#------------------------------------------------------------------------------
#$Date: 2020-10-06 11:07:15 +0300 (Tue, 06 Oct 2020) $
#$Revision: 257484 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/02/7240255.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7240255
loop_
_publ_author_name
'Medvedev, Alexander G.'
'Grishanov, Dmitry A.'
'Churakov, Andrei V.'
'Mikhaylov, Alexey A.'
'Lev, Ovadia'
'Prikhodchenko, Petr V.'
_publ_section_title
;
 Hydroperoxo double hydrogen bonding: stabilization of hydroperoxo
 complexes exemplified by triphenylsilicon and triphenylgermanium
 hydroperoxides
;
_journal_issue                   11
_journal_name_full               CrystEngComm
_journal_page_first              1922
_journal_page_last               1928
_journal_paper_doi               10.1039/C9CE01882D
_journal_volume                  22
_journal_year                    2020
_chemical_formula_moiety         'C18 H16 Ge O2'
_chemical_formula_sum            'C18 H16 Ge O2'
_chemical_formula_weight         336.90
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   difmap
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2019-05-12 deposited with the CCDC.	2020-01-07 downloaded from the CCDC.
;
_cell_angle_alpha                88.4868(9)
_cell_angle_beta                 89.8466(10)
_cell_angle_gamma                65.3416(9)
_cell_formula_units_Z            4
_cell_length_a                   9.8517(3)
_cell_length_b                   11.4503(3)
_cell_length_c                   15.0058(4)
_cell_measurement_reflns_used    8393
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      30.531
_cell_measurement_theta_min      2.275
_cell_volume                     1537.77(7)
_computing_cell_refinement       'SAINT (Bruker, 2018)'
_computing_data_collection       'APEX3 (Bruker, 2018)'
_computing_data_reduction        'SAINT (Bruker, 2018)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXTL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker SMART APEX II'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0257
_diffrn_reflns_av_sigmaI/netI    0.0419
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            15171
_diffrn_reflns_theta_full        27.00
_diffrn_reflns_theta_max         27.00
_diffrn_reflns_theta_min         2.27
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    1.993
_exptl_absorpt_correction_T_max  0.9803
_exptl_absorpt_correction_T_min  0.5028
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 2016)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.455
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             688
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.01
_refine_diff_density_max         0.939
_refine_diff_density_min         -0.590
_refine_diff_density_rms         0.076
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_parameters     507
_refine_ls_number_reflns         6668
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.069
_refine_ls_R_factor_all          0.0517
_refine_ls_R_factor_gt           0.0394
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0599P)²+0.2515P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1003
_refine_ls_wR_factor_ref         0.1052
_reflns_number_gt                5425
_reflns_number_total             6668
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            c9ce01882d3.cif
_cod_data_source_block           a_CCDC1
_cod_depositor_comments
'Adding full bibliography for 7240253--7240255.cif.'
_cod_database_code               7240255
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.77416(3) 0.73674(3) 0.98171(2) 0.03190(10) Uani 1 1 d . . .
Ge2 Ge 0.23679(3) 0.74788(3) 0.471202(19) 0.02620(10) Uani 1 1 d . . .
O11 O 0.4965(3) 0.8918(2) 0.93441(18) 0.0554(7) Uani 1 1 d . . .
O12 O 0.6352(2) 0.9023(2) 0.95913(15) 0.0442(5) Uani 1 1 d . . .
O21 O 0.3354(2) 0.5005(2) 0.50300(17) 0.0436(6) Uani 1 1 d . . .
O22 O 0.3726(2) 0.58666(18) 0.44324(14) 0.0340(4) Uani 1 1 d . . .
C11 C 0.7119(3) 0.6542(3) 1.0769(2) 0.0361(7) Uani 1 1 d . . .
C12 C 0.5923(4) 0.6194(4) 1.0659(2) 0.0460(8) Uani 1 1 d . . .
C13 C 0.5538(4) 0.5560(4) 1.1321(3) 0.0520(9) Uani 1 1 d . . .
C14 C 0.6314(4) 0.5235(4) 1.2124(3) 0.0508(9) Uani 1 1 d . . .
C15 C 0.7504(4) 0.5559(3) 1.2252(2) 0.0487(8) Uani 1 1 d . . .
