#------------------------------------------------------------------------------
#$Date: 2019-11-14 12:43:48 +0200 (Thu, 14 Nov 2019) $
#$Revision: 227777 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/50/7235068.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7235068
loop_
_publ_author_name
'Csaba Jobbagy'
'Peter Baranyai'
'Gabor Marsi'
'Barbara Racz'
'Liang Li'
'Pance Naumov'
'Andrea Deak'
_publ_section_title
;
 Novel gold(i) diphosphine-based dimers with aurophilicity triggered
 multistimuli light-emitting properties
;
_journal_name_full               'Journal of Materials Chemistry C'
_journal_page_first              10253
_journal_page_last               10264
_journal_paper_doi               10.1039/C6TC01427E
_journal_volume                  4
_journal_year                    2016
_chemical_formula_moiety
'C72 H56 Au2 O2 P4, 2(N O3), 3.557(C H2 Cl2), H2 O'
_chemical_formula_sum            'C75.56 H65.11 Au2 Cl7.11 N2 O9 P4'
_chemical_formula_weight         1915.11
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_cell_angle_alpha                91.7440(10)
_cell_angle_beta                 101.6430(10)
_cell_angle_gamma                112.0480(10)
_cell_formula_units_Z            2
_cell_length_a                   12.5913(4)
_cell_length_b                   13.4958(4)
_cell_length_c                   23.9939(9)
_cell_measurement_reflns_used    110441
_cell_measurement_temperature    98(2)
_cell_measurement_theta_max      26.39
_cell_measurement_theta_min      3.02
_cell_volume                     3675.9(2)
_computing_cell_refinement       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_collection       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_molecular_graphics    'PLATON (Spek, 2014)'
_computing_publication_material  'WinGX (Farrugia, 2014), PLATON (Spek, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SIR92 (Altomare et al., 1994)'
_diffrn_ambient_temperature      98(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'R Axis Rapid (Rigaku/MSC, 2005)'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0486
_diffrn_reflns_av_unetI/netI     0.0795
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            132875
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.373
_diffrn_reflns_theta_min         3.022
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    4.391
_exptl_absorpt_correction_T_max  0.196
_exptl_absorpt_correction_T_min  0.0952
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.730
_exptl_crystal_description       prism
_exptl_crystal_F_000             1887
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.500
_exptl_crystal_size_min          0.250
_refine_diff_density_max         2.502
_refine_diff_density_min         -1.980
_refine_diff_density_rms         0.160
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.176
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     905
_refine_ls_number_reflns         14938
_refine_ls_number_restraints     10
_refine_ls_restrained_S_all      1.185
_refine_ls_R_factor_all          0.0644
_refine_ls_R_factor_gt           0.0514
_refine_ls_shift/su_max          1.208
_refine_ls_shift/su_mean         0.009
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+27.8092P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1185
_refine_ls_wR_factor_ref         0.1217
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                12114
_reflns_number_total             14938
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            1000006.cif
_cod_data_source_block           PCOD1000006
_cod_database_code               7235068
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.217
_shelx_estimated_absorpt_t_max   0.407
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.54036(3) 0.67561(2) 0.76244(2) 0.01993(9) Uani 1 1 d . . . . .
Au2 Au 0.27143(3) 0.51437(2) 0.75684(2) 0.01910(8) Uani 1 1 d . . . . .
P1 P 0.58315(19) 0.58328(16) 0.69233(8) 0.0178(4) Uani 1 1 d . . . . .
P2 P 0.31481(18) 0.39082(16) 0.81241(8) 0.0175(4) Uani 1 1 d . . . . .
P3 P 0.56569(19) 0.79963(16) 0.83881(8) 0.0192(4) Uani 1 1 d . . . . .
P4 P 0.19295(18) 0.61977(15) 0.70161(8) 0.0173(4) Uani 1 1 d . . . . .
O1 O 0.3905(5) 0.3882(4) 0.7052(2) 0.0206(12) Uani 1 1 d . . . . .
O2 O 0.3145(5) 0.7306(4) 0.8164(2) 0.0229(12) Uani 1 1 d . . . . .
C1 C 0.4618(7) 0.4985(6) 0.6354(3) 0.0182(16) Uani 1 1 d . . . . .
C2 C 0.4482(7) 0.5234(6) 0.5787(3) 0.0207(17) Uani 1 1 d . . . . .
H1 H 0.5093 0.5810 0.5681 0.025 Uiso 1 1 calc R U . . .
C3 C 0.3459(8) 0.4642(7) 0.5381(3) 0.0268(19) Uani 1 1 d . . . . .
H3 H 0.3382 0.4800 0.4995 0.032 Uiso 1 1 calc R U . . .
C4 C 0.2557(8) 0.3827(7) 0.5533(3) 0.0281(19) Uani 1 1 d . . . . .
H4 H 0.1846 0.3445 0.5256 0.034 Uiso 1 1 calc R U . . .
C5 C 0.2682(8) 0.3561(7) 0.6089(3) 0.0263(19) Uani 1 1 d . . . . .
H5 H 0.2056 0.2996 0.6192 0.032 Uiso 1 1 calc R U . . .
C6 C 0.3701(7) 0.4108(6) 0.6489(3) 0.0190(16) Uani 1 1 d . . . . .
C7 C 0.3352(7) 0.2827(6) 0.7178(3) 0.0200(17) Uani 1 1 d . . . . .
C8 C 0.2965(7) 0.2716(6) 0.7677(3) 0.0219(17) Uani 1 1 d . . . . .
C9 C 0.2450(9) 0.1665(7) 0.7821(4) 0.033(2) Uani 1 1 d . . . . .
H9 H 0.2179 0.1557 0.8165 0.039 Uiso 1 1 calc R U . . .
C10 C 0.2335(10) 0.0792(7) 0.7468(4) 0.041(2) Uani 1 1 d . . . . .
H10 H 0.1980 0.0086 0.7566 0.049 Uiso 1 1 calc R U . . .
C11 C 0.2737(10) 0.0941(7) 0.6968(4) 0.038(2) Uani 1 1 d . . . . .
H11 H 0.2642 0.0333 0.6723 0.046 Uiso 1 1 calc R U . . .
C12 C 0.3270(8) 0.1956(6) 0.6823(3) 0.028(2) Uani 1 1 d . . . . .
H12 H 0.3575 0.2061 0.6488 0.034 Uiso 1 1 calc R U . . .
C13 C 0.4760(7) 0.7560(6) 0.8912(3) 0.0197(16) Uani 1 1 d . . . . .
C14 C 0.5258(8) 0.7554(6) 0.9489(3) 0.0250(19) Uani 1 1 d . . . . .
