#------------------------------------------------------------------------------
#$Date: 2019-11-28 18:27:04 +0200 (Thu, 28 Nov 2019) $
#$Revision: 244277 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/86/7238665.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7238665
loop_
_publ_author_name
'Kumar Bisht, Kamal'
'Cherian Kathalikkattil, Amal'
'Suresh, Eringathodi'
_publ_section_title
;
 Structure modulation, argentophilic interactions and photoluminescence
 properties of silver(i) coordination polymers with isomeric N-donor
 ligands
;
_journal_issue                   22
_journal_name_full               'RSC Advances'
_journal_page_first              8421
_journal_paper_doi               10.1039/c2ra20642k
_journal_volume                  2
_journal_year                    2012
_chemical_formula_sum            'C44 H35 Ag2 F6 N5 O14 S2'
_chemical_formula_weight         1251.63
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                85.752(2)
_cell_angle_beta                 73.7830(10)
_cell_angle_gamma                72.581(3)
_cell_formula_units_Z            2
_cell_length_a                   11.2497(7)
_cell_length_b                   14.6138(8)
_cell_length_c                   15.2418(9)
_cell_measurement_reflns_used    7143
_cell_measurement_temperature    110(2)
_cell_measurement_theta_max      28.27
_cell_measurement_theta_min      2.78
_cell_volume                     2295.6(2)
_computing_cell_refinement       'BRUKER SMART'
_computing_data_collection       'BRUKER SMART'
_computing_data_reduction        'BRUKER SAINT'
_computing_molecular_graphics    ORTEP
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      110(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.931
_diffrn_measurement_device_type  'BRUKER SMART APEX CCD DIFFRACTOMETER'
_diffrn_measurement_method       'OMEGA-PHI SCAN'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0181
_diffrn_reflns_av_sigmaI/netI    0.0266
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            19515
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         27.99
_diffrn_reflns_theta_min         2.01
_exptl_absorpt_coefficient_mu    1.043
_exptl_absorpt_correction_T_max  0.9212
_exptl_absorpt_correction_T_min  0.7588
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'BRUKER SADABS'
_exptl_crystal_density_diffrn    1.811
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plates
_exptl_crystal_F_000             1252
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.08
_refine_diff_density_max         2.734
_refine_diff_density_min         -1.098
_refine_diff_density_rms         0.104
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     654
_refine_ls_number_reflns         10313
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.032
_refine_ls_R_factor_all          0.0418
_refine_ls_R_factor_gt           0.0396
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0568P)²+4.8102P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1077
_refine_ls_wR_factor_ref         0.1094
_reflns_number_gt                9634
_reflns_number_total             10313
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2ra20642k.txt
_cod_data_source_block           complex1_77cffm
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'MULTI-SCAN' was
changed to 'multi-scan' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/RSC/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/RSC/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7238665
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.01213(2) 0.333674(17) 0.075466(14) 0.02665(7) Uani 1 d .
Ag2 Ag 0.00810(2) 0.115844(16) 0.021180(13) 0.02664(7) Uani 1 d .
S1 S 0.69556(7) 0.31783(5) 0.20007(5) 0.02603(15) Uani 1 d .
S2 S 0.32640(7) 0.17368(5) -0.09313(5) 0.02323(14) Uani 1 d .
F1 F 0.5249(3) 0.3194(4) 0.1158(2) 0.1098(16) Uani 1 d .
F2 F 0.44908(19) 0.41083(17) 0.23116(18) 0.0524(6) Uani 1 d .
F3 F 0.5683(3) 0.4536(4) 0.1135(4) 0.154(3) Uani 1 d .
F4 F 0.49984(19) 0.25420(17) -0.18831(13) 0.0421(5) Uani 1 d .
F5 F 0.4488(2) 0.27871(18) -0.04264(14) 0.0469(6) Uani 1 d .
F6 F 0.3170(2) 0.35446(15) -0.12017(16) 0.0456(5) Uani 1 d .
O1 O -0.16269(17) 0.37856(14) 0.45878(12) 0.0192(4) Uani 1 d .
O2 O -0.20434(19) 0.42081(18) 0.60550(13) 0.0298(5) Uani 1 d .
O3 O -0.7973(2) 0.35718(18) 0.53877(14) 0.0294(5) Uani 1 d .
O4 O -0.83470(17) 0.40580(14) 0.68274(12) 0.0189(4) Uani 1 d .
