#------------------------------------------------------------------------------
#$Date: 2020-05-16 04:59:24 +0300 (Sat, 16 May 2020) $
#$Revision: 252071 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/05/7240537.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7240537
loop_
_publ_author_name
'Liu, Jian-Jun'
'Que, Qi-Tao'
'Liu, Dan'
'Suo, Hongbo'
'Liu, Jiaming'
'Xia, Shu-Biao'
_publ_section_title
;
 A multifunction photochromic metal-organic framework with Lewis acid
 sites for selective amines and anion sensing
;
_journal_name_full               CrystEngComm
_journal_paper_doi               10.1039/D0CE00560F
_journal_year                    2020
_chemical_formula_moiety         'C36 H30 Eu N4 O12, Cl'
_chemical_formula_sum            'C36 H30 Cl Eu N4 O12'
_chemical_formula_weight         898.05
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2020-04-01 deposited with the CCDC.	2020-05-14 downloaded from the CCDC.
;
_cell_angle_alpha                95.8520(10)
_cell_angle_beta                 106.5110(10)
_cell_angle_gamma                107.9380(10)
_cell_formula_units_Z            2
_cell_length_a                   9.6088(7)
_cell_length_b                   14.6537(11)
_cell_length_c                   16.9619(14)
_cell_measurement_reflns_used    12867
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.560
_cell_measurement_theta_min      2.363
_cell_volume                     2131.0(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SMART'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.941
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0214
_diffrn_reflns_av_unetI/netI     0.0498
_diffrn_reflns_Laue_measured_fraction_full 0.987
_diffrn_reflns_Laue_measured_fraction_max 0.941
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            12867
_diffrn_reflns_point_group_measured_fraction_full 0.987
_diffrn_reflns_point_group_measured_fraction_max 0.941
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.560
_diffrn_reflns_theta_min         2.363
_exptl_absorpt_coefficient_mu    1.594
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.8569
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2004)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.400
_exptl_crystal_description       block
_exptl_crystal_F_000             900
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.796
_refine_diff_density_min         -2.295
_refine_diff_density_rms         0.139
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     511
_refine_ls_number_reflns         9270
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.046
_refine_ls_R_factor_all          0.0456
_refine_ls_R_factor_gt           0.0393
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0705P)²+1.4465P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1088
_refine_ls_wR_factor_ref         0.1129
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8142
_reflns_number_total             9270
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0ce00560f2.cif
_cod_data_source_block           Complex1
_cod_database_code               7240537
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.07177(2) 0.26804(2) 0.57621(2) 0.00945(7) Uani 1 1 d . . . . .
O8 O 0.9090(3) 0.5690(2) 0.41652(17) 0.0131(6) Uani 1 1 d . . . . .
O2 O -0.1930(3) 0.0079(2) 0.40199(18) 0.0139(6) Uani 1 1 d . . . . .
O10 O 0.0010(3) 0.2731(3) 0.70046(19) 0.0206(7) Uani 1 1 d D . . . .
H10A H -0.085(3) 0.276(4) 0.698(3) 0.031 Uiso 1 1 d D U . . .
H10B H 0.041(5) 0.267(4) 0.7501(17) 0.031 Uiso 1 1 d D U . . .
O12 O 0.3200(3) 0.3790(2) 0.69178(18) 0.0158(6) Uani 1 1 d D . . . .
H12A H 0.400(4) 0.364(4) 0.706(3) 0.024 Uiso 1 1 d D U . . .
H12B H 0.316(5) 0.405(3) 0.7380(18) 0.024 Uiso 1 1 d D U . . .
O4 O -0.6991(3) -0.2413(2) 0.36324(18) 0.0161(6) Uani 1 1 d . . . . .
O5 O 0.2659(3) 0.2797(2) 0.51691(18) 0.0163(6) Uani 1 1 d . . . . .
O1 O -0.0452(3) 0.0999(2) 0.52881(18) 0.0146(6) Uani 1 1 d . . . . .
O9 O -0.0298(4) 0.2668(2) 0.42387(18) 0.0176(6) Uani 1 1 d D . . . .
