#------------------------------------------------------------------------------
#$Date: 2019-11-23 09:13:47 +0200 (Sat, 23 Nov 2019) $
#$Revision: 232673 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/53/7235300.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7235300
loop_
_publ_author_name
'Ma, Ai-Qing'
'Zhu, Long-Guan'
_publ_section_title
;
 Diverse silver(i) sulfobenzoate coordination polymers and their recycling
 property as homogeneous catalyst in oxygenation of sulfide
;
_journal_issue                   28
_journal_name_full               'RSC Adv.'
_journal_page_first              14691
_journal_paper_doi               10.1039/C3RA47136E
_journal_volume                  4
_journal_year                    2014
_chemical_formula_sum            'C35 H40 Ag2 N8 O9 S'
_chemical_formula_weight         964.55
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                98.0970(10)
_cell_angle_beta                 98.2860(10)
_cell_angle_gamma                113.9710(10)
_cell_formula_units_Z            2
_cell_length_a                   10.6331(3)
_cell_length_b                   11.3717(3)
_cell_length_c                   18.0884(5)
_cell_measurement_temperature    295(2)
_cell_volume                     1928.99(9)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      295(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0258
_diffrn_reflns_av_sigmaI/netI    0.0250
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            19941
_diffrn_reflns_theta_full        25.10
_diffrn_reflns_theta_max         25.10
_diffrn_reflns_theta_min         1.17
_exptl_absorpt_coefficient_mu    1.133
_exptl_crystal_density_diffrn    1.661
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             976
_refine_diff_density_max         1.172
_refine_diff_density_min         -0.749
_refine_diff_density_rms         0.078
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.064
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     520
_refine_ls_number_reflns         6820
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.063
_refine_ls_R_factor_all          0.0438
_refine_ls_R_factor_gt           0.0380
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0613P)²+2.2631P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1071
_refine_ls_wR_factor_ref         0.1166
_reflns_number_gt                6009
_reflns_number_total             6820
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ra47136e2.cif
_cod_data_source_block           m
_cod_database_code               7235300
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.16774(3) 0.73267(3) 0.377259(19) 0.05922(12) Uani 1 1 d .
Ag2 Ag 0.06903(3) 0.17741(3) 0.095842(18) 0.05607(12) Uani 1 1 d .
S1 S 0.39586(11) 0.23123(10) 0.21068(6) 0.0530(2) Uani 1 1 d .
N1 N 0.3089(3) 0.8471(3) 0.49342(17) 0.0429(7) Uani 1 1 d .
N2 N 0.3422(3) 0.9748(3) 0.52197(17) 0.0397(6) Uani 1 1 d .
N3 N -0.0530(3) 0.7055(3) 0.33706(19) 0.0499(7) Uani 1 1 d .
N4 N -0.1703(4) 0.6007(4) 0.3410(2) 0.0593(9) Uani 1 1 d .
N5 N 0.1524(4) 0.1642(3) -0.00257(18) 0.0538(8) Uani 1 1 d .
N6 N 0.1099(4) 0.1882(3) -0.0700(2) 0.0608(9) Uani 1 1 d .
N7 N 0.1780(3) 0.8170(3) -0.16758(18) 0.0469(7) Uani 1 1 d .
N8 N 0.0498(3) 0.8189(3) -0.17925(19) 0.0510(8) Uani 1 1 d .
O1 O 0.2613(4) 0.6180(3) 0.30641(18) 0.0669(8) Uani 1 1 d .
O2 O 0.3354(4) 0.7676(3) 0.2374(2) 0.0729(9) Uani 1 1 d .
O3 O 0.4701(5) 0.2696(4) 0.2901(2) 0.0984(13) Uani 1 1 d .
O4 O 0.2509(4) 0.1477(3) 0.1959(3) 0.0852(12) Uani 1 1 d .
O5 O 0.4677(4) 0.1796(3) 0.1631(3) 0.0908(12) Uani 1 1 d .
C1 C 0.3190(4) 0.6613(4) 0.2542(2) 0.0503(9) Uani 1 1 d .
C2 C 0.3729(4) 0.5756(3) 0.2093(2) 0.0431(8) Uani 1 1 d .
