#------------------------------------------------------------------------------
#$Date: 2020-10-06 10:55:23 +0300 (Tue, 06 Oct 2020) $
#$Revision: 257459 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/96/7239627.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7239627
loop_
_publ_author_name
'Xu, Qi-Wei'
'Dong, Gaoyun'
'Cui, Ruifang'
'Li, Xia'
_publ_section_title
;
 3D lanthanide-coordination frameworks constructed by a ternary
 mixed-ligand: crystal structure, luminescence and luminescence sensing
;
_journal_issue                   4
_journal_name_full               CrystEngComm
_journal_page_first              740
_journal_page_last               750
_journal_paper_doi               10.1039/C9CE01779H
_journal_volume                  22
_journal_year                    2020
_chemical_formula_sum            'C28 H16 Dy N2 O9'
_chemical_formula_weight         686.93
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2019-09-24 deposited with the CCDC.	2019-12-13 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 114.362(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.4150(4)
_cell_length_b                   15.1696(6)
_cell_length_c                   18.3689(5)
_cell_measurement_reflns_used    4343
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.982
_cell_measurement_theta_min      2.832
_cell_volume                     2643.72(17)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Rigaku Saturn724 CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0787
_diffrn_reflns_av_sigmaI/netI    0.0369
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            34271
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         2.95
_exptl_absorpt_coefficient_mu    2.884
_exptl_absorpt_correction_T_max  0.7854
_exptl_absorpt_correction_T_min  0.4241
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.726
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1344
_exptl_crystal_size_max          0.359
_exptl_crystal_size_mid          0.110
_exptl_crystal_size_min          0.088
_refine_diff_density_max         0.882
_refine_diff_density_min         -1.296
_refine_diff_density_rms         0.222
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.093
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     362
_refine_ls_number_reflns         4642
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.094
_refine_ls_R_factor_all          0.0423
_refine_ls_R_factor_gt           0.0342
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0585P)²+0.6460P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0898
_refine_ls_wR_factor_ref         0.0936
_reflns_number_gt                4043
_reflns_number_total             4642
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c9ce01779h2.cif
_cod_data_source_block           111
_cod_depositor_comments
;Adding full bibliography for 7239626--7239630.cif.

 Adding full bibliography for 7239626--7239630.cif.
;
_cod_original_cell_volume        2643.71(16)
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7239627
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Dy1 Dy -0.007128(19) -0.367283(12) -0.126511(11) 0.02242(10) Uani 1 1 d .
O8 O -0.1078(3) -0.49507(19) -0.10190(17) 0.0305(7) Uani 1 1 d .
O4 O -0.0932(4) -0.0524(2) 0.24748(19) 0.0388(8) Uani 1 1 d .
O9 O -0.1268(3) -0.5787(2) -0.00712(17) 0.0308(7) Uani 1 1 d .
O6 O -0.0266(3) -0.21397(18) -0.09632(18) 0.0327(7) Uani 1 1 d .
O7 O -0.0977(4) -0.3099(2) -0.03117(19) 0.0388(8) Uani 1 1 d .
O1 O -0.7526(4) 0.1665(3) -0.3003(2) 0.0474(9) Uani 1 1 d .
O5 O -0.0017(4) -0.1836(2) 0.2486(2) 0.0417(8) Uani 1 1 d .
O3 O -0.2204(4) -0.0747(2) -0.11981(18) 0.0415(9) Uani 1 1 d .
N1 N 0.2457(4) -0.3045(2) -0.0778(2) 0.0322(9) Uani 1 1 d .
O2 O -0.5861(4) 0.2697(3) -0.2735(3) 0.0701(12) Uani 1 1 d U
H2 H -0.6552 0.3021 -0.2920 0.105 Uiso 1 1 calc R
C9 C -0.2012(6) -0.0151(3) 0.0066(3) 0.0520(15) Uani 1 1 d .
H9 H -0.2442 0.0371 -0.0180 0.062 Uiso 1 1 calc R
C13 C -0.1107(5) -0.1590(3) -0.0014(3) 0.0273(10) Uani 1 1 d .
C12 C -0.0755(4) -0.1694(3) 0.0791(3) 0.0283(10) Uani 1 1 d .
H12 H -0.0335 -0.2218 0.1038 0.034 Uiso 1 1 calc R
C23 C 0.5194(6) -0.2412(4) -0.0264(4) 0.0657(17) Uani 1 1 d .