H14 H 0.6090 0.7825 0.9622 0.030 Uiso 1 1 calc R U . . .
C15 C 0.4552(8) 0.7160(7) 0.9863(3) 0.028(2) Uani 1 1 d . . . . .
H15 H 0.4893 0.7164 1.0255 0.033 Uiso 1 1 calc R U . . .
C16 C 0.3336(8) 0.6755(7) 0.9667(3) 0.0262(19) Uani 1 1 d . . . . .
H16 H 0.2845 0.6459 0.9924 0.031 Uiso 1 1 calc R U . . .
C17 C 0.2826(8) 0.6780(7) 0.9093(3) 0.0247(18) Uani 1 1 d . . . . .
H17 H 0.1995 0.6496 0.8956 0.030 Uiso 1 1 calc R U . . .
C18 C 0.3558(7) 0.7226(6) 0.8736(3) 0.0192(16) Uani 1 1 d . . . . .
C19 C 0.2097(7) 0.7456(6) 0.7988(3) 0.0178(16) Uani 1 1 d . . . . .
C20 C 0.1440(7) 0.6998(6) 0.7450(3) 0.0187(16) Uani 1 1 d . . . . .
C21 C 0.0446(7) 0.7199(7) 0.7231(3) 0.0241(18) Uani 1 1 d . . . . .
H21 H -0.0009 0.6892 0.6856 0.029 Uiso 1 1 calc R U . . .
C22 C 0.0112(8) 0.7844(7) 0.7555(3) 0.0258(19) Uani 1 1 d . . . . .
H22 H -0.0581 0.7966 0.7407 0.031 Uiso 1 1 calc R U . . .
C23 C 0.0797(8) 0.8315(6) 0.8101(3) 0.0242(18) Uani 1 1 d . . . . .
H23 H 0.0579 0.8774 0.8320 0.029 Uiso 1 1 calc R U . . .
C24 C 0.1788(8) 0.8121(6) 0.8324(3) 0.0242(18) Uani 1 1 d . . . . .
H24 H 0.2251 0.8433 0.8698 0.029 Uiso 1 1 calc R U . . .
C1A C 0.6798(7) 0.6781(6) 0.6548(3) 0.0205(17) Uani 1 1 d . . . . .
C2A C 0.6802(9) 0.7816(7) 0.6502(3) 0.031(2) Uani 1 1 d . . . . .
H2A H 0.6312 0.8041 0.6684 0.037 Uiso 1 1 calc R U . . .
C3A C 0.7518(10) 0.8512(7) 0.6193(4) 0.044(3) Uani 1 1 d . . . . .
H3A H 0.7500 0.9204 0.6155 0.052 Uiso 1 1 calc R U . . .
C4A C 0.8257(9) 0.8204(8) 0.5941(4) 0.039(2) Uani 1 1 d . . . . .
H4A H 0.8757 0.8689 0.5736 0.047 Uiso 1 1 calc R U . . .
C5A C 0.8269(8) 0.7184(7) 0.5989(3) 0.0294(19) Uani 1 1 d . . . . .
H5A H 0.8777 0.6972 0.5815 0.035 Uiso 1 1 calc R U . . .
C6A C 0.7542(7) 0.6473(7) 0.6289(3) 0.0238(18) Uani 1 1 d . . . . .
H6A H 0.7551 0.5776 0.6318 0.029 Uiso 1 1 calc R U . . .
C1B C 0.6686(7) 0.5075(6) 0.7231(3) 0.0202(17) Uani 1 1 d . . . . .
C2B C 0.7628(8) 0.5586(7) 0.7692(3) 0.0259(19) Uani 1 1 d . . . . .
H2B H 0.7782 0.6293 0.7850 0.031 Uiso 1 1 calc R U . . .
C3B C 0.8348(8) 0.5060(7) 0.7921(4) 0.033(2) Uani 1 1 d . . . . .
H3B H 0.9007 0.5416 0.8231 0.040 Uiso 1 1 calc R U . . .
C4B C 0.8106(9) 0.4018(8) 0.7699(4) 0.039(2) Uani 1 1 d . . . . .
H4B H 0.8584 0.3652 0.7863 0.046 Uiso 1 1 calc R U . . .
C5B C 0.7180(9) 0.3518(8) 0.7243(4) 0.039(2) Uani 1 1 d . . . . .
H5B H 0.7025 0.2808 0.7089 0.047 Uiso 1 1 calc R U . . .
C6B C 0.6453(8) 0.4039(6) 0.6998(3) 0.0259(19) Uani 1 1 d . . . . .
H6B H 0.5813 0.3690 0.6678 0.031 Uiso 1 1 calc R U . . .
C1C C 0.2187(7) 0.3483(6) 0.8619(3) 0.0186(16) Uani 1 1 d . . . . .
C2C C 0.2369(8) 0.2827(6) 0.9042(3) 0.0232(18) Uani 1 1 d . . . . .
H2C H 0.2995 0.2588 0.9065 0.028 Uiso 1 1 calc R U . . .
C3C C 0.1662(8) 0.2530(7) 0.9421(3) 0.029(2) Uani 1 1 d . . . . .
H3C H 0.1792 0.2084 0.9703 0.035 Uiso 1 1 calc R U . . .
C4C C 0.0743(8) 0.2885(8) 0.9390(3) 0.033(2) Uani 1 1 d . . . . .
H4C H 0.0242 0.2677 0.9650 0.040 Uiso 1 1 calc R U . . .
C5C C 0.0565(9) 0.3543(9) 0.8977(4) 0.043(3) Uani 1 1 d . . . . .
H5C H -0.0041 0.3805 0.8964 0.052 Uiso 1 1 calc R U . . .
C6C C 0.1264(8) 0.3815(7) 0.8591(3) 0.031(2) Uani 1 1 d . . . . .
H6C H 0.1114 0.4237 0.8299 0.037 Uiso 1 1 calc R U . . .
C1D C 0.4610(7) 0.4348(6) 0.8587(3) 0.0210(17) Uani 1 1 d . . . . .
C2D C 0.4851(8) 0.5024(6) 0.9078(3) 0.0261(19) Uani 1 1 d . . . . .
H2D H 0.4271 0.5263 0.9158 0.031 Uiso 1 1 calc R U . . .
C3D C 0.5966(8) 0.5364(7) 0.9466(4) 0.033(2) Uani 1 1 d . . . . .
H3D H 0.6138 0.5834 0.9804 0.040 Uiso 1 1 calc R U . . .
C4D C 0.6795(8) 0.5011(7) 0.9349(4) 0.035(2) Uani 1 1 d . . . . .
