#------------------------------------------------------------------------------
#$Date: 2019-11-23 09:48:32 +0200 (Sat, 23 Nov 2019) $
#$Revision: 232774 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/54/7235427.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7235427
loop_
_publ_author_name
'Bodman, Samantha E.'
'Crowther, Anthony C.'
'Geraghty, Paul B.'
'Fitchett, Christopher M.'
_publ_section_title
;
 Structural control: can [2 × 2] silver grids be formed from
 4,5-disubstituted 3,6-di(2-pyridyl) pyridazines?
;
_journal_issue                   1
_journal_name_full               CrystEngComm
_journal_page_first              81
_journal_paper_doi               10.1039/C4CE01851F
_journal_volume                  17
_journal_year                    2015
_chemical_formula_moiety
'2(C34 H28 Ag2 N8), 2(C H2 Cl2), 4(B F4), H2 O'
_chemical_formula_sum            'C70 H62 Ag4 B4 Cl4 F16 N16 O'
_chemical_formula_weight         2063.87
_space_group_crystal_system      monoclinic
_space_group_IT_number           13
_space_group_name_Hall           '-P 2yac'
_space_group_name_H-M_alt        'P 1 2/n 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_audit_creation_date             2014-05-12
_audit_creation_method
;
Olex2 1.2-beta
(compiled 2014.03.20 svn.r2918 for OlexSys, GUI svn.r4816)
;
_cell_angle_alpha                90
_cell_angle_beta                 102.5639(7)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   23.76695(15)
_cell_length_b                   13.12396(9)
_cell_length_c                   25.09710(17)
_cell_measurement_reflns_used    35616
_cell_measurement_temperature    120.01(10)
_cell_measurement_theta_max      75.7774
_cell_measurement_theta_min      2.8920
_cell_volume                     7640.75(9)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_diffrn_ambient_temperature      120.01(10)
_diffrn_detector_area_resol_mean 10.6501
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_details
;
#__ type_ start__ end____ width___ exp.time_
  1 omega  -78.00   -1.00   1.0000    6.1800
omega____ theta____ kappa____ phi______ frames
    -      -39.9218  124.0000  117.0000 77

#__ type_ start__ end____ width___ exp.time_
  2 omega   65.00  132.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000 -147.0000 -126.0000 67

#__ type_ start__ end____ width___ exp.time_
  3 omega   30.00   56.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000    9.0000  118.0000 26

#__ type_ start__ end____ width___ exp.time_
  4 omega   88.00  177.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000    9.0000  118.0000 89

#__ type_ start__ end____ width___ exp.time_
  5 omega   81.00  157.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000  147.0000  103.0000 76

#__ type_ start__ end____ width___ exp.time_
  6 omega  -43.00   34.00   1.0000    6.1800
omega____ theta____ kappa____ phi______ frames
    -      -39.9218   37.0000  120.0000 77

#__ type_ start__ end____ width___ exp.time_
  7 omega -111.00  -86.00   1.0000    6.1800
omega____ theta____ kappa____ phi______ frames
    -      -39.9218 -147.0000 -103.0000 25

#__ type_ start__ end____ width___ exp.time_
  8 omega  -32.00    4.00   1.0000    6.1800
omega____ theta____ kappa____ phi______ frames
    -      -39.9218   37.0000 -180.0000 36

#__ type_ start__ end____ width___ exp.time_
  9 omega  -28.00   36.00   1.0000    6.1800
omega____ theta____ kappa____ phi______ frames
    -      -39.9218   37.0000   60.0000 64

#__ type_ start__ end____ width___ exp.time_
 10 omega   58.00   94.00   1.0000    6.1800
omega____ theta____ kappa____ phi______ frames
    -       39.9218 -125.0000    0.0000 36

#__ type_ start__ end____ width___ exp.time_
 11 omega   72.00  148.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000  178.0000 -120.0000 76

#__ type_ start__ end____ width___ exp.time_
 12 omega  107.00  178.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000   30.0000  -30.0000 71

#__ type_ start__ end____ width___ exp.time_
 13 omega   38.00  111.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000 -111.0000   60.0000 73

#__ type_ start__ end____ width___ exp.time_
 14 omega   29.00   90.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000  -94.0000   90.0000 61

#__ type_ start__ end____ width___ exp.time_
 15 omega  117.00  166.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000  124.0000  -38.0000 49

#__ type_ start__ end____ width___ exp.time_
 16 omega   77.00  116.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000 -111.0000   90.0000 39

#__ type_ start__ end____ width___ exp.time_
 17 omega   38.00   88.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000  -45.0000 -120.0000 50

#__ type_ start__ end____ width___ exp.time_
 18 omega   32.00   58.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000  -94.0000 -180.0000 26

#__ type_ start__ end____ width___ exp.time_
 19 omega   79.00  105.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000  -94.0000 -180.0000 26

#__ type_ start__ end____ width___ exp.time_
 20 omega   29.00   89.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000  -94.0000  -90.0000 60

#__ type_ start__ end____ width___ exp.time_
 21 omega   63.00   88.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000  -30.0000 -180.0000 25

#__ type_ start__ end____ width___ exp.time_
 22 omega   72.00   98.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000  -45.0000   30.0000 26

#__ type_ start__ end____ width___ exp.time_
 23 omega -114.00  -10.00   1.0000    6.1800
omega____ theta____ kappa____ phi______ frames
    -      -39.9218  -57.0000   90.0000 104

#__ type_ start__ end____ width___ exp.time_
 24 omega -114.00  -10.00   1.0000    6.1800
omega____ theta____ kappa____ phi______ frames
    -      -39.9218  -57.0000  -30.0000 104

#__ type_ start__ end____ width___ exp.time_
 25 omega -114.00  -10.00   1.0000    6.1800
omega____ theta____ kappa____ phi______ frames
    -      -39.9218  -57.0000 -150.0000 104

#__ type_ start__ end____ width___ exp.time_
 26 omega    1.00   29.00   1.0000    6.1800
omega____ theta____ kappa____ phi______ frames
    -       39.9218   91.0000   13.0000 28

#__ type_ start__ end____ width___ exp.time_
 27 omega   34.00   91.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000  -30.0000  150.0000 57

#__ type_ start__ end____ width___ exp.time_
 28 omega   84.00  178.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000   45.0000 -180.0000 94

#__ type_ start__ end____ width___ exp.time_
 29 omega   81.00  178.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000   30.0000 -120.0000 97

#__ type_ start__ end____ width___ exp.time_
 30 omega   78.00  164.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000   77.0000   30.0000 86

