#------------------------------------------------------------------------------
#$Date: 2019-11-24 02:41:29 +0200 (Sun, 24 Nov 2019) $
#$Revision: 236307 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/65/7236564.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7236564
loop_
_publ_author_name
'Chen, Wen-Miao'
'Meng, Xiao-Ling'
'Zhuang, Gui-Lin'
'Wang, Zhi'
'Kurmoo, Mohamedally'
'Zhao, Quan-Qin'
'Wang, Xing-Po'
'Shan, Bairong'
'Tung, Chen-Ho'
'Sun, Di'
_publ_section_title
;
 A superior fluorescent sensor for Al3+ and UO22+ based on a Co(ii)
 metal--organic framework with exposed pyrimidyl Lewis base sites
;
_journal_issue                   25
_journal_name_full               'Journal of Materials Chemistry A'
_journal_page_first              13079
_journal_paper_doi               10.1039/C7TA01546A
_journal_volume                  5
_journal_year                    2017
_chemical_formula_moiety         'C72 H48 Co4 N12 O16'
_chemical_formula_sum            'C72 H48 Co4 N12 O16'
_chemical_formula_weight         1572.94
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_audit_creation_date             2016-05-28
_audit_creation_method
;
Olex2 1.2-beta
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_audit_update_record
;
2017-02-16 deposited with the CCDC.
2017-05-24 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 95.467(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   15.673(4)
_cell_length_b                   15.378(4)
_cell_length_c                   15.991(4)
_cell_measurement_reflns_used    4038
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      26.433
_cell_measurement_theta_min      2.559
_cell_volume                     3836.6(17)
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution
;
Superflip (Palatinus & Chapuis, 2007;Palatinus & van der Lee, 2008;
Palatinus et al., 2012)
;
_diffrn_ambient_temperature      298.15
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  BRUKERAPEXII
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0369
_diffrn_reflns_av_unetI/netI     0.0632
_diffrn_reflns_Laue_measured_fraction_full 0.989
_diffrn_reflns_Laue_measured_fraction_max 0.985
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            18532
_diffrn_reflns_point_group_measured_fraction_full 0.989
_diffrn_reflns_point_group_measured_fraction_max 0.985
_diffrn_reflns_theta_full        25.214
_diffrn_reflns_theta_max         27.542
_diffrn_reflns_theta_min         2.556
_exptl_absorpt_coefficient_mu    0.920
_exptl_crystal_density_diffrn    1.362
_exptl_crystal_description       block
_exptl_crystal_F_000             1600
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.06
_refine_diff_density_max         0.837
_refine_diff_density_min         -0.425
_refine_diff_density_rms         0.102
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     471
_refine_ls_number_reflns         8750
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.046
_refine_ls_R_factor_all          0.0988
_refine_ls_R_factor_gt           0.0616
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0578P)²+10.9658P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1539
_refine_ls_wR_factor_ref         0.1705
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5828
_reflns_number_total             8750
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7ta01546a2.cif
_cod_data_source_block           p
_cod_original_cell_volume        3836.7(18)
_cod_database_code               7236564
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.947
_shelx_estimated_absorpt_t_min   0.914
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C9(H9), C10(H10), C11(H11), C12(H12), C15(H15), C16(H16),
 C21(H21), C22(H22), C23(H23), C24(H24), C27(H27), C28(H28), C30(H30), C32(H32),
  C33(H33), C34(H34)
2.b Idealised Me refined as rotating group:
 C25(H25a,H25b,H25c), C36(H36a,H36b,H36c)
;
_shelx_shelxl_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
Co1 Co 0.26107(3) 0.06700(3) 0.34007(3) 0.01987(14) Uani 1 1 d .
Co2 Co 0.23914(4) 0.09023(3) 0.16276(3) 0.02045(14) Uani 1 1 d .
O1 O 0.1432(2) 0.1732(2) 0.1781(2) 0.0423(8) Uani 1 1 d .
O2 O 0.1704(2) 0.1670(2) 0.3160(2) 0.0477(9) Uani 1 1 d .
O3 O -0.1586(2) 0.4877(2) 0.3303(2) 0.0475(9) Uani 1 1 d .