H4D H 0.7546 0.5242 0.9606 0.042 Uiso 1 1 calc R U . . .
C5D C 0.6543(8) 0.4320(8) 0.8860(4) 0.035(2) Uani 1 1 d . . . . .
H5D H 0.7115 0.4063 0.8788 0.043 Uiso 1 1 calc R U . . .
C6D C 0.5466(8) 0.3998(7) 0.8473(3) 0.0278(19) Uani 1 1 d . . . . .
H6D H 0.5308 0.3540 0.8132 0.033 Uiso 1 1 calc R U . . .
C1E C 0.5569(8) 0.9250(7) 0.8189(4) 0.031(2) Uani 1 1 d . . . . .
C2E C 0.5103(12) 0.9804(9) 0.8479(6) 0.076(5) Uani 1 1 d . . . . .
H2E H 0.4771 0.9527 0.8792 0.091 Uiso 1 1 calc R U . . .
C3E C 0.5123(14) 1.0798(11) 0.8305(8) 0.099(6) Uani 1 1 d . . . . .
H3E H 0.4795 1.1197 0.8498 0.119 Uiso 1 1 calc R U . . .
C4E C 0.5619(12) 1.1185(11) 0.7856(7) 0.082(5) Uani 1 1 d . . . . .
H4E H 0.5655 1.1866 0.7749 0.098 Uiso 1 1 calc R U . . .
C5E C 0.6045(12) 1.0636(8) 0.7571(5) 0.066(4) Uani 1 1 d . . . . .
H5E H 0.6377 1.0918 0.7259 0.079 Uiso 1 1 calc R U . . .
C6E C 0.6012(10) 0.9655(7) 0.7723(4) 0.044(3) Uani 1 1 d . . . . .
H6E H 0.6295 0.9249 0.7507 0.052 Uiso 1 1 calc R U . . .
C1F C 0.7166(7) 0.8355(6) 0.8776(3) 0.0197(16) Uani 1 1 d . . . . .
C2F C 0.9068(9) 0.9635(8) 0.9260(4) 0.044(3) Uani 1 1 d . . . . .
H2F H 0.9573 1.0358 0.9407 0.052 Uiso 1 1 calc R U . . .
C3F C 0.7907(9) 0.9409(7) 0.8996(4) 0.035(2) Uani 1 1 d . . . . .
H3F H 0.7618 0.9967 0.8965 0.043 Uiso 1 1 calc R U . . .
C6F C 0.7598(7) 0.7537(7) 0.8825(3) 0.0242(18) Uani 1 1 d . . . . .
H6F H 0.7093 0.6817 0.8674 0.029 Uiso 1 1 calc R U . . .
C5F C 0.8773(8) 0.7780(8) 0.9096(3) 0.035(2) Uani 1 1 d . . . . .
H5F H 0.9071 0.7228 0.9131 0.042 Uiso 1 1 calc R U . . .
C4F C 0.9509(8) 0.8851(9) 0.9316(4) 0.038(2) Uani 1 1 d . . . . .
H4F H 1.0309 0.9029 0.9503 0.046 Uiso 1 1 calc R U . . .
C1G C 0.2849(7) 0.7152(6) 0.6624(3) 0.0200(17) Uani 1 1 d . . . . .
C2G C 0.3247(8) 0.8254(6) 0.6755(4) 0.0274(19) Uani 1 1 d . . . . .
H2G H 0.3114 0.8546 0.7087 0.033 Uiso 1 1 calc R U . . .
C3G C 0.3840(9) 0.8929(7) 0.6398(4) 0.034(2) Uani 1 1 d . . . . .
H3G H 0.4074 0.9684 0.6479 0.041 Uiso 1 1 calc R U . . .
C4G C 0.4096(8) 0.8539(7) 0.5936(3) 0.0280(19) Uani 1 1 d . . . . .
H4G H 0.4508 0.9018 0.5698 0.034 Uiso 1 1 calc R U . . .
C5G C 0.3751(8) 0.7437(7) 0.5814(3) 0.0287(19) Uani 1 1 d . . . . .
H5G H 0.3948 0.7161 0.5499 0.034 Uiso 1 1 calc R U . . .
C6G C 0.3114(8) 0.6733(7) 0.6153(3) 0.0250(18) Uani 1 1 d . . . . .
H6G H 0.2863 0.5977 0.6066 0.030 Uiso 1 1 calc R U . . .
C1H C 0.0610(7) 0.5357(6) 0.6485(3) 0.0209(17) Uani 1 1 d . . . . .
C2H C 0.0305(8) 0.5649(7) 0.5943(3) 0.031(2) Uani 1 1 d . . . . .
H2H H 0.0799 0.6299 0.5831 0.037 Uiso 1 1 calc R U . . .
C3H C -0.0748(8) 0.4966(8) 0.5565(4) 0.036(2) Uani 1 1 d . . . . .
H3H H -0.0953 0.5155 0.5192 0.043 Uiso 1 1 calc R U . . .
C4H C -0.1473(9) 0.4049(8) 0.5720(4) 0.041(2) Uani 1 1 d . . . . .
H4H H -0.2183 0.3603 0.5458 0.050 Uiso 1 1 calc R U . . .
C5H C -0.1186(10) 0.3762(8) 0.6255(4) 0.048(3) Uani 1 1 d . . . . .
H5H H -0.1702 0.3121 0.6365 0.057 Uiso 1 1 calc R U . . .
C6H C -0.0142(9) 0.4407(7) 0.6635(4) 0.038(2) Uani 1 1 d . . . . .
H6H H 0.0060 0.4196 0.7003 0.045 Uiso 1 1 calc R U . . .
N1 N 0.6536(8) 0.0997(7) 0.6065(4) 0.052(2) Uani 1 1 d . . . . .
O3 O 0.5905(7) 0.1401(6) 0.6253(3) 0.055(2) Uani 1 1 d . . . . .
O4 O 0.6381(9) 0.0715(8) 0.5569(4) 0.085(3) Uani 1 1 d . . . . .
O5 O 0.7301(10) 0.0884(12) 0.6401(5) 0.146(6) Uani 1 1 d . . . . .
N2 N 0.6876(11) 0.9790(8) 0.0503(4) 0.0420(15) Uani 1 1 d D . . . .
O6 O 0.6390(16) 0.9133(13) 0.0760(7) 0.244(13) Uani 1 1 d D . . . .
O7 O 0.6407(12) 1.0391(8) 0.0246(8) 0.197(9) Uani 1 1 d D . . . .
O8 O 0.7568(13) 0.9692(12) 0.0383(7) 0.177(8) Uani 1 1 d D . . . .
C26 C 0.9151(12) 0.1571(10) 0.5482(5) 0.062(3) Uani 1 1 d . . . . .
