#------------------------------------------------------------------------------
#$Date: 2019-10-30 12:03:37 +0200 (Wed, 30 Oct 2019) $
#$Revision: 220542 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/48/7234874.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7234874
loop_
_publ_author_name
'Alessia Provino'
'Volodymyr Smetana'
'Durga Paudyal'
'Karl A. Gschneidner, Jr.'
'Anja-Verena Mudring'
'Vitalij K. Pecharsky'
'Pietro Manfrinetti'
'Marina Putti'
_publ_section_title
;
 Gd3Ni2 and Gd3CoxNi2-x: magnetism and unexpected Co/Ni crystallographic
 ordering
;
_journal_name_full               'Journal of Materials Chemistry C'
_journal_page_first              6078
_journal_page_last               6089
_journal_paper_doi               10.1039/C6TC01035K
_journal_volume                  4
_journal_year                    2016
_chemical_formula_sum            'Gd3 Ni2'
_chemical_formula_weight         589.17
_chemical_melting_point          988
_chemical_name_systematic        'Tri gadolinium di nickel'
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 106.44(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.445(3)
_cell_length_b                   3.7270(7)
_cell_length_c                   9.6460(19)
_cell_measurement_reflns_used    900
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.66
_cell_measurement_theta_min      3.16
_cell_volume                     463.60(18)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'Bruker CCD'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0347
_diffrn_reflns_av_sigmaI/netI    0.0518
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       4
_diffrn_reflns_limit_k_min       -4
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            900
_diffrn_reflns_theta_full        26.66
_diffrn_reflns_theta_max         26.66
_diffrn_reflns_theta_min         3.16
_exptl_absorpt_coefficient_mu    50.078
_exptl_absorpt_correction_T_max  0.09
_exptl_absorpt_correction_T_min  0.07
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_crystal_colour            'metallic shiny'
_exptl_crystal_density_diffrn    8.441
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'irregular fragment'
_exptl_crystal_F_000             992
_exptl_crystal_recrystallization_method 'Peritectic formation'
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.925
_refine_diff_density_min         -2.815
_refine_diff_density_rms         0.416
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_matrix_type           full
_refine_ls_number_parameters     31
_refine_ls_number_reflns         527
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0619
_refine_ls_R_factor_gt           0.0379
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0300P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0633
_refine_ls_wR_factor_ref         0.0685
_reflns_number_gt                400
_reflns_number_total             527
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            J-Mater-Chem-C-2016-4-6078.cif
_cod_data_source_block           mnf1
_cod_original_cell_volume        463.60(16)
_cod_original_sg_symbol_H-M      C2/m
_cod_database_code               7234874
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Gd1 Gd 0.36797(9) 0.0000 0.00179(11) 0.0145(3) Uani 1 2 d S . .
Gd2 Gd 0.35598(9) 0.0000 -0.37046(12) 0.0152(3) Uani 1 2 d S . .
Gd3 Gd 0.40290(10) -0.5000 0.32720(12) 0.0155(3) Uani 1 2 d S . .
Ni4 Ni 0.5358(3) -0.5000 0.1432(3) 0.0193(6) Uani 1 2 d S . .
Ni5 Ni 0.2423(3) 0.0000 0.2268(3) 0.0204(7) Uani 1 2 d S . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Gd Gd -0.1653 3.9035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ni4 Gd1 Ni4 81.65(9) 5_655 5_645
Ni4 Gd1 Ni5 104.40(9) 5_655 7_545
Ni4 Gd1 Ni5 54.67(8) 5_645 7_545
Ni4 Gd1 Ni5 54.67(8) 5_655 7
Ni4 Gd1 Ni5 104.40(9) 5_645 7
Ni5 Gd1 Ni5 78.46(9) 7_545 7
Ni4 Gd1 Ni4 54.49(10) 5_655 1_565
Ni4 Gd1 Ni4 104.24(6) 5_645 1_565
Ni5 Gd1 Ni4 154.64(9) 7_545 1_565
Ni5 Gd1 Ni4 95.95(7) 7 1_565
Ni4 Gd1 Ni4 104.24(6) 5_655 .