#__ type_ start__ end____ width___ exp.time_
 31 omega   82.00  178.00   1.0000   24.7000
omega____ theta____ kappa____ phi______ frames
    -      112.0000   61.0000  -90.0000 96
;
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      0.0646012000
_diffrn_orient_matrix_UB_12      0.0236606000
_diffrn_orient_matrix_UB_13      0.0062609000
_diffrn_orient_matrix_UB_21      0.0125710000
_diffrn_orient_matrix_UB_22      -0.1145780000
_diffrn_orient_matrix_UB_23      -0.0039534000
_diffrn_orient_matrix_UB_31      -0.0088825000
_diffrn_orient_matrix_UB_32      0.0095807000
_diffrn_orient_matrix_UB_33      -0.0624552000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0271
_diffrn_reflns_av_unetI/netI     0.0183
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            81531
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         75.966
_diffrn_reflns_theta_min         2.894
_diffrn_source                   'SuperNova (Cu) X-ray Source'
_exptl_absorpt_coefficient_mu    10.224
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.61505
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.794
_exptl_crystal_description       block
_exptl_crystal_F_000             4013
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.12
_refine_diff_density_max         1.604
_refine_diff_density_min         -1.359
_refine_diff_density_rms         0.104
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1081
_refine_ls_number_reflns         15848
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.042
_refine_ls_R_factor_all          0.0691
_refine_ls_R_factor_gt           0.0586
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0744P)²+28.9034P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1558
_refine_ls_wR_factor_ref         0.1671
_reflns_Friedel_coverage         0.000
_reflns_number_gt                13529
_reflns_number_total             15848
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c4ce01851f1.cif
_cod_data_source_block           6
_cod_original_cell_volume        7640.74(9)
_cod_database_code               7235427
_shelxl_version_number           2014-3
_chemical_oxdiff_formula         C17H14N4B1F4AG1
_chemical_oxdiff_usercomment     7490
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_reflns_odcompleteness_completeness 99.94
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     74.33
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All O(H,H) groups
2. Others
 Sof(Ag7)=1-FVAR(1)
 Sof(Ag5)=Sof(Ag9)=0.5*(1-FVAR(2))
 Sof(Ag4)=Sof(Ag8)=0.5*FVAR(2)
 Sof(Ag6)=FVAR(1)
 Sof(F24)=1-FVAR(2)
 Sof(F21)=FVAR(2)
 Sof(F28)=1-FVAR(3)
 Sof(F30)=FVAR(3)
3.a Free rotating group:
 O93(H93A,H93B)
3.b Secondary CH2 refined with riding coordinates:
 C5(H5A,H5B), C6(H6A,H6B), C7(H7A,H7B), C27(H27A,H27B), C28(H28A,H28B),
 C29(H29A,H29B), C48(H48A,H48B), C50(H50A,H50B), C51(H51A,H51B), C70(H70A,H70B),
  C71(H71A,H71B), C72(H72A,H72B), C87(H87A,H87B), C90(H90A,H90B)
3.c Aromatic/amide H refined with riding coordinates:
 C13(H13), C14(H14), C15(H15), C16(H16), C19(H19), C20(H20), C21(H21),
 C22(H22), C34(H34), C35(H35), C36(H36), C37(H37), C40(H40), C41(H41), C42(H42),
  C43(H43), C56(H56), C57(H57), C58(H58), C59(H59), C62(H62), C63(H63),
 C64(H64), C65(H65), C77(H77), C78(H78), C79(H79), C80(H80), C83(H83), C84(H84),
  C85(H85), C86(H86)
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.67093(2) 0.57531(3) 0.20602(2) 0.05048(11) Uani 1 1 d . . . . .
Ag2 Ag 0.7500 0.34546(4) 0.2500 0.05216(15) Uani 1 2 d S T P . .
Ag3 Ag 0.7500 0.80433(4) 0.2500 0.04189(12) Uani 1 2 d S T P . .
Ag4 Ag 0.2500 0.5356(3) 0.2500 0.0783(9) Uani 0.471(3) 2 d S T P A 1
Ag5 Ag 0.2500 0.49196(13) 0.2500 0.0434(4) Uani 0.529(3) 2 d S T P A 2
Ag6 Ag 0.26057(6) 0.32164(19) 0.32767(6) 0.0618(4) Uani 0.471(3) 1 d . . . A 1
Ag7 Ag 0.24655(6) 0.27529(13) 0.32494(5) 0.0530(3) Uani 0.529(3) 1 d . . . A 2
Ag8 Ag 0.2500 0.10766(15) 0.2500 0.0500(5) Uani 0.471(3) 2 d S T P A 1
Ag9 Ag 0.2500 0.03230(16) 0.2500 0.0650(5) Uani 0.529(3) 2 d S T P A 2
Cl88 Cl 0.65055(12) -0.02686(18) 0.59450(10) 0.1022(7) Uani 1 1 d . . . . .
Cl89 Cl 0.67675(13) 0.1141(2) 0.51442(10) 0.1066(7) Uani 1 1 d . . . . .
Cl91 Cl 0.55214(12) 0.7281(2) 0.03221(15) 0.1357(12) Uani 1 1 d . . . B 1
Cl92 Cl 0.44796(14) 0.8093(3) 0.05295(16) 0.1352(11) Uani 1 1 d . . . B 1
F11 F 0.79480(17) 0.3660(3) 0.63927(15) 0.0673(9) Uani 1 1 d . . . . .
F12 F 0.8540(2) 0.3269(5) 0.5836(2) 0.114(2) Uani 1 1 d . . . . .
F13 F 0.8241(3) 0.4866(4) 0.58805(19) 0.119(2) Uani 1 1 d . . . . .
F14 F 0.76235(19) 0.3679(4) 0.54840(17) 0.0924(14) Uani 1 1 d . . . . .
F16 F 0.53166(18) 0.4223(3) 0.30176(16) 0.0731(10) Uani 1 1 d . . . . .
F17 F 0.59497(15) 0.2914(2) 0.31936(15) 0.0615(8) Uani 1 1 d . . . . .
F18 F 0.5858(2) 0.3851(4) 0.24140(17) 0.0840(12) Uani 1 1 d . . . . .
F19 F 0.51390(17) 0.2762(3) 0.25196(15) 0.0714(10) Uani 1 1 d . . . . .
F21 F 0.5840(4) 0.1427(14) 0.1686(5) 0.107(6) Uani 0.430(14) 1 d . . . . .
F22 F 0.6041(4) -0.0101(5) 0.1397(2) 0.140(3) Uani 1 1 d . . . . .
F23 F 0.5388(3) 0.0872(8) 0.0894(3) 0.184(4) Uani 1 1 d . . . . .
F24 F 0.5237(5) -0.0509(12) 0.1384(5) 0.151(7) Uani 0.570(14) 1 d . . . . .
F25 F 0.5365(9) 0.0618(9) 0.1791(5) 0.281(9) Uani 1 1 d . . . . .