C3 C 0.3534(4) 0.4540(4) 0.2245(2) 0.0434(8) Uani 1 1 d .
H3 H 0.3016 0.4216 0.2604 0.052 Uiso 1 1 calc R
C4 C 0.4118(4) 0.3801(4) 0.1858(2) 0.0450(8) Uani 1 1 d .
C5 C 0.4851(5) 0.4261(4) 0.1315(2) 0.0576(10) Uani 1 1 d .
H5 H 0.5227 0.3762 0.1057 0.069 Uiso 1 1 calc R
C6 C 0.5034(5) 0.5462(4) 0.1150(3) 0.0616(11) Uani 1 1 d .
H6 H 0.5530 0.5772 0.0781 0.074 Uiso 1 1 calc R
C7 C 0.4469(5) 0.6202(4) 0.1542(2) 0.0533(9) Uani 1 1 d .
H7 H 0.4592 0.7011 0.1431 0.064 Uiso 1 1 calc R
C8 C 0.3674(4) 0.8094(4) 0.5495(2) 0.0514(9) Uani 1 1 d .
H8 H 0.3620 0.7251 0.5463 0.062 Uiso 1 1 calc R
C9 C 0.4376(4) 0.9115(5) 0.6135(2) 0.0560(10) Uani 1 1 d .
H9 H 0.4868 0.9096 0.6599 0.067 Uiso 1 1 calc R
C10 C 0.4188(4) 1.0148(4) 0.5939(2) 0.0499(9) Uani 1 1 d .
H10 H 0.4531 1.0987 0.6249 0.060 Uiso 1 1 calc R
C11 C 0.2816(4) 1.0460(4) 0.4800(2) 0.0455(8) Uani 1 1 d .
H11A H 0.2770 1.0202 0.4259 0.055 Uiso 1 1 calc R
H11B H 0.3428 1.1398 0.4967 0.055 Uiso 1 1 calc R
C12 C 0.1353(3) 1.0202(3) 0.49139(18) 0.0356(7) Uani 1 1 d .
C13 C 0.0535(4) 0.9143(3) 0.51936(19) 0.0391(7) Uani 1 1 d .
H13 H 0.0891 0.8558 0.5326 0.047 Uiso 1 1 calc R
C14 C 0.0801(4) 1.1062(3) 0.4720(2) 0.0390(7) Uani 1 1 d .
H14 H 0.1335 1.1780 0.4531 0.047 Uiso 1 1 calc R
C15 C -0.0963(5) 0.7969(5) 0.3240(2) 0.0601(11) Uani 1 1 d .
H15 H -0.0371 0.8806 0.3190 0.072 Uiso 1 1 calc R
C16 C -0.2359(6) 0.7535(7) 0.3189(3) 0.0776(15) Uani 1 1 d .
H16 H -0.2895 0.7994 0.3096 0.093 Uiso 1 1 calc R
C17 C -0.2817(5) 0.6301(7) 0.3301(3) 0.0827(16) Uani 1 1 d .
H17 H -0.3743 0.5744 0.3303 0.099 Uiso 1 1 calc R
C18 C -0.1641(6) 0.4790(5) 0.3512(3) 0.0744(13) Uani 1 1 d .
H18A H -0.1238 0.4505 0.3115 0.089 Uiso 1 1 calc R
H18B H -0.2593 0.4113 0.3453 0.089 Uiso 1 1 calc R
C19 C -0.0772(5) 0.4929(4) 0.4288(2) 0.0580(10) Uani 1 1 d .
C20 C -0.1099(5) 0.5349(4) 0.4958(3) 0.0624(11) Uani 1 1 d .
H20 H -0.1839 0.5590 0.4937 0.075 Uiso 1 1 calc R
C21 C 0.0321(5) 0.4587(4) 0.4335(3) 0.0623(11) Uani 1 1 d .
H21 H 0.0553 0.4307 0.3888 0.075 Uiso 1 1 calc R
C22 C 0.2553(5) 0.1283(4) -0.0113(3) 0.0625(11) Uani 1 1 d .