Ni4 Gd1 Ni4 54.49(10) 5_645 .
Ni5 Gd1 Ni4 95.95(7) 7_545 .
Ni5 Gd1 Ni4 154.64(9) 7 .
Ni4 Gd1 Ni4 78.46(9) 1_565 .
Ni4 Gd1 Ni5 139.04(4) 5_655 .
Ni4 Gd1 Ni5 139.04(4) 5_645 .
Ni5 Gd1 Ni5 105.36(8) 7_545 .
Ni5 Gd1 Ni5 105.36(8) 7 .
Ni4 Gd1 Ni5 99.98(8) 1_565 .
Ni4 Gd1 Ni5 99.98(8) . .
Ni4 Gd1 Gd2 53.17(6) 5_655 .
Ni4 Gd1 Gd2 53.17(6) 5_645 .
Ni5 Gd1 Gd2 51.23(6) 7_545 .
Ni5 Gd1 Gd2 51.23(6) 7 .
Ni4 Gd1 Gd2 106.13(7) 1_565 .
Ni4 Gd1 Gd2 106.13(7) . .
Ni5 Gd1 Gd2 146.04(7) . .
Ni4 Gd1 Gd1 53.34(6) 5_655 5_655
Ni4 Gd1 Gd1 53.34(6) 5_645 5_655
Ni5 Gd1 Gd1 106.55(7) 7_545 5_655
Ni5 Gd1 Gd1 106.55(7) 7 5_655
Ni4 Gd1 Gd1 50.90(6) 1_565 5_655
Ni4 Gd1 Gd1 50.90(6) . 5_655
Ni5 Gd1 Gd1 138.43(8) . 5_655
Gd2 Gd1 Gd1 75.53(5) . 5_655
Ni4 Gd1 Gd3 97.19(5) 5_655 1_565
Ni4 Gd1 Gd3 143.96(8) 5_645 1_565
Ni5 Gd1 Gd3 154.46(8) 7_545 1_565
Ni5 Gd1 Gd3 103.96(5) 7 1_565
Ni4 Gd1 Gd3 50.89(7) 1_565 1_565
Ni4 Gd1 Gd3 91.73(6) . 1_565
Ni5 Gd1 Gd3 49.21(5) . 1_565
Gd2 Gd1 Gd3 147.976(16) . 1_565
Gd1 Gd1 Gd3 97.20(5) 5_655 1_565
Ni4 Gd1 Gd3 143.96(8) 5_655 .
Ni4 Gd1 Gd3 97.19(5) 5_645 .
Ni5 Gd1 Gd3 103.96(5) 7_545 .
Ni5 Gd1 Gd3 154.46(8) 7 .
Ni4 Gd1 Gd3 91.73(6) 1_565 .
Ni4 Gd1 Gd3 50.89(7) . .
Ni5 Gd1 Gd3 49.21(5) . .
Gd2 Gd1 Gd3 147.976(16) . .
Gd1 Gd1 Gd3 97.20(5) 5_655 .
Gd3 Gd1 Gd3 63.02(3) 1_565 .
Ni4 Gd1 Gd1 146.96(8) 5_655 7_545
Ni4 Gd1 Gd1 100.05(6) 5_645 7_545
Ni5 Gd1 Gd1 54.64(7) 7_545 7_545
Ni5 Gd1 Gd1 93.64(7) 7 7_545
Ni4 Gd1 Gd1 150.68(7) 1_565 7_545
Ni4 Gd1 Gd1 103.29(5) . 7_545
Ni5 Gd1 Gd1 50.71(6) . 7_545
Gd2 Gd1 Gd1 101.47(5) . 7_545
Gd1 Gd1 Gd1 149.47(2) 5_655 7_545
Gd3 Gd1 Gd1 99.89(5) 1_565 7_545
Gd3 Gd1 Gd1 68.97(4) . 7_545
Ni5 Gd2 Ni5 81.33(9) 7 7_545
Ni5 Gd2 Ni4 54.75(9) 7 5_655
Ni5 Gd2 Ni4 104.56(9) 7_545 5_655
Ni5 Gd2 Ni4 104.56(9) 7 5_645
Ni5 Gd2 Ni4 54.75(9) 7_545 5_645
Ni4 Gd2 Ni4 78.96(8) 5_655 5_645
Ni5 Gd2 Gd1 53.44(6) 7 .