H9A H -0.125(2) 0.251(4) 0.394(3) 0.026 Uiso 1 1 d D U . . .
H9B H 0.011(4) 0.248(4) 0.391(2) 0.026 Uiso 1 1 d D U . . .
O7 O 0.7529(3) 0.4308(2) 0.32289(18) 0.0177(6) Uani 1 1 d . . . . .
O3 O -0.7975(3) -0.2419(2) 0.46769(17) 0.0133(6) Uani 1 1 d . . . . .
O11 O 0.2105(3) 0.1757(2) 0.66256(18) 0.0162(6) Uani 1 1 d D . . . .
H11A H 0.309(2) 0.205(3) 0.679(3) 0.024 Uiso 1 1 d D U . . .
H11B H 0.201(5) 0.1177(16) 0.642(3) 0.024 Uiso 1 1 d D U . . .
O6 O 0.2449(3) 0.2663(2) 0.3815(2) 0.0249(7) Uani 1 1 d . . . . .
N2 N -0.3670(4) 0.0013(2) 0.7171(2) 0.0132(7) Uani 1 1 d . . . . .
N3 N 0.8029(4) 0.5036(2) 0.6852(2) 0.0122(7) Uani 1 1 d . . . . .
N1 N -0.3119(5) 0.1756(3) 1.1346(2) 0.0253(9) Uani 1 1 d . . . . .
N4 N 1.2566(5) 0.6689(3) 1.1146(2) 0.0241(8) Uani 1 1 d . . . . .
C20 C 0.4855(4) 0.3683(3) 0.4852(2) 0.0114(7) Uani 1 1 d . . . . .
C21 C 0.5621(4) 0.3919(3) 0.4275(2) 0.0107(7) Uani 1 1 d . . . . .
H21 H 0.5105 0.3628 0.3695 0.013 Uiso 1 1 calc R U . . .
C8 C -0.4827(5) 0.0454(3) 0.8145(3) 0.0182(9) Uani 1 1 d . . . . .
H8 H -0.5726 0.0495 0.8253 0.022 Uiso 1 1 calc R U . . .
C22 C 0.7137(4) 0.4580(3) 0.4545(3) 0.0114(7) Uani 1 1 d . . . . .
C3 C -0.3304(5) 0.1119(3) 0.9680(3) 0.0198(9) Uani 1 1 d . . . . .
C25 C 0.7163(5) 0.4699(3) 0.5961(2) 0.0116(7) Uani 1 1 d . . . . .
C24 C 0.7924(4) 0.4980(3) 0.5400(2) 0.0112(7) Uani 1 1 d . . . . .
H24 H 0.8959 0.5434 0.5591 0.013 Uiso 1 1 calc R U . . .
C23 C 0.7955(5) 0.4863(3) 0.3919(3) 0.0132(8) Uani 1 1 d . . . . .
C30 C 1.0313(5) 0.5256(3) 0.7976(3) 0.0207(9) Uani 1 1 d . . . . .
H30 H 1.1297 0.5186 0.8167 0.025 Uiso 1 1 calc R U . . .
C17 C -0.6876(4) -0.2157(3) 0.4387(2) 0.0112(7) Uani 1 1 d . . . . .
C7 C -0.3426(5) 0.0748(3) 0.8808(3) 0.0182(9) Uani 1 1 d . . . . .
C18 C -0.1643(4) 0.0317(3) 0.4793(3) 0.0114(7) Uani 1 1 d . . . . .
C31 C 0.9413(5) 0.4936(3) 0.7137(3) 0.0173(8) Uani 1 1 d . . . . .
H31 H 0.9783 0.4641 0.6755 0.021 Uiso 1 1 calc R U . . .
C26 C 0.5640(4) 0.4075(3) 0.5710(2) 0.0118(7) Uani 1 1 d . . . . .
H26 H 0.5135 0.3915 0.6111 0.014 Uiso 1 1 calc R U . . .
C15 C -0.2813(4) -0.0232(3) 0.5174(3) 0.0118(8) Uani 1 1 d . . . . .
