#------------------------------------------------------------------------------
#$Date: 2019-11-28 16:29:13 +0200 (Thu, 28 Nov 2019) $
#$Revision: 244108 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/83/7238301.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7238301
loop_
_publ_author_name
'Chen, Man-Sheng'
'Su, Zhi'
'Chen, Min'
'Chen, Shui-Sheng'
'Li, Yi-Zhi'
'Sun, Wei-Yin'
_publ_section_title
;
 Three-dimensional lanthanide--silver heterometallic coordination
 polymers: syntheses, structures and properties
;
_journal_issue                   10
_journal_name_full               CrystEngComm
_journal_page_first              3267
_journal_paper_doi               10.1039/c005207h
_journal_volume                  12
_journal_year                    2010
_chemical_formula_sum            'C28 H18 Ag N4 O11 Pr'
_chemical_formula_weight         835.24
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                107.772(3)
_cell_angle_beta                 106.823(3)
_cell_angle_gamma                102.759(4)
_cell_formula_units_Z            2
_cell_length_a                   10.499(2)
_cell_length_b                   11.141(2)
_cell_length_c                   13.738(3)
_cell_measurement_temperature    293(2)
_cell_volume                     1377.9(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0476
_diffrn_reflns_av_sigmaI/netI    0.0333
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            6873
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         2.04
_exptl_absorpt_coefficient_mu    2.530
_exptl_absorpt_correction_T_max  0.7511
_exptl_absorpt_correction_T_min  0.6316
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_crystal_density_diffrn    2.013
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             816
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.12
_refine_diff_density_max         1.613
_refine_diff_density_min         -2.977
_refine_diff_density_rms         0.155
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     406
_refine_ls_number_reflns         4784
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.031
_refine_ls_R_factor_all          0.0368
_refine_ls_R_factor_gt           0.0360
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0700P)²+2.2675P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0966
_refine_ls_wR_factor_ref         0.0974
_reflns_number_gt                4628
_reflns_number_total             4784
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c005207h.txt
_cod_data_source_block           7
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/RSC/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_H-M      'P-1 '
_cod_database_code               7238301
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 1.11656(5) 0.76720(7) 1.44976(4) 0.06028(17) Uani 1 1 d .
Pr1 Pr 0.636413(19) 0.453281(18) 0.612252(15) 0.01472(10) Uani 1 1 d U
C1 C 0.3222(4) 0.2435(4) 0.3986(3) 0.0185(8) Uani 1 1 d .
C2 C 0.2941(4) 0.1021(4) 0.3221(3) 0.0211(8) Uani 1 1 d .
C3 C 0.2461(5) 0.0663(4) 0.2084(3) 0.0245(9) Uani 1 1 d .
H3 H 0.2241 0.1273 0.1787 0.029 Uiso 1 1 calc R
C4 C 0.2310(5) -0.0615(4) 0.1386(3) 0.0241(8) Uani 1 1 d .
C5 C 0.2633(4) -0.1520(4) 0.1838(3) 0.0241(9) Uani 1 1 d .
H5 H 0.2553 -0.2367 0.1379 0.029 Uiso 1 1 calc R
C6 C 0.3075(4) -0.1164(4) 0.2974(3) 0.0213(8) Uani 1 1 d .
C7 C 0.3233(4) 0.0100(4) 0.3671(3) 0.0215(8) Uani 1 1 d .
H7 H 0.3530 0.0333 0.4431 0.026 Uiso 1 1 calc R
C8 C 0.3429(4) -0.2164(4) 0.3437(3) 0.0207(8) Uani 1 1 d .
C9 C 0.2558(5) -0.0227(5) -0.0199(4) 0.0327(10) Uani 1 1 d .
C10 C 0.2165(5) -0.0775(5) -0.1431(4) 0.0299(10) Uani 1 1 d .
C11 C 0.0797(5) -0.1419(5) -0.2204(4) 0.0357(11) Uani 1 1 d .
H11 H 0.0045 -0.1582 -0.1979 0.043 Uiso 1 1 calc R
C12 C 0.0560(6) -0.1814(6) -0.3306(4) 0.0431(13) Uani 1 1 d .
H12 H -0.0369 -0.2239 -0.3816 0.052 Uiso 1 1 calc R
C13 C 0.2941(5) -0.1004(6) -0.2922(4) 0.0406(12) Uani 1 1 d .
