#------------------------------------------------------------------------------
#$Date: 2019-11-28 19:00:47 +0200 (Thu, 28 Nov 2019) $
#$Revision: 244368 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/88/7238812.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7238812
loop_
_publ_author_name
'Chorazy, Szymon'
'Nakabayashi, Koji'
'Ozaki, Noriaki'
'Pełka, Robert'
'Fic, Tomasz'
'Mlynarski, Jacek'
'Sieklucka, Barbara'
'Ohkoshi, Shin-ichi'
_publ_section_title
;
 Thermal switching between blue and red luminescence in magnetic chiral
 cyanido-bridged EuIII--WVcoordination helices
;
_journal_issue                   4
_journal_name_full               'RSC Adv.'
_journal_page_first              1065
_journal_paper_doi               10.1039/C2RA23033J
_journal_volume                  3
_journal_year                    2013
_chemical_absolute_configuration rmad
_chemical_formula_sum            'C114 H147 Eu3 N46 O23 W3'
_chemical_formula_weight         3537.21
_space_group_IT_number           4
_space_group_name_Hall           'P 2yb'
_space_group_name_H-M_alt        'P 1 21 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 95.6620(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   13.1255(3)
_cell_length_b                   18.6363(3)
_cell_length_c                   30.2302(6)
_cell_measurement_temperature    90(2)
_cell_volume                     7358.6(3)
_computing_cell_refinement       'RAPID AUTO'
_computing_data_collection       'RAPID AUTO'
_computing_data_reduction        'RAPID AUTO'
_computing_molecular_graphics    'Mercury 2.3'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      90(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0507
_diffrn_reflns_av_sigmaI/netI    0.0768
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       39
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_number            72119
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.08
_exptl_absorpt_coefficient_mu    3.671
_exptl_absorpt_correction_T_max  0.7578
_exptl_absorpt_correction_T_min  0.5272
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR (Rigaku, 1995)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.596
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             3496
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.386
_refine_diff_density_min         -1.543
_refine_diff_density_rms         0.145
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.018(4)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.075
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1802
_refine_ls_number_reflns         33394
_refine_ls_number_restraints     173
_refine_ls_restrained_S_all      1.081
_refine_ls_R_factor_all          0.0452
_refine_ls_R_factor_gt           0.0410
_refine_ls_shift/su_max          0.059
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+20.0086P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0835
_refine_ls_wR_factor_ref         0.0862
_reflns_number_gt                31116
_reflns_number_total             33394
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2ra23033j.txt
_cod_data_source_block           shelxl
_cod_original_sg_symbol_H-M      'P 21'
_cod_database_code               7238812
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
W1 W 0.30857(2) 0.251616(13) 0.631477(9) 0.01148(6) Uani 1 1 d . . .
W2 W 0.06534(2) 0.222130(13) 0.288253(9) 0.01329(6) Uani 1 1 d . . .
W3 W -0.31187(3) 0.300071(15) -0.040372(9) 0.02250(7) Uani 1 1 d . . .
Eu1 Eu 0.65517(3) 0.224051(18) 0.771852(11) 0.01512(7) Uani 1 1 d . A .
Eu2 Eu 0.18405(2) 0.378507(15) 0.455022(10) 0.00920(6) Uani 1 1 d . . .
Eu3 Eu -0.26575(3) 0.198018(17) 0.142394(11) 0.01640(7) Uani 1 1 d . B .
O1L O 0.8922(4) 0.0569(3) 0.83551(18) 0.0305(13) Uani 1 1 d . . .
O2L O 0.8162(4) 0.2794(3) 0.64474(17) 0.0267(12) Uani 1 1 d . . .
O3L O -0.0237(3) 0.5583(2) 0.38545(17) 0.0187(11) Uani 1 1 d . . .
O4L O 0.4457(4) 0.5250(2) 0.52124(18) 0.0211(11) Uani 1 1 d . . .
O5L O -0.4893(5) 0.0187(3) 0.0837(2) 0.0427(16) Uani 1 1 d . . .
O6L O -0.4384(4) 0.2541(3) 0.26808(17) 0.0266(11) Uani 1 1 d . . .
O1D O 0.6231(4) 0.1202(2) 0.72504(17) 0.0200(11) Uani 1 1 d . . .
O3D O 0.5855(4) 0.3410(2) 0.78190(16) 0.0244(12) Uani 1 1 d . . .
O4D O 0.8064(4) 0.2910(3) 0.79567(19) 0.0361(14) Uani 1 1 d . . .
O5D O 0.2674(4) 0.4166(2) 0.39200(16) 0.0180(10) Uani 1 1 d . . .
O6D O 0.2916(3) 0.2800(2) 0.44429(16) 0.0158(10) Uani 1 1 d . . .
O7D O 0.0626(3) 0.2888(2) 0.47523(15) 0.0136(10) Uani 1 1 d U . .
O8D O 0.1030(4) 0.4358(2) 0.51268(16) 0.0171(10) Uani 1 1 d . . .
O9D O -0.4236(4) 0.2617(3) 0.11966(18) 0.0323(13) Uani 1 1 d . . .
O10D O -0.1984(5) 0.3124(3) 0.13572(18) 0.0353(14) Uani 1 1 d . . .
O11D O -0.1152(4) 0.1567(3) 0.11435(19) 0.0305(13) Uani 1 1 d . . .
O1S O 0.5293(10) 0.2729(5) 0.3889(4) 0.133(5) Uani 1 1 d . . .
N1A N 0.2056(5) 0.3277(3) 0.7161(2) 0.0333(16) Uani 1 1 d . . .
N2A N 0.2623(5) 0.1156(3) 0.6970(2) 0.0221(13) Uani 1 1 d . . .
N3A N 0.0585(4) 0.2392(3) 0.6038(2) 0.0239(14) Uani 1 1 d . . .
N4A N 0.2460(4) 0.3217(3) 0.53161(19) 0.0153(12) Uani 1 1 d . . .
N5A N 0.2846(5) 0.1099(3) 0.5644(2) 0.0278(15) Uani 1 1 d . . .
N6A N 0.5263(4) 0.2363(3) 0.58545(19) 0.0182(12) Uani 1 1 d . . .
N7A N 0.4989(4) 0.2455(3) 0.71270(19) 0.0190(12) Uani 1 1 d . . .
N8A N 0.3869(5) 0.4211(3) 0.6344(2) 0.0293(15) Uani 1 1 d . . .
N1B N -0.1130(5) 0.2166(3) 0.2030(2) 0.0224(13) Uani 1 1 d . . .
N2B N 0.1178(5) 0.0796(3) 0.2281(2) 0.0309(16) Uani 1 1 d . . .
N3B N 0.0834(5) 0.0899(3) 0.3624(2) 0.0264(15) Uani 1 1 d . . .
N4B N 0.3129(5) 0.1986(4) 0.3165(2) 0.0341(16) Uani 1 1 d . . .
N5B N -0.1630(5) 0.1991(3) 0.3257(2) 0.0263(14) Uani 1 1 d . . .
N6B N -0.0159(5) 0.3908(3) 0.2772(2) 0.0284(15) Uani 1 1 d . . .
N7B N 0.1104(4) 0.3081(3) 0.3841(2) 0.0185(12) Uani 1 1 d . . .
N8B N 0.1850(5) 0.2921(4) 0.2063(2) 0.0363(17) Uani 1 1 d . . .
N1C N -0.2729(5) 0.2293(3) 0.0604(2) 0.0299(15) Uani 1 1 d . . .
N2C N -0.5547(6) 0.3336(4) -0.0782(3) 0.046(2) Uani 1 1 d . . .
N3C N -0.2812(7) 0.4444(4) -0.1004(3) 0.046(2) Uani 1 1 d . . .
N4C N 0.6619(5) 0.2489(3) 0.8541(2) 0.0286(14) Uani 1 1 d . . .
N5C N -0.0982(7) 0.3775(5) 0.0044(3) 0.064(2) Uani 1 1 d . . .
N6C N -0.3933(7) 0.4188(4) 0.0296(3) 0.057(3) Uani 1 1 d . . .
N7C N -0.4434(7) 0.1488(4) -0.0418(3) 0.054(2) Uani 1 1 d . . .
N8C N -0.1211(7) 0.1870(5) -0.0524(3) 0.065(3) Uani 1 1 d . . .
N1L N 0.7481(5) 0.1211(3) 0.8175(2) 0.0223(13) Uani 1 1 d . . .
N2L N 0.8224(4) 0.1715(3) 0.74307(19) 0.0189(12) Uani 1 1 d . . .
N3L N 0.7134(4) 0.2799(3) 0.70058(19) 0.0193(12) Uani 1 1 d . . .
N4L N 0.0406(4) 0.4528(3) 0.41287(18) 0.0118(11) Uani 1 1 d . . .
N5L N 0.2075(4) 0.5198(3) 0.45328(18) 0.0121(11) Uani 1 1 d . . .
N6L N 0.3551(4) 0.4310(3) 0.49100(18) 0.0115(11) Uani 1 1 d . . .
N7L N -0.3593(5) 0.0968(3) 0.09585(19) 0.0200(13) Uani 1 1 d . . .
N8L N -0.4300(5) 0.1427(3) 0.1729(2) 0.0222(13) Uani 1 1 d . . .
N9L N -0.3264(4) 0.2530(3) 0.21498(19) 0.0213(12) Uani 1 1 d . . .
N1D N 0.5309(4) 0.0608(3) 0.6697(2) 0.0189(13) Uani 1 1 d . . .
N3D N 0.4432(5) 0.4049(3) 0.7914(2) 0.0260(14) Uani 1 1 d . . .
N4D N 0.9255(10) 0.3325(8) 0.8477(4) 0.119(5) Uani 1 1 d . . .
N5D N 0.3061(4) 0.4025(3) 0.32123(19) 0.0169(12) Uani 1 1 d . . .
N6D N 0.3424(4) 0.1651(3) 0.4439(2) 0.0198(13) Uani 1 1 d . . .
N7D N 0.0238(4) 0.1695(3) 0.47279(19) 0.0180(12) Uani 1 1 d . . .
N8D N 0.0712(5) 0.4379(3) 0.5853(2) 0.0200(13) Uani 1 1 d . . .
N9D N -0.5794(7) 0.2823(5) 0.0847(3) 0.065(3) Uani 1 1 d . . .
N10D N -0.1225(6) 0.4167(3) 0.1232(2) 0.0379(19) Uani 1 1 d . . .
N11D N 0.0488(11) 0.1322(7) 0.1020(5) 0.113(4) Uani 1 1 d DU . .
N1S N 0.5955(9) 0.1611(6) 0.3756(4) 0.082(3) Uani 1 1 d . . .
C1A C 0.2410(5) 0.3008(3) 0.6863(2) 0.0176(14) Uani 1 1 d . . .
C2A C 0.2757(5) 0.1616(3) 0.6738(2) 0.0133(13) Uani 1 1 d U . .
C3A C 0.1444(5) 0.2430(3) 0.6150(2) 0.0170(14) Uani 1 1 d . . .
C4A C 0.2705(5) 0.2971(3) 0.5665(2) 0.0131(13) Uani 1 1 d . . .
C5A C 0.2926(5) 0.1583(3) 0.5885(2) 0.0179(14) Uani 1 1 d . . .
C6A C 0.4504(6) 0.2430(3) 0.6019(2) 0.0164(14) Uani 1 1 d . . .
C7A C 0.4338(5) 0.2479(4) 0.6846(2) 0.0157(13) Uani 1 1 d . . .
C8A C 0.3629(5) 0.3612(3) 0.6332(2) 0.0177(14) Uani 1 1 d U . .
C1B C -0.0486(5) 0.2189(4) 0.2317(2) 0.0183(14) Uani 1 1 d . . .
C2B C 0.0991(6) 0.1275(3) 0.2503(2) 0.0190(15) Uani 1 1 d . . .
C3B C 0.0767(6) 0.1354(3) 0.3371(2) 0.0195(15) Uani 1 1 d . . .
C4B C 0.2284(6) 0.2080(4) 0.3067(2) 0.0225(16) Uani 1 1 d . . .
C5B C -0.0844(5) 0.2105(3) 0.3139(2) 0.0156(14) Uani 1 1 d . . .
C6B C 0.0099(6) 0.3316(4) 0.2810(2) 0.0222(16) Uani 1 1 d U . .
C7B C 0.0949(5) 0.2770(3) 0.3517(2) 0.0123(13) Uani 1 1 d . . .
C8B C 0.1438(6) 0.2682(4) 0.2349(2) 0.0226(16) Uani 1 1 d . . .
C1C C -0.2845(6) 0.2532(4) 0.0247(2) 0.0254(16) Uani 1 1 d . . .
C2C C -0.4687(7) 0.3240(4) -0.0649(3) 0.034(2) Uani 1 1 d . . .
C3C C -0.2919(7) 0.3951(4) -0.0791(3) 0.0305(19) Uani 1 1 d . . .
C4C C 0.6724(6) 0.2672(4) 0.8909(3) 0.0249(17) Uani 1 1 d . . .
C5C C -0.1737(7) 0.3509(4) -0.0119(3) 0.0344(19) Uani 1 1 d . . .
C6C C -0.3651(8) 0.3790(4) 0.0043(3) 0.043(2) Uani 1 1 d . . .
C7C C -0.3961(7) 0.2014(4) -0.0405(3) 0.0309(19) Uani 1 1 d . . .
C8C C -0.1882(7) 0.2242(5) -0.0482(3) 0.039(2) Uani 1 1 d . . .
C1L C 0.7287(5) 0.0802(4) 0.8588(2) 0.0193(15) Uani 1 1 d . . .
H1L H 0.7063 0.1143 0.8815 0.023 Uiso 1 1 calc R . .
C2L C 0.8349(6) 0.0513(4) 0.8747(3) 0.0268(17) Uani 1 1 d . . .
H2L1 H 0.8674 0.0806 0.8996 0.032 Uiso 1 1 calc R . .
H2L2 H 0.8311 0.0009 0.8846 0.032 Uiso 1 1 calc R . .
C3L C 0.8352(6) 0.1013(4) 0.8080(3) 0.0223(16) Uani 1 1 d . . .
C4L C 0.8799(6) 0.1240(4) 0.7677(3) 0.0248(16) Uani 1 1 d . . .
C5L C 0.9749(6) 0.1005(4) 0.7554(3) 0.0278(17) Uani 1 1 d . . .
H5L H 1.0148 0.0669 0.7733 0.033 Uiso 1 1 calc R . .
