#------------------------------------------------------------------------------
#$Date: 2025-08-23 00:12:46 +0300 (Sat, 23 Aug 2025) $
#$Revision: 301866 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/54/7235423.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7235423
loop_
_publ_author_name
'Bodman, Samantha E.'
'Crowther, Anthony C.'
'Geraghty, Paul B.'
'Fitchett, Christopher M.'
_publ_section_title
;
 Structural control: can [2 × 2] silver grids be formed from
 4,5-disubstituted 3,6-di(2-pyridyl) pyridazines?
;
_journal_issue                   1
_journal_name_full               CrystEngComm
_journal_page_first              81
_journal_paper_doi               10.1039/C4CE01851F
_journal_volume                  17
_journal_year                    2015
_chemical_formula_moiety         'C25 H27 Ag2 N7, C H2 Cl2, 2(F6 P)'
_chemical_formula_sum            'C26 H29 Ag2 Cl2 F12 N7 P2'
_chemical_formula_weight         1016.14
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_audit_creation_date             2014-05-12
_audit_creation_method
;
Olex2 1.2-beta
(compiled 2014.03.20 svn.r2918 for OlexSys, GUI svn.r4816)
;
_cell_angle_alpha                109.104(3)
_cell_angle_beta                 94.569(2)
_cell_angle_gamma                109.486(2)
_cell_formula_units_Z            2
_cell_length_a                   10.8963(2)
_cell_length_b                   13.6018(4)
_cell_length_c                   13.9028(4)
_cell_measurement_reflns_used    23358
_cell_measurement_temperature    120.01(10)
_cell_measurement_theta_max      37.4060
_cell_measurement_theta_min      3.2070
_cell_volume                     1793.81(10)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2013)'
_diffrn_ambient_temperature      120.01(10)
_diffrn_detector_area_resol_mean 5.3250
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      0.0040640000
_diffrn_orient_matrix_UB_12      -0.0335653000
_diffrn_orient_matrix_UB_13      0.0289360000
_diffrn_orient_matrix_UB_21      -0.0705180000
_diffrn_orient_matrix_UB_22      -0.0258093000
_diffrn_orient_matrix_UB_23      -0.0111866000
_diffrn_orient_matrix_UB_31      0.0017285000
_diffrn_orient_matrix_UB_32      -0.0421019000
_diffrn_orient_matrix_UB_33      -0.0457145000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0241
_diffrn_reflns_av_unetI/netI     0.0251
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            30541
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         29.997
_diffrn_reflns_theta_min         2.740
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    1.424
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.82621
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.881
_exptl_crystal_description       block
_exptl_crystal_F_000             1000
_exptl_crystal_size_max          0.29
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.2
_refine_diff_density_max         1.419
_refine_diff_density_min         -1.231
_refine_diff_density_rms         0.108
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     463
_refine_ls_number_reflns         10454
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.044
_refine_ls_R_factor_all          0.0377
_refine_ls_R_factor_gt           0.0325
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0432P)²+2.9145P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0859
_refine_ls_wR_factor_ref         0.0902
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9310
_reflns_number_total             10454
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c4ce01851f1.cif
_cod_data_source_block           2
_cod_original_cell_volume        1793.82(9)
_cod_database_code               7235423
_shelxl_version_number           2014-3
_chemical_oxdiff_formula         'C11 H10 N O'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_reflns_odcompleteness_completeness 99.92
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     27.50
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C4(H4A,H4B), C5(H5A,H5B), C6(H6A,H6B), C7(H7A,H7B), C8(H8A,H8B), C40(H40A,H40B)
2.b Aromatic/amide H refined with riding coordinates:
 C14(H14), C15(H15), C16(H16), C17(H17), C20(H20), C21(H21), C22(H22), C23(H23)
2.c Idealised Me refined as rotating group:
 C32(H32A,H32B,H32C), C35(H35A,H35B,H35C), C38(H38A,H38B,H38C)
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
Ag1 Ag 0.33853(2) 0.34606(2) -0.14951(2) 0.01893(5) Uani 1 1 d .
Ag2 Ag 0.33060(2) 0.57372(2) -0.03469(2) 0.02036(5) Uani 1 1 d .
Cl41 Cl 0.34987(16) 0.22261(10) 0.56756(8) 0.0702(3) Uani 1 1 d .
Cl42 Cl 0.32088(11) 0.08988(9) 0.34804(7) 0.0524(2) Uani 1 1 d .
P10 P 0.23202(7) 0.78384(6) 0.48617(5) 0.02632(13) Uani 1 1 d .