H13 H 0.3682 -0.0870 -0.3163 0.049 Uiso 1 1 calc R
C14 C 0.3252(5) -0.0571(5) -0.1809(4) 0.0390(11) Uani 1 1 d .
H14 H 0.4186 -0.0144 -0.1308 0.047 Uiso 1 1 calc R
C15 C 0.3267(4) 0.5677(4) 0.5970(3) 0.0207(8) Uani 1 1 d .
C16 C 0.2983(4) 0.5840(4) 0.6996(3) 0.0191(8) Uani 1 1 d .
C17 C 0.4120(4) 0.6318(4) 0.7998(3) 0.0210(8) Uani 1 1 d .
H17 H 0.5039 0.6526 0.8022 0.025 Uiso 1 1 calc R
C18 C 0.3878(4) 0.6482(4) 0.8961(3) 0.0207(8) Uani 1 1 d .
C19 C 0.2511(4) 0.6196(4) 0.8931(3) 0.0220(8) Uani 1 1 d .
H19 H 0.2355 0.6305 0.9581 0.026 Uiso 1 1 calc R
C20 C 0.1371(4) 0.5743(4) 0.7929(3) 0.0215(8) Uani 1 1 d .
C21 C 0.1601(4) 0.5556(4) 0.6958(3) 0.0214(8) Uani 1 1 d .
H21 H 0.0842 0.5242 0.6286 0.026 Uiso 1 1 calc R
C22 C -0.0092(4) 0.5599(4) 0.7934(3) 0.0217(8) Uani 1 1 d .
C23 C 0.5216(4) 0.6537(4) 1.0770(3) 0.0242(9) Uani 1 1 d .
C24 C 0.6679(4) 0.7094(4) 1.1665(4) 0.0258(9) Uani 1 1 d .
C25 C 0.7892(5) 0.7296(6) 1.1439(4) 0.0417(12) Uani 1 1 d .
H25 H 0.7833 0.7180 1.0726 0.050 Uiso 1 1 calc R
C26 C 0.9173(5) 0.7664(7) 1.2265(5) 0.0492(15) Uani 1 1 d .
H26 H 0.9973 0.7777 1.2092 0.059 Uiso 1 1 calc R
C27 C 0.8158(6) 0.7714(6) 1.3529(4) 0.0448(13) Uani 1 1 d .
H27 H 0.8246 0.7877 1.4255 0.054 Uiso 1 1 calc R
C28 C 0.6832(5) 0.7328(6) 1.2740(4) 0.0385(12) Uani 1 1 d .
H28 H 0.6046 0.7226 1.2930 0.046 Uiso 1 1 calc R
N1 N 0.1599(5) -0.1621(5) -0.3690(3) 0.0388(10) Uani 1 1 d .
N2 N 0.1881(4) -0.0988(4) 0.0223(3) 0.0267(8) Uani 1 1 d .
H2 H 0.1179 -0.1710 -0.0220 0.032 Uiso 1 1 calc R
N3 N 0.9337(4) 0.7871(5) 1.3313(3) 0.0398(10) Uani 1 1 d .
N4 N 0.5073(4) 0.6997(4) 0.9968(3) 0.0250(8) Uani 1 1 d .
H4 H 0.5767 0.7663 1.0070 0.030 Uiso 1 1 calc R
O1 O 0.4005(3) 0.2808(3) 0.4983(2) 0.0259(6) Uani 1 1 d .
O2 O 0.2648(3) 0.3135(3) 0.3568(2) 0.0233(6) Uani 1 1 d .
O3 O 0.3328(3) -0.2132(3) 0.4333(2) 0.0235(6) Uani 1 1 d .
O4 O 0.3826(3) -0.3025(3) 0.2887(2) 0.0263(6) Uani 1 1 d .
O5 O 0.3462(5) 0.0862(4) 0.0377(3) 0.0645(14) Uani 1 1 d .
O6 O 0.4458(3) 0.5611(3) 0.5960(2) 0.0215(6) Uani 1 1 d .
O7 O 0.2331(3) 0.5626(4) 0.5131(2) 0.0311(7) Uani 1 1 d .
O8 O -0.0173(3) 0.6322(3) 0.8800(3) 0.0333(7) Uani 1 1 d .
O9 O -0.1127(3) 0.4794(3) 0.7065(2) 0.0265(6) Uani 1 1 d .
