#------------------------------------------------------------------------------
#$Date: 2019-11-28 16:29:13 +0200 (Thu, 28 Nov 2019) $
#$Revision: 244108 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/83/7238300.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7238300
loop_
_publ_author_name
'Chen, Man-Sheng'
'Su, Zhi'
'Chen, Min'
'Chen, Shui-Sheng'
'Li, Yi-Zhi'
'Sun, Wei-Yin'
_publ_section_title
;
 Three-dimensional lanthanide--silver heterometallic coordination
 polymers: syntheses, structures and properties
;
_journal_issue                   10
_journal_name_full               CrystEngComm
_journal_page_first              3267
_journal_paper_doi               10.1039/c005207h
_journal_volume                  12
_journal_year                    2010
_chemical_formula_sum            'C28 H18 Ag La N4 O11'
_chemical_formula_weight         833.24
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                107.969(2)
_cell_angle_beta                 106.7870(10)
_cell_angle_gamma                103.220(2)
_cell_formula_units_Z            2
_cell_length_a                   10.5151(10)
_cell_length_b                   11.1900(11)
_cell_length_c                   13.7534(13)
_cell_measurement_temperature    293(2)
_cell_volume                     1381.1(2)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.983
_diffrn_measured_fraction_theta_max 0.983
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0619
_diffrn_reflns_av_sigmaI/netI    0.0438
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            6891
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         1.69
_exptl_absorpt_coefficient_mu    2.307
_exptl_absorpt_correction_T_max  0.7383
_exptl_absorpt_correction_T_min  0.5854
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_crystal_density_diffrn    2.004
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             812
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.14
_refine_diff_density_max         1.745
_refine_diff_density_min         -2.388
_refine_diff_density_rms         0.131
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     406
_refine_ls_number_reflns         4801
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.0353
_refine_ls_R_factor_gt           0.0334
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0641P)²+1.1790P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0913
_refine_ls_wR_factor_ref         0.0926
_reflns_number_gt                4597
_reflns_number_total             4801
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c005207h.txt
_cod_data_source_block           6
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/RSC/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_H-M      'P-1 '
_cod_database_code               7238300
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 1.38028(4) 1.23142(5) 1.05143(3) 0.05412(15) Uani 1 1 d .
La1 La 0.865178(19) 0.548045(17) -0.113267(14) 0.01457(10) Uani 1 1 d .
C1 C 0.5071(4) 0.4440(4) -0.2946(3) 0.0203(7) Uani 1 1 d .
C2 C 0.3614(4) 0.4280(4) -0.2937(3) 0.0204(7) Uani 1 1 d .
C3 C 0.2467(4) 0.3824(4) -0.3939(3) 0.0211(7) Uani 1 1 d .
H3 H 0.2617 0.3719 -0.4590 0.025 Uiso 1 1 calc R
C4 C 0.1105(4) 0.3527(4) -0.3965(3) 0.0190(7) Uani 1 1 d .
C5 C 0.0871(4) 0.3679(4) -0.3003(3) 0.0205(7) Uani 1 1 d .
H5 H -0.0049 0.3460 -0.3028 0.025 Uiso 1 1 calc R
C6 C 0.2017(4) 0.4161(4) -0.1997(3) 0.0203(7) Uani 1 1 d .
C7 C 0.3388(4) 0.4452(4) -0.1967(3) 0.0222(8) Uani 1 1 d .
H7 H 0.4153 0.4763 -0.1297 0.027 Uiso 1 1 calc R
C8 C 0.1738(4) 0.4311(3) -0.0974(3) 0.0196(7) Uani 1 1 d .
C9 C -0.0241(4) 0.3460(4) -0.5773(3) 0.0219(8) Uani 1 1 d .
C10 C -0.1708(4) 0.2896(4) -0.6658(3) 0.0243(8) Uani 1 1 d .
C11 C -0.1867(5) 0.2672(5) -0.7737(4) 0.0368(10) Uani 1 1 d .
H11 H -0.1080 0.2793 -0.7926 0.044 Uiso 1 1 calc R
C12 C -0.3205(5) 0.2266(6) -0.8530(4) 0.0419(12) Uani 1 1 d .