P17 P 0.26292(7) 0.07123(6) 0.05359(6) 0.02878(14) Uani 1 1 d .
F11 F 0.14059(18) 0.73246(18) 0.55628(16) 0.0412(4) Uani 1 1 d .
F12 F 0.2908(3) 0.90298(18) 0.57928(18) 0.0619(7) Uani 1 1 d .
F13 F 0.1165(2) 0.81403(19) 0.44279(18) 0.0493(5) Uani 1 1 d .
F14 F 0.3224(2) 0.8356(2) 0.41623(18) 0.0491(5) Uani 1 1 d .
F15 F 0.1718(2) 0.66370(17) 0.39284(19) 0.0564(6) Uani 1 1 d .
F16 F 0.3474(2) 0.7519(2) 0.5291(2) 0.0593(7) Uani 1 1 d .
F18 F 0.1886(2) 0.14425(19) 0.0268(2) 0.0595(6) Uani 1 1 d .
F19 F 0.16447(19) -0.03802(17) -0.04178(17) 0.0462(5) Uani 1 1 d .
F20 F 0.3625(2) 0.18005(17) 0.15050(17) 0.0487(5) Uani 1 1 d .
F21 F 0.1637(2) 0.0411(2) 0.12694(19) 0.0561(6) Uani 1 1 d .
F22 F 0.3381(2) -0.00287(17) 0.08063(19) 0.0473(5) Uani 1 1 d .
F23 F 0.3632(2) 0.10039(19) -0.01909(19) 0.0528(5) Uani 1 1 d .
N1 N 0.35189(18) 0.39024(16) 0.02901(14) 0.0155(3) Uani 1 1 d .
N11 N 0.46522(18) 0.41896(16) 0.09433(14) 0.0151(3) Uani 1 1 d .
N12 N 0.1288(2) 0.42952(18) -0.05813(15) 0.0192(4) Uani 1 1 d .
N18 N 0.69634(19) 0.56740(17) 0.25988(14) 0.0178(4) Uani 1 1 d .
N30 N 0.2764(3) 0.7011(2) -0.0876(2) 0.0355(5) Uani 1 1 d .
N33 N 0.1960(3) 0.1639(2) -0.2299(2) 0.0434(7) Uani 1 1 d .
N36 N 0.5545(3) 0.3138(2) -0.14320(19) 0.0327(5) Uani 1 1 d .
C2 C 0.2401(2) 0.38311(18) 0.06537(16) 0.0153(4) Uani 1 1 d .
C3 C 0.2354(2) 0.40714(18) 0.17070(16) 0.0151(4) Uani 1 1 d .
C4 C 0.1087(2) 0.3982(2) 0.20886(18) 0.0194(4) Uani 1 1 d .
H4A H 0.0387 0.3817 0.1514 0.023 Uiso 1 1 calc R
H4B H 0.1211 0.4702 0.2617 0.023 Uiso 1 1 calc R
C5 C 0.0644(2) 0.3065(2) 0.25489(19) 0.0240(5) Uani 1 1 d .
H5A H -0.0307 0.2834 0.2520 0.029 Uiso 1 1 calc R
H5B H 0.0802 0.2413 0.2122 0.029 Uiso 1 1 calc R
C6 C 0.1363(2) 0.3446(2) 0.36719(18) 0.0243(5) Uani 1 1 d .
H6A H 0.1206 0.4100 0.4092 0.029 Uiso 1 1 calc R
H6B H 0.0971 0.2852 0.3926 0.029 Uiso 1 1 calc R
C7 C 0.2862(2) 0.3740(2) 0.38384(18) 0.0219(4) Uani 1 1 d .
H7A H 0.3027 0.3087 0.3425 0.026 Uiso 1 1 calc R
H7B H 0.3210 0.3917 0.4565 0.026 Uiso 1 1 calc R
C8 C 0.3620(2) 0.4740(2) 0.35441(16) 0.0182(4) Uani 1 1 d .
H8A H 0.3251 0.5314 0.3778 0.022 Uiso 1 1 calc R
H8B H 0.4547 0.5065 0.3903 0.022 Uiso 1 1 calc R
C9 C 0.3549(2) 0.44060(18) 0.23908(16) 0.0145(4) Uani 1 1 d .
C10 C 0.4668(2) 0.44288(18) 0.19577(16) 0.0148(4) Uani 1 1 d .
C13 C 0.1205(2) 0.35296(19) -0.01505(16) 0.0166(4) Uani 1 1 d .