O4 O -0.1649(2) 0.4830(3) 0.1913(2) 0.0528(10) Uani 1 1 d .
O5 O 0.3512(2) 0.1594(2) 0.3310(2) 0.0424(8) Uani 1 1 d .
O6 O 0.3296(2) 0.1829(2) 0.1931(2) 0.0395(8) Uani 1 1 d .
O7 O 0.6620(2) 0.5033(2) 0.3091(3) 0.0556(10) Uani 1 1 d .
O8 O 0.6543(3) 0.4713(3) 0.1743(3) 0.0606(11) Uani 1 1 d .
N1 N 0.2512(3) 0.0840(2) 0.4657(2) 0.0318(9) Uani 1 1 d .
N2 N 0.2227(4) 0.0746(3) 0.5964(2) 0.0536(13) Uani 1 1 d .
N3 N 0.1395(5) -0.0210(4) 0.6672(3) 0.088(2) Uani 1 1 d .
N4 N 0.1434(5) -0.0206(4) 0.8176(3) 0.091(2) Uani 1 1 d .
N5 N 0.2382(3) 0.0674(3) 0.9007(2) 0.0492(12) Uani 1 1 d .
N6 N 0.2500(3) 0.0920(3) 1.0364(2) 0.0342(9) Uani 1 1 d .
C1 C 0.3688(3) 0.1960(3) 0.2643(3) 0.0295(9) Uani 1 1 d .
C2 C 0.4413(3) 0.2615(3) 0.2678(3) 0.0295(9) Uani 1 1 d .
C3 C 0.4468(3) 0.3104(3) 0.1957(3) 0.0436(12) Uani 1 1 d .
H3 H 0.4072 0.3015 0.1495 0.052 Uiso 1 1 calc R
C4 C 0.5109(3) 0.3726(3) 0.1913(3) 0.0445(13) Uani 1 1 d .
H4 H 0.5135 0.4039 0.1419 0.053 Uiso 1 1 calc R
C5 C 0.5697(3) 0.3885(3) 0.2575(3) 0.0348(10) Uani 1 1 d .
C6 C 0.6338(3) 0.4596(3) 0.2470(3) 0.0382(11) Uani 1 1 d .
C7 C 0.5682(3) 0.3389(3) 0.3330(3) 0.0395(11) Uani 1 1 d .
C8 C 0.5028(3) 0.2751(3) 0.3388(3) 0.0382(11) Uani 1 1 d .
C9 C 0.5034(4) 0.2257(5) 0.4141(4) 0.071(2) Uani 1 1 d .
H9 H 0.4619 0.1832 0.4190 0.085 Uiso 1 1 calc R
C10 C 0.5643(5) 0.2402(6) 0.4788(5) 0.124(4) Uani 1 1 d .
H10 H 0.5628 0.2089 0.5284 0.149 Uiso 1 1 calc R
C11 C 0.6292(6) 0.3012(7) 0.4720(5) 0.123(4) Uani 1 1 d .
H11 H 0.6716 0.3082 0.5163 0.148 Uiso 1 1 calc R
C12 C 0.6313(4) 0.3492(5) 0.4036(4) 0.078(2) Uani 1 1 d .
H12 H 0.6745 0.3904 0.4012 0.094 Uiso 1 1 calc R
C13 C 0.1276(3) 0.1929(3) 0.2512(3) 0.0294(9) Uani 1 1 d .
C14 C 0.0545(3) 0.2546(3) 0.2593(3) 0.0301(9) Uani 1 1 d .
C15 C 0.0348(3) 0.3107(4) 0.1942(3) 0.0459(13) Uani 1 1 d .
H15 H 0.0642 0.3065 0.1465 0.055 Uiso 1 1 calc R
C16 C -0.0284(3) 0.3742(4) 0.1974(3) 0.0468(14) Uani 1 1 d .
H16 H -0.0396 0.4118 0.1521 0.056 Uiso 1 1 calc R
C17 C -0.0742(3) 0.3827(3) 0.2656(3) 0.0312(10) Uani 1 1 d .
