#------------------------------------------------------------------------------
#$Date: 2020-05-28 04:45:35 +0300 (Thu, 28 May 2020) $
#$Revision: 252419 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/05/7240583.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7240583
loop_
_publ_author_name
'Fellowes, Thomas'
'van Koeverden, Martin P.'
'White, Jonathan'
_publ_section_title
;
 Thermal conversion of a pyridine solvate to a de-solvate facilitated by
 rearrangement of chalcogen bonds. The solvate and non-solvate structures
 of N-(2-nitro-4-(3-oxobenzo[d][1,2]selenazol-2(3H)-yl)phenyl)picolinamide
;
_journal_name_full               CrystEngComm
_journal_paper_doi               10.1039/D0CE00662A
_journal_year                    2020
_chemical_formula_sum            'C24 H17 N5 O4 Se'
_chemical_formula_weight         518.39
_space_group_crystal_system      monoclinic
_space_group_IT_number           7
_space_group_name_Hall           'P -2yc'
_space_group_name_H-M_alt        'P 1 c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2020-05-02 deposited with the CCDC.	2020-05-26 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 98.154(4)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   4.9726(2)
_cell_length_b                   14.6836(5)
_cell_length_c                   14.4255(5)
_cell_measurement_reflns_used    3423
_cell_measurement_temperature    100.00(10)
_cell_measurement_theta_max      75.4450
_cell_measurement_theta_min      3.0190
_cell_volume                     1042.64(7)
_computing_cell_refinement       'CrysAlisPro 1.171.40.36a (Rigaku OD, 2018)'
_computing_data_collection       'CrysAlisPro 1.171.40.36a (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.40.36a (Rigaku OD, 2018)'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.00(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0558
_diffrn_reflns_av_unetI/netI     0.0714
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.974
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_h_min       -5
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            6794
_diffrn_reflns_point_group_measured_fraction_full 0.750
_diffrn_reflns_point_group_measured_fraction_max 0.710
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         76.785
_diffrn_reflns_theta_min         3.010
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'PhotonJet (Cu) X-ray Source'
_exptl_absorpt_coefficient_mu    2.829
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.88658
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.40.36a (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.651
_exptl_crystal_description       needle
_exptl_crystal_F_000             524
_exptl_crystal_size_max          0.120
_exptl_crystal_size_mid          0.033
_exptl_crystal_size_min          0.026
_refine_diff_density_max         0.635
_refine_diff_density_min         -0.727
_refine_diff_density_rms         0.091
_refine_ls_abs_structure_details
;
 Flack x determined using 848 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.03(3)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.099
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     307
_refine_ls_number_reflns         3132
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.098
_refine_ls_R_factor_all          0.0447
_refine_ls_R_factor_gt           0.0422
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0561P)²+0.3921P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1088
_refine_ls_wR_factor_ref         0.1106
_reflns_Friedel_coverage         0.451
_reflns_Friedel_fraction_full    0.501
_reflns_Friedel_fraction_max     0.443
_reflns_number_gt                2977
_reflns_number_total             3132
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0ce00662a2.cif
_cod_data_source_block           1PYR
_cod_original_sg_symbol_H-M      'P c'
_cod_database_code               7240583
_shelx_shelxl_version_number     2016/6
_chemical_oxdiff_usercomment     'Tom Fellowes Se intermediate with pyridine'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_oxdiff_exptl_absorpt_empirical_full_min 0.759
_oxdiff_exptl_absorpt_empirical_full_max 1.299
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'x, -y, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 1.2330(12) 0.5110(4) 0.6729(5) 0.0243(12) Uani 1 1 d . . . . .
C2 C 1.3093(12) 0.5973(4) 0.7088(4) 0.0222(11) Uani 1 1 d . . . . .
C3 C 1.5305(13) 0.6068(4) 0.7777(4) 0.0258(12) Uani 1 1 d . . . . .
H3 H 1.585177 0.665562 0.800853 0.031 Uiso 1 1 calc R U . . .
C4 C 1.6726(13) 0.5298(4) 0.8131(4) 0.0276(12) Uani 1 1 d . . . . .