C14 C -0.4166(4) -0.0990(3) 0.4663(2) 0.0105(7) Uani 1 1 d . . . . .
H14 H -0.4288 -0.1210 0.4092 0.013 Uiso 1 1 calc R U . . .
C13 C -0.5340(4) -0.1427(3) 0.4980(2) 0.0103(7) Uani 1 1 d . . . . .
C10 C -0.2294(5) 0.0288(3) 0.7800(3) 0.0170(8) Uani 1 1 d . . . . .
H10 H -0.1419 0.0218 0.7682 0.020 Uiso 1 1 calc R U . . .
C4 C -0.4558(6) 0.1235(4) 0.9876(3) 0.0290(11) Uani 1 1 d . . . . .
H4 H -0.5518 0.1097 0.9443 0.035 Uiso 1 1 calc R U . . .
C16 C -0.2642(4) 0.0083(3) 0.6009(3) 0.0130(8) Uani 1 1 d . . . . .
H16 H -0.1731 0.0599 0.6366 0.016 Uiso 1 1 calc R U . . .
C9 C -0.4930(5) 0.0105(3) 0.7339(3) 0.0175(8) Uani 1 1 d . . . . .
H9 H -0.5889 -0.0074 0.6895 0.021 Uiso 1 1 calc R U . . .
C12 C -0.5161(4) -0.1123(3) 0.5810(3) 0.0124(8) Uani 1 1 d . . . . .
H12 H -0.5946 -0.1426 0.6034 0.015 Uiso 1 1 calc R U . . .
C11 C -0.3813(5) -0.0364(3) 0.6315(2) 0.0129(8) Uani 1 1 d . . . . .
C33 C 1.0164(5) 0.6344(4) 1.0042(3) 0.0261(10) Uani 1 1 d . . . . .
H33 H 0.9132 0.6343 0.9882 0.031 Uiso 1 1 calc R U . . .
C32 C 1.0726(5) 0.6029(3) 0.9445(3) 0.0171(8) Uani 1 1 d . . . . .
C29 C 0.9775(5) 0.5678(3) 0.8538(2) 0.0151(8) Uani 1 1 d . . . . .
C6 C -0.2148(5) 0.0667(3) 0.8611(3) 0.0220(9) Uani 1 1 d . . . . .
H6 H -0.1164 0.0876 0.9040 0.026 Uiso 1 1 calc R U . . .
C19 C 0.3185(4) 0.2991(3) 0.4584(3) 0.0137(8) Uani 1 1 d . . . . .
C5 C -0.4406(6) 0.1550(4) 1.0703(3) 0.0315(12) Uani 1 1 d . . . . .
H5 H -0.5283 0.1624 1.0816 0.038 Uiso 1 1 calc R U . . .
C1 C -0.1909(6) 0.1651(4) 1.1159(3) 0.0331(12) Uani 1 1 d . . . . .
H1 H -0.0967 0.1793 1.1609 0.040 Uiso 1 1 calc R U . . .
C2 C -0.1940(6) 0.1350(4) 1.0353(3) 0.0335(12) Uani 1 1 d . . . . .
H2 H -0.1034 0.1300 1.0260 0.040 Uiso 1 1 calc R U . . .
C34 C 1.1114(5) 0.6664(4) 1.0880(3) 0.0252(10) Uani 1 1 d . . . . .
H34 H 1.0702 0.6876 1.1281 0.030 Uiso 1 1 calc R U . . .
C36 C 1.2255(6) 0.6062(4) 0.9727(3) 0.0367(13) Uani 1 1 d . . . . .
H36 H 1.2707 0.5861 0.9342 0.044 Uiso 1 1 calc R U . . .
C27 C 0.7459(6) 0.5417(4) 0.7388(3) 0.0266(11) Uani 1 1 d . . . . .
H27 H 0.6460 0.5463 0.7183 0.032 Uiso 1 1 calc R U . . .
C35 C 1.3109(7) 0.6392(5) 1.0577(3) 0.0401(14) Uani 1 1 d . . . . .
H35 H 1.4147 0.6406 1.0758 0.048 Uiso 1 1 calc R U . . .
