#------------------------------------------------------------------------------
#$Date: 2019-11-07 21:26:15 +0200 (Thu, 07 Nov 2019) $
#$Revision: 223509 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/44/7234436.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7234436
loop_
_publ_author_name
'Wang, Juan'
'Yang, Mingfang'
'Sun, Juan'
'Li, Hui'
'Liu, Jinjin'
'Wang, Qinglun'
'Li, Licun'
'Ma, Yue'
'Zhao, Bin'
'Cheng, Peng'
_publ_section_title
;
 Enhancing the energy barrier of dysprosium(iii) single-molecule magnets
 by tuning the magnetic interactions through different N-oxide bridging
 ligands
;
_journal_issue                   41
_journal_name_full               CrystEngComm
_journal_page_first              6219
_journal_paper_doi               10.1039/C9CE01378D
_journal_volume                  21
_journal_year                    2019
_chemical_formula_moiety         'C38 H14 F36 Ho2 N4 O14'
_chemical_formula_sum            'C38 H14 F36 Ho2 N4 O14'
_chemical_formula_weight         1764.39
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2019-03-05 deposited with the CCDC.    2019-09-30 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 104.98(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   20.537(4)
_cell_length_b                   12.827(3)
_cell_length_c                   21.849(4)
_cell_measurement_reflns_used    10156
_cell_measurement_temperature    113
_cell_measurement_theta_max      27.9
_cell_measurement_theta_min      1.9
_cell_volume                     5560(2)
_computing_cell_refinement
;
CrystalClear-SM Expert 2.1 b42 (Rigaku, 2015)
;
_computing_data_collection
;
CrystalClear-SM Expert 2.1 b42 (Rigaku, 2015)
;
_computing_data_reduction
;
CrystalClear-SM Expert 2.1 b42 (Rigaku, 2015)
;
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      113
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Rigaku Pilatus 200K'
_diffrn_measurement_method       'profile data from ω-scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0370
_diffrn_reflns_av_unetI/netI     0.0347
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            27430
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.884
_diffrn_reflns_theta_min         1.891
_exptl_absorpt_coefficient_mu    3.010
_exptl_absorpt_correction_T_max  0.786
_exptl_absorpt_correction_T_min  0.704
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.108
_exptl_crystal_description       block
_exptl_crystal_F_000             3360
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.575
_refine_diff_density_min         -1.209
_refine_diff_density_rms         0.100
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.065
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     424
_refine_ls_number_reflns         6617
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.065
_refine_ls_R_factor_all          0.0312
_refine_ls_R_factor_gt           0.0277
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0275P)²+3.0189P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0596
_refine_ls_wR_factor_ref         0.0611
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6025
_reflns_number_total             6617
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9ce01378d2.cif
_cod_data_source_block           hoopz
_cod_depositor_comments
'Adding full bibliography for 7234434--7234439.cif.'
_cod_database_code               7234436
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Ho1 Ho 0.30833(2) 0.23782(2) 0.09085(2) 0.01926(5) Uani 1 1 d . .
F1 F 0.46046(15) 0.25934(17) 0.31004(11) 0.0703(8) Uani 1 1 d . .
F2 F 0.44429(10) 0.10461(15) 0.33889(8) 0.0461(5) Uani 1 1 d . .
F3 F 0.36391(12) 0.2146(2) 0.32128(10) 0.0640(7) Uani 1 1 d . .
F4 F 0.46373(9) -0.12619(13) 0.17864(8) 0.0395(4) Uani 1 1 d . .
F5 F 0.45768(9) -0.06482(14) 0.08597(8) 0.0431(5) Uani 1 1 d . .
F6 F 0.37068(9) -0.13688(13) 0.10604(9) 0.0457(5) Uani 1 1 d . .
F7 F 0.21677(10) -0.08572(14) 0.14780(10) 0.0532(5) Uani 1 1 d . .
F8 F 0.12200(10) -0.02244(18) 0.09625(11) 0.0649(6) Uani 1 1 d . .
F9 F 0.14664(12) -0.02917(16) 0.19791(11) 0.0672(7) Uani 1 1 d . .