C14 C 0.0099(2) 0.2546(2) -0.04151(19) 0.0226(4) Uani 1 1 d .
H14 H 0.0079 0.2036 -0.0100 0.027 Uiso 1 1 calc R
C15 C -0.0983(2) 0.2334(3) -0.1160(2) 0.0285(5) Uani 1 1 d .
H15 H -0.1736 0.1675 -0.1359 0.034 Uiso 1 1 calc R
C16 C -0.0916(3) 0.3124(3) -0.1599(2) 0.0291(5) Uani 1 1 d .
H16 H -0.1631 0.3009 -0.2092 0.035 Uiso 1 1 calc R
C17 C 0.0225(3) 0.4084(2) -0.12930(19) 0.0251(5) Uani 1 1 d .
H17 H 0.0261 0.4610 -0.1592 0.030 Uiso 1 1 calc R
C19 C 0.6000(2) 0.47516(19) 0.26047(16) 0.0156(4) Uani 1 1 d .
C20 C 0.6215(2) 0.4121(2) 0.31584(17) 0.0196(4) Uani 1 1 d .
H20 H 0.5522 0.3494 0.3155 0.024 Uiso 1 1 calc R
C21 C 0.7497(3) 0.4452(2) 0.37193(18) 0.0235(5) Uani 1 1 d .
H21 H 0.7681 0.4040 0.4088 0.028 Uiso 1 1 calc R
C22 C 0.8492(2) 0.5403(2) 0.37203(18) 0.0242(5) Uani 1 1 d .
H22 H 0.9355 0.5637 0.4089 0.029 Uiso 1 1 calc R
C23 C 0.8190(2) 0.6002(2) 0.31677(18) 0.0221(5) Uani 1 1 d .
H23 H 0.8857 0.6654 0.3190 0.027 Uiso 1 1 calc R
C31 C 0.3050(3) 0.7659(2) -0.1249(2) 0.0277(5) Uani 1 1 d .
C32 C 0.3429(3) 0.8472(2) -0.1746(2) 0.0314(6) Uani 1 1 d .
H32A H 0.3002 0.8114 -0.2470 0.047 Uiso 1 1 calc GR
H32B H 0.4378 0.8758 -0.1678 0.047 Uiso 1 1 calc GR
H32C H 0.3157 0.9082 -0.1416 0.047 Uiso 1 1 calc GR
C34 C 0.1298(3) 0.0735(3) -0.2532(2) 0.0350(6) Uani 1 1 d .
C35 C 0.0472(4) -0.0439(3) -0.2803(4) 0.0538(10) Uani 1 1 d .
H35A H 0.0920 -0.0901 -0.3162 0.081 Uiso 1 1 calc GR
H35B H -0.0359 -0.0622 -0.3246 0.081 Uiso 1 1 calc GR
H35C H 0.0306 -0.0573 -0.2180 0.081 Uiso 1 1 calc GR
C37 C 0.5374(3) 0.2218(2) -0.1846(2) 0.0261(5) Uani 1 1 d .
C38 C 0.5160(4) 0.1046(3) -0.2355(3) 0.0425(7) Uani 1 1 d .
H38A H 0.5746 0.0974 -0.2830 0.064 Uiso 1 1 calc GR
H38B H 0.4252 0.0631 -0.2731 0.064 Uiso 1 1 calc GR
H38C H 0.5337 0.0753 -0.1841 0.064 Uiso 1 1 calc GR
C40 C 0.3548(4) 0.0992(3) 0.4764(3) 0.0401(7) Uani 1 1 d .
H40A H 0.4423 0.0975 0.4916 0.048 Uiso 1 1 calc R
H40B H 0.2901 0.0342 0.4835 0.048 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 Ag2 66.17(5) . .
N1 Ag1 N36 92.72(7) . .
N18 Ag1 Ag2 67.67(5) 2_665 .
N18 Ag1 N1 133.63(7) 2_665 .
N18 Ag1 N36 115.34(8) 2_665 .
N33 Ag1 Ag2 139.07(8) . .
N33 Ag1 N1 106.51(9) . .
N33 Ag1 N18 105.06(9) . 2_665
N33 Ag1 N36 98.17(10) . .
N36 Ag1 Ag2 121.76(6) . .
N11 Ag2 Ag1 65.70(4) 2_665 .
N12 Ag2 Ag1 68.58(5) . .
N12 Ag2 N11 134.03(7) . 2_665
N12 Ag2 N36 115.53(8) . 2_665
N30 Ag2 Ag1 133.63(7) . .