H4 H 1.826941 0.535827 0.859711 0.033 Uiso 1 1 calc R U . . .
C5 C 1.5884(13) 0.4443(4) 0.7800(4) 0.0267(12) Uani 1 1 d . . . . .
H5 H 1.683687 0.391914 0.805695 0.032 Uiso 1 1 calc R U . . .
C6 C 1.3673(12) 0.4335(4) 0.7101(4) 0.0252(12) Uani 1 1 d . . . . .
H6 H 1.309680 0.374611 0.688401 0.030 Uiso 1 1 calc R U . . .
C7 C 1.1338(12) 0.6740(4) 0.6708(4) 0.0226(11) Uani 1 1 d . . . . .
C8 C 0.7315(11) 0.7019(4) 0.5529(4) 0.0188(10) Uani 1 1 d . . . . .
C9 C 0.7489(12) 0.7959(4) 0.5531(4) 0.0206(11) Uani 1 1 d . . . . .
H9 H 0.898111 0.825070 0.589689 0.025 Uiso 1 1 calc R U . . .
C10 C 0.5510(11) 0.8479(4) 0.5003(4) 0.0208(11) Uani 1 1 d . . . . .
C11 C 0.3249(11) 0.8090(4) 0.4432(4) 0.0202(11) Uani 1 1 d . . . . .
C12 C 0.3142(12) 0.7135(4) 0.4435(4) 0.0216(11) Uani 1 1 d . . . . .
H12 H 0.167971 0.683691 0.405880 0.026 Uiso 1 1 calc R U . . .
C13 C 0.5102(12) 0.6615(4) 0.4967(4) 0.0230(11) Uani 1 1 d . . . . .
H13 H 0.494649 0.596976 0.495271 0.028 Uiso 1 1 calc R U . . .
C14 C -0.0780(13) 0.8320(4) 0.3234(4) 0.0238(12) Uani 1 1 d . . . . .
C15 C -0.2640(12) 0.9071(4) 0.2835(4) 0.0217(11) Uani 1 1 d . . . . .
C16 C -0.4970(13) 0.8841(4) 0.2221(5) 0.0265(12) Uani 1 1 d . . . . .
H16 H -0.537524 0.822443 0.205752 0.032 Uiso 1 1 calc R U . . .
C17 C -0.6674(13) 0.9540(5) 0.1859(4) 0.0287(13) Uani 1 1 d . . . . .
H17 H -0.829039 0.941124 0.144456 0.034 Uiso 1 1 calc R U . . .
C18 C -0.5991(15) 1.0423(5) 0.2107(5) 0.0320(14) Uani 1 1 d . . . . .
H18 H -0.712318 1.091243 0.186143 0.038 Uiso 1 1 calc R U . . .
C19 C -0.3628(14) 1.0594(5) 0.2721(5) 0.0310(13) Uani 1 1 d . . . . .
H19 H -0.318420 1.120705 0.288790 0.037 Uiso 1 1 calc R U . . .
C20 C 1.1517(13) 0.3338(4) 0.4694(5) 0.0305(13) Uani 1 1 d . . . . .
H20 H 1.258002 0.379910 0.446034 0.037 Uiso 1 1 calc R U . . .
C21 C 1.1528(14) 0.2469(4) 0.4313(5) 0.0319(13) Uani 1 1 d . . . . .
H21 H 1.257190 0.234340 0.382528 0.038 Uiso 1 1 calc R U . . .
C22 C 1.0007(13) 0.1792(4) 0.4650(5) 0.0296(13) Uani 1 1 d . . . . .
H22 H 1.000860 0.118973 0.440906 0.035 Uiso 1 1 calc R U . . .
C23 C 0.8476(15) 0.2014(4) 0.5349(5) 0.0327(14) Uani 1 1 d . . . . .
H23 H 0.738970 0.156688 0.559480 0.039 Uiso 1 1 calc R U . . .
C24 C 0.8561(14) 0.2904(4) 0.5684(5) 0.0319(14) Uani 1 1 d . . . . .
H24 H 0.748712 0.305730 0.615640 0.038 Uiso 1 1 calc R U . . .