H23 H 0.6105 -0.2191 -0.0092 0.079 Uiso 1 1 calc R
C24 C 0.4171(6) -0.1907(4) -0.0241(4) 0.0671(19) Uani 1 1 d .
H24 H 0.4366 -0.1334 -0.0047 0.080 Uiso 1 1 calc R
N2 N 0.1802(4) -0.4738(2) -0.1294(2) 0.0336(9) Uani 1 1 d .
C14 C -0.0621(5) -0.1145(3) 0.2120(3) 0.0320(11) Uani 1 1 d .
C15 C -0.0781(4) -0.2322(3) -0.0467(2) 0.0273(10) Uani 1 1 d .
C8 C -0.1777(5) -0.0813(3) -0.0384(3) 0.0326(11) Uani 1 1 d .
C21 C 0.5937(6) -0.3875(5) -0.0591(4) 0.0571(16) Uani 1 1 d .
H21 H 0.6860 -0.3681 -0.0432 0.069 Uiso 1 1 calc R
C2 C -0.6280(5) 0.1869(3) -0.2718(3) 0.0309(10) Uani 1 1 d U
C16 C 0.1496(6) -0.5570(4) -0.1525(3) 0.0509(14) Uani 1 1 d .
H16 H 0.0577 -0.5766 -0.1670 0.061 Uiso 1 1 calc R
C28 C -0.0679(4) -0.5210(3) -0.0313(2) 0.0218(9) Uani 1 1 d .
C17 C 0.2497(8) -0.6168(4) -0.1562(4) 0.0594(17) Uani 1 1 d .
H17 H 0.2245 -0.6748 -0.1723 0.071 Uiso 1 1 calc R
C4 C -0.2798(5) 0.0654(3) -0.1849(3) 0.0390(12) Uani 1 1 d .
H4 H -0.1871 0.0718 -0.1787 0.047 Uiso 1 1 calc R
C3 C -0.3784(5) 0.1305(3) -0.2213(3) 0.0368(12) Uani 1 1 d .
H3 H -0.3515 0.1820 -0.2388 0.044 Uiso 1 1 calc R
C25 C 0.2813(6) -0.2236(3) -0.0508(4) 0.0520(14) Uani 1 1 d .
H25 H 0.2111 -0.1865 -0.0497 0.062 Uiso 1 1 calc R
C5 C -0.5164(5) 0.1194(3) -0.2320(3) 0.0297(10) Uani 1 1 d .
C6 C -0.1007(5) -0.1046(3) 0.1242(3) 0.0341(11) Uani 1 1 d .
C26 C 0.3491(5) -0.3573(3) -0.0802(3) 0.0325(11) Uani 1 1 d .
C7 C -0.3218(5) -0.0092(3) -0.1578(3) 0.0334(11) Uani 1 1 d .
C22 C 0.4892(5) -0.3285(4) -0.0550(3) 0.0458(13) Uani 1 1 d .
C10 C -0.4583(6) -0.0228(3) -0.1691(3) 0.0452(13) Uani 1 1 d .
H10 H -0.4844 -0.0745 -0.1515 0.054 Uiso 1 1 calc R
C27 C 0.3150(5) -0.4467(3) -0.1070(3) 0.0334(11) Uani 1 1 d .
C18 C 0.3819(7) -0.5890(4) -0.1360(3) 0.0569(16) Uani 1 1 d .
H18 H 0.4485 -0.6276 -0.1395 0.068 Uiso 1 1 calc R
C11 C -0.1615(6) -0.0259(3) 0.0870(3) 0.0489(14) Uani 1 1 d .
H11 H -0.1753 0.0197 0.1169 0.059 Uiso 1 1 calc R
C19 C -0.5574(5) 0.0420(3) -0.2075(3) 0.0416(12) Uani 1 1 d .
H19 H -0.6513 0.0335 -0.2167 0.050 Uiso 1 1 calc R
C20 C 0.5598(6) -0.4700(5) -0.0857(3) 0.0545(16) Uani 1 1 d .
H20 H 0.6291 -0.5069 -0.0883 0.065 Uiso 1 1 calc R
C1A C 0.4211(6) -0.5026(4) -0.1098(3) 0.0446(14) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O8 Dy1 O1 80.52(12) . 2_444
O8 Dy1 O9 68.78(10) . 3_545
O1 Dy1 O9 133.37(12) 2_444 3_545
O8 Dy1 O6 131.83(10) . .