F10 F 0.14997(13) 0.33207(17) 0.25785(11) 0.0721(7) Uani 1 1 d . .
F11 F 0.20225(10) 0.44803(15) 0.21937(10) 0.0561(6) Uani 1 1 d . .
F12 F 0.10772(10) 0.39293(18) 0.16436(11) 0.0676(7) Uani 1 1 d . .
F13 F 0.42221(14) 0.5333(2) 0.20944(12) 0.0926(10) Uani 1 1 d . .
F14 F 0.48995(10) 0.57795(17) 0.15696(10) 0.0595(6) Uani 1 1 d . .
F15 F 0.38755(14) 0.61953(19) 0.12501(16) 0.1110(12) Uani 1 1 d . .
F16 F 0.53094(12) 0.3614(2) -0.00400(13) 0.0869(9) Uani 1 1 d . .
F17 F 0.45170(12) 0.2728(2) -0.06017(11) 0.0716(8) Uani 1 1 d . .
F18 F 0.51662(15) 0.2051(2) 0.01946(13) 0.0962(11) Uani 1 1 d . .
O1 O 0.36245(10) 0.22346(15) 0.19600(9) 0.0281(4) Uani 1 1 d . .
O2 O 0.37039(9) 0.08438(14) 0.10147(8) 0.0235(4) Uani 1 1 d . .
O3 O 0.23872(9) 0.10648(14) 0.11102(9) 0.0280(4) Uani 1 1 d . .
O4 O 0.23204(9) 0.31312(15) 0.13876(9) 0.0278(4) Uani 1 1 d . .
O5 O 0.35737(9) 0.40037(14) 0.11839(9) 0.0260(4) Uani 1 1 d . .
O6 O 0.38951(10) 0.26125(14) 0.03481(10) 0.0261(4) Uani 1 1 d . .
O7 O 0.23945(8) 0.34379(13) 0.00913(8) 0.0221(4) Uani 1 1 d . .
N1 N 0.22768(11) 0.44500(16) 0.01900(11) 0.0244(5) Uani 1 1 d . .
N2 N 0.20436(16) 0.6504(2) 0.03927(13) 0.0472(8) Uani 1 1 d . .
C1 C 0.41592(16) 0.1829(2) 0.30097(14) 0.0351(7) Uani 1 1 d . .
C2 C 0.39424(13) 0.1522(2) 0.23077(13) 0.0254(6) Uani 1 1 d . .
C3 C 0.41276(13) 0.0557(2) 0.21220(13) 0.0248(6) Uani 1 1 d . .
H3 H 0.4341 0.0076 0.2427 0.030 Uiso 1 1 calc R U
C4 C 0.39962(13) 0.0302(2) 0.14813(13) 0.0222(6) Uani 1 1 d . .
C5 C 0.42348(15) -0.0758(2) 0.13060(14) 0.0295(6) Uani 1 1 d . .
C6 C 0.17223(17) -0.0113(3) 0.14969(17) 0.0416(8) Uani 1 1 d . .
C7 C 0.20269(14) 0.0976(2) 0.14966(14) 0.0294(6) Uani 1 1 d . .
C8 C 0.18505(15) 0.1749(2) 0.18585(15) 0.0332(7) Uani 1 1 d . .
H8 H 0.1640 0.1578 0.2175 0.040 Uiso 1 1 calc R U
C9 C 0.19858(14) 0.2786(2) 0.17523(15) 0.0299(6) Uani 1 1 d . .
C10 C 0.16507(17) 0.3632(3) 0.20545(17) 0.0413(8) Uani 1 1 d . .
C11 C 0.42812(18) 0.5446(3) 0.15239(17) 0.0426(8) Uani 1 1 d . .
C12 C 0.41104(14) 0.4430(2) 0.11392(13) 0.0280(6) Uani 1 1 d . .
C13 C 0.45263(14) 0.4114(2) 0.07676(14) 0.0302(6) Uani 1 1 d . .
H13 H 0.4909 0.4502 0.0767 0.036 Uiso 1 1 calc R U
C14 C 0.43811(13) 0.3228(2) 0.03962(13) 0.0257(6) Uani 1 1 d . .
