#------------------------------------------------------------------------------
#$Date: 2020-10-06 14:47:07 +0300 (Tue, 06 Oct 2020) $
#$Revision: 258128 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/08/7240895.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7240895
loop_
_publ_author_name
'Battistin, Federica'
'Vidal, Alessio'
'Balducci, Gabriele'
'Alessio, Enzo'
_publ_section_title
;
 Investigating the reactivity of neutral water-soluble Ru(ii)--PTA
 carbonyls towards the model imine ligands pyridine and
 2,2′-bipyridine
;
_journal_issue                   45
_journal_name_full               'RSC Advances'
_journal_page_first              26717
_journal_page_last               26727
_journal_paper_doi               10.1039/D0RA05898J
_journal_volume                  10
_journal_year                    2020
_chemical_formula_moiety         'C17 H20 Cl2 N5 O P Ru, H2 O'
_chemical_formula_sum            'C17 H22 Cl2 N5 O2 P Ru'
_chemical_formula_weight         531.33
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   difmap
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2020-06-04 deposited with the CCDC.	2020-07-07 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 94.767(19)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   6.799(10)
_cell_length_b                   21.768(5)
_cell_length_c                   13.521(3)
_cell_measurement_reflns_used    26966
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      33.091
_cell_measurement_theta_min      1.751
_cell_volume                     1994(3)
_computing_cell_refinement       'XDS (Kabsch, 2010)'
_computing_data_collection       'Elettra XRD1 Data Collection SW'
_computing_data_reduction        'XDS - CCP4'
_computing_molecular_graphics
;
ShelXle (Hubschle et al. 2011)
Coot (Emsley et al., 2010) 
Ortep3 for Windows (Farrugia, 2012)
;
_computing_publication_material  'private software'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution
'SHELXT (Sheldrick, 2015), Sir2014 (Burla, 2015)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.862
_diffrn_measurement_device_type
;
Huber 4-circles Kappa Goniometer, Pilatus 2M detector
;
_diffrn_measurement_method       'Rotating crystal'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.700
_diffrn_reflns_av_R_equivalents  0.0466
_diffrn_reflns_av_unetI/netI     0.0285
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.862
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       -33
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            41070
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.862
_diffrn_reflns_theta_full        24.835
_diffrn_reflns_theta_max         33.091
_diffrn_reflns_theta_min         1.751
_diffrn_source                   'Elettra Synchrotron - XRD1 BL'
_exptl_absorpt_coefficient_mu    1.097
_exptl_absorpt_correction_T_max  1.106
_exptl_absorpt_correction_T_min  0.786
_exptl_absorpt_correction_type   refdelf
_exptl_absorpt_process_details
;
        Parkin S,Moezzi B & Hope H, (1995) J. Appl. Cryst. 28, 53-56
        Cubic fit to sin(theta)/lambda - 24 parameters
;
_exptl_crystal_colour            'pale orange'
_exptl_crystal_density_diffrn    1.770
_exptl_crystal_description       needle
_exptl_crystal_F_000             1072
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: water'
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.100
_refine_diff_density_max         0.911
_refine_diff_density_min         -0.828
_refine_diff_density_rms         0.143
_refine_ls_extinction_coef       0.0537(12)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2017/1 (Sheldrick 2017)'
_refine_ls_goodness_of_fit_ref   1.007
_refine_ls_hydrogen_treatment    refxyz
_refine_ls_matrix_type           full
_refine_ls_number_parameters     321
_refine_ls_number_reflns         6828
_refine_ls_number_restraints     29
_refine_ls_restrained_S_all      1.005
_refine_ls_R_factor_all          0.0279
_refine_ls_R_factor_gt           0.0278
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0538P)²+1.5208P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0805
_refine_ls_wR_factor_ref         0.0807
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6754
_reflns_number_total             6828
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0ra05898j2.cif
_cod_data_source_block           fb290-05
_cod_depositor_comments
'Adding full bibliography for 7240894--7240896.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7240895
_shelx_shelxl_version_number     2017/1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.771
_shelx_estimated_absorpt_t_max   0.898
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.43380(2) 0.60986(2) 0.68961(2) 0.00958(5) Uani 1 1 d . . . . .
Cl1 Cl 0.66328(5) 0.68272(2) 0.76967(3) 0.01598(7) Uani 1 1 d . . . . .