C6L C 1.0097(6) 0.1272(4) 0.7165(3) 0.0334(19) Uani 1 1 d . . .
H6L H 1.0732 0.1117 0.7073 0.040 Uiso 1 1 calc R . .
C7L C 0.9502(6) 0.1767(4) 0.6917(3) 0.0307(18) Uani 1 1 d . . .
H7L H 0.9724 0.1962 0.6652 0.037 Uiso 1 1 calc R . .
C8L C 0.8576(6) 0.1975(4) 0.7061(2) 0.0230(15) Uani 1 1 d . . .
C9L C 0.7919(5) 0.2534(4) 0.6840(2) 0.0216(15) Uani 1 1 d . . .
C10L C 0.7346(6) 0.3293(4) 0.6308(2) 0.0291(18) Uani 1 1 d . . .
H10A H 0.6879 0.3086 0.6064 0.035 Uiso 1 1 calc R . .
H10B H 0.7630 0.3748 0.6203 0.035 Uiso 1 1 calc R . .
C11L C 0.6772(6) 0.3425(3) 0.6723(2) 0.0213(15) Uani 1 1 d . . .
H11L H 0.6015 0.3398 0.6643 0.026 Uiso 1 1 calc R . .
C12L C 0.6459(7) 0.0242(4) 0.8481(3) 0.0320(19) Uani 1 1 d . . .
H12L H 0.5836 0.0494 0.8341 0.038 Uiso 1 1 calc R . .
C13L C 0.6781(7) -0.0328(4) 0.8146(3) 0.036(2) Uani 1 1 d . . .
H13A H 0.6229 -0.0679 0.8086 0.054 Uiso 1 1 calc R . .
H13B H 0.7403 -0.0573 0.8273 0.054 Uiso 1 1 calc R . .
H13C H 0.6914 -0.0091 0.7868 0.054 Uiso 1 1 calc R . .
C14L C 0.6179(8) -0.0113(4) 0.8911(3) 0.041(2) Uani 1 1 d . . .
H4A H 0.5641 -0.0471 0.8839 0.061 Uiso 1 1 calc R . .
H4B H 0.5932 0.0252 0.9107 0.061 Uiso 1 1 calc R . .
H4C H 0.6786 -0.0349 0.9060 0.061 Uiso 1 1 calc R . .
C15L C 0.7058(6) 0.4132(4) 0.6974(3) 0.0297(18) Uani 1 1 d . . .
H15L H 0.6738 0.4120 0.7261 0.036 Uiso 1 1 calc R . .
C16L C 0.8216(7) 0.4227(5) 0.7086(3) 0.047(3) Uani 1 1 d . . .
H16A H 0.8350 0.4678 0.7248 0.070 Uiso 1 1 calc R . .
H16B H 0.8551 0.4239 0.6810 0.070 Uiso 1 1 calc R . .
H16C H 0.8487 0.3825 0.7270 0.070 Uiso 1 1 calc R . .
C17L C 0.6599(8) 0.4771(4) 0.6704(3) 0.047(3) Uani 1 1 d . . .
H7A H 0.5859 0.4702 0.6639 0.071 Uiso 1 1 calc R . .
H7B H 0.6916 0.4807 0.6425 0.071 Uiso 1 1 calc R . .
H7C H 0.6728 0.5214 0.6876 0.071 Uiso 1 1 calc R . .
C18L C -0.0567(5) 0.4322(3) 0.3860(2) 0.0165(14) Uani 1 1 d . . .
H18L H -0.0404 0.4020 0.3602 0.020 Uiso 1 1 calc R . .
C19L C -0.0998(5) 0.5061(4) 0.3685(3) 0.0239(16) Uani 1 1 d . . .
H19A H -0.1087 0.5067 0.3356 0.029 Uiso 1 1 calc R . .
H19B H -0.1667 0.5161 0.3798 0.029 Uiso 1 1 calc R . .
C20L C 0.0489(5) 0.5208(3) 0.4101(2) 0.0159(14) Uani 1 1 d . . .
C21L C 0.1369(5) 0.5611(3) 0.4321(2) 0.0152(14) Uani 1 1 d . . .
C22L C 0.1435(6) 0.6360(3) 0.4310(3) 0.0224(16) Uani 1 1 d . . .
H22L H 0.0905 0.6642 0.4161 0.027 Uiso 1 1 calc R . .
C23L C 0.2302(5) 0.6675(4) 0.4526(3) 0.0235(16) Uani 1 1 d . . .
H23L H 0.2381 0.7182 0.4523 0.028 Uiso 1 1 calc R . .
C24L C 0.3060(6) 0.6244(3) 0.4748(3) 0.0249(17) Uani 1 1 d . . .
H24L H 0.3661 0.6452 0.4895 0.030 Uiso 1 1 calc R . .
C25L C 0.2917(5) 0.5503(3) 0.4750(2) 0.0153(14) Uani 1 1 d . . .
C26L C 0.3637(5) 0.4986(3) 0.4955(2) 0.0141(13) Uani 1 1 d . . .
C27L C 0.4998(6) 0.4595(3) 0.5403(3) 0.0238(16) Uani 1 1 d . . .
H27A H 0.4889 0.4533 0.5720 0.029 Uiso 1 1 calc R . .
H27B H 0.5742 0.4623 0.5375 0.029 Uiso 1 1 calc R . .
C28L C 0.4508(5) 0.3985(3) 0.5122(2) 0.0135(13) Uani 1 1 d . . .
H28L H 0.4336 0.3582 0.5320 0.016 Uiso 1 1 calc R . .
C29L C -0.1266(5) 0.3901(3) 0.4141(2) 0.0160(14) Uani 1 1 d . . .
H29L H -0.0883 0.3464 0.4254 0.019 Uiso 1 1 calc R . .
C30L C -0.2209(6) 0.3647(4) 0.3841(3) 0.0298(19) Uani 1 1 d . . .
H30A H -0.1988 0.3383 0.3587 0.045 Uiso 1 1 calc R . .
H30B H -0.2617 0.4064 0.3734 0.045 Uiso 1 1 calc R . .
H30C H -0.2624 0.3332 0.4011 0.045 Uiso 1 1 calc R . .
C31L C -0.1565(5) 0.4316(4) 0.4545(3) 0.0256(16) Uani 1 1 d . . .
H31A H -0.2007 0.4016 0.4711 0.038 Uiso 1 1 calc R . .
H31B H -0.1933 0.4754 0.4445 0.038 Uiso 1 1 calc R . .
H31C H -0.0946 0.4445 0.4737 0.038 Uiso 1 1 calc R . .
C32L C 0.5162(5) 0.3700(3) 0.4766(2) 0.0178(14) Uani 1 1 d . . .
H32L H 0.4738 0.3339 0.4586 0.021 Uiso 1 1 calc R . .
C33L C 0.6103(5) 0.3314(4) 0.4975(3) 0.0228(16) Uani 1 1 d . . .
H33A H 0.5896 0.2943 0.5179 0.034 Uiso 1 1 calc R . .
H33B H 0.6558 0.3658 0.5141 0.034 Uiso 1 1 calc R . .
H33C H 0.6463 0.3090 0.4742 0.034 Uiso 1 1 calc R . .
C34L C 0.5460(6) 0.4275(4) 0.4447(3) 0.0268(18) Uani 1 1 d . . .
H34A H 0.4842 0.4515 0.4311 0.040 Uiso 1 1 calc R . .
H34B H 0.5823 0.4053 0.4214 0.040 Uiso 1 1 calc R . .
H34C H 0.5907 0.4627 0.4609 0.040 Uiso 1 1 calc R . .
C35L C -0.3443(6) 0.0638(4) 0.0515(3) 0.0261(17) Uani 1 1 d . . .
H35L H -0.3586 0.1014 0.0282 0.031 Uiso 1 1 calc R . .
C36L C -0.4316(8) 0.0087(5) 0.0462(3) 0.046(3) Uani 1 1 d . . .
H36A H -0.4754 0.0169 0.0181 0.056 Uiso 1 1 calc R . .
H36B H -0.4038 -0.0407 0.0460 0.056 Uiso 1 1 calc R . .
C37L C -0.4397(6) 0.0694(3) 0.1086(3) 0.0248(17) Uani 1 1 d . . .
C38L C -0.4839(6) 0.0907(3) 0.1498(3) 0.0232(16) Uani 1 1 d . . .
C39L C -0.5740(6) 0.0632(4) 0.1621(3) 0.0298(18) Uani 1 1 d . . .
H39L H -0.6093 0.0261 0.1454 0.036 Uiso 1 1 calc R . .
C40L C -0.6120(6) 0.0912(4) 0.1997(3) 0.0319(19) Uani 1 1 d . . .
H40L H -0.6737 0.0728 0.2093 0.038 Uiso 1 1 calc R . .
C41L C -0.5599(6) 0.1460(4) 0.2234(3) 0.0289(17) Uani 1 1 d . . .
H41L H -0.5852 0.1666 0.2489 0.035 Uiso 1 1 calc R . .
C42L C -0.4698(6) 0.1691(4) 0.2082(2) 0.0239(16) Uani 1 1 d . . .
C43L C -0.4072(5) 0.2264(4) 0.2302(2) 0.0227(15) Uani 1 1 d . . .
C44L C -0.3586(6) 0.3049(4) 0.2845(3) 0.0304(18) Uani 1 1 d . . .
H44A H -0.3177 0.2856 0.3112 0.036 Uiso 1 1 calc R . .
H44B H -0.3889 0.3513 0.2922 0.036 Uiso 1 1 calc R . .
C45L C -0.2904(6) 0.3141(3) 0.2450(2) 0.0235(16) Uani 1 1 d . . .
H45L H -0.2170 0.3061 0.2562 0.028 Uiso 1 1 calc R . .
C46L C -0.2381(7) 0.0363(6) 0.0486(3) 0.052(3) Uani 1 1 d . . .
H46L H -0.1893 0.0771 0.0547 0.062 Uiso 1 1 calc R . .
C47L C -0.2300(9) 0.0101(6) 0.0005(3) 0.065(3) Uani 1 1 d . . .
H47A H -0.1607 -0.0079 -0.0022 0.098 Uiso 1 1 calc R . .
H47B H -0.2447 0.0501 -0.0202 0.098 Uiso 1 1 calc R . .
H47C H -0.2796 -0.0285 -0.0067 0.098 Uiso 1 1 calc R . .
C48L C -0.2109(11) -0.0230(7) 0.0844(4) 0.088(4) Uani 1 1 d U . .
H48A H -0.1409 -0.0400 0.0822 0.133 Uiso 1 1 calc R . .
H48B H -0.2588 -0.0632 0.0793 0.133 Uiso 1 1 calc R . .
H48C H -0.2160 -0.0030 0.1140 0.133 Uiso 1 1 calc R . .
C49L C -0.3003(6) 0.3843(4) 0.2212(3) 0.0302(18) Uani 1 1 d . . .
H49L H -0.2563 0.3822 0.1961 0.036 Uiso 1 1 calc R . .
C50L C -0.2612(7) 0.4464(5) 0.2519(3) 0.048(3) Uani 1 1 d . . .
H50A H -0.2686 0.4917 0.2354 0.072 Uiso 1 1 calc R . .
H50B H -0.1888 0.4386 0.2621 0.072 Uiso 1 1 calc R . .
H50C H -0.3011 0.4485 0.2776 0.072 Uiso 1 1 calc R . .
C51L C -0.4114(7) 0.4013(4) 0.2014(3) 0.044(2) Uani 1 1 d . . .
H51A H -0.4126 0.4477 0.1861 0.066 Uiso 1 1 calc R . .
H51B H -0.4564 0.4032 0.2254 0.066 Uiso 1 1 calc R . .
H51C H -0.4351 0.3637 0.1802 0.066 Uiso 1 1 calc R . .
C1D C 0.5464(6) 0.0852(3) 0.7114(2) 0.0216(15) Uani 1 1 d . . .
C2D C 0.4424(6) 0.0157(4) 0.6563(3) 0.0291(18) Uani 1 1 d . . .
H2D1 H 0.4426 0.0026 0.6249 0.044 Uiso 1 1 calc R . .
H2D2 H 0.3795 0.0422 0.6605 0.044 Uiso 1 1 calc R . .
H2D3 H 0.4455 -0.0279 0.6745 0.044 Uiso 1 1 calc R . .
C3D C 0.5992(6) 0.0793(4) 0.6357(2) 0.0256(17) Uani 1 1 d . . .
H3D1 H 0.5747 0.0562 0.6076 0.038 Uiso 1 1 calc R . .
H3D2 H 0.6687 0.0626 0.6453 0.038 Uiso 1 1 calc R . .
H3D3 H 0.5998 0.1315 0.6317 0.038 Uiso 1 1 calc R . .
C7D C 0.5144(6) 0.3585(4) 0.8054(2) 0.0244(16) Uani 1 1 d . . .
C8D C 0.4321(8) 0.4349(4) 0.7475(3) 0.043(2) Uani 1 1 d . . .
H8D1 H 0.4321 0.4874 0.7495 0.065 Uiso 1 1 calc R . .
H8D2 H 0.3674 0.4186 0.7317 0.065 Uiso 1 1 calc R . .
H8D3 H 0.4893 0.4192 0.7313 0.065 Uiso 1 1 calc R . .
C9D C 0.3580(6) 0.4175(4) 0.8194(3) 0.039(2) Uani 1 1 d . . .
H9D1 H 0.3107 0.4531 0.8051 0.058 Uiso 1 1 calc R . .
H9D2 H 0.3858 0.4353 0.8487 0.058 Uiso 1 1 calc R . .
H9D3 H 0.3213 0.3724 0.8231 0.058 Uiso 1 1 calc R . .
C10D C 0.8328(8) 0.3351(7) 0.8225(4) 0.065(3) Uani 1 1 d . . .
C11D C 0.9897(11) 0.2624(10) 0.8480(7) 0.157(9) Uani 1 1 d . . .
H11A H 1.0541 0.2690 0.8669 0.236 Uiso 1 1 calc R . .
H11B H 1.0045 0.2510 0.8177 0.236 Uiso 1 1 calc R . .
H11C H 0.9510 0.2229 0.8597 0.236 Uiso 1 1 calc R . .
C12D C 0.9592(13) 0.3832(9) 0.8825(6) 0.128(6) Uani 1 1 d U . .
H12A H 1.0279 0.3700 0.8956 0.192 Uiso 1 1 calc R . .
H12B H 0.9117 0.3822 0.9055 0.192 Uiso 1 1 calc R . .