C15 C 0.48515(15) 0.2908(3) -0.00134(16) 0.0348(7) Uani 1 1 d . .
C16 C 0.27102(16) 0.5170(2) 0.00870(14) 0.0315(7) Uani 1 1 d . .
H16 H 0.3087 0.4986 -0.0050 0.038 Uiso 1 1 calc R U
C17 C 0.25719(18) 0.6201(2) 0.01940(17) 0.0444(9) Uani 1 1 d . .
H17 H 0.2866 0.6710 0.0123 0.053 Uiso 1 1 calc R U
C18 C 0.16267(18) 0.5750(3) 0.04807(15) 0.0419(8) Uani 1 1 d . .
H18 H 0.1250 0.5941 0.0617 0.050 Uiso 1 1 calc R U
C19 C 0.17248(15) 0.4706(2) 0.03803(13) 0.0311(7) Uani 1 1 d . .
H19 H 0.1423 0.4201 0.0442 0.037 Uiso 1 1 calc R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ho Ho -0.2175 4.6783 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Ho1 O4 77.80(7) . .
O1 Ho1 O2 73.73(7) . .
O4 Ho1 O2 136.71(7) . .
O1 Ho1 O3 85.07(7) . .
O4 Ho1 O3 72.21(7) . .
O2 Ho1 O3 73.46(7) . .
O1 Ho1 O5 75.33(7) . .
O4 Ho1 O5 78.87(7) . .
O2 Ho1 O5 122.94(7) . .
O3 Ho1 O5 147.90(7) . .
O1 Ho1 O6 108.09(8) . .
O4 Ho1 O6 147.80(7) . .
O2 Ho1 O6 73.33(6) . .
O3 Ho1 O6 138.78(6) . .
O5 Ho1 O6 72.51(6) . .
O1 Ho1 O7 149.37(6) . 7
O4 Ho1 O7 115.52(7) . 7
O2 Ho1 O7 78.78(6) . 7
O3 Ho1 O7 74.26(7) . 7
O5 Ho1 O7 132.57(6) . 7
O6 Ho1 O7 75.92(7) . 7
O1 Ho1 O7 146.64(7) . .
O4 Ho1 O7 76.19(6) . .
O2 Ho1 O7 139.34(6) . .
O3 Ho1 O7 106.21(7) . .
O5 Ho1 O7 79.45(6) . .
O6 Ho1 O7 84.26(7) . .
O7 Ho1 O7 62.85(7) 7 .
C2 O1 Ho1 134.97(18) . .
C4 O2 Ho1 133.41(17) . .
C7 O3 Ho1 133.44(18) . .
C9 O4 Ho1 133.21(19) . .
C12 O5 Ho1 134.42(18) . .
C14 O6 Ho1 134.33(19) . .
N1 O7 Ho1 121.29(14) . 7
N1 O7 Ho1 121.56(14) . .
Ho1 O7 Ho1 117.15(7) 7 .
C16 N1 C19 122.2(2) . .
C16 N1 O7 118.8(2) . .
C19 N1 O7 119.0(2) . .
C17 N2 C18 116.3(3) . .
F1 C1 F3 108.0(3) . .
F1 C1 F2 106.9(3) . .
F3 C1 F2 106.5(3) . .
F1 C1 C2 110.6(3) . .
F3 C1 C2 111.3(3) . .
F2 C1 C2 113.2(2) . .
O1 C2 C3 127.7(3) . .
O1 C2 C1 112.8(2) . .
C3 C2 C1 119.5(2) . .
C2 C3 C4 120.5(2) . .
C2 C3 H3 119.8 . .
C4 C3 H3 119.8 . .
O2 C4 C3 127.9(2) . .
O2 C4 C5 114.1(2) . .
C3 C4 C5 118.0(2) . .
F4 C5 F6 108.0(2) . .
F4 C5 F5 106.8(2) . .
F6 C5 F5 107.0(2) . .
F4 C5 C4 114.2(2) . .
F6 C5 C4 110.1(2) . .
F5 C5 C4 110.4(2) . .
F9 C6 F7 108.7(3) . .