Cl2 Cl 0.21947(4) 0.53801(2) 0.59909(2) 0.01337(7) Uani 1 1 d . . . . .
C1 C 0.3028(2) 0.61044(6) 0.80348(11) 0.0134(2) Uani 1 1 d . . . . .
O1 O 0.22895(17) 0.61655(5) 0.87683(9) 0.0186(2) Uani 1 1 d . . . . .
P2 P 0.60895(5) 0.52598(2) 0.75277(2) 0.01007(7) Uani 1 1 d . . . . .
N21 N 0.94591(17) 0.47632(6) 0.84969(9) 0.0141(2) Uani 1 1 d . . . . .
N22 N 0.75524(18) 0.40873(6) 0.72884(9) 0.0156(2) Uani 1 1 d . . . . .
N23 N 0.62717(17) 0.43160(6) 0.89151(9) 0.0140(2) Uani 1 1 d . . . . .
C21 C 0.86368(19) 0.53501(6) 0.80949(10) 0.0136(2) Uani 1 1 d D . . . .
H21A H 0.945(3) 0.5501(8) 0.7581(9) 0.020 Uiso 1 1 d D U . . .
H21B H 0.866(3) 0.5649(6) 0.8638(9) 0.018(5) Uiso 1 1 d D . . . .
C22 C 0.6471(2) 0.45844(6) 0.67245(10) 0.0149(2) Uani 1 1 d D . . . .
H22A H 0.722(2) 0.4696(10) 0.6162(8) 0.022 Uiso 1 1 d D U . . .
H22B H 0.5141(12) 0.4453(10) 0.6479(11) 0.022 Uiso 1 1 d D U . . .
C23 C 0.50520(19) 0.48502(6) 0.85644(10) 0.0137(2) Uani 1 1 d D . . . .
H23A H 0.505(2) 0.5140(8) 0.9119(10) 0.021 Uiso 1 1 d D U . . .
H23B H 0.3694(9) 0.4725(9) 0.8361(14) 0.021 Uiso 1 1 d D U . . .
C24 C 0.9515(2) 0.42972(7) 0.77099(11) 0.0162(2) Uani 1 1 d D . . . .
H24A H 1.020(3) 0.3938(7) 0.8009(14) 0.024 Uiso 1 1 d D U . . .
H24B H 1.024(2) 0.4450(8) 0.7164(11) 0.024 Uiso 1 1 d D U . . .
C25 C 0.6435(2) 0.38650(6) 0.81040(12) 0.0165(3) Uani 1 1 d D . . . .
H25A H 0.718(2) 0.3503(5) 0.8349(16) 0.025 Uiso 1 1 d D U . . .
H25B H 0.5119(14) 0.3738(8) 0.7828(17) 0.025 Uiso 1 1 d D U . . .
C26 C 0.82962(19) 0.45180(7) 0.92799(10) 0.0146(2) Uani 1 1 d D . . . .
H26A H 0.899(3) 0.4159(5) 0.9573(12) 0.022 Uiso 1 1 d D U . . .
H26B H 0.824(3) 0.4840(6) 0.9784(9) 0.022 Uiso 1 1 d D U . . .
N31 N 0.26630(17) 0.68227(5) 0.61725(9) 0.01281(19) Uani 1 1 d . . . . .
N32 N 0.58538(16) 0.62666(5) 0.55855(8) 0.01145(18) Uani 1 1 d . . . . .
C32 C 0.1015(2) 0.70717(6) 0.65019(11) 0.0159(2) Uani 1 1 d D . . . .
H32 H 0.065(3) 0.6919(10) 0.7144(8) 0.024 Uiso 1 1 d D U . . .
C33 C -0.0085(2) 0.75227(6) 0.59714(12) 0.0176(2) Uani 1 1 d D . . . .
H33 H -0.124(2) 0.7698(10) 0.6255(16) 0.026 Uiso 1 1 d D U . . .
C34 C 0.0529(2) 0.77247(7) 0.50727(12) 0.0188(3) Uani 1 1 d D . . . .
H34 H -0.019(3) 0.8046(8) 0.4685(15) 0.028 Uiso 1 1 d D U . . .
C35 C 0.2213(2) 0.74628(6) 0.47247(11) 0.0176(2) Uani 1 1 d D . . . .
H35 H 0.271(3) 0.7600(11) 0.4101(9) 0.026 Uiso 1 1 d D U . . .
