#------------------------------------------------------------------------------
#$Date: 2020-10-06 14:40:37 +0300 (Tue, 06 Oct 2020) $
#$Revision: 258095 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/98/7239857.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7239857
loop_
_publ_author_name
'Shin, Jong Won'
'Jeong, Ah Rim'
'Jeong, Jong Hwa'
'Zenno, Hikaru'
'Hayami, Shinya'
'Min, Kil Sik'
_publ_section_title
;
 Two-dimensional square-grid iron(ii) coordination polymers showing
 anion-dependent spin crossover behavior
;
_journal_issue                   9
_journal_name_full               'RSC Advances'
_journal_page_first              5040
_journal_page_last               5049
_journal_paper_doi               10.1039/C9RA09782A
_journal_volume                  10
_journal_year                    2020
_chemical_formula_sum            'C46 H45 Fe N14 O3 Se2'
_chemical_formula_weight         1055.72
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2019-08-09 deposited with the CCDC.	2020-01-24 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 99.73(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   9.6220(19)
_cell_length_b                   14.689(3)
_cell_length_c                   19.691(4)
_cell_measurement_reflns_used    38256
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      29.59
_cell_measurement_theta_min      0.46
_cell_volume                     2743.0(10)
_computing_cell_refinement       HKL3000
_computing_data_collection       'PAL ADSC Quantum-210 ADX Program'
_computing_data_reduction        HKL3000
_computing_molecular_graphics    ORTEP
_computing_publication_material  WINGX
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'ADSC Q210 CCD area detector'
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.800
_diffrn_reflns_av_R_equivalents  0.0605
_diffrn_reflns_av_unetI/netI     0.0437
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            19072
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        28.685
_diffrn_reflns_theta_max         29.606
_diffrn_reflns_theta_min         2.362
_diffrn_source                   'PLSII 2D bending magnet'
_exptl_absorpt_coefficient_mu    2.252
_exptl_absorpt_correction_T_max  0.896
_exptl_absorpt_correction_T_min  0.729
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'HKL3000 Scalepack'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.278
_exptl_crystal_description       block
_exptl_crystal_F_000             1074
_exptl_crystal_size_max          0.150
_exptl_crystal_size_mid          0.050
_exptl_crystal_size_min          0.050
_platon_squeeze_details
;
;
_refine_diff_density_max         1.466
_refine_diff_density_min         -0.542
_refine_diff_density_rms         0.135
_refine_ls_extinction_coef       0.027(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.065
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     316
_refine_ls_number_reflns         5381
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.065
_refine_ls_R_factor_all          0.0883
_refine_ls_R_factor_gt           0.0806
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[σ²(Fo²)+(0.1751P)²+4.5218P]
 where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2648
_refine_ls_wR_factor_ref         0.2712
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4563
_reflns_number_total             5381
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9ra09782a2.cif
_cod_data_source_block           shelx_CCDC2
_cod_depositor_comments
'Adding full bibliography for 7239855--7239857.cif.'
_cod_original_cell_volume        2743.1(10)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7239857
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.729
_shelx_estimated_absorpt_t_max   0.896
_shelxl_version_number           2013-2
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Fe1 Fe 0.5000 0.0000 0.0000 0.0322(3) Uani 1 2 d S . P
Se1 Se 0.92662(12) 0.19628(14) 0.03484(7) 0.0958(6) Uani 0.8 1 d . . P
Se2 Se 0.8665(9) 0.2490(6) 0.0360(3) 0.117(3) Uani 0.2 1 d . . P
N1 N 0.6519(4) -0.0890(3) 0.06679(19) 0.0406(8) Uani 1 1 d . . .
N2 N 0.9472(4) -0.2157(3) 0.22059(19) 0.0409(8) Uani 1 1 d . . .
N3 N 1.3785(5) -0.2435(5) 0.2108(4) 0.0819(17) Uani 1 1 d . . .
N4 N 1.1490(10) -0.5110(4) 0.2026(5) 0.097(2) Uani 1 1 d . . .