H22 H 0.3044 0.1056 0.0266 0.075 Uiso 1 1 calc R
C23 C 0.2782(7) 0.1297(5) -0.0836(3) 0.0797(16) Uani 1 1 d .
H23 H 0.3435 0.1083 -0.1041 0.096 Uiso 1 1 calc R
C24 C 0.1867(7) 0.1685(5) -0.1187(3) 0.0848(17) Uani 1 1 d .
H24 H 0.1779 0.1798 -0.1688 0.102 Uiso 1 1 calc R
C25 C 0.0021(5) 0.2361(5) -0.0811(3) 0.0767(14) Uani 1 1 d .
H25A H -0.0462 0.2241 -0.0393 0.092 Uiso 1 1 calc R
H25B H -0.0669 0.1838 -0.1282 0.092 Uiso 1 1 calc R
C26 C 0.0626(4) 0.3805(4) -0.0851(2) 0.0557(10) Uani 1 1 d .
C27 C 0.1630(6) 0.4789(5) -0.0255(3) 0.0760(15) Uani 1 1 d .
H27 H 0.1951 0.4569 0.0187 0.091 Uiso 1 1 calc R
C28 C 0.2162(5) 0.6092(5) -0.0307(2) 0.0688(13) Uani 1 1 d .
H28 H 0.2847 0.6735 0.0099 0.083 Uiso 1 1 calc R
C29 C 0.1702(4) 0.6463(4) -0.0946(2) 0.0461(8) Uani 1 1 d .
C30 C 0.0682(5) 0.5477(4) -0.1537(2) 0.0561(10) Uani 1 1 d .
H30 H 0.0338 0.5699 -0.1972 0.067 Uiso 1 1 calc R
C31 C 0.0167(5) 0.4165(4) -0.1489(2) 0.0593(10) Uani 1 1 d .
H31 H -0.0503 0.3518 -0.1898 0.071 Uiso 1 1 calc R
C32 C 0.2351(4) 0.7899(4) -0.0976(2) 0.0532(9) Uani 1 1 d .
H32A H 0.2205 0.8400 -0.0543 0.064 Uiso 1 1 calc R
H32B H 0.3360 0.8203 -0.0923 0.064 Uiso 1 1 calc R
C33 C 0.2345(4) 0.8395(4) -0.2281(2) 0.0580(10) Uani 1 1 d .
H33 H 0.3213 0.8422 -0.2335 0.070 Uiso 1 1 calc R
C34 C 0.1431(5) 0.8579(5) -0.2807(3) 0.0659(11) Uani 1 1 d .
H34 H 0.1548 0.8762 -0.3284 0.079 Uiso 1 1 calc R
C35 C 0.0298(5) 0.8436(4) -0.2485(2) 0.0570(10) Uani 1 1 d .
H35 H -0.0500 0.8503 -0.2720 0.068 Uiso 1 1 calc R
O1W O 0.2000(4) 0.9256(4) 0.2758(2) 0.0802(10) Uani 1 1 d D
O2W O 0.4489(5) 0.6057(4) 0.4319(2) 0.0949(13) Uani 1 1 d D
O3W O 0.3953(6) -0.0984(4) 0.1134(3) 0.1070(15) Uani 1 1 d D
O4W O 0.3803(6) 0.3397(5) 0.4218(3) 0.1156(16) Uani 1 1 d D
H3A H 0.406(6) -0.020(2) 0.126(2) 0.080 Uiso 1 1 d D
H1B H 0.221(5) 0.993(3) 0.256(3) 0.080 Uiso 1 1 d D
H3B H 0.380(6) -0.132(4) 0.1519(18) 0.080 Uiso 1 1 d D
H1A H 0.252(5) 0.889(4) 0.262(3) 0.080 Uiso 1 1 d D
H2A H 0.401(5) 0.618(4) 0.3944(19) 0.080 Uiso 1 1 d D
H4B H 0.396(4) 0.327(5) 0.4671(13) 0.080 Uiso 1 1 d D
H2B H 0.431(5) 0.5247(17) 0.423(3) 0.080 Uiso 1 1 d D
H4A H 0.465(2) 0.376(5) 0.413(3) 0.080 Uiso 1 1 d D
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N3 Ag1 N1 125.54(11) . .