H12C H 0.9609 0.4315 0.8698 0.192 Uiso 1 1 calc R . .
C13D C 0.3183(5) 0.3868(3) 0.3642(2) 0.0178(14) Uani 1 1 d . . .
C14D C 0.3720(6) 0.3708(4) 0.2909(2) 0.0256(17) Uani 1 1 d . . .
H14A H 0.3522 0.3884 0.2607 0.038 Uiso 1 1 calc R . .
H14B H 0.3651 0.3185 0.2915 0.038 Uiso 1 1 calc R . .
H14C H 0.4432 0.3841 0.2999 0.038 Uiso 1 1 calc R . .
C15D C 0.2269(6) 0.4526(4) 0.3022(3) 0.0279(17) Uani 1 1 d . . .
H15A H 0.2308 0.4567 0.2701 0.042 Uiso 1 1 calc R . .
H15B H 0.2379 0.4998 0.3161 0.042 Uiso 1 1 calc R . .
H15C H 0.1592 0.4345 0.3077 0.042 Uiso 1 1 calc R . .
C16D C 0.2809(5) 0.2181(4) 0.4286(2) 0.0219(15) Uani 1 1 d . . .
C17D C 0.3346(7) 0.0954(4) 0.4211(4) 0.050(3) Uani 1 1 d . . .
H17A H 0.3841 0.0619 0.4361 0.075 Uiso 1 1 calc R . .
H17B H 0.3492 0.1016 0.3902 0.075 Uiso 1 1 calc R . .
H17C H 0.2652 0.0763 0.4218 0.075 Uiso 1 1 calc R . .
C18D C 0.4202(6) 0.1741(4) 0.4804(3) 0.0244(16) Uani 1 1 d . . .
H18A H 0.4563 0.1286 0.4863 0.037 Uiso 1 1 calc R . .
H18B H 0.3884 0.1890 0.5069 0.037 Uiso 1 1 calc R . .
H18C H 0.4689 0.2109 0.4728 0.037 Uiso 1 1 calc R . .
C19D C 0.0836(5) 0.2247(4) 0.4858(2) 0.0181(14) Uani 1 1 d . . .
C20D C -0.0699(6) 0.1799(4) 0.4424(3) 0.0302(19) Uani 1 1 d . . .
H20A H -0.0792 0.2312 0.4359 0.045 Uiso 1 1 calc R . .
H20B H -0.1290 0.1618 0.4564 0.045 Uiso 1 1 calc R . .
H20C H -0.0637 0.1538 0.4147 0.045 Uiso 1 1 calc R . .
C21D C 0.0519(6) 0.0971(3) 0.4848(3) 0.0237(16) Uani 1 1 d . . .
H21A H -0.0016 0.0642 0.4723 0.036 Uiso 1 1 calc R . .
H21B H 0.0598 0.0926 0.5173 0.036 Uiso 1 1 calc R . .
H21C H 0.1168 0.0851 0.4731 0.036 Uiso 1 1 calc R . .
C22D C 0.0595(6) 0.4112(3) 0.5452(2) 0.0197(15) Uani 1 1 d . . .
C23D C 0.0151(7) 0.4106(4) 0.6206(3) 0.033(2) Uani 1 1 d . . .
H23A H 0.0345 0.4376 0.6480 0.050 Uiso 1 1 calc R . .
H23B H 0.0314 0.3598 0.6255 0.050 Uiso 1 1 calc R . .
H23C H -0.0585 0.4160 0.6122 0.050 Uiso 1 1 calc R . .
C24D C 0.1424(7) 0.4966(4) 0.5975(3) 0.0311(18) Uani 1 1 d . . .
H24A H 0.1819 0.5074 0.5724 0.047 Uiso 1 1 calc R . .
H24B H 0.1891 0.4825 0.6233 0.047 Uiso 1 1 calc R . .
H24C H 0.1039 0.5393 0.6048 0.047 Uiso 1 1 calc R . .
C25D C -0.4814(7) 0.2733(6) 0.0863(4) 0.064(3) Uani 1 1 d . . .
C26D C -0.6415(11) 0.2983(9) 0.0444(5) 0.103(5) Uani 1 1 d U . .
H26A H -0.7130 0.3038 0.0506 0.154 Uiso 1 1 calc R . .
H26B H -0.6364 0.2591 0.0231 0.154 Uiso 1 1 calc R . .
H26C H -0.6178 0.3431 0.0317 0.154 Uiso 1 1 calc R . .
C27D C -0.6335(8) 0.2796(6) 0.1257(4) 0.061(3) Uani 1 1 d . . .
H27C H -0.7068 0.2880 0.1180 0.091 Uiso 1 1 calc R . .
H27D H -0.6057 0.3167 0.1465 0.091 Uiso 1 1 calc R . .
H27E H -0.6234 0.2323 0.1396 0.091 Uiso 1 1 calc R . .
C28D C -0.1926(7) 0.3691(4) 0.1136(3) 0.0322(19) Uani 1 1 d . . .
C29D C -0.0447(9) 0.4098(6) 0.1619(4) 0.072(4) Uani 1 1 d U . .
H29A H 0.0011 0.4515 0.1631 0.108 Uiso 1 1 calc R . .
H29B H -0.0048 0.3659 0.1590 0.108 Uiso 1 1 calc R . .
H29C H -0.0789 0.4076 0.1893 0.108 Uiso 1 1 calc R . .
C30D C -0.1161(10) 0.4839(5) 0.0969(4) 0.066(3) Uani 1 1 d . . .
H30D H -0.0577 0.5126 0.1096 0.098 Uiso 1 1 calc R . .
H30E H -0.1793 0.5116 0.0979 0.098 Uiso 1 1 calc R . .
H30F H -0.1070 0.4719 0.0660 0.098 Uiso 1 1 calc R . .
C31D C -0.0265(8) 0.1426(6) 0.1260(3) 0.049(3) Uani 1 1 d . . .
C32D C 0.1578(16) 0.1251(12) 0.1241(8) 0.171(7) Uani 1 1 d U . .
H32A H 0.2050 0.1181 0.1013 0.256 Uiso 1 1 calc R . .
H32B H 0.1619 0.0839 0.1443 0.256 Uiso 1 1 calc R . .
H32C H 0.1765 0.1689 0.1410 0.256 Uiso 1 1 calc R . .
C33D C 0.0294(17) 0.1159(12) 0.0537(6) 0.172(6) Uani 1 1 d DU . .
H33D H 0.0840 0.0849 0.0447 0.258 Uiso 1 1 calc R . .
H33E H 0.0281 0.1607 0.0367 0.258 Uiso 1 1 calc R . .
H33F H -0.0366 0.0914 0.0479 0.258 Uiso 1 1 calc R . .
O2D O 0.5042(4) 0.1769(3) 0.79921(18) 0.0258(12) Uani 1 1 d . . .
N2D N 0.3529(7) 0.1764(6) 0.8259(3) 0.072(3) Uani 1 1 d U . .
C4D C 0.4057(8) 0.1860(7) 0.7935(4) 0.042(3) Uani 0.80 1 d P A 1
C5D C 0.2366(12) 0.1778(11) 0.8127(6) 0.098(6) Uani 0.80 1 d PU A 1
H5D1 H 0.2116 0.2272 0.8139 0.147 Uiso 0.80 1 calc PR A 1
H5D2 H 0.2022 0.1479 0.8334 0.147 Uiso 0.80 1 calc PR A 1
H5D3 H 0.2220 0.1591 0.7824 0.147 Uiso 0.80 1 calc PR A 1
C6D C 0.3847(14) 0.1399(10) 0.8667(5) 0.095(6) Uani 0.80 1 d P A 1
H6D1 H 0.3540 0.0919 0.8661 0.142 Uiso 0.80 1 calc PR A 1
H6D2 H 0.3623 0.1672 0.8917 0.142 Uiso 0.80 1 calc PR A 1
H6D3 H 0.4595 0.1357 0.8701 0.142 Uiso 0.80 1 calc PR A 1
C4E C 0.472(3) 0.187(2) 0.8381(13) 0.028(8) Uani 0.20 1 d PU A 2
C5E C 0.310(3) 0.210(2) 0.7891(15) 0.037(10) Uani 0.20 1 d PU A 2
H5E1 H 0.3579 0.2110 0.7663 0.056 Uiso 0.20 1 calc PR A 2
H5E2 H 0.2924 0.2597 0.7967 0.056 Uiso 0.20 1 calc PR A 2
H5E3 H 0.2472 0.1850 0.7776 0.056 Uiso 0.20 1 calc PR A 2
C6E C 0.318(3) 0.203(2) 0.8762(14) 0.039(10) Uani 0.20 1 d PU A 2
H6E1 H 0.3783 0.2010 0.8983 0.058 Uiso 0.20 1 calc PR A 2
H6E2 H 0.2653 0.1707 0.8853 0.058 Uiso 0.20 1 calc PR A 2
H6E3 H 0.2921 0.2520 0.8740 0.058 Uiso 0.20 1 calc PR A 2
O12D O -0.2257(4) 0.0886(3) 0.18446(17) 0.0260(12) Uani 1 1 d . . .
N12D N -0.1439(5) 0.0223(3) 0.2396(2) 0.0231(14) Uani 1 1 d . . .
C34D C -0.1580(18) 0.0493(11) 0.1985(8) 0.018(5) Uani 0.30 1 d PU B 1
C35D C -0.205(2) 0.0390(16) 0.2750(11) 0.039(7) Uani 0.30 1 d PU B 1
H35A H -0.2491 0.0799 0.2665 0.059 Uiso 0.30 1 calc PR B 1
H35B H -0.1596 0.0511 0.3018 0.059 Uiso 0.30 1 calc PR B 1
H35C H -0.2467 -0.0026 0.2811 0.059 Uiso 0.30 1 calc PR B 1
C36D C -0.056(2) -0.0234(16) 0.2531(11) 0.039(7) Uani 0.30 1 d PU B 1
H36C H -0.0086 -0.0230 0.2299 0.059 Uiso 0.30 1 calc PR B 1
H36D H -0.0790 -0.0726 0.2575 0.059 Uiso 0.30 1 calc PR B 1
H36E H -0.0203 -0.0052 0.2809 0.059 Uiso 0.30 1 calc PR B 1
C34E C -0.2015(9) 0.0774(6) 0.2240(4) 0.033(3) Uani 0.70 1 d P B 2
C35E C -0.1231(13) 0.0113(6) 0.2870(4) 0.052(4) Uani 0.70 1 d P B 2
H35D H -0.0491 0.0074 0.2948 0.079 Uiso 0.70 1 calc PR B 2
H35E H -0.1566 -0.0328 0.2956 0.079 Uiso 0.70 1 calc PR B 2
H35F H -0.1497 0.0521 0.3028 0.079 Uiso 0.70 1 calc PR B 2
C36E C -0.0957(9) -0.0284(6) 0.2106(5) 0.037(3) Uani 0.70 1 d P B 2
H36F H -0.1219 -0.0199 0.1796 0.056 Uiso 0.70 1 calc PR B 2
H36G H -0.1116 -0.0777 0.2189 0.056 Uiso 0.70 1 calc PR B 2
H36H H -0.0213 -0.0215 0.2141 0.056 Uiso 0.70 1 calc PR B 2
C1S C 0.5285(13) 0.2204(10) 0.3688(6) 0.105(5) Uani 1 1 d U . .
C2S C 0.5849(10) 0.1069(5) 0.3424(4) 0.073(4) Uani 1 1 d . . .
H2S1 H 0.5203 0.1139 0.3237 0.109 Uiso 1 1 calc R . .
H2S2 H 0.5849 0.0597 0.3566 0.109 Uiso 1 1 calc R . .
H2S3 H 0.6422 0.1100 0.3240 0.109 Uiso 1 1 calc R . .
C3S C 0.6762(11) 0.1648(8) 0.4049(5) 0.100(5) Uani 1 1 d U . .
H3S1 H 0.7139 0.1194 0.4052 0.149 Uiso 1 1 calc R . .
H3S2 H 0.6544 0.1740 0.4344 0.149 Uiso 1 1 calc R . .
H3S3 H 0.7207 0.2040 0.3968 0.149 Uiso 1 1 calc R . .
O2S O 0.280(2) 0.0838(16) 0.0137(12) 0.182(12) Uani 0.50 1 d PU C 1
O3S O 0.0935(13) 0.3814(8) 0.0715(7) 0.091(6) Uani 0.50 1 d P D 1
O4S O 0.3640(17) 0.0720(11) -0.0381(8) 0.116(7) Uani 0.50 1 d PU E 1
O5S O 0.2274(16) 0.2997(10) -0.0962(7) 0.106(6) Uani 0.50 1 d PU F 1
O6S O 0.107(4) 0.283(2) -0.0346(15) 0.28(2) Uani 0.50 1 d PU G 1
O7S O 0.198(3) 0.1682(18) -0.0486(12) 0.185(13) Uani 0.50 1 d PU H 1
O3T O 0.077(3) 0.3100(18) 0.0923(11) 0.192(13) Uani 0.50 1 d PU I 2
O7T O 0.110(3) 0.1790(19) -0.0807(13) 0.199(13) Uani 0.50 1 d PU J 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C6A W1 C4A 77.4(2) . .
C6A W1 C1A 142.1(3) . .
C4A W1 C1A 117.3(2) . .
C6A W1 C8A 77.5(2) . .
C4A W1 C8A 72.3(2) . .
C1A W1 C8A 75.0(3) . .
C6A W1 C3A 141.3(2) . .
C4A W1 C3A 71.6(2) . .
C1A W1 C3A 74.6(3) . .
C8A W1 C3A 113.2(2) . .
C6A W1 C5A 74.2(2) . .
C4A W1 C5A 76.6(2) . .
C1A W1 C5A 141.0(3) . .
C8A W1 C5A 141.6(3) . .
C3A W1 C5A 76.6(2) . .
C6A W1 C2A 114.6(2) . .
C4A W1 C2A 142.9(2) . .
C1A W1 C2A 75.9(2) . .
C8A W1 C2A 142.9(3) . .
C3A W1 C2A 80.1(2) . .
C5A W1 C2A 73.8(3) . .
C6A W1 C7A 71.6(2) . .
C4A W1 C7A 140.7(2) . .
C1A W1 C7A 77.6(3) . .
C8A W1 C7A 77.9(2) . .
C3A W1 C7A 145.6(2) . .
C5A W1 C7A 115.9(3) . .
C2A W1 C7A 73.9(2) . .
C1B W2 C6B 75.4(3) . .
C1B W2 C2B 73.8(3) . .
