#------------------------------------------------------------------------------
#$Date: 2019-11-28 22:09:33 +0200 (Thu, 28 Nov 2019) $
#$Revision: 244766 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/95/7239551.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7239551
loop_
_publ_author_name
'Wang, Hai-Ning'
'Liu, Fu-Hong'
'Wang, Xin-Long'
'Shao, Kui-Zhan'
'Su, Zhong-Min'
_publ_section_title
;
 Three neutral metal--organic frameworks with micro- and meso-pores for
 adsorption and separation of dyes
;
_journal_issue                   42
_journal_name_full               'Journal of Materials Chemistry A'
_journal_page_first              13060
_journal_paper_doi               10.1039/c3ta13242k
_journal_volume                  1
_journal_year                    2013
_chemical_formula_moiety         'C408 H592 Cu24 N76 O196'
_chemical_formula_sum            'C408 H592 Cu24 N76 O196'
_chemical_formula_weight         11218.04
_space_group_IT_number           225
_space_group_name_Hall           '-F 4 2 3'
_space_group_name_H-M_alt        'F m -3 m'
_symmetry_cell_setting           cubic
_symmetry_space_group_name_H-M   'F m -3 m'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   40.0928(17)
_cell_length_b                   40.0928(17)
_cell_length_c                   40.0928(17)
_cell_measurement_reflns_used    82270
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.02
_cell_measurement_theta_min      1.44
_cell_volume                     64446(5)
_computing_cell_refinement       'SMART (Bruker, 1997)'
_computing_data_collection       'SMART (Bruker, 1997)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL-PLUS (Sheldrick, 1990)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97(Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX CCD area-detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0591
_diffrn_reflns_av_sigmaI/netI    0.0203
_diffrn_reflns_limit_h_max       46
_diffrn_reflns_limit_h_min       -47
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -47
_diffrn_reflns_limit_l_max       47
_diffrn_reflns_limit_l_min       -47
_diffrn_reflns_number            82270
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         1.44
_exptl_absorpt_coefficient_mu    0.852
_exptl_absorpt_correction_T_max  0.8758
_exptl_absorpt_correction_T_min  0.8414
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS(Sheldrick, 1996)'
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.156
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             23339
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_platon_squeeze_details
;
;
_refine_diff_density_max         0.590
_refine_diff_density_min         -0.393
_refine_diff_density_rms         0.051
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.085
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     86