N1 N 0.9300(10) 0.6454(3) 0.6041(3) 0.0218(10) Uani 1 1 d . . . . .
N2 N 0.5932(10) 0.9462(3) 0.5051(4) 0.0220(9) Uani 1 1 d . . . . .
N3 N 0.1254(10) 0.8612(3) 0.3905(4) 0.0212(10) Uani 1 1 d . . . . .
H3A H 0.130909 0.920130 0.401723 0.025 Uiso 1 1 calc R U . . .
N4 N -0.1937(11) 0.9929(4) 0.3092(4) 0.0271(11) Uani 1 1 d . . . . .
N5 N 1.0086(12) 0.3549(4) 0.5370(4) 0.0278(11) Uani 1 1 d . . . . .
O1 O 1.1730(9) 0.7536(3) 0.6982(3) 0.0301(9) Uani 1 1 d . . . . .
O2 O 0.8152(9) 0.9745(3) 0.5429(3) 0.0282(10) Uani 1 1 d . . . . .
O3 O 0.4095(10) 0.9986(3) 0.4719(4) 0.0269(9) Uani 1 1 d . . . . .
O4 O -0.1123(10) 0.7533(3) 0.2960(4) 0.0318(10) Uani 1 1 d . . . . .
Se1 Se 0.93855(7) 0.51659(3) 0.57303(5) 0.02229(18) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.7943 1.1372 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C6 C1 C2 120.6(6) . . ?
C6 C1 Se1 127.1(5) . . ?
C2 C1 Se1 112.3(5) . . ?
C3 C2 C1 120.3(6) . . ?
C3 C2 C7 123.8(5) . . ?
C1 C2 C7 115.9(5) . . ?
C2 C3 C4 119.5(6) . . ?
C2 C3 H3 120.3 . . ?
C4 C3 H3 120.3 . . ?
C5 C4 C3 119.8(6) . . ?
C5 C4 H4 120.1 . . ?
C3 C4 H4 120.1 . . ?
C4 C5 C6 121.4(6) . . ?
C4 C5 H5 119.3 . . ?
C6 C5 H5 119.3 . . ?
C1 C6 C5 118.3(6) . . ?
C1 C6 H6 120.8 . . ?
C5 C6 H6 120.8 . . ?
O1 C7 N1 125.8(5) . . ?
O1 C7 C2 122.7(5) . . ?
N1 C7 C2 111.5(5) . . ?
C9 C8 C13 117.8(5) . . ?
C9 C8 N1 123.1(5) . . ?
C13 C8 N1 119.0(5) . . ?
C8 C9 C10 120.7(5) . . ?
C8 C9 H9 119.6 . . ?
C10 C9 H9 119.6 . . ?
C9 C10 C11 122.7(5) . . ?
C9 C10 N2 115.7(5) . . ?
C11 C10 N2 121.6(5) . . ?
N3 C11 C12 121.9(5) . . ?
N3 C11 C10 122.7(5) . . ?
C12 C11 C10 115.4(5) . . ?
C13 C12 C11 122.0(5) . . ?
C13 C12 H12 119.0 . . ?
C11 C12 H12 119.0 . . ?
C12 C13 C8 121.4(5) . . ?
C12 C13 H13 119.3 . . ?
C8 C13 H13 119.3 . . ?
O4 C14 N3 125.5(6) . . ?
O4 C14 C15 121.3(6) . . ?
N3 C14 C15 113.3(5) . . ?
N4 C15 C16 124.1(6) . . ?
N4 C15 C14 117.4(5) . . ?
C16 C15 C14 118.5(5) . . ?
C17 C16 C15 117.9(6) . . ?
C17 C16 H16 121.0 . . ?
C15 C16 H16 121.0 . . ?
C18 C17 C16 119.0(6) . . ?
C18 C17 H17 120.5 . . ?
C16 C17 H17 120.5 . . ?
C17 C18 C19 119.4(6) . . ?
C17 C18 H18 120.3 . . ?
C19 C18 H18 120.3 . . ?
N4 C19 C18 123.0(6) . . ?
N4 C19 H19 118.5 . . ?
C18 C19 H19 118.5 . . ?
N5 C20 C21 122.6(6) . . ?
