#------------------------------------------------------------------------------
#$Date: 2021-03-05 03:44:16 +0200 (Fri, 05 Mar 2021) $
#$Revision: 262561 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/20/7242039.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7242039
loop_
_publ_author_name
'Venter, Chané'
'Akerman, Matthew P.'
_publ_section_title
;
 Pre-organisation of ligand donor sets modulates the supramolecular
 structure of bis(pyridyl--imine) silver(i) chelates
;
_journal_issue                   5
_journal_name_full               CrystEngComm
_journal_page_first              1294
_journal_page_last               1304
_journal_paper_doi               10.1039/D0CE01610A
_journal_volume                  23
_journal_year                    2021
_chemical_formula_moiety         'C18 H14 Ag N4, F6 Sb [+ solvent]'
_chemical_formula_sum            'C18 H14 Ag F6 N4 Sb'
_chemical_formula_weight         629.96
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2020-09-23 deposited with the CCDC.	2021-01-08 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 96.078(4)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   13.6966(13)
_cell_length_b                   13.1588(12)
_cell_length_c                   26.895(3)
_cell_measurement_reflns_used    9294
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.1
_cell_measurement_theta_min      1.5
_cell_volume                     4820.1(8)
_computing_cell_refinement       'SAINT-Plus (Bruker, 2012)'
_computing_data_collection       'APEX2 (Bruker, 2012)'
_computing_data_reduction        'SAINT-Plus (Bruker, 2012)'
_computing_molecular_graphics    'WinGX (Farrugia, 2012)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.970
_diffrn_measurement_device_type  'Bruker APEXII CCD'
_diffrn_measurement_method       'ω and φ-scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Incoatec microsource'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0409
_diffrn_reflns_av_unetI/netI     0.0566
_diffrn_reflns_Laue_measured_fraction_full 0.989
_diffrn_reflns_Laue_measured_fraction_max 0.970
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            34605
_diffrn_reflns_point_group_measured_fraction_full 0.989
_diffrn_reflns_point_group_measured_fraction_max 0.970
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.053
_diffrn_reflns_theta_min         1.495
_exptl_absorpt_coefficient_mu    1.989
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.5493
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS, Bruker 2012'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.736
_exptl_crystal_description       needle
_exptl_crystal_F_000             2416
_exptl_crystal_size_max          0.210
_exptl_crystal_size_mid          0.080
_exptl_crystal_size_min          0.010
_refine_diff_density_max         3.352
_refine_diff_density_min         -4.123
_refine_diff_density_rms         0.228
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.135
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     541
_refine_ls_number_reflns         11340
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.135
_refine_ls_R_factor_all          0.1064
_refine_ls_R_factor_gt           0.0909
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0132P)²+145.7698P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1788
_refine_ls_wR_factor_ref         0.1851
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9294
_reflns_number_total             11340
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0ce01610a2.cif
_cod_data_source_block           shelx_CCDC1
_cod_depositor_comments
'Adding full bibliography for 7242038--7242041.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7242039
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.680
_shelx_estimated_absorpt_t_max   0.980
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 0.57209(5) 0.89800(5) 0.38668(3) 0.02203(16) Uani 1 1 d . . . . .
Sb2 Sb 0.93381(5) 1.38586(5) 0.12945(3) 0.02244(16) Uani 1 1 d . . . . .
Ag1 Ag 0.57028(6) 1.39507(6) 0.32780(3) 0.02333(17) Uani 1 1 d . . . . .
Ag2 Ag 0.91818(6) 0.88615(6) 0.17519(3) 0.02446(18) Uani 1 1 d . . . . .
F1 F 0.5472(7) 0.7689(5) 0.4094(3) 0.052(2) Uani 1 1 d . . . . .
F2 F 0.5669(7) 0.8576(5) 0.3193(3) 0.054(2) Uani 1 1 d . . . . .
F3 F 0.5955(7) 1.0284(5) 0.3634(3) 0.050(2) Uani 1 1 d . . . . .
F4 F 0.4370(5) 0.9258(6) 0.3794(3) 0.055(2) Uani 1 1 d . . . . .
F5 F 0.7064(6) 0.8717(7) 0.3933(4) 0.069(3) Uani 1 1 d . . . . .