C28 C 0.8306(6) 0.5740(4) 0.8227(3) 0.0299(11) Uani 1 1 d . . . . .
H28 H 0.7890 0.6008 0.8599 0.036 Uiso 1 1 calc R U . . .
Cl1 Cl -0.5270(4) -0.2792(2) 0.2727(2) 0.1119(9) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O8 155.96(10) . 2_666 ?
O1 Eu1 O5 93.94(10) . . ?
O8 Eu1 O5 95.51(10) 2_666 . ?
O1 Eu1 O10 95.69(11) . . ?
O8 Eu1 O10 87.88(11) 2_666 . ?
O5 Eu1 O10 147.95(10) . . ?
O1 Eu1 O3 76.44(10) . 2_456 ?
O8 Eu1 O3 81.98(9) 2_666 2_456 ?
O5 Eu1 O3 139.09(10) . 2_456 ?
O10 Eu1 O3 72.95(10) . 2_456 ?
O1 Eu1 O11 67.14(10) . . ?
O8 Eu1 O11 136.29(10) 2_666 . ?
O5 Eu1 O11 80.76(10) . . ?
O10 Eu1 O11 75.06(10) . . ?
O3 Eu1 O11 127.97(10) 2_456 . ?
O1 Eu1 O9 82.27(10) . . ?
O8 Eu1 O9 80.28(10) 2_666 . ?
O5 Eu1 O9 70.08(10) . . ?
O10 Eu1 O9 141.56(10) . . ?
O3 Eu1 O9 69.26(10) 2_456 . ?
O11 Eu1 O9 135.90(10) . . ?
O1 Eu1 O12 134.01(10) . . ?
O8 Eu1 O12 69.90(9) 2_666 . ?
O5 Eu1 O12 75.63(10) . . ?
O10 Eu1 O12 75.72(10) . . ?
O3 Eu1 O12 138.25(9) 2_456 . ?
O11 Eu1 O12 66.99(9) . . ?
O9 Eu1 O12 131.52(10) . . ?
C23 O8 Eu1 134.6(3) . 2_666 ?
Eu1 O10 H10A 120(3) . . ?
Eu1 O10 H10B 135(3) . . ?
H10A O10 H10B 105(2) . . ?
Eu1 O12 H12A 122(3) . . ?
Eu1 O12 H12B 120(3) . . ?
H12A O12 H12B 104(2) . . ?
C19 O5 Eu1 149.4(3) . . ?
C18 O1 Eu1 144.8(3) . . ?
Eu1 O9 H9A 126(3) . . ?
Eu1 O9 H9B 120(3) . . ?
H9A O9 H9B 104(2) . . ?
C17 O3 Eu1 137.9(3) . 2_456 ?
Eu1 O11 H11A 111(3) . . ?
Eu1 O11 H11B 121(3) . . ?
H11A O11 H11B 102(2) . . ?
C10 N2 C9 119.7(4) . . ?
C10 N2 C11 120.8(3) . . ?
C9 N2 C11 119.5(3) . . ?
C31 N3 C27 120.3(4) . . ?
C31 N3 C25 118.1(3) . . ?
C27 N3 C25 121.6(3) . . ?
C5 N1 C1 116.0(4) . . ?
C35 N4 C34 117.1(4) . . ?
C21 C20 C26 119.9(4) . . ?
C21 C20 C19 122.1(4) . . ?
C26 C20 C19 118.0(3) . . ?
C22 C21 C20 120.2(4) . . ?
C22 C21 H21 119.9 . . ?
C20 C21 H21 119.9 . . ?
C9 C8 C7 121.2(4) . . ?
C9 C8 H8 119.4 . . ?
C7 C8 H8 119.4 . . ?
C21 C22 C24 120.2(4) . . ?
C21 C22 C23 120.4(4) . . ?
C24 C22 C23 119.4(3) . . ?
C4 C3 C2 116.0(4) . . ?
C4 C3 C7 122.0(4) . . ?
C2 C3 C7 122.0(4) . . ?
C24 C25 C26 122.7(4) . . ?