F9 C6 F8 107.5(3) . .
F7 C6 F8 106.0(3) . .
F9 C6 C7 114.1(3) . .
F7 C6 C7 111.7(3) . .
F8 C6 C7 108.5(3) . .
O3 C7 C8 127.3(3) . .
O3 C7 C6 113.1(3) . .
C8 C7 C6 119.3(3) . .
C7 C8 C9 120.0(3) . .
C7 C8 H8 120.0 . .
C9 C8 H8 120.0 . .
O4 C9 C8 127.4(3) . .
O4 C9 C10 113.9(3) . .
C8 C9 C10 118.5(3) . .
F11 C10 F10 107.5(3) . .
F11 C10 F12 106.0(3) . .
F10 C10 F12 107.7(3) . .
F11 C10 C9 112.8(3) . .
F10 C10 C9 113.2(3) . .
F12 C10 C9 109.3(3) . .
F13 C11 F15 108.4(3) . .
F13 C11 F14 107.0(3) . .
F15 C11 F14 106.4(3) . .
F13 C11 C12 111.5(3) . .
F15 C11 C12 110.1(3) . .
F14 C11 C12 113.3(3) . .
O5 C12 C13 127.2(3) . .
O5 C12 C11 114.0(3) . .
C13 C12 C11 118.7(3) . .
C12 C13 C14 120.9(3) . .
C12 C13 H13 119.6 . .
C14 C13 H13 119.6 . .
O6 C14 C13 127.7(3) . .
O6 C14 C15 113.0(3) . .
C13 C14 C15 119.3(3) . .
F18 C15 F17 106.4(3) . .
F18 C15 F16 107.5(3) . .
F17 C15 F16 106.1(3) . .
F18 C15 C14 110.8(3) . .
F17 C15 C14 111.7(3) . .
F16 C15 C14 114.0(3) . .
N1 C16 C17 117.1(3) . .
N1 C16 H16 121.5 . .
C17 C16 H16 121.5 . .
N2 C17 C16 123.8(3) . .
N2 C17 H17 118.1 . .
C16 C17 H17 118.1 . .
N2 C18 C19 123.6(3) . .
N2 C18 H18 118.2 . .
C19 C18 H18 118.2 . .
N1 C19 C18 117.0(3) . .
N1 C19 H19 121.5 . .
C18 C19 H19 121.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ho1 O1 2.286(2) .
Ho1 O4 2.3090(19) .
Ho1 O2 2.3236(18) .
Ho1 O3 2.3241(18) .
Ho1 O5 2.3260(19) .
Ho1 O6 2.329(2) .
Ho1 O7 2.3921(18) 7
Ho1 O7 2.3939(18) .
F1 C1 1.320(4) .
F2 C1 1.336(3) .
F3 C1 1.322(4) .
F4 C5 1.324(3) .
F5 C5 1.348(3) .
F6 C5 1.333(3) .
F7 C6 1.330(4) .
F8 C6 1.351(4) .
F9 C6 1.313(3) .
F10 C10 1.323(4) .
F11 C10 1.319(4) .
F12 C10 1.339(4) .
F13 C11 1.291(4) .
F14 C11 1.319(4) .
F15 C11 1.311(4) .
F16 C15 1.317(4) .
F17 C15 1.312(4) .
F18 C15 1.296(4) .
O1 C2 1.258(3) .
O2 C4 1.252(3) .
O3 C7 1.264(3) .
O4 C9 1.260(3) .
O5 C12 1.257(3) .
O6 C14 1.256(3) .
O7 N1 1.348(3) .
O7 Ho1 2.3922(18) 7
N1 C16 1.342(4) .
N1 C19 1.345(3) .
N2 C17 1.327(4) .
N2 C18 1.338(4) .
C1 C2 1.534(4) .
C2 C3 1.386(4) .
C3 C4 1.394(4) .
C3 H3 0.9300 .
C4 C5 1.527(4) .
C6 C7 1.530(4) .
C7 C8 1.374(4) .
C8 C9 1.390(4) .
C8 H8 0.9300 .
C9 C10 1.524(4) .
C11 C12 1.541(4) .