H26A H 0.9331 0.2218 0.5748 0.074 Uiso 1 1 calc R U . . .
H26B H 0.8339 0.1064 0.5473 0.074 Uiso 1 1 calc R U . . .
Cl1 Cl 0.9244(3) 0.1942(3) 0.47888(15) 0.0736(10) Uani 1 1 d . . . . .
Cl2 Cl 1.0131(3) 0.0966(2) 0.57322(13) 0.0557(7) Uani 1 1 d . . . . .
C27 C 0.4150(11) 0.1445(8) 0.5164(4) 0.052(3) Uani 1 1 d . . . . .
H27A H 0.4007 0.1295 0.4743 0.062 Uiso 1 1 calc R U . . .
H27B H 0.4704 0.1123 0.5344 0.062 Uiso 1 1 calc R U . . .
Cl3 Cl 0.4798(3) 0.2877(2) 0.53672(11) 0.0560(8) Uani 1 1 d . . . . .
Cl4 Cl 0.2829(3) 0.0859(2) 0.53743(12) 0.0621(8) Uani 1 1 d . . . . .
C28 C 0.0625(13) 0.9211(10) 0.2764(5) 0.074(4) Uani 1 1 d . . . . .
H28A H 0.0118 0.9469 0.2942 0.088 Uiso 1 1 calc R U . . .
H28B H 0.1427 0.9522 0.3015 0.088 Uiso 1 1 calc R U . . .
Cl5 Cl 0.0107(4) 0.7834(3) 0.27461(19) 0.1125(19) Uani 1 1 d . . . . .
Cl6 Cl 0.0682(4) 0.9698(4) 0.21190(17) 0.1017(16) Uani 1 1 d . . . . .
C29 C -0.082(2) 0.4971(18) 0.9281(11) 0.213(9) Uani 0.557(8) 1 d D . P . .
H29A H -0.1589 0.5035 0.9186 0.255 Uiso 0.557(8) 1 calc R U P . .
H29B H -0.0815 0.4463 0.8975 0.255 Uiso 0.557(8) 1 calc R U P . .
Cl7 Cl 0.0188(7) 0.6131(7) 0.9264(3) 0.104(3) Uani 0.557(8) 1 d D . P . .
Cl8 Cl -0.0722(11) 0.4456(7) 0.9860(7) 0.213(9) Uani 0.557(8) 1 d D . P . .
O9 O 0.7752(7) 1.1599(5) -0.0196(3) 0.0420(15) Uani 1 1 d D . . . .
H91 H 0.736(7) 1.110(5) -0.004(3) 0.050 Uiso 1 1 d D U . . .
H92 H 0.844(5) 1.196(6) 0.002(3) 0.050 Uiso 1 1 d D U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 Au1 P3 160.70(8) . .
P1 Au1 Au2 99.79(6) . .
P3 Au1 Au2 99.08(6) . .
P2 Au2 P4 169.64(8) . .
P2 Au2 Au1 97.14(5) . .
P4 Au2 Au1 93.16(5) . .
C1 P1 C1A 103.4(4) . .
C1 P1 C1B 109.6(4) . .
C1A P1 C1B 103.3(4) . .
C1 P1 Au1 117.4(3) . .
C1A P1 Au1 109.8(2) . .
C1B P1 Au1 112.0(2) . .
C1D P2 C1C 103.2(3) . .
C1D P2 C8 105.5(4) . .
C1C P2 C8 108.0(4) . .
C1D P2 Au2 117.5(3) . .
C1C P2 Au2 111.1(2) . .
C8 P2 Au2 110.9(2) . .
C1E P3 C1F 105.2(4) . .
C1E P3 C13 106.5(4) . .
C1F P3 C13 106.0(3) . .
C1E P3 Au1 115.1(3) . .
C1F P3 Au1 104.1(2) . .
C13 P3 Au1 118.7(3) . .
C1G P4 C1H 105.6(4) . .
C1G P4 C20 104.8(3) . .
C1H P4 C20 104.8(4) . .
C1G P4 Au2 118.5(2) . .
C1H P4 Au2 110.7(2) . .
C20 P4 Au2 111.3(2) . .
C6 O1 C7 119.4(6) . .
C18 O2 C19 120.5(6) . .
C2 C1 C6 118.0(7) . .
C2 C1 P1 122.3(6) . .
C6 C1 P1 119.2(5) . .
C3 C2 C1 120.2(8) . .
C3 C2 H1 119.9 . .
C1 C2 H1 119.9 . .
C4 C3 C2 120.3(7) . .
C4 C3 H3 119.8 . .
C2 C3 H3 119.8 . .
C3 C4 C5 120.2(8) . .
C3 C4 H4 119.9 . .
C5 C4 H4 119.9 . .
C6 C5 C4 120.2(8) . .
C6 C5 H5 119.9 . .
C4 C5 H5 119.9 . .
C5 C6 O1 123.9(8) . .
C5 C6 C1 120.8(7) . .
O1 C6 C1 115.2(7) . .
C8 C7 C12 122.9(7) . .
C8 C7 O1 116.7(6) . .
C12 C7 O1 120.3(7) . .
C7 C8 C9 117.4(7) . .
C7 C8 P2 119.6(6) . .
C9 C8 P2 123.0(6) . .
C10 C9 C8 120.6(8) . .
C10 C9 H9 119.7 . .
C8 C9 H9 119.7 . .
C9 C10 C11 120.1(8) . .
C9 C10 H10 119.9 . .
C11 C10 H10 119.9 . .
C12 C11 C10 120.8(8) . .
C12 C11 H11 119.6 . .
C10 C11 H11 119.6 . .
C11 C12 C7 118.2(8) . .
C11 C12 H12 120.9 . .
C7 C12 H12 120.9 . .
C18 C13 C14 118.9(7) . .
C18 C13 P3 119.1(5) . .
C14 C13 P3 122.0(6) . .
C15 C14 C13 120.4(8) . .
C15 C14 H14 119.8 . .
C13 C14 H14 119.8 . .
C14 C15 C16 119.8(8) . .
C14 C15 H15 120.1 . .
C16 C15 H15 120.1 . .
C15 C16 C17 120.5(8) . .
C15 C16 H16 119.8 . .
C17 C16 H16 119.8 . .
C18 C17 C16 118.3(8) . .
C18 C17 H17 120.8 . .
C16 C17 H17 120.8 . .
C17 C18 C13 121.8(7) . .
C17 C18 O2 122.9(7) . .
C13 C18 O2 115.1(7) . .
C20 C19 O2 116.6(6) . .
C20 C19 C24 121.6(7) . .