C6B W2 C2B 142.6(3) . .
C1B W2 C4B 141.9(3) . .
C6B W2 C4B 116.9(3) . .
C2B W2 C4B 77.9(3) . .
C1B W2 C7B 139.6(2) . .
C6B W2 C7B 71.1(2) . .
C2B W2 C7B 145.0(2) . .
C4B W2 C7B 75.3(2) . .
C1B W2 C8B 76.4(3) . .
C6B W2 C8B 74.5(3) . .
C2B W2 C8B 78.1(3) . .
C4B W2 C8B 73.2(3) . .
C7B W2 C8B 114.3(2) . .
C1B W2 C3B 120.7(3) . .
C6B W2 C3B 139.8(3) . .
C2B W2 C3B 75.6(3) . .
C4B W2 C3B 74.8(3) . .
C7B W2 C3B 76.0(2) . .
C8B W2 C3B 142.0(3) . .
C1B W2 C5B 72.7(3) . .
C6B W2 C5B 79.9(3) . .
C2B W2 C5B 110.0(3) . .
C4B W2 C5B 142.4(2) . .
C7B W2 C5B 79.8(2) . .
C8B W2 C5B 143.9(3) . .
C3B W2 C5B 72.1(3) . .
C7C W3 C5C 142.4(3) . .
C7C W3 C1C 72.1(3) . .
C5C W3 C1C 75.8(3) . .
C7C W3 C3C 142.6(3) . .
C5C W3 C3C 73.3(3) . .
C1C W3 C3C 144.4(3) . .
C7C W3 C4C 75.8(3) . 1_454
C5C W3 C4C 120.5(3) . 1_454
C1C W3 C4C 139.3(3) . 1_454
C3C W3 C4C 73.4(3) . 1_454
C7C W3 C6C 112.7(4) . .
C5C W3 C6C 76.2(4) . .
C1C W3 C6C 74.9(3) . .
C3C W3 C6C 81.1(3) . .
C4C W3 C6C 142.2(3) 1_454 .
C7C W3 C2C 72.8(3) . .
C5C W3 C2C 141.5(3) . .
C1C W3 C2C 117.7(3) . .
C3C W3 C2C 78.9(3) . .
C4C W3 C2C 74.4(3) 1_454 .
C6C W3 C2C 73.6(3) . .
C7C W3 C8C 80.4(3) . .
C5C W3 C8C 73.9(3) . .
C1C W3 C8C 77.1(3) . .
C3C W3 C8C 110.0(3) . .
C4C W3 C8C 73.3(3) 1_454 .
C6C W3 C8C 143.0(3) . .
C2C W3 C8C 142.0(3) . .
O2D Eu1 O4D 141.17(19) . .
O2D Eu1 O3D 87.19(17) . .
O4D Eu1 O3D 78.65(19) . .
O2D Eu1 O1D 78.74(17) . .
O4D Eu1 O1D 133.37(17) . .
O3D Eu1 O1D 139.35(17) . .
O2D Eu1 N4C 71.1(2) . .
O4D Eu1 N4C 70.1(2) . .
O3D Eu1 N4C 71.61(18) . .
O1D Eu1 N4C 135.52(19) . .
O2D Eu1 N3L 139.72(19) . .
O4D Eu1 N3L 74.7(2) . .
O3D Eu1 N3L 83.48(17) . .
O1D Eu1 N3L 83.26(17) . .
N4C Eu1 N3L 140.0(2) . .
O2D Eu1 N1L 84.62(19) . .
O4D Eu1 N1L 83.9(2) . .
O3D Eu1 N1L 140.37(18) . .
O1D Eu1 N1L 76.39(18) . .
N4C Eu1 N1L 69.05(19) . .
N3L Eu1 N1L 125.52(19) . .
O2D Eu1 N7A 70.83(18) . .
O4D Eu1 N7A 134.18(19) . .
O3D Eu1 N7A 70.37(17) . .
O1D Eu1 N7A 69.00(17) . .
N4C Eu1 N7A 126.50(19) . .
N3L Eu1 N7A 69.12(18) . .
N1L Eu1 N7A 140.55(18) . .
O2D Eu1 N2L 136.54(17) . .
O4D Eu1 N2L 66.35(18) . .
O3D Eu1 N2L 136.27(18) . .
O1D Eu1 N2L 67.04(17) . .
N4C Eu1 N2L 116.45(19) . .
N3L Eu1 N2L 63.09(18) . .
N1L Eu1 N2L 62.43(19) . .
N7A Eu1 N2L 117.05(18) . .
O6D Eu2 O8D 140.01(16) . .
O6D Eu2 O5D 78.16(15) . .
O8D Eu2 O5D 136.13(15) . .
O6D Eu2 O7D 85.15(15) . .
O8D Eu2 O7D 76.87(15) . .
O5D Eu2 O7D 140.02(16) . .
O6D Eu2 N4L 140.36(16) . .
O8D Eu2 N4L 76.32(16) . .
O5D Eu2 N4L 79.40(16) . .
O7D Eu2 N4L 91.62(15) . .
O6D Eu2 N6L 81.15(16) . .
O8D Eu2 N6L 87.39(16) . .
O5D Eu2 N6L 77.10(16) . .
O7D Eu2 N6L 135.90(16) . .
N4L Eu2 N6L 124.55(16) . .
O6D Eu2 N4A 70.53(17) . .
O8D Eu2 N4A 69.77(16) . .
O5D Eu2 N4A 134.49(17) . .
O7D Eu2 N4A 69.59(16) . .
N4L Eu2 N4A 144.02(16) . .
N6L Eu2 N4A 66.32(16) . .
O6D Eu2 N7B 71.00(16) . .
O8D Eu2 N7B 131.98(17) . .
O5D Eu2 N7B 70.00(17) . .
O7D Eu2 N7B 70.26(16) . .
N4L Eu2 N7B 70.77(16) . .
N6L Eu2 N7B 140.27(17) . .
N4A Eu2 N7B 125.63(16) . .
O6D Eu2 N5L 134.28(16) . .
O8D Eu2 N5L 68.33(15) . .
O5D Eu2 N5L 68.10(16) . .
O7D Eu2 N5L 140.22(15) . .
N4L Eu2 N5L 62.39(16) . .
N6L Eu2 N5L 62.31(16) . .
N4A Eu2 N5L 113.28(16) . .
N7B Eu2 N5L 121.07(16) . .
O10D Eu3 O11D 85.9(2) . .
O10D Eu3 O9D 81.3(2) . .
O11D Eu3 O9D 141.35(19) . .
O10D Eu3 O12D 138.57(19) . .
O11D Eu3 O12D 76.61(19) . .
O9D Eu3 O12D 133.78(18) . .
O10D Eu3 N1C 71.47(19) . .
O11D Eu3 N1C 71.0(2) . .
O9D Eu3 N1C 70.3(2) . .
O12D Eu3 N1C 133.48(19) . .
O10D Eu3 N7L 141.74(19) . .
O11D Eu3 N7L 86.32(18) . .
O9D Eu3 N7L 81.76(19) . .
O12D Eu3 N7L 74.90(18) . .
N1C Eu3 N7L 70.57(18) . .
O10D Eu3 N1B 70.47(19) . .
O11D Eu3 N1B 71.43(18) . .
O9D Eu3 N1B 135.32(18) . .
O12D Eu3 N1B 68.41(17) . .
N1C Eu3 N1B 127.5(2) . .
N7L Eu3 N1B 140.41(18) . .
O10D Eu3 N9L 82.16(19) . .
O11D Eu3 N9L 139.97(18) . .
O9D Eu3 N9L 73.99(18) . .
O12D Eu3 N9L 87.57(18) . .
N1C Eu3 N9L 138.1(2) . .
N7L Eu3 N9L 125.01(18) . .
N1B Eu3 N9L 68.56(18) . .
O10D Eu3 N8L 136.06(19) . .
O11D Eu3 N8L 137.89(18) . .
O9D Eu3 N8L 65.53(18) . .
O12D Eu3 N8L 68.36(18) . .
N1C Eu3 N8L 118.6(2) . .
N7L Eu3 N8L 62.93(18) . .
N1B Eu3 N8L 113.92(19) . .
N9L Eu3 N8L 62.14(18) . .
C3L O1L C2L 104.2(5) . .
C9L O2L C10L 104.8(5) . .
C20L O3L C19L 105.7(5) . .
C26L O4L C27L 104.1(5) . .
C37L O5L C36L 105.8(6) . .
C43L O6L C44L 105.5(5) . .
C1D O1D Eu1 135.2(4) . .
C7D O3D Eu1 128.0(4) . .
C10D O4D Eu1 138.3(6) . .
C13D O5D Eu2 135.9(4) . .
C16D O6D Eu2 136.4(4) . .
C19D O7D Eu2 125.7(4) . .
C22D O8D Eu2 132.2(4) . .
C25D O9D Eu3 139.9(7) . .
C28D O10D Eu3 149.4(6) . .
C31D O11D Eu3 141.4(6) . .
C4A N4A Eu2 177.5(5) . .
C7A N7A Eu1 172.2(5) . .
C1B N1B Eu3 173.4(6) . .
C7B N7B Eu2 168.5(5) . .
C1C N1C Eu3 169.2(6) . .
C4C N4C Eu1 171.8(6) . .
C3L N1L C1L 105.8(6) . .
C3L N1L Eu1 118.9(5) . .
C1L N1L Eu1 135.0(4) . .
C4L N2L C8L 118.7(6) . .
C4L N2L Eu1 120.3(5) . .
C8L N2L Eu1 120.6(5) . .
C9L N3L C11L 107.3(6) . .
C9L N3L Eu1 119.0(5) . .
C11L N3L Eu1 133.7(4) . .
C20L N4L C18L 107.0(5) . .
C20L N4L Eu2 120.3(4) . .
C18L N4L Eu2 132.5(4) . .
C21L N5L C25L 119.4(5) . .
C21L N5L Eu2 120.7(4) . .
C25L N5L Eu2 119.9(4) . .
C26L N6L C28L 107.3(5) . .
C26L N6L Eu2 118.9(4) . .
C28L N6L Eu2 133.6(4) . .
C37L N7L C35L 107.0(6) . .
C37L N7L Eu3 119.6(5) . .
C35L N7L Eu3 133.2(4) . .
C42L N8L C38L 117.0(6) . .
C42L N8L Eu3 122.4(5) . .
C38L N8L Eu3 120.2(5) . .
C43L N9L C45L 107.1(6) . .
C43L N9L Eu3 118.5(5) . .
C45L N9L Eu3 134.4(4) . .
C1D N1D C2D 120.0(6) . .
C1D N1D C3D 122.1(6) . .
C2D N1D C3D 117.8(6) . .
C7D N3D C8D 124.1(7) . .
C7D N3D C9D 118.1(7) . .
C8D N3D C9D 116.9(7) . .
C10D N4D C12D 124.9(15) . .
C10D N4D C11D 118.9(12) . .
C12D N4D C11D 114.6(15) . .
C13D N5D C14D 120.6(6) . .
C13D N5D C15D 122.4(6) . .
C14D N5D C15D 117.0(6) . .
C16D N6D C18D 122.7(6) . .
C16D N6D C17D 118.8(6) . .
C18D N6D C17D 118.4(6) . .
C19D N7D C21D 121.5(6) . .
C19D N7D C20D 121.0(6) . .
C21D N7D C20D 117.4(6) . .
C22D N8D C23D 122.0(6) . .
C22D N8D C24D 122.1(6) . .
C23D N8D C24D 115.9(6) . .
C25D N9D C26D 122.9(11) . .
C25D N9D C27D 121.1(9) . .
C26D N9D C27D 116.0(10) . .
C28D N10D C29D 122.6(7) . .
C28D N10D C30D 122.4(8) . .
C29D N10D C30D 115.0(7) . .
C31D N11D C33D 121.0(15) . .
C31D N11D C32D 120.0(15) . .
C33D N11D C32D 118.4(15) . .
C3S N1S C1S 120.3(15) . .
C3S N1S C2S 122.0(13) . .
C1S N1S C2S 115.8(13) . .
N1A C1A W1 179.2(7) . .
N2A C2A W1 176.9(6) . .
N3A C3A W1 176.0(6) . .
N4A C4A W1 177.4(6) . .
N5A C5A W1 177.8(6) . .
N6A C6A W1 178.0(5) . .
N7A C7A W1 179.4(6) . .
N8A C8A W1 176.4(6) . .
N1B C1B W2 176.5(6) . .
N2B C2B W2 176.0(6) . .
N3B C3B W2 179.3(7) . .
N4B C4B W2 178.0(7) . .
N5B C5B W2 174.5(6) . .
N6B C6B W2 177.4(7) . .
N7B C7B W2 177.5(5) . .
N8B C8B W2 179.3(7) . .
N1C C1C W3 177.4(7) . .
N2C C2C W3 176.8(8) . .
N3C C3C W3 178.4(7) . .
N4C C4C W3 178.5(7) . 1_656
N5C C5C W3 178.5(8) . .
N6C C6C W3 177.0(8) . .
N7C C7C W3 177.8(7) . .
N8C C8C W3 177.1(9) . .
N1L C1L C12L 110.4(6) . .
N1L C1L C2L 102.5(6) . .
C12L C1L C2L 116.0(6) . .
N1L C1L H1L 109.2 . .
C12L C1L H1L 109.2 . .
C2L C1L H1L 109.2 . .
O1L C2L C1L 104.2(6) . .
O1L C2L H2L1 110.9 . .
C1L C2L H2L1 110.9 . .
O1L C2L H2L2 110.9 . .
C1L C2L H2L2 110.9 . .
H2L1 C2L H2L2 108.9 . .
N1L C3L O1L 119.9(7) . .
N1L C3L C4L 123.5(7) . .
O1L C3L C4L 116.6(6) . .
N2L C4L C5L 121.6(7) . .
N2L C4L C3L 113.8(6) . .
C5L C4L C3L 124.6(7) . .
C6L C5L C4L 119.0(7) . .
C6L C5L H5L 120.5 . .
C4L C5L H5L 120.5 . .
C7L C6L C5L 118.8(7) . .
C7L C6L H6L 120.6 . .
C5L C6L H6L 120.6 . .
C6L C7L C8L 118.8(8) . .
C6L C7L H7L 120.6 . .
C8L C7L H7L 120.6 . .
N2L C8L C7L 123.1(7) . .
N2L C8L C9L 113.5(6) . .
C7L C8L C9L 123.3(7) . .
N3L C9L O2L 118.1(7) . .