O1 Dy1 O6 75.63(12) 2_444 .
O9 Dy1 O6 99.30(10) 3_545 .
O8 Dy1 O5 129.07(11) . 4
O1 Dy1 O5 79.96(13) 2_444 4
O9 Dy1 O5 146.65(11) 3_545 4
O6 Dy1 O5 87.02(11) . 4
O8 Dy1 O4 75.54(10) . 4
O1 Dy1 O4 71.24(12) 2_444 4
O9 Dy1 O4 128.96(11) 3_545 4
O6 Dy1 O4 131.74(11) . 4
O5 Dy1 O4 53.68(11) 4 4
O8 Dy1 O7 79.73(10) . .
O1 Dy1 O7 72.62(12) 2_444 .
O9 Dy1 O7 68.12(11) 3_545 .
O6 Dy1 O7 53.45(10) . .
O5 Dy1 O7 135.98(12) 4 .
O4 Dy1 O7 138.84(12) 4 .
O8 Dy1 N2 83.50(11) . .
O1 Dy1 N2 140.09(12) 2_444 .
O9 Dy1 N2 71.31(11) 3_545 .
O6 Dy1 N2 138.68(11) . .
O5 Dy1 N2 82.33(12) 4 .
O4 Dy1 N2 69.43(12) 4 .
O7 Dy1 N2 139.34(12) . .
O8 Dy1 N1 135.45(11) . .
O1 Dy1 N1 143.75(13) 2_444 .
O9 Dy1 N1 72.20(11) 3_545 .
O6 Dy1 N1 74.72(11) . .
O5 Dy1 N1 78.13(12) 4 .
O4 Dy1 N1 115.85(12) 4 .
O7 Dy1 N1 104.89(12) . .
N2 Dy1 N1 64.04(12) . .
O8 Dy1 C15 105.68(12) . .
O1 Dy1 C15 72.01(12) 2_444 .
O9 Dy1 C15 83.23(11) 3_545 .
O6 Dy1 C15 26.90(11) . .
O5 Dy1 C15 112.03(12) 4 .
O4 Dy1 C15 142.46(12) 4 .
O7 Dy1 C15 26.56(11) . .
N2 Dy1 C15 147.84(12) . .
N1 Dy1 C15 90.02(12) . .
O8 Dy1 C14 102.23(12) . 4
O1 Dy1 C14 73.20(13) 2_444 4
O9 Dy1 C14 145.73(12) 3_545 4
O6 Dy1 C14 109.79(12) . 4
O5 Dy1 C14 26.89(12) 4 4
O4 Dy1 C14 26.81(12) 4 4
O7 Dy1 C14 144.91(12) . 4
N2 Dy1 C14 74.87(13) . 4
N1 Dy1 C14 97.91(13) . 4
C15 Dy1 C14 130.37(13) . 4
C28 O8 Dy1 118.5(3) . .
C14 O4 Dy1 92.6(3) . 4_556
C28 O9 Dy1 115.9(3) . 3_545
C15 O6 Dy1 93.2(3) . .
C15 O7 Dy1 91.4(3) . .
C2 O1 Dy1 171.5(3) . 2_454
C14 O5 Dy1 92.2(3) . 4_556
C8 O3 C7 115.5(3) . .
C25 N1 C26 117.2(4) . .
C25 N1 Dy1 124.1(3) . .
C26 N1 Dy1 118.6(3) . .
C2 O2 H2 109.5 . .
C11 C9 C8 120.5(5) . .
C11 C9 H9 119.7 . .
C8 C9 H9 119.7 . .
C12 C13 C8 118.5(4) . .
C12 C13 C15 119.2(4) . .
C8 C13 C15 122.3(4) . .
C6 C12 C13 122.1(4) . .
C6 C12 H12 119.0 . .
C13 C12 H12 119.0 . .
C24 C23 C22 119.7(5) . .
C24 C23 H23 120.2 . .
C22 C23 H23 120.2 . .
C23 C24 C25 119.8(6) . .
C23 C24 H24 120.1 . .
C25 C24 H24 120.1 . .
C16 N2 C27 117.8(4) . .
C16 N2 Dy1 121.6(3) . .