N5 C20 H20 118.7 . . ?
C21 C20 H20 118.7 . . ?
C22 C21 C20 119.3(6) . . ?
C22 C21 H21 120.3 . . ?
C20 C21 H21 120.3 . . ?
C21 C22 C23 118.2(6) . . ?
C21 C22 H22 120.9 . . ?
C23 C22 H22 120.9 . . ?
C22 C23 C24 118.8(6) . . ?
C22 C23 H23 120.6 . . ?
C24 C23 H23 120.6 . . ?
N5 C24 C23 122.7(6) . . ?
N5 C24 H24 118.7 . . ?
C23 C24 H24 118.7 . . ?
C7 N1 C8 125.6(5) . . ?
C7 N1 Se1 115.1(4) . . ?
C8 N1 Se1 119.1(4) . . ?
O2 N2 O3 121.8(5) . . ?
O2 N2 C10 117.9(5) . . ?
O3 N2 C10 120.2(5) . . ?
C14 N3 C11 127.8(5) . . ?
C14 N3 H3A 116.1 . . ?
C11 N3 H3A 116.1 . . ?
C15 N4 C19 116.5(6) . . ?
C20 N5 C24 118.4(6) . . ?
C20 N5 Se1 119.2(4) . . ?
C24 N5 Se1 120.6(4) . . ?
C1 Se1 N1 84.7(2) . . ?
C1 Se1 N5 90.1(2) . . ?
N1 Se1 N5 173.2(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C6 1.389(9) . ?
C1 C2 1.400(9) . ?
C1 Se1 1.905(7) . ?
C2 C3 1.382(9) . ?
C2 C7 1.482(8) . ?
C3 C4 1.391(9) . ?
C3 H3 0.9500 . ?
C4 C5 1.387(9) . ?
C4 H4 0.9500 . ?
C5 C6 1.392(9) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 O1 1.240(7) . ?
C7 N1 1.361(8) . ?
C8 C9 1.382(8) . ?
C8 C13 1.403(8) . ?
C8 N1 1.415(7) . ?
C9 C10 1.385(8) . ?
C9 H9 0.9500 . ?
C10 C11 1.417(8) . ?
C10 N2 1.459(7) . ?
C11 N3 1.392(7) . ?
C11 C12 1.403(8) . ?
C12 C13 1.383(8) . ?
C12 H12 0.9500 . ?
C13 H13 0.9500 . ?
C14 O4 1.224(8) . ?
C14 N3 1.366(8) . ?
C14 C15 1.500(8) . ?
C15 N4 1.346(8) . ?
C15 C16 1.396(9) . ?
C16 C17 1.385(9) . ?
C16 H16 0.9500 . ?
C17 C18 1.375(11) . ?
C17 H17 0.9500 . ?
C18 C19 1.390(10) . ?
C18 H18 0.9500 . ?
C19 N4 1.348(9) . ?
C19 H19 0.9500 . ?
C20 N5 1.323(9) . ?
C20 C21 1.389(9) . ?
C20 H20 0.9500 . ?
C21 C22 1.379(10) . ?
C21 H21 0.9500 . ?
C22 C23 1.386(10) . ?
C22 H22 0.9500 . ?
C23 C24 1.392(9) . ?
C23 H23 0.9500 . ?
C24 N5 1.332(9) . ?
C24 H24 0.9500 . ?
N1 Se1 1.945(5) . ?
N2 O2 1.232(7) . ?
N2 O3 1.237(7) . ?
N3 H3A 0.8800 . ?
N5 Se1 2.466(5) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C6 H6 N5 0.95 2.48 3.080(8) 120.8 .
C9 H9 O1 0.95 2.19 2.822(7) 122.7 .
C12 H12 O4 0.95 2.21 2.843(7) 123.4 .
C13 H13 Se1 0.95 2.61 3.100(6) 112.3 .
C18 H18 O1 0.95 2.36 3.200(8) 147.0 2_374
C21 H21 O1 0.95 2.64 3.378(8) 135.1 2_564
N3 H3A N4 0.88 2.22 2.665(7) 111.2 .