N30 Ag2 N11 102.54(8) . 2_665
N30 Ag2 N12 105.21(9) . .
N30 Ag2 N36 102.20(9) . 2_665
N36 Ag2 Ag1 122.35(6) 2_665 .
N36 Ag2 N11 93.07(7) 2_665 2_665
F12 P10 F11 89.75(13) . .
F12 P10 F14 90.08(13) . .
F12 P10 F15 179.55(15) . .
F12 P10 F16 90.11(15) . .
F13 P10 F11 89.94(12) . .
F13 P10 F12 90.51(14) . .
F13 P10 F14 89.62(12) . .
F13 P10 F15 89.29(14) . .
F13 P10 F16 179.34(15) . .
F14 P10 F11 179.53(12) . .
F15 P10 F11 89.84(12) . .
F15 P10 F14 90.33(13) . .
F16 P10 F11 89.86(11) . .
F16 P10 F14 90.58(12) . .
F16 P10 F15 90.08(15) . .
F18 P17 F19 90.60(13) . .
F18 P17 F20 90.21(13) . .
F18 P17 F21 90.29(14) . .
F18 P17 F22 179.93(18) . .
F18 P17 F23 90.57(14) . .
F19 P17 F20 179.12(13) . .
F19 P17 F22 89.33(11) . .
F20 P17 F22 89.87(12) . .
F21 P17 F19 89.43(13) . .
F21 P17 F20 90.20(13) . .
F21 P17 F22 89.72(13) . .
F23 P17 F19 90.65(12) . .
F23 P17 F20 89.71(12) . .
F23 P17 F21 179.13(14) . .
F23 P17 F22 89.41(13) . .
N11 N1 Ag1 122.12(13) . .
N11 N1 C2 119.61(18) . .
C2 N1 Ag1 118.25(14) . .
N1 N11 Ag2 121.90(13) . 2_665
N1 N11 C10 119.51(18) . .
C10 N11 Ag2 118.58(14) . 2_665
C13 N12 Ag2 120.87(15) . .
C13 N12 C17 117.4(2) . .
C17 N12 Ag2 120.74(16) . .
C19 N18 Ag1 121.21(14) . 2_665
C19 N18 C23 118.1(2) . .
C23 N18 Ag1 120.26(16) . 2_665
C31 N30 Ag2 147.9(2) . .
C34 N33 Ag1 168.2(3) . .
Ag2 N36 Ag1 102.45(9) 2_665 .
C37 N36 Ag1 112.0(2) . .
C37 N36 Ag2 124.9(2) . 2_665
N1 C2 C3 123.5(2) . .
N1 C2 C13 114.48(18) . .
C3 C2 C13 121.91(19) . .
C2 C3 C4 122.23(19) . .
C9 C3 C2 116.62(19) . .
C9 C3 C4 121.15(19) . .
C3 C4 H4A 109.0 . .
C3 C4 H4B 109.0 . .
C3 C4 C5 112.8(2) . .
H4A C4 H4B 107.8 . .
C5 C4 H4A 109.0 . .
C5 C4 H4B 109.0 . .
C4 C5 H5A 108.9 . .
C4 C5 H5B 108.9 . .
H5A C5 H5B 107.7 . .
C6 C5 C4 113.4(2) . .
C6 C5 H5A 108.9 . .
C6 C5 H5B 108.9 . .
C5 C6 H6A 108.4 . .
C5 C6 H6B 108.4 . .
H6A C6 H6B 107.5 . .
C7 C6 C5 115.51(19) . .
C7 C6 H6A 108.4 . .
C7 C6 H6B 108.4 . .
C6 C7 H7A 108.9 . .
C6 C7 H7B 108.9 . .
C6 C7 C8 113.5(2) . .
H7A C7 H7B 107.7 . .
C8 C7 H7A 108.9 . .
C8 C7 H7B 108.9 . .
C7 C8 H8A 109.1 . .
C7 C8 H8B 109.1 . .
H8A C8 H8B 107.8 . .
C9 C8 C7 112.60(18) . .
C9 C8 H8A 109.1 . .
C9 C8 H8B 109.1 . .
C3 C9 C8 120.83(19) . .
C3 C9 C10 116.96(19) . .
C10 C9 C8 122.20(19) . .
N11 C10 C9 123.69(19) . .
N11 C10 C19 114.13(18) . .
C9 C10 C19 122.16(18) . .
N12 C13 C2 114.65(19) . .
N12 C13 C14 123.1(2) . .