O5 O 0.16790(17) 0.14079(14) -0.36753(12) 0.0184(4) Uani 1 d .
O6 O 0.20363(19) 0.11051(16) -0.51667(13) 0.0254(4) Uani 1 d .
O7 O 0.80279(18) 0.15245(16) -0.44158(13) 0.0247(4) Uani 1 d .
O8 O 0.84253(17) 0.10956(14) -0.58789(12) 0.0186(4) Uani 1 d .
O9 O 0.7919(2) 0.27834(19) 0.11809(15) 0.0356(5) Uani 1 d .
O10 O 0.7209(3) 0.3935(3) 0.2385(3) 0.0920(16) Uani 1 d .
O11 O 0.6533(4) 0.2515(3) 0.2621(3) 0.0949(16) Uani 1 d .
O12 O 0.2824(2) 0.1759(2) -0.17343(15) 0.0376(5) Uani 1 d .
O13 O 0.4287(3) 0.09037(19) -0.0843(2) 0.0468(6) Uani 1 d .
O14 O 0.2232(2) 0.20476(16) -0.01064(14) 0.0294(5) Uani 1 d .
N1 N 0.0788(2) 0.31028(17) 0.19802(15) 0.0202(4) Uani 1 d .
N2 N -1.0504(2) 0.40180(17) 0.95818(16) 0.0213(5) Uani 1 d .
N3 N -0.0617(2) 0.16840(17) -0.09874(15) 0.0207(4) Uani 1 d .
N4 N 1.0782(2) 0.07802(17) -0.85676(16) 0.0209(4) Uani 1 d .
N5 N 0.1879(3) -0.0346(2) -0.0793(2) 0.0331(6) Uani 1 d .
C1 C 0.2056(3) 0.2686(2) 0.18887(18) 0.0221(5) Uani 1 d .
H1 H 0.2583 0.2427 0.1324 0.027 Uiso 1 calc R
C2 C 0.2603(3) 0.2629(2) 0.26016(19) 0.0243(6) Uani 1 d .
H2 H 0.3486 0.2343 0.2514 0.029 Uiso 1 calc R
C3 C 0.1829(3) 0.3001(2) 0.34487(18) 0.0213(5) Uani 1 d .
H3 H 0.2182 0.2968 0.3938 0.026 Uiso 1 calc R
C4 C 0.0511(2) 0.34271(18) 0.35556(17) 0.0178(5) Uani 1 d .
C5 C 0.0028(3) 0.34679(19) 0.28040(18) 0.0192(5) Uani 1 d .
H5 H -0.0850 0.3757 0.2871 0.023 Uiso 1 calc R
C6 C -0.0326(2) 0.3835(2) 0.44747(18) 0.0204(5) Uani 1 d .
H6A H 0.0023 0.3474 0.4952 0.024 Uiso 1 calc R
H6B H -0.0339 0.4497 0.4521 0.024 Uiso 1 calc R
C7 C -0.2407(2) 0.40010(19) 0.54433(17) 0.0187(5) Uani 1 d .
C8 C -0.3738(2) 0.39402(18) 0.55476(17) 0.0169(5) Uani 1 d .
C9 C -0.4598(3) 0.4124(2) 0.64173(18) 0.0206(5) Uani 1 d .
H9 H -0.4323 0.4264 0.6900 0.025 Uiso 1 calc R
C10 C -0.5856(3) 0.40982(19) 0.65633(18) 0.0199(5) Uani 1 d .
H10 H -0.6431 0.4221 0.7143 0.024 Uiso 1 calc R
C11 C -0.6259(2) 0.38868(18) 0.58372(17) 0.0167(5) Uani 1 d .
C12 C -0.5399(2) 0.37010(18) 0.49637(17) 0.0180(5) Uani 1 d .
H12 H -0.5673 0.3559 0.4482 0.022 Uiso 1 calc R
C13 C -0.4134(2) 0.37302(18) 0.48184(17) 0.0175(5) Uani 1 d .
H13 H -0.3558 0.3610 0.4239 0.021 Uiso 1 calc R
C14 C -0.7596(2) 0.38202(18) 0.59727(17) 0.0175(5) Uani 1 d .
C15 C -0.9608(2) 0.3894(2) 0.70094(18) 0.0208(5) Uani 1 d .
H15A H -0.9502 0.3221 0.6919 0.025 Uiso 1 calc R
H15B H -1.0079 0.4267 0.6594 0.025 Uiso 1 calc R
C16 C -1.0342(2) 0.41892(19) 0.79777(18) 0.0176(5) Uani 1 d .