C16 C 0.7910(4) 0.6200(3) 1.1582(2) 0.0420(7) Uani 1 1 d . . .
C21 C 0.9411(3) 0.7742(3) 1.01332(19) 0.0329(6) Uani 1 1 d . . .
C22 C 0.9329(4) 0.8549(4) 1.0833(2) 0.0495(9) Uani 1 1 d . . .
C23 C 1.0548(5) 0.8800(4) 1.1051(3) 0.0601(10) Uani 1 1 d . . .
C24 C 1.1854(4) 0.8262(4) 1.0582(2) 0.0522(9) Uani 1 1 d . . .
C25 C 1.1959(4) 0.7449(4) 0.9886(2) 0.0448(8) Uani 1 1 d . . .
C26 C 1.0755(3) 0.7203(3) 0.96661(19) 0.0347(6) Uani 1 1 d . . .
C31 C 0.8003(3) 0.6508(3) 0.86996(19) 0.0316(6) Uani 1 1 d . . .
C32 C 0.8304(4) 0.7073(3) 0.7931(2) 0.0372(7) Uani 1 1 d . . .
C33 C 0.8478(4) 0.6495(4) 0.7125(2) 0.0455(8) Uani 1 1 d . . .
C34 C 0.8363(4) 0.5330(4) 0.7061(2) 0.0490(9) Uani 1 1 d . . .
C35 C 0.8085(4) 0.4751(3) 0.7807(2) 0.0450(8) Uani 1 1 d . . .
C36 C 0.7900(3) 0.5336(3) 0.8630(2) 0.0388(7) Uani 1 1 d . . .
C41 C 0.2614(3) 0.7711(3) 0.59604(17) 0.0283(6) Uani 1 1 d . . .
C42 C 0.1414(4) 0.8125(3) 0.6532(2) 0.0375(7) Uani 1 1 d . . .
C43 C 0.1611(5) 0.8345(3) 0.7422(2) 0.0464(8) Uani 1 1 d . . .
C44 C 0.3008(5) 0.8149(4) 0.7732(2) 0.0495(9) Uani 1 1 d . . .
C45 C 0.4219(4) 0.7706(3) 0.7181(2) 0.0452(8) Uani 1 1 d . . .
C46 C 0.4027(4) 0.7487(3) 0.6298(2) 0.0394(7) Uani 1 1 d . . .
C51 C 0.3060(3) 0.8491(3) 0.39364(19) 0.0286(6) Uani 1 1 d . . .
C52 C 0.3190(4) 0.9574(3) 0.4242(2) 0.0370(7) Uani 1 1 d . . .
C53 C 0.3743(4) 1.0265(3) 0.3685(3) 0.0453(8) Uani 1 1 d . . .
C54 C 0.4155(4) 0.9878(3) 0.2830(2) 0.0409(7) Uani 1 1 d . . .
C55 C 0.4048(4) 0.8802(4) 0.2520(2) 0.0424(8) Uani 1 1 d . . .
C56 C 0.3491(4) 0.8118(3) 0.3069(2) 0.0378(7) Uani 1 1 d . . .
C61 C 0.0410(3) 0.7589(3) 0.44115(18) 0.0266(6) Uani 1 1 d . . .
C62 C -0.0428(3) 0.8420(3) 0.3729(2) 0.0354(7) Uani 1 1 d . . .
C63 C -0.1831(4) 0.8504(3) 0.3507(2) 0.0422(8) Uani 1 1 d . . .
C64 C -0.2404(3) 0.7741(3) 0.3960(2) 0.0377(7) Uani 1 1 d . . .
C65 C -0.1586(3) 0.6910(3) 0.4630(2) 0.0343(7) Uani 1 1 d . . .
C66 C -0.0187(3) 0.6831(3) 0.4859(2) 0.0299(6) Uani 1 1 d . . .
H1 H 0.429(5) 0.965(4) 0.967(3) 0.067(12) Uiso 1 1 d . . .
H2 H 0.425(5) 0.475(4) 0.531(3) 0.089(15) Uiso 1 1 d . . .
H12 H 0.529(4) 0.648(3) 1.008(2) 0.039(9) Uiso 1 1 d . . .
H13 H 0.478(4) 0.533(3) 1.127(2) 0.054(10) Uiso 1 1 d . . .
H14 H 0.618(4) 0.488(4) 1.268(3) 0.066(12) Uiso 1 1 d . . .
