1 1 d .
H17 H -0.0367 1.0795 -0.3255 0.083 Uiso 1 1 calc R
C3 C 0.17675(12) 0.36236(19) 0.0161(3) 0.0545(6) Uani 1 1 d .
H3A H 0.1420 0.3993 -0.0623 0.065 Uiso 1 1 calc R
H3B H 0.1508 0.3142 0.0792 0.065 Uiso 1 1 calc R
C4 C 0.22614(13) 0.2860(2) -0.0613(3) 0.0606(6) Uani 1 1 d .
H4A H 0.2575 0.2425 0.0168 0.073 Uiso 1 1 calc R
H4B H 0.1978 0.2303 -0.1283 0.073 Uiso 1 1 calc R
C25 C 0.48501(12) 0.9597(2) 0.2960(3) 0.0610(6) Uani 1 1 d .
H25 H 0.5110 0.9272 0.3845 0.073 Uiso 1 1 calc R
C18 C 0.02327(12) 0.9342(2) -0.3042(3) 0.0621(6) Uani 1 1 d .
H18 H 0.0004 0.8988 -0.3940 0.075 Uiso 1 1 calc R
C23 C 0.46510(13) 1.1159(2) 0.1168(3) 0.0685(7) Uani 1 1 d .
H23 H 0.4773 1.1888 0.0827 0.082 Uiso 1 1 calc R
C24 C 0.50332(13) 1.0674(3) 0.2479(3) 0.0716(8) Uani 1 1 d .
H24 H 0.5415 1.1078 0.3037 0.086 Uiso 1 1 calc R
H20 H 0.3189(12) 0.909(2) -0.094(3) 0.056(7) Uiso 1 1 d .
H13 H 0.1844(13) 0.907(2) 0.103(3) 0.070(8) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C1 O12 O11 107.68(12)
C1 O7 O8 107.55(12)
C10 O11 O12 105.55(12)
C9 O8 O7 106.16(12)
O12 C1 O7 108.93(15)
O12 C1 C6 112.14(15)
O12 C1 C2 104.98(14)
O7 C1 C6 106.11(14)
O7 C1 C2 112.60(15)
C2 C1 C6 112.15(18)
C21 N20 C10 122.94(17)
C1 C6 C5 112.79(17)
C25 C26 C21 120.6(2)
C26 C21 N20 123.93(19)
C22 C21 N20 119.06(18)
C22 C21 C26 117.00(19)
O11 C10 C9 112.70(15)
N20 C10 O11 106.80(15)
N20 C10 C9 109.05(16)
C14 N13 C9 122.63(18)
C1 C2 C3 110.52(16)
O8 C9 C10 113.15(15)
N13 C9 O8 105.69(15)
N13 C9 C10 109.41(16)
C18 C19 C14 120.5(2)
F2 C22 C21 117.39(18)
F2 C22 C23 119.7(2)
C23 C22 C21 122.9(2)
C19 C14 N13 123.7(2)
C15 C14 N13 119.44(19)
C15 C14 C19 116.83(19)
F1 C15 C14 117.14(19)
F1 C15 C16 119.6(2)
C16 C15 C14 123.2(2)
C4 C5 C6 111.42(17)
C15 C16 C17 118.9(2)
C16 C17 C18 119.7(2)
C2 C3 C4 111.74(19)
C5 C4 C3 111.55(19)
C24 C25 C26 120.7(2)
C17 C18 C19 120.9(2)
C22 C23 C24 118.8(2)
C25 C24 C23 119.9(2)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
O12 O11 1.4652(17)
O12 C1 1.426(2)
O7 O8 1.4680(17)
O7 C1 1.427(2)
O11 C10 1.448(2)
O8 C9 1.446(2)
C1 C6 1.514(3)
C1 C2 1.512(3)
N20 C21 1.396(2)
N20 C10 1.404(2)
F1 C15 1.360(2)
C6 C5 1.515(3)
C26 C21 1.387(3)
C26 C25 1.379(3)
F2 C22 1.360(2)
C21 C22 1.383(3)
C10 C9 1.541(3)
N13 C9 1.405(2)
N13 C14 1.400(3)
C2 C3 1.517(3)
C19 C14 1.385(3)
C19 C18 1.379(3)
C22 C23 1.367(3)
C14 C15 1.383(3)
C15 C16 1.368(3)
C5 C4 1.512(3)
C16 C17 1.371(3)
C17 C18 1.373(4)
C3 C4 1.518(3)
C25 C24 1.367(4)
C23 C24 1.376(4)