C17 C -1.1572(3) 0.4847(2) 0.8171(2) 0.0238(5) Uani 1 d .
H17 H -1.1939 0.5120 0.7702 0.029 Uiso 1 calc R
C18 C -1.2240(3) 0.5087(2) 0.9075(2) 0.0282(6) Uani 1 d .
H18 H -1.3060 0.5527 0.9221 0.034 Uiso 1 calc R
C19 C -1.1677(3) 0.4667(2) 0.9755(2) 0.0250(6) Uani 1 d .
H19 H -1.2127 0.4839 1.0359 0.030 Uiso 1 calc R
C20 C -0.9856(3) 0.3787(2) 0.87051(18) 0.0200(5) Uani 1 d .
H20 H -0.9043 0.3337 0.8581 0.024 Uiso 1 calc R
C21 C -0.1832(3) 0.2274(2) -0.08520(19) 0.0235(5) Uani 1 d .
H21 H -0.2317 0.2463 -0.0258 0.028 Uiso 1 calc R
C22 C -0.2384(3) 0.2608(2) -0.1560(2) 0.0252(6) Uani 1 d .
H22 H -0.3220 0.3023 -0.1443 0.030 Uiso 1 calc R
C23 C -0.1679(3) 0.2317(2) -0.24473(19) 0.0214(5) Uani 1 d .
H23 H -0.2041 0.2522 -0.2932 0.026 Uiso 1 calc R
C24 C -0.0418(2) 0.17125(18) -0.26007(17) 0.0170(5) Uani 1 d .
C25 C 0.0072(3) 0.1416(2) -0.18528(18) 0.0196(5) Uani 1 d .
H25 H 0.0914 0.1013 -0.1953 0.023 Uiso 1 calc R
C26 C 0.0358(2) 0.1390(2) -0.35574(18) 0.0193(5) Uani 1 d .
H26A H 0.0351 0.0745 -0.3663 0.023 Uiso 1 calc R
H26B H -0.0015 0.1813 -0.3994 0.023 Uiso 1 calc R
C27 C 0.2424(2) 0.12517(18) -0.45429(17) 0.0176(5) Uani 1 d .
C28 C 0.3772(2) 0.12747(18) -0.46460(17) 0.0166(5) Uani 1 d .
C29 C 0.4610(3) 0.11634(19) -0.55249(17) 0.0192(5) Uani 1 d .
H29 H 0.4317 0.1085 -0.6020 0.023 Uiso 1 calc R
C30 C 0.5882(2) 0.11695(19) -0.56625(17) 0.0189(5) Uani 1 d .
H30 H 0.6442 0.1096 -0.6248 0.023 Uiso 1 calc R
C31 C 0.6309(2) 0.12868(18) -0.49151(17) 0.0164(5) Uani 1 d .
C32 C 0.5471(2) 0.14041(19) -0.40361(18) 0.0189(5) Uani 1 d .
H32 H 0.5762 0.1487 -0.3542 0.023 Uiso 1 calc R
C33 C 0.4198(2) 0.13965(19) -0.38996(17) 0.0184(5) Uani 1 d .
H33 H 0.3636 0.1472 -0.3315 0.022 Uiso 1 calc R
C34 C 0.7657(2) 0.13214(18) -0.50271(17) 0.0170(5) Uani 1 d .
C35 C 0.9728(2) 0.1147(2) -0.60023(17) 0.0189(5) Uani 1 d .
H35A H 1.0110 0.0744 -0.5559 0.023 Uiso 1 calc R
H35B H 0.9706 0.1802 -0.5907 0.023 Uiso 1 calc R
C36 C 1.0531(2) 0.08168(18) -0.69542(17) 0.0171(5) Uani 1 d .
C37 C 1.1834(3) 0.0315(2) -0.70897(19) 0.0211(5) Uani 1 d .
H37 H 1.2188 0.0159 -0.6596 0.025 Uiso 1 calc R
C38 C 1.2598(3) 0.0049(2) -0.7971(2) 0.0239(5) Uani 1 d .
H38 H 1.3468 -0.0293 -0.8077 0.029 Uiso 1 calc R
C39 C 1.2042(3) 0.0301(2) -0.86866(19) 0.0234(5) Uani 1 d .
H39 H 1.2560 0.0133 -0.9278 0.028 Uiso 1 calc R
C40 C 1.0044(3) 0.10304(19) -0.77111(18) 0.0188(5) Uani 1 d .