O2 C19 C24 121.5(7) . .
C19 C20 C21 119.3(7) . .
C19 C20 P4 119.7(6) . .
C21 C20 P4 120.9(6) . .
C22 C21 C20 120.4(7) . .
C22 C21 H21 119.8 . .
C20 C21 H21 119.8 . .
C21 C22 C23 119.7(7) . .
C21 C22 H22 120.2 . .
C23 C22 H22 120.2 . .
C24 C23 C22 120.6(7) . .
C24 C23 H23 119.7 . .
C22 C23 H23 119.7 . .
C23 C24 C19 118.4(7) . .
C23 C24 H24 120.8 . .
C19 C24 H24 120.8 . .
C6A C1A C2A 119.1(8) . .
C6A C1A P1 119.5(6) . .
C2A C1A P1 121.4(6) . .
C3A C2A C1A 120.2(8) . .
C3A C2A H2A 119.9 . .
C1A C2A H2A 119.9 . .
C4A C3A C2A 120.4(8) . .
C4A C3A H3A 119.8 . .
C2A C3A H3A 119.8 . .
C3A C4A C5A 119.8(9) . .
C3A C4A H4A 120.1 . .
C5A C4A H4A 120.1 . .
C6A C5A C4A 120.4(8) . .
C6A C5A H5A 119.8 . .
C4A C5A H5A 119.8 . .
C5A C6A C1A 120.1(7) . .
C5A C6A H6A 120.0 . .
C1A C6A H6A 120.0 . .
C2B C1B C6B 120.5(7) . .
C2B C1B P1 117.6(6) . .
C6B C1B P1 121.8(6) . .
C1B C2B C3B 119.7(8) . .
C1B C2B H2B 120.2 . .
C3B C2B H2B 120.2 . .
C4B C3B C2B 120.2(8) . .
C4B C3B H3B 119.9 . .
C2B C3B H3B 119.9 . .
C5B C4B C3B 120.0(8) . .
C5B C4B H4B 120.0 . .
C3B C4B H4B 120.0 . .
C4B C5B C6B 120.9(9) . .
C4B C5B H5B 119.5 . .
C6B C5B H5B 119.5 . .
C1B C6B C5B 118.8(8) . .
C1B C6B H6B 120.6 . .
C5B C6B H6B 120.6 . .
C6C C1C C2C 118.5(7) . .
C6C C1C P2 120.2(6) . .
C2C C1C P2 121.3(6) . .
C3C C2C C1C 121.1(8) . .
C3C C2C H2C 119.5 . .
C1C C2C H2C 119.5 . .
C2C C3C C4C 119.6(8) . .
C2C C3C H3C 120.2 . .
C4C C3C H3C 120.2 . .
C5C C4C C3C 119.8(8) . .
C5C C4C H4C 120.1 . .
C3C C4C H4C 120.1 . .
C6C C5C C4C 120.0(8) . .
C6C C5C H5C 120.0 . .
C4C C5C H5C 120.0 . .
C5C C6C C1C 121.0(8) . .
C5C C6C H6C 119.5 . .
C1C C6C H6C 119.5 . .
C2D C1D C6D 119.8(7) . .
C2D C1D P2 117.5(6) . .
C6D C1D P2 122.7(6) . .
C1D C2D C3D 119.9(8) . .
C1D C2D H2D 120.0 . .
C3D C2D H2D 120.0 . .
C4D C3D C2D 119.6(8) . .
C4D C3D H3D 120.2 . .
C2D C3D H3D 120.2 . .
C3D C4D C5D 120.2(8) . .
C3D C4D H4D 119.9 . .
C5D C4D H4D 119.9 . .
C4D C5D C6D 120.7(8) . .
C4D C5D H5D 119.6 . .
C6D C5D H5D 119.6 . .
C5D C6D C1D 119.7(8) . .
C5D C6D H6D 120.1 . .
C1D C6D H6D 120.1 . .
C2E C1E C6E 119.6(9) . .
C2E C1E P3 122.8(8) . .
C6E C1E P3 117.6(7) . .
C1E C2E C3E 118.4(11) . .
C1E C2E H2E 120.8 . .
C3E C2E H2E 120.8 . .
C4E C3E C2E 119.6(11) . .
C4E C3E H3E 120.2 . .
C2E C3E H3E 120.2 . .
C5E C4E C3E 121.6(11) . .
C5E C4E H4E 119.2 . .
C3E C4E H4E 119.2 . .
C4E C5E C6E 119.9(13) . .
C4E C5E H5E 120.0 . .
C6E C5E H5E 120.0 . .
C5E C6E C1E 120.8(11) . .
C5E C6E H6E 119.6 . .
C1E C6E H6E 119.6 . .
C3F C1F C6F 120.0(8) . .
C3F C1F P3 122.2(6) . .
C6F C1F P3 117.7(6) . .
C4F C2F C3F 122.0(9) . .
C4F C2F H2F 119.0 . .
C3F C2F H2F 119.0 . .
C2F C3F C1F 119.2(8) . .
C2F C3F H3F 120.4 . .
C1F C3F H3F 120.4 . .
C5F C6F C1F 120.0(8) . .
C5F C6F H6F 120.0 . .
C1F C6F H6F 120.0 . .
C6F C5F C4F 119.2(8) . .
C6F C5F H5F 120.4 . .
C4F C5F H5F 120.4 . .
C2F C4F C5F 119.6(8) . .
C2F C4F H4F 120.2 . .
C5F C4F H4F 120.2 . .
C2G C1G C6G 119.7(7) . .
C2G C1G P4 123.1(6) . .
C6G C1G P4 117.2(6) . .
C1G C2G C3G 119.5(8) . .
C1G C2G H2G 120.3 . .
C3G C2G H2G 120.3 . .
C4G C3G C2G 121.7(8) . .
C4G C3G H3G 119.1 . .
C2G C3G H3G 119.1 . .
C3G C4G C5G 119.5(8) . .
C3G C4G H4G 120.3 . .
C5G C4G H4G 120.3 . .
C4G C5G C6G 120.2(8) . .
C4G C5G H5G 119.9 . .
C6G C5G H5G 119.9 . .
C5G C6G C1G 119.3(7) . .
C5G C6G H6G 120.4 . .
C1G C6G H6G 120.4 . .
C6H C1H C2H 118.8(8) . .
C6H C1H P4 118.4(6) . .
C2H C1H P4 122.7(7) . .
C1H C2H C3H 118.9(9) . .
C1H C2H H2H 120.5 . .
C3H C2H H2H 120.5 . .
C4H C3H C2H 121.4(9) . .
C4H C3H H3H 119.3 . .