H12 H -0.3301 0.2092 -0.9259 0.050 Uiso 1 1 calc R
C13 C -0.4210(5) 0.2306(6) -0.7265(4) 0.0451(12) Uani 1 1 d .
H13 H -0.5013 0.2187 -0.7096 0.054 Uiso 1 1 calc R
C14 C -0.2918(5) 0.2674(5) -0.6431(4) 0.0398(11) Uani 1 1 d .
H14 H -0.2857 0.2773 -0.5721 0.048 Uiso 1 1 calc R
C15 C 1.1842(4) 0.7592(4) 0.1045(3) 0.0189(7) Uani 1 1 d .
C16 C 1.2093(4) 0.8992(4) 0.1802(3) 0.0217(8) Uani 1 1 d .
C17 C 1.2568(4) 0.9369(4) 0.2939(3) 0.0223(8) Uani 1 1 d .
H17 H 1.2804 0.8775 0.3243 0.027 Uiso 1 1 calc R
C18 C 1.2691(4) 1.0630(4) 0.3626(3) 0.0226(8) Uani 1 1 d .
C19 C 1.2353(4) 1.1515(4) 0.3178(3) 0.0232(8) Uani 1 1 d .
H19 H 1.2413 1.2353 0.3636 0.028 Uiso 1 1 calc R
C20 C 1.1922(4) 1.1155(4) 0.2036(3) 0.0210(7) Uani 1 1 d .
C21 C 1.1784(4) 0.9899(4) 0.1350(3) 0.0204(7) Uani 1 1 d .
H21 H 1.1486 0.9656 0.0589 0.024 Uiso 1 1 calc R
C22 C 1.1533(4) 1.2132(4) 0.1569(3) 0.0200(7) Uani 1 1 d .
C23 C 1.2457(5) 1.0252(4) 0.5213(3) 0.0305(9) Uani 1 1 d .
C24 C 1.2834(5) 1.0798(4) 0.6444(3) 0.0269(8) Uani 1 1 d .
C25 C 1.1735(5) 1.0573(5) 0.6810(4) 0.0368(10) Uani 1 1 d .
H25 H 1.0800 1.0132 0.6304 0.044 Uiso 1 1 calc R
C26 C 1.2050(5) 1.1009(5) 0.7926(4) 0.0380(10) Uani 1 1 d .
H26 H 1.1307 1.0860 0.8163 0.046 Uiso 1 1 calc R
C27 C 1.4419(5) 1.1861(5) 0.8335(4) 0.0385(11) Uani 1 1 d .
H27 H 1.5344 1.2303 0.8858 0.046 Uiso 1 1 calc R
C28 C 1.4202(5) 1.1470(5) 0.7225(3) 0.0330(9) Uani 1 1 d .
H28 H 1.4961 1.1655 0.7010 0.040 Uiso 1 1 calc R
N1 N -0.4369(4) 0.2109(4) -0.8310(3) 0.0369(9) Uani 1 1 d .
N2 N -0.0102(3) 0.3007(3) -0.4968(3) 0.0236(7) Uani 1 1 d .
H2 H -0.0803 0.2345 -0.5068 0.028 Uiso 1 1 calc R
N3 N 1.3384(4) 1.1644(4) 0.8700(3) 0.0354(8) Uani 1 1 d .
N4 N 1.3116(4) 1.1013(3) 0.4797(3) 0.0251(7) Uani 1 1 d .
H4 H 1.3811 1.1746 0.5243 0.030 Uiso 1 1 calc R
O1 O 0.6117(3) 0.5253(3) -0.2079(2) 0.0263(6) Uani 1 1 d .
O2 O 0.5148(3) 0.3721(3) -0.3812(2) 0.0318(7) Uani 1 1 d .
O3 O 0.2679(3) 0.4383(3) -0.0136(2) 0.0314(7) Uani 1 1 d .
O4 O 0.0536(3) 0.4363(3) -0.0965(2) 0.0210(5) Uani 1 1 d .
O5 O 0.0726(3) 0.4286(3) -0.5795(2) 0.0304(6) Uani 1 1 d .