N3L C9L C8L 123.5(6) . .
O2L C9L C8L 118.4(6) . .
O2L C10L C11L 105.7(6) . .
O2L C10L H10A 110.6 . .
C11L C10L H10A 110.6 . .
O2L C10L H10B 110.6 . .
C11L C10L H10B 110.6 . .
H10A C10L H10B 108.7 . .
N3L C11L C10L 100.8(6) . .
N3L C11L C15L 109.5(6) . .
C10L C11L C15L 114.9(6) . .
N3L C11L H11L 110.4 . .
C10L C11L H11L 110.4 . .
C15L C11L H11L 110.4 . .
C1L C12L C14L 110.1(7) . .
C1L C12L C13L 111.8(7) . .
C14L C12L C13L 111.0(7) . .
C1L C12L H12L 107.9 . .
C14L C12L H12L 107.9 . .
C13L C12L H12L 107.9 . .
C12L C13L H13A 109.5 . .
C12L C13L H13B 109.5 . .
H13A C13L H13B 109.5 . .
C12L C13L H13C 109.5 . .
H13A C13L H13C 109.5 . .
H13B C13L H13C 109.5 . .
C12L C14L H4A 109.5 . .
C12L C14L H4B 109.5 . .
H4A C14L H4B 109.5 . .
C12L C14L H4C 109.5 . .
H4A C14L H4C 109.5 . .
H4B C14L H4C 109.5 . .
C17L C15L C16L 110.9(7) . .
C17L C15L C11L 109.6(7) . .
C16L C15L C11L 113.1(7) . .
C17L C15L H15L 107.7 . .
C16L C15L H15L 107.7 . .
C11L C15L H15L 107.7 . .
C15L C16L H16A 109.5 . .
C15L C16L H16B 109.5 . .
H16A C16L H16B 109.5 . .
C15L C16L H16C 109.5 . .
H16A C16L H16C 109.5 . .
H16B C16L H16C 109.5 . .
C15L C17L H7A 109.5 . .
C15L C17L H7B 109.5 . .
H7A C17L H7B 109.5 . .
C15L C17L H7C 109.5 . .
H7A C17L H7C 109.5 . .
H7B C17L H7C 109.5 . .
N4L C18L C29L 111.0(5) . .
N4L C18L C19L 102.7(5) . .
C29L C18L C19L 115.0(6) . .
N4L C18L H18L 109.3 . .
C29L C18L H18L 109.3 . .
C19L C18L H18L 109.3 . .
O3L C19L C18L 105.0(5) . .
O3L C19L H19A 110.7 . .
C18L C19L H19A 110.7 . .
O3L C19L H19B 110.7 . .
C18L C19L H19B 110.7 . .
H19A C19L H19B 108.8 . .
N4L C20L O3L 119.5(6) . .
N4L C20L C21L 122.9(6) . .
O3L C20L C21L 117.6(5) . .
N5L C21L C22L 123.4(6) . .
N5L C21L C20L 113.6(5) . .
C22L C21L C20L 122.9(6) . .
C23L C22L C21L 117.5(6) . .
C23L C22L H22L 121.3 . .
C21L C22L H22L 121.3 . .
C22L C23L C24L 119.6(6) . .
C22L C23L H23L 120.2 . .
C24L C23L H23L 120.2 . .
C25L C24L C23L 118.9(7) . .
C25L C24L H24L 120.6 . .
C23L C24L H24L 120.6 . .
N5L C25L C24L 121.1(6) . .
N5L C25L C26L 113.3(5) . .
C24L C25L C26L 125.4(6) . .
N6L C26L O4L 118.5(6) . .
N6L C26L C25L 124.6(6) . .
O4L C26L C25L 116.9(5) . .
O4L C27L C28L 103.6(5) . .
O4L C27L H27A 111.0 . .
C28L C27L H27A 111.0 . .
O4L C27L H27B 111.0 . .
C28L C27L H27B 111.0 . .
H27A C27L H27B 109.0 . .
N6L C28L C27L 103.3(5) . .
N6L C28L C32L 110.3(5) . .
C27L C28L C32L 114.5(6) . .
N6L C28L H28L 109.5 . .
C27L C28L H28L 109.5 . .
C32L C28L H28L 109.5 . .
C18L C29L C31L 113.6(5) . .
C18L C29L C30L 108.9(6) . .
C31L C29L C30L 111.8(6) . .
C18L C29L H29L 107.4 . .
C31L C29L H29L 107.4 . .
C30L C29L H29L 107.4 . .
C29L C30L H30A 109.5 . .
C29L C30L H30B 109.5 . .
H30A C30L H30B 109.5 . .
C29L C30L H30C 109.5 . .
H30A C30L H30C 109.5 . .
H30B C30L H30C 109.5 . .
C29L C31L H31A 109.5 . .
C29L C31L H31B 109.5 . .
H31A C31L H31B 109.5 . .
C29L C31L H31C 109.5 . .
H31A C31L H31C 109.5 . .
H31B C31L H31C 109.5 . .
C33L C32L C34L 110.5(6) . .
C33L C32L C28L 111.1(6) . .
C34L C32L C28L 113.5(5) . .
C33L C32L H32L 107.1 . .
C34L C32L H32L 107.1 . .
C28L C32L H32L 107.1 . .
C32L C33L H33A 109.5 . .
C32L C33L H33B 109.5 . .
H33A C33L H33B 109.5 . .
C32L C33L H33C 109.5 . .
H33A C33L H33C 109.5 . .
H33B C33L H33C 109.5 . .
C32L C34L H34A 109.5 . .
C32L C34L H34B 109.5 . .
H34A C34L H34B 109.5 . .
C32L C34L H34C 109.5 . .
H34A C34L H34C 109.5 . .
H34B C34L H34C 109.5 . .
C46L C35L N7L 113.4(7) . .
C46L C35L C36L 117.0(7) . .
N7L C35L C36L 101.8(6) . .
C46L C35L H35L 108.0 . .
N7L C35L H35L 108.0 . .
C36L C35L H35L 108.0 . .
O5L C36L C35L 106.0(6) . .
O5L C36L H36A 110.5 . .
C35L C36L H36A 110.5 . .
O5L C36L H36B 110.5 . .
C35L C36L H36B 110.5 . .
H36A C36L H36B 108.7 . .
N7L C37L O5L 119.2(7) . .
N7L C37L C38L 123.7(6) . .
O5L C37L C38L 117.1(7) . .
N8L C38L C39L 123.2(7) . .
N8L C38L C37L 113.5(6) . .
C39L C38L C37L 123.2(7) . .
C38L C39L C40L 118.0(7) . .
C38L C39L H39L 121.0 . .
C40L C39L H39L 121.0 . .
C41L C40L C39L 120.0(7) . .
C41L C40L H40L 120.0 . .
C39L C40L H40L 120.0 . .
C42L C41L C40L 117.0(7) . .
C42L C41L H41L 121.5 . .
C40L C41L H41L 121.5 . .
N8L C42L C41L 124.7(7) . .
N8L C42L C43L 112.8(6) . .
C41L C42L C43L 122.5(7) . .
N9L C43L O6L 118.8(6) . .
N9L C43L C42L 123.9(6) . .
O6L C43L C42L 117.2(6) . .
O6L C44L C45L 104.8(6) . .
O6L C44L H44A 110.8 . .
C45L C44L H44A 110.8 . .
O6L C44L H44B 110.8 . .
C45L C44L H44B 110.8 . .
H44A C44L H44B 108.9 . .
C49L C45L N9L 111.5(6) . .
C49L C45L C44L 115.6(6) . .
N9L C45L C44L 102.0(5) . .
C49L C45L H45L 109.1 . .
N9L C45L H45L 109.1 . .
C44L C45L H45L 109.1 . .
C35L C46L C47L 108.3(8) . .
C35L C46L C48L 110.6(9) . .
C47L C46L C48L 113.3(9) . .
C35L C46L H46L 108.2 . .
C47L C46L H46L 108.2 . .
C48L C46L H46L 108.2 . .
C46L C47L H47A 109.5 . .
C46L C47L H47B 109.5 . .
H47A C47L H47B 109.5 . .
C46L C47L H47C 109.5 . .
H47A C47L H47C 109.5 . .
H47B C47L H47C 109.5 . .
C46L C48L H48A 109.5 . .
C46L C48L H48B 109.5 . .
H48A C48L H48B 109.5 . .
C46L C48L H48C 109.5 . .
H48A C48L H48C 109.5 . .
H48B C48L H48C 109.5 . .
C45L C49L C50L 111.3(7) . .
C45L C49L C51L 113.5(7) . .
C50L C49L C51L 108.9(6) . .
C45L C49L H49L 107.7 . .
C50L C49L H49L 107.7 . .
C51L C49L H49L 107.7 . .
C49L C50L H50A 109.5 . .
C49L C50L H50B 109.5 . .
H50A C50L H50B 109.5 . .
C49L C50L H50C 109.5 . .
H50A C50L H50C 109.5 . .
H50B C50L H50C 109.5 . .
C49L C51L H51A 109.5 . .
C49L C51L H51B 109.5 . .
H51A C51L H51B 109.5 . .
C49L C51L H51C 109.5 . .
H51A C51L H51C 109.5 . .
H51B C51L H51C 109.5 . .
O1D C1D N1D 122.6(7) . .
N1D C2D H2D1 109.5 . .
N1D C2D H2D2 109.5 . .
H2D1 C2D H2D2 109.5 . .
N1D C2D H2D3 109.5 . .
H2D1 C2D H2D3 109.5 . .
H2D2 C2D H2D3 109.5 . .
N1D C3D H3D1 109.5 . .
N1D C3D H3D2 109.5 . .
H3D1 C3D H3D2 109.5 . .
N1D C3D H3D3 109.5 . .
H3D1 C3D H3D3 109.5 . .
H3D2 C3D H3D3 109.5 . .
O3D C7D N3D 121.8(7) . .
N3D C8D H8D1 109.5 . .
N3D C8D H8D2 109.5 . .
H8D1 C8D H8D2 109.5 . .
N3D C8D H8D3 109.5 . .
H8D1 C8D H8D3 109.5 . .
H8D2 C8D H8D3 109.5 . .
N3D C9D H9D1 109.5 . .
N3D C9D H9D2 109.5 . .
H9D1 C9D H9D2 109.5 . .
N3D C9D H9D3 109.5 . .
H9D1 C9D H9D3 109.5 . .
H9D2 C9D H9D3 109.5 . .
O4D C10D N4D 122.8(12) . .
N4D C11D H11A 109.5 . .
N4D C11D H11B 109.5 . .
H11A C11D H11B 109.5 . .
N4D C11D H11C 109.5 . .
H11A C11D H11C 109.5 . .
H11B C11D H11C 109.5 . .
N4D C12D H12A 109.5 . .
N4D C12D H12B 109.5 . .
H12A C12D H12B 109.5 . .
N4D C12D H12C 109.5 . .
H12A C12D H12C 109.5 . .
H12B C12D H12C 109.5 . .
O5D C13D N5D 122.6(6) . .
N5D C14D H14A 109.5 . .
N5D C14D H14B 109.5 . .
H14A C14D H14B 109.5 . .
N5D C14D H14C 109.5 . .
H14A C14D H14C 109.5 . .
H14B C14D H14C 109.5 . .
N5D C15D H15A 109.5 . .
N5D C15D H15B 109.5 . .
H15A C15D H15B 109.5 . .
N5D C15D H15C 109.5 . .
H15A C15D H15C 109.5 . .
H15B C15D H15C 109.5 . .
O6D C16D N6D 120.9(6) . .
N6D C17D H17A 109.5 . .
N6D C17D H17B 109.5 . .
H17A C17D H17B 109.5 . .
N6D C17D H17C 109.5 . .
H17A C17D H17C 109.5 . .
H17B C17D H17C 109.5 . .
N6D C18D H18A 109.5 . .
N6D C18D H18B 109.5 . .
H18A C18D H18B 109.5 . .
N6D C18D H18C 109.5 . .
H18A C18D H18C 109.5 . .
H18B C18D H18C 109.5 . .
O7D C19D N7D 123.4(6) . .
N7D C20D H20A 109.5 . .
N7D C20D H20B 109.5 . .
H20A C20D H20B 109.5 . .
N7D C20D H20C 109.5 . .
H20A C20D H20C 109.5 . .
H20B C20D H20C 109.5 . .
N7D C21D H21A 109.5 . .
N7D C21D H21B 109.5 . .
H21A C21D H21B 109.5 . .
N7D C21D H21C 109.5 . .
H21A C21D H21C 109.5 . .
H21B C21D H21C 109.5 . .
O8D C22D N8D 124.1(7) . .
N8D C23D H23A 109.5 . .
N8D C23D H23B 109.5 . .
H23A C23D H23B 109.5 . .
N8D C23D H23C 109.5 . .
H23A C23D H23C 109.5 . .
H23B C23D H23C 109.5 . .
N8D C24D H24A 109.5 . .
N8D C24D H24B 109.5 . .
H24A C24D H24B 109.5 . .
N8D C24D H24C 109.5 . .
H24A C24D H24C 109.5 . .
H24B C24D H24C 109.5 . .
O9D C25D N9D 126.3(10) . .
N9D C26D H26A 109.5 . .
N9D C26D H26B 109.5 . .
H26A C26D H26B 109.5 . .
N9D C26D H26C 109.5 . .
H26A C26D H26C 109.5 . .
H26B C26D H26C 109.5 . .
N9D C27D H27C 109.5 . .
N9D C27D H27D 109.5 . .
H27C C27D H27D 109.5 . .
N9D C27D H27E 109.5 . .
H27C C27D H27E 109.5 . .
H27D C27D H27E 109.5 . .
O10D C28D N10D 122.5(8) . .
N10D C29D H29A 109.5 . .
N10D C29D H29B 109.5 . .
H29A C29D H29B 109.5 . .
N10D C29D H29C 109.5 . .
H29A C29D H29C 109.5 . .
H29B C29D H29C 109.5 . .
N10D C30D H30D 109.5 . .
N10D C30D H30E 109.5 . .
H30D C30D H30E 109.5 . .
N10D C30D H30F 109.5 . .
H30D C30D H30F 109.5 . .
H30E C30D H30F 109.5 . .
O11D C31D N11D 129.2(11) . .
N11D C32D H32A 109.5 . .
N11D C32D H32B 109.5 . .
H32A C32D H32B 109.5 . .
N11D C32D H32C 109.5 . .
H32A C32D H32C 109.5 . .
H32B C32D H32C 109.5 . .