F27 F 0.4414(5) 0.1483(8) 0.5740(4) 0.198(4) Uani 1 1 d . . . . .
F28 F 0.4282(4) 0.1979(12) 0.4952(4) 0.196(7) Uani 0.760(13) 1 d . . . C 1
F29 F 0.5033(6) 0.1432(9) 0.5207(6) 0.274(7) Uani 1 1 d . . . . .
F30 F 0.5053(9) 0.1175(11) 0.5845(7) 0.081(7) Uani 0.240(13) 1 d . . . C 2
F31 F 0.4843(5) 0.2816(6) 0.5558(5) 0.203(4) Uani 1 1 d . . . . .
O93 O 0.1396(5) 0.1076(13) 0.5303(3) 0.240(8) Uani 1 1 d . . . . .
H93A H 0.1452 0.0823 0.5622 0.361 Uiso 1 1 d G . . . .
H93B H 0.1102 0.0798 0.5101 0.361 Uiso 1 1 d G . . . .
N1 N 0.70359(17) 0.6762(3) 0.14301(17) 0.0422(9) Uani 1 1 d . . . . .
N2 N 0.73346(17) 0.7615(3) 0.15934(16) 0.0406(8) Uani 1 1 d . . . . .
N11 N 0.80012(18) 0.9156(3) 0.20420(18) 0.0420(9) Uani 1 1 d . . . . .
N17 N 0.64872(17) 0.4983(4) 0.1236(2) 0.0497(10) Uani 1 1 d . . . . .
N23 N 0.71467(16) 0.4563(3) 0.31242(17) 0.0409(9) Uani 1 1 d . . . . .
N24 N 0.68354(16) 0.5391(3) 0.29437(18) 0.0402(9) Uani 1 1 d . . . . .
N32 N 0.61062(17) 0.6841(3) 0.2436(2) 0.0523(11) Uani 1 1 d . . . . .
N38 N 0.7667(2) 0.2740(4) 0.3348(2) 0.0546(11) Uani 1 1 d . . . . .
N44 N 0.16576(19) 0.3698(4) 0.29730(19) 0.0537(11) Uani 1 1 d . . . . .
N45 N 0.16422(16) 0.4550(4) 0.26838(18) 0.0503(11) Uani 1 1 d . . . . .
N54 N 0.1753(2) 0.6312(4) 0.2192(2) 0.0590(12) Uani 1 1 d . . . . .
N60 N 0.1865(3) 0.2129(5) 0.3662(2) 0.0744(17) Uani 1 1 d . . . . .
N66 N 0.3371(2) 0.2396(4) 0.3085(2) 0.0617(14) Uani 1 1 d . . . . .
N67 N 0.33598(19) 0.1553(4) 0.2797(2) 0.0564(12) Uani 1 1 d . . . . .
N75 N 0.3237(2) -0.0290(4) 0.2312(3) 0.0714(16) Uani 1 1 d . . . . .
N81 N 0.3293(3) 0.3944(5) 0.3771(2) 0.079(2) Uani 1 1 d . . . . .
C3 C 0.7600(2) 0.8132(4) 0.1259(2) 0.0435(11) Uani 1 1 d . . . . .
C4 C 0.7601(3) 0.7741(4) 0.0739(2) 0.0511(12) Uani 1 1 d . . . . .
C5 C 0.7903(3) 0.8121(5) 0.0305(2) 0.0638(16) Uani 1 1 d . . . . .
H5A H 0.8297 0.8323 0.0464 0.077 Uiso 1 1 calc R . . . .
H5B H 0.7700 0.8693 0.0107 0.077 Uiso 1 1 calc R . . . .
C6 C 0.7886(3) 0.7191(5) -0.0064(2) 0.0664(17) Uani 1 1 d . . . . .
H6A H 0.8235 0.6791 0.0046 0.080 Uiso 1 1 calc R . . . .
H6B H 0.7849 0.7399 -0.0441 0.080 Uiso 1 1 calc R . . . .
C7 C 0.7355(3) 0.6567(5) 0.0003(2) 0.0645(16) Uani 1 1 d . . . . .
H7A H 0.7015 0.6754 -0.0271 0.077 Uiso 1 1 calc R . . . .
H7B H 0.7422 0.5841 -0.0022 0.077 Uiso 1 1 calc R . . . .
C8 C 0.7289(3) 0.6861(4) 0.0572(2) 0.0496(12) Uani 1 1 d . . . . .
C10 C 0.6993(2) 0.6393(4) 0.0923(2) 0.0459(11) Uani 1 1 d . . . . .
C12 C 0.7887(2) 0.9090(4) 0.1497(2) 0.0450(11) Uani 1 1 d . . . . .
C13 C 0.8029(3) 0.9880(4) 0.1175(3) 0.0617(15) Uani 1 1 d . . . . .
H13 H 0.7939 0.9831 0.0796 0.074 Uiso 1 1 calc R . . . .
C14 C 0.8306(3) 1.0734(4) 0.1430(3) 0.0673(18) Uani 1 1 d . . . . .
H14 H 0.8401 1.1269 0.1223 0.081 Uiso 1 1 calc R . . . .
C15 C 0.8439(3) 1.0793(4) 0.1990(3) 0.0583(15) Uani 1 1 d . . . . .
H15 H 0.8633 1.1353 0.2169 0.070 Uiso 1 1 calc R . . . .
C16 C 0.8276(2) 0.9993(4) 0.2277(2) 0.0496(12) Uani 1 1 d . . . . .
H16 H 0.8360 1.0033 0.2656 0.059 Uiso 1 1 calc R . . . .
C18 C 0.6610(2) 0.5465(5) 0.0803(2) 0.0532(13) Uani 1 1 d . . . . .
C19 C 0.6386(3) 0.5147(6) 0.0277(3) 0.0699(18) Uani 1 1 d . . . . .
H19 H 0.6469 0.5493 -0.0020 0.084 Uiso 1 1 calc R . . . .
C20 C 0.6027(3) 0.4280(7) 0.0203(3) 0.087(3) Uani 1 1 d . . . . .
H20 H 0.5876 0.4036 -0.0146 0.105 Uiso 1 1 calc R . . . .
C21 C 0.5902(3) 0.3799(7) 0.0644(3) 0.078(2) Uani 1 1 d . . . . .
H21 H 0.5657 0.3238 0.0601 0.094 Uiso 1 1 calc R . . . .
C22 C 0.6144(2) 0.4163(5) 0.1150(3) 0.0612(16) Uani 1 1 d . . . . .
H22 H 0.6067 0.3825 0.1452 0.073 Uiso 1 1 calc R . . . .
C25 C 0.64638(19) 0.5789(4) 0.3224(2) 0.0420(11) Uani 1 1 d . . . . .
C26 C 0.6378(2) 0.5328(4) 0.3695(2) 0.0434(11) Uani 1 1 d . . . . .
C27 C 0.5938(2) 0.5531(5) 0.4034(3) 0.0545(14) Uani 1 1 d . . . . .
H27A H 0.5563 0.5676 0.3804 0.065 Uiso 1 1 calc R . . . .
H27B H 0.6054 0.6100 0.4280 0.065 Uiso 1 1 calc R . . . .
C28 C 0.5927(2) 0.4547(5) 0.4349(2) 0.0573(14) Uani 1 1 d . . . . .
H28A H 0.5621 0.4104 0.4160 0.069 Uiso 1 1 calc R . . . .
H28B H 0.5866 0.4685 0.4712 0.069 Uiso 1 1 calc R . . . .
C29 C 0.6522(2) 0.4049(5) 0.4381(2) 0.0543(13) Uani 1 1 d . . . . .
H29A H 0.6791 0.4237 0.4715 0.065 Uiso 1 1 calc R . . . .
H29B H 0.6491 0.3312 0.4360 0.065 Uiso 1 1 calc R . . . .
C30 C 0.6703(2) 0.4479(4) 0.3888(2) 0.0441(11) Uani 1 1 d . . . . .
C31 C 0.7101(2) 0.4121(4) 0.3592(2) 0.0436(11) Uani 1 1 d . . . . .
C33 C 0.6156(2) 0.6724(4) 0.2977(3) 0.0490(13) Uani 1 1 d . . . . .
C34 C 0.5949(3) 0.7441(4) 0.3293(3) 0.0645(18) Uani 1 1 d . . . . .
H34 H 0.5992 0.7342 0.3667 0.077 Uiso 1 1 calc R . . . .
C35 C 0.5679(3) 0.8304(5) 0.3045(5) 0.086(3) Uani 1 1 d . . . . .
H35 H 0.5533 0.8790 0.3247 0.103 Uiso 1 1 calc R . . . .
C36 C 0.5630(3) 0.8431(5) 0.2488(5) 0.086(3) Uani 1 1 d . . . . .
H36 H 0.5455 0.9009 0.2310 0.103 Uiso 1 1 calc R . . . .
C37 C 0.5847(2) 0.7684(4) 0.2202(3) 0.0652(18) Uani 1 1 d . . . . .
H37 H 0.5811 0.7770 0.1828 0.078 Uiso 1 1 calc R . . . .
C39 C 0.7478(2) 0.3219(4) 0.3752(2) 0.0484(12) Uani 1 1 d . . . . .
C40 C 0.7649(3) 0.2915(5) 0.4290(3) 0.0627(15) Uani 1 1 d . . . . .
H40 H 0.7522 0.3272 0.4562 0.075 Uiso 1 1 calc R . . . .
C41 C 0.8009(3) 0.2079(6) 0.4426(3) 0.079(2) Uani 1 1 d . . . . .