H15 H 0.805(5) 0.526(4) 1.283(3) 0.071(12) Uiso 1 1 d . . .
H16 H 0.870(4) 0.644(3) 1.163(2) 0.051(10) Uiso 1 1 d . . .
H22 H 0.838(4) 0.905(3) 1.109(2) 0.048(10) Uiso 1 1 d . . .
H23 H 1.040(4) 0.939(3) 1.155(3) 0.057(10) Uiso 1 1 d . . .
H24 H 1.270(4) 0.845(3) 1.071(2) 0.051(10) Uiso 1 1 d . . .
H25 H 1.297(4) 0.701(4) 0.959(3) 0.058(11) Uiso 1 1 d . . .
H26 H 1.082(3) 0.658(3) 0.922(2) 0.041(9) Uiso 1 1 d . . .
H32 H 0.830(3) 0.787(3) 0.796(2) 0.030(8) Uiso 1 1 d . . .
H33 H 0.863(4) 0.694(3) 0.660(2) 0.047(9) Uiso 1 1 d . . .
H34 H 0.841(4) 0.494(4) 0.658(3) 0.060(11) Uiso 1 1 d . . .
H35 H 0.804(5) 0.396(4) 0.770(3) 0.072(12) Uiso 1 1 d . . .
H36 H 0.775(4) 0.497(3) 0.918(2) 0.048(10) Uiso 1 1 d . . .
H42 H 0.053(3) 0.830(2) 0.6330(18) 0.020(7) Uiso 1 1 d . . .
H43 H 0.081(4) 0.866(3) 0.775(2) 0.051(11) Uiso 1 1 d . . .
H44 H 0.303(4) 0.837(4) 0.824(3) 0.061(12) Uiso 1 1 d . . .
H45 H 0.510(4) 0.754(3) 0.746(2) 0.054(11) Uiso 1 1 d . . .
H46 H 0.479(4) 0.725(3) 0.596(3) 0.055(11) Uiso 1 1 d . . .
H52 H 0.291(3) 0.982(3) 0.480(2) 0.033(8) Uiso 1 1 d . . .
H53 H 0.378(4) 1.098(4) 0.388(3) 0.054(10) Uiso 1 1 d . . .
H54 H 0.457(4) 1.023(3) 0.243(2) 0.048(10) Uiso 1 1 d . . .
H55 H 0.431(3) 0.854(3) 0.197(2) 0.036(9) Uiso 1 1 d . . .
H56 H 0.346(4) 0.743(4) 0.281(3) 0.057(11) Uiso 1 1 d . . .
H62 H 0.000(3) 0.895(3) 0.347(2) 0.035(8) Uiso 1 1 d . . .
H63 H -0.237(4) 0.895(3) 0.306(2) 0.047(10) Uiso 1 1 d . . .
H64 H -0.332(4) 0.781(3) 0.385(2) 0.041(9) Uiso 1 1 d . . .
H65 H -0.196(4) 0.649(3) 0.496(2) 0.038(9) Uiso 1 1 d . . .
H66 H 0.034(3) 0.631(3) 0.530(2) 0.027(8) Uiso 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O12 Ge1 C11 111.61(12) . . ?
O12 Ge1 C21 98.52(11) . . ?
C11 Ge1 C21 113.54(12) . . ?
O12 Ge1 C31 105.60(11) . . ?
C11 Ge1 C31 113.19(12) . . ?
C21 Ge1 C31 113.14(12) . . ?
O22 Ge2 C41 107.78(11) . . ?
O22 Ge2 C61 107.20(10) . . ?
C41 Ge2 C61 113.51(11) . . ?
O22 Ge2 C51 99.39(10) . . ?
C41 Ge2 C51 113.06(11) . . ?
C61 Ge2 C51 114.52(11) . . ?
O12 O11 H1 97(2) . . ?
O11 O12 Ge1 105.89(15) . . ?
O22 O21 H2 90(3) . . ?
O21 O22 Ge2 104.12(14) . . ?
C12 C11 C16 117.6(3) . . ?
C12 C11 Ge1 121.5(2) . . ?
C16 C11 Ge1 120.8(2) . . ?
C13 C12 C11 121.0(3) . . ?
C13 C12 H12 120.2(18) . . ?