N3 H3A O3 0.88 1.97 2.641(7) 132.2 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 4.1(9) . . . . ?
Se1 C1 C2 C3 -176.0(5) . . . . ?
C6 C1 C2 C7 -173.7(5) . . . . ?
Se1 C1 C2 C7 6.2(7) . . . . ?
C1 C2 C3 C4 -1.7(10) . . . . ?
C7 C2 C3 C4 175.9(6) . . . . ?
C2 C3 C4 C5 -1.1(10) . . . . ?
C3 C4 C5 C6 1.6(10) . . . . ?
C2 C1 C6 C5 -3.5(9) . . . . ?
Se1 C1 C6 C5 176.5(5) . . . . ?
C4 C5 C6 C1 0.7(9) . . . . ?
C3 C2 C7 O1 0.1(10) . . . . ?
C1 C2 C7 O1 177.9(6) . . . . ?
C3 C2 C7 N1 -179.6(6) . . . . ?
C1 C2 C7 N1 -1.9(8) . . . . ?
C13 C8 C9 C10 1.0(9) . . . . ?
N1 C8 C9 C10 178.8(5) . . . . ?
C8 C9 C10 C11 -0.8(9) . . . . ?
C8 C9 C10 N2 -179.2(5) . . . . ?
C9 C10 C11 N3 179.8(5) . . . . ?
N2 C10 C11 N3 -2.0(8) . . . . ?
C9 C10 C11 C12 0.0(8) . . . . ?
N2 C10 C11 C12 178.2(5) . . . . ?
N3 C11 C12 C13 -179.1(6) . . . . ?
C10 C11 C12 C13 0.7(8) . . . . ?
C11 C12 C13 C8 -0.5(9) . . . . ?
C9 C8 C13 C12 -0.4(9) . . . . ?
N1 C8 C13 C12 -178.3(5) . . . . ?
O4 C14 C15 N4 -172.3(6) . . . . ?
N3 C14 C15 N4 7.4(8) . . . . ?
O4 C14 C15 C16 7.5(9) . . . . ?
N3 C14 C15 C16 -172.8(5) . . . . ?
N4 C15 C16 C17 -0.4(9) . . . . ?
C14 C15 C16 C17 179.9(6) . . . . ?
C15 C16 C17 C18 0.7(9) . . . . ?
C16 C17 C18 C19 -0.6(10) . . . . ?
C17 C18 C19 N4 0.1(11) . . . . ?
N5 C20 C21 C22 -0.4(11) . . . . ?
C20 C21 C22 C23 1.2(10) . . . . ?
C21 C22 C23 C24 -0.6(10) . . . . ?
C22 C23 C24 N5 -1.0(11) . . . . ?
O1 C7 N1 C8 1.7(10) . . . . ?
C2 C7 N1 C8 -178.6(5) . . . . ?
O1 C7 N1 Se1 176.9(5) . . . . ?
C2 C7 N1 Se1 -3.4(6) . . . . ?
C9 C8 N1 C7 11.7(9) . . . . ?
C13 C8 N1 C7 -170.5(6) . . . . ?
C9 C8 N1 Se1 -163.4(4) . . . . ?
C13 C8 N1 Se1 14.4(7) . . . . ?
C9 C10 N2 O2 10.6(8) . . . . ?
C11 C10 N2 O2 -167.8(6) . . . . ?
C9 C10 N2 O3 -169.3(5) . . . . ?
C11 C10 N2 O3 12.3(8) . . . . ?
O4 C14 N3 C11 -2.7(10) . . . . ?
C15 C14 N3 C11 177.6(5) . . . . ?
C12 C11 N3 C14 -10.5(9) . . . . ?
C10 C11 N3 C14 169.8(6) . . . . ?
C16 C15 N4 C19 -0.1(9) . . . . ?
C14 C15 N4 C19 179.7(6) . . . . ?
C18 C19 N4 C15 0.2(10) . . . . ?
C21 C20 N5 C24 -1.2(10) . . . . ?
C21 C20 N5 Se1 -165.9(5) . . . . ?
C23 C24 N5 C20 1.9(10) . . . . ?
C23 C24 N5 Se1 166.4(5) . . . . ?