H41 H 0.8124 0.1864 0.4787 0.094 Uiso 1 1 calc R . . . .
C42 C 0.8191(3) 0.1577(6) 0.4014(4) 0.084(2) Uani 1 1 d . . . . .
H42 H 0.8429 0.1008 0.4089 0.100 Uiso 1 1 calc R . . . .
C43 C 0.8011(3) 0.1935(5) 0.3480(3) 0.0736(19) Uani 1 1 d . . . . .
H43 H 0.8138 0.1596 0.3202 0.088 Uiso 1 1 calc R . . . .
C46 C 0.12085(18) 0.5224(4) 0.2651(2) 0.0414(10) Uani 1 1 d . . . . .
C47 C 0.07834(18) 0.5066(4) 0.2948(2) 0.0418(11) Uani 1 1 d . . . . .
C48 C 0.0295(2) 0.5742(4) 0.3030(3) 0.0529(13) Uani 1 1 d . . . . .
H48A H -0.0037 0.5678 0.2730 0.063 Uiso 1 1 calc R . . . .
H48B H 0.0413 0.6450 0.3069 0.063 Uiso 1 1 calc R . . . .
C50 C 0.0167(2) 0.5328(5) 0.3559(3) 0.0632(16) Uani 1 1 d . . . . .
H50A H -0.0241 0.5393 0.3556 0.076 Uiso 1 1 calc R . . . .
H50B H 0.0386 0.5694 0.3871 0.076 Uiso 1 1 calc R . . . .
C51 C 0.0346(2) 0.4198(5) 0.3581(3) 0.0556(14) Uani 1 1 d . . . . .
H51A H 0.0496 0.3978 0.3954 0.067 Uiso 1 1 calc R . . . .
H51B H 0.0024 0.3765 0.3416 0.067 Uiso 1 1 calc R . . . .
C52 C 0.08068(19) 0.4184(4) 0.3254(2) 0.0437(11) Uani 1 1 d . . . . .
C53 C 0.1246(2) 0.3493(4) 0.3241(2) 0.0505(12) Uani 1 1 d . . . . .
C55 C 0.1234(2) 0.6117(4) 0.2295(2) 0.0495(12) Uani 1 1 d . . . . .
C56 C 0.0746(3) 0.6687(5) 0.2061(3) 0.0606(14) Uani 1 1 d . . . . .
H56 H 0.0386 0.6516 0.2123 0.073 Uiso 1 1 calc R . . . .
C57 C 0.0809(4) 0.7511(6) 0.1735(3) 0.082(2) Uani 1 1 d . . . . .
H57 H 0.0494 0.7913 0.1580 0.098 Uiso 1 1 calc R . . . .
C58 C 0.1353(5) 0.7724(6) 0.1643(3) 0.092(3) Uani 1 1 d . . . . .
H58 H 0.1412 0.8276 0.1430 0.111 Uiso 1 1 calc R . . . .
C59 C 0.1803(4) 0.7093(6) 0.1878(3) 0.082(2) Uani 1 1 d . . . . .
H59 H 0.2165 0.7229 0.1811 0.099 Uiso 1 1 calc R . . . .
C61 C 0.1319(3) 0.2496(5) 0.3540(3) 0.0644(17) Uani 1 1 d . . . . .
C62 C 0.0863(4) 0.1970(6) 0.3665(4) 0.092(3) Uani 1 1 d . . . . .
H62 H 0.0490 0.2223 0.3565 0.111 Uiso 1 1 calc R . . . .
C63 C 0.0977(6) 0.1048(7) 0.3946(5) 0.131(5) Uani 1 1 d . . . . .
H63 H 0.0673 0.0683 0.4032 0.157 Uiso 1 1 calc R . . . .
C64 C 0.1512(7) 0.0679(7) 0.4093(5) 0.138(6) Uani 1 1 d . . . . .
H64 H 0.1591 0.0083 0.4297 0.166 Uiso 1 1 calc R . . . .
C65 C 0.1929(5) 0.1210(7) 0.3934(3) 0.101(4) Uani 1 1 d . . . . .
H65 H 0.2297 0.0931 0.4015 0.121 Uiso 1 1 calc R . . . .
C68 C 0.3838(2) 0.1014(4) 0.2806(2) 0.0470(12) Uani 1 1 d . . . . .
C69 C 0.4355(2) 0.1279(4) 0.3168(2) 0.0473(12) Uani 1 1 d . . . . .
C70 C 0.4919(2) 0.0724(4) 0.3324(3) 0.0612(16) Uani 1 1 d . . . . .
H70A H 0.5165 0.0870 0.3072 0.073 Uiso 1 1 calc R . . . .
H70B H 0.4861 -0.0007 0.3338 0.073 Uiso 1 1 calc R . . . .
C71 C 0.5176(2) 0.1158(4) 0.3896(3) 0.0646(17) Uani 1 1 d . . . . .
H71A H 0.5594 0.1159 0.3970 0.078 Uiso 1 1 calc R . . . .
H71B H 0.5050 0.0767 0.4177 0.078 Uiso 1 1 calc R . . . .
C72 C 0.4936(2) 0.2259(4) 0.3869(3) 0.0559(14) Uani 1 1 d . . . . .
H72A H 0.4887 0.2488 0.4223 0.067 Uiso 1 1 calc R . . . .
H72B H 0.5186 0.2731 0.3733 0.067 Uiso 1 1 calc R . . . .
C73 C 0.4366(2) 0.2147(4) 0.3473(2) 0.0476(12) Uani 1 1 d . . . . .
C74 C 0.3861(3) 0.2727(4) 0.3408(2) 0.0553(14) Uani 1 1 d . . . . .
C76 C 0.3766(2) 0.0110(4) 0.2442(3) 0.0529(13) Uani 1 1 d . . . . .
C77 C 0.4216(3) -0.0268(4) 0.2236(3) 0.0620(16) Uani 1 1 d . . . . .
H77 H 0.4576 0.0046 0.2321 0.074 Uiso 1 1 calc R . . . .
C78 C 0.4130(4) -0.1113(5) 0.1903(3) 0.086(3) Uani 1 1 d . . . . .
H78 H 0.4428 -0.1384 0.1761 0.103 Uiso 1 1 calc R . . . .
C79 C 0.3585(5) -0.1547(6) 0.1787(4) 0.110(4) Uani 1 1 d . . . . .
H79 H 0.3514 -0.2135 0.1576 0.132 Uiso 1 1 calc R . . . .
C80 C 0.3159(4) -0.1105(7) 0.1984(4) 0.101(3) Uani 1 1 d . . . . .
H80 H 0.2791 -0.1384 0.1887 0.122 Uiso 1 1 calc R . . . .
C82 C 0.3818(3) 0.3715(5) 0.3685(2) 0.0644(18) Uani 1 1 d . . . . .
C83 C 0.4284(4) 0.4363(5) 0.3823(3) 0.073(2) Uani 1 1 d . . . . .
H83 H 0.4639 0.4190 0.3747 0.088 Uiso 1 1 calc R . . . .
C84 C 0.4211(5) 0.5283(5) 0.4077(3) 0.089(3) Uani 1 1 d . . . . .
H84 H 0.4515 0.5739 0.4179 0.107 Uiso 1 1 calc R . . . .
C85 C 0.3662(6) 0.5502(7) 0.4176(3) 0.109(4) Uani 1 1 d . . . . .
H85 H 0.3597 0.6103 0.4349 0.131 Uiso 1 1 calc R . . . .
C86 C 0.3241(6) 0.4839(8) 0.4017(3) 0.108(4) Uani 1 1 d . . . . .
H86 H 0.2881 0.5003 0.4081 0.130 Uiso 1 1 calc R . . . .
C87 C 0.6239(4) 0.0328(6) 0.5304(3) 0.0779(19) Uani 1 1 d . . . . .
H87A H 0.6136 -0.0187 0.5023 0.093 Uiso 1 1 calc R . . . .
H87B H 0.5896 0.0717 0.5318 0.093 Uiso 1 1 calc R . . . .
C90 C 0.5143(5) 0.8435(9) 0.0314(5) 0.122(4) Uani 1 1 d . . . B 1
H90A H 0.5056 0.8728 -0.0050 0.147 Uiso 1 1 calc R . . B 1
H90B H 0.5366 0.8923 0.0565 0.147 Uiso 1 1 calc R . . B 1
B10 B 0.8085(3) 0.3853(6) 0.5899(3) 0.0607(17) Uani 1 1 d . . . . .
B15 B 0.5570(3) 0.3430(6) 0.2777(3) 0.0582(16) Uani 1 1 d . . . . .
B20 B 0.5560(6) 0.060(2) 0.1387(5) 0.158(9) Uani 1 1 d . . . . .
B26 B 0.4707(5) 0.1898(7) 0.5405(4) 0.079(2) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0090 0.0039 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N32 104.44(16) . .
N17 Ag1 N1 71.18(16) . .
N17 Ag1 N32 126.54(16) . .
N24 Ag1 N1 143.96(14) . .
N24 Ag1 N17 140.50(16) . .
N24 Ag1 N32 72.08(17) . .
N23 Ag2 N23 106.0(2) 2_655 .
N38 Ag2 N23 146.88(16) . 2_655
N38 Ag2 N23 69.99(15) 2_655 2_655
N38 Ag2 N23 146.88(16) 2_655 .