_refine_ls_number_reflns         2824
_refine_ls_number_restraints     64
_refine_ls_restrained_S_all      1.557
_refine_ls_R_factor_all          0.0560
_refine_ls_R_factor_gt           0.0449
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0979P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1336
_refine_ls_wR_factor_ref         0.1399
_reflns_number_gt                2369
_reflns_number_total             2824
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            c3ta13242k.txt
_cod_data_source_block           2
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Cubic' was changed to
'cubic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/RSC/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_H-M      Fm-3m
_cod_database_code               7239551
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x, z'
'-x, -y, z'
'y, -x, z'
'x, -y, -z'
'y, x, -z'
'-x, y, -z'
'-y, -x, -z'
'z, x, y'
'-x, z, y'
'-z, -x, y'
'x, -z, y'
'z, -x, -y'
'x, z, -y'
'-z, x, -y'
'-x, -z, -y'
'y, z, x'
'-z, -y, -x'
'-z, y, x'
'z, y, -x'
'z, -y, x'
'y, -z, -x'
'-y, -z, x'
'-y, z, -x'
'x, y+1/2, z+1/2'
'-y, x+1/2, z+1/2'
'-x, -y+1/2, z+1/2'
'y, -x+1/2, z+1/2'
'x, -y+1/2, -z+1/2'
'y, x+1/2, -z+1/2'
'-x, y+1/2, -z+1/2'
'-y, -x+1/2, -z+1/2'
'z, x+1/2, y+1/2'
'-x, z+1/2, y+1/2'
'-z, -x+1/2, y+1/2'
'x, -z+1/2, y+1/2'
'z, -x+1/2, -y+1/2'
'x, z+1/2, -y+1/2'
'-z, x+1/2, -y+1/2'
'-x, -z+1/2, -y+1/2'
'y, z+1/2, x+1/2'
'-z, -y+1/2, -x+1/2'
'-z, y+1/2, x+1/2'
'z, y+1/2, -x+1/2'
'z, -y+1/2, x+1/2'
'y, -z+1/2, -x+1/2'
'-y, -z+1/2, x+1/2'
'-y, z+1/2, -x+1/2'
'x+1/2, y, z+1/2'
'-y+1/2, x, z+1/2'
'-x+1/2, -y, z+1/2'
'y+1/2, -x, z+1/2'
'x+1/2, -y, -z+1/2'
'y+1/2, x, -z+1/2'
'-x+1/2, y, -z+1/2'
'-y+1/2, -x, -z+1/2'
'z+1/2, x, y+1/2'
'-x+1/2, z, y+1/2'
'-z+1/2, -x, y+1/2'
'x+1/2, -z, y+1/2'
'z+1/2, -x, -y+1/2'
'x+1/2, z, -y+1/2'
'-z+1/2, x, -y+1/2'
'-x+1/2, -z, -y+1/2'
'y+1/2, z, x+1/2'
'-z+1/2, -y, -x+1/2'
'-z+1/2, y, x+1/2'
'z+1/2, y, -x+1/2'
'z+1/2, -y, x+1/2'
'y+1/2, -z, -x+1/2'
'-y+1/2, -z, x+1/2'
'-y+1/2, z, -x+1/2'
'x+1/2, y+1/2, z'
'-y+1/2, x+1/2, z'
'-x+1/2, -y+1/2, z'
'y+1/2, -x+1/2, z'
'x+1/2, -y+1/2, -z'
'y+1/2, x+1/2, -z'
'-x+1/2, y+1/2, -z'
'-y+1/2, -x+1/2, -z'
'z+1/2, x+1/2, y'
'-x+1/2, z+1/2, y'
'-z+1/2, -x+1/2, y'
'x+1/2, -z+1/2, y'
'z+1/2, -x+1/2, -y'
'x+1/2, z+1/2, -y'
'-z+1/2, x+1/2, -y'
'-x+1/2, -z+1/2, -y'
'y+1/2, z+1/2, x'
'-z+1/2, -y+1/2, -x'
'-z+1/2, y+1/2, x'
'z+1/2, y+1/2, -x'
'z+1/2, -y+1/2, x'
'y+1/2, -z+1/2, -x'
'-y+1/2, -z+1/2, x'
'-y+1/2, z+1/2, -x'
'-x, -y, -z'
'y, -x, -z'
'x, y, -z'
'-y, x, -z'
'-x, y, z'
'-y, -x, z'
'x, -y, z'
'y, x, z'
'-z, -x, -y'
'x, -z, -y'
'z, x, -y'
'-x, z, -y'
'-z, x, y'
'-x, -z, y'
'z, -x, y'
'x, z, y'
'-y, -z, -x'
'z, y, x'
'z, -y, -x'
'-z, -y, x'
'-z, y, -x'
'-y, z, x'
'y, z, -x'
'y, -z, x'
'-x, -y+1/2, -z+1/2'
'y, -x+1/2, -z+1/2'
'x, y+1/2, -z+1/2'
'-y, x+1/2, -z+1/2'