O6 O 1.1079(3) 0.7206(3) 0.0037(2) 0.0250(6) Uani 1 1 d .
O7 O 1.2398(3) 0.6898(2) 0.1474(2) 0.0228(6) Uani 1 1 d .
O8 O 1.1136(3) 1.2977(3) 0.2117(2) 0.0272(6) Uani 1 1 d .
O9 O 1.1625(3) 1.2087(3) 0.0663(2) 0.0236(6) Uani 1 1 d .
O10 O 1.1549(5) 0.9147(4) 0.4629(3) 0.0612(12) Uani 1 1 d .
O1W O 0.7954(3) 0.4189(3) -0.3245(2) 0.0246(6) Uani 1 1 d .
H1WB H 0.7057 0.3946 -0.3547 0.030 Uiso 1 1 d R
H1WA H 0.8295 0.4727 -0.3502 0.030 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
La La -0.2871 2.4523 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N3 121.39(14) 1_767 .
N1 Ag1 O9 124.30(12) 1_767 1_556
N3 Ag1 O9 106.76(12) . 1_556
O7 La1 O6 132.80(9) 2_765 .
O7 La1 O8 142.09(9) 2_765 2_775
O6 La1 O8 76.56(9) . 2_775
O7 La1 O1 83.91(9) 2_765 .
O6 La1 O1 141.78(9) . .
O8 La1 O1 77.01(9) 2_775 .
O7 La1 O3 77.73(10) 2_765 2_665
O6 La1 O3 105.52(9) . 2_665
O8 La1 O3 122.38(9) 2_775 2_665
O1 La1 O3 67.36(8) . 2_665
O7 La1 O4 68.99(8) 2_765 1_655
O6 La1 O4 69.44(8) . 1_655
O8 La1 O4 114.09(8) 2_775 1_655
O1 La1 O4 147.80(9) . 1_655
O3 La1 O4 120.36(8) 2_665 1_655
O7 La1 O1W 75.67(8) 2_765 .
O6 La1 O1W 119.79(8) . .
O8 La1 O1W 67.65(8) 2_775 .
O1 La1 O1W 73.49(8) . .
O3 La1 O1W 134.37(9) 2_665 .
O4 La1 O1W 82.92(8) 1_655 .
O7 La1 O4 79.38(8) 2_765 2_665
O6 La1 O4 69.67(8) . 2_665
O8 La1 O4 138.51(8) 2_775 2_665
O1 La1 O4 116.95(8) . 2_665
O3 La1 O4 49.77(8) 2_665 2_665
O4 La1 O4 75.85(8) 1_655 2_665
O1W La1 O4 151.73(8) . 2_665
O7 La1 O9 147.44(8) 2_765 2_775
O6 La1 O9 72.68(8) . 2_775
O8 La1 O9 49.85(8) 2_775 2_775
O1 La1 O9 69.20(9) . 2_775
O3 La1 O9 75.20(9) 2_665 2_775
O4 La1 O9 141.71(8) 1_655 2_775
O1W La1 O9 111.87(8) . 2_775
O4 La1 O9 96.32(8) 2_665 2_775
O7 La1 C22 151.13(9) 2_765 2_775
O6 La1 C22 76.00(9) . 2_775
O8 La1 C22 24.82(9) 2_775 2_775
O1 La1 C22 68.46(10) . 2_775
O3 La1 C22 98.20(10) 2_665 2_775
O4 La1 C22 133.34(9) 1_655 2_775
O1W La1 C22 88.17(9) . 2_775
O4 La1 C22 120.00(9) 2_665 2_775
O9 La1 C22 25.37(9) 2_775 2_775
O7 La1 C8 77.81(9) 2_765 2_665
O6 La1 C8 87.54(9) . 2_665
O8 La1 C8 134.47(9) 2_775 2_665
O1 La1 C8 91.69(9) . 2_665
O3 La1 C8 24.38(9) 2_665 2_665
O4 La1 C8 98.92(9) 1_655 2_665
O1W La1 C8 150.74(9) . 2_665
O4 La1 C8 25.40(9) 2_665 2_665
O9 La1 C8 84.77(9) 2_775 2_665
C22 La1 C8 110.10(10) 2_775 2_665
O7 La1 La1 70.05(6) 2_765 2_765
O6 La1 La1 63.73(6) . 2_765
O8 La1 La1 137.63(7) 2_775 2_765
O1 La1 La1 144.81(6) . 2_765
O3 La1 La1 83.85(6) 2_665 2_765
O4 La1 La1 39.03(5) 1_655 2_765
O1W La1 La1 119.72(6) . 2_765
O4 La1 La1 36.81(5) 2_665 2_765
O9 La1 La1 123.81(6) 2_775 2_765
C22 La1 La1 138.49(7) 2_775 2_765
C8 La1 La1 60.60(7) 2_665 2_765
O2 C1 O1 124.8(3) . .