Ni5 Gd2 Gd1 53.44(6) 7_545 .
Ni4 Gd2 Gd1 51.12(6) 5_655 .
Ni4 Gd2 Gd1 51.12(6) 5_645 .
Ni5 Gd2 Gd3 49.68(6) 7 7_545
Ni5 Gd2 Gd3 49.68(6) 7_545 7_545
Ni4 Gd2 Gd3 101.75(7) 5_655 7_545
Ni4 Gd2 Gd3 101.75(7) 5_645 7_545
Gd1 Gd2 Gd3 69.71(4) . 7_545
Ni5 Gd2 Gd3 97.41(6) 7 5_655
Ni5 Gd2 Gd3 142.43(8) 7_545 5_655
Ni4 Gd2 Gd3 49.81(7) 5_655 5_655
Ni4 Gd2 Gd3 90.13(7) 5_645 5_655
Gd1 Gd2 Gd3 95.71(4) . 5_655
Gd3 Gd2 Gd3 146.75(2) 7_545 5_655
Ni5 Gd2 Gd3 142.43(8) 7 5_645
Ni5 Gd2 Gd3 97.41(6) 7_545 5_645
Ni4 Gd2 Gd3 90.13(7) 5_655 5_645
Ni4 Gd2 Gd3 49.81(7) 5_645 5_645
Gd1 Gd2 Gd3 95.71(4) . 5_645
Gd3 Gd2 Gd3 146.75(2) 7_545 5_645
Gd3 Gd2 Gd3 61.23(3) 5_655 5_645
Ni5 Gd2 Gd3 157.64(7) 7 1_554
Ni5 Gd2 Gd3 105.17(5) 7_545 1_554
Ni4 Gd2 Gd3 139.30(8) 5_655 1_554
Ni4 Gd2 Gd3 96.38(5) 5_645 1_554
Gd1 Gd2 Gd3 146.82(2) . 1_554
Gd3 Gd2 Gd3 118.65(4) 7_545 1_554
Gd3 Gd2 Gd3 90.19(4) 5_655 1_554
Gd3 Gd2 Gd3 59.01(4) 5_645 1_554
Ni5 Gd2 Gd3 105.17(5) 7 1_564
Ni5 Gd2 Gd3 157.64(7) 7_545 1_564
Ni4 Gd2 Gd3 96.38(5) 5_655 1_564
Ni4 Gd2 Gd3 139.30(8) 5_645 1_564
Gd1 Gd2 Gd3 146.82(2) . 1_564
Gd3 Gd2 Gd3 118.65(4) 7_545 1_564
Gd3 Gd2 Gd3 59.01(4) 5_655 1_564
Gd3 Gd2 Gd3 90.19(4) 5_645 1_564
Gd3 Gd2 Gd3 61.16(3) 1_554 1_564
Ni5 Gd2 Gd2 106.32(8) 7 7_544
Ni5 Gd2 Gd2 68.13(7) 7_545 7_544
Ni4 Gd2 Gd2 161.04(8) 5_655 7_544
Ni4 Gd2 Gd2 107.94(5) 5_645 7_544
Gd1 Gd2 Gd2 119.15(5) . 7_544
Gd3 Gd2 Gd2 59.88(4) 7_545 7_544
Gd3 Gd2 Gd2 144.90(5) 5_655 7_544
Gd3 Gd2 Gd2 107.90(3) 5_645 7_544
Gd3 Gd2 Gd2 58.77(3) 1_554 7_544
Gd3 Gd2 Gd2 89.53(4) 1_564 7_544
Ni5 Gd2 Gd2 68.13(7) 7 7_554
Ni5 Gd2 Gd2 106.32(8) 7_545 7_554
Ni4 Gd2 Gd2 107.94(5) 5_655 7_554
Ni4 Gd2 Gd2 161.04(8) 5_645 7_554
Gd1 Gd2 Gd2 119.15(5) . 7_554
Gd3 Gd2 Gd2 59.88(4) 7_545 7_554
Gd3 Gd2 Gd2 107.90(3) 5_655 7_554
Gd3 Gd2 Gd2 144.90(5) 5_645 7_554
Gd3 Gd2 Gd2 89.53(4) 1_554 7_554
Gd3 Gd2 Gd2 58.77(3) 1_564 7_554
Gd2 Gd2 Gd2 60.20(4) 7_544 7_554
Ni5 Gd3 Ni5 83.13(10) 1_545 .