N38 Ag2 N23 69.99(15) . .
N38 Ag2 N38 131.4(2) . 2_655
N2 Ag3 N2 151.6(2) 2_655 .
N2 Ag3 N11 70.19(15) 2_655 2_655
N2 Ag3 N11 130.18(14) . 2_655
N2 Ag3 N11 130.18(14) 2_655 .
N2 Ag3 N11 70.19(15) . .
N11 Ag3 N11 102.72(19) 2_655 .
N45 Ag4 N45 128.4(3) 2 .
N54 Ag4 N45 146.93(17) . 2
N54 Ag4 N45 70.40(17) 2 2
N54 Ag4 N45 146.93(17) 2 .
N54 Ag4 N45 70.40(17) . .
N54 Ag4 N54 109.5(3) 2 .
N45 Ag5 N45 155.0(3) 2 .
N45 Ag5 N54 67.19(17) 2 2
N45 Ag5 N54 134.28(17) . 2
N45 Ag5 N54 134.28(17) 2 .
N45 Ag5 N54 67.19(17) . .
N54 Ag5 N54 88.3(2) 2 .
N44 Ag6 N60 65.34(18) . .
N66 Ag6 N44 146.8(2) . .
N66 Ag6 N60 117.3(2) . .
N81 Ag6 N44 131.5(2) . .
N81 Ag6 N60 122.8(2) . .
N81 Ag6 N66 77.2(2) . .
N44 Ag7 N66 144.28(19) . .
N44 Ag7 N81 108.65(18) . .
N60 Ag7 N44 75.1(2) . .
N60 Ag7 N66 139.7(2) . .
N60 Ag7 N81 120.07(19) . .
N66 Ag7 N81 65.58(19) . .
N67 Ag8 N67 145.5(3) . 2
N67 Ag8 N75 68.46(18) . .
N67 Ag8 N75 140.59(19) . 2
N67 Ag8 N75 140.59(19) 2 .
N67 Ag8 N75 68.46(18) 2 2
N75 Ag8 N75 93.6(2) 2 .
N67 Ag9 N67 102.6(2) . 2
N75 Ag9 N67 69.73(19) . .
N75 Ag9 N67 146.24(19) . 2
N75 Ag9 N67 146.24(19) 2 .
N75 Ag9 N67 69.73(19) 2 2
N75 Ag9 N75 134.3(3) 2 .
B20 F21 F25 46.4(8) . .
B20 F25 F21 57.4(13) . .
B26 F27 F30 65.1(9) . .
B26 F29 F30 64.7(9) . .
F27 F30 F29 87.7(11) . .
F27 F30 B26 50.7(8) . .
B26 F30 F29 43.5(6) . .
H93A O93 H93B 109.5 . .
N2 N1 Ag1 120.1(3) . .
N2 N1 C10 121.0(4) . .
C10 N1 Ag1 118.2(3) . .
N1 N2 Ag3 118.2(3) . .
C3 N2 Ag3 119.7(3) . .
C3 N2 N1 121.5(4) . .
C12 N11 Ag3 116.8(3) . .
C12 N11 C16 118.1(5) . .
C16 N11 Ag3 123.0(4) . .
C18 N17 Ag1 118.7(4) . .
C22 N17 Ag1 121.2(4) . .
C22 N17 C18 118.8(5) . .
N24 N23 Ag2 120.9(3) . .
C31 N23 Ag2 114.4(3) . .
C31 N23 N24 120.4(4) . .
N23 N24 Ag1 117.1(3) . .
N23 N24 C25 121.0(4) . .
C25 N24 Ag1 118.4(3) . .
C33 N32 Ag1 113.9(3) . .
C37 N32 Ag1 125.9(5) . .
C37 N32 C33 118.0(6) . .
C39 N38 Ag2 119.3(4) . .
C43 N38 Ag2 122.1(4) . .
C43 N38 C39 118.0(6) . .
N45 N44 Ag6 108.7(3) . .
N45 N44 Ag7 123.3(3) . .
C53 N44 Ag6 123.4(4) . .
C53 N44 Ag7 113.7(4) . .
C53 N44 N45 120.7(4) . .
N44 N45 Ag4 123.1(3) . .
N44 N45 Ag5 112.1(3) . .
N44 N45 C46 121.1(4) . .
C46 N45 Ag4 111.4(4) . .
C46 N45 Ag5 124.3(4) . .
C55 N54 Ag4 122.4(4) . .
C55 N54 Ag5 114.5(4) . .
C59 N54 Ag4 119.3(5) . .
C59 N54 Ag5 126.4(5) . .
C59 N54 C55 118.2(7) . .
C61 N60 Ag6 114.3(5) . .
C61 N60 Ag7 118.0(5) . .
C61 N60 C65 114.8(8) . .
C65 N60 Ag6 130.7(6) . .
C65 N60 Ag7 124.9(6) . .
N67 N66 Ag6 126.7(4) . .
N67 N66 Ag7 111.0(4) . .
N67 N66 C74 121.0(4) . .
C74 N66 Ag6 110.7(4) . .
C74 N66 Ag7 123.0(4) . .
N66 N67 Ag8 110.1(3) . .
N66 N67 Ag9 127.0(3) . .
N66 N67 C68 121.3(5) . .
C68 N67 Ag8 127.2(4) . .
C68 N67 Ag9 106.9(4) . .
C76 N75 Ag8 108.5(4) . .
C76 N75 Ag9 126.1(5) . .
C76 N75 C80 117.5(7) . .
C80 N75 Ag8 130.5(5) . .
C80 N75 Ag9 116.1(5) . .
C82 N81 Ag6 116.3(5) . .
C82 N81 Ag7 114.0(5) . .
C82 N81 C86 116.7(9) . .
C86 N81 Ag6 122.8(6) . .
C86 N81 Ag7 127.9(7) . .
N2 C3 C4 119.6(5) . .
N2 C3 C12 114.4(4) . .
C4 C3 C12 126.0(5) . .
C3 C4 C5 130.2(5) . .
C8 C4 C3 118.4(5) . .
C8 C4 C5 111.3(5) . .
C4 C5 H5A 111.2 . .
C4 C5 H5B 111.2 . .
C4 C5 C6 102.6(5) . .
H5A C5 H5B 109.2 . .
C6 C5 H5A 111.2 . .
C6 C5 H5B 111.2 . .
C5 C6 H6A 110.6 . .
C5 C6 H6B 110.6 . .
C5 C6 C7 105.7(5) . .
H6A C6 H6B 108.7 . .
C7 C6 H6A 110.6 . .
C7 C6 H6B 110.6 . .
C6 C7 H7A 111.2 . .
C6 C7 H7B 111.2 . .
H7A C7 H7B 109.1 . .
C8 C7 C6 102.8(5) . .
C8 C7 H7A 111.2 . .
C8 C7 H7B 111.2 . .
C4 C8 C7 109.7(5) . .
C10 C8 C4 119.3(5) . .
C10 C8 C7 131.0(5) . .
N1 C10 C8 119.9(5) . .
N1 C10 C18 113.4(5) . .
C8 C10 C18 126.7(5) . .
N11 C12 C3 115.9(4) . .
N11 C12 C13 121.5(5) . .
C13 C12 C3 122.6(5) . .
C12 C13 H13 120.6 . .
C14 C13 C12 118.8(6) . .
C14 C13 H13 120.6 . .
C13 C14 H14 120.0 . .
C15 C14 C13 119.9(5) . .
C15 C14 H14 120.0 . .
C14 C15 H15 121.2 . .
C14 C15 C16 117.7(5) . .
C16 C15 H15 121.2 . .
N11 C16 C15 123.9(6) . .
N11 C16 H16 118.0 . .
C15 C16 H16 118.0 . .
N17 C18 C10 116.5(5) . .
N17 C18 C19 121.7(6) . .
C19 C18 C10 121.8(6) . .
C18 C19 H19 121.1 . .
C18 C19 C20 117.9(7) . .
C20 C19 H19 121.1 . .
C19 C20 H20 120.0 . .
C21 C20 C19 120.0(6) . .
C21 C20 H20 120.0 . .
C20 C21 H21 120.9 . .
C22 C21 C20 118.1(7) . .
C22 C21 H21 120.9 . .
N17 C22 C21 123.4(7) . .
N17 C22 H22 118.3 . .
C21 C22 H22 118.3 . .
N24 C25 C26 120.8(5) . .
N24 C25 C33 114.8(5) . .
C26 C25 C33 124.4(4) . .
C25 C26 C27 130.9(5) . .
C30 C26 C25 118.5(4) . .
C30 C26 C27 110.4(5) . .
C26 C27 H27A 111.0 . .
C26 C27 H27B 111.0 . .
C26 C27 C28 103.6(5) . .
H27A C27 H27B 109.0 . .
C28 C27 H27A 111.0 . .
C28 C27 H27B 111.0 . .
C27 C28 H28A 110.6 . .
C27 C28 H28B 110.6 . .
C27 C28 C29 105.6(5) . .
H28A C28 H28B 108.8 . .
C29 C28 H28A 110.6 . .
C29 C28 H28B 110.6 . .
C28 C29 H29A 111.2 . .
C28 C29 H29B 111.2 . .
H29A C29 H29B 109.1 . .
C30 C29 C28 102.7(5) . .
C30 C29 H29A 111.2 . .
C30 C29 H29B 111.2 . .
C26 C30 C29 110.7(4) . .
C26 C30 C31 118.3(5) . .
C31 C30 C29 130.9(5) . .
N23 C31 C30 120.8(5) . .
N23 C31 C39 115.1(4) . .
C30 C31 C39 124.1(5) . .
N32 C33 C25 116.2(5) . .
N32 C33 C34 122.3(6) . .
C34 C33 C25 121.4(6) . .
C33 C34 H34 120.5 . .
C35 C34 C33 119.0(8) . .
C35 C34 H34 120.5 . .
C34 C35 H35 120.6 . .
C34 C35 C36 118.9(7) . .
C36 C35 H35 120.6 . .