O2 C1 C2 117.3(3) . .
O1 C1 C2 117.9(3) . .
C7 C2 C3 119.9(3) . .
C7 C2 C1 120.9(3) . .
C3 C2 C1 118.9(3) . .
C4 C3 C2 119.9(3) . .
C4 C3 H3 120.1 . .
C2 C3 H3 120.1 . .
C5 C4 C3 120.5(3) . .
C5 C4 N2 117.4(3) . .
C3 C4 N2 122.1(3) . .
C4 C5 C6 119.8(3) . .
C4 C5 H5 120.1 . .
C6 C5 H5 120.1 . .
C7 C6 C5 119.9(3) . .
C7 C6 C8 121.2(3) . .
C5 C6 C8 118.8(3) . .
C2 C7 C6 120.0(3) . .
C2 C7 H7 120.0 . .
C6 C7 H7 120.0 . .
O3 C8 O4 121.1(3) . .
O3 C8 C6 119.5(3) . .
O4 C8 C6 119.5(3) . .
O3 C8 La1 56.52(18) . 2_665
O4 C8 La1 64.58(18) . 2_665
C6 C8 La1 175.6(3) . 2_665
O5 C9 N2 123.8(3) . .
O5 C9 C10 121.4(3) . .
N2 C9 C10 114.8(3) . .
C11 C10 C14 117.9(4) . .
C11 C10 C9 119.1(4) . .
C14 C10 C9 122.9(3) . .
C12 C11 C10 119.1(4) . .
C12 C11 H11 120.5 . .
C10 C11 H11 120.5 . .
N1 C12 C11 123.5(4) . .
N1 C12 H12 118.3 . .
C11 C12 H12 118.3 . .
N1 C13 C14 123.1(4) . .
N1 C13 H13 118.5 . .
C14 C13 H13 118.5 . .
C13 C14 C10 119.3(4) . .
C13 C14 H14 120.3 . .
C10 C14 H14 120.3 . .
O6 C15 O7 125.5(3) . .
O6 C15 C16 117.2(3) . .
O7 C15 C16 117.3(3) . .
C17 C16 C21 119.9(3) . .
C17 C16 C15 120.5(3) . .
C21 C16 C15 119.5(3) . .
C16 C17 C18 120.2(3) . .
C16 C17 H17 119.9 . .
C18 C17 H17 119.9 . .
C19 C18 C17 119.9(3) . .
C19 C18 N4 119.2(3) . .
C17 C18 N4 120.9(3) . .
C18 C19 C20 120.0(3) . .
C18 C19 H19 120.0 . .
C20 C19 H19 120.0 . .
C21 C20 C19 120.2(3) . .
C21 C20 C22 121.0(3) . .
C19 C20 C22 118.7(3) . .
C20 C21 C16 119.7(3) . .
C20 C21 H21 120.1 . .
C16 C21 H21 120.1 . .
O8 C22 O9 122.5(3) . .
O8 C22 C20 117.2(3) . .
O9 C22 C20 120.3(3) . .
O8 C22 La1 57.55(18) . 2_775
O9 C22 La1 66.27(18) . 2_775
C20 C22 La1 166.4(2) . 2_775
O10 C23 N4 122.5(4) . .
O10 C23 C24 119.1(4) . .
N4 C23 C24 118.4(4) . .