C24 C25 N3 118.3(3) . . ?
C26 C25 N3 118.9(3) . . ?
C25 C24 C22 118.4(4) . . ?
C25 C24 H24 120.8 . . ?
C22 C24 H24 120.8 . . ?
O7 C23 O8 124.6(4) . . ?
O7 C23 C22 120.0(3) . . ?
O8 C23 C22 115.4(3) . . ?
C31 C30 C29 119.8(4) . . ?
C31 C30 H30 120.1 . . ?
C29 C30 H30 120.1 . . ?
O4 C17 O3 124.7(4) . . ?
O4 C17 C13 118.0(3) . . ?
O3 C17 C13 117.1(3) . . ?
C8 C7 C6 116.7(4) . . ?
C8 C7 C3 121.6(4) . . ?
C6 C7 C3 121.7(4) . . ?
O2 C18 O1 125.0(4) . . ?
O2 C18 C15 118.3(3) . . ?
O1 C18 C15 116.7(4) . . ?
N3 C31 C30 121.2(4) . . ?
N3 C31 H31 119.4 . . ?
C30 C31 H31 119.4 . . ?
C25 C26 C20 118.5(4) . . ?
C25 C26 H26 120.7 . . ?
C20 C26 H26 120.7 . . ?
C16 C15 C14 119.2(4) . . ?
C16 C15 C18 120.5(3) . . ?
C14 C15 C18 119.9(4) . . ?
C13 C14 C15 120.8(4) . . ?
C13 C14 H14 119.6 . . ?
C15 C14 H14 119.6 . . ?
C12 C13 C14 119.9(3) . . ?
C12 C13 C17 120.1(3) . . ?
C14 C13 C17 119.6(3) . . ?
N2 C10 C6 120.8(4) . . ?
N2 C10 H10 119.6 . . ?
C6 C10 H10 119.6 . . ?
C5 C4 C3 120.0(5) . . ?
C5 C4 H4 120.0 . . ?
C3 C4 H4 120.0 . . ?
C11 C16 C15 119.2(4) . . ?
C11 C16 H16 120.4 . . ?
C15 C16 H16 120.4 . . ?
N2 C9 C8 120.6(4) . . ?
N2 C9 H9 119.7 . . ?
C8 C9 H9 119.7 . . ?
C13 C12 C11 119.0(4) . . ?
C13 C12 H12 120.5 . . ?
C11 C12 H12 120.5 . . ?
C16 C11 C12 121.8(4) . . ?
C16 C11 N2 118.8(3) . . ?
C12 C11 N2 119.3(3) . . ?
C32 C33 C34 119.7(4) . . ?
C32 C33 H33 120.1 . . ?
C34 C33 H33 120.1 . . ?
C33 C32 C36 116.8(4) . . ?
C33 C32 C29 122.6(4) . . ?
C36 C32 C29 120.6(4) . . ?
C30 C29 C28 117.6(4) . . ?
C30 C29 C32 120.7(4) . . ?
C28 C29 C32 121.7(4) . . ?
C10 C6 C7 120.9(4) . . ?
C10 C6 H6 119.6 . . ?
C7 C6 H6 119.6 . . ?
O6 C19 O5 125.5(4) . . ?
O6 C19 C20 118.7(4) . . ?
O5 C19 C20 115.7(3) . . ?
N1 C5 C4 124.2(5) . . ?
N1 C5 H5 117.9 . . ?
C4 C5 H5 117.9 . . ?
N1 C1 C2 124.1(5) . . ?
N1 C1 H1 117.9 . . ?
C2 C1 H1 117.9 . . ?
C1 C2 C3 119.7(5) . . ?
C1 C2 H2 120.2 . . ?
C3 C2 H2 120.2 . . ?
N4 C34 C33 123.3(4) . . ?
N4 C34 H34 118.3 . . ?
C33 C34 H34 118.3 . . ?
C35 C36 C32 119.1(5) . . ?
C35 C36 H36 120.4 . . ?
C32 C36 H36 120.4 . . ?
N3 C27 C28 120.6(4) . . ?
N3 C27 H27 119.7 . . ?
