#------------------------------------------------------------------------------
#$Date: 2020-06-04 04:41:58 +0300 (Thu, 04 Jun 2020) $
#$Revision: 252627 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/06/7240603.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7240603
loop_
_publ_author_name
'Bo, Qi-Bing'
'Wang, Jia-Yin'
'Shi, Yang'
'Tao, Dong-Liang'
'Yin, Guo-Yin'
_publ_section_title
;
 2D chain layer versus 1D chain: rigid aromatic benzoate disassembling
 flexible alicyclic dicarboxylate-based lanthanide coordination polymers
 with enhanced photoluminescence and characteristic behavior of
 single-molecule magnet.
;
_journal_name_full               CrystEngComm
_journal_paper_doi               10.1039/D0CE00583E
_journal_year                    2020
_chemical_formula_moiety         '0.5(C30 H36 Dy4 O30)'
_chemical_formula_sum            'C15 H18 Dy2 O15'
_chemical_formula_weight         763.29
_space_group_crystal_system      monoclinic
_space_group_IT_number           11
_space_group_name_Hall           '-P 2yb'
_space_group_name_H-M_alt        'P 1 21/m 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_audit_creation_date             2019-11-02
_audit_creation_method
;
Olex2 1.2-alpha
(compiled 2016.11.07 svn.r3352 for OlexSys, GUI svn.r5261)
;
_audit_update_record
;
2019-11-02 deposited with the CCDC.	2020-06-03 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 106.22(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   9.759(2)
_cell_length_b                   7.9677(16)
_cell_length_c                   12.790(3)
_cell_measurement_reflns_used    2334
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.5400
_cell_measurement_theta_min      4.1860
_cell_volume                     954.9(4)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SIR2004 (Burla et al., 2007)'
_diffrn_ambient_temperature      293.15
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.0355
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_details
;
#__ type_ start__ end____ width___ exp.time_
  1 omega   35.00   88.00   1.0000    1.9850
omega____ theta____ kappa____ phi______ frames
    -       15.8569  178.0000  -60.0000 53

#__ type_ start__ end____ width___ exp.time_
  2 omega   35.00   88.00   1.0000    1.9850
omega____ theta____ kappa____ phi______ frames
    -       15.8569  178.0000  150.0000 53

#__ type_ start__ end____ width___ exp.time_
  3 omega  -51.00   33.00   1.0000    1.9850
omega____ theta____ kappa____ phi______ frames
    -       15.8569  -57.0000    0.0000 84

#__ type_ start__ end____ width___ exp.time_
  4 omega  -14.00   87.00   1.0000    1.9850
omega____ theta____ kappa____ phi______ frames
    -       15.8569   19.0000    0.0000 101

#__ type_ start__ end____ width___ exp.time_
  5 omega  -11.00   24.00   1.0000    1.9850
omega____ theta____ kappa____ phi______ frames
    -       15.8569   77.0000   60.0000 35
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      0.0261526000
_diffrn_orient_matrix_UB_12      0.0183357000
_diffrn_orient_matrix_UB_13      0.0565472000
_diffrn_orient_matrix_UB_21      -0.0355828000
_diffrn_orient_matrix_UB_22      -0.0720690000
_diffrn_orient_matrix_UB_23      0.0116426000
_diffrn_orient_matrix_UB_31      0.0613910000
_diffrn_orient_matrix_UB_32      -0.0490600000
_diffrn_orient_matrix_UB_33      0.0026529000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.710
_diffrn_reflns_av_R_equivalents  0.1028
_diffrn_reflns_av_unetI/netI     0.0993
_diffrn_reflns_Laue_measured_fraction_full 0.993
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            6076
_diffrn_reflns_point_group_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_theta_full        25.214
_diffrn_reflns_theta_max         26.339
_diffrn_reflns_theta_min         3.314