'-x, y+1/2, z+1/2'
'-y, -x+1/2, z+1/2'
'x, -y+1/2, z+1/2'
'y, x+1/2, z+1/2'
'-z, -x+1/2, -y+1/2'
'x, -z+1/2, -y+1/2'
'z, x+1/2, -y+1/2'
'-x, z+1/2, -y+1/2'
'-z, x+1/2, y+1/2'
'-x, -z+1/2, y+1/2'
'z, -x+1/2, y+1/2'
'x, z+1/2, y+1/2'
'-y, -z+1/2, -x+1/2'
'z, y+1/2, x+1/2'
'z, -y+1/2, -x+1/2'
'-z, -y+1/2, x+1/2'
'-z, y+1/2, -x+1/2'
'-y, z+1/2, x+1/2'
'y, z+1/2, -x+1/2'
'y, -z+1/2, x+1/2'
'-x+1/2, -y, -z+1/2'
'y+1/2, -x, -z+1/2'
'x+1/2, y, -z+1/2'
'-y+1/2, x, -z+1/2'
'-x+1/2, y, z+1/2'
'-y+1/2, -x, z+1/2'
'x+1/2, -y, z+1/2'
'y+1/2, x, z+1/2'
'-z+1/2, -x, -y+1/2'
'x+1/2, -z, -y+1/2'
'z+1/2, x, -y+1/2'
'-x+1/2, z, -y+1/2'
'-z+1/2, x, y+1/2'
'-x+1/2, -z, y+1/2'
'z+1/2, -x, y+1/2'
'x+1/2, z, y+1/2'
'-y+1/2, -z, -x+1/2'
'z+1/2, y, x+1/2'
'z+1/2, -y, -x+1/2'
'-z+1/2, -y, x+1/2'
'-z+1/2, y, -x+1/2'
'-y+1/2, z, x+1/2'
'y+1/2, z, -x+1/2'
'y+1/2, -z, x+1/2'
'-x+1/2, -y+1/2, -z'
'y+1/2, -x+1/2, -z'
'x+1/2, y+1/2, -z'
'-y+1/2, x+1/2, -z'
'-x+1/2, y+1/2, z'
'-y+1/2, -x+1/2, z'
'x+1/2, -y+1/2, z'
'y+1/2, x+1/2, z'
'-z+1/2, -x+1/2, -y'
'x+1/2, -z+1/2, -y'
'z+1/2, x+1/2, -y'
'-x+1/2, z+1/2, -y'
'-z+1/2, x+1/2, y'
'-x+1/2, -z+1/2, y'
'z+1/2, -x+1/2, y'
'x+1/2, z+1/2, y'
'-y+1/2, -z+1/2, -x'
'z+1/2, y+1/2, x'
'z+1/2, -y+1/2, -x'
'-z+1/2, -y+1/2, x'
'-z+1/2, y+1/2, -x'
'-y+1/2, z+1/2, x'
'y+1/2, z+1/2, -x'
'y+1/2, -z+1/2, x'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cu1 Cu 0.0000 0.359171(12) 0.140829(12) 0.0481(3) Uani 1 4 d S
Cu2 Cu 0.0000 0.312783(12) 0.187217(12) 0.0538(3) Uani 1 4 d S
O1 O 0.03459(6) 0.33126(6) 0.12055(6) 0.0666(7) Uani 1 1 d .
O2 O 0.03433(7) 0.29177(7) 0.15953(7) 0.0737(8) Uani 1 1 d .
O3 O 0.12025(15) 0.20957(17) 0.12025(15) 0.182(3) Uani 1 2 d SDU
H3A H 0.1351 0.2104 0.1343 0.218 Uiso 1 2 calc SRD
C1 C 0.04503(10) 0.30509(9) 0.13328(9) 0.0636(9) Uani 1 1 d .
C2 C 0.07348(11) 0.28767(10) 0.11599(11) 0.0766(12) Uani 1 1 d .
C3 C 0.08503(14) 0.25740(13) 0.12646(14) 0.1073(18) Uani 1 1 d U
H3 H 0.0749 0.2470 0.1445 0.129 Uiso 1 1 calc R
C4 C 0.11102(18) 0.2423(2) 0.11102(18) 0.126(3) Uani 1 2 d SDU
C5 C 0.08829(10) 0.30304(14) 0.08829(10) 0.0657(13) Uani 1 2 d S
H5 H 0.0799 0.3230 0.0799 0.079 Uiso 1 2 calc SR
N1 N 0.0000 0.27456(8) 0.22544(8) 0.0530(13) Uani 1 4 d S
C6 C 0.0000 0.24257(18) 0.21916(17) 0.114(2) Uani 1 2 d SU
H6 H 0.0000 0.2358 0.1970 0.137 Uiso 1 2 calc SR
O1W O 0.0000 0.39692(12) 0.10308(12) 0.135(3) Uani 1 4 d SDU
H1B H 0.0296 0.3987 0.1013 0.162 Uiso 0.50 2 d SPRD
H1A H 0.0000 0.4197 0.0933 0.162 Uiso 0.50 2 d SPRD
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0030 0.0020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3200 1.2650 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0060 0.0030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0110 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Cu1 O1 88.45(16) 101 40
O1 Cu1 O1 90.15(16) 101 .