C36 C 0.32498(19) 0.70118(6) 0.52885(10) 0.0131(2) Uani 1 1 d . . . . .
C37 C 0.50580(19) 0.67174(6) 0.49765(10) 0.0122(2) Uani 1 1 d . . . . .
C38 C 0.5952(2) 0.69025(6) 0.41333(11) 0.0158(2) Uani 1 1 d D . . . .
H38 H 0.538(3) 0.7230(7) 0.3703(14) 0.024 Uiso 1 1 d D U . . .
C39 C 0.7724(2) 0.66345(7) 0.39190(10) 0.0161(2) Uani 1 1 d D . . . .
H39 H 0.836(3) 0.6790(10) 0.3345(11) 0.024 Uiso 1 1 d D U . . .
C310 C 0.8568(2) 0.61852(7) 0.45529(11) 0.0140(2) Uani 1 1 d D . . . .
H310 H 0.9807(18) 0.5991(9) 0.4401(18) 0.021 Uiso 1 1 d D U . . .
C311 C 0.7576(2) 0.60122(6) 0.53694(10) 0.0130(2) Uani 1 1 d D . . . .
H311 H 0.812(3) 0.5712(7) 0.5858(12) 0.020 Uiso 1 1 d D U . . .
O4 O 0.3229(2) 0.36816(8) 0.99467(10) 0.0318(3) Uani 1 1 d D . . . .
H41 H 0.344(4) 0.3533(14) 1.0510(12) 0.048 Uiso 1 1 d D U . . .
H42 H 0.429(3) 0.3828(13) 0.979(2) 0.048 Uiso 1 1 d D U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ru Ru -1.2940 0.8285 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1472 0.1563 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0110 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0064 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1015 0.0932 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Ru1 N31 95.82(7) . . ?
C1 Ru1 N32 169.83(5) . . ?
N31 Ru1 N32 76.77(7) . . ?
C1 Ru1 P2 88.09(6) . . ?
N31 Ru1 P2 174.09(3) . . ?
N32 Ru1 P2 99.88(6) . . ?
C1 Ru1 Cl2 96.62(7) . . ?
N31 Ru1 Cl2 88.24(6) . . ?
N32 Ru1 Cl2 90.17(6) . . ?
P2 Ru1 Cl2 86.90(5) . . ?
C1 Ru1 Cl1 87.71(7) . . ?
N31 Ru1 Cl1 91.18(6) . . ?
N32 Ru1 Cl1 85.52(6) . . ?
P2 Ru1 Cl1 93.41(6) . . ?
Cl2 Ru1 Cl1 175.664(12) . . ?
O1 C1 Ru1 173.12(12) . . ?
C21 P2 C23 98.07(8) . . ?
C21 P2 C22 98.94(7) . . ?
C23 P2 C22 98.17(7) . . ?
C21 P2 Ru1 120.51(6) . . ?
C23 P2 Ru1 116.41(7) . . ?
C22 P2 Ru1 120.20(5) . . ?
C26 N21 C24 108.50(11) . . ?
C26 N21 C21 111.58(12) . . ?
C24 N21 C21 111.15(11) . . ?
C24 N22 C25 108.55(13) . . ?
C24 N22 C22 111.43(12) . . ?
C25 N22 C22 111.13(13) . . ?
C25 N23 C23 110.91(11) . . ?
C25 N23 C26 108.44(12) . . ?
C23 N23 C26 110.56(12) . . ?
N21 C21 P2 111.93(9) . . ?
N21 C21 H21A 109.4(12) . . ?
P2 C21 H21A 107.9(12) . . ?
N21 C21 H21B 108.3(12) . . ?
P2 C21 H21B 109.9(12) . . ?
H21A C21 H21B 109.4(2) . . ?
N22 C22 P2 111.35(9) . . ?
N22 C22 H22A 108.2(13) . . ?
P2 C22 H22A 111.3(13) . . ?
N22 C22 H22B 111.4(13) . . ?
P2 C22 H22B 105.0(13) . . ?
H22A C22 H22B 109.5(2) . . ?
N23 C23 P2 112.45(11) . . ?
N23 C23 H23A 107.2(12) . . ?
P2 C23 H23A 107.2(12) . . ?
N23 C23 H23B 111.2(13) . . ?