C35 C36 H36 120.7 . .
C37 C36 C35 118.6(7) . .
C37 C36 H36 120.7 . .
N32 C37 C36 123.2(8) . .
N32 C37 H37 118.4 . .
C36 C37 H37 118.4 . .
N38 C39 C31 116.7(5) . .
N38 C39 C40 121.6(5) . .
C40 C39 C31 121.6(5) . .
C39 C40 H40 119.9 . .
C39 C40 C41 120.1(6) . .
C41 C40 H40 119.9 . .
C40 C41 H41 120.9 . .
C42 C41 C40 118.2(7) . .
C42 C41 H41 120.9 . .
C41 C42 H42 120.6 . .
C41 C42 C43 118.7(6) . .
C43 C42 H42 120.6 . .
N38 C43 C42 123.2(7) . .
N38 C43 H43 118.4 . .
C42 C43 H43 118.4 . .
N45 C46 C47 120.2(5) . .
N45 C46 C55 115.2(5) . .
C47 C46 C55 124.7(4) . .
C46 C47 C48 130.8(5) . .
C52 C47 C46 118.4(4) . .
C52 C47 C48 110.8(4) . .
C47 C48 H48A 111.3 . .
C47 C48 H48B 111.3 . .
C47 C48 C50 102.4(5) . .
H48A C48 H48B 109.2 . .
C50 C48 H48A 111.3 . .
C50 C48 H48B 111.3 . .
C48 C50 H50A 110.6 . .
C48 C50 H50B 110.6 . .
C48 C50 C51 105.6(5) . .
H50A C50 H50B 108.8 . .
C51 C50 H50A 110.6 . .
C51 C50 H50B 110.6 . .
C50 C51 H51A 111.2 . .
C50 C51 H51B 111.2 . .
H51A C51 H51B 109.1 . .
C52 C51 C50 102.7(5) . .
C52 C51 H51A 111.2 . .
C52 C51 H51B 111.2 . .
C47 C52 C51 110.3(4) . .
C47 C52 C53 118.2(5) . .
C53 C52 C51 131.4(5) . .
N44 C53 C52 121.3(5) . .
N44 C53 C61 114.4(5) . .
C52 C53 C61 124.2(6) . .
N54 C55 C46 115.3(5) . .
N54 C55 C56 122.1(6) . .
C56 C55 C46 122.5(5) . .
C55 C56 H56 120.6 . .
C57 C56 C55 118.7(7) . .
C57 C56 H56 120.6 . .
C56 C57 H57 120.7 . .
C56 C57 C58 118.6(8) . .
C58 C57 H57 120.7 . .
C57 C58 H58 120.9 . .
C59 C58 C57 118.1(7) . .
C59 C58 H58 120.9 . .
N54 C59 C58 124.1(8) . .
N54 C59 H59 117.9 . .
C58 C59 H59 117.9 . .
N60 C61 C53 115.1(7) . .
N60 C61 C62 122.2(7) . .
C62 C61 C53 122.7(6) . .
C61 C62 H62 120.9 . .
C61 C62 C63 118.3(9) . .
C63 C62 H62 120.9 . .
C62 C63 H63 119.2 . .
C64 C63 C62 121.5(12) . .
C64 C63 H63 119.2 . .
C63 C64 H64 121.7 . .
C63 C64 C65 116.7(9) . .
C65 C64 H64 121.7 . .
N60 C65 H65 116.8 . .
C64 C65 N60 126.4(9) . .
C64 C65 H65 116.8 . .
N67 C68 C69 120.2(5) . .
N67 C68 C76 115.4(5) . .
C69 C68 C76 124.3(4) . .
C68 C69 C70 131.0(5) . .
C73 C69 C68 118.4(5) . .
C73 C69 C70 110.5(5) . .
C69 C70 H70A 111.3 . .
C69 C70 H70B 111.3 . .
C69 C70 C71 102.3(5) . .
H70A C70 H70B 109.2 . .
C71 C70 H70A 111.3 . .
C71 C70 H70B 111.3 . .
C70 C71 H71A 111.0 . .
C70 C71 H71B 111.0 . .
C70 C71 C72 103.7(5) . .
H71A C71 H71B 109.0 . .
C72 C71 H71A 111.0 . .
C72 C71 H71B 111.0 . .
C71 C72 H72A 111.4 . .
C71 C72 H72B 111.4 . .
H72A C72 H72B 109.2 . .
C73 C72 C71 102.0(4) . .
C73 C72 H72A 111.4 . .
C73 C72 H72B 111.4 . .
C69 C73 C72 110.8(4) . .
C69 C73 C74 118.4(5) . .
C74 C73 C72 130.6(5) . .
N66 C74 C73 120.4(6) . .
N66 C74 C82 115.2(5) . .
C73 C74 C82 124.4(6) . .
N75 C76 C68 116.1(6) . .
N75 C76 C77 122.3(6) . .
C77 C76 C68 121.6(5) . .
C76 C77 H77 120.3 . .
C78 C77 C76 119.4(6) . .
C78 C77 H77 120.3 . .
C77 C78 H78 121.0 . .
C77 C78 C79 118.0(9) . .
C79 C78 H78 121.0 . .
C78 C79 H79 120.5 . .
C80 C79 C78 119.1(8) . .
C80 C79 H79 120.5 . .
N75 C80 C79 123.7(7) . .
N75 C80 H80 118.2 . .
C79 C80 H80 118.2 . .
N81 C82 C74 115.6(7) . .
N81 C82 C83 123.0(6) . .
C83 C82 C74 121.4(6) . .
C82 C83 H83 120.8 . .
C82 C83 C84 118.3(8) . .
C84 C83 H83 120.8 . .
C83 C84 H84 121.0 . .
C83 C84 C85 117.9(10) . .
C85 C84 H84 121.0 . .
C84 C85 H85 120.6 . .
C86 C85 C84 118.9(8) . .
C86 C85 H85 120.6 . .
N81 C86 H86 117.5 . .
C85 C86 N81 125.1(10) . .
C85 C86 H86 117.5 . .
Cl88 C87 H87A 109.7 . .
Cl88 C87 H87B 109.7 . .
Cl89 C87 Cl88 110.0(5) . .
Cl89 C87 H87A 109.7 . .
Cl89 C87 H87B 109.7 . .
H87A C87 H87B 108.2 . .
Cl91 C90 Cl92 104.9(6) . .
Cl91 C90 H90A 110.8 . .
Cl91 C90 H90B 110.8 . .
Cl92 C90 H90A 110.8 . .
Cl92 C90 H90B 110.8 . .
H90A C90 H90B 108.9 . .
F11 B10 F13 109.0(6) . .
F12 B10 F11 110.7(5) . .
F12 B10 F13 108.2(7) . .
F14 B10 F11 110.6(6) . .
F14 B10 F12 110.2(7) . .
F14 B10 F13 108.2(6) . .
F17 B15 F16 107.8(5) . .
F18 B15 F16 108.1(6) . .
F18 B15 F17 111.0(6) . .
F18 B15 F19 111.6(5) . .
F19 B15 F16 108.9(6) . .
F19 B15 F17 109.3(6) . .
F21 B20 F22 101.5(10) . .
F21 B20 F24 148.7(12) . .
F22 B20 F24 78.6(15) . .
F23 B20 F21 109(2) . .
F23 B20 F22 105.9(13) . .
F23 B20 F24 101.0(13) . .
F25 B20 F21 76.3(14) . .
F25 B20 F22 116.0(17) . .
F25 B20 F23 136.0(19) . .
F25 B20 F24 75.8(13) . .
F27 B26 F28 99.6(10) . .
F27 B26 F30 64.2(9) . .
F29 B26 F27 122.8(11) . .
F29 B26 F28 97.2(11) . .
F29 B26 F30 71.8(10) . .
F29 B26 F31 117.9(13) . .
F31 B26 F27 109.3(9) . .
F31 B26 F28 105.7(11) . .
F31 B26 F30 107.6(11) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.322(4) .
Ag1 N17 2.260(5) .
Ag1 N24 2.223(4) .
Ag1 N32 2.361(5) .
Ag2 N23 2.418(4) 2_655
Ag2 N23 2.418(4) .
Ag2 N38 2.280(5) 2_655
Ag2 N38 2.280(5) .
Ag3 N2 2.293(4) 2_655
Ag3 N2 2.293(4) .
Ag3 N11 2.338(4) 2_655
Ag3 N11 2.338(4) .
Ag4 N45 2.428(5) 2
Ag4 N45 2.428(5) .
Ag4 N54 2.174(6) 2
Ag4 N54 2.174(6) .
Ag5 N45 2.239(4) .
Ag5 N45 2.239(4) 2
Ag5 N54 2.548(6) .
Ag5 N54 2.548(6) 2
Ag6 N44 2.304(4) .
Ag6 N60 2.611(8) .
Ag6 N66 2.253(4) .
Ag6 N81 2.059(8) .
Ag7 N44 2.264(4) .
Ag7 N60 2.104(8) .
Ag7 N66 2.325(5) .
Ag7 N81 2.628(8) .
Ag8 N67 2.112(5) .
Ag8 N67 2.112(5) 2
Ag8 N75 2.619(7) .
Ag8 N75 2.619(7) 2
Ag9 N67 2.584(5) 2
Ag9 N67 2.584(6) .
Ag9 N75 2.072(6) 2
Ag9 N75 2.072(6) .
Cl88 C87 1.776(8) .
Cl89 C87 1.760(8) .
Cl91 C90 1.759(11) .
Cl92 C90 1.831(13) .