C28 C24 C25 118.5(4) . .
C28 C24 C23 123.9(4) . .
C25 C24 C23 117.6(4) . .
C26 C25 C24 119.0(4) . .
C26 C25 H25 120.5 . .
C24 C25 H25 120.5 . .
N3 C26 C25 123.3(4) . .
N3 C26 H26 118.4 . .
C25 C26 H26 118.4 . .
N3 C27 C28 123.9(4) . .
N3 C27 H27 118.0 . .
C28 C27 H27 118.0 . .
C24 C28 C27 118.4(4) . .
C24 C28 H28 120.8 . .
C27 C28 H28 120.8 . .
C12 N1 C13 117.1(4) . .
C12 N1 Ag1 115.9(3) . 1_343
C13 N1 Ag1 122.8(3) . 1_343
C9 N2 C4 125.4(3) . .
C9 N2 H2 117.3 . .
C4 N2 H2 117.3 . .
C27 N3 C26 116.9(4) . .
C27 N3 Ag1 122.2(3) . .
C26 N3 Ag1 120.8(3) . .
C23 N4 C18 121.4(3) . .
C23 N4 H4 119.3 . .
C18 N4 H4 119.3 . .
C1 O1 La1 136.9(2) . .
C8 O3 La1 99.1(2) . 2_665
C8 O4 La1 151.2(2) . 1_455
C8 O4 La1 90.0(2) . 2_665
La1 O4 La1 104.15(8) 1_455 2_665
C15 O6 La1 131.0(2) . .
C15 O7 La1 128.7(2) . 2_765
C22 O8 La1 97.6(2) . 2_775
C22 O9 Ag1 118.7(2) . 1_554
C22 O9 La1 88.4(2) . 2_775
Ag1 O9 La1 107.05(10) 1_554 2_775
La1 O1W H1WB 106.5 . .
La1 O1W H1WA 109.0 . .
H1WB O1W H1WA 106.7 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.236(4) 1_767
Ag1 N3 2.246(3) .
Ag1 O9 2.322(3) 1_556
La1 O7 2.472(2) 2_765
La1 O6 2.508(3) .
La1 O8 2.511(3) 2_775
La1 O1 2.519(3) .
La1 O3 2.524(3) 2_665
La1 O4 2.567(2) 1_655
La1 O1W 2.600(3) .
La1 O4 2.698(2) 2_665
La1 O9 2.701(3) 2_775
La1 C22 2.949(4) 2_775
La1 C8 2.988(4) 2_665
C1 O2 1.252(5) .
C1 O1 1.255(5) .
C1 C2 1.505(5) .
C2 C7 1.385(5) .
C2 C3 1.392(5) .
C3 C4 1.382(5) .
C3 H3 0.9300 .
C4 C5 1.381(5) .
C4 N2 1.417(5) .
C5 C6 1.392(5) .
C5 H5 0.9300 .
C6 C7 1.389(5) .
C6 C8 1.487(5) .
C7 H7 0.9300 .
C8 O3 1.249(5) .
C8 O4 1.282(5) .
C8 La1 2.988(4) 2_665
C9 O5 1.222(5) .
C9 N2 1.338(5) .
C9 C10 1.502(5) .
C10 C11 1.378(6) .
C10 C14 1.383(6) .
C11 C12 1.375(6) .
C11 H11 0.9300 .
C12 N1 1.330(6) .
C12 H12 0.9300 .
C13 N1 1.338(6) .
C13 C14 1.372(6) .
C13 H13 0.9300 .
C14 H14 0.9300 .
C15 O6 1.258(4) .
C15 O7 1.259(4) .
C15 C16 1.501(5) .
C16 C17 1.385(5) .
C16 C21 1.394(5) .
C17 C18 1.387(5) .
C17 H17 0.9300 .
C18 C19 1.378(5) .
C18 N4 1.430(5) .
C19 C20 1.395(5) .
C19 H19 0.9300 .
C20 C21 1.378(5) .
C20 C22 1.504(5) .
C21 H21 0.9300 .
C22 O8 1.249(5) .
C22 O9 1.264(4) .