Ni5 Gd3 Ni4 109.94(8) 1_545 .
Ni5 Gd3 Ni4 109.94(8) . .
Ni5 Gd3 Gd1 56.82(7) 1_545 1_545
Ni5 Gd3 Gd1 98.41(7) . 1_545
Ni4 Gd3 Gd1 53.26(5) . 1_545
Ni5 Gd3 Gd1 98.41(7) 1_545 .
Ni5 Gd3 Gd1 56.82(7) . .
Ni4 Gd3 Gd1 53.26(5) . .
Gd1 Gd3 Gd1 63.02(3) 1_545 .
Ni5 Gd3 Gd3 127.13(7) 1_545 5_646
Ni5 Gd3 Gd3 127.13(7) . 5_646
Ni4 Gd3 Gd3 99.10(8) . 5_646
Gd1 Gd3 Gd3 133.98(4) 1_545 5_646
Gd1 Gd3 Gd3 133.98(4) . 5_646
Ni5 Gd3 Gd2 50.92(6) 1_545 7_545
Ni5 Gd3 Gd2 50.92(6) . 7_545
Ni4 Gd3 Gd2 149.71(8) . 7_545
Gd1 Gd3 Gd2 102.13(4) 1_545 7_545
Gd1 Gd3 Gd2 102.13(4) . 7_545
Gd3 Gd3 Gd2 111.20(5) 5_646 7_545
Ni5 Gd3 Gd2 161.25(7) 1_545 5_655
Ni5 Gd3 Gd2 105.73(5) . 5_655
Ni4 Gd3 Gd2 51.71(6) . 5_655
Gd1 Gd3 Gd2 104.97(4) 1_545 5_655
Gd1 Gd3 Gd2 74.09(4) . 5_655
Gd3 Gd3 Gd2 60.55(4) 5_646 5_655
Gd2 Gd3 Gd2 146.75(2) 7_545 5_655
Ni5 Gd3 Gd2 105.73(5) 1_545 5_645
Ni5 Gd3 Gd2 161.25(7) . 5_645
Ni4 Gd3 Gd2 51.71(6) . 5_645
Gd1 Gd3 Gd2 74.09(4) 1_545 5_645
Gd1 Gd3 Gd2 104.97(4) . 5_645
Gd3 Gd3 Gd2 60.55(4) 5_646 5_645
Gd2 Gd3 Gd2 146.75(2) 7_545 5_645
Gd2 Gd3 Gd2 61.23(3) 5_655 5_645
Ni5 Gd3 Gd2 108.87(7) 1_545 1_556
Ni5 Gd3 Gd2 69.41(7) . 1_556
Ni4 Gd3 Gd2 140.78(5) . 1_556
Gd1 Gd3 Gd2 163.22(5) 1_545 1_556
Gd1 Gd3 Gd2 115.19(2) . 1_556
Gd3 Gd3 Gd2 60.45(3) 5_646 1_556
Gd2 Gd3 Gd2 61.35(4) 7_545 1_556
Gd2 Gd3 Gd2 89.81(4) 5_655 1_556
Gd2 Gd3 Gd2 120.99(4) 5_645 1_556
Ni5 Gd3 Gd2 69.41(7) 1_545 1_546
Ni5 Gd3 Gd2 108.87(7) . 1_546
Ni4 Gd3 Gd2 140.78(5) . 1_546
Gd1 Gd3 Gd2 115.19(2) 1_545 1_546
Gd1 Gd3 Gd2 163.22(5) . 1_546
Gd3 Gd3 Gd2 60.45(3) 5_646 1_546
Gd2 Gd3 Gd2 61.35(4) 7_545 1_546
Gd2 Gd3 Gd2 120.99(4) 5_655 1_546
Gd2 Gd3 Gd2 89.81(4) 5_645 1_546