P2 C23 H23B 109.3(13) . . ?
H23A C23 H23B 109.4(2) . . ?
N21 C24 N22 114.48(12) . . ?
N21 C24 H24A 107.0(13) . . ?
N22 C24 H24A 107.0(14) . . ?
N21 C24 H24B 110.8(13) . . ?
N22 C24 H24B 108.0(13) . . ?
H24A C24 H24B 109.5(2) . . ?
N23 C25 N22 114.31(11) . . ?
N23 C25 H25A 110.5(13) . . ?
N22 C25 H25A 103.5(13) . . ?
N23 C25 H25B 110.2(13) . . ?
N22 C25 H25B 108.6(14) . . ?
H25A C25 H25B 109.4(2) . . ?
N21 C26 N23 113.92(12) . . ?
N21 C26 H26A 108.0(13) . . ?
N23 C26 H26A 107.5(13) . . ?
N21 C26 H26B 107.2(13) . . ?
N23 C26 H26B 110.7(13) . . ?
H26A C26 H26B 109.5(2) . . ?
C32 N31 C36 118.77(12) . . ?
C32 N31 Ru1 124.76(10) . . ?
C36 N31 Ru1 116.34(10) . . ?
C311 N32 C37 118.20(11) . . ?
C311 N32 Ru1 126.29(10) . . ?
C37 N32 Ru1 115.21(10) . . ?
N31 C32 C33 122.38(14) . . ?
N31 C32 H32 115.6(14) . . ?
C33 C32 H32 122.0(15) . . ?
C34 C33 C32 119.04(14) . . ?
C34 C33 H33 121.9(14) . . ?
C32 C33 H33 119.1(14) . . ?
C33 C34 C35 118.70(13) . . ?
C33 C34 H34 121.4(15) . . ?
C35 C34 H34 119.9(15) . . ?
C34 C35 C36 119.60(14) . . ?
C34 C35 H35 121.0(14) . . ?
C36 C35 H35 119.4(15) . . ?
N31 C36 C35 121.49(13) . . ?
N31 C36 C37 115.64(11) . . ?
C35 C36 C37 122.86(13) . . ?
N32 C37 C38 121.55(13) . . ?
N32 C37 C36 115.92(12) . . ?
C38 C37 C36 122.48(12) . . ?
C39 C38 C37 119.54(13) . . ?
C39 C38 H38 119.3(14) . . ?
C37 C38 H38 121.1(14) . . ?
C310 C39 C38 119.09(13) . . ?
C310 C39 H39 122.9(14) . . ?
C38 C39 H39 117.9(14) . . ?
C39 C310 C311 118.42(14) . . ?
C39 C310 H310 119.4(14) . . ?
C311 C310 H310 122.1(14) . . ?
N32 C311 C310 123.17(13) . . ?
N32 C311 H311 114.5(13) . . ?
C310 C311 H311 122.2(13) . . ?
H41 O4 H42 107(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 C1 1.8418(17) . ?
Ru1 N31 2.1339(15) . ?
Ru1 N32 2.1539(14) . ?
Ru1 P2 2.3048(10) . ?
Ru1 Cl2 2.4023(13) . ?
Ru1 Cl1 2.4169(15) . ?
C1 O1 1.1558(19) . ?
P2 C21 1.845(3) . ?
P2 C23 1.8497(14) . ?
P2 C22 1.8588(14) . ?
N21 C26 1.4731(19) . ?
N21 C24 1.4729(18) . ?
N21 C21 1.4799(18) . ?
N22 C24 1.479(3) . ?
N22 C25 1.472(2) . ?
N22 C22 1.4831(19) . ?
N23 C25 1.483(2) . ?
N23 C23 1.4831(19) . ?
N23 C26 1.489(3) . ?
C21 H21A 0.9801(12) . ?
C21 H21B 0.9799(10) . ?
C22 H22A 0.9798(11) . ?
C22 H22B 0.9799(16) . ?
C23 H23A 0.9800(10) . ?
C23 H23B 0.9800(16) . ?
C24 H24A 0.9799(11) . ?
C24 H24B 0.9799(11) . ?
C25 H25A 0.9800(11) . ?
C25 H25B 0.9799(15) . ?
C26 H26A 0.9799(11) . ?
C26 H26B 0.9798(10) . ?
N31 C32 1.353(2) . ?
N31 C36 1.3552(18) . ?