C18 C -0.1376(3) 0.4567(3) 0.2631(3) 0.0324(10) Uani 1 1 d .
C19 C -0.0584(3) 0.3231(3) 0.3341(3) 0.0303(10) Uani 1 1 d .
C20 C 0.0073(3) 0.2586(3) 0.3307(3) 0.0296(9) Uani 1 1 d .
C21 C 0.0198(3) 0.1985(3) 0.3983(3) 0.0433(12) Uani 1 1 d .
H21 H 0.0617 0.1559 0.3972 0.052 Uiso 1 1 calc R
C22 C -0.0286(4) 0.2023(4) 0.4649(4) 0.0596(17) Uani 1 1 d .
H22 H -0.0195 0.1620 0.5081 0.072 Uiso 1 1 calc R
C23 C -0.0911(4) 0.2653(4) 0.4687(4) 0.0614(17) Uani 1 1 d .
H23 H -0.1225 0.2675 0.5152 0.074 Uiso 1 1 calc R
C24 C -0.1075(3) 0.3243(4) 0.4053(3) 0.0458(13) Uani 1 1 d .
H24 H -0.1506 0.3654 0.4084 0.055 Uiso 1 1 calc R
C25 C 0.2289(7) -0.0659(4) 0.5137(4) 0.094(3) Uani 1 1 d .
H25A H 0.2235 -0.0925 0.5673 0.141 Uiso 1 1 calc GR
H25B H 0.2800 -0.0866 0.4916 0.141 Uiso 1 1 calc GR
H25C H 0.1799 -0.0806 0.4756 0.141 Uiso 1 1 calc GR
C26 C 0.2338(4) 0.0305(3) 0.5239(3) 0.0482(14) Uani 1 1 d .
C27 C 0.2506(3) 0.1661(3) 0.5006(3) 0.0380(11) Uani 1 1 d .
H27 H 0.2588 0.2176 0.4720 0.046 Uiso 1 1 calc R
C28 C 0.2367(4) 0.1605(3) 0.5813(3) 0.0473(14) Uani 1 1 d .
H28 H 0.2365 0.2060 0.6195 0.057 Uiso 1 1 calc R
C29 C 0.1962(4) 0.0426(4) 0.6727(3) 0.0586(17) Uani 1 1 d .
C30 C 0.2339(4) 0.0766(4) 0.7489(3) 0.0535(16) Uani 1 1 d .
H30 H 0.2769 0.1184 0.7520 0.064 Uiso 1 1 calc R
C31 C 0.2011(4) 0.0421(4) 0.8191(3) 0.0615(17) Uani 1 1 d .
C32 C 0.1151(7) -0.0487(6) 0.7407(4) 0.116(4) Uani 1 1 d .
H32 H 0.0739 -0.0924 0.7379 0.139 Uiso 1 1 calc R
C33 C 0.3207(4) 0.0914(5) 0.9217(4) 0.0676(19) Uani 1 1 d .
H33 H 0.3631 0.0981 0.8852 0.081 Uiso 1 1 calc R
C34 C 0.3294(4) 0.1032(5) 1.0032(3) 0.0612(17) Uani 1 1 d .
H34 H 0.3806 0.1170 1.0346 0.073 Uiso 1 1 calc R
C35 C 0.1957(4) 0.0709(3) 0.9738(3) 0.0448(13) Uani 1 1 d .
C36 C 0.1039(4) 0.0567(5) 0.9797(4) 0.0672(19) Uani 1 1 d .
H36A H 0.0714 0.0876 0.9352 0.101 Uiso 1 1 calc GR
H36B H 0.0888 0.0776 1.0329 0.101 Uiso 1 1 calc GR
H36C H 0.0915 -0.0043 0.9748 0.101 Uiso 1 1 calc GR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 Co1 Co2 73.20(10) . .
O4 Co1 Co2 79.37(11) 2_545 .
O4 Co1 O2 86.94(17) 2_545 .
O4 Co1 O5 161.20(14) 2_545 .
O4 Co1 N1 101.68(15) 2_545 .
O5 Co1 Co2 81.88(9) . .
O5 Co1 O2 86.43(16) . .