C27 N2 Dy1 120.5(3) . .
O4 C14 O5 121.5(4) . .
O4 C14 C6 118.0(4) . .
O5 C14 C6 120.6(4) . .
O4 C14 Dy1 60.6(2) . 4_556
O5 C14 Dy1 60.9(2) . 4_556
C6 C14 Dy1 176.6(3) . 4_556
O7 C15 O6 122.0(4) . .
O7 C15 C13 118.2(4) . .
O6 C15 C13 119.7(4) . .
O7 C15 Dy1 62.1(2) . .
O6 C15 Dy1 60.0(2) . .
C13 C15 Dy1 177.8(3) . .
O3 C8 C9 122.5(4) . .
O3 C8 C13 117.6(4) . .
C9 C8 C13 119.9(4) . .
C20 C21 C22 120.8(6) . .
C20 C21 H21 119.6 . .
C22 C21 H21 119.6 . .
O1 C2 O2 121.9(4) . .
O1 C2 C5 120.6(4) . .
O2 C2 C5 117.4(4) . .
N2 C16 C17 123.0(6) . .
N2 C16 H16 118.5 . .
C17 C16 H16 118.5 . .
O9 C28 O8 125.9(4) . .
O9 C28 C28 117.2(4) . 3_545
O8 C28 C28 116.9(4) . 3_545
C18 C17 C16 118.8(6) . .
C18 C17 H17 120.6 . .
C16 C17 H17 120.6 . .
C3 C4 C7 118.6(5) . .
C3 C4 H4 120.7 . .
C7 C4 H4 120.7 . .
C5 C3 C4 120.3(4) . .
C5 C3 H3 119.9 . .
C4 C3 H3 119.9 . .
N1 C25 C24 123.8(5) . .
N1 C25 H25 118.1 . .
C24 C25 H25 118.1 . .
C3 C5 C19 120.0(4) . .
C3 C5 C2 122.7(4) . .
C19 C5 C2 117.3(4) . .
C12 C6 C11 118.5(4) . .
C12 C6 C14 122.8(4) . .
C11 C6 C14 118.7(4) . .
N1 C26 C22 122.3(5) . .
N1 C26 C27 118.7(4) . .
C22 C26 C27 118.9(5) . .
C10 C7 C4 122.4(4) . .
C10 C7 O3 119.3(4) . .
C4 C7 O3 118.3(4) . .
C26 C22 C23 117.1(5) . .
C26 C22 C21 119.6(6) . .
C23 C22 C21 123.2(5) . .
C7 C10 C19 118.6(5) . .
C7 C10 H10 120.7 . .
C19 C10 H10 120.7 . .
N2 C27 C1A 122.5(5) . .
N2 C27 C26 118.0(4) . .
C1A C27 C26 119.5(5) . .
C17 C18 C1A 120.8(5) . .
C17 C18 H18 119.6 . .
C1A C18 H18 119.6 . .
C9 C11 C6 120.4(4) . .
C9 C11 H11 119.8 . .
C6 C11 H11 119.8 . .
C5 C19 C10 120.0(5) . .
C5 C19 H19 120.0 . .
C10 C19 H19 120.0 . .
C21 C20 C1A 121.6(5) . .
C21 C20 H20 119.2 . .
C1A C20 H20 119.2 . .
C18 C1A C27 117.0(5) . .
C18 C1A C20 123.4(5) . .
C27 C1A C20 119.6(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O8 2.335(3) .
Dy1 O1 2.357(3) 2_444
Dy1 O9 2.412(3) 3_545
Dy1 O6 2.419(3) .
Dy1 O5 2.443(3) 4
Dy1 O4 2.436(3) 4
Dy1 O7 2.466(3) .
Dy1 N2 2.550(4) .
Dy1 N1 2.588(4) .
Dy1 C15 2.790(4) .
Dy1 C14 2.793(5) 4
O8 C28 1.251(5) .
O4 C14 1.261(5) .
O4 Dy1 2.436(3) 4_556
O9 C28 1.250(5) .
O9 Dy1 2.412(3) 3_545
O6 C15 1.264(5) .
O7 C15 1.248(5) .
O1 C2 1.223(6) .
O1 Dy1 2.357(3) 2_454
O5 C14 1.264(6) .
O5 Dy1 2.443(3) 4_556
O3 C8 1.377(5) .
O3 C7 1.407(5) .