N32 C311 1.349(2) . ?
N32 C37 1.3638(17) . ?
C32 C33 1.396(2) . ?
C32 H32 0.9799(11) . ?
C33 C34 1.389(2) . ?
C33 H33 0.9800(14) . ?
C34 C35 1.395(2) . ?
C34 H34 0.9799(11) . ?
C35 C36 1.3975(19) . ?
C35 H35 0.9799(11) . ?
C36 C37 1.479(2) . ?
C37 C38 1.3953(19) . ?
C38 C39 1.390(2) . ?
C38 H38 0.9800(11) . ?
C39 C310 1.393(2) . ?
C39 H39 0.9799(11) . ?
C310 C311 1.392(2) . ?
C310 H310 0.9799(15) . ?
C311 H311 0.9799(11) . ?
O4 H41 0.829(10) . ?
O4 H42 0.833(10) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C26 N21 C21 P2 -60.97(14) . . . . ?
C24 N21 C21 P2 60.30(13) . . . . ?
C23 P2 C21 N21 49.98(10) . . . . ?
C22 P2 C21 N21 -49.67(10) . . . . ?
Ru1 P2 C21 N21 177.20(7) . . . . ?
C24 N22 C22 P2 -59.72(13) . . . . ?
C25 N22 C22 P2 61.48(14) . . . . ?
C21 P2 C22 N22 49.27(11) . . . . ?
C23 P2 C22 N22 -50.29(12) . . . . ?
Ru1 P2 C22 N22 -177.41(8) . . . . ?
C25 N23 C23 P2 -59.79(13) . . . . ?
C26 N23 C23 P2 60.54(14) . . . . ?
C21 P2 C23 N23 -50.39(12) . . . . ?
C22 P2 C23 N23 49.91(11) . . . . ?
Ru1 P2 C23 N23 179.60(7) . . . . ?
C26 N21 C24 N22 55.61(15) . . . . ?
C21 N21 C24 N22 -67.45(15) . . . . ?
C25 N22 C24 N21 -55.17(15) . . . . ?
C22 N22 C24 N21 67.52(15) . . . . ?
C23 N23 C25 N22 66.86(17) . . . . ?
C26 N23 C25 N22 -54.72(15) . . . . ?
C24 N22 C25 N23 54.67(15) . . . . ?
C22 N22 C25 N23 -68.21(16) . . . . ?
C24 N21 C26 N23 -55.38(15) . . . . ?
C21 N21 C26 N23 67.42(16) . . . . ?
C25 N23 C26 N21 54.98(15) . . . . ?
C23 N23 C26 N21 -66.81(15) . . . . ?
C36 N31 C32 C33 -1.0(2) . . . . ?
Ru1 N31 C32 C33 -176.49(11) . . . . ?
N31 C32 C33 C34 0.0(2) . . . . ?
C32 C33 C34 C35 0.9(2) . . . . ?
C33 C34 C35 C36 -0.7(2) . . . . ?
C32 N31 C36 C35 1.1(2) . . . . ?
Ru1 N31 C36 C35 177.01(10) . . . . ?
C32 N31 C36 C37 -179.78(12) . . . . ?
Ru1 N31 C36 C37 -3.90(15) . . . . ?
C34 C35 C36 N31 -0.3(2) . . . . ?
C34 C35 C36 C37 -179.31(13) . . . . ?
C311 N32 C37 C38 1.92(19) . . . . ?
Ru1 N32 C37 C38 175.96(10) . . . . ?
C311 N32 C37 C36 -175.65(12) . . . . ?
Ru1 N32 C37 C36 -1.61(14) . . . . ?
N31 C36 C37 N32 3.65(17) . . . . ?
C35 C36 C37 N32 -177.28(13) . . . . ?
N31 C36 C37 C38 -173.90(13) . . . . ?
C35 C36 C37 C38 5.2(2) . . . . ?
N32 C37 C38 C39 -1.8(2) . . . . ?
C36 C37 C38 C39 175.65(13) . . . . ?
C37 C38 C39 C310 0.1(2) . . . . ?
C38 C39 C310 C311 1.3(2) . . . . ?
C37 N32 C311 C310 -0.4(2) . . . . ?
Ru1 N32 C311 C310 -173.74(10) . . . . ?
C39 C310 C311 N32 -1.2(2) . . . . ?