O5 Co1 N1 95.71(14) . .
O8 Co1 Co2 89.79(12) 2_645 .
O8 Co1 O2 162.97(16) 2_645 .
O8 Co1 O4 89.34(18) 2_645 2_545
O8 Co1 O5 91.88(17) 2_645 .
O8 Co1 N1 108.57(16) 2_645 .
N1 Co1 Co2 161.59(11) . .
N1 Co1 O2 88.46(14) . .
O1 Co2 Co1 88.81(10) . .
O1 Co2 O3 90.62(16) . 2_545
O1 Co2 O6 92.20(15) . .
O1 Co2 O7 160.40(15) . 2_645
O1 Co2 N6 104.26(15) . 1_554
O3 Co2 Co1 82.21(10) 2_545 .
O3 Co2 O6 162.44(13) 2_545 .
O3 Co2 O7 86.68(16) 2_545 2_645
O3 Co2 N6 100.12(15) 2_545 1_554
O6 Co2 Co1 80.53(9) . .
O6 Co2 O7 84.87(15) . 2_645
O6 Co2 N6 95.97(15) . 1_554
O7 Co2 Co1 71.59(12) 2_645 .
N6 Co2 Co1 166.64(11) 1_554 .
N6 Co2 O7 95.32(16) 1_554 2_645
C13 O1 Co2 118.9(3) . .
C13 O2 Co1 133.4(3) . .
C18 O3 Co2 124.1(3) . 2
C18 O4 Co1 128.2(3) . 2
C1 O5 Co1 126.0(3) . .
C1 O6 Co2 126.6(3) . .
C6 O7 Co2 136.6(4) . 2_655
C6 O8 Co1 116.3(3) . 2_655
C26 N1 Co1 131.8(3) . .
C26 N1 C27 106.4(4) . .
C27 N1 Co1 121.2(3) . .
C26 N2 C29 129.0(5) . .
C28 N2 C26 107.1(4) . .
C28 N2 C29 123.7(4) . .
C29 N3 C32 115.1(5) . .
C31 N4 C32 114.8(5) . .
C33 N5 C31 126.5(5) . .
C33 N5 C35 107.5(4) . .
C35 N5 C31 126.0(5) . .
C34 N6 Co2 122.3(3) . 1_556
C35 N6 Co2 130.7(4) . 1_556
C35 N6 C34 106.1(4) . .
O5 C1 C2 119.3(4) . .
O6 C1 O5 124.6(4) . .
O6 C1 C2 116.1(4) . .
C3 C2 C1 115.8(4) . .
C3 C2 C8 119.3(4) . .
C8 C2 C1 124.9(4) . .
C2 C3 C4 121.1(4) . .
C5 C4 C3 121.5(4) . .
C4 C5 C6 117.0(4) . .
C4 C5 C7 119.9(4) . .
C7 C5 C6 123.1(4) . .
O7 C6 O8 124.2(5) . .
O7 C6 C5 119.5(5) . .
O8 C6 C5 116.3(5) . .
C5 C7 C8 119.4(4) . .
C5 C7 C12 122.7(4) . .
C8 C7 C12 117.9(5) . .
C7 C8 C2 118.8(4) . .
C9 C8 C2 122.8(4) . .
C9 C8 C7 118.3(4) . .
C10 C9 C8 120.3(5) . .
C9 C10 C11 121.1(6) . .
C12 C11 C10 121.0(6) . .
C11 C12 C7 121.3(6) . .
O1 C13 C14 116.8(4) . .
O2 C13 O1 124.1(4) . .
O2 C13 C14 119.0(4) . .
C15 C14 C13 116.9(4) . .
C15 C14 C20 119.3(4) . .
C20 C14 C13 123.8(4) . .
C14 C15 C16 121.6(4) . .
C17 C16 C15 121.6(4) . .
C16 C17 C18 116.5(4) . .
C16 C17 C19 119.0(4) . .
C19 C17 C18 124.6(4) . .
O3 C18 O4 124.7(4) . .
O3 C18 C17 119.6(4) . .
O4 C18 C17 115.7(4) . .
C17 C19 C20 119.1(4) . .