C28 C27 H27 119.7 . . ?
N4 C35 C36 123.9(5) . . ?
N4 C35 H35 118.0 . . ?
C36 C35 H35 118.0 . . ?
C27 C28 C29 120.5(4) . . ?
C27 C28 H28 119.8 . . ?
C29 C28 H28 119.8 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.315(3) . ?
Eu1 O8 2.325(3) 2_666 ?
Eu1 O5 2.329(3) . ?
Eu1 O10 2.392(3) . ?
Eu1 O3 2.419(3) 2_456 ?
Eu1 O11 2.482(3) . ?
Eu1 O9 2.485(3) . ?
Eu1 O12 2.545(3) . ?
O8 C23 1.287(5) . ?
O8 Eu1 2.325(3) 2_666 ?
O2 C18 1.249(5) . ?
O10 H10A 0.833(19) . ?
O10 H10B 0.847(19) . ?
O12 H12A 0.837(19) . ?
O12 H12B 0.851(18) . ?
O4 C17 1.260(5) . ?
O5 C19 1.255(5) . ?
O1 C18 1.261(5) . ?
O9 H9A 0.849(19) . ?
O9 H9B 0.834(19) . ?
O7 C23 1.236(5) . ?
O3 C17 1.260(5) . ?
O3 Eu1 2.419(3) 2_456 ?
O11 H11A 0.854(19) . ?
O11 H11B 0.850(19) . ?
O6 C19 1.253(5) . ?
N2 C10 1.353(5) . ?
N2 C9 1.361(5) . ?
N2 C11 1.453(5) . ?
N3 C31 1.338(5) . ?
N3 C27 1.343(5) . ?
N3 C25 1.449(5) . ?
N1 C5 1.322(6) . ?
N1 C1 1.337(7) . ?
N4 C35 1.317(7) . ?
N4 C34 1.327(6) . ?
C20 C21 1.393(5) . ?
C20 C26 1.399(5) . ?
C20 C19 1.516(5) . ?
C21 C22 1.390(5) . ?
C21 H21 0.9500 . ?
C8 C9 1.376(6) . ?
C8 C7 1.395(6) . ?
C8 H8 0.9500 . ?
C22 C24 1.396(5) . ?
C22 C23 1.510(5) . ?
C3 C4 1.391(6) . ?
C3 C2 1.391(7) . ?
C3 C7 1.480(6) . ?
C25 C24 1.378(5) . ?
C25 C26 1.379(5) . ?
C24 H24 0.9500 . ?
C30 C31 1.381(6) . ?
C30 C29 1.384(6) . ?
C30 H30 0.9500 . ?
C17 C13 1.516(5) . ?
C7 C6 1.397(6) . ?
C18 C15 1.513(5) . ?
C31 H31 0.9500 . ?
C26 H26 0.9500 . ?
C15 C16 1.392(5) . ?
C15 C14 1.396(5) . ?
C14 C13 1.394(5) . ?
C14 H14 0.9500 . ?
C13 C12 1.378(5) . ?
C10 C6 1.380(6) . ?
C10 H10 0.9500 . ?
C4 C5 1.383(6) . ?
C4 H4 0.9500 . ?
C16 C11 1.382(6) . ?
C16 H16 0.9500 . ?
C9 H9 0.9500 . ?
C12 C11 1.391(5) . ?
C12 H12 0.9500 . ?
C33 C32 1.378(6) . ?
C33 C34 1.391(6) . ?
C33 H33 0.9500 . ?
C32 C36 1.394(6) . ?
C32 C29 1.489(5) . ?
C29 C28 1.394(6) . ?
C6 H6 0.9500 . ?
C5 H5 0.9500 . ?
C1 C2 1.382(7) . ?
C1 H1 0.9500 . ?
C2 H2 0.9500 . ?
C34 H34 0.9500 . ?
C36 C35 1.388(7) . ?
C36 H36 0.9500 . ?
C27 C28 1.371(6) . ?
C27 H27 0.9500 . ?
C35 H35 0.9500 . ?
C28 H28 0.9500 . ?