N3 Ag1 O1 120.92(12) . .
N1 Ag1 O1 113.04(11) . .
N8 Ag2 N5 169.24(13) 2_565 .
O4 S1 O5 112.1(3) . .
O4 S1 O3 115.7(3) . .
O5 S1 O3 110.3(3) . .
O4 S1 C4 106.78(17) . .
O5 S1 C4 106.6(2) . .
O3 S1 C4 104.6(2) . .
C8 N1 N2 104.8(3) . .
C8 N1 Ag1 131.3(3) . .
N2 N1 Ag1 123.7(2) . .
C10 N2 N1 111.1(3) . .
C10 N2 C11 127.6(3) . .
N1 N2 C11 120.8(3) . .
C15 N3 N4 105.0(4) . .
C15 N3 Ag1 128.0(3) . .
N4 N3 Ag1 124.9(3) . .
N3 N4 C17 109.2(4) . .
N3 N4 C18 120.4(4) . .
C17 N4 C18 130.3(5) . .
C22 N5 N6 105.9(4) . .
C22 N5 Ag2 127.6(3) . .
N6 N5 Ag2 126.4(3) . .
C24 N6 N5 109.3(4) . .
C24 N6 C25 129.0(4) . .
N5 N6 C25 121.7(4) . .
C33 N7 N8 110.5(3) . .
C33 N7 C32 128.2(3) . .
N8 N7 C32 121.3(3) . .
C35 N8 N7 105.4(3) . .
C35 N8 Ag2 127.3(3) . 2_565
N7 N8 Ag2 126.2(2) . 2_565
C1 O1 Ag1 120.7(3) . .
O2 C1 O1 124.9(4) . .
O2 C1 C2 118.7(4) . .
O1 C1 C2 116.4(3) . .
C7 C2 C3 119.0(3) . .
C7 C2 C1 120.2(3) . .
C3 C2 C1 120.8(3) . .
C2 C3 C4 119.9(4) . .
C2 C3 H3 120.0 . .
C4 C3 H3 120.0 . .
C5 C4 C3 120.2(3) . .
C5 C4 S1 120.6(3) . .
C3 C4 S1 119.1(3) . .
C4 C5 C6 120.4(4) . .
C4 C5 H5 119.8 . .
C6 C5 H5 119.8 . .
C5 C6 C7 119.2(4) . .
C5 C6 H6 120.4 . .
C7 C6 H6 120.4 . .
C2 C7 C6 121.2(4) . .
C2 C7 H7 119.4 . .
C6 C7 H7 119.4 . .
N1 C8 C9 111.4(3) . .
N1 C8 H8 124.3 . .
C9 C8 H8 124.3 . .
C10 C9 C8 104.8(3) . .
C10 C9 H9 127.6 . .
C8 C9 H9 127.6 . .
N2 C10 C9 107.9(4) . .
N2 C10 H10 126.1 . .
C9 C10 H10 126.1 . .
N2 C11 C12 112.4(3) . .
N2 C11 H11A 109.1 . .
C12 C11 H11A 109.1 . .
N2 C11 H11B 109.1 . .
C12 C11 H11B 109.1 . .
H11A C11 H11B 107.8 . .
C13 C12 C14 118.6(3) . .
C13 C12 C11 123.0(3) . .
C14 C12 C11 118.4(3) . .
C14 C13 C12 121.0(3) 2_576 .
C14 C13 H13 119.5 2_576 .
C12 C13 H13 119.5 . .
C13 C14 C12 120.4(3) 2_576 .
C13 C14 H14 119.8 2_576 .
C12 C14 H14 119.8 . .
N3 C15 C16 111.9(5) . .
N3 C15 H15 124.1 . .
C16 C15 H15 124.1 . .
C17 C16 C15 105.6(5) . .
C17 C16 H16 127.2 . .
C15 C16 H16 127.2 . .
C16 C17 N4 108.3(5) . .
C16 C17 H17 125.8 . .
N4 C17 H17 125.8 . .
N4 C18 C19 112.8(4) . .