C11 C12 H12 118.7(18) . . ?
C12 C13 C14 121.0(3) . . ?
C12 C13 H13 123(2) . . ?
C14 C13 H13 116(2) . . ?
C13 C14 C15 119.4(4) . . ?
C13 C14 H14 134(2) . . ?
C15 C14 H14 106(2) . . ?
C16 C15 C14 120.0(4) . . ?
C16 C15 H15 124(2) . . ?
C14 C15 H15 116(2) . . ?
C15 C16 C11 120.9(3) . . ?
C15 C16 H16 124(2) . . ?
C11 C16 H16 115(2) . . ?
C22 C21 C26 117.8(3) . . ?
C22 C21 Ge1 121.6(2) . . ?
C26 C21 Ge1 120.6(2) . . ?
C23 C22 C21 120.5(3) . . ?
C23 C22 H22 119(2) . . ?
C21 C22 H22 119(2) . . ?
C24 C23 C22 120.7(3) . . ?
C24 C23 H23 124(2) . . ?
C22 C23 H23 116(2) . . ?
C23 C24 C25 119.6(3) . . ?
C23 C24 H24 122(2) . . ?
C25 C24 H24 119(2) . . ?
C26 C25 C24 119.9(3) . . ?
C26 C25 H25 123(2) . . ?
C24 C25 H25 117(2) . . ?
C25 C26 C21 121.5(3) . . ?
C25 C26 H26 121.8(19) . . ?
C21 C26 H26 116.5(19) . . ?
C36 C31 C32 118.5(3) . . ?
C36 C31 Ge1 122.1(2) . . ?
C32 C31 Ge1 119.3(2) . . ?
C33 C32 C31 120.8(3) . . ?
C33 C32 H32 120(2) . . ?
C31 C32 H32 119(2) . . ?
C32 C33 C34 120.2(3) . . ?
C32 C33 H33 119(2) . . ?
C34 C33 H33 121(2) . . ?
C35 C34 C33 120.0(3) . . ?
C35 C34 H34 115(3) . . ?
C33 C34 H34 125(3) . . ?
C34 C35 C36 120.1(3) . . ?
C34 C35 H35 114(3) . . ?
C36 C35 H35 126(3) . . ?
C31 C36 C35 120.3(3) . . ?
C31 C36 H36 116(2) . . ?
C35 C36 H36 124(2) . . ?
C42 C41 C46 118.7(3) . . ?
C42 C41 Ge2 121.4(2) . . ?
C46 C41 Ge2 119.9(2) . . ?
C41 C42 C43 120.2(3) . . ?
C41 C42 H42 119.9(18) . . ?
C43 C42 H42 119.8(18) . . ?
C44 C43 C42 119.9(3) . . ?
C44 C43 H43 123(3) . . ?
C42 C43 H43 117(3) . . ?
C45 C44 C43 120.8(3) . . ?
C45 C44 H44 124(3) . . ?
C43 C44 H44 115(3) . . ?
C44 C45 C46 119.4(3) . . ?
C44 C45 H45 114(2) . . ?
C46 C45 H45 126(2) . . ?
C45 C46 C41 120.9(3) . . ?
C45 C46 H46 117(3) . . ?
C41 C46 H46 122(3) . . ?
C52 C51 C56 118.5(3) . . ?
C52 C51 Ge2 121.0(2) . . ?
C56 C51 Ge2 120.5(2) . . ?
C51 C52 C53 120.3(3) . . ?
C51 C52 H52 119.0(19) . . ?
C53 C52 H52 120.7(19) . . ?
C54 C53 C52 119.9(3) . . ?
C54 C53 H53 121(2) . . ?
C52 C53 H53 119(2) . . ?
C55 C54 C53 120.6(3) . . ?
C55 C54 H54 113(2) . . ?
C53 C54 H54 127(2) . . ?
C54 C55 C56 119.6(3) . . ?
C54 C55 H55 122(2) . . ?
C56 C55 H55 119(2) . . ?
C55 C56 C51 121.1(3) . . ?
C55 C56 H56 114(2) . . ?
C51 C56 H56 125(2) . . ?
C62 C61 C66 118.4(3) . . ?
C62 C61 Ge2 120.3(2) . . ?
C66 C61 Ge2 121.3(2) . . ?
C63 C62 C61 120.8(3) . . ?