C2H C3H H3H 119.3 . .
C3H C4H C5H 120.0(9) . .
C3H C4H H4H 120.0 . .
C5H C4H H4H 120.0 . .
C4H C5H C6H 120.0(10) . .
C4H C5H H5H 120.0 . .
C6H C5H H5H 120.0 . .
C1H C6H C5H 120.7(8) . .
C1H C6H H6H 119.6 . .
C5H C6H H6H 119.6 . .
O5 N1 O4 119.5(11) . .
O5 N1 O3 117.8(11) . .
O4 N1 O3 122.7(10) . .
O8 N2 O6 114.2(15) . .
O8 N2 O7 120.5(17) . .
O6 N2 O7 122.3(16) . .
Cl2 C26 Cl1 111.1(6) . .
Cl2 C26 H26A 109.4 . .
Cl1 C26 H26A 109.4 . .
Cl2 C26 H26B 109.4 . .
Cl1 C26 H26B 109.4 . .
H26A C26 H26B 108.0 . .
Cl4 C27 Cl3 111.1(5) . .
Cl4 C27 H27A 109.4 . .
Cl3 C27 H27A 109.4 . .
Cl4 C27 H27B 109.4 . .
Cl3 C27 H27B 109.4 . .
H27A C27 H27B 108.0 . .
Cl6 C28 Cl5 116.0(7) . .
Cl6 C28 H28A 108.3 . .
Cl5 C28 H28A 108.3 . .
Cl6 C28 H28B 108.3 . .
Cl5 C28 H28B 108.3 . .
H28A C28 H28B 107.4 . .
Cl8 C29 Cl7 117.1(17) . .
Cl8 C29 H29A 108.0 . .
Cl7 C29 H29A 108.0 . .
Cl8 C29 H29B 108.0 . .
Cl7 C29 H29B 108.0 . .
H29A C29 H29B 107.3 . .
C29 Cl7 Cl8 72.5(11) . 2_567
C29 Cl8 Cl8 89.3(12) . 2_567
C29 Cl8 Cl7 168.8(12) . 2_567
Cl8 Cl8 Cl7 80.5(10) 2_567 2_567
H91 O9 H92 110(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 P1 2.3271(18) .
Au1 P3 2.3317(19) .
Au1 Au2 3.2383(5) .
Au2 P2 2.3197(18) .
Au2 P4 2.3234(18) .
P1 C1 1.806(8) .
P1 C1A 1.809(8) .
P1 C1B 1.817(7) .
P2 C1D 1.813(8) .
P2 C1C 1.818(8) .
P2 C8 1.819(7) .
P3 C1E 1.809(8) .
P3 C1F 1.811(8) .
P3 C13 1.821(8) .
P4 C1G 1.810(8) .
P4 C1H 1.821(8) .
P4 C20 1.822(7) .
O1 C6 1.388(8) .
O1 C7 1.404(9) .
O2 C18 1.389(8) .
O2 C19 1.393(9) .
C1 C2 1.403(10) .
C1 C6 1.410(11) .
C2 C3 1.385(11) .
C2 H1 0.9500 .
C3 C4 1.373(12) .
C3 H3 0.9500 .
C4 C5 1.386(11) .
C4 H4 0.9500 .
C5 C6 1.364(11) .
C5 H5 0.9500 .
C7 C8 1.372(11) .
C7 C12 1.390(10) .
C8 C9 1.408(11) .
C9 C10 1.374(12) .
C9 H9 0.9500 .
C10 C11 1.384(13) .
C10 H10 0.9500 .
C11 C12 1.372(12) .
C11 H11 0.9500 .
C12 H12 0.9500 .
C13 C18 1.375(11) .
C13 C14 1.403(10) .
C14 C15 1.368(12) .
C14 H14 0.9500 .
C15 C16 1.389(12) .
C15 H15 0.9500 .
C16 C17 1.405(10) .
C16 H16 0.9500 .
C17 C18 1.371(11) .
C17 H17 0.9500 .
C19 C20 1.367(10) .
C19 C24 1.398(10) .
C20 C21 1.383(10) .
C21 C22 1.379(11) .
C21 H21 0.9500 .
C22 C23 1.394(11) .
C22 H22 0.9500 .
C23 C24 1.376(11) .
C23 H23 0.9500 .
C24 H24 0.9500 .
C1A C6A 1.397(11) .
C1A C2A 1.402(10) .
C2A C3A 1.386(13) .
C2A H2A 0.9500 .
C3A C4A 1.381(14) .
C3A H3A 0.9500 .
C4A C5A 1.390(12) .
C4A H4A 0.9500 .
C5A C6A 1.387(11) .
C5A H5A 0.9500 .
C6A H6A 0.9500 .
C1B C2B 1.383(11) .
C1B C6B 1.391(10) .
C2B C3B 1.391(11) .
C2B H2B 0.9500 .
C3B C4B 1.387(12) .
C3B H3B 0.9500 .
C4B C5B 1.364(14) .
C4B H4B 0.9500 .
C5B C6B 1.402(11) .
C5B H5B 0.9500 .
C6B H6B 0.9500 .
C1C C6C 1.384(11) .
C1C C2C 1.406(10) .
C2C C3C 1.363(12) .
C2C H2C 0.9500 .
C3C C4C 1.399(12) .
C3C H3C 0.9500 .
C4C C5C 1.390(12) .
C4C H4C 0.9500 .
C5C C6C 1.370(12) .
C5C H5C 0.9500 .
C6C H6C 0.9500 .
C1D C2D 1.378(11) .
C1D C6D 1.397(11) .
C2D C3D 1.417(11) .
C2D H2D 0.9500 .
C3D C4D 1.370(13) .
C3D H3D 0.9500 .
C4D C5D 1.383(13) .
C4D H4D 0.9500 .
C5D C6D 1.383(12) .
C5D H5D 0.9500 .
C6D H6D 0.9500 .
C1E C2E 1.361(13) .
C1E C6E 1.384(13) .
C2E C3E 1.409(15) .
C2E H2E 0.9500 .
C3E C4E 1.374(19) .
C3E H3E 0.9500 .
C4E C5E 1.311(18) .
C4E H4E 0.9500 .
C5E C6E 1.372(13) .
C5E H5E 0.9500 .
C6E H6E 0.9500 .
C1F C3F 1.390(12) .
C1F C6F 1.400(10) .
C2F C4F 1.367(14) .
C2F C3F 1.382(13) .
C2F H2F 0.9500 .
C3F H3F 0.9500 .
C6F C5F 1.397(12) .
C6F H6F 0.9500 .
C5F C4F 1.407(14) .
C5F H5F 0.9500 .