C12 C13 1.383(4) .
C13 C14 1.383(4) .
C13 H13 0.9300 .
C14 C15 1.533(4) .
C16 C17 1.385(4) .
C16 H16 0.9300 .
C17 H17 0.9300 .
C18 C19 1.381(4) .
C18 H18 0.9300 .
C19 H19 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
Ho1 O7 N1 C16 -92.4(2) 7
Ho1 O7 N1 C16 88.0(3) .
Ho1 O7 N1 C19 86.8(3) 7
Ho1 O7 N1 C19 -92.9(2) .
Ho1 O1 C2 C3 7.4(5) .
Ho1 O1 C2 C1 -175.33(19) .
F1 C1 C2 O1 -65.8(3) .
F3 C1 C2 O1 54.4(3) .
F2 C1 C2 O1 174.3(2) .
F1 C1 C2 C3 111.7(3) .
F3 C1 C2 C3 -128.1(3) .
F2 C1 C2 C3 -8.2(4) .
O1 C2 C3 C4 3.6(4) .
C1 C2 C3 C4 -173.4(3) .
Ho1 O2 C4 C3 -11.1(4) .
Ho1 O2 C4 C5 169.43(17) .
C2 C3 C4 O2 -1.6(4) .
C2 C3 C4 C5 177.9(2) .
O2 C4 C5 F4 169.6(2) .
C3 C4 C5 F4 -10.0(4) .
O2 C4 C5 F6 -68.8(3) .
C3 C4 C5 F6 111.7(3) .
O2 C4 C5 F5 49.2(3) .
C3 C4 C5 F5 -130.4(3) .
Ho1 O3 C7 C8 12.3(5) .
Ho1 O3 C7 C6 -173.11(19) .
F9 C6 C7 O3 166.5(3) .
F7 C6 C7 O3 42.7(4) .
F8 C6 C7 O3 -73.7(3) .
F9 C6 C7 C8 -18.4(4) .
F7 C6 C7 C8 -142.2(3) .
F8 C6 C7 C8 101.3(3) .
O3 C7 C8 C9 9.8(5) .
C6 C7 C8 C9 -164.5(3) .
Ho1 O4 C9 C8 -17.6(5) .
Ho1 O4 C9 C10 168.3(2) .
C7 C8 C9 O4 -7.3(5) .
C7 C8 C9 C10 166.7(3) .
O4 C9 C10 F11 -36.3(4) .
C8 C9 C10 F11 149.0(3) .
O4 C9 C10 F10 -158.6(3) .
C8 C9 C10 F10 26.7(4) .
O4 C9 C10 F12 81.4(3) .
C8 C9 C10 F12 -93.3(3) .
Ho1 O5 C12 C13 16.0(4) .
Ho1 O5 C12 C11 -167.4(2) .
F13 C11 C12 O5 47.3(4) .
F15 C11 C12 O5 -73.0(4) .
F14 C11 C12 O5 168.1(3) .
F13 C11 C12 C13 -135.7(3) .
F15 C11 C12 C13 104.0(4) .
F14 C11 C12 C13 -15.0(4) .
O5 C12 C13 C14 -1.2(5) .
C11 C12 C13 C14 -177.7(3) .
Ho1 O6 C14 C13 -11.3(5) .
Ho1 O6 C14 C15 168.14(19) .
C12 C13 C14 O6 -1.1(5) .
C12 C13 C14 C15 179.5(3) .
O6 C14 C15 F18 -67.6(4) .
C13 C14 C15 F18 112.0(3) .
O6 C14 C15 F17 50.8(4) .
C13 C14 C15 F17 -129.7(3) .
O6 C14 C15 F16 171.0(3) .
C13 C14 C15 F16 -9.5(4) .
C19 N1 C16 C17 0.9(4) .
O7 N1 C16 C17 -180.0(2) .
C18 N2 C17 C16 -1.0(5) .
N1 C16 C17 N2 0.3(5) .
C17 N2 C18 C19 0.4(5) .
C16 N1 C19 C18 -1.4(4) .
O7 N1 C19 C18 179.5(2) .
N2 C18 C19 N1 0.7(5) .