C14 C13 C2 122.2(2) . .
C13 C14 H14 120.6 . .
C13 C14 C15 118.8(2) . .
C15 C14 H14 120.6 . .
C14 C15 H15 120.7 . .
C16 C15 C14 118.6(2) . .
C16 C15 H15 120.7 . .
C15 C16 H16 120.5 . .
C17 C16 C15 119.0(2) . .
C17 C16 H16 120.5 . .
N12 C17 C16 123.0(2) . .
N12 C17 H17 118.5 . .
C16 C17 H17 118.5 . .
N18 C19 C10 115.56(19) . .
N18 C19 C20 123.1(2) . .
C20 C19 C10 121.3(2) . .
C19 C20 H20 120.9 . .
C19 C20 C21 118.1(2) . .
C21 C20 H20 120.9 . .
C20 C21 H21 120.5 . .
C22 C21 C20 119.1(2) . .
C22 C21 H21 120.5 . .
C21 C22 H22 120.4 . .
C21 C22 C23 119.3(2) . .
C23 C22 H22 120.4 . .
N18 C23 C22 122.3(2) . .
N18 C23 H23 118.9 . .
C22 C23 H23 118.9 . .
N30 C31 C32 178.6(3) . .
C31 C32 H32A 109.5 . .
C31 C32 H32B 109.5 . .
C31 C32 H32C 109.5 . .
H32A C32 H32B 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
N33 C34 C35 177.8(4) . .
C34 C35 H35A 109.5 . .
C34 C35 H35B 109.5 . .
C34 C35 H35C 109.5 . .
H35A C35 H35B 109.5 . .
H35A C35 H35C 109.5 . .
H35B C35 H35C 109.5 . .
N36 C37 C38 178.9(3) . .
C37 C38 H38A 109.5 . .
C37 C38 H38B 109.5 . .
C37 C38 H38C 109.5 . .
H38A C38 H38B 109.5 . .
H38A C38 H38C 109.5 . .
H38B C38 H38C 109.5 . .
Cl41 C40 H40A 109.0 . .
Cl41 C40 H40B 109.0 . .
Cl42 C40 Cl41 112.71(19) . .
Cl42 C40 H40A 109.0 . .
Cl42 C40 H40B 109.0 . .
H40A C40 H40B 107.8 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 Ag2 3.0182(3) .
Ag1 N1 2.3346(18) .
Ag1 N18 2.296(2) 2_665
Ag1 N33 2.268(3) .
Ag1 N36 2.534(2) .
Ag2 N11 2.4181(18) 2_665
Ag2 N12 2.319(2) .
Ag2 N30 2.310(2) .
Ag2 N36 2.404(2) 2_665
Cl41 C40 1.762(3) .
Cl42 C40 1.747(4) .
P10 F11 1.6022(19) .
P10 F12 1.586(2) .
P10 F13 1.582(2) .
P10 F14 1.597(2) .
P10 F15 1.596(2) .
P10 F16 1.594(2) .
P17 F18 1.585(2) .
P17 F19 1.593(2) .
P17 F20 1.604(2) .
P17 F21 1.591(2) .
P17 F22 1.606(2) .
P17 F23 1.588(2) .
N1 N11 1.330(2) .
N1 C2 1.341(3) .
N11 Ag2 2.4181(18) 2_665
N11 C10 1.337(3) .
N12 C13 1.344(3) .
N12 C17 1.346(3) .
N18 Ag1 2.296(2) 2_665
N18 C19 1.344(3) .
N18 C23 1.347(3) .
N30 C31 1.135(4) .
N33 C34 1.118(4) .
N36 Ag2 2.404(2) 2_665
N36 C37 1.134(4) .
C2 C3 1.401(3) .
C2 C13 1.493(3) .
C3 C4 1.500(3) .
C3 C9 1.389(3) .
C4 H4A 0.9700 .
C4 H4B 0.9700 .
C4 C5 1.540(3) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C5 C6 1.525(3) .
C6 H6A 0.9700 .
C6 H6B 0.9700 .
C6 C7 1.524(3) .
C7 H7A 0.9700 .
C7 H7B 0.9700 .
C7 C8 1.539(3) .
C8 H8A 0.9700 .
C8 H8B 0.9700 .
C8 C9 1.504(3) .
C9 C10 1.398(3) .
C10 C19 1.489(3) .
C13 C14 1.382(3) .
C14 H14 0.9300 .
C14 C15 1.388(3) .
C15 H15 0.9300 .