N5 N 0.8516(5) -0.3431(3) 0.2756(2) 0.0467(9) Uani 1 1 d . . .
N6 N 0.6027(4) -0.4508(2) 0.41309(19) 0.0408(8) Uani 1 1 d . . .
N7 N 0.6492(4) 0.1090(3) 0.0168(2) 0.0451(9) Uani 1 1 d . . .
C1 C 0.8915(4) -0.1247(3) 0.1153(2) 0.0377(9) Uani 1 1 d . . .
H1 H 0.9867 -0.1172 0.1133 0.045 Uiso 1 1 calc R U .
C2 C 0.7913(4) -0.0824(3) 0.0681(2) 0.0409(9) Uani 1 1 d . . .
H2 H 0.8221 -0.0465 0.0347 0.049 Uiso 1 1 calc R U .
C3 C 0.6122(5) -0.1455(3) 0.1141(3) 0.0458(10) Uani 1 1 d . . .
H3 H 0.5162 -0.1542 0.1132 0.055 Uiso 1 1 calc R U .
C4 C 0.7045(5) -0.1908(3) 0.1635(3) 0.0439(10) Uani 1 1 d . . .
H4 H 0.6705 -0.2289 0.1946 0.053 Uiso 1 1 calc R U .
C5 C 0.8496(4) -0.1793(3) 0.1667(2) 0.0360(9) Uani 1 1 d . . .
C6 C 1.0922(4) -0.2227(3) 0.2165(2) 0.0411(10) Uani 1 1 d . . .
C7 C 1.1958(6) -0.1978(4) 0.2711(3) 0.0583(13) Uani 1 1 d . . .
H7 H 1.1719 -0.1728 0.3109 0.070 Uiso 1 1 calc R U .
C8 C 1.3355(7) -0.2108(5) 0.2650(4) 0.0776(19) Uani 1 1 d . . .
H8 H 1.4037 -0.1950 0.3024 0.093 Uiso 1 1 calc R U .
C9 C 1.2785(6) -0.2651(5) 0.1584(4) 0.0693(17) Uani 1 1 d . . .
H9 H 1.3073 -0.2877 0.1189 0.083 Uiso 1 1 calc R U .
C10 C 1.1352(5) -0.2570(4) 0.1574(3) 0.0502(11) Uani 1 1 d . . .
H10 H 1.0702 -0.2736 0.1189 0.060 Uiso 1 1 calc R U .
C11 C 0.8975(5) -0.2472(3) 0.2817(2) 0.0409(9) Uani 1 1 d . . .
H11A H 0.8192 -0.2095 0.2898 0.049 Uiso 1 1 calc R U .
H11B H 0.9724 -0.2409 0.3211 0.049 Uiso 1 1 calc R U .
C12 C 1.0837(7) -0.4175(4) 0.2888(3) 0.0686(17) Uani 1 1 d . . .
H12 H 1.1087 -0.3912 0.3321 0.082 Uiso 1 1 calc R U .
C13 C 1.1783(9) -0.4705(5) 0.2620(5) 0.089(2) Uani 1 1 d . . .
H13 H 1.2680 -0.4780 0.2877 0.106 Uiso 1 1 calc R U .
C14 C 1.0215(12) -0.5008(6) 0.1663(5) 0.100(3) Uani 1 1 d . . .
H14 H 0.9989 -0.5306 0.1242 0.120 Uiso 1 1 calc R U .
C15 C 0.9169(8) -0.4453(5) 0.1898(4) 0.0790(19) Uani 1 1 d . . .
H15 H 0.8278 -0.4386 0.1634 0.095 Uiso 1 1 calc R U .
C16 C 0.9503(6) -0.4031(3) 0.2509(3) 0.0543(13) Uani 1 1 d . . .
C17 C 0.7681(5) -0.3781(3) 0.3204(2) 0.0405(9) Uani 1 1 d . . .