F6 F 0.5803(6) 0.9498(6) 0.4521(2) 0.0450(19) Uani 1 1 d . . . . .
F7 F 0.9186(6) 1.3498(5) 0.0622(3) 0.0461(19) Uani 1 1 d . . . . .
F8 F 0.9072(5) 1.2509(5) 0.1472(2) 0.0385(17) Uani 1 1 d . . . . .
F9 F 0.7988(5) 1.4124(6) 0.1287(4) 0.060(2) Uani 1 1 d . . . . .
F10 F 0.9560(5) 1.5210(4) 0.1114(3) 0.0394(17) Uani 1 1 d . . . . .
F11 F 1.0668(5) 1.3552(5) 0.1323(3) 0.0457(19) Uani 1 1 d . . . . .
F12 F 0.9480(6) 1.4215(7) 0.1972(3) 0.058(2) Uani 1 1 d . . . . .
N1 N 0.6942(6) 1.5213(6) 0.3220(3) 0.0199(17) Uani 1 1 d . . . . .
N2 N 0.6685(6) 1.3424(5) 0.2702(3) 0.0155(15) Uani 1 1 d . . . . .
N3 N 0.5782(6) 0.9806(6) 0.1643(3) 0.0163(16) Uani 1 1 d . . . . .
N5 N 0.7993(6) 0.7610(6) 0.1851(3) 0.0213(17) Uani 1 1 d . . . . .
N6 N 0.8269(6) 0.9393(6) 0.2375(3) 0.0169(16) Uani 1 1 d . . . . .
C25 C 0.8478(6) 1.0296(6) 0.2650(3) 0.0136(17) Uani 1 1 d . . . . .
N7 N 0.9353(6) 1.3011(6) 0.3389(3) 0.0176(16) Uani 1 1 d . . . . .
C14 C 0.5963(7) 0.8519(6) 0.1047(4) 0.019(2) Uani 1 1 d . . . . .
C16 C 0.6236(9) 0.7212(8) 0.0451(4) 0.032(3) Uani 1 1 d . . . . .
H16 H 0.6622 0.6907 0.0218 0.038 Uiso 1 1 calc R U . . .
C1 C 0.7081(8) 1.6105(9) 0.3457(4) 0.031(2) Uani 1 1 d . . . . .
H1 H 0.6592 1.6335 0.3655 0.037 Uiso 1 1 calc R U . . .
C2 C 0.7913(8) 1.6717(7) 0.3426(4) 0.025(2) Uani 1 1 d . . . . .
H2 H 0.8007 1.7327 0.3614 0.030 Uiso 1 1 calc R U . . .
C3 C 0.8587(7) 1.6398(8) 0.3114(4) 0.022(2) Uani 1 1 d . . . . .
H3 H 0.9153 1.6799 0.3080 0.027 Uiso 1 1 calc R U . . .
C4 C 0.8447(7) 1.5505(7) 0.2849(4) 0.023(2) Uani 1 1 d . . . . .
H4 H 0.8912 1.5285 0.2633 0.027 Uiso 1 1 calc R U . . .
C5 C 0.7606(7) 1.4925(7) 0.2904(4) 0.0168(18) Uani 1 1 d . . . . .
C6 C 0.7425(7) 1.3982(7) 0.2634(3) 0.0190(19) Uani 1 1 d . . . . .
H6 H 0.7863 1.3774 0.2402 0.023 Uiso 1 1 calc R U . . .
C7 C 0.6513(6) 1.2508(7) 0.2417(4) 0.0155(18) Uani 1 1 d . . . . .
C8 C 0.6085(6) 1.1702(7) 0.2647(3) 0.0146(17) Uani 1 1 d . . . . .
H8 H 0.5946 1.1767 0.2984 0.018 Uiso 1 1 calc R U . . .
C9 C 0.5857(6) 1.0805(7) 0.2392(3) 0.0158(18) Uani 1 1 d . . . . .
H9 H 0.5567 1.0254 0.2551 0.019 Uiso 1 1 calc R U . . .
C10 C 0.6063(6) 1.0727(7) 0.1898(4) 0.0161(18) Uani 1 1 d . . . . .
C11 C 0.6472(7) 1.1542(7) 0.1662(4) 0.0195(19) Uani 1 1 d . . . . .