C17 C19 C24 122.2(4) . .
C24 C19 C20 118.6(4) . .
C14 C20 C19 119.3(4) . .
C21 C20 C14 122.6(4) . .
C21 C20 C19 118.0(4) . .
C22 C21 C20 121.2(5) . .
C21 C22 C23 120.9(5) . .
C24 C23 C22 121.1(5) . .
C23 C24 C19 120.2(5) . .
N1 C26 N2 110.3(4) . .
N1 C26 C25 124.6(5) . .
N2 C26 C25 125.1(5) . .
C28 C27 N1 109.9(4) . .
C27 C28 N2 106.1(4) . .
N3 C29 N2 116.9(5) . .
N3 C29 C30 124.1(5) . .
C30 C29 N2 119.0(5) . .
C31 C30 C29 113.8(5) . .
N4 C31 N5 115.7(5) . .
N4 C31 C30 124.8(5) . .
C30 C31 N5 119.0(5) . .
N4 C32 N3 127.3(7) . .
C34 C33 N5 106.9(5) . .
C33 C34 N6 110.3(6) . .
N5 C35 C36 126.5(5) . .
N6 C35 N5 109.1(5) . .
N6 C35 C36 124.4(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Co1 Co2 2.8459(10) .
Co1 O2 2.104(3) .
Co1 O4 2.013(3) 2_545
Co1 O5 2.018(3) .
Co1 O8 2.009(4) 2_645
Co1 N1 2.047(3) .
Co2 O1 2.005(3) .
Co2 O3 2.029(3) 2_545
Co2 O6 2.036(3) .
Co2 O7 2.064(3) 2_645
Co2 N6 2.044(4) 1_554
O1 C13 1.254(5) .
O2 C13 1.246(5) .
O3 Co2 2.029(3) 2
O3 C18 1.248(6) .
O4 Co1 2.013(3) 2
O4 C18 1.253(6) .
O5 C1 1.260(5) .
O6 C1 1.257(5) .
O7 Co2 2.064(3) 2_655
O7 C6 1.244(6) .
O8 Co1 2.009(4) 2_655
O8 C6 1.248(6) .
N1 C26 1.291(6) .
N1 C27 1.380(5) .
N2 C26 1.369(6) .
N2 C28 1.364(6) .
N2 C29 1.415(6) .
N3 C29 1.318(7) .
N3 C32 1.340(8) .
N4 C31 1.322(8) .
N4 C32 1.339(8) .
N5 C31 1.431(6) .
N5 C33 1.356(8) .
N5 C35 1.400(6) .
N6 Co2 2.044(4) 1_556
N6 C34 1.409(7) .
N6 C35 1.293(6) .
C1 C2 1.515(5) .
C2 C3 1.386(6) .
C2 C8 1.433(6) .
C3 C4 1.393(6) .
C4 C5 1.358(7) .
C5 C6 1.506(6) .
C5 C7 1.429(6) .
C7 C8 1.430(6) .
C7 C12 1.438(7) .
C8 C9 1.423(7) .
C9 C10 1.358(9) .
C10 C11 1.395(10) .
C11 C12 1.322(9) .
C13 C14 1.503(6) .
C14 C15 1.364(6) .
C14 C20 1.421(6) .
C15 C16 1.395(6) .
C16 C17 1.367(6) .
C17 C18 1.509(6) .
C17 C19 1.431(6) .
C19 C20 1.435(6) .
C19 C24 1.435(6) .
C20 C21 1.420(6) .
C21 C22 1.367(7) .
C22 C23 1.383(8) .
C23 C24 1.367(7) .
C25 C26 1.492(7) .
C27 C28 1.332(6) .
C29 C30 1.404(7) .
C30 C31 1.383(7) .
C33 C34 1.311(8) .
C35 C36 1.468(8) .
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.000 0.000 0.000 49 29 ' '
2 0.000 0.000 0.500 45 22 ' '
3 0.500 0.000 0.500 30 16 ' '
4 0.000 0.500 1.000 45 23 ' '
5 1.000 0.500 0.500 49 27 ' '
6 0.500 0.500 0.000 30 16 ' '