O10 O 0.4250(3) 0.5708(3) 1.0797(3) 0.0328(7) Uani 1 1 d .
O1W O 0.7012(3) 0.5811(3) 0.8191(2) 0.0242(6) Uani 1 1 d U
H1WB H 0.7854 0.6344 0.8432 0.029 Uiso 1 1 d R
H1WA H 0.7061 0.5232 0.8472 0.029 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pr Pr -0.2180 2.8214 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N3 Ag1 N1 121.60(16) . 1_667
N3 Ag1 O3 124.05(13) . 1_666
N1 Ag1 O3 106.71(13) 1_667 1_666
O2 Pr1 O1 133.19(10) 2_666 .
O2 Pr1 O4 142.14(10) 2_666 2_656
O1 Pr1 O4 76.10(10) . 2_656
O2 Pr1 O9 83.47(10) 2_666 1_655
O1 Pr1 O9 141.80(10) . 1_655
O4 Pr1 O9 77.60(10) 2_656 1_655
O2 Pr1 O7 78.32(11) 2_666 2_666
O1 Pr1 O7 104.94(11) . 2_666
O4 Pr1 O7 122.15(10) 2_656 2_666
O9 Pr1 O7 67.42(10) 1_655 2_666
O2 Pr1 O6 69.52(9) 2_666 .
O1 Pr1 O6 69.65(10) . .
O4 Pr1 O6 112.94(9) 2_656 .
O9 Pr1 O6 147.41(10) 1_655 .
O7 Pr1 O6 121.53(9) 2_666 .
O2 Pr1 O1W 75.81(10) 2_666 .
O1 Pr1 O1W 119.50(10) . .
O4 Pr1 O1W 67.56(10) 2_656 .
O9 Pr1 O1W 73.74(9) 1_655 .
O7 Pr1 O1W 135.17(10) 2_666 .
O6 Pr1 O1W 81.98(9) . .
O2 Pr1 O3 147.45(9) 2_666 2_656
O1 Pr1 O3 71.93(10) . 2_656
O4 Pr1 O3 50.46(9) 2_656 2_656
O9 Pr1 O3 70.00(10) 1_655 2_656
O7 Pr1 O3 74.34(10) 2_666 2_656
O6 Pr1 O3 141.11(9) . 2_656
O1W Pr1 O3 112.54(9) . 2_656
O2 Pr1 O6 78.84(9) 2_666 2_666
O1 Pr1 O6 69.89(9) . 2_666
O4 Pr1 O6 139.02(9) 2_656 2_666
O9 Pr1 O6 117.34(9) 1_655 2_666
O7 Pr1 O6 50.27(9) 2_666 2_666
O6 Pr1 O6 75.91(9) . 2_666
O1W Pr1 O6 150.90(9) . 2_666
O3 Pr1 O6 96.52(8) 2_656 2_666
O2 Pr1 C8 151.71(10) 2_666 2_656
O1 Pr1 C8 75.05(10) . 2_656
O4 Pr1 C8 25.24(10) 2_656 2_656
O9 Pr1 C8 69.37(11) 1_655 2_656
O7 Pr1 C8 97.59(11) 2_666 2_656
O6 Pr1 C8 132.33(10) . 2_656
O1W Pr1 C8 88.72(10) . 2_656
O3 Pr1 C8 25.50(10) 2_656 2_656
O6 Pr1 C8 120.19(10) 2_666 2_656
O2 Pr1 C15 77.69(10) 2_666 2_666
O1 Pr1 C15 87.29(11) . 2_666
O4 Pr1 C15 134.86(10) 2_656 2_666
O9 Pr1 C15 92.07(11) 1_655 2_666
O7 Pr1 C15 24.78(11) 2_666 2_666
O6 Pr1 C15 99.34(10) . 2_666
O1W Pr1 C15 151.11(10) . 2_666
O3 Pr1 C15 84.59(9) 2_656 2_666
O6 Pr1 C15 25.50(10) 2_666 2_666
C8 Pr1 C15 110.07(11) 2_656 2_666
O2 Pr1 Pr1 70.01(7) 2_666 2_666
O1 Pr1 Pr1 64.00(7) . 2_666
O4 Pr1 Pr1 137.04(7) 2_656 2_666
O9 Pr1 Pr1 144.97(7) 1_655 2_666
O7 Pr1 Pr1 84.66(7) 2_666 2_666
O6 Pr1 Pr1 39.13(6) . 2_666
O1W Pr1 Pr1 118.85(6) . 2_666
O3 Pr1 Pr1 123.66(6) 2_656 2_666
O6 Pr1 Pr1 36.77(6) 2_666 2_666
C8 Pr1 Pr1 137.98(8) 2_656 2_666
C15 Pr1 Pr1 60.84(8) 2_666 2_666
O1 C1 O2 125.7(4) . .