H40 H 0.9172 0.1360 -0.7623 0.023 Uiso 1 calc R
C41 C 0.5528(3) 0.3809(3) 0.1629(3) 0.0420(8) Uani 1 d .
C42 C 0.4022(3) 0.2699(2) -0.1117(2) 0.0307(6) Uani 1 d .
C43 C 0.4156(6) -0.0777(5) -0.1890(4) 0.0819(16) Uiso 1 d .
H43A H 0.4221 -0.1275 -0.2293 0.123 Uiso 1 calc R
H43B H 0.4848 -0.0981 -0.1601 0.123 Uiso 1 calc R
H43C H 0.4214 -0.0207 -0.2234 0.123 Uiso 1 calc R
C44 C 0.2889(4) -0.0572(3) -0.1178(4) 0.0599(13) Uani 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag1 N1 161.93(9) 1_654 .
N2 Ag1 Ag2 93.58(6) 1_654 .
N1 Ag1 Ag2 104.43(6) . .
N3 Ag2 N4 174.21(9) . 1_456
N3 Ag2 N5 89.83(9) . .
N4 Ag2 N5 94.04(9) 1_456 .
N3 Ag2 Ag1 93.35(6) . .
N4 Ag2 Ag1 80.86(6) 1_456 .
N5 Ag2 Ag1 133.80(6) . .
O11 S1 O10 115.7(3) . .
O11 S1 O9 115.8(2) . .
O10 S1 O9 113.2(2) . .
O11 S1 C41 103.1(2) . .
O10 S1 C41 102.1(2) . .
O9 S1 C41 104.70(16) . .
O13 S2 O12 115.43(17) . .
O13 S2 O14 115.42(15) . .
O12 S2 O14 113.96(14) . .
O13 S2 C42 103.67(16) . .
O12 S2 C42 103.49(15) . .
O14 S2 C42 102.48(14) . .
C7 O1 C6 113.78(19) . .
C14 O4 C15 113.9(2) . .
C27 O5 C26 113.84(19) . .
C34 O8 C35 113.65(19) . .
C1 N1 C5 118.5(2) . .
C1 N1 Ag1 118.01(18) . .
C5 N1 Ag1 122.89(18) . .
C19 N2 C20 118.0(2) . .
C19 N2 Ag1 116.72(18) . 1_456
C20 N2 Ag1 125.03(19) . 1_456
C25 N3 C21 117.9(2) . .
C25 N3 Ag2 123.89(19) . .
C21 N3 Ag2 118.12(18) . .
C40 N4 C39 118.1(2) . .
C40 N4 Ag2 124.02(18) . 1_654
C39 N4 Ag2 117.79(18) . 1_654
C44 N5 Ag2 141.1(3) . .
N1 C1 C2 122.3(2) . .
N1 C1 H1 118.8 . .
C2 C1 H1 118.8 . .
C1 C2 C3 119.5(3) . .
C1 C2 H2 120.2 . .
C3 C2 H2 120.2 . .
C2 C3 C4 118.8(3) . .
C2 C3 H3 120.6 . .
C4 C3 H3 120.6 . .
C5 C4 C3 118.6(2) . .
C5 C4 C6 122.7(2) . .
C3 C4 C6 118.7(2) . .
N1 C5 C4 122.3(2) . .
N1 C5 H5 118.9 . .
C4 C5 H5 118.9 . .
O1 C6 C4 109.3(2) . .
O1 C6 H6A 109.8 . .
C4 C6 H6A 109.8 . .
O1 C6 H6B 109.8 . .
C4 C6 H6B 109.8 . .
H6A C6 H6B 108.3 . .
O2 C7 O1 122.8(2) . .
O2 C7 C8 124.2(2) . .
O1 C7 C8 113.0(2) . .
C13 C8 C9 120.6(2) . .
C13 C8 C7 122.6(2) . .
C9 C8 C7 116.8(2) . .
C10 C9 C8 120.1(2) . .
C10 C9 H9 119.9 . .
C8 C9 H9 119.9 . .
C9 C10 C11 119.6(2) . .
C9 C10 H10 120.2 . .
C11 C10 H10 120.2 . .
C10 C11 C12 120.5(2) . .
C10 C11 C14 121.2(2) . .
C12 C11 C14 118.3(2) . .
C13 C12 C11 119.8(2) . .
C13 C12 H12 120.1 . .
C11 C12 H12 120.1 . .