C18 C 0.6833(5) -0.3226(3) 0.3543(3) 0.0508(12) Uani 1 1 d . . .
H18 H 0.6808 -0.2600 0.3470 0.061 Uiso 1 1 calc R U .
C19 C 0.6035(5) -0.3616(3) 0.3984(3) 0.0485(11) Uani 1 1 d . . .
H19 H 0.5463 -0.3235 0.4195 0.058 Uiso 1 1 calc R U .
C20 C 0.6839(6) -0.5031(3) 0.3802(3) 0.0474(11) Uani 1 1 d . . .
H20 H 0.6856 -0.5654 0.3890 0.057 Uiso 1 1 calc R U .
C21 C 0.7650(5) -0.4708(3) 0.3341(3) 0.0484(11) Uani 1 1 d . . .
H21 H 0.8176 -0.5110 0.3122 0.058 Uiso 1 1 calc R U .
C22 C 0.7534(6) 0.1471(4) 0.0245(2) 0.0541(12) Uani 1 1 d . . .
C23 C 1.5039(12) 0.0002(8) 0.3289(8) 0.143(5) Uani 1 1 d . . .
H23A H 1.4872 0.0137 0.2805 0.215 Uiso 1 1 calc R U .
H23B H 1.5395 0.0535 0.3542 0.215 Uiso 1 1 calc R U .
H23C H 1.4171 -0.0182 0.3428 0.215 Uiso 1 1 calc R U .
O1 O 1.6094(10) -0.0749(8) 0.3432(6) 0.180(4) Uani 1 1 d . . .
H1A H 1.6846 -0.0583 0.3330 0.270 Uiso 1 1 calc R U .
O2 O 0.208(3) 0.135(2) 0.5040(18) 0.270(17) Uani 0.5 1 d . . P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0048 0.0021 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0087 0.0042 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0151 0.0080 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3685 1.0547 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.5348 2.8072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N7 Fe1 N7 180.0 3_655 .
N7 Fe1 N1 89.54(15) 3_655 3_655
N7 Fe1 N1 90.46(15) . 3_655
N7 Fe1 N1 90.46(15) 3_655 .
N7 Fe1 N1 89.54(15) . .
N1 Fe1 N1 180.0 3_655 .
N7 Fe1 N6 89.33(14) 3_655 2_655
N7 Fe1 N6 90.67(14) . 2_655
N1 Fe1 N6 86.04(13) 3_655 2_655
N1 Fe1 N6 93.96(13) . 2_655
N7 Fe1 N6 90.67(14) 3_655 4
N7 Fe1 N6 89.33(14) . 4
N1 Fe1 N6 93.96(13) 3_655 4
N1 Fe1 N6 86.04(13) . 4
N6 Fe1 N6 180.00(16) 2_655 4
Se2 Se1 C22 77.1(4) . .
Se1 Se2 C22 72.0(4) . .
C2 N1 C3 115.5(4) . .
C2 N1 Fe1 121.7(3) . .
C3 N1 Fe1 122.4(3) . .
C5 N2 C6 121.8(3) . .
C5 N2 C11 118.7(3) . .
C6 N2 C11 119.5(3) . .
C8 N3 C9 116.0(5) . .
C13 N4 C14 118.4(7) . .
C17 N5 C16 118.3(4) . .
C17 N5 C11 119.9(4) . .
C16 N5 C11 114.0(4) . .
C20 N6 C19 115.6(4) . .
C20 N6 Fe1 123.6(3) . 2_645
C19 N6 Fe1 120.0(3) . 2_645
C22 N7 Fe1 160.7(4) . .
C2 C1 C5 119.6(4) . .
C2 C1 H1 120.2 . .
C5 C1 H1 120.2 . .
N1 C2 C1 124.6(4) . .
N1 C2 H2 117.7 . .
C1 C2 H2 117.7 . .
N1 C3 C4 124.2(4) . .
N1 C3 H3 117.9 . .
C4 C3 H3 117.9 . .
C3 C4 C5 119.7(4) . .