O1 C1 C2 117.2(3) . .
O2 C1 C2 117.1(4) . .
C3 C2 C7 120.5(4) . .
C3 C2 C1 120.1(4) . .
C7 C2 C1 119.3(4) . .
C2 C3 C4 119.8(4) . .
C2 C3 H3 120.1 . .
C4 C3 H3 120.1 . .
C5 C4 C3 119.6(4) . .
C5 C4 N2 119.4(4) . .
C3 C4 N2 121.0(4) . .
C4 C5 C6 120.1(4) . .
C4 C5 H5 119.9 . .
C6 C5 H5 119.9 . .
C7 C6 C5 120.8(4) . .
C7 C6 C8 120.5(4) . .
C5 C6 C8 118.7(4) . .
C6 C7 C2 119.2(4) . .
C6 C7 H7 120.4 . .
C2 C7 H7 120.4 . .
O4 C8 O3 122.0(4) . .
O4 C8 C6 117.0(4) . .
O3 C8 C6 121.0(4) . .
O4 C8 Pr1 57.1(2) . 2_656
O3 C8 Pr1 66.0(2) . 2_656
C6 C8 Pr1 167.5(3) . 2_656
O5 C9 N2 122.6(4) . .
O5 C9 C10 119.5(4) . .
N2 C9 C10 117.9(4) . .
C11 C10 C14 118.2(4) . .
C11 C10 C9 124.4(4) . .
C14 C10 C9 117.4(4) . .
C12 C11 C10 119.3(5) . .
C12 C11 H11 120.4 . .
C10 C11 H11 120.4 . .
N1 C12 C11 123.5(5) . .
N1 C12 H12 118.2 . .
C11 C12 H12 118.2 . .
N1 C13 C14 122.9(5) . .
N1 C13 H13 118.6 . .
C14 C13 H13 118.6 . .
C13 C14 C10 119.5(5) . .
C13 C14 H14 120.2 . .
C10 C14 H14 120.2 . .
O7 C15 O6 121.0(4) . .
O7 C15 C16 119.3(4) . .
O6 C15 C16 119.7(4) . .
O7 C15 Pr1 56.0(2) . 2_666
O6 C15 Pr1 65.0(2) . 2_666
C16 C15 Pr1 174.8(3) . 2_666
C17 C16 C21 120.4(4) . .
C17 C16 C15 118.8(4) . .
C21 C16 C15 120.8(4) . .
C18 C17 C16 119.6(4) . .
C18 C17 H17 120.2 . .
C16 C17 H17 120.2 . .
C19 C18 C17 120.4(4) . .
C19 C18 N4 121.9(4) . .
C17 C18 N4 117.6(4) . .
C18 C19 C20 120.0(4) . .
C18 C19 H19 120.0 . .
C20 C19 H19 120.0 . .
C21 C20 C19 120.0(4) . .
C21 C20 C22 120.7(4) . .
C19 C20 C22 119.0(4) . .
C20 C21 C16 119.5(4) . .
C20 C21 H21 120.2 . .
C16 C21 H21 120.2 . .
O8 C22 O9 125.2(4) . .
O8 C22 C20 117.2(4) . .
O9 C22 C20 117.5(4) . .
O10 C23 N4 123.9(4) . .
O10 C23 C24 120.7(4) . .
N4 C23 C24 115.3(4) . .
C28 C24 C25 117.7(4) . .
C28 C24 C23 119.6(4) . .
C25 C24 C23 122.6(4) . .
C26 C25 C24 119.8(5) . .
C26 C25 H25 120.1 . .
C24 C25 H25 120.1 . .
N3 C26 C25 123.2(5) . .
N3 C26 H26 118.4 . .
C25 C26 H26 118.4 . .
N3 C27 C28 123.6(5) . .
N3 C27 H27 118.2 . .