C22 La1 2.949(4) 2_775
C23 O10 1.221(5) .
C23 N4 1.339(5) .
C23 C24 1.504(5) .
C24 C28 1.379(6) .
C24 C25 1.390(6) .
C25 C26 1.369(6) .
C25 H25 0.9300 .
C26 N3 1.349(6) .
C26 H26 0.9300 .
C27 N3 1.328(6) .
C27 C28 1.385(6) .
C27 H27 0.9300 .
C28 H28 0.9300 .
N1 Ag1 2.236(4) 1_343
N2 H2 0.8600 .
N4 H4 0.8600 .
O3 La1 2.524(3) 2_665
O4 La1 2.567(2) 1_455
O4 La1 2.698(2) 2_665
O7 La1 2.472(2) 2_765
O8 La1 2.511(3) 2_775
O9 Ag1 2.322(3) 1_554
O9 La1 2.701(3) 2_775
O1W H1WB 0.8500 .
O1W H1WA 0.8500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O2 C1 C2 C7 147.3(4) . .
O1 C1 C2 C7 -30.7(5) . .
O2 C1 C2 C3 -26.3(5) . .
O1 C1 C2 C3 155.7(4) . .
C7 C2 C3 C4 -0.9(6) . .
C1 C2 C3 C4 172.8(3) . .
C2 C3 C4 C5 0.0(6) . .
C2 C3 C4 N2 -177.3(3) . .
C3 C4 C5 C6 1.3(6) . .
N2 C4 C5 C6 178.8(3) . .
C4 C5 C6 C7 -1.8(5) . .
C4 C5 C6 C8 -179.7(3) . .
C3 C2 C7 C6 0.4(6) . .
C1 C2 C7 C6 -173.1(3) . .
C5 C6 C7 C2 0.9(6) . .
C8 C6 C7 C2 178.8(3) . .
C7 C6 C8 O3 -17.3(5) . .
C5 C6 C8 O3 160.6(4) . .
C7 C6 C8 O4 162.7(3) . .
C5 C6 C8 O4 -19.3(5) . .
C7 C6 C8 La1 -41(3) . 2_665
C5 C6 C8 La1 137(3) . 2_665
O5 C9 C10 C11 35.9(6) . .
N2 C9 C10 C11 -145.4(4) . .
O5 C9 C10 C14 -139.6(5) . .
N2 C9 C10 C14 39.1(6) . .
C14 C10 C11 C12 1.2(7) . .
C9 C10 C11 C12 -174.4(4) . .
C10 C11 C12 N1 1.9(8) . .
N1 C13 C14 C10 2.0(9) . .
C11 C10 C14 C13 -3.1(7) . .
C9 C10 C14 C13 172.4(5) . .
O6 C15 C16 C17 161.9(3) . .
O7 C15 C16 C17 -17.3(5) . .
O6 C15 C16 C21 -15.2(5) . .
O7 C15 C16 C21 165.6(3) . .
C21 C16 C17 C18 2.2(6) . .
C15 C16 C17 C18 -174.9(4) . .
C16 C17 C18 C19 -0.6(6) . .
C16 C17 C18 N4 177.1(3) . .
C17 C18 C19 C20 -1.6(6) . .
N4 C18 C19 C20 -179.4(3) . .
C18 C19 C20 C21 2.3(6) . .
C18 C19 C20 C22 178.8(3) . .
C19 C20 C21 C16 -0.7(6) . .
C22 C20 C21 C16 -177.1(3) . .
C17 C16 C21 C20 -1.5(6) . .
C15 C16 C21 C20 175.6(3) . .
C21 C20 C22 O8 152.0(4) . .
C19 C20 C22 O8 -24.4(5) . .
C21 C20 C22 O9 -28.6(5) . .
C19 C20 C22 O9 155.0(4) . .
C21 C20 C22 La1 -144.1(9) . 2_775
C19 C20 C22 La1 39.5(13) . 2_775
O10 C23 C24 C28 138.3(5) . .
N4 C23 C24 C28 -42.9(6) . .
O10 C23 C24 C25 -39.7(6) . .
N4 C23 C24 C25 139.2(4) . .