H11 H 0.6596 1.1486 0.1322 0.023 Uiso 1 1 calc R U . . .
C12 C 0.6693(7) 1.2423(7) 0.1919(4) 0.020(2) Uani 1 1 d . . . . .
H12 H 0.6971 1.2978 0.1758 0.024 Uiso 1 1 calc R U . . .
C13 C 0.6286(7) 0.9443(7) 0.1316(4) 0.020(2) Uani 1 1 d . . . . .
H13 H 0.6874 0.9772 0.1246 0.024 Uiso 1 1 calc R U . . .
C15 C 0.6543(9) 0.8087(8) 0.0701(4) 0.032(2) Uani 1 1 d . . . . .
H15 H 0.7145 0.8397 0.0641 0.038 Uiso 1 1 calc R U . . .
C32 C 0.9337(9) 1.4296(8) 0.4014(4) 0.028(2) Uani 1 1 d . . . . .
C19 C 0.7853(8) 0.6746(7) 0.1600(4) 0.024(2) Uani 1 1 d . . . . .
H19 H 0.8304 0.6548 0.1373 0.029 Uiso 1 1 calc R U . . .
C20 C 0.7053(8) 0.6128(8) 0.1664(4) 0.028(2) Uani 1 1 d . . . . .
H20 H 0.6970 0.5515 0.1477 0.034 Uiso 1 1 calc R U . . .
C21 C 0.6381(7) 0.6372(7) 0.1986(4) 0.022(2) Uani 1 1 d . . . . .
H21 H 0.5830 0.5950 0.2022 0.027 Uiso 1 1 calc R U . . .
C22 C 0.6546(7) 0.7282(7) 0.2265(4) 0.022(2) Uani 1 1 d . . . . .
H22 H 0.6106 0.7491 0.2495 0.026 Uiso 1 1 calc R U . . .
C23 C 0.7369(7) 0.7861(7) 0.2191(4) 0.0179(19) Uani 1 1 d . . . . .
C24 C 0.7571(7) 0.8805(6) 0.2473(4) 0.0190(19) Uani 1 1 d . . . . .
H24 H 0.7178 0.8982 0.2730 0.023 Uiso 1 1 calc R U . . .
C30 C 0.8260(7) 1.0451(7) 0.3142(4) 0.0189(19) Uani 1 1 d . . . . .
H30 H 0.7922 0.9939 0.3305 0.023 Uiso 1 1 calc R U . . .
C29 C 0.8531(7) 1.1329(7) 0.3390(3) 0.0175(18) Uani 1 1 d . . . . .
H29 H 0.8393 1.1421 0.3726 0.021 Uiso 1 1 calc R U . . .
C28 C 0.9016(7) 1.2098(7) 0.3146(3) 0.0162(18) Uani 1 1 d . . . . .
C31 C 0.8970(8) 1.3364(7) 0.3762(4) 0.025(2) Uani 1 1 d . . . . .
H31 H 0.8433 1.3016 0.3881 0.030 Uiso 1 1 calc R U . . .
C33 C 0.8800(10) 1.4737(8) 0.4378(4) 0.033(3) Uani 1 1 d . . . . .
H33 H 0.8222 1.4426 0.4474 0.040 Uiso 1 1 calc R U . . .
C34 C 0.9153(11) 1.5655(9) 0.4591(4) 0.040(3) Uani 1 1 d . . . . .
H34 H 0.8808 1.5986 0.4833 0.048 Uiso 1 1 calc R U . . .
C27 C 0.9239(7) 1.1948(7) 0.2664(3) 0.0173(18) Uani 1 1 d . . . . .
H27 H 0.9591 1.2453 0.2504 0.021 Uiso 1 1 calc R U . . .
C26 C 0.8946(7) 1.1053(7) 0.2410(3) 0.0196(19) Uani 1 1 d . . . . .
H26 H 0.9070 1.0966 0.2072 0.024 Uiso 1 1 calc R U . . .
N4 N 0.5084(7) 0.8114(6) 0.1129(3) 0.0233(18) Uani 1 1 d . . . . .
N8 N 1.0198(8) 1.4703(6) 0.3881(3) 0.032(2) Uani 1 1 d . . . . .
C18 C 0.4793(9) 0.7265(7) 0.0890(4) 0.027(2) Uani 1 1 d . . . . .