_diffrn_source                   'Enhance (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    7.848
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.29451
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear whiteish white'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   whiteish
_exptl_crystal_colour_primary    white
_exptl_crystal_density_diffrn    2.654
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             720
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.024
_refine_diff_density_max         4.777
_refine_diff_density_min         -5.173
_refine_diff_density_rms         0.495
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.076
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     89
_refine_ls_number_reflns         2076
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.076
_refine_ls_R_factor_all          0.1100
_refine_ls_R_factor_gt           0.0963
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[σ²(Fo²)+(0.0366P)²+120.5462P]
 where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2124
_refine_ls_wR_factor_ref         0.2233
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1646
_reflns_number_total             2076
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0ce00583e2.cif
_cod_data_source_block           cpdc-Dy
_cod_original_cell_volume        955.0(4)
_cod_database_code               7240603
_shelxl_version_number           2013-2
_chemical_oxdiff_formula         'C H O Dy'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.834
_shelx_estimated_absorpt_t_min   0.154
_reflns_odcompleteness_completeness 99.38
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All O(H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(O1) = Uanis(O2) = Uanis(C1) = Uanis(C2) = Uanis(C3)
Uanis(O3) = Uanis(C4) = Uanis(C5) = Uanis(C6)
Uanis(O6) = Uanis(O5) = Uanis(C7) = Uanis(C8) = Uanis(C9)
Uanis(O7) = Uanis(O8) = Uanis(O9)
3. Others
 Fixed Sof: H7A(0.5) H7B(0.5) H8A(0.5) H8B(0.5) H9A(0.5) H9B(0.5)
4.a Riding coordinates:
 O7(H7A,H7B), O8(H8A,H8B), O9(H9A,H9B)
4.b Ternary CH refined with riding coordinates:
 C2(H2), C5(H5), C8(H8)
4.c Secondary CH2 refined with riding coordinates:
 C3(H3A,H3B), C6(H6A,H6B), C9(H9C,H9D)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.49022(13) 0.7500 0.13299(11) 0.0159(4) Uani 1 2 d S T P . .
Dy2 Dy 0.89520(13) 0.2500 0.50500(11) 0.0219(4) Uani 1 2 d S T P . .
O1 O 0.5837(16) 0.570(2) 0.2753(15) 0.045(3) Uani 1 1 d . . . . .
O2 O 0.7201(16) 0.426(2) 0.4136(15) 0.045(3) Uani 1 1 d . . . . .
O3 O 0.6564(13) 0.9311(17) 0.0884(12) 0.021(2) Uani 1 1 d . . . . .
O4 O 0.6797(15) 1.041(2) -0.0665(12) 0.028(3) Uani 1 1 d . . . . .
O5 O 0.9976(18) 0.574(2) 0.5980(13) 0.035(2) Uani 1 1 d . . . . .
O6 O 0.8446(18) 0.423(2) 0.6465(13) 0.035(2) Uani 1 1 d . . . . .
O7 O 0.452(2) 0.7500 -0.0636(19) 0.028(3) Uani 1 2 d S T P . .
H7A H 0.4073 0.8288 -0.1054 0.042 Uiso 0.5 1 d R . . . .
H7B H 0.4056 0.6721 -0.1054 0.042 Uiso 0.5 1 d R . . . .
O8 O 0.321(2) 0.7500 0.2389(19) 0.028(3) Uani 1 2 d S T P . .
H8A H 0.3099 0.8225 0.2856 0.042 Uiso 0.5 1 d R . . . .
H8B H 0.2568 0.6773 0.2402 0.042 Uiso 0.5 1 d R . . . .
O9 O 1.134(2) 0.2500 0.6153(19) 0.028(3) Uani 1 2 d S T P . .
H9A H 1.1669 0.1744 0.6639 0.042 Uiso 0.5 1 d R . . . .
H9B H 1.2114 0.2951 0.6087 0.042 Uiso 0.5 1 d R . . . .
C1 C 0.600(2) 0.452(4) 0.341(2) 0.045(3) Uani 1 1 d . . . . .
C2 C 0.474(2) 0.347(3) 0.343(2) 0.045(3) Uani 1 1 d . . . . .
H2 H 0.3824 0.3961 0.3026 0.054 Uiso 1 1 calc R . . . .
C3 C 0.465(4) 0.2500 0.442(3) 0.045(3) Uani 1 2 d S T P . .
H3A H 0.3751 0.2500 0.4594 0.054 Uiso 1 2 calc RS T P . .
H3B H 0.5490 0.2500 0.5042 0.054 Uiso 1 2 calc RS T P . .
C4 C 0.718(2) 0.945(2) 0.0139(17) 0.021(2) Uani 1 1 d . . . . .