N11D C33D H33D 109.5 . .
N11D C33D H33E 109.5 . .
H33D C33D H33E 109.5 . .
N11D C33D H33F 109.5 . .
H33D C33D H33F 109.5 . .
H33E C33D H33F 109.5 . .
C4D O2D C4E 72.1(18) . .
C4D O2D Eu1 139.0(6) . .
C4E O2D Eu1 127.9(18) . .
C4D N2D C5E 61.1(19) . .
C4D N2D C6D 126.6(11) . .
C5E N2D C6D 172(2) . .
C4D N2D C5D 113.7(12) . .
C5E N2D C5D 57.0(19) . .
C6D N2D C5D 115.3(12) . .
C4D N2D C4E 63.9(15) . .
C5E N2D C4E 117(2) . .
C6D N2D C4E 70.2(16) . .
C5D N2D C4E 171.9(17) . .
C4D N2D C6E 149.7(18) . .
C5E N2D C6E 118(2) . .
C6D N2D C6E 56.6(16) . .
C5D N2D C6E 83.3(17) . .
C4E N2D C6E 96(2) . .
N2D C4D O2D 119.5(10) . .
N2D C5D H5D1 109.5 . .
N2D C5D H5D2 109.5 . .
N2D C5D H5D3 109.5 . .
N2D C6D H6D1 109.5 . .
N2D C6D H6D2 109.5 . .
N2D C6D H6D3 109.5 . .
O2D C4E N2D 100(3) . .
N2D C5E H5E1 109.5 . .
N2D C5E H5E2 109.5 . .
H5E1 C5E H5E2 109.5 . .
N2D C5E H5E3 109.5 . .
H5E1 C5E H5E3 109.5 . .
H5E2 C5E H5E3 109.5 . .
N2D C6E H6E1 109.5 . .
N2D C6E H6E2 109.5 . .
H6E1 C6E H6E2 109.5 . .
N2D C6E H6E3 109.5 . .
H6E1 C6E H6E3 109.5 . .
H6E2 C6E H6E3 109.5 . .
C34D O12D C34E 55.7(12) . .
C34D O12D Eu3 144.4(11) . .
C34E O12D Eu3 132.4(6) . .
C34E N12D C34D 50.2(11) . .
C34E N12D C35D 76.0(14) . .
C34D N12D C35D 125.3(17) . .
C34E N12D C35E 120.1(10) . .
C34D N12D C35E 165.7(11) . .
C35D N12D C35E 49.7(14) . .
C34E N12D C36D 162.3(13) . .
C34D N12D C36D 120.8(17) . .
C35D N12D C36D 113.7(19) . .
C35E N12D C36D 64.9(14) . .
C34E N12D C36E 123.2(9) . .
C34D N12D C36E 73.6(11) . .
C35D N12D C36E 152.7(13) . .
C35E N12D C36E 116.7(9) . .
C36D N12D C36E 54.4(13) . .
O12D C34D N12D 126.2(19) . .
N12D C35D H35A 109.5 . .
N12D C35D H35B 109.5 . .
H35A C35D H35B 109.5 . .
N12D C35D H35C 109.5 . .
H35A C35D H35C 109.5 . .
H35B C35D H35C 109.5 . .
N12D C36D H36C 109.5 . .
N12D C36D H36D 109.5 . .
N12D C36D H36E 109.5 . .
O12D C34E N12D 124.0(12) . .
N12D C35E H35D 109.5 . .
N12D C35E H35E 109.5 . .
H35D C35E H35E 109.5 . .
N12D C35E H35F 109.5 . .
H35D C35E H35F 109.5 . .
H35E C35E H35F 109.5 . .
N12D C36E H36F 109.5 . .
N12D C36E H36G 109.5 . .
H36F C36E H36G 109.5 . .
N12D C36E H36H 109.5 . .
H36F C36E H36H 109.5 . .
H36G C36E H36H 109.5 . .
O1S C1S N1S 127.9(19) . .
N1S C2S H2S1 109.5 . .
N1S C2S H2S2 109.5 . .
H2S1 C2S H2S2 109.5 . .
N1S C2S H2S3 109.5 . .
H2S1 C2S H2S3 109.5 . .
H2S2 C2S H2S3 109.5 . .
N1S C3S H3S1 109.5 . .
N1S C3S H3S2 109.5 . .
H3S1 C3S H3S2 109.5 . .
N1S C3S H3S3 109.5 . .
H3S1 C3S H3S3 109.5 . .
H3S2 C3S H3S3 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
W1 C6A 2.150(7) .
W1 C4A 2.153(6) .
W1 C1A 2.160(6) .
W1 C8A 2.162(7) .
W1 C3A 2.169(7) .
W1 C5A 2.169(7) .
W1 C2A 2.178(6) .
W1 C7A 2.182(6) .
W2 C1B 2.160(6) .
W2 C6B 2.170(7) .
W2 C2B 2.173(6) .
W2 C4B 2.173(8) .
W2 C7B 2.174(7) .
W2 C8B 2.174(7) .
W2 C3B 2.183(6) .
W2 C5B 2.193(6) .
W3 C7C 2.145(9) .
W3 C5C 2.149(9) .
W3 C1C 2.150(7) .
W3 C3C 2.153(7) .
W3 C4C 2.155(8) 1_454
W3 C6C 2.159(8) .
W3 C2C 2.164(9) .
W3 C8C 2.183(10) .
Eu1 O2D 2.389(5) .
Eu1 O4D 2.394(6) .
Eu1 O3D 2.394(5) .
Eu1 O1D 2.410(5) .
Eu1 N4C 2.523(6) .
Eu1 N3L 2.576(5) .
Eu1 N1L 2.596(6) .
Eu1 N7A 2.616(6) .
Eu1 N2L 2.629(5) .
Eu2 O6D 2.358(4) .
Eu2 O8D 2.382(4) .
Eu2 O5D 2.396(4) .
Eu2 O7D 2.429(4) .
Eu2 N4L 2.571(5) .
Eu2 N6L 2.589(5) .
Eu2 N4A 2.602(6) .
Eu2 N7B 2.616(6) .
Eu2 N5L 2.653(5) .
Eu3 O10D 2.325(5) .
Eu3 O11D 2.355(6) .
Eu3 O9D 2.428(5) .
Eu3 O12D 2.434(5) .
Eu3 N1C 2.539(6) .
Eu3 N7L 2.590(5) .
Eu3 N1B 2.602(6) .
Eu3 N9L 2.616(6) .
Eu3 N8L 2.637(6) .
O1L C3L 1.347(8) .
O1L C2L 1.468(9) .
O2L C9L 1.349(8) .
O2L C10L 1.449(9) .
O3L C20L 1.346(8) .
O3L C19L 1.452(8) .
O4L C26L 1.357(8) .
O4L C27L 1.498(8) .
O5L C37L 1.336(8) .
O5L C36L 1.436(10) .
O6L C43L 1.355(8) .
O6L C44L 1.462(9) .
O1D C1D 1.235(8) .
O3D C7D 1.271(9) .
O4D C10D 1.182(12) .
O5D C13D 1.254(8) .
O6D C16D 1.249(8) .
O7D C19D 1.260(8) .
O8D C22D 1.270(8) .
O9D C25D 1.219(11) .
O10D C28D 1.256(8) .
O11D C31D 1.212(11) .
O1S C1S 1.152(18) .
N1A C1A 1.166(9) .
N2A C2A 1.133(8) .
N3A C3A 1.147(9) .
N4A C4A 1.165(8) .
N5A C5A 1.157(9) .
N6A C6A 1.162(9) .
N7A C7A 1.145(8) .
N8A C8A 1.159(9) .
N1B C1B 1.150(9) .
N2B C2B 1.159(9) .
N3B C3B 1.142(9) .
N4B C4B 1.133(9) .
N5B C5B 1.144(8) .
N6B C6B 1.156(9) .
N7B C7B 1.139(8) .
N8B C8B 1.154(9) .
N1C C1C 1.163(9) .
N2C C2C 1.175(11) .
N3C C3C 1.140(9) .
N4C C4C 1.159(9) .
N5C C5C 1.172(11) .
N6C C6C 1.153(10) .
N7C C7C 1.159(11) .
N8C C8C 1.138(11) .
N1L C3L 1.263(9) .
N1L C1L 1.506(9) .
N2L C4L 1.341(9) .
N2L C8L 1.342(9) .
N3L C9L 1.289(9) .
N3L C11L 1.497(9) .
N4L C20L 1.276(8) .
N4L C18L 1.494(8) .
N5L C21L 1.321(8) .
N5L C25L 1.353(8) .
N6L C26L 1.270(8) .
N6L C28L 1.481(8) .
N7L C37L 1.266(9) .
N7L C35L 1.505(9) .
N8L C42L 1.328(9) .
N8L C38L 1.353(9) .
N9L C43L 1.295(9) .
N9L C45L 1.503(8) .
N1D C1D 1.337(9) .
N1D C2D 1.458(9) .
N1D C3D 1.469(9) .
N3D C7D 1.312(9) .
N3D C8D 1.433(10) .
N3D C9D 1.488(10) .
N4D C10D 1.372(17) .
N4D C12D 1.448(17) .
N4D C11D 1.555(19) .
N5D C13D 1.325(9) .
N5D C14D 1.447(8) .
N5D C15D 1.471(9) .
N6D C16D 1.329(8) .
N6D C18D 1.437(9) .
N6D C17D 1.469(8) .
N7D C19D 1.330(8) .
N7D C21D 1.438(8) .
N7D C20D 1.473(9) .
N8D C22D 1.305(9) .
N8D C23D 1.447(9) .
N8D C24D 1.462(10) .
N9D C25D 1.293(12) .
N9D C26D 1.429(15) .
N9D C27D 1.490(13) .
N10D C28D 1.290(10) .
N10D C29D 1.482(12) .
N10D C30D 1.491(10) .
N11D C31D 1.298(15) .
N11D C33D 1.487(9) .
N11D C32D 1.52(2) .
N1S C3S 1.314(16) .
N1S C1S 1.414(19) .
N1S C2S 1.421(15) .
C4C W3 2.155(8) 1_656
C1L C12L 1.518(11) .
C1L C2L 1.527(10) .
C1L H1L 1.0000 .
C2L H2L1 0.9900 .
C2L H2L2 0.9900 .
C3L C4L 1.464(11) .
C4L C5L 1.406(10) .
C5L C6L 1.395(11) .
C5L H5L 0.9500 .
C6L C7L 1.382(12) .
C6L H6L 0.9500 .
C7L C8L 1.386(10) .
C7L H7L 0.9500 .
C8L C9L 1.469(10) .
C10L C11L 1.545(10) .
C10L H10A 0.9900 .
C10L H10B 0.9900 .
C11L C15L 1.549(10) .
C11L H11L 1.0000 .
C12L C14L 1.533(11) .
C12L C13L 1.556(10) .
C12L H12L 1.0000 .
C13L H13A 0.9800 .
C13L H13B 0.9800 .
C13L H13C 0.9800 .
C14L H4A 0.9800 .
C14L H4B 0.9800 .
C14L H4C 0.9800 .
C15L C17L 1.534(11) .
C15L C16L 1.535(12) .
C15L H15L 1.0000 .
C16L H16A 0.9800 .
C16L H16B 0.9800 .
C16L H16C 0.9800 .
C17L H7A 0.9800 .
C17L H7B 0.9800 .
C17L H7C 0.9800 .
C18L C29L 1.526(9) .
C18L C19L 1.561(9) .
C18L H18L 1.0000 .
C19L H19A 0.9900 .
C19L H19B 0.9900 .
C20L C21L 1.481(9) .
C21L C22L 1.399(8) .
C22L C23L 1.385(10) .
C22L H22L 0.9500 .
C23L C24L 1.398(10) .
C23L H23L 0.9500 .
C24L C25L 1.393(9) .
C24L H24L 0.9500 .
C25L C26L 1.445(9) .
C27L C28L 1.523(9) .
C27L H27A 0.9900 .
C27L H27B 0.9900 .
C28L C32L 1.537(9) .
C28L H28L 1.0000 .
C29L C31L 1.530(9) .
C29L C30L 1.535(10) .
C29L H29L 1.0000 .
C30L H30A 0.9800 .
C30L H30B 0.9800 .
C30L H30C 0.9800 .
C31L H31A 0.9800 .
C31L H31B 0.9800 .
C31L H31C 0.9800 .
C32L C33L 1.514(9) .
C32L C34L 1.517(9) .
C32L H32L 1.0000 .
C33L H33A 0.9800 .
C33L H33B 0.9800 .
C33L H33C 0.9800 .
C34L H34A 0.9800 .
C34L H34B 0.9800 .
C34L H34C 0.9800 .
C35L C46L 1.496(12) .
C35L C36L 1.535(10) .
C35L H35L 1.0000 .
C36L H36A 0.9900 .
C36L H36B 0.9900 .
C37L C38L 1.479(11) .
C38L C39L 1.374(10) .
C39L C40L 1.388(11) .
C39L H39L 0.9500 .
C40L C41L 1.387(11) .
C40L H40L 0.9500 .
C41L C42L 1.379(10) .
C41L H41L 0.9500 .
C42L C43L 1.467(10) .
C44L C45L 1.571(10) .
C44L H44A 0.9900 .
C44L H44B 0.9900 .
C45L C49L 1.492(10) .
C45L H45L 1.0000 .
C46L C47L 1.549(12) .
C46L C48L 1.562(16) .
C46L H46L 1.0000 .
C47L H47A 0.9800 .
C47L H47B 0.9800 .
C47L H47C 0.9800 .
C48L H48A 0.9800 .
C48L H48B 0.9800 .
C48L H48C 0.9800 .
C49L C50L 1.539(10) .
C49L C51L 1.554(12) .
C49L H49L 1.0000 .
C50L H50A 0.9800 .
C50L H50B 0.9800 .
C50L H50C 0.9800 .
C51L H51A 0.9800 .
C51L H51B 0.9800 .
C51L H51C 0.9800 .
C2D H2D1 0.9800 .
C2D H2D2 0.9800 .
C2D H2D3 0.9800 .
C3D H3D1 0.9800 .
C3D H3D2 0.9800 .
C3D H3D3 0.9800 .
C8D H8D1 0.9800 .
C8D H8D2 0.9800 .
C8D H8D3 0.9800 .
C9D H9D1 0.9800 .
C9D H9D2 0.9800 .
C9D H9D3 0.9800 .
C11D H11A 0.9800 .
C11D H11B 0.9800 .
C11D H11C 0.9800 .