C3 C4 H4 120.1 . .
C5 C4 H4 120.1 . .
C4 C5 N2 121.8(4) . .
C4 C5 C1 116.3(4) . .
N2 C5 C1 121.9(4) . .
C7 C6 C10 117.8(5) . .
C7 C6 N2 121.6(5) . .
C10 C6 N2 120.6(4) . .
C8 C7 C6 118.6(6) . .
C8 C7 H7 120.7 . .
C6 C7 H7 120.7 . .
N3 C8 C7 124.8(6) . .
N3 C8 H8 117.6 . .
C7 C8 H8 117.6 . .
N3 C9 C10 125.7(6) . .
N3 C9 H9 117.2 . .
C10 C9 H9 117.2 . .
C9 C10 C6 117.1(5) . .
C9 C10 H10 121.4 . .
C6 C10 H10 121.4 . .
N2 C11 N5 112.0(4) . .
N2 C11 H11A 109.2 . .
N5 C11 H11A 109.2 . .
N2 C11 H11B 109.2 . .
N5 C11 H11B 109.2 . .
H11A C11 H11B 107.9 . .
C13 C12 C16 119.6(7) . .
C13 C12 H12 120.2 . .
C16 C12 H12 120.2 . .
N4 C13 C12 123.3(9) . .
N4 C13 H13 118.3 . .
C12 C13 H13 118.3 . .
N4 C14 C15 122.0(8) . .
N4 C14 H14 119.0 . .
C15 C14 H14 119.0 . .
C16 C15 C14 118.5(8) . .
C16 C15 H15 120.7 . .
C14 C15 H15 120.7 . .
C15 C16 C12 118.1(6) . .
C15 C16 N5 120.9(6) . .
C12 C16 N5 121.0(5) . .
N5 C17 C21 121.3(4) . .
N5 C17 C18 122.3(4) . .
C21 C17 C18 116.4(4) . .
C19 C18 C17 119.4(4) . .
C19 C18 H18 120.3 . .
C17 C18 H18 120.3 . .
N6 C19 C18 124.4(4) . .
N6 C19 H19 117.8 . .
C18 C19 H19 117.8 . .
N6 C20 C21 124.2(4) . .
N6 C20 H20 117.9 . .
C21 C20 H20 117.9 . .
C20 C21 C17 119.9(4) . .
C20 C21 H21 120.0 . .
C17 C21 H21 120.0 . .
N7 C22 Se1 174.0(5) . .
N7 C22 Se2 155.1(6) . .
Se1 C22 Se2 30.8(3) . .
O1 C23 H23A 109.5 . .
O1 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
O1 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C23 O1 H1A 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Fe1 N7 2.138(4) 3_655
Fe1 N7 2.138(4) .
Fe1 N1 2.219(3) 3_655
Fe1 N1 2.219(3) .
Fe1 N6 2.236(3) 2_655
Fe1 N6 2.236(3) 4
Se1 Se2 0.968(10) .
Se1 C22 1.796(5) .
Se2 C22 1.841(8) .
N1 C2 1.341(5) .
N1 C3 1.350(6) .
N2 C5 1.398(5) .
N2 C6 1.414(5) .
N2 C11 1.445(5) .
N3 C8 1.301(10) .
N3 C9 1.324(10) .
N4 C13 1.301(12) .
N4 C14 1.320(13) .
N5 C17 1.389(5) .
N5 C16 1.439(6) .
N5 C11 1.475(6) .
N6 C20 1.339(6) .
N6 C19 1.342(6) .
N6 Fe1 2.236(3) 2_645
N7 C22 1.136(7) .
C1 C2 1.370(6) .
C1 C5 1.404(5) .
C1 H1 0.9300 .
C2 H2 0.9300 .
C3 C4 1.373(6) .
C3 H3 0.9300 .
C4 C5 1.398(6) .
C4 H4 0.9300 .
C6 C7 1.385(7) .
C6 C10 1.394(7) .