C5 C 0.8508(19) 0.846(2) 0.0218(17) 0.021(2) Uani 1 1 d . . . . .
H5 H 0.9149 0.8970 -0.0162 0.025 Uiso 1 1 calc R . . . .
C6 C 0.926(3) 0.7500 0.123(3) 0.021(2) Uani 1 2 d S T P . .
H6A H 1.0296 0.7500 0.1452 0.025 Uiso 1 2 calc RS T P . .
H6B H 0.8830 0.7500 0.1832 0.025 Uiso 1 2 calc RS T P . .
C7 C 0.923(3) 0.551(3) 0.6611(19) 0.035(2) Uani 1 1 d . . . . .
C8 C 0.925(3) 0.656(3) 0.7553(19) 0.035(2) Uani 1 1 d . . . . .
H8 H 0.8773 0.6057 0.8055 0.042 Uiso 1 1 calc R . . . .
C9 C 1.061(4) 0.7500 0.811(3) 0.035(2) Uani 1 2 d S T P . .
H9C H 1.0918 0.7500 0.8902 0.042 Uiso 1 2 calc RS T P . .
H9D H 1.1376 0.7500 0.7766 0.042 Uiso 1 2 calc RS T P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 O1 77.4(10) . 4_575 ?
O1 Dy1 O3 115.2(5) . . ?
O1 Dy1 O3 70.2(6) 4_575 . ?
O1 Dy1 O3 115.2(5) 4_575 4_575 ?
O1 Dy1 O3 70.2(6) . 4_575 ?
O1 Dy1 O4 85.8(6) . 2_645 ?
O1 Dy1 O4 144.9(6) 4_575 2_645 ?
O1 Dy1 O4 144.9(6) . 3_675 ?
O1 Dy1 O4 85.8(6) 4_575 3_675 ?
O1 Dy1 O7 136.9(5) . . ?
O1 Dy1 O7 136.9(5) 4_575 . ?
O1 Dy1 O8 74.8(6) . . ?
O1 Dy1 O8 74.7(6) 4_575 . ?
O3 Dy1 O3 75.5(6) 4_575 . ?
O3 Dy1 O7 70.6(5) 4_575 . ?
O3 Dy1 O7 70.6(5) . . ?
O3 Dy1 O8 139.6(4) 4_575 . ?
O3 Dy1 O8 139.6(4) . . ?
O4 Dy1 O3 144.6(5) 3_675 4_575 ?
O4 Dy1 O3 144.6(5) 2_645 . ?
O4 Dy1 O3 86.7(5) 2_645 4_575 ?
O4 Dy1 O3 86.7(5) 3_675 . ?
O4 Dy1 O4 90.9(8) 2_645 3_675 ?
O4 Dy1 O7 74.7(5) 3_675 . ?
O4 Dy1 O7 74.7(5) 2_645 . ?
O4 Dy1 O8 71.1(5) 2_645 . ?
O4 Dy1 O8 71.1(5) 3_675 . ?
O8 Dy1 O7 130.4(7) . . ?
O2 Dy2 O2 76.5(9) 4_565 . ?
O2 Dy2 O5 77.5(6) 4_565 4_565 ?
O2 Dy2 O5 117.9(7) 4_565 3_766 ?
O2 Dy2 O5 152.4(6) . 4_565 ?
O2 Dy2 O5 74.5(6) 4_565 2_746 ?
O2 Dy2 O5 74.5(6) . 3_766 ?
O2 Dy2 O5 77.5(6) . . ?
O2 Dy2 O5 117.9(7) . 2_746 ?
O2 Dy2 O5 152.4(6) 4_565 . ?
O2 Dy2 O6 75.7(6) 4_565 4_565 ?
O2 Dy2 O6 117.0(6) . 4_565 ?
O2 Dy2 O6 117.0(6) 4_565 . ?
O2 Dy2 O6 75.7(6) . . ?
O2 Dy2 O9 141.5(5) . . ?
O2 Dy2 O9 141.5(5) 4_565 . ?
O5 Dy2 O5 127.0(3) 3_766 4_565 ?
O5 Dy2 O5 63.0(6) 3_766 . ?
O5 Dy2 O5 72.8(8) 2_746 3_766 ?