C28 C24 C25 C26 -0.8(7) . .
C23 C24 C25 C26 177.3(4) . .
C24 C25 C26 N3 -0.5(8) . .
C25 C24 C28 C27 1.4(6) . .
C23 C24 C28 C27 -176.6(4) . .
N3 C27 C28 C24 -0.8(7) . .
C11 C12 N1 C13 -3.0(8) . .
C11 C12 N1 Ag1 154.7(4) . 1_343
C14 C13 N1 C12 1.0(8) . .
C14 C13 N1 Ag1 -155.0(4) . 1_343
O5 C9 N2 C4 8.6(6) . .
C10 C9 N2 C4 -170.0(3) . .
C5 C4 N2 C9 137.6(4) . .
C3 C4 N2 C9 -45.0(6) . .
C28 C27 N3 C26 -0.4(7) . .
C28 C27 N3 Ag1 -179.7(4) . .
C25 C26 N3 C27 1.1(7) . .
C25 C26 N3 Ag1 -179.6(4) . .
N1 Ag1 N3 C27 -41.1(4) 1_767 .
O9 Ag1 N3 C27 168.1(4) 1_556 .
N1 Ag1 N3 C26 139.6(4) 1_767 .
O9 Ag1 N3 C26 -11.2(4) 1_556 .
O10 C23 N4 C18 6.6(7) . .
C24 C23 N4 C18 -172.3(4) . .
C19 C18 N4 C23 125.3(4) . .
C17 C18 N4 C23 -52.4(6) . .
O2 C1 O1 La1 -27.9(6) . .
C2 C1 O1 La1 149.9(3) . .
O7 La1 O1 C1 -47.8(4) 2_765 .
O6 La1 O1 C1 146.5(3) . .
O8 La1 O1 C1 99.2(4) 2_775 .
O3 La1 O1 C1 -127.0(4) 2_665 .
O4 La1 O1 C1 -15.6(4) 1_655 .
O1W La1 O1 C1 29.0(3) . .
O4 La1 O1 C1 -122.6(3) 2_665 .
O9 La1 O1 C1 150.9(4) 2_775 .
C22 La1 O1 C1 123.6(4) 2_775 .
C8 La1 O1 C1 -125.4(4) 2_665 .
La1 La1 O1 C1 -89.5(4) 2_765 .
O4 C8 O3 La1 2.1(4) . 2_665
C6 C8 O3 La1 -177.8(3) . 2_665
O3 C8 O4 La1 118.7(4) . 1_455
C6 C8 O4 La1 -61.4(6) . 1_455
La1 C8 O4 La1 120.6(5) 2_665 1_455
O3 C8 O4 La1 -1.9(4) . 2_665
C6 C8 O4 La1 178.0(3) . 2_665
O7 C15 O6 La1 67.6(5) . .
C16 C15 O6 La1 -111.5(3) . .
O7 La1 O6 C15 -52.4(3) 2_765 .
O8 La1 O6 C15 155.4(3) 2_775 .
O1 La1 O6 C15 108.0(3) . .
O3 La1 O6 C15 35.1(3) 2_665 .
O4 La1 O6 C15 -82.1(3) 1_655 .
O1W La1 O6 C15 -150.6(3) . .
O4 La1 O6 C15 -0.1(3) 2_665 .
O9 La1 O6 C15 103.7(3) 2_775 .
C22 La1 O6 C15 129.8(3) 2_775 .
C8 La1 O6 C15 18.4(3) 2_665 .
La1 La1 O6 C15 -39.8(3) 2_765 .
O6 C15 O7 La1 -42.1(5) . 2_765
C16 C15 O7 La1 137.0(3) . 2_765
O9 C22 O8 La1 -13.9(4) . 2_775
C20 C22 O8 La1 165.5(3) . 2_775
O8 C22 O9 Ag1 121.4(3) . 1_554
C20 C22 O9 Ag1 -58.0(4) . 1_554
La1 C22 O9 Ag1 108.58(18) 2_775 1_554
O8 C22 O9 La1 12.8(4) . 2_775
C20 C22 O9 La1 -166.5(3) . 2_775