C7 C8 1.382(9) .
C7 H7 0.9300 .
C8 H8 0.9300 .
C9 C10 1.381(7) .
C9 H9 0.9300 .
C10 H10 0.9300 .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C12 C13 1.370(8) .
C12 C16 1.387(9) .
C12 H12 0.9300 .
C13 H13 0.9300 .
C14 C15 1.431(11) .
C14 H14 0.9300 .
C15 C16 1.343(9) .
C15 H15 0.9300 .
C17 C21 1.390(7) .
C17 C18 1.399(6) .
C18 C19 1.378(6) .
C18 H18 0.9300 .
C19 H19 0.9300 .
C20 C21 1.377(6) .
C20 H20 0.9300 .
C21 H21 0.9300 .
C23 O1 1.494(14) .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
O1 H1A 0.8200 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
C3 N1 C2 C1 -3.3(7) .
Fe1 N1 C2 C1 169.4(4) .
C5 C1 C2 N1 0.0(7) .
C2 N1 C3 C4 3.2(7) .
Fe1 N1 C3 C4 -169.4(4) .
N1 C3 C4 C5 0.1(8) .
C3 C4 C5 N2 172.7(5) .
C3 C4 C5 C1 -3.5(7) .
C6 N2 C5 C4 165.3(4) .
C11 N2 C5 C4 -14.4(6) .
C6 N2 C5 C1 -18.8(6) .
C11 N2 C5 C1 161.6(4) .
C2 C1 C5 C4 3.5(6) .
C2 C1 C5 N2 -172.7(4) .
C5 N2 C6 C7 135.2(5) .
C11 N2 C6 C7 -45.1(6) .
C5 N2 C6 C10 -46.1(6) .
C11 N2 C6 C10 133.6(4) .
C10 C6 C7 C8 -2.1(7) .
N2 C6 C7 C8 176.7(5) .
C9 N3 C8 C7 0.1(11) .
C6 C7 C8 N3 1.4(10) .
C8 N3 C9 C10 -1.0(10) .
N3 C9 C10 C6 0.3(9) .
C7 C6 C10 C9 1.3(7) .
N2 C6 C10 C9 -177.5(4) .
C5 N2 C11 N5 87.8(5) .
C6 N2 C11 N5 -91.8(5) .
C17 N5 C11 N2 -163.4(4) .
C16 N5 C11 N2 47.9(5) .
C14 N4 C13 C12 -0.4(11) .
C16 C12 C13 N4 -1.7(10) .
C13 N4 C14 C15 1.5(12) .
N4 C14 C15 C16 -0.5(11) .
C14 C15 C16 C12 -1.6(9) .
C14 C15 C16 N5 177.0(5) .
C13 C12 C16 C15 2.6(8) .
C13 C12 C16 N5 -176.0(5) .
C17 N5 C16 C15 96.0(6) .
C11 N5 C16 C15 -114.8(6) .
C17 N5 C16 C12 -85.4(6) .
C11 N5 C16 C12 63.8(6) .
C16 N5 C17 C21 -8.7(7) .
C11 N5 C17 C21 -156.1(5) .
C16 N5 C17 C18 171.2(5) .
C11 N5 C17 C18 23.8(7) .
N5 C17 C18 C19 -179.7(5) .
C21 C17 C18 C19 0.2(8) .
C20 N6 C19 C18 -1.7(8) .
Fe1 N6 C19 C18 168.5(4) 2_645
C17 C18 C19 N6 1.5(9) .
C19 N6 C20 C21 0.2(8) .
Fe1 N6 C20 C21 -169.6(4) 2_645
N6 C20 C21 C17 1.4(9) .
N5 C17 C21 C20 178.3(5) .
C18 C17 C21 C20 -1.5(8) .
Fe1 N7 C22 Se2 175.4(7) .
Se1 Se2 C22 N7 -177.7(10) .
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 -0.016 0.000 0.500 177 25 ' '
2 -0.022 0.500 0.000 177 25 ' '