N1 C25 1.318(6) .
N1 C26 1.358(6) .
O2 C2 1.334(6) .
O2 H2 0.8200 .
C9 C11 1.370(7) .
C9 C8 1.385(6) .
C9 H9 0.9300 .
C13 C12 1.378(6) .
C13 C8 1.396(6) .
C13 C15 1.508(6) .
C12 C6 1.378(6) .
C12 H12 0.9300 .
C23 C24 1.325(9) .
C23 C22 1.412(9) .
C23 H23 0.9300 .
C24 C25 1.386(7) .
C24 H24 0.9300 .
N2 C16 1.328(6) .
N2 C27 1.353(6) .
C14 C6 1.500(6) .
C14 Dy1 2.793(5) 4_556
C21 C20 1.336(8) .
C21 C22 1.435(8) .
C21 H21 0.9300 .
C2 C5 1.495(6) .
C16 C17 1.404(8) .
C16 H16 0.9300 .
C28 C28 1.545(8) 3_545
C17 C18 1.338(9) .
C17 H17 0.9300 .
C4 C3 1.382(7) .
C4 C7 1.378(7) .
C4 H4 0.9300 .
C3 C5 1.378(7) .
C3 H3 0.9300 .
C25 H25 0.9300 .
C5 C19 1.387(6) .
C6 C11 1.392(7) .
C26 C22 1.406(7) .
C26 C27 1.437(7) .
C7 C10 1.365(7) .
C10 C19 1.388(7) .
C10 H10 0.9300 .
C27 C1A 1.410(6) .
C18 C1A 1.398(8) .
C18 H18 0.9300 .
C11 H11 0.9300 .
C19 H19 0.9300 .
C20 C1A 1.414(8) .
C20 H20 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 Dy1 O8 C28 -130.2(3) 2_444 .
O9 Dy1 O8 C28 14.0(3) 3_545 .
O6 Dy1 O8 C28 -69.4(3) . .
O5 Dy1 O8 C28 161.1(3) 4 .
O4 Dy1 O8 C28 156.8(3) 4 .
O7 Dy1 O8 C28 -56.3(3) . .
N2 Dy1 O8 C28 86.5(3) . .
N1 Dy1 O8 C28 44.5(4) . .
C15 Dy1 O8 C28 -62.1(3) . .
C14 Dy1 O8 C28 159.4(3) 4 .
O8 Dy1 O6 C15 15.7(3) . .
O1 Dy1 O6 C15 78.5(3) 2_444 .
O9 Dy1 O6 C15 -54.1(2) 3_545 .
O5 Dy1 O6 C15 158.9(3) 4 .
O4 Dy1 O6 C15 126.2(2) 4 .
O7 Dy1 O6 C15 -0.3(2) . .
N2 Dy1 O6 C15 -126.3(3) . .
N1 Dy1 O6 C15 -122.6(3) . .
C14 Dy1 O6 C15 144.3(2) 4 .
O8 Dy1 O7 C15 -167.6(3) . .
O1 Dy1 O7 C15 -84.4(3) 2_444 .
O9 Dy1 O7 C15 121.3(3) 3_545 .
O6 Dy1 O7 C15 0.3(2) . .
O5 Dy1 O7 C15 -30.3(3) 4 .
O4 Dy1 O7 C15 -113.9(3) 4 .
N2 Dy1 O7 C15 125.2(3) . .
N1 Dy1 O7 C15 57.9(3) . .
C14 Dy1 O7 C15 -70.9(3) 4 .
O8 Dy1 N1 C25 -130.8(4) . .
O1 Dy1 N1 C25 40.4(5) 2_444 .
O9 Dy1 N1 C25 -101.0(4) 3_545 .
O6 Dy1 N1 C25 4.2(4) . .
O5 Dy1 N1 C25 94.4(4) 4 .
O4 Dy1 N1 C25 133.6(4) 4 .
O7 Dy1 N1 C25 -40.4(4) . .
N2 Dy1 N1 C25 -178.4(5) . .
C15 Dy1 N1 C25 -18.2(4) . .
C14 Dy1 N1 C25 112.7(4) 4 .
O8 Dy1 N1 C26 49.6(4) . .
O1 Dy1 N1 C26 -139.2(3) 2_444 .
O9 Dy1 N1 C26 79.4(3) 3_545 .