C12 C13 C8 119.4(2) . .
C12 C13 H13 120.3 . .
C8 C13 H13 120.3 . .
O3 C14 O4 122.9(2) . .
O3 C14 C11 124.3(2) . .
O4 C14 C11 112.7(2) . .
O4 C15 C16 108.3(2) . .
O4 C15 H15A 110.0 . .
C16 C15 H15A 110.0 . .
O4 C15 H15B 110.0 . .
C16 C15 H15B 110.0 . .
H15A C15 H15B 108.4 . .
C20 C16 C17 118.1(2) . .
C20 C16 C15 121.6(2) . .
C17 C16 C15 120.2(2) . .
C18 C17 C16 118.8(3) . .
C18 C17 H17 120.6 . .
C16 C17 H17 120.6 . .
C19 C18 C17 119.2(3) . .
C19 C18 H18 120.4 . .
C17 C18 H18 120.4 . .
N2 C19 C18 122.7(3) . .
N2 C19 H19 118.7 . .
C18 C19 H19 118.7 . .
N2 C20 C16 123.0(2) . .
N2 C20 H20 118.5 . .
C16 C20 H20 118.5 . .
N3 C21 C22 122.6(3) . .
N3 C21 H21 118.7 . .
C22 C21 H21 118.7 . .
C21 C22 C23 119.2(3) . .
C21 C22 H22 120.4 . .
C23 C22 H22 120.4 . .
C22 C23 C24 118.9(3) . .
C22 C23 H23 120.5 . .
C24 C23 H23 120.5 . .
C25 C24 C23 118.3(2) . .
C25 C24 C26 122.1(2) . .
C23 C24 C26 119.6(2) . .
N3 C25 C24 123.0(2) . .
N3 C25 H25 118.5 . .
C24 C25 H25 118.5 . .
O5 C26 C24 108.7(2) . .
O5 C26 H26A 110.0 . .
C24 C26 H26A 110.0 . .
O5 C26 H26B 110.0 . .
C24 C26 H26B 110.0 . .
H26A C26 H26B 108.3 . .
O6 C27 O5 123.3(2) . .
O6 C27 C28 123.9(2) . .
O5 C27 C28 112.8(2) . .
C33 C28 C29 120.5(2) . .
C33 C28 C27 122.0(2) . .
C29 C28 C27 117.5(2) . .
C30 C29 C28 120.1(2) . .
C30 C29 H29 119.9 . .
C28 C29 H29 119.9 . .
C29 C30 C31 119.4(2) . .
C29 C30 H30 120.3 . .
C31 C30 H30 120.3 . .
C30 C31 C32 120.6(2) . .
C30 C31 C34 121.6(2) . .
C32 C31 C34 117.8(2) . .
C33 C32 C31 119.9(2) . .
C33 C32 H32 120.0 . .
C31 C32 H32 120.0 . .
C32 C33 C28 119.5(2) . .
C32 C33 H33 120.3 . .
C28 C33 H33 120.3 . .
O7 C34 O8 123.1(2) . .
O7 C34 C31 123.8(2) . .
O8 C34 C31 113.1(2) . .
O8 C35 C36 109.5(2) . .
O8 C35 H35A 109.8 . .
C36 C35 H35A 109.8 . .
O8 C35 H35B 109.8 . .
C36 C35 H35B 109.8 . .
H35A C35 H35B 108.2 . .
C40 C36 C37 118.4(2) . .
C40 C36 C35 122.7(2) . .
C37 C36 C35 118.8(2) . .
C38 C37 C36 119.2(3) . .
C38 C37 H37 120.4 . .
C36 C37 H37 120.4 . .
C39 C38 C37 118.7(3) . .
C39 C38 H38 120.6 . .
C37 C38 H38 120.6 . .
N4 C39 C38 122.9(3) . .
N4 C39 H39 118.6 . .
C38 C39 H39 118.6 . .
N4 C40 C36 122.6(2) . .
N4 C40 H40 118.7 . .
C36 C40 H40 118.7 . .
F3 C41 F2 107.9(4) . .
F3 C41 F1 110.1(5) . .
F2 C41 F1 104.8(3) . .
F3 C41 S1 112.2(3) . .
F2 C41 S1 112.9(3) . .
F1 C41 S1 108.8(3) . .
F5 C42 F4 108.1(3) . .
F5 C42 F6 107.2(3) . .
F4 C42 F6 107.7(3) . .
F5 C42 S2 111.8(2) . .