C28 C27 H27 118.2 . .
C27 C28 C24 119.2(4) . .
C27 C28 H28 120.4 . .
C24 C28 H28 120.4 . .
C12 N1 C13 116.6(4) . .
C12 N1 Ag1 122.3(4) . 1_443
C13 N1 Ag1 121.1(3) . 1_443
C9 N2 C4 121.1(4) . .
C9 N2 H2 119.4 . .
C4 N2 H2 119.4 . .
C26 N3 C27 116.4(4) . .
C26 N3 Ag1 123.2(4) . .
C27 N3 Ag1 116.1(3) . .
C23 N4 C18 125.8(4) . .
C23 N4 H4 117.1 . .
C18 N4 H4 117.1 . .
C1 O1 Pr1 131.4(3) . .
C1 O2 Pr1 129.1(2) . 2_666
C8 O3 Ag1 119.2(3) . 1_444
C8 O3 Pr1 88.5(2) . 2_656
Ag1 O3 Pr1 107.99(11) 1_444 2_656
C8 O4 Pr1 97.7(2) . 2_656
C15 O6 Pr1 152.8(3) . .
C15 O6 Pr1 89.5(2) . 2_666
Pr1 O6 Pr1 104.09(9) . 2_666
C15 O7 Pr1 99.3(2) . 2_666
C22 O9 Pr1 137.6(3) . 1_455
Pr1 O1W H1WB 105.1 . .
Pr1 O1W H1WA 105.1 . .
H1WB O1W H1WA 106.0 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N3 2.232(4) .
Ag1 N1 2.239(4) 1_667
Ag1 O3 2.315(3) 1_666
Pr1 O2 2.426(3) 2_666
Pr1 O1 2.468(3) .
Pr1 O4 2.473(3) 2_656
Pr1 O9 2.481(3) 1_655
Pr1 O7 2.482(3) 2_666
Pr1 O6 2.542(3) .
Pr1 O1W 2.559(3) .
Pr1 O3 2.669(3) 2_656
Pr1 O6 2.680(3) 2_666
Pr1 C8 2.920(4) 2_656
Pr1 C15 2.956(4) 2_666
C1 O1 1.255(5) .
C1 O2 1.258(5) .
C1 C2 1.508(5) .
C2 C3 1.389(6) .
C2 C7 1.396(6) .
C3 C4 1.397(6) .
C3 H3 0.9300 .
C4 C5 1.388(6) .
C4 N2 1.424(5) .
C5 C6 1.389(6) .
C5 H5 0.9300 .
C6 C7 1.382(6) .
C6 C8 1.504(5) .
C7 H7 0.9300 .
C8 O4 1.256(5) .
C8 O3 1.258(5) .
C8 Pr1 2.920(4) 2_656
C9 O5 1.212(6) .
C9 N2 1.353(6) .
C9 C10 1.505(6) .
C10 C11 1.379(7) .
C10 C14 1.386(7) .
C11 C12 1.368(7) .
C11 H11 0.9300 .
C12 N1 1.348(7) .
C12 H12 0.9300 .
C13 N1 1.356(7) .
C13 C14 1.367(7) .
C13 H13 0.9300 .
C14 H14 0.9300 .
C15 O7 1.256(5) .
C15 O6 1.273(5) .
C15 C16 1.491(5) .
C15 Pr1 2.956(4) 2_666
C16 C17 1.386(6) .
C16 C21 1.397(6) .
C17 C18 1.384(6) .
C17 H17 0.9300 .
C18 C19 1.385(6) .
C18 N4 1.418(5) .
C19 C20 1.393(6) .
C19 H19 0.9300 .
C20 C21 1.385(6) .
C20 C22 1.511(5) .
C21 H21 0.9300 .
C22 O8 1.255(5) .
C22 O9 1.256(5) .
C23 O10 1.230(5) .
C23 N4 1.335(6) .
C23 C24 1.508(6) .
C24 C28 1.373(6) .
C24 C25 1.384(7) .
C25 C26 1.361(7) .
C25 H25 0.9300 .
C26 N3 1.339(7) .
C26 H26 0.9300 .
C27 N3 1.341(7) .
C27 C28 1.369(7) .
C27 H27 0.9300 .
C28 H28 0.9300 .
N1 Ag1 2.239(4) 1_443
N2 H2 0.8600 .
N4 H4 0.8600 .