C4F H4F 0.9500 .
C1G C2G 1.382(10) .
C1G C6G 1.401(10) .
C2G C3G 1.383(12) .
C2G H2G 0.9500 .
C3G C4G 1.360(12) .
C3G H3G 0.9500 .
C4G C5G 1.386(12) .
C4G H4G 0.9500 .
C5G C6G 1.396(11) .
C5G H5G 0.9500 .
C6G H6G 0.9500 .
C1H C6H 1.387(12) .
C1H C2H 1.390(11) .
C2H C3H 1.405(12) .
C2H H2H 0.9500 .
C3H C4H 1.350(14) .
C3H H3H 0.9500 .
C4H C5H 1.369(13) .
C4H H4H 0.9500 .
C5H C6H 1.389(13) .
C5H H5H 0.9500 .
C6H H6H 0.9500 .
N1 O5 1.185(12) .
N1 O4 1.193(12) .
N1 O3 1.259(10) .
N2 O8 1.023(15) .
N2 O6 1.149(16) .
N2 O7 1.275(13) .
C26 Cl2 1.741(12) .
C26 Cl1 1.766(11) .
C26 H26A 0.9900 .
C26 H26B 0.9900 .
C27 Cl4 1.739(12) .
C27 Cl3 1.799(11) .
C27 H27A 0.9900 .
C27 H27B 0.9900 .
C28 Cl6 1.703(12) .
C28 Cl5 1.719(12) .
C28 H28A 0.9900 .
C28 H28B 0.9900 .
C29 Cl8 1.575(19) .
C29 Cl7 1.611(18) .
C29 H29A 0.9900 .
C29 H29B 0.9900 .
Cl7 Cl8 2.331(18) 2_567
Cl8 Cl8 1.83(3) 2_567
Cl8 Cl7 2.331(18) 2_567
O9 H91 0.83(2) .
O9 H92 0.87(3) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
C1A P1 C1 C2 -10.0(7) . . . .
C1B P1 C1 C2 -119.7(6) . . . .
Au1 P1 C1 C2 111.1(6) . . . .
C1A P1 C1 C6 177.3(6) . . . .
C1B P1 C1 C6 67.6(6) . . . .
Au1 P1 C1 C6 -61.7(6) . . . .
C6 C1 C2 C3 1.5(10) . . . .
P1 C1 C2 C3 -171.3(6) . . . .
C1 C2 C3 C4 1.8(11) . . . .
C2 C3 C4 C5 -2.7(12) . . . .
C3 C4 C5 C6 0.1(12) . . . .
C4 C5 C6 O1 -179.0(7) . . . .
C4 C5 C6 C1 3.3(11) . . . .
C7 O1 C6 C5 29.3(10) . . . .
C7 O1 C6 C1 -152.9(6) . . . .
C2 C1 C6 C5 -4.1(10) . . . .
P1 C1 C6 C5 169.0(6) . . . .
C2 C1 C6 O1 178.0(6) . . . .
P1 C1 C6 O1 -8.9(8) . . . .
C6 O1 C7 C8 -141.7(7) . . . .
C6 O1 C7 C12 41.6(10) . . . .
C12 C7 C8 C9 -1.0(13) . . . .
O1 C7 C8 C9 -177.6(7) . . . .
C12 C7 C8 P2 178.3(6) . . . .
O1 C7 C8 P2 1.7(10) . . . .
C1D P2 C8 C7 -86.5(7) . . . .
C1C P2 C8 C7 163.6(6) . . . .
Au2 P2 C8 C7 41.7(7) . . . .
C1D P2 C8 C9 92.7(8) . . . .
C1C P2 C8 C9 -17.2(8) . . . .
Au2 P2 C8 C9 -139.1(7) . . . .
C7 C8 C9 C10 -0.6(13) . . . .
P2 C8 C9 C10 -179.9(8) . . . .
C8 C9 C10 C11 0.6(16) . . . .
C9 C10 C11 C12 1.1(16) . . . .
C10 C11 C12 C7 -2.6(15) . . . .
C8 C7 C12 C11 2.6(13) . . . .
O1 C7 C12 C11 179.1(8) . . . .
C1E P3 C13 C18 68.9(7) . . . .
C1F P3 C13 C18 -179.4(6) . . . .
Au1 P3 C13 C18 -62.9(6) . . . .
C1E P3 C13 C14 -111.1(6) . . . .
C1F P3 C13 C14 0.6(7) . . . .
Au1 P3 C13 C14 117.1(6) . . . .
C18 C13 C14 C15 4.0(11) . . . .
P3 C13 C14 C15 -176.0(6) . . . .
C13 C14 C15 C16 0.6(11) . . . .
C14 C15 C16 C17 -2.2(12) . . . .
C15 C16 C17 C18 -0.8(11) . . . .
C16 C17 C18 C13 5.6(11) . . . .
C16 C17 C18 O2 -179.0(6) . . . .
C14 C13 C18 C17 -7.2(11) . . . .
P3 C13 C18 C17 172.8(6) . . . .
C14 C13 C18 O2 177.1(6) . . . .
P3 C13 C18 O2 -2.9(9) . . . .
C19 O2 C18 C17 32.3(10) . . . .
C19 O2 C18 C13 -152.0(7) . . . .
C18 O2 C19 C20 -147.3(7) . . . .
C18 O2 C19 C24 38.5(11) . . . .
O2 C19 C20 C21 -174.2(7) . . . .
C24 C19 C20 C21 0.1(12) . . . .
O2 C19 C20 P4 2.4(10) . . . .
C24 C19 C20 P4 176.6(6) . . . .
C1G P4 C20 C19 -89.9(7) . . . .
C1H P4 C20 C19 159.1(6) . . . .
Au2 P4 C20 C19 39.4(7) . . . .
C1G P4 C20 C21 86.6(7) . . . .
C1H P4 C20 C21 -24.4(8) . . . .
Au2 P4 C20 C21 -144.1(6) . . . .
C19 C20 C21 C22 -0.8(12) . . . .
P4 C20 C21 C22 -177.3(7) . . . .
C20 C21 C22 C23 1.5(13) . . . .
C21 C22 C23 C24 -1.6(13) . . . .
C22 C23 C24 C19 0.9(13) . . . .
C20 C19 C24 C23 -0.1(13) . . . .
O2 C19 C24 C23 173.8(7) . . . .
C1 P1 C1A C6A -80.0(7) . . . .
C1B P1 C1A C6A 34.3(7) . . . .
Au1 P1 C1A C6A 153.9(5) . . . .
C1 P1 C1A C2A 98.9(7) . . . .
C1B P1 C1A C2A -146.9(7) . . . .