N4 C18 H18A 109.0 . .
C19 C18 H18A 109.0 . .
N4 C18 H18B 109.0 . .
C19 C18 H18B 109.0 . .
H18A C18 H18B 107.8 . .
C21 C19 C20 118.7(4) . .
C21 C19 C18 120.0(4) . .
C20 C19 C18 121.2(5) . .
C19 C20 C21 120.2(4) . 2_566
C19 C20 H20 119.9 . .
C21 C20 H20 119.9 2_566 .
C19 C21 C20 121.1(4) . 2_566
C19 C21 H21 119.4 . .
C20 C21 H21 119.4 2_566 .
N5 C22 C23 110.5(5) . .
N5 C22 H22 124.8 . .
C23 C22 H22 124.8 . .
C24 C23 C22 105.3(5) . .
C24 C23 H23 127.3 . .
C22 C23 H23 127.3 . .
N6 C24 C23 109.0(4) . .
N6 C24 H24 125.5 . .
C23 C24 H24 125.5 . .
N6 C25 C26 112.7(4) . .
N6 C25 H25A 109.1 . .
C26 C25 H25A 109.1 . .
N6 C25 H25B 109.1 . .
C26 C25 H25B 109.1 . .
H25A C25 H25B 107.8 . .
C31 C26 C27 118.0(4) . .
C31 C26 C25 119.8(4) . .
C27 C26 C25 122.1(4) . .
C28 C27 C26 120.9(4) . .
C28 C27 H27 119.6 . .
C26 C27 H27 119.6 . .
C27 C28 C29 121.5(4) . .
C27 C28 H28 119.3 . .
C29 C28 H28 119.3 . .
C28 C29 C30 117.6(4) . .
C28 C29 C32 118.9(4) . .
C30 C29 C32 123.6(3) . .
C29 C30 C31 120.9(4) . .
C29 C30 H30 119.5 . .
C31 C30 H30 119.5 . .
C26 C31 C30 121.2(4) . .
C26 C31 H31 119.4 . .
C30 C31 H31 119.4 . .
N7 C32 C29 113.9(3) . .
N7 C32 H32A 108.8 . .
C29 C32 H32A 108.8 . .
N7 C32 H32B 108.8 . .
C29 C32 H32B 108.8 . .
H32A C32 H32B 107.7 . .
N7 C33 C34 107.9(4) . .
N7 C33 H33 126.0 . .
C34 C33 H33 126.0 . .
C33 C34 C35 105.5(4) . .
C33 C34 H34 127.2 . .
C35 C34 H34 127.2 . .
N8 C35 C34 110.7(4) . .
N8 C35 H35 124.6 . .
C34 C35 H35 124.6 . .
H1B O1W H1A 105.6(16) . .
H2A O2W H2B 107.7(17) . .
H3A O3W H3B 107.3(17) . .
H4B O4W H4A 103.7(16) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N3 2.234(3) .
Ag1 N1 2.257(3) .
Ag1 O1 2.299(3) .
Ag2 N8 2.110(3) 2_565
Ag2 N5 2.113(3) .
S1 O4 1.404(4) .
S1 O5 1.442(4) .
S1 O3 1.447(4) .
S1 C4 1.761(4) .
N1 C8 1.326(5) .
N1 N2 1.349(4) .
N2 C10 1.338(5) .
N2 C11 1.449(4) .
N3 C15 1.332(5) .
N3 N4 1.350(5) .
N4 C17 1.353(6) .
N4 C18 1.447(6) .
N5 C22 1.335(6) .
N5 N6 1.343(5) .
N6 C24 1.340(7) .
N6 C25 1.455(7) .
N7 C33 1.330(5) .
N7 N8 1.358(4) .
N7 C32 1.452(5) .
N8 C35 1.328(5) .
N8 Ag2 2.110(3) 2_565
O1 C1 1.250(5) .
O2 C1 1.237(5) .
C1 C2 1.517(5) .
C2 C7 1.384(6) .
C2 C3 1.386(5) .
C3 C4 1.402(5) .
C3 H3 0.9300 .
C4 C5 1.371(6) .
C5 C6 1.381(6) .