Gd2 Gd3 Gd2 61.16(3) 1_556 1_546
Ni5 Gd3 Gd3 131.57(5) 1_545 1_565
Ni5 Gd3 Gd3 48.43(5) . 1_565
Ni4 Gd3 Gd3 90.0 . 1_565
Gd1 Gd3 Gd3 121.511(15) 1_545 1_565
Gd1 Gd3 Gd3 58.489(15) . 1_565
Gd3 Gd3 Gd3 90.0 5_646 1_565
Gd2 Gd3 Gd3 90.0 7_545 1_565
Gd2 Gd3 Gd3 59.386(16) 5_655 1_565
Gd2 Gd3 Gd3 120.614(16) 5_645 1_565
Gd2 Gd3 Gd3 59.420(14) 1_556 1_565
Gd2 Gd3 Gd3 120.580(14) 1_546 1_565
Ni4 Ni4 Ni5 110.79(19) 5_645 3_545
Ni4 Ni4 Gd1 64.60(10) 5_645 5_655
Ni5 Ni4 Gd1 64.50(8) 3_545 5_655
Ni4 Ni4 Gd1 64.60(10) 5_645 5_645
Ni5 Ni4 Gd1 64.50(8) 3_545 5_645
Gd1 Ni4 Gd1 81.65(9) 5_655 5_645
Ni4 Ni4 Gd3 122.73(19) 5_645 .
Ni5 Ni4 Gd3 126.48(13) 3_545 .
Gd1 Ni4 Gd3 139.14(5) 5_655 .
Gd1 Ni4 Gd3 139.14(5) 5_645 .
Ni4 Ni4 Gd2 137.32(8) 5_645 5_655
Ni5 Ni4 Gd2 61.26(8) 3_545 5_655
Gd1 Ni4 Gd2 75.71(6) 5_655 5_655
Gd1 Ni4 Gd2 125.76(12) 5_645 5_655
Gd3 Ni4 Gd2 78.48(7) . 5_655
Ni4 Ni4 Gd2 137.32(8) 5_645 5_645
Ni5 Ni4 Gd2 61.26(8) 3_545 5_645
Gd1 Ni4 Gd2 125.76(12) 5_655 5_645
Gd1 Ni4 Gd2 75.71(6) 5_645 5_645
Gd3 Ni4 Gd2 78.48(7) . 5_645
Gd2 Ni4 Gd2 78.96(8) 5_655 5_645
Ni4 Ni4 Gd1 60.91(10) 5_645 1_545
Ni5 Ni4 Gd1 137.42(6) 3_545 1_545
Gd1 Ni4 Gd1 125.51(10) 5_655 1_545
Gd1 Ni4 Gd1 75.76(6) 5_645 1_545
Gd3 Ni4 Gd1 75.85(8) . 1_545
Gd2 Ni4 Gd1 154.33(12) 5_655 1_545
Gd2 Ni4 Gd1 95.57(5) 5_645 1_545
Ni4 Ni4 Gd1 60.91(10) 5_645 .
Ni5 Ni4 Gd1 137.42(6) 3_545 .
Gd1 Ni4 Gd1 75.76(6) 5_655 .
Gd1 Ni4 Gd1 125.51(10) 5_645 .
Gd3 Ni4 Gd1 75.85(8) . .
Gd2 Ni4 Gd1 95.57(5) 5_655 .
Gd2 Ni4 Gd1 154.33(12) 5_645 .
Gd1 Ni4 Gd1 78.46(9) 1_545 .
Ni4 Ni5 Gd3 137.58(5) 3_455 1_565
Ni4 Ni5 Gd3 137.58(5) 3_455 .
Gd3 Ni5 Gd3 83.13(10) 1_565 .