H18 H 0.4186 0.6970 0.0954 0.033 Uiso 1 1 calc R U . . .
C36 C 1.0478(10) 1.5584(9) 0.4098(4) 0.034(3) Uani 1 1 d . . . . .
H36 H 1.1053 1.5901 0.4002 0.041 Uiso 1 1 calc R U . . .
C17 C 0.5348(10) 0.6787(8) 0.0547(4) 0.034(3) Uani 1 1 d . . . . .
H17 H 0.5118 0.6180 0.0383 0.040 Uiso 1 1 calc R U . . .
C35 C 0.9979(11) 1.6064(10) 0.4454(4) 0.045(3) Uani 1 1 d . . . . .
H35 H 1.0223 1.6683 0.4600 0.054 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
F1 Sb1 F5 90.7(4) . . ?
F1 Sb1 F3 179.2(4) . . ?
F5 Sb1 F3 90.0(4) . . ?
F1 Sb1 F4 89.9(4) . . ?
F5 Sb1 F4 179.3(5) . . ?
F3 Sb1 F4 89.3(4) . . ?
F1 Sb1 F6 91.1(3) . . ?
F5 Sb1 F6 91.0(4) . . ?
F3 Sb1 F6 89.2(3) . . ?
F4 Sb1 F6 89.3(4) . . ?
F1 Sb1 F2 94.0(3) . . ?
F5 Sb1 F2 88.6(4) . . ?
F3 Sb1 F2 85.8(3) . . ?
F4 Sb1 F2 91.0(4) . . ?
F6 Sb1 F2 175.0(3) . . ?
F11 Sb2 F7 89.6(4) . . ?
F11 Sb2 F12 90.8(4) . . ?
F7 Sb2 F12 179.4(4) . . ?
F11 Sb2 F10 91.8(3) . . ?
F7 Sb2 F10 89.7(3) . . ?
F12 Sb2 F10 90.7(4) . . ?
F11 Sb2 F9 177.4(4) . . ?
F7 Sb2 F9 91.6(4) . . ?
F12 Sb2 F9 88.0(4) . . ?
F10 Sb2 F9 90.5(3) . . ?
F11 Sb2 F8 90.0(3) . . ?
F7 Sb2 F8 90.1(3) . . ?
F12 Sb2 F8 89.5(3) . . ?
F10 Sb2 F8 178.2(3) . . ?
F9 Sb2 F8 87.8(3) . . ?
N2 Ag1 N4 133.2(3) . 2_655 ?
N2 Ag1 N3 142.2(3) . 2_655 ?
N4 Ag1 N3 72.1(3) 2_655 2_655 ?
N2 Ag1 N1 72.0(3) . . ?
N4 Ag1 N1 140.0(3) 2_655 . ?
N3 Ag1 N1 107.5(3) 2_655 . ?
N8 Ag2 N6 132.3(3) 2_745 . ?
N8 Ag2 N5 138.2(3) 2_745 . ?
N6 Ag2 N5 72.2(3) . . ?
N8 Ag2 N7 73.7(3) 2_745 2_745 ?
N6 Ag2 N7 142.7(3) . 2_745 ?
N5 Ag2 N7 107.2(3) . 2_745 ?
C1 N1 C5 117.9(9) . . ?
C1 N1 Ag1 130.1(7) . . ?
C5 N1 Ag1 111.9(6) . . ?
C6 N2 C7 119.6(8) . . ?
C6 N2 Ag1 117.3(6) . . ?
C7 N2 Ag1 123.1(6) . . ?
C13 N3 C10 121.0(8) . . ?
C13 N3 Ag1 115.0(6) . 2_645 ?
C10 N3 Ag1 123.7(6) . 2_645 ?
C19 N5 C23 119.0(9) . . ?
C19 N5 Ag2 127.5(7) . . ?
C23 N5 Ag2 113.5(6) . . ?
C24 N6 C25 121.1(8) . . ?
C24 N6 Ag2 116.2(6) . . ?
C25 N6 Ag2 122.7(6) . . ?
C26 C25 C30 119.4(8) . . ?
C26 C25 N6 116.2(8) . . ?
C30 C25 N6 124.4(8) . . ?
C31 N7 C28 122.2(9) . . ?