C5 H5 0.9300 .
C6 C7 1.392(6) .
C6 H6 0.9300 .
C7 H7 0.9300 .
C8 C9 1.383(6) .
C8 H8 0.9300 .
C9 C10 1.354(6) .
C9 H9 0.9300 .
C10 H10 0.9300 .
C11 C12 1.513(4) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C12 C13 1.382(5) .
C12 C14 1.388(5) .
C13 C14 1.379(5) 2_576
C13 H13 0.9300 .
C14 C13 1.379(5) 2_576
C14 H14 0.9300 .
C15 C16 1.345(7) .
C15 H15 0.9300 .
C16 C17 1.341(8) .
C16 H16 0.9300 .
C17 H17 0.9300 .
C18 C19 1.514(7) .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C19 C21 1.363(7) .
C19 C20 1.382(6) .
C20 C21 1.395(7) 2_566
C20 H20 0.9300 .
C21 C20 1.395(7) 2_566
C21 H21 0.9300 .
C22 C23 1.366(7) .
C22 H22 0.9300 .
C23 C24 1.340(9) .
C23 H23 0.9300 .
C24 H24 0.9300 .
C25 C26 1.518(6) .
C25 H25A 0.9700 .
C25 H25B 0.9700 .
C26 C31 1.369(6) .
C26 C27 1.383(6) .
C27 C28 1.377(7) .
C27 H27 0.9300 .
C28 C29 1.377(6) .
C28 H28 0.9300 .
C29 C30 1.384(5) .
C29 C32 1.505(6) .
C30 C31 1.385(6) .
C30 H30 0.9300 .
C31 H31 0.9300 .
C32 H32A 0.9700 .
C32 H32B 0.9700 .
C33 C34 1.359(6) .
C33 H33 0.9300 .
C34 C35 1.373(6) .
C34 H34 0.9300 .
C35 H35 0.9300 .
O1W H1B 0.858(10) .
O1W H1A 0.858(10) .
O2W H2A 0.849(10) .
O2W H2B 0.847(10) .
O3W H3A 0.849(10) .
O3W H3B 0.848(10) .
O4W H4B 0.855(10) .
O4W H4A 0.878(10) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N3 Ag1 N1 C8 118.1(3) . .
O1 Ag1 N1 C8 -53.8(3) . .
N3 Ag1 N1 N2 -56.4(3) . .
O1 Ag1 N1 N2 131.8(2) . .
C8 N1 N2 C10 -0.2(4) . .
Ag1 N1 N2 C10 175.5(2) . .
C8 N1 N2 C11 -172.5(3) . .
Ag1 N1 N2 C11 3.2(4) . .
N1 Ag1 N3 C15 66.2(4) . .
O1 Ag1 N3 C15 -122.5(3) . .
N1 Ag1 N3 N4 -94.9(3) . .
O1 Ag1 N3 N4 76.4(3) . .
C15 N3 N4 C17 0.2(5) . .
Ag1 N3 N4 C17 164.8(3) . .
C15 N3 N4 C18 177.1(4) . .
Ag1 N3 N4 C18 -18.3(5) . .
N8 Ag2 N5 C22 -148.9(6) 2_565 .
N8 Ag2 N5 N6 29.8(9) 2_565 .
C22 N5 N6 C24 -0.6(5) . .
Ag2 N5 N6 C24 -179.5(3) . .
C22 N5 N6 C25 -177.1(4) . .
Ag2 N5 N6 C25 4.0(5) . .
C33 N7 N8 C35 -0.1(4) . .
C32 N7 N8 C35 -178.7(3) . .
C33 N7 N8 Ag2 -168.5(3) . 2_565
C32 N7 N8 Ag2 12.9(5) . 2_565
N3 Ag1 O1 C1 86.4(3) . .
N1 Ag1 O1 C1 -101.3(3) . .
Ag1 O1 C1 O2 2.4(6) . .
Ag1 O1 C1 C2 -178.0(2) . .
O2 C1 C2 C7 4.2(5) . .
O1 C1 C2 C7 -175.4(4) . .
O2 C1 C2 C3 -178.2(4) . .