Ni4 Ni5 Gd2 63.99(8) 3_455 7
Gd3 Ni5 Gd2 79.40(5) 1_565 7
Gd3 Ni5 Gd2 132.91(12) . 7
Ni4 Ni5 Gd2 63.99(8) 3_455 7_545
Gd3 Ni5 Gd2 132.91(12) 1_565 7_545
Gd3 Ni5 Gd2 79.40(5) . 7_545
Gd2 Ni5 Gd2 81.33(9) 7 7_545
Ni4 Ni5 Gd1 60.83(8) 3_455 7_545
Gd3 Ni5 Gd1 148.51(13) 1_565 7_545
Gd3 Ni5 Gd1 90.77(5) . 7_545
Gd2 Ni5 Gd1 124.82(12) 7 7_545
Gd2 Ni5 Gd1 75.33(6) 7_545 7_545
Ni4 Ni5 Gd1 60.83(8) 3_455 7
Gd3 Ni5 Gd1 90.77(5) 1_565 7
Gd3 Ni5 Gd1 148.51(13) . 7
Gd2 Ni5 Gd1 75.33(6) 7 7
Gd2 Ni5 Gd1 124.82(12) 7_545 7
Gd1 Ni5 Gd1 78.46(9) 7_545 7
Ni4 Ni5 Gd1 121.02(13) 3_455 .
Gd3 Ni5 Gd1 73.97(8) 1_565 .
Gd3 Ni5 Gd1 73.97(8) . .
Gd2 Ni5 Gd1 139.15(5) 7 .
Gd2 Ni5 Gd1 139.15(5) 7_545 .
Gd1 Ni5 Gd1 74.64(8) 7_545 .
Gd1 Ni5 Gd1 74.64(8) 7 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Gd1 Ni4 2.851(3) 5_655
Gd1 Ni4 2.851(3) 5_645
Gd1 Ni5 2.946(3) 7_545
Gd1 Ni5 2.946(3) 7
Gd1 Ni4 2.947(3) 1_565
Gd1 Ni4 2.947(3) .
Gd1 Ni5 3.105(3) .
Gd1 Gd2 3.5484(16) .
Gd1 Gd1 3.560(3) 5_655
Gd1 Gd3 3.5654(14) 1_565
Gd1 Gd3 3.5654(14) .
Gd1 Gd1 3.671(2) 7_545
Gd2 Ni5 2.860(3) 7
Gd2 Ni5 2.860(3) 7_545
Gd2 Ni4 2.931(3) 5_655
Gd2 Ni4 2.931(3) 5_645
Gd2 Gd3 3.621(2) 7_545
Gd2 Gd3 3.6593(17) 5_655
Gd2 Gd3 3.6593(17) 5_645
Gd2 Gd3 3.6629(14) 1_554
Gd2 Gd3 3.6629(14) 1_564
Gd2 Gd2 3.716(2) 7_544
Gd2 Gd2 3.716(2) 7_554
Gd3 Ni5 2.809(3) 1_545
Gd3 Ni5 2.809(3) .
Gd3 Ni4 2.853(3) .
Gd3 Gd1 3.5654(14) 1_545
Gd3 Gd3 3.606(3) 5_646
Gd3 Gd2 3.621(2) 7_545
Gd3 Gd2 3.6593(17) 5_655
Gd3 Gd2 3.6593(17) 5_645
Gd3 Gd2 3.6629(14) 1_556
Gd3 Gd2 3.6629(14) 1_546
Gd3 Gd3 3.7270(7) 1_565
Ni4 Ni4 2.655(6) 5_645
Ni4 Ni5 2.663(4) 3_545
Ni4 Gd1 2.851(3) 5_655
Ni4 Gd1 2.851(3) 5_645
Ni4 Gd2 2.931(3) 5_655
Ni4 Gd2 2.931(3) 5_645
Ni4 Gd1 2.947(3) 1_545
Ni5 Ni4 2.663(4) 3_455
Ni5 Gd3 2.809(3) 1_565
Ni5 Gd2 2.860(3) 7
Ni5 Gd2 2.860(3) 7_545
Ni5 Gd1 2.946(3) 7_545
Ni5 Gd1 2.946(3) 7