O5 Dy2 O5 63.0(6) 2_746 4_565 ?
O5 Dy2 O5 127.0(3) 2_746 . ?
O5 Dy2 O5 125.8(6) . 4_565 ?
O5 Dy2 O6 107.1(5) 3_766 . ?
O5 Dy2 O6 165.0(6) 3_766 4_565 ?
O5 Dy2 O6 107.1(5) 2_746 4_565 ?
O5 Dy2 O6 165.0(6) 2_746 . ?
O5 Dy2 O9 79.4(6) 2_746 . ?
O5 Dy2 O9 79.4(6) 3_766 . ?
O6 Dy2 O5 46.3(5) 4_565 4_565 ?
O6 Dy2 O5 108.5(5) 4_565 . ?
O6 Dy2 O5 46.3(5) . . ?
O6 Dy2 O5 108.5(5) . 4_565 ?
O6 Dy2 O6 69.0(7) . 4_565 ?
O9 Dy2 O5 65.6(3) . 4_565 ?
O9 Dy2 O5 65.6(4) . . ?
O9 Dy2 O6 85.8(6) . . ?
O9 Dy2 O6 85.8(6) . 4_565 ?
C1 O1 Dy1 163.1(16) . . ?
C1 O2 Dy2 150.5(19) . . ?
C4 O3 Dy1 137.7(13) . . ?
C4 O4 Dy1 138.9(13) . 3_675 ?
Dy2 O5 Dy2 117.0(6) 3_766 . ?
C7 O5 Dy2 86.3(15) . . ?
C7 O5 Dy2 152.2(16) . 3_766 ?
C7 O6 Dy2 109.0(15) . . ?
Dy1 O7 H7A 123.2 . . ?
Dy1 O7 H7B 122.9 . . ?
H7A O7 H7B 93.1 . . ?
Dy1 O8 H8A 129.2 . . ?
Dy1 O8 H8B 129.2 . . ?
H8A O8 H8B 101.6 . . ?
Dy2 O9 H9A 122.4 . . ?
Dy2 O9 H9B 133.4 . . ?
H9A O9 H9B 101.9 . . ?
O1 C1 O2 122(2) . . ?
O1 C1 C2 119(2) . . ?
O2 C1 C2 119(2) . . ?
C1 C2 C2 124.0(14) . 4_565 ?
C1 C2 H2 113.5 . . ?
C1 C2 C3 123(2) . . ?
C2 C2 H2 113.5 4_565 . ?
C3 C2 C2 58.9(14) . 4_565 ?
C3 C2 H2 113.5 . . ?
C2 C3 C2 62(3) . 4_565 ?
C2 C3 H3A 117.5 . . ?
C2 C3 H3A 117.5 4_565 . ?
C2 C3 H3B 117.5 . . ?
C2 C3 H3B 117.5 4_565 . ?
H3A C3 H3B 114.6 . . ?
O3 C4 C5 119.2(17) . . ?
O4 C4 O3 125.1(18) . . ?
O4 C4 C5 115.6(17) . . ?
C4 C5 C5 121.7(10) . 4_575 ?
C4 C5 H5 114.3 . . ?
C4 C5 C6 122.0(19) . . ?
C5 C5 H5 114.3 4_575 . ?
C6 C5 C5 59.5(9) . 4_575 ?
C6 C5 H5 114.3 . . ?
C5 C6 C5 61.1(18) 4_575 . ?
C5 C6 H6A 117.7 . . ?
C5 C6 H6A 117.7 4_575 . ?
C5 C6 H6B 117.7 4_575 . ?
C5 C6 H6B 117.7 . . ?
H6A C6 H6B 114.8 . . ?
O5 C7 O6 118(2) . . ?
O5 C7 C8 125(2) . . ?
O6 C7 C8 117(2) . . ?
C7 C8 C8 124.9(12) . 4_575 ?
C7 C8 H8 114.1 . . ?
C7 C8 C9 119(2) . . ?
C8 C8 H8 114.1 4_575 . ?
C8 C8 C9 60.4(11) 4_575 . ?
C9 C8 H8 114.1 . . ?
C8 C9 C8 59(2) 4_575 . ?
C8 C9 H9C 117.8 4_575 . ?
C8 C9 H9C 117.8 . . ?