C15 C16 1.384(4) .
C16 H16 0.9300 .
C16 C17 1.379(4) .
C17 H17 0.9300 .
C19 C20 1.386(3) .
C20 H20 0.9300 .
C20 C21 1.393(3) .
C21 H21 0.9300 .
C21 C22 1.382(4) .
C22 H22 0.9300 .
C22 C23 1.383(4) .
C23 H23 0.9300 .
C31 C32 1.452(4) .
C32 H32A 0.9600 .
C32 H32B 0.9600 .
C32 H32C 0.9600 .
C34 C35 1.447(4) .
C35 H35A 0.9600 .
C35 H35B 0.9600 .
C35 H35C 0.9600 .
C37 C38 1.443(4) .
C38 H38A 0.9600 .
C38 H38B 0.9600 .
C38 H38C 0.9600 .
C40 H40A 0.9700 .
C40 H40B 0.9700 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Ag1 N1 N11 Ag2 -0.8(2) . 2_665
Ag1 N1 N11 C10 -179.68(15) . .
Ag1 N1 C2 C3 179.83(16) . .
Ag1 N1 C2 C13 -3.2(2) . .
Ag1 N18 C19 C10 -7.5(3) 2_665 .
Ag1 N18 C19 C20 171.60(17) 2_665 .
Ag1 N18 C23 C22 -170.06(18) 2_665 .
Ag2 N11 C10 C9 -179.51(16) 2_665 .
Ag2 N11 C10 C19 1.8(2) 2_665 .
Ag2 N12 C13 C2 13.0(3) . .
Ag2 N12 C13 C14 -167.77(18) . .
Ag2 N12 C17 C16 167.9(2) . .
N1 N11 C10 C9 -0.6(3) . .
N1 N11 C10 C19 -179.24(18) . .
N1 C2 C3 C4 -179.9(2) . .
N1 C2 C3 C9 0.4(3) . .
N1 C2 C13 N12 -64.1(3) . .
N1 C2 C13 C14 116.8(2) . .
N11 N1 C2 C3 1.6(3) . .
N11 N1 C2 C13 178.57(19) . .
N11 C10 C19 N18 60.9(3) . .
N11 C10 C19 C20 -118.2(2) . .
N12 C13 C14 C15 -0.1(4) . .
N18 C19 C20 C21 -1.1(3) . .
C2 N1 N11 Ag2 177.37(15) . 2_665
C2 N1 N11 C10 -1.5(3) . .
C2 C3 C4 C5 115.6(2) . .
C2 C3 C9 C8 176.9(2) . .
C2 C3 C9 C10 -2.4(3) . .
C2 C13 C14 C15 179.0(2) . .
C3 C2 C13 N12 112.9(2) . .
C3 C2 C13 C14 -66.2(3) . .
C3 C4 C5 C6 81.4(3) . .
C3 C9 C10 N11 2.6(3) . .
C3 C9 C10 C19 -178.9(2) . .
C4 C3 C9 C8 -2.8(3) . .
C4 C3 C9 C10 178.0(2) . .
C4 C5 C6 C7 -63.7(3) . .
C5 C6 C7 C8 62.7(3) . .
C6 C7 C8 C9 -80.5(2) . .
C7 C8 C9 C3 68.2(3) . .
C7 C8 C9 C10 -112.6(2) . .
C8 C9 C10 N11 -176.7(2) . .
C8 C9 C10 C19 1.9(3) . .
C9 C3 C4 C5 -64.8(3) . .
C9 C10 C19 N18 -117.8(2) . .
C9 C10 C19 C20 63.1(3) . .
C10 C19 C20 C21 177.9(2) . .
C13 N12 C17 C16 -0.8(4) . .
C13 C2 C3 C4 3.3(3) . .
C13 C2 C3 C9 -176.3(2) . .
C13 C14 C15 C16 -0.8(4) . .
C14 C15 C16 C17 0.9(4) . .
C15 C16 C17 N12 -0.1(4) . .
C17 N12 C13 C2 -178.3(2) . .
C17 N12 C13 C14 0.9(3) . .
C19 N18 C23 C22 2.3(3) . .
C19 C20 C21 C22 1.3(3) . .
C20 C21 C22 C23 0.2(4) . .
C21 C22 C23 N18 -2.0(4) . .
C23 N18 C19 C10 -179.8(2) . .
C23 N18 C19 C20 -0.6(3) . .
loop_
_cod_related_entry_id
_cod_related_entry_database
_cod_related_entry_code
1 PubChem 168339267