C63 C62 H62 124.0(19) . . ?
C61 C62 H62 115.0(19) . . ?
C62 C63 C64 119.9(3) . . ?
C62 C63 H63 125(2) . . ?
C64 C63 H63 115(2) . . ?
C65 C64 C63 120.0(3) . . ?
C65 C64 H64 119(2) . . ?
C63 C64 H64 121(2) . . ?
C64 C65 C66 120.3(3) . . ?
C64 C65 H65 121(2) . . ?
C66 C65 H65 118(2) . . ?
C65 C66 C61 120.7(3) . . ?
C65 C66 H66 120.5(19) . . ?
C61 C66 H66 118.8(19) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 O12 1.840(2) . ?
Ge1 C11 1.928(3) . ?
Ge1 C21 1.928(3) . ?
Ge1 C31 1.929(3) . ?
Ge2 O22 1.830(2) . ?
Ge2 C41 1.929(3) . ?
Ge2 C61 1.933(3) . ?
Ge2 C51 1.935(3) . ?
O11 O12 1.471(3) . ?
O11 H1 0.97(4) . ?
O21 O22 1.471(3) . ?
O21 H2 0.91(5) . ?
C11 C12 1.404(4) . ?
C11 C16 1.405(5) . ?
C12 C13 1.360(5) . ?
C12 H12 1.03(3) . ?
C13 C14 1.384(6) . ?
C13 H13 0.89(4) . ?
C14 C15 1.385(5) . ?
C14 H14 0.95(4) . ?
C15 C16 1.383(5) . ?
C15 H15 0.99(4) . ?
C16 H16 0.93(3) . ?
C21 C22 1.397(4) . ?
C21 C26 1.400(4) . ?
C22 C23 1.387(5) . ?
C22 H22 0.96(4) . ?
C23 C24 1.373(6) . ?
C23 H23 0.99(4) . ?
C24 C25 1.392(5) . ?
C24 H24 0.97(3) . ?
C25 C26 1.372(4) . ?
C25 H25 1.02(4) . ?
C26 H26 0.97(3) . ?
C31 C36 1.394(4) . ?
C31 C32 1.399(4) . ?
C32 C33 1.369(5) . ?
C32 H32 0.91(3) . ?
C33 C34 1.391(5) . ?
C33 H33 0.97(3) . ?
C34 C35 1.371(5) . ?
C34 H34 0.85(4) . ?
C35 C36 1.396(5) . ?
C35 H35 0.95(4) . ?
C36 H36 0.95(3) . ?
C41 C42 1.381(4) . ?
C41 C46 1.399(4) . ?
C42 C43 1.394(5) . ?
C42 H42 0.87(3) . ?
C43 C44 1.378(5) . ?
C43 H43 0.87(4) . ?
C44 C45 1.369(5) . ?
C44 H44 0.82(4) . ?
C45 C46 1.384(5) . ?
C45 H45 0.91(3) . ?
C46 H46 0.85(4) . ?
C51 C52 1.388(4) . ?
C51 C56 1.390(4) . ?
C52 C53 1.394(4) . ?
C52 H52 0.90(3) . ?
C53 C54 1.373(5) . ?
C53 H53 0.90(4) . ?
C54 C55 1.372(5) . ?
C54 H54 0.91(3) . ?
C55 C56 1.384(4) . ?
C55 H55 0.88(3) . ?
C56 H56 0.89(4) . ?
C61 C62 1.390(4) . ?
C61 C66 1.394(4) . ?
C62 C63 1.386(4) . ?
C62 H62 0.95(3) . ?
C63 C64 1.387(5) . ?
C63 H63 0.86(4) . ?
C64 C65 1.370(4) . ?
C64 H64 0.89(3) . ?
C65 C66 1.387(4) . ?
C65 H65 0.87(3) . ?
C66 H66 0.88(3) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O11 H1 O12 0.97(4) 1.79(4) 2.726(3) 160(3) 2_677
O21 H2 O22 0.91(5) 1.86(5) 2.738(3) 164(4) 2_666
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ge1 O12 O11 H1 139(2) . . . . ?
Ge2 O22 O21 H2 -115(3) . . . . ?
C21 Ge1 O12 O11 -179.32(18) . . . . ?
C51 Ge2 O22 O21 176.87(15) . . . . ?