C12D H12A 0.9800 .
C12D H12B 0.9800 .
C12D H12C 0.9800 .
C14D H14A 0.9800 .
C14D H14B 0.9800 .
C14D H14C 0.9800 .
C15D H15A 0.9800 .
C15D H15B 0.9800 .
C15D H15C 0.9800 .
C17D H17A 0.9800 .
C17D H17B 0.9800 .
C17D H17C 0.9800 .
C18D H18A 0.9800 .
C18D H18B 0.9800 .
C18D H18C 0.9800 .
C20D H20A 0.9800 .
C20D H20B 0.9800 .
C20D H20C 0.9800 .
C21D H21A 0.9800 .
C21D H21B 0.9800 .
C21D H21C 0.9800 .
C23D H23A 0.9800 .
C23D H23B 0.9800 .
C23D H23C 0.9800 .
C24D H24A 0.9800 .
C24D H24B 0.9800 .
C24D H24C 0.9800 .
C26D H26A 0.9800 .
C26D H26B 0.9800 .
C26D H26C 0.9800 .
C27D H27C 0.9800 .
C27D H27D 0.9800 .
C27D H27E 0.9800 .
C29D H29A 0.9800 .
C29D H29B 0.9800 .
C29D H29C 0.9800 .
C30D H30D 0.9800 .
C30D H30E 0.9800 .
C30D H30F 0.9800 .
C32D H32A 0.9800 .
C32D H32B 0.9800 .
C32D H32C 0.9800 .
C33D H33D 0.9800 .
C33D H33E 0.9800 .
C33D H33F 0.9800 .
O2D C4D 1.298(11) .
O2D C4E 1.30(4) .
N2D C4D 1.266(13) .
N2D C5E 1.36(4) .
N2D C6D 1.434(16) .
N2D C5D 1.539(18) .
N2D C4E 1.58(4) .
N2D C6E 1.70(4) .
C5D H5D1 0.9800 .
C5D H5D2 0.9800 .
C5D H5D3 0.9800 .
C6D H6D1 0.9800 .
C6D H6D2 0.9800 .
C6D H6D3 0.9800 .
C5E H5E1 0.9800 .
C5E H5E2 0.9800 .
C5E H5E3 0.9800 .
C6E H6E1 0.9800 .
C6E H6E2 0.9800 .
C6E H6E3 0.9800 .
O12D C34D 1.20(2) .
O12D C34E 1.225(12) .
N12D C34E 1.334(13) .
N12D C34D 1.33(2) .
N12D C35D 1.43(3) .
N12D C35E 1.448(13) .
N12D C36D 1.46(3) .
N12D C36E 1.473(12) .
C35D H35A 0.9800 .
C35D H35B 0.9800 .
C35D H35C 0.9800 .
C36D H36C 0.9800 .
C36D H36D 0.9800 .
C36D H36E 0.9800 .
C35E H35D 0.9800 .
C35E H35E 0.9800 .
C35E H35F 0.9800 .
C36E H36F 0.9800 .
C36E H36G 0.9800 .
C36E H36H 0.9800 .
C2S H2S1 0.9800 .
C2S H2S2 0.9800 .
C2S H2S3 0.9800 .
C3S H3S1 0.9800 .
C3S H3S2 0.9800 .
C3S H3S3 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
O2D Eu1 O1D C1D 27.0(7)
O4D Eu1 O1D C1D -178.3(6)
O3D Eu1 O1D C1D -45.1(8)
N4C Eu1 O1D C1D 74.6(7)
N3L Eu1 O1D C1D -116.8(7)
N1L Eu1 O1D C1D 114.1(7)
N7A Eu1 O1D C1D -46.7(6)
N2L Eu1 O1D C1D 179.6(7)
O2D Eu1 O3D C7D 17.8(6)
O4D Eu1 O3D C7D -125.8(6)
O1D Eu1 O3D C7D 86.9(6)
N4C Eu1 O3D C7D -53.2(6)
N3L Eu1 O3D C7D 158.6(6)
N1L Eu1 O3D C7D -60.3(7)
N7A Eu1 O3D C7D 88.4(6)
N2L Eu1 O3D C7D -162.6(6)
O2D Eu1 O4D C10D -28.7(13)
O3D Eu1 O4D C10D 42.1(12)
O1D Eu1 O4D C10D -166.9(11)
N4C Eu1 O4D C10D -32.2(12)
N3L Eu1 O4D C10D 128.4(12)
N1L Eu1 O4D C10D -102.2(12)
N7A Eu1 O4D C10D 89.8(12)
N2L Eu1 O4D C10D -164.7(12)
O6D Eu2 O5D C13D 16.0(7)
O8D Eu2 O5D C13D 171.7(6)
O7D Eu2 O5D C13D -51.4(7)
N4L Eu2 O5D C13D -131.1(7)
N6L Eu2 O5D C13D 99.5(7)
N4A Eu2 O5D C13D 62.9(7)
N7B Eu2 O5D C13D -57.9(7)
N5L Eu2 O5D C13D 164.5(7)
O8D Eu2 O6D C16D 102.3(7)
O5D Eu2 O6D C16D -104.1(7)
O7D Eu2 O6D C16D 39.4(7)
N4L Eu2 O6D C16D -47.3(8)
N6L Eu2 O6D C16D 177.3(7)
N4A Eu2 O6D C16D 109.4(7)
N7B Eu2 O6D C16D -31.4(7)
N5L Eu2 O6D C16D -146.6(6)
O6D Eu2 O7D C19D 17.2(5)
O8D Eu2 O7D C19D -126.8(5)
O5D Eu2 O7D C19D 82.3(6)
N4L Eu2 O7D C19D 157.7(5)
N6L Eu2 O7D C19D -54.7(6)
N4A Eu2 O7D C19D -53.8(5)
N7B Eu2 O7D C19D 88.8(5)
N5L Eu2 O7D C19D -156.0(5)
O6D Eu2 O8D C22D -39.3(7)
O5D Eu2 O8D C22D 179.5(6)
O7D Eu2 O8D C22D 26.3(6)
N4L Eu2 O8D C22D 121.3(6)
N6L Eu2 O8D C22D -112.2(6)
N4A Eu2 O8D C22D -46.5(6)
N7B Eu2 O8D C22D 73.7(7)
N5L Eu2 O8D C22D -173.4(7)
O10D Eu3 O9D C25D 98.4(10)
O11D Eu3 O9D C25D 26.3(11)
O12D Eu3 O9D C25D -106.9(10)
N1C Eu3 O9D C25D 25.1(9)
N7L Eu3 O9D C25D -47.2(9)
N1B Eu3 O9D C25D 148.9(9)
N9L Eu3 O9D C25D -177.3(10)
N8L Eu3 O9D C25D -111.1(10)
O11D Eu3 O10D C28D 95.3(11)
O9D Eu3 O10D C28D -48.1(11)
O12D Eu3 O10D C28D 159.7(10)
N1C Eu3 O10D C28D 23.9(11)
N7L Eu3 O10D C28D 16.5(12)
N1B Eu3 O10D C28D 167.0(11)
N9L Eu3 O10D C28D -123.0(11)
N8L Eu3 O10D C28D -88.4(11)
O10D Eu3 O11D C31D 82.3(11)
O9D Eu3 O11D C31D 152.9(10)
O12D Eu3 O11D C31D -59.8(10)
N1C Eu3 O11D C31D 154.1(11)
N7L Eu3 O11D C31D -135.2(11)
N1B Eu3 O11D C31D 11.5(10)
N9L Eu3 O11D C31D 9.6(12)
N8L Eu3 O11D C31D -93.9(11)
O6D Eu2 N7B C7B -43(2)
O8D Eu2 N7B C7B 175(2)
O5D Eu2 N7B C7B 41(2)
O7D Eu2 N7B C7B -135(3)
N4L Eu2 N7B C7B 126(3)
N6L Eu2 N7B C7B 5(3)
N4A Eu2 N7B C7B -90(2)
N5L Eu2 N7B C7B 88(2)
O10D Eu3 N1C C1C -55(3)
O11D Eu3 N1C C1C -147(3)
O9D Eu3 N1C C1C 33(3)
O12D Eu3 N1C C1C 165(3)
N7L Eu3 N1C C1C 121(3)
N1B Eu3 N1C C1C -100(3)
N9L Eu3 N1C C1C -1(3)
N8L Eu3 N1C C1C 78(3)
O2D Eu1 N1L C3L 159.8(6)
O4D Eu1 N1L C3L -57.3(6)
O3D Eu1 N1L C3L -121.2(5)
O1D Eu1 N1L C3L 80.1(6)
N4C Eu1 N1L C3L -128.4(6)
N3L Eu1 N1L C3L 8.9(6)
N7A Eu1 N1L C3L 109.2(6)
N2L Eu1 N1L C3L 9.2(5)
O2D Eu1 N1L C1L -28.2(6)
O4D Eu1 N1L C1L 114.6(6)
O3D Eu1 N1L C1L 50.8(7)
O1D Eu1 N1L C1L -107.9(6)
N4C Eu1 N1L C1L 43.6(6)
N3L Eu1 N1L C1L -179.2(6)
N7A Eu1 N1L C1L -78.9(7)
N2L Eu1 N1L C1L -178.9(7)
O2D Eu1 N2L C4L -52.5(6)
O4D Eu1 N2L C4L 88.2(5)
O3D Eu1 N2L C4L 128.0(5)
O1D Eu1 N2L C4L -93.5(5)
N4C Eu1 N2L C4L 37.4(6)
N3L Eu1 N2L C4L 172.4(6)
N1L Eu1 N2L C4L -7.3(5)
N7A Eu1 N2L C4L -142.7(5)
O2D Eu1 N2L C8L 134.8(5)
O4D Eu1 N2L C8L -84.4(5)
O3D Eu1 N2L C8L -44.7(6)
O1D Eu1 N2L C8L 93.9(5)
N4C Eu1 N2L C8L -135.2(5)
N3L Eu1 N2L C8L -0.3(5)
N1L Eu1 N2L C8L -180.0(6)
N7A Eu1 N2L C8L 44.7(6)
O2D Eu1 N3L C9L -127.8(5)
O4D Eu1 N3L C9L 74.4(5)
O3D Eu1 N3L C9L 154.4(5)
O1D Eu1 N3L C9L -64.1(5)
N4C Eu1 N3L C9L 103.5(5)
N1L Eu1 N3L C9L 3.8(6)
N7A Eu1 N3L C9L -134.2(5)
N2L Eu1 N3L C9L 3.5(5)
O2D Eu1 N3L C11L 54.9(7)
O4D Eu1 N3L C11L -102.9(6)
O3D Eu1 N3L C11L -22.9(6)
O1D Eu1 N3L C11L 118.6(6)
N4C Eu1 N3L C11L -73.8(7)
N1L Eu1 N3L C11L -173.5(5)
N7A Eu1 N3L C11L 48.5(6)
N2L Eu1 N3L C11L -173.8(6)
O6D Eu2 N4L C20L -125.5(5)
O8D Eu2 N4L C20L 74.1(5)
O5D Eu2 N4L C20L -69.1(5)
O7D Eu2 N4L C20L 150.1(5)
N6L Eu2 N4L C20L -3.0(6)
N4A Eu2 N4L C20L 93.8(5)
N7B Eu2 N4L C20L -141.4(5)
N5L Eu2 N4L C20L 1.6(5)
O6D Eu2 N4L C18L 49.7(6)
O8D Eu2 N4L C18L -110.8(5)
O5D Eu2 N4L C18L 106.1(5)
O7D Eu2 N4L C18L -34.7(5)
N6L Eu2 N4L C18L 172.2(5)
N4A Eu2 N4L C18L -91.0(6)
N7B Eu2 N4L C18L 33.7(5)
N5L Eu2 N4L C18L 176.8(6)
O6D Eu2 N5L C21L 134.6(5)
O8D Eu2 N5L C21L -85.6(5)
O5D Eu2 N5L C21L 89.1(5)
O7D Eu2 N5L C21L -54.8(6)
N4L Eu2 N5L C21L -0.2(5)
N6L Eu2 N5L C21L 175.6(5)
N4A Eu2 N5L C21L -140.5(5)
N7B Eu2 N5L C21L 41.3(5)
O6D Eu2 N5L C25L -46.7(6)
O8D Eu2 N5L C25L 93.1(5)
O5D Eu2 N5L C25L -92.2(5)
O7D Eu2 N5L C25L 123.9(5)
N4L Eu2 N5L C25L 178.5(5)
N6L Eu2 N5L C25L -5.7(4)
N4A Eu2 N5L C25L 38.3(5)
N7B Eu2 N5L C25L -140.0(5)
O6D Eu2 N6L C26L 160.1(5)
O8D Eu2 N6L C26L -58.4(5)
O5D Eu2 N6L C26L 80.3(5)
O7D Eu2 N6L C26L -126.4(5)
N4L Eu2 N6L C26L 13.0(5)
N4A Eu2 N6L C26L -127.4(5)
N7B Eu2 N6L C26L 114.7(5)
N5L Eu2 N6L C26L 8.5(5)
O6D Eu2 N6L C28L -25.4(5)
O8D Eu2 N6L C28L 116.2(5)
O5D Eu2 N6L C28L -105.2(5)
O7D Eu2 N6L C28L 48.1(6)
N4L Eu2 N6L C28L -172.4(5)
N4A Eu2 N6L C28L 47.1(5)
N7B Eu2 N6L C28L -70.7(6)
N5L Eu2 N6L C28L -177.0(6)
O10D Eu3 N7L C37L -129.7(5)
O11D Eu3 N7L C37L 151.6(6)
O9D Eu3 N7L C37L -65.3(6)
O12D Eu3 N7L C37L 74.5(6)
N1C Eu3 N7L C37L -137.2(6)
N1B Eu3 N7L C37L 96.9(6)
N9L Eu3 N7L C37L -1.5(6)
N8L Eu3 N7L C37L 1.4(5)
O10D Eu3 N7L C35L 44.0(8)
O11D Eu3 N7L C35L -34.6(6)
O9D Eu3 N7L C35L 108.5(6)
O12D Eu3 N7L C35L -111.8(6)
N1C Eu3 N7L C35L 36.6(6)
N1B Eu3 N7L C35L -89.3(7)
N9L Eu3 N7L C35L 172.3(6)
N8L Eu3 N7L C35L 175.2(7)
O10D Eu3 N8L C42L -36.1(7)
O11D Eu3 N8L C42L 138.5(5)
O9D Eu3 N8L C42L -80.6(6)
O12D Eu3 N8L C42L 102.6(6)
N1C Eu3 N8L C42L -128.6(5)
N7L Eu3 N8L C42L -173.8(6)
N1B Eu3 N8L C42L 50.1(6)
N9L Eu3 N8L C42L 3.5(5)
O10D Eu3 N8L C38L 136.3(5)
O11D Eu3 N8L C38L -49.2(6)
O9D Eu3 N8L C38L 91.7(5)
O12D Eu3 N8L C38L -85.1(5)