F4 C42 S2 110.9(2) . .
F6 C42 S2 111.0(2) . .
C44 C43 H43A 109.5 . .
C44 C43 H43B 109.5 . .
H43A C43 H43B 109.5 . .
C44 C43 H43C 109.5 . .
H43A C43 H43C 109.5 . .
H43B C43 H43C 109.5 . .
N5 C44 C43 166.6(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N2 2.168(2) 1_654
Ag1 N1 2.169(2) .
Ag1 Ag2 3.3642(4) .
Ag2 N3 2.186(2) .
Ag2 N4 2.190(2) 1_456
Ag2 N5 2.716(3) .
S1 O11 1.397(3) .
S1 O10 1.423(3) .
S1 O9 1.430(2) .
S1 C41 1.815(4) .
S2 O13 1.431(3) .
S2 O12 1.438(2) .
S2 O14 1.445(2) .
S2 C42 1.818(3) .
F1 C41 1.346(5) .
F2 C41 1.312(4) .
F3 C41 1.282(5) .
F4 C42 1.339(3) .
F5 C42 1.330(4) .
F6 C42 1.341(4) .
O1 C7 1.351(3) .
O1 C6 1.449(3) .
O2 C7 1.207(3) .
O3 C14 1.208(3) .
O4 C14 1.345(3) .
O4 C15 1.456(3) .
O5 C27 1.347(3) .
O5 C26 1.454(3) .
O6 C27 1.207(3) .
O7 C34 1.209(3) .
O8 C34 1.345(3) .
O8 C35 1.449(3) .
N1 C1 1.345(4) .
N1 C5 1.349(3) .
N2 C19 1.343(4) .
N2 C20 1.344(3) .
N2 Ag1 2.168(2) 1_456
N3 C25 1.348(3) .
N3 C21 1.348(4) .
N4 C40 1.346(3) .
N4 C39 1.347(4) .
N4 Ag2 2.190(2) 1_654
N5 C44 1.084(5) .
C1 C2 1.376(4) .
C1 H1 0.9300 .
C2 C3 1.383(4) .
C2 H2 0.9300 .
C3 C4 1.392(4) .
C3 H3 0.9300 .
C4 C5 1.389(4) .
C4 C6 1.502(3) .
C5 H5 0.9300 .
C6 H6A 0.9700 .
C6 H6B 0.9700 .
C7 C8 1.490(3) .
C8 C13 1.392(4) .
C8 C9 1.395(3) .
C9 C10 1.382(4) .
C9 H9 0.9300 .
C10 C11 1.393(4) .
C10 H10 0.9300 .
C11 C12 1.400(3) .
C11 C14 1.491(3) .
C12 C13 1.391(4) .
C12 H12 0.9300 .
C13 H13 0.9300 .
C15 C16 1.499(4) .
C15 H15A 0.9700 .
C15 H15B 0.9700 .
C16 C20 1.387(4) .
C16 C17 1.395(4) .
C17 C18 1.387(4) .
C17 H17 0.9300 .
C18 C19 1.375(4) .
C18 H18 0.9300 .
C19 H19 0.9300 .
C20 H20 0.9300 .
C21 C22 1.379(4) .
C21 H21 0.9300 .
C22 C23 1.387(4) .
C22 H22 0.9300 .
C23 C24 1.393(4) .
C23 H23 0.9300 .
C24 C25 1.388(4) .
C24 C26 1.502(3) .
C25 H25 0.9300 .
C26 H26A 0.9700 .
C26 H26B 0.9700 .
C27 C28 1.491(3) .
C28 C33 1.393(4) .
C28 C29 1.394(3) .
C29 C30 1.389(4) .
C29 H29 0.9300 .
C30 C31 1.394(4) .
C30 H30 0.9300 .
C31 C32 1.395(3) .
C31 C34 1.493(3) .
C32 C33 1.391(4) .
C32 H32 0.9300 .
C33 H33 0.9300 .
C35 C36 1.505(3) .
C35 H35A 0.9700 .
C35 H35B 0.9700 .
C36 C40 1.388(4) .
C36 C37 1.393(4) .
C37 C38 1.388(4) .
C37 H37 0.9300 .
C38 C39 1.379(4) .
C38 H38 0.9300 .
C39 H39 0.9300 .
C40 H40 0.9300 .
C43 C44 1.493(7) .
C43 H43A 0.9600 .
C43 H43B 0.9600 .
C43 H43C 0.9600 .