F11 B10 1.371(8) .
F12 B10 1.362(9) .
F13 B10 1.384(9) .
F14 B10 1.358(8) .
F16 B15 1.403(8) .
F17 B15 1.398(8) .
F18 B15 1.369(9) .
F19 B15 1.396(7) .
F21 F25 1.61(2) .
F21 B20 1.40(2) .
F22 B20 1.47(2) .
F23 B20 1.268(15) .
F24 B20 1.65(3) .
F25 B20 1.202(15) .
F27 F30 1.54(2) .
F27 B26 1.320(12) .
F28 B26 1.351(13) .
F29 F30 1.63(2) .
F29 B26 1.178(10) .
F30 B26 1.55(2) .
F31 B26 1.284(12) .
O93 H93A 0.8508 .
O93 H93B 0.8501 .
N1 N2 1.341(6) .
N1 C10 1.344(7) .
N2 C3 1.339(7) .
N11 C12 1.338(7) .
N11 C16 1.347(7) .
N17 C18 1.344(8) .
N17 C22 1.339(7) .
N23 N24 1.337(6) .
N23 C31 1.335(7) .
N24 C25 1.348(6) .
N32 C33 1.344(8) .
N32 C37 1.339(7) .
N38 C39 1.350(7) .
N38 C43 1.332(8) .
N44 N45 1.330(7) .
N44 C53 1.328(8) .
N45 C46 1.347(6) .
N54 C55 1.339(7) .
N54 C59 1.313(10) .
N60 C61 1.355(9) .
N60 C65 1.377(11) .
N66 N67 1.319(8) .
N66 C74 1.339(9) .
N67 C68 1.334(6) .
N75 C76 1.336(7) .
N75 C80 1.338(12) .
N81 C82 1.344(9) .
N81 C86 1.346(11) .
C3 C4 1.403(7) .
C3 C12 1.492(7) .
C4 C5 1.513(8) .
C4 C8 1.388(8) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C5 C6 1.529(9) .
C6 H6A 0.9700 .
C6 H6B 0.9700 .
C6 C7 1.545(10) .
C7 H7A 0.9700 .
C7 H7B 0.9700 .
C7 C8 1.519(8) .
C8 C10 1.384(8) .
C10 C18 1.511(8) .
C12 C13 1.400(8) .
C13 H13 0.9300 .
C13 C14 1.385(9) .
C14 H14 0.9300 .
C14 C15 1.373(10) .
C15 H15 0.9300 .
C15 C16 1.376(8) .
C16 H16 0.9300 .
C18 C19 1.375(8) .
C19 H19 0.9300 .
C19 C20 1.410(11) .
C20 H20 0.9300 .
C20 C21 1.363(12) .
C21 H21 0.9300 .
C21 C22 1.362(9) .
C22 H22 0.9300 .
C25 C26 1.384(8) .
C25 C33 1.492(7) .
C26 C27 1.508(7) .
C26 C30 1.382(8) .
C27 H27A 0.9700 .
C27 H27B 0.9700 .
C27 C28 1.517(9) .
C28 H28A 0.9700 .
C28 H28B 0.9700 .
C28 C29 1.545(8) .
C29 H29A 0.9700 .
C29 H29B 0.9700 .
C29 C30 1.504(8) .
C30 C31 1.406(7) .
C31 C39 1.486(7) .
C33 C34 1.389(8) .
C34 H34 0.9300 .
C34 C35 1.382(10) .
C35 H35 0.9300 .
C35 C36 1.388(13) .
C36 H36 0.9300 .
C36 C37 1.379(11) .
C37 H37 0.9300 .
C39 C40 1.384(9) .
C40 H40 0.9300 .
C40 C41 1.387(9) .
C41 H41 0.9300 .
C41 C42 1.374(11) .
C42 H42 0.9300 .
C42 C43 1.397(11) .
C43 H43 0.9300 .
C46 C47 1.396(7) .
C46 C55 1.482(8) .
C47 C48 1.510(6) .
C47 C52 1.384(8) .
C48 H48A 0.9700 .
C48 H48B 0.9700 .
C48 C50 1.524(9) .
C50 H50A 0.9700 .
C50 H50B 0.9700 .
C50 C51 1.541(9) .
C51 H51A 0.9700 .
C51 H51B 0.9700 .
C51 C52 1.504(7) .
C52 C53 1.390(7) .
C53 C61 1.500(9) .
C55 C56 1.398(8) .
C56 H56 0.9300 .
C56 C57 1.382(10) .
C57 H57 0.9300 .
C57 C58 1.390(13) .
C58 H58 0.9300 .
C58 C59 1.380(13) .
C59 H59 0.9300 .
C61 C62 1.377(12) .
C62 H62 0.9300 .
C62 C63 1.397(12) .
C63 H63 0.9300 .
C63 C64 1.335(17) .
C64 H64 0.9300 .
C64 C65 1.342(17) .
C65 H65 0.9300 .
C68 C69 1.404(7) .
C68 C76 1.485(8) .
C69 C70 1.502(6) .
C69 C73 1.370(8) .
C70 H70A 0.9700 .
C70 H70B 0.9700 .
C70 C71 1.542(9) .
C71 H71A 0.9700 .
C71 H71B 0.9700 .
C71 C72 1.549(7) .
C72 H72A 0.9700 .
C72 H72B 0.9700 .
C72 C73 1.504(8) .
C73 C74 1.399(7) .
C74 C82 1.486(9) .
C76 C77 1.379(9) .
C77 H77 0.9300 .
C77 C78 1.377(9) .
C78 H78 0.9300 .
C78 C79 1.386(13) .
C79 H79 0.9300 .
C79 C80 1.352(15) .
C80 H80 0.9300 .
C82 C83 1.380(11) .
C83 H83 0.9300 .
C83 C84 1.395(9) .
C84 H84 0.9300 .
C84 C85 1.411(15) .
C85 H85 0.9300 .
C85 C86 1.318(16) .
C86 H86 0.9300 .
C87 H87A 0.9700 .
C87 H87B 0.9700 .
C90 H90A 0.9700 .
C90 H90B 0.9700 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
B26 F27 F30_b F29 -24.9(8)
Ag1 N1 N2 Ag3 -0.6(4)
Ag1 N1 N2 C3 170.1(3)
Ag1 N1 C10 C8 -166.3(4)
Ag1 N1 C10 C18 13.4(5)
Ag1 N17 C18 C10 11.7(6)
Ag1 N17 C18 C19 -166.6(5)
Ag1 N17 C22 C21 166.0(5)
Ag1 N24 C25 C26 156.0(4)
Ag1 N24 C25 C33 -22.6(5)
Ag1 N32 C33 C25 -14.1(5)
Ag1 N32 C33 C34 164.2(4)
Ag1 N32 C37 C36 -162.1(4)
Ag2 N23 N24 Ag1 -4.0(4)
Ag2 N23 N24 C25 154.8(3)
Ag2 N23 C31 C30 -153.7(4)
Ag2 N23 C31 C39 23.9(5)
Ag2 N38 C39 C31 8.1(6)
Ag2 N38 C39 C40 -169.0(5)
Ag2 N38 C43 C42 170.0(6)
Ag3 N2 C3 C4 166.2(4)
Ag3 N2 C3 C12 -12.3(5)
Ag3 N11 C12 C3 -18.0(6)
Ag3 N11 C12 C13 161.8(4)
Ag3 N11 C16 C15 -162.0(4)
Ag4 N45 C46 C47 -153.1(4)
Ag4 N45 C46 C55 25.5(5)
Ag4 N54 C55 C46 2.0(6)
Ag4 N54 C55 C56 -174.9(4)
Ag4 N54 C59 C58 177.3(6)
Ag5 N45 C46 C47 -156.8(3)
Ag5 N45 C46 C55 21.9(6)
Ag5 N54 C55 C46 10.0(6)
Ag5 N54 C55 C56 -166.9(4)
Ag5 N54 C59 C58 167.9(6)
Ag6 N44 N45 Ag4 2.4(5)
Ag6 N44 N45 Ag5 11.0(4)
Ag6 N44 N45 C46 -151.8(4)
Ag6 N44 C53 C52 143.2(4)
Ag6 N44 C53 C61 -34.0(6)
Ag6 N60 C61 C53 -4.0(6)
Ag6 N60 C61 C62 173.7(6)
Ag6 N60 C65 C64 -176.3(7)
Ag6 N66 N67 Ag8 2.2(6)
Ag6 N66 N67 Ag9 -13.0(7)
Ag6 N66 N67 C68 -165.3(4)
Ag6 N66 C74 C73 161.8(4)
Ag6 N66 C74 C82 -17.1(6)
Ag6 N81 C82 C74 -21.8(7)
Ag6 N81 C82 C83 155.5(5)
Ag6 N81 C86 C85 -155.5(7)
Ag7 N44 N45 Ag4 -8.0(6)
Ag7 N44 N45 Ag5 0.6(5)
Ag7 N44 N45 C46 -162.3(4)
Ag7 N44 C53 C52 159.6(4)
Ag7 N44 C53 C61 -17.6(6)
Ag7 N60 C61 C53 -16.1(7)
Ag7 N60 C61 C62 161.6(6)
Ag7 N60 C65 C64 -163.8(8)
Ag7 N66 N67 Ag8 10.3(4)
Ag7 N66 N67 Ag9 -4.8(5)
Ag7 N66 N67 C68 -157.1(4)
Ag7 N66 C74 C73 148.3(4)
Ag7 N66 C74 C82 -30.6(7)
Ag7 N81 C82 C74 -11.5(6)
Ag7 N81 C82 C83 165.9(5)
Ag7 N81 C86 C85 -165.5(6)
Ag8 N67 C68 C69 -158.7(4)
Ag8 N67 C68 C76 17.6(7)
Ag8 N75 C76 C68 18.7(6)
Ag8 N75 C76 C77 -158.9(5)
Ag8 N75 C80 C79 157.2(7)
Ag9 N67 C68 C69 -150.7(4)
Ag9 N67 C68 C76 25.6(6)
Ag9 N75 C76 C68 7.0(8)