O1 Cu1 O1 167.32(14) 40 .
O1 Cu1 O1 167.32(14) 101 130
O1 Cu1 O1 90.15(16) 40 130
O1 Cu1 O1 88.45(16) . 130
O1 Cu1 O1W 96.34(7) 101 .
O1 Cu1 O1W 96.34(7) 40 .
O1 Cu1 O1W 96.34(7) . .
O1 Cu1 O1W 96.34(7) 130 .
O1 Cu1 Cu2 83.66(7) 101 .
O1 Cu1 Cu2 83.66(7) 40 .
O1 Cu1 Cu2 83.66(7) . .
O1 Cu1 Cu2 83.66(7) 130 .
O1W Cu1 Cu2 180.00(19) . .
O2 Cu2 O2 168.93(14) 101 130
O2 Cu2 O2 89.30(18) 101 .
O2 Cu2 O2 89.63(18) 130 .
O2 Cu2 O2 89.63(18) 101 40
O2 Cu2 O2 89.30(18) 130 40
O2 Cu2 O2 168.93(14) . 40
O2 Cu2 N1 95.54(7) 101 .
O2 Cu2 N1 95.54(7) 130 .
O2 Cu2 N1 95.54(7) . .
O2 Cu2 N1 95.54(7) 40 .
O2 Cu2 Cu1 84.46(7) 101 .
O2 Cu2 Cu1 84.46(7) 130 .
O2 Cu2 Cu1 84.46(7) . .
O2 Cu2 Cu1 84.46(7) 40 .
N1 Cu2 Cu1 180.00(13) . .
C1 O1 Cu1 123.5(2) . .
C1 O2 Cu2 122.1(2) . .
C4 O3 H3A 109.5 . .
O1 C1 O2 126.1(4) . .
O1 C1 C2 117.3(3) . .
O2 C1 C2 116.6(3) . .
C3 C2 C5 119.4(4) . .
C3 C2 C1 121.8(4) . .
C5 C2 C1 118.8(3) . .
C4 C3 C2 121.2(5) . .
C4 C3 H3 119.4 . .
C2 C3 H3 119.4 . .
C3 C4 C3 120.2(7) 114 .
C3 C4 O3 119.8(4) 114 .
C3 C4 O3 119.8(4) . .
C2 C5 C2 118.5(5) 114 .
C2 C5 H5 120.7 114 .
C2 C5 H5 120.7 . .
C6 N1 C6 112.2(7) . 130
C6 N1 Cu2 123.9(3) . .
C6 N1 Cu2 123.9(3) 130 .
N1 C6 C6 123.9(3) . 10
N1 C6 H6 118.0 . .
C6 C6 H6 118.0 10 .
Cu1 O1W H1B 94.8 . .
Cu1 O1W H1A 158.2 . .
H1B O1W H1A 85.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu1 O1 1.958(2) 101
Cu1 O1 1.958(2) 40
Cu1 O1 1.958(2) .
Cu1 O1 1.958(2) 130
Cu1 O1W 2.141(7) .
Cu1 Cu2 2.6302(10) .
Cu2 O2 1.959(3) 101
Cu2 O2 1.959(3) 130
Cu2 O2 1.959(3) .
Cu2 O2 1.959(3) 40
Cu2 N1 2.167(5) .
O1 C1 1.240(4) .
O2 C1 1.256(4) .
O3 C4 1.412(9) .
O3 H3A 0.8200 .
C1 C2 1.506(6) .
C2 C3 1.365(6) .
C2 C5 1.402(4) .
C3 C4 1.355(6) .
C3 H3 0.9300 .
C4 C3 1.355(6) 114
C5 C2 1.402(4) 114
C5 H5 0.9300 .