O6 Dy1 N1 C26 -175.3(4) . .
O5 Dy1 N1 C26 -85.2(3) 4 .
O4 Dy1 N1 C26 -45.9(4) 4 .
O7 Dy1 N1 C26 140.0(3) . .
N2 Dy1 N1 C26 2.0(3) . .
C15 Dy1 N1 C26 162.3(3) . .
C14 Dy1 N1 C26 -66.9(3) 4 .
C8 C13 C12 C6 -2.0(7) . .
C15 C13 C12 C6 179.1(4) . .
C22 C23 C24 C25 -0.9(10) . .
O8 Dy1 N2 C16 29.7(4) . .
O1 Dy1 N2 C16 -37.1(5) 2_444 .
O9 Dy1 N2 C16 99.4(4) 3_545 .
O6 Dy1 N2 C16 -177.8(3) . .
O5 Dy1 N2 C16 -101.3(4) 4 .
O4 Dy1 N2 C16 -47.3(4) 4 .
O7 Dy1 N2 C16 95.6(4) . .
N1 Dy1 N2 C16 178.2(4) . .
C15 Dy1 N2 C16 138.9(4) . .
C14 Dy1 N2 C16 -74.9(4) 4 .
O8 Dy1 N2 C27 -150.3(3) . .
O1 Dy1 N2 C27 143.0(3) 2_444 .
O9 Dy1 N2 C27 -80.5(3) 3_545 .
O6 Dy1 N2 C27 2.2(4) . .
O5 Dy1 N2 C27 78.8(3) 4 .
O4 Dy1 N2 C27 132.8(3) 4 .
O7 Dy1 N2 C27 -84.3(4) . .
N1 Dy1 N2 C27 -1.7(3) . .
C15 Dy1 N2 C27 -41.0(4) . .
C14 Dy1 N2 C27 105.2(3) 4 .
Dy1 O4 C14 O5 -2.7(5) 4_556 .
Dy1 O4 C14 C6 176.6(4) 4_556 .
Dy1 O5 C14 O4 2.7(5) 4_556 .
Dy1 O5 C14 C6 -176.5(4) 4_556 .
Dy1 O7 C15 O6 -0.6(4) . .
Dy1 O7 C15 C13 -177.6(3) . .
Dy1 O6 C15 O7 0.6(4) . .
Dy1 O6 C15 C13 177.5(3) . .
C12 C13 C15 O7 40.2(6) . .
C8 C13 C15 O7 -138.7(5) . .
C12 C13 C15 O6 -136.9(4) . .
C8 C13 C15 O6 44.3(6) . .
C12 C13 C15 Dy1 -57(9) . .
C8 C13 C15 Dy1 124(9) . .
O8 Dy1 C15 O7 12.7(3) . .
O1 Dy1 C15 O7 87.0(3) 2_444 .
O9 Dy1 C15 O7 -53.0(3) 3_545 .
O6 Dy1 C15 O7 -179.4(4) . .
O5 Dy1 C15 O7 157.8(3) 4 .
O4 Dy1 C15 O7 99.2(3) 4 .
N2 Dy1 C15 O7 -90.3(3) . .
N1 Dy1 C15 O7 -125.1(3) . .
C14 Dy1 C15 O7 134.5(3) 4 .
O8 Dy1 C15 O6 -167.9(2) . .
O1 Dy1 C15 O6 -93.6(3) 2_444 .
O9 Dy1 C15 O6 126.4(2) 3_545 .
O5 Dy1 C15 O6 -22.8(3) 4 .
O4 Dy1 C15 O6 -81.4(3) 4 .
O7 Dy1 C15 O6 179.4(4) . .
N2 Dy1 C15 O6 89.1(3) . .
N1 Dy1 C15 O6 54.3(2) . .
C14 Dy1 C15 O6 -46.1(3) 4 .
O8 Dy1 C15 C13 111(9) . .
O1 Dy1 C15 C13 -175(9) 2_444 .
O9 Dy1 C15 C13 45(9) 3_545 .
O6 Dy1 C15 C13 -81(9) . .
O5 Dy1 C15 C13 -104(9) 4 .
O4 Dy1 C15 C13 -162(9) 4 .
O7 Dy1 C15 C13 98(9) . .
N2 Dy1 C15 C13 8(9) . .
N1 Dy1 C15 C13 -27(9) . .