Ag9 N75 C76 C77 -170.6(5)
Ag9 N75 C80 C79 174.5(7)
F21 F25 B20 F22 96.2(13)
F21 F25 B20 F23 -103(4)
F21 F25 B20 F24 165.7(15)
F25 F21 B20 F22 -114.2(16)
F25 F21 B20 F23 134(2)
F25 F21 B20 F24 -27(3)
F27 F30 B26 F28 -67(2)
F27 F30 B26 F29 -142.3(13)
F27 F30 B26 F31 103.4(10)
F29 F30 B26 F27 142.3(13)
F29 F30 B26 F28 75(2)
F29 F30 B26 F31 -114.4(14)
F30 F27 B26 F28 148.8(11)
F30 F27 B26 F29 43.8(15)
F30 F27 B26 F31 -100.8(12)
F30 F29 B26 F27 -41.0(14)
F30 F29 B26 F28 -147.2(12)
F30 F29 B26 F31 100.8(13)
N1 N2 C3 C4 -4.4(7)
N1 N2 C3 C12 177.0(4)
N1 C10 C18 N17 -16.4(6)
N1 C10 C18 C19 161.9(5)
N2 N1 C10 C8 3.9(7)
N2 N1 C10 C18 -176.4(4)
N2 C3 C4 C5 -174.6(6)
N2 C3 C4 C8 4.6(8)
N2 C3 C12 N11 20.0(6)
N2 C3 C12 C13 -159.8(5)
N11 C12 C13 C14 1.5(9)
N17 C18 C19 C20 -1.1(10)
N23 N24 C25 C26 -2.6(6)
N23 N24 C25 C33 178.9(4)
N23 C31 C39 N38 -21.9(7)
N23 C31 C39 C40 155.2(5)
N24 N23 C31 C30 3.5(7)
N24 N23 C31 C39 -178.9(4)
N24 C25 C26 C27 -170.6(5)
N24 C25 C26 C30 3.3(7)
N24 C25 C33 N32 24.3(6)
N24 C25 C33 C34 -154.0(5)
N32 C33 C34 C35 0.3(8)
N38 C39 C40 C41 -2.0(10)
N44 N45 C46 C47 3.9(7)
N44 N45 C46 C55 -177.5(4)
N44 C53 C61 N60 22.5(7)
N44 C53 C61 C62 -155.1(7)
N45 N44 C53 C52 -3.8(8)
N45 N44 C53 C61 179.0(5)
N45 C46 C47 C48 172.8(5)
N45 C46 C47 C52 -2.9(7)
N45 C46 C55 N54 -19.9(6)
N45 C46 C55 C56 157.0(5)
N54 C55 C56 C57 -3.4(9)
N60 C61 C62 C63 2.5(12)
N66 N67 C68 C69 6.4(8)
N66 N67 C68 C76 -177.3(5)
N66 C74 C82 N81 26.4(7)
N66 C74 C82 C83 -151.0(6)
N67 N66 C74 C73 -4.3(9)
N67 N66 C74 C82 176.8(5)
N67 C68 C69 C70 169.1(6)
N67 C68 C69 C73 -5.3(8)
N67 C68 C76 N75 -24.5(7)
N67 C68 C76 C77 153.2(6)
N75 C76 C77 C78 -3.0(10)
N81 C82 C83 C84 2.1(10)
C3 C4 C5 C6 162.3(6)
C3 C4 C8 C7 -179.3(5)
C3 C4 C8 C10 -0.7(8)
C3 C12 C13 C14 -178.7(6)
C4 C3 C12 N11 -158.4(5)
C4 C3 C12 C13 21.7(8)
C4 C5 C6 C7 26.5(7)
C4 C8 C10 N1 -3.5(8)
C4 C8 C10 C18 176.8(5)
C5 C4 C8 C7 0.0(7)
C5 C4 C8 C10 178.6(5)
C5 C6 C7 C8 -26.7(6)
C6 C7 C8 C4 16.7(6)
C6 C7 C8 C10 -161.7(6)
C7 C8 C10 N1 174.8(5)
C7 C8 C10 C18 -4.8(9)
C8 C4 C5 C6 -16.9(7)
C8 C10 C18 N17 163.3(5)
C8 C10 C18 C19 -18.5(9)
C10 N1 N2 Ag3 -170.6(3)
C10 N1 N2 C3 0.2(7)
C10 C18 C19 C20 -179.3(6)
C12 N11 C16 C15 0.9(8)
C12 C3 C4 C5 3.8(9)
C12 C3 C4 C8 -177.1(5)
C12 C13 C14 C15 0.5(10)
C13 C14 C15 C16 -1.6(10)
C14 C15 C16 N11 0.9(9)
C16 N11 C12 C3 178.0(4)
C16 N11 C12 C13 -2.1(8)
C18 N17 C22 C21 -1.3(9)
C18 C19 C20 C21 1.5(11)
C19 C20 C21 C22 -1.8(12)
C20 C21 C22 N17 1.7(11)
C22 N17 C18 C10 179.3(5)
C22 N17 C18 C19 1.0(8)
C25 C26 C27 C28 159.0(5)
C25 C26 C30 C29 -176.4(4)
C25 C26 C30 C31 -0.7(7)
C25 C33 C34 C35 178.6(5)
C26 C25 C33 N32 -154.2(5)
C26 C25 C33 C34 27.5(7)
C26 C27 C28 C29 25.1(6)
C26 C30 C31 N23 -2.7(7)
C26 C30 C31 C39 180.0(5)
C27 C26 C30 C29 -1.3(6)
C27 C26 C30 C31 174.4(4)
C27 C28 C29 C30 -25.7(6)
C28 C29 C30 C26 16.9(6)
C28 C29 C30 C31 -158.1(5)
C29 C30 C31 N23 172.0(5)
C29 C30 C31 C39 -5.4(8)
C30 C26 C27 C28 -15.3(6)
C30 C31 C39 N38 155.6(5)
C30 C31 C39 C40 -27.3(8)
C31 N23 N24 Ag1 -159.7(3)
C31 N23 N24 C25 -0.9(6)
C31 C39 C40 C41 -179.0(6)
C33 N32 C37 C36 0.0(8)
C33 C25 C26 C27 7.8(8)
C33 C25 C26 C30 -178.3(4)
C33 C34 C35 C36 -0.8(9)
C34 C35 C36 C37 0.8(10)
C35 C36 C37 N32 -0.4(9)
C37 N32 C33 C25 -178.2(4)
C37 N32 C33 C34 0.1(7)
C39 N38 C43 C42 -0.9(11)
C39 C40 C41 C42 0.5(11)
C40 C41 C42 C43 0.7(13)
C41 C42 C43 N38 -0.5(13)
C43 N38 C39 C31 179.3(6)
C43 N38 C39 C40 2.2(9)
C46 C47 C48 C50 -157.5(5)
C46 C47 C52 C51 175.1(4)
C46 C47 C52 C53 -1.2(7)
C46 C55 C56 C57 179.9(6)
C47 C46 C55 N54 158.7(5)
C47 C46 C55 C56 -24.4(8)
C47 C48 C50 C51 -27.7(6)
C47 C52 C53 N44 4.5(7)
C47 C52 C53 C61 -178.5(5)
C48 C47 C52 C51 -1.4(6)
C48 C47 C52 C53 -177.7(5)
C48 C50 C51 C52 27.1(6)
C50 C51 C52 C47 -16.1(6)
C50 C51 C52 C53 159.5(6)
C51 C52 C53 N44 -170.8(5)
C51 C52 C53 C61 6.1(9)
C52 C47 C48 C50 18.5(6)
C52 C53 C61 N60 -154.6(5)
C52 C53 C61 C62 27.8(9)
C53 N44 N45 Ag4 153.7(4)
C53 N44 N45 Ag5 162.3(4)
C53 N44 N45 C46 -0.5(7)
C53 C61 C62 C63 -179.9(8)
C55 N54 C59 C58 -0.6(10)
C55 C46 C47 C48 -5.7(8)
C55 C46 C47 C52 178.6(4)
C55 C56 C57 C58 1.5(10)
C56 C57 C58 C59 0.7(11)
C57 C58 C59 N54 -1.3(12)
C59 N54 C55 C46 179.9(5)
C59 N54 C55 C56 3.0(8)
C61 N60 C65 C64 -1.6(12)
C61 C62 C63 C64 0.2(16)
C62 C63 C64 C65 -3.4(18)
C63 C64 C65 N60 4.2(16)
C65 N60 C61 C53 -179.6(5)
C65 N60 C61 C62 -1.9(9)
C68 C69 C70 C71 -154.6(6)
C68 C69 C73 C72 175.1(5)
C68 C69 C73 C74 -0.3(8)
C68 C76 C77 C78 179.5(6)
C69 C68 C76 N75 151.7(6)
C69 C68 C76 C77 -30.7(9)
C69 C70 C71 C72 -31.0(6)
C69 C73 C74 N66 5.0(8)
C69 C73 C74 C82 -176.2(5)
C70 C69 C73 C72 -0.4(7)
C70 C69 C73 C74 -175.8(5)
C70 C71 C72 C73 30.7(6)
C71 C72 C73 C69 -19.4(7)
C71 C72 C73 C74 155.3(6)
C72 C73 C74 N66 -169.3(6)
C72 C73 C74 C82 9.5(10)
C73 C69 C70 C71 20.2(7)
C73 C74 C82 N81 -152.4(6)
C73 C74 C82 C83 30.2(9)
C74 N66 N67 Ag8 165.9(4)
C74 N66 N67 Ag9 150.7(4)
C74 N66 N67 C68 -1.5(8)
C74 C82 C83 C84 179.3(6)
C76 N75 C80 C79 0.9(12)
C76 C68 C69 C70 -6.8(10)
C76 C68 C69 C73 178.7(5)
C76 C77 C78 C79 0.4(11)
C77 C78 C79 C80 2.6(13)
C78 C79 C80 N75 -3.4(14)
C80 N75 C76 C68 180.0(6)
C80 N75 C76 C77 2.4(9)
C82 N81 C86 C85 0.5(11)
C82 C83 C84 C85 -0.5(10)
C83 C84 C85 C86 -1.0(11)
C84 C85 C86 N81 1.0(13)
C86 N81 C82 C74 -179.4(5)
C86 N81 C82 C83 -2.1(9)
B26 F29 F30 F27 28.3(10)