O1 C1 C2 C3 2.3(5) . .
C7 C2 C3 C4 1.8(5) . .
C1 C2 C3 C4 -175.9(3) . .
C2 C3 C4 C5 -1.7(6) . .
C2 C3 C4 S1 175.8(3) . .
O4 S1 C4 C5 -121.3(4) . .
O5 S1 C4 C5 -1.4(4) . .
O3 S1 C4 C5 115.6(4) . .
O4 S1 C4 C3 61.3(4) . .
O5 S1 C4 C3 -178.8(3) . .
O3 S1 C4 C3 -61.8(4) . .
C3 C4 C5 C6 0.7(6) . .
S1 C4 C5 C6 -176.7(4) . .
C4 C5 C6 C7 0.2(7) . .
C3 C2 C7 C6 -0.9(6) . .
C1 C2 C7 C6 176.8(4) . .
C5 C6 C7 C2 0.0(7) . .
N2 N1 C8 C9 0.0(4) . .
Ag1 N1 C8 C9 -175.2(3) . .
N1 C8 C9 C10 0.1(4) . .
N1 N2 C10 C9 0.3(4) . .
C11 N2 C10 C9 171.9(3) . .
C8 C9 C10 N2 -0.3(4) . .
C10 N2 C11 C12 -88.8(4) . .
N1 N2 C11 C12 82.0(4) . .
N2 C11 C12 C13 -17.5(5) . .
N2 C11 C12 C14 163.2(3) . .
C14 C12 C13 C14 0.0(6) . 2_576
C11 C12 C13 C14 -179.3(3) . 2_576
C13 C12 C14 C13 0.0(6) . 2_576
C11 C12 C14 C13 179.3(3) . 2_576
N4 N3 C15 C16 -0.6(5) . .
Ag1 N3 C15 C16 -164.6(3) . .
N3 C15 C16 C17 0.7(6) . .
C15 C16 C17 N4 -0.5(6) . .
N3 N4 C17 C16 0.2(6) . .
C18 N4 C17 C16 -176.3(5) . .
N3 N4 C18 C19 66.9(6) . .
C17 N4 C18 C19 -116.9(5) . .
N4 C18 C19 C21 -125.1(5) . .
N4 C18 C19 C20 57.5(6) . .
C21 C19 C20 C21 -0.3(7) . 2_566
C18 C19 C20 C21 177.1(4) . 2_566
C20 C19 C21 C20 0.3(7) . 2_566
C18 C19 C21 C20 -177.2(4) . 2_566
N6 N5 C22 C23 0.1(5) . .
Ag2 N5 C22 C23 179.0(3) . .
N5 C22 C23 C24 0.4(6) . .
N5 N6 C24 C23 0.8(6) . .
C25 N6 C24 C23 177.1(4) . .
C22 C23 C24 N6 -0.8(6) . .
C24 N6 C25 C26 -69.3(6) . .
N5 N6 C25 C26 106.6(5) . .
N6 C25 C26 C31 121.2(5) . .
N6 C25 C26 C27 -59.4(7) . .
C31 C26 C27 C28 -0.7(8) . .
C25 C26 C27 C28 179.9(5) . .
C26 C27 C28 C29 0.9(9) . .
C27 C28 C29 C30 0.0(7) . .
C27 C28 C29 C32 -178.5(5) . .
C28 C29 C30 C31 -1.2(7) . .
C32 C29 C30 C31 177.3(4) . .
C27 C26 C31 C30 -0.5(7) . .
C25 C26 C31 C30 179.0(5) . .
C29 C30 C31 C26 1.4(7) . .
C33 N7 C32 C29 -101.5(5) . .
N8 N7 C32 C29 76.8(4) . .
C28 C29 C32 N7 -179.9(4) . .
C30 C29 C32 N7 1.7(5) . .
N8 N7 C33 C34 0.5(5) . .
C32 N7 C33 C34 179.0(4) . .
N7 C33 C34 C35 -0.6(5) . .
N7 N8 C35 C34 -0.3(5) . .
Ag2 N8 C35 C34 167.9(3) 2_565 .
C33 C34 C35 N8 0.6(6) . .