O2 Pr1 2.426(3) 2_666
O3 Ag1 2.315(3) 1_444
O3 Pr1 2.669(3) 2_656
O4 Pr1 2.473(3) 2_656
O6 Pr1 2.680(3) 2_666
O7 Pr1 2.482(3) 2_666
O9 Pr1 2.481(3) 1_455
O1W H1WB 0.8500 .
O1W H1WA 0.8501 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 C1 C2 C3 -160.6(4) . .
O2 C1 C2 C3 19.5(6) . .
O1 C1 C2 C7 16.3(5) . .
O2 C1 C2 C7 -163.6(4) . .
C7 C2 C3 C4 -2.0(6) . .
C1 C2 C3 C4 174.9(4) . .
C2 C3 C4 C5 0.5(6) . .
C2 C3 C4 N2 -177.2(4) . .
C3 C4 C5 C6 1.3(6) . .
N2 C4 C5 C6 179.0(4) . .
C4 C5 C6 C7 -1.6(6) . .
C4 C5 C6 C8 -179.4(4) . .
C5 C6 C7 C2 0.0(6) . .
C8 C6 C7 C2 177.9(4) . .
C3 C2 C7 C6 1.7(6) . .
C1 C2 C7 C6 -175.2(4) . .
C7 C6 C8 O4 -151.7(4) . .
C5 C6 C8 O4 26.2(6) . .
C7 C6 C8 O3 28.4(6) . .
C5 C6 C8 O3 -153.7(4) . .
C7 C6 C8 Pr1 149.7(11) . 2_656
C5 C6 C8 Pr1 -32.4(15) . 2_656
O5 C9 C10 C11 -137.5(6) . .
N2 C9 C10 C11 42.8(7) . .
O5 C9 C10 C14 40.0(7) . .
N2 C9 C10 C14 -139.7(5) . .
C14 C10 C11 C12 -0.9(7) . .
C9 C10 C11 C12 176.6(5) . .
C10 C11 C12 N1 0.6(9) . .
N1 C13 C14 C10 0.7(8) . .
C11 C10 C14 C13 0.3(8) . .
C9 C10 C14 C13 -177.4(5) . .
O7 C15 C16 C17 -159.6(4) . .
O6 C15 C16 C17 19.4(6) . .
Pr1 C15 C16 C17 -135(3) 2_666 .
O7 C15 C16 C21 18.6(6) . .
O6 C15 C16 C21 -162.5(4) . .
Pr1 C15 C16 C21 43(3) 2_666 .
C21 C16 C17 C18 1.5(6) . .
C15 C16 C17 C18 179.7(4) . .
C16 C17 C18 C19 -1.1(6) . .
C16 C17 C18 N4 -178.9(4) . .
C17 C18 C19 C20 -0.2(6) . .
N4 C18 C19 C20 177.4(4) . .
C18 C19 C20 C21 1.2(6) . .
C18 C19 C20 C22 -172.6(4) . .
C19 C20 C21 C16 -0.8(6) . .
C22 C20 C21 C16 172.9(4) . .
C17 C16 C21 C20 -0.5(6) . .
C15 C16 C21 C20 -178.7(4) . .
C21 C20 C22 O8 -148.1(4) . .
C19 C20 C22 O8 25.7(6) . .
C21 C20 C22 O9 30.1(6) . .
C19 C20 C22 O9 -156.2(4) . .
O10 C23 C24 C28 -36.5(6) . .
N4 C23 C24 C28 144.2(5) . .
O10 C23 C24 C25 138.8(5) . .
N4 C23 C24 C25 -40.4(6) . .
C28 C24 C25 C26 2.5(8) . .
C23 C24 C25 C26 -173.0(5) . .
C24 C25 C26 N3 -1.2(10) . .
N3 C27 C28 C24 -0.6(9) . .
C25 C24 C28 C27 -1.6(8) . .
C23 C24 C28 C27 174.0(5) . .
C11 C12 N1 C13 0.3(8) . .
C11 C12 N1 Ag1 178.5(4) . 1_443
C14 C13 N1 C12 -1.0(8) . .
C14 C13 N1 Ag1 -179.2(4) . 1_443
O5 C9 N2 C4 -7.3(8) . .
C10 C9 N2 C4 172.3(4) . .
C5 C4 N2 C9 -125.4(5) . .