N1C Eu3 N8L C38L 43.8(6)
N7L Eu3 N8L C38L -1.5(5)
N1B Eu3 N8L C38L -137.5(5)
N9L Eu3 N8L C38L 175.8(6)
O10D Eu3 N9L C43L 153.3(6)
O11D Eu3 N9L C43L -132.7(5)
O9D Eu3 N9L C43L 70.1(5)
O12D Eu3 N9L C43L -67.0(5)
N1C Eu3 N9L C43L 102.6(6)
N7L Eu3 N9L C43L 2.7(6)
N1B Eu3 N9L C43L -134.7(6)
N8L Eu3 N9L C43L -0.2(5)
O10D Eu3 N9L C45L -24.0(6)
O11D Eu3 N9L C45L 50.0(7)
O9D Eu3 N9L C45L -107.1(6)
O12D Eu3 N9L C45L 115.8(6)
N1C Eu3 N9L C45L -74.7(7)
N7L Eu3 N9L C45L -174.6(6)
N1B Eu3 N9L C45L 48.0(6)
N8L Eu3 N9L C45L -177.5(7)
C3L N1L C1L C12L -109.6(7)
Eu1 N1L C1L C12L 77.7(7)
C3L N1L C1L C2L 14.5(7)
Eu1 N1L C1L C2L -158.1(5)
C3L O1L C2L C1L 15.7(7)
N1L C1L C2L O1L -18.2(7)
C12L C1L C2L O1L 102.1(7)
C1L N1L C3L O1L -5.2(9)
Eu1 N1L C3L O1L 168.9(5)
C1L N1L C3L C4L 174.7(7)
Eu1 N1L C3L C4L -11.2(10)
C2L O1L C3L N1L -7.1(9)
C2L O1L C3L C4L 172.9(6)
C8L N2L C4L C5L -0.6(10)
Eu1 N2L C4L C5L -173.4(5)
C8L N2L C4L C3L 178.1(6)
Eu1 N2L C4L C3L 5.3(8)
N1L C3L C4L N2L 4.0(11)
O1L C3L C4L N2L -176.1(6)
N1L C3L C4L C5L -177.3(7)
O1L C3L C4L C5L 2.6(11)
N2L C4L C5L C6L -0.3(11)
C3L C4L C5L C6L -178.8(7)
C4L C5L C6L C7L 0.9(12)
C5L C6L C7L C8L -0.6(11)
C4L N2L C8L C7L 1.0(11)
Eu1 N2L C8L C7L 173.7(5)
C4L N2L C8L C9L -175.3(6)
Eu1 N2L C8L C9L -2.5(8)
C6L C7L C8L N2L -0.3(11)
C6L C7L C8L C9L 175.5(7)
C11L N3L C9L O2L -7.5(8)
Eu1 N3L C9L O2L 174.6(4)
C11L N3L C9L C8L 171.2(6)
Eu1 N3L C9L C8L -6.8(9)
C10L O2L C9L N3L -4.7(8)
C10L O2L C9L C8L 176.6(6)
N2L C8L C9L N3L 6.2(10)
C7L C8L C9L N3L -170.0(7)
N2L C8L C9L O2L -175.2(6)
C7L C8L C9L O2L 8.6(10)
C9L O2L C10L C11L 14.1(7)
C9L N3L C11L C10L 15.1(7)
Eu1 N3L C11L C10L -167.4(5)
C9L N3L C11L C15L -106.4(7)
Eu1 N3L C11L C15L 71.2(7)
O2L C10L C11L N3L -17.5(7)
O2L C10L C11L C15L 100.1(7)
N1L C1L C12L C14L -173.6(6)
C2L C1L C12L C14L 70.5(8)
N1L C1L C12L C13L 62.5(8)
C2L C1L C12L C13L -53.4(9)
N3L C11L C15L C17L -174.6(6)
C10L C11L C15L C17L 72.9(9)
N3L C11L C15L C16L 61.1(8)
C10L C11L C15L C16L -51.5(9)
C20L N4L C18L C29L -124.2(6)
Eu2 N4L C18L C29L 60.2(7)
C20L N4L C18L C19L -0.8(7)
Eu2 N4L C18L C19L -176.5(4)
C20L O3L C19L C18L -2.2(7)
N4L C18L C19L O3L 1.8(7)
C29L C18L C19L O3L 122.4(6)
C18L N4L C20L O3L -0.6(8)
Eu2 N4L C20L O3L 175.7(4)
C18L N4L C20L C21L -179.3(6)
Eu2 N4L C20L C21L -3.0(9)
C19L O3L C20L N4L 1.9(8)
C19L O3L C20L C21L -179.4(6)
C25L N5L C21L C22L -0.6(10)
Eu2 N5L C21L C22L 178.2(5)
C25L N5L C21L C20L -179.7(6)
Eu2 N5L C21L C20L -1.0(7)
N4L C20L C21L N5L 2.7(9)
O3L C20L C21L N5L -176.0(6)
N4L C20L C21L C22L -176.5(7)
O3L C20L C21L C22L 4.8(10)
N5L C21L C22L C23L 1.5(11)
C20L C21L C22L C23L -179.4(7)
C21L C22L C23L C24L -0.8(11)
C22L C23L C24L C25L -0.6(12)
C21L N5L C25L C24L -1.0(10)
Eu2 N5L C25L C24L -179.8(5)
C21L N5L C25L C26L -178.3(6)
Eu2 N5L C25L C26L 3.0(7)
C23L C24L C25L N5L 1.6(11)
C23L C24L C25L C26L 178.5(7)
C28L N6L C26L O4L -7.5(8)
Eu2 N6L C26L O4L 168.3(4)
C28L N6L C26L C25L 172.6(6)
Eu2 N6L C26L C25L -11.5(9)
C27L O4L C26L N6L -4.4(8)
C27L O4L C26L C25L 175.5(6)
N5L C25L C26L N6L 5.7(10)
C24L C25L C26L N6L -171.4(7)
N5L C25L C26L O4L -174.2(6)
C24L C25L C26L O4L 8.7(10)
C26L O4L C27L C28L 13.7(7)
C26L N6L C28L C27L 15.6(7)
Eu2 N6L C28L C27L -159.4(5)
C26L N6L C28L C32L -107.2(6)
Eu2 N6L C28L C32L 77.9(6)
O4L C27L C28L N6L -17.4(7)
O4L C27L C28L C32L 102.5(6)
N4L C18L C29L C31L 59.5(7)
C19L C18L C29L C31L -56.5(8)
N4L C18L C29L C30L -175.2(5)
C19L C18L C29L C30L 68.8(7)
N6L C28L C32L C33L -175.5(5)
C27L C28L C32L C33L 68.6(7)
N6L C28L C32L C34L 59.2(7)
C27L C28L C32L C34L -56.7(8)
C37L N7L C35L C46L -130.8(8)
Eu3 N7L C35L C46L 54.9(9)
C37L N7L C35L C36L -4.2(8)
Eu3 N7L C35L C36L -178.5(6)
C37L O5L C36L C35L -3.0(10)
C46L C35L C36L O5L 128.5(8)
N7L C35L C36L O5L 4.3(9)
C35L N7L C37L O5L 2.7(9)
Eu3 N7L C37L O5L 178.0(5)
C35L N7L C37L C38L -176.6(7)
Eu3 N7L C37L C38L -1.3(10)
C36L O5L C37L N7L 0.2(10)
C36L O5L C37L C38L 179.6(7)
C42L N8L C38L C39L -2.5(11)
Eu3 N8L C38L C39L -175.3(6)
C42L N8L C38L C37L 174.2(6)
Eu3 N8L C38L C37L 1.5(8)
N7L C37L C38L N8L -0.1(11)
O5L C37L C38L N8L -179.4(6)
N7L C37L C38L C39L 176.6(7)
O5L C37L C38L C39L -2.7(11)
N8L C38L C39L C40L 1.2(12)
C37L C38L C39L C40L -175.2(7)
C38L C39L C40L C41L 0.8(12)
C39L C40L C41L C42L -1.3(12)
C38L N8L C42L C41L 2.0(11)
Eu3 N8L C42L C41L 174.6(6)
C38L N8L C42L C43L -178.4(6)
Eu3 N8L C42L C43L -5.8(8)
C40L C41L C42L N8L -0.1(12)
C40L C41L C42L C43L -179.8(7)
C45L N9L C43L O6L -2.8(9)
Eu3 N9L C43L O6L 179.3(5)
C45L N9L C43L C42L 175.2(7)
Eu3 N9L C43L C42L -2.7(9)
C44L O6L C43L N9L -6.4(9)
C44L O6L C43L C42L 175.4(6)
N8L C42L C43L N9L 5.6(11)
C41L C42L C43L N9L -174.7(7)
N8L C42L C43L O6L -176.3(6)
C41L C42L C43L O6L 3.3(11)
C43L O6L C44L C45L 12.1(7)
C43L N9L C45L C49L -114.1(7)
Eu3 N9L C45L C49L 63.4(8)
C43L N9L C45L C44L 9.9(7)
Eu3 N9L C45L C44L -172.6(5)
O6L C44L C45L C49L 107.9(7)
O6L C44L C45L N9L -13.2(7)
N7L C35L C46L C47L -175.0(7)
C36L C35L C46L C47L 66.8(11)
N7L C35L C46L C48L 60.3(9)
C36L C35L C46L C48L -57.9(10)
N9L C45L C49L C50L -178.8(6)
C44L C45L C49L C50L 65.3(9)
N9L C45L C49L C51L 58.0(8)
C44L C45L C49L C51L -57.9(9)
Eu1 O1D C1D N1D 138.8(6)
C2D N1D C1D O1D 175.9(6)
C3D N1D C1D O1D -5.8(10)
Eu1 O3D C7D N3D -138.6(6)
C8D N3D C7D O3D 6.2(12)
C9D N3D C7D O3D 174.9(7)
Eu1 O4D C10D N4D 136.9(10)
C12D N4D C10D O4D -176.7(13)
C11D N4D C10D O4D -12(2)
Eu2 O5D C13D N5D 138.1(5)
C14D N5D C13D O5D 175.2(6)
C15D N5D C13D O5D -4.2(10)
Eu2 O6D C16D N6D -149.7(5)
C18D N6D C16D O6D 3.5(11)
C17D N6D C16D O6D -173.1(7)
Eu2 O7D C19D N7D -140.0(5)
C21D N7D C19D O7D 178.5(6)
C20D N7D C19D O7D 3.5(10)
Eu2 O8D C22D N8D 137.7(5)
C23D N8D C22D O8D 176.2(6)
C24D N8D C22D O8D -4.4(11)
Eu3 O9D C25D N9D 148.0(9)
C26D N9D C25D O9D 177.6(13)
C27D N9D C25D O9D 0.3(19)
Eu3 O10D C28D N10D -166.4(7)
C29D N10D C28D O10D -1.9(15)
C30D N10D C28D O10D -179.8(8)
Eu3 O11D C31D N11D -166.0(9)
C33D N11D C31D O11D -18(2)
C32D N11D C31D O11D 171.6(14)
O4D Eu1 O2D C4D 114.2(10)
O3D Eu1 O2D C4D 46.3(10)
O1D Eu1 O2D C4D -95.4(10)
N4C Eu1 O2D C4D 117.8(10)
N3L Eu1 O2D C4D -30.2(11)
N1L Eu1 O2D C4D -172.6(10)
N7A Eu1 O2D C4D -23.9(10)
N2L Eu1 O2D C4D -133.4(10)
O4D Eu1 O2D C4E 7(2)
O3D Eu1 O2D C4E -61(2)
O1D Eu1 O2D C4E 157(2)
N4C Eu1 O2D C4E 10(2)
N3L Eu1 O2D C4E -138(2)
N1L Eu1 O2D C4E 80(2)
N7A Eu1 O2D C4E -132(2)
N2L Eu1 O2D C4E 119(2)
C5E N2D C4D O2D 166(2)
C6D N2D C4D O2D -16(2)
C5D N2D C4D O2D -171.2(12)
C4E N2D C4D O2D 17.4(17)
C6E N2D C4D O2D 69(4)
C4E O2D C4D N2D -20(2)
Eu1 O2D C4D N2D -147.9(9)
C4D O2D C4E N2D 14.0(13)
Eu1 O2D C4E N2D 153.0(10)
C4D N2D C4E O2D -15.3(15)
C5E N2D C4E O2D -46(3)
C6D N2D C4E O2D 137(2)
C6E N2D C4E O2D -172(2)
O10D Eu3 O12D C34D -40(2)
O11D Eu3 O12D C34D 27(2)
O9D Eu3 O12D C34D 179(2)
N1C Eu3 O12D C34D 74(2)
N7L Eu3 O12D C34D 117(2)
N1B Eu3 O12D C34D -48(2)
N9L Eu3 O12D C34D -116(2)
N8L Eu3 O12D C34D -177(2)
O10D Eu3 O12D C34E 47.6(10)
O11D Eu3 O12D C34E 115.3(10)
O9D Eu3 O12D C34E -92.6(10)
N1C Eu3 O12D C34E 162.0(9)
N7L Eu3 O12D C34E -155.0(10)
N1B Eu3 O12D C34E 40.2(9)
N9L Eu3 O12D C34E -27.7(10)
N8L Eu3 O12D C34E -88.6(10)
C34E O12D C34D N12D 16.9(14)
Eu3 O12D C34D N12D 133.7(15)
C34E N12D C34D O12D -16.7(14)
C35D N12D C34D O12D -4(3)
C35E N12D C34D O12D -68(6)
C36D N12D C34D O12D -178(2)
C36E N12D C34D O12D 154(2)
C34D O12D C34E N12D -16.5(14)
Eu3 O12D C34E N12D -151.6(6)
C34D N12D C34E O12D 15.9(14)
C35D N12D C34E O12D -153.4(16)
C35E N12D C34E O12D -177.1(10)
C36D N12D C34E O12D 81(5)
C36E N12D C34E O12D 5.1(15)
C3S N1S C1S O1S -8(3)
C2S N1S C1S O1S -172.5(15)