Au1 P1 C1A C2A -27.3(7) . . . .
C6A C1A C2A C3A 1.4(13) . . . .
P1 C1A C2A C3A -177.5(7) . . . .
C1A C2A C3A C4A -1.8(15) . . . .
C2A C3A C4A C5A 1.2(15) . . . .
C3A C4A C5A C6A -0.1(14) . . . .
C4A C5A C6A C1A -0.3(12) . . . .
C2A C1A C6A C5A -0.3(12) . . . .
P1 C1A C6A C5A 178.6(6) . . . .
C1 P1 C1B C2B -177.4(6) . . . .
C1A P1 C1B C2B 72.9(7) . . . .
Au1 P1 C1B C2B -45.2(7) . . . .
C1 P1 C1B C6B 6.1(8) . . . .
C1A P1 C1B C6B -103.6(7) . . . .
Au1 P1 C1B C6B 138.3(6) . . . .
C6B C1B C2B C3B 0.2(13) . . . .
P1 C1B C2B C3B -176.4(6) . . . .
C1B C2B C3B C4B -1.6(13) . . . .
C2B C3B C4B C5B 1.9(15) . . . .
C3B C4B C5B C6B -0.8(16) . . . .
C2B C1B C6B C5B 0.8(13) . . . .
P1 C1B C6B C5B 177.3(7) . . . .
C4B C5B C6B C1B -0.5(14) . . . .
C1D P2 C1C C6C 132.9(7) . . . .
C8 P2 C1C C6C -115.6(7) . . . .
Au2 P2 C1C C6C 6.1(8) . . . .
C1D P2 C1C C2C -46.1(7) . . . .
C8 P2 C1C C2C 65.3(7) . . . .
Au2 P2 C1C C2C -172.9(6) . . . .
C6C C1C C2C C3C -0.5(12) . . . .
P2 C1C C2C C3C 178.5(7) . . . .
C1C C2C C3C C4C -0.3(13) . . . .
C2C C3C C4C C5C -0.5(13) . . . .
C3C C4C C5C C6C 2.1(15) . . . .
C4C C5C C6C C1C -2.9(16) . . . .
C2C C1C C6C C5C 2.2(14) . . . .
P2 C1C C6C C5C -176.9(8) . . . .
C1C P2 C1D C2D -47.6(7) . . . .
C8 P2 C1D C2D -160.8(6) . . . .
Au2 P2 C1D C2D 75.0(7) . . . .
C1C P2 C1D C6D 130.0(7) . . . .
C8 P2 C1D C6D 16.8(8) . . . .
Au2 P2 C1D C6D -107.4(6) . . . .
C6D C1D C2D C3D 0.2(12) . . . .
P2 C1D C2D C3D 177.9(6) . . . .
C1D C2D C3D C4D -0.4(13) . . . .
C2D C3D C4D C5D -0.5(13) . . . .
C3D C4D C5D C6D 1.7(14) . . . .
C4D C5D C6D C1D -1.9(13) . . . .
C2D C1D C6D C5D 1.0(12) . . . .
P2 C1D C6D C5D -176.6(7) . . . .
C1F P3 C1E C2E -100.7(11) . . . .
C13 P3 C1E C2E 11.5(11) . . . .
Au1 P3 C1E C2E 145.3(10) . . . .
C1F P3 C1E C6E 78.6(8) . . . .
C13 P3 C1E C6E -169.2(8) . . . .
Au1 P3 C1E C6E -35.4(9) . . . .
C6E C1E C2E C3E -2(2) . . . .
P3 C1E C2E C3E 177.2(12) . . . .
C1E C2E C3E C4E -1(3) . . . .
C2E C3E C4E C5E 2(3) . . . .
C3E C4E C5E C6E -1(2) . . . .
C4E C5E C6E C1E -2.3(19) . . . .
C2E C1E C6E C5E 3.6(17) . . . .
P3 C1E C6E C5E -175.7(9) . . . .
C1E P3 C1F C3F 16.8(8) . . . .
C13 P3 C1F C3F -95.7(7) . . . .
Au1 P3 C1F C3F 138.3(7) . . . .
C1E P3 C1F C6F -160.0(6) . . . .
C13 P3 C1F C6F 87.4(6) . . . .
Au1 P3 C1F C6F -38.6(6) . . . .
C4F C2F C3F C1F -0.6(14) . . . .
C6F C1F C3F C2F 0.3(13) . . . .
P3 C1F C3F C2F -176.5(7) . . . .
C3F C1F C6F C5F 0.0(12) . . . .
P3 C1F C6F C5F 177.0(6) . . . .
C1F C6F C5F C4F -0.1(12) . . . .
C3F C2F C4F C5F 0.6(14) . . . .
C6F C5F C4F C2F -0.2(13) . . . .
C1H P4 C1G C2G 123.0(7) . . . .
C20 P4 C1G C2G 12.6(8) . . . .
Au2 P4 C1G C2G -112.2(6) . . . .
C1H P4 C1G C6G -54.2(7) . . . .
C20 P4 C1G C6G -164.6(6) . . . .
Au2 P4 C1G C6G 70.5(7) . . . .
C6G C1G C2G C3G 4.0(13) . . . .
P4 C1G C2G C3G -173.2(7) . . . .
C1G C2G C3G C4G -3.4(14) . . . .
C2G C3G C4G C5G 0.3(14) . . . .
C3G C4G C5G C6G 2.0(13) . . . .
C4G C5G C6G C1G -1.3(12) . . . .
C2G C1G C6G C5G -1.7(12) . . . .
P4 C1G C6G C5G 175.6(6) . . . .
C1G P4 C1H C6H 166.1(7) . . . .
C20 P4 C1H C6H -83.5(7) . . . .
Au2 P4 C1H C6H 36.6(7) . . . .
C1G P4 C1H C2H -16.4(8) . . . .
C20 P4 C1H C2H 94.0(7) . . . .
Au2 P4 C1H C2H -145.9(6) . . . .
C6H C1H C2H C3H -0.7(12) . . . .
P4 C1H C2H C3H -178.2(7) . . . .
C1H C2H C3H C4H 1.2(14) . . . .
C2H C3H C4H C5H -0.5(15) . . . .
C3H C4H C5H C6H -0.8(16) . . . .
C2H C1H C6H C5H -0.6(14) . . . .
P4 C1H C6H C5H 177.1(8) . . . .
C4H C5H C6H C1H 1.3(16) . . . .
Cl8 C29 Cl7 Cl8 6.2(16) . . . 2_567
Cl7 C29 Cl8 Cl8 -8(2) . . . 2_567
Cl7 C29 Cl8 Cl7 -32(8) . . . 2_567