C8 C9 H9D 117.8 . . ?
C8 C9 H9D 117.8 4_575 . ?
H9C C9 H9D 115.0 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O1 2.299(17) . ?
Dy1 O1 2.299(17) 4_575 ?
Dy1 O3 2.356(13) . ?
Dy1 O3 2.356(13) 4_575 ?
Dy1 O4 2.335(15) 3_675 ?
Dy1 O4 2.335(15) 2_645 ?
Dy1 O7 2.44(2) . ?
Dy1 O8 2.41(2) . ?
Dy2 O2 2.267(16) 4_565 ?
Dy2 O2 2.267(16) . ?
Dy2 O5 2.358(16) 2_746 ?
Dy2 O5 2.358(16) 3_766 ?
Dy2 O5 2.904(17) . ?
Dy2 O5 2.904(17) 4_565 ?
Dy2 O6 2.433(17) . ?
Dy2 O6 2.433(17) 4_565 ?
Dy2 O9 2.36(2) . ?
O1 C1 1.24(3) . ?
O2 C1 1.29(3) . ?
O3 C4 1.27(2) . ?
O4 Dy1 2.335(15) 3_675 ?
O4 C4 1.25(2) . ?
O5 Dy2 2.358(16) 3_766 ?
O5 C7 1.24(3) . ?
O6 C7 1.26(3) . ?
O7 H7A 0.8600 . ?
O7 H7B 0.8599 . ?
O8 H8A 0.8600 . ?
O8 H8B 0.8600 . ?
O9 H9A 0.8600 . ?
O9 H9B 0.8602 . ?
C1 C2 1.49(3) . ?
C2 C2 1.55(5) 4_565 ?
C2 H2 0.9800 . ?
C2 C3 1.50(4) . ?
C3 C2 1.50(4) 4_565 ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C4 C5 1.49(2) . ?
C5 C5 1.54(4) 4_575 ?
C5 H5 0.9800 . ?
C5 C6 1.51(3) . ?
C6 C5 1.51(3) 4_575 ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C8 1.46(3) . ?
C8 C8 1.50(4) 4_575 ?
C8 H8 0.9800 . ?
C8 C9 1.52(4) . ?
C9 C8 1.52(4) 4_575 ?
C9 H9C 0.9700 . ?
C9 H9D 0.9700 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 O1 C1 O2 174(5) . . . . ?
Dy1 O1 C1 C2 -12(9) . . . . ?
Dy1 O3 C4 O4 98(2) . . . . ?
Dy1 O3 C4 C5 -84(2) . . . . ?
Dy1 O4 C4 O3 5(4) 3_675 . . . ?
Dy1 O4 C4 C5 -172.6(14) 3_675 . . . ?
Dy2 O2 C1 O1 -135(3) . . . . ?
Dy2 O2 C1 C2 51(5) . . . . ?
Dy2 O5 C7 O6 143(3) 3_766 . . . ?
Dy2 O5 C7 O6 -5(2) . . . . ?
Dy2 O5 C7 C8 171(2) . . . . ?
Dy2 O5 C7 C8 -40(5) 3_766 . . . ?
Dy2 O6 C7 O5 7(3) . . . . ?
Dy2 O6 C7 C8 -170.2(17) . . . . ?
O1 C1 C2 C2 132(2) . . . 4_565 ?
O1 C1 C2 C3 -156(3) . . . . ?
O2 C1 C2 C2 -54(3) . . . 4_565 ?
O2 C1 C2 C3 19(4) . . . . ?
O3 C4 C5 C5 62(2) . . . 4_575 ?
O3 C4 C5 C6 -9(3) . . . . ?
O4 C4 C5 C5 -120.1(15) . . . 4_575 ?
O4 C4 C5 C6 168.5(17) . . . . ?
O5 C7 C8 C8 44(3) . . . 4_575 ?
O5 C7 C8 C9 -28(3) . . . . ?
O6 C7 C8 C8 -138.9(16) . . . 4_575 ?
O6 C7 C8 C9 149(2) . . . . ?
C1 C2 C3 C2 -113(2) . . . 4_565 ?
C4 C5 C6 C5 110.6(16) . . . 4_575 ?
C7 C8 C9 C8 116.0(18) . . . 4_575 ?