C14 Dy1 C15 C13 -127(9) 4 .
C7 O3 C8 C9 -16.9(7) . .
C7 O3 C8 C13 162.0(4) . .
C11 C9 C8 O3 177.6(5) . .
C11 C9 C8 C13 -1.3(8) . .
C12 C13 C8 O3 -175.7(4) . .
C15 C13 C8 O3 3.1(7) . .
C12 C13 C8 C9 3.2(7) . .
C15 C13 C8 C9 -178.0(5) . .
Dy1 O1 C2 O2 66(3) 2_454 .
Dy1 O1 C2 C5 -115(2) 2_454 .
C27 N2 C16 C17 -1.3(8) . .
Dy1 N2 C16 C17 178.8(4) . .
Dy1 O9 C28 O8 167.4(3) 3_545 .
Dy1 O9 C28 C28 -11.5(6) 3_545 3_545
Dy1 O8 C28 O9 167.5(3) . .
Dy1 O8 C28 C28 -13.6(6) . 3_545
N2 C16 C17 C18 -0.5(9) . .
C7 C4 C3 C5 -1.7(8) . .
C26 N1 C25 C24 -1.0(8) . .
Dy1 N1 C25 C24 179.4(5) . .
C23 C24 C25 N1 1.3(11) . .
C4 C3 C5 C19 -1.2(8) . .
C4 C3 C5 C2 -179.3(5) . .
O1 C2 C5 C3 159.3(5) . .
O2 C2 C5 C3 -21.9(7) . .
O1 C2 C5 C19 -18.8(7) . .
O2 C2 C5 C19 159.9(5) . .
C13 C12 C6 C11 -1.1(7) . .
C13 C12 C6 C14 -179.5(4) . .
O4 C14 C6 C12 -178.0(4) . .
O5 C14 C6 C12 1.2(7) . .
Dy1 C14 C6 C12 -114(6) 4_556 .
O4 C14 C6 C11 3.5(7) . .
O5 C14 C6 C11 -177.2(5) . .
Dy1 C14 C6 C11 67(6) 4_556 .
C25 N1 C26 C22 0.3(7) . .
Dy1 N1 C26 C22 179.9(4) . .
C25 N1 C26 C27 178.2(5) . .
Dy1 N1 C26 C27 -2.2(6) . .
C3 C4 C7 C10 3.2(8) . .
C3 C4 C7 O3 -179.2(4) . .
C8 O3 C7 C10 -74.8(6) . .
C8 O3 C7 C4 107.6(5) . .
N1 C26 C22 C23 0.1(7) . .
C27 C26 C22 C23 -177.8(5) . .
N1 C26 C22 C21 -179.9(5) . .
C27 C26 C22 C21 2.2(7) . .
C24 C23 C22 C26 0.2(9) . .
C24 C23 C22 C21 -179.8(6) . .
C20 C21 C22 C26 -0.9(8) . .
C20 C21 C22 C23 179.0(5) . .
C4 C7 C10 C19 -1.8(8) . .
O3 C7 C10 C19 -179.3(4) . .
C16 N2 C27 C1A 1.9(7) . .
Dy1 N2 C27 C1A -178.2(3) . .
C16 N2 C27 C26 -178.6(4) . .
Dy1 N2 C27 C26 1.3(5) . .
N1 C26 C27 N2 0.6(6) . .
C22 C26 C27 N2 178.6(4) . .
N1 C26 C27 C1A -179.9(4) . .
C22 C26 C27 C1A -1.9(7) . .
C16 C17 C18 C1A 1.7(9) . .
C8 C9 C11 C6 -1.9(9) . .
C12 C6 C11 C9 3.0(8) . .
C14 C6 C11 C9 -178.5(5) . .
C3 C5 C19 C10 2.7(8) . .
C2 C5 C19 C10 -179.1(5) . .
C7 C10 C19 C5 -1.2(8) . .
C22 C21 C20 C1A -0.6(9) . .
C17 C18 C1A C27 -1.0(8) . .
C17 C18 C1A C20 178.2(6) . .
N2 C27 C1A C18 -0.8(7) . .
C26 C27 C1A C18 179.7(4) . .
N2 C27 C1A C20 179.9(4) . .
C26 C27 C1A C20 0.4(7) . .
C21 C20 C1A C18 -178.4(5) . .
C21 C20 C1A C27 0.9(8) . .