N1 C6 1.307(7) .
N1 C6 1.307(7) 130
C6 C6 1.327(13) 10
C6 H6 0.9300 .
O1W H1B 1.1910 .
O1W H1A 0.9937 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 Cu1 Cu2 O2 0.51(12) 101 101
O1 Cu1 Cu2 O2 89.65(12) 40 101
O1 Cu1 Cu2 O2 -90.35(12) . 101
O1 Cu1 Cu2 O2 -179.49(12) 130 101
O1W Cu1 Cu2 O2 135(100) . 101
O1 Cu1 Cu2 O2 -179.49(12) 101 130
O1 Cu1 Cu2 O2 -90.35(12) 40 130
O1 Cu1 Cu2 O2 89.65(12) . 130
O1 Cu1 Cu2 O2 0.51(12) 130 130
O1W Cu1 Cu2 O2 -45(100) . 130
O1 Cu1 Cu2 O2 90.35(12) 101 .
O1 Cu1 Cu2 O2 179.49(12) 40 .
O1 Cu1 Cu2 O2 -0.51(12) . .
O1 Cu1 Cu2 O2 -89.65(12) 130 .
O1W Cu1 Cu2 O2 -135(100) . .
O1 Cu1 Cu2 O2 -89.65(12) 101 40
O1 Cu1 Cu2 O2 -0.51(12) 40 40
O1 Cu1 Cu2 O2 179.49(12) . 40
O1 Cu1 Cu2 O2 90.35(12) 130 40
O1W Cu1 Cu2 O2 45(100) . 40
O1 Cu1 Cu2 N1 -134.57(8) 101 .
O1 Cu1 Cu2 N1 -45.43(8) 40 .
O1 Cu1 Cu2 N1 134.57(8) . .
O1 Cu1 Cu2 N1 45.43(8) 130 .
O1W Cu1 Cu2 N1 0.0 . .
O1 Cu1 O1 C1 -84.8(3) 101 .
O1 Cu1 O1 C1 -1.2(3) 40 .
O1 Cu1 O1 C1 82.6(3) 130 .
O1W Cu1 O1 C1 178.8(3) . .
Cu2 Cu1 O1 C1 -1.2(3) . .
O2 Cu2 O2 C1 86.9(3) 101 .
O2 Cu2 O2 C1 -82.1(3) 130 .
O2 Cu2 O2 C1 2.4(3) 40 .
N1 Cu2 O2 C1 -177.6(3) . .
Cu1 Cu2 O2 C1 2.4(3) . .
Cu1 O1 C1 O2 3.7(6) . .
Cu1 O1 C1 C2 -175.6(3) . .
Cu2 O2 C1 O1 -4.4(6) . .
Cu2 O2 C1 C2 174.9(3) . .
O1 C1 C2 C3 -174.7(5) . .
O2 C1 C2 C3 5.9(7) . .
O1 C1 C2 C5 5.0(7) . .
O2 C1 C2 C5 -174.4(4) . .
C5 C2 C3 C4 1.4(11) . .
C1 C2 C3 C4 -178.9(7) . .
C2 C3 C4 C3 1.1(16) . 114
C2 C3 C4 O3 -173.7(8) . .
C3 C2 C5 C2 -3.9(10) . 114
C1 C2 C5 C2 176.4(3) . 114
O2 Cu2 N1 C6 44.92(9) 101 .
O2 Cu2 N1 C6 -135.08(9) 130 .
O2 Cu2 N1 C6 -44.92(9) . .
O2 Cu2 N1 C6 135.08(9) 40 .
Cu1 Cu2 N1 C6 180(100) . .
O2 Cu2 N1 C6 -135.08(9) 101 130
O2 Cu2 N1 C6 44.92(9) 130 130
O2 Cu2 N1 C6 135.08(9) . 130
O2 Cu2 N1 C6 -44.92(9) 40 130
Cu1 Cu2 N1 C6 0(100) . 130
C6 N1 C6 C6 0.000(1) 130 10
Cu2 N1 C6 C6 180.0 . 10
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
1 -0.004 -0.010 -0.005 45890.2 10248.6