C3 C4 N2 C9 52.3(6) . .
C25 C26 N3 C27 -0.9(10) . .
C25 C26 N3 Ag1 154.9(5) . .
C28 C27 N3 C26 1.8(9) . .
C28 C27 N3 Ag1 -155.8(5) . .
N1 Ag1 N3 C26 168.8(5) 1_667 .
O3 Ag1 N3 C26 23.4(5) 1_666 .
N1 Ag1 N3 C27 -35.2(5) 1_667 .
O3 Ag1 N3 C27 179.3(4) 1_666 .
O10 C23 N4 C18 -9.4(7) . .
C24 C23 N4 C18 169.8(4) . .
C19 C18 N4 C23 46.1(6) . .
C17 C18 N4 C23 -136.2(4) . .
O2 C1 O1 Pr1 -65.5(5) . .
C2 C1 O1 Pr1 114.6(3) . .
O2 Pr1 O1 C1 49.5(4) 2_666 .
O4 Pr1 O1 C1 -158.4(4) 2_656 .
O9 Pr1 O1 C1 -110.7(3) 1_655 .
O7 Pr1 O1 C1 -38.3(4) 2_666 .
O6 Pr1 O1 C1 80.2(3) . .
O1W Pr1 O1 C1 147.9(3) . .
O3 Pr1 O1 C1 -106.0(3) 2_656 .
O6 Pr1 O1 C1 -1.7(3) 2_666 .
C8 Pr1 O1 C1 -132.4(4) 2_656 .
C15 Pr1 O1 C1 -20.8(3) 2_666 .
Pr1 Pr1 O1 C1 37.9(3) 2_666 .
O1 C1 O2 Pr1 42.3(5) . 2_666
C2 C1 O2 Pr1 -137.8(3) . 2_666
O4 C8 O3 Ag1 -121.4(4) . 1_444
C6 C8 O3 Ag1 58.5(4) . 1_444
Pr1 C8 O3 Ag1 -109.8(2) 2_656 1_444
O4 C8 O3 Pr1 -11.6(4) . 2_656
C6 C8 O3 Pr1 168.3(3) . 2_656
O3 C8 O4 Pr1 12.6(4) . 2_656
C6 C8 O4 Pr1 -167.3(3) . 2_656
O7 C15 O6 Pr1 -119.7(5) . .
C16 C15 O6 Pr1 61.4(7) . .
Pr1 C15 O6 Pr1 -121.0(5) 2_666 .
O7 C15 O6 Pr1 1.4(4) . 2_666
C16 C15 O6 Pr1 -177.6(3) . 2_666
O2 Pr1 O6 C15 -158.9(6) 2_666 .
O1 Pr1 O6 C15 44.5(6) . .
O4 Pr1 O6 C15 -19.7(6) 2_656 .
O9 Pr1 O6 C15 -122.9(5) 1_655 .
O7 Pr1 O6 C15 140.0(5) 2_666 .
O1W Pr1 O6 C15 -81.1(6) . .
O3 Pr1 O6 C15 35.1(6) 2_656 .
O6 Pr1 O6 C15 118.0(6) 2_666 .
C8 Pr1 O6 C15 -0.3(6) 2_656 .
C15 Pr1 O6 C15 128.1(5) 2_666 .
Pr1 Pr1 O6 C15 118.0(6) 2_666 .
O2 Pr1 O6 Pr1 83.15(11) 2_666 2_666
O1 Pr1 O6 Pr1 -73.44(11) . 2_666
O4 Pr1 O6 Pr1 -137.64(10) 2_656 2_666
O9 Pr1 O6 Pr1 119.11(16) 1_655 2_666
O7 Pr1 O6 Pr1 22.01(15) 2_666 2_666
O1W Pr1 O6 Pr1 160.93(11) . 2_666
O3 Pr1 O6 Pr1 -82.83(15) 2_656 2_666
O6 Pr1 O6 Pr1 0.0 2_666 2_666
C8 Pr1 O6 Pr1 -118.21(13) 2_656 2_666
C15 Pr1 O6 Pr1 10.13(12) 2_666 2_666
O6 C15 O7 Pr1 -1.5(4) . 2_666
C16 C15 O7 Pr1 177.4(3) . 2_666
O8 C22 O9 Pr1 26.0(7) . 1_455
C20 C22 O9 Pr1 -151.9(3) . 1_455