C31 N7 Ag2 112.4(7) . 2_755 ?
C28 N7 Ag2 124.5(6) . 2_755 ?
N4 C14 C15 121.6(9) . . ?
N4 C14 C13 118.3(9) . . ?
C15 C14 C13 120.2(9) . . ?
C15 C16 C17 118.3(11) . . ?
C15 C16 H16 120.9 . . ?
C17 C16 H16 120.9 . . ?
N1 C1 C2 123.4(10) . . ?
N1 C1 H1 118.3 . . ?
C2 C1 H1 118.3 . . ?
C3 C2 C1 117.4(10) . . ?
C3 C2 H2 121.3 . . ?
C1 C2 H2 121.3 . . ?
C4 C3 C2 120.7(10) . . ?
C4 C3 H3 119.7 . . ?
C2 C3 H3 119.7 . . ?
C3 C4 C5 118.6(10) . . ?
C3 C4 H4 120.7 . . ?
C5 C4 H4 120.7 . . ?
N1 C5 C4 121.7(9) . . ?
N1 C5 C6 117.5(8) . . ?
C4 C5 C6 120.8(9) . . ?
N2 C6 C5 121.1(9) . . ?
N2 C6 H6 119.5 . . ?
C5 C6 H6 119.5 . . ?
C8 C7 C12 119.6(8) . . ?
C8 C7 N2 117.2(8) . . ?
C12 C7 N2 123.0(8) . . ?
C9 C8 C7 121.0(8) . . ?
C9 C8 H8 119.5 . . ?
C7 C8 H8 119.5 . . ?
C8 C9 C10 118.6(8) . . ?
C8 C9 H9 120.7 . . ?
C10 C9 H9 120.7 . . ?
C9 C10 C11 120.6(8) . . ?
C9 C10 N3 116.8(8) . . ?
C11 C10 N3 122.4(8) . . ?
C12 C11 C10 120.1(9) . . ?
C12 C11 H11 120.0 . . ?
C10 C11 H11 120.0 . . ?
C11 C12 C7 120.1(9) . . ?
C11 C12 H12 119.9 . . ?
C7 C12 H12 119.9 . . ?
N3 C13 C14 120.0(9) . . ?
N3 C13 H13 120.0 . . ?
C14 C13 H13 120.0 . . ?
C16 C15 C14 119.8(11) . . ?
C16 C15 H15 120.1 . . ?
C14 C15 H15 120.1 . . ?
N8 C32 C33 123.0(11) . . ?
N8 C32 C31 117.7(9) . . ?
C33 C32 C31 119.2(11) . . ?
N5 C19 C20 120.9(10) . . ?
N5 C19 H19 119.6 . . ?
C20 C19 H19 119.6 . . ?
C21 C20 C19 122.2(10) . . ?
C21 C20 H20 118.9 . . ?
C19 C20 H20 118.9 . . ?
C20 C21 C22 116.9(9) . . ?
C20 C21 H21 121.5 . . ?
C22 C21 H21 121.5 . . ?
C23 C22 C21 118.3(9) . . ?
C23 C22 H22 120.9 . . ?
C21 C22 H22 120.9 . . ?
N5 C23 C22 122.7(9) . . ?
N5 C23 C24 117.2(8) . . ?
C22 C23 C24 120.1(9) . . ?
N6 C24 C23 120.7(9) . . ?
N6 C24 H24 119.7 . . ?
C23 C24 H24 119.7 . . ?
C29 C30 C25 120.7(8) . . ?
C29 C30 H30 119.7 . . ?
C25 C30 H30 119.7 . . ?
C30 C29 C28 119.8(9) . . ?
C30 C29 H29 120.1 . . ?
C28 C29 H29 120.1 . . ?
C27 C28 C29 119.9(9) . . ?
C27 C28 N7 117.4(8) . . ?
C29 C28 N7 122.6(8) . . ?
N7 C31 C32 121.6(10) . . ?
N7 C31 H31 119.2 . . ?
C32 C31 H31 119.2 . . ?
C34 C33 C32 117.1(12) . . ?
C34 C33 H33 121.4 . . ?
C32 C33 H33 121.4 . . ?
C35 C34 C33 119.9(11) . . ?
C35 C34 H34 120.1 . . ?
C33 C34 H34 120.1 . . ?
C28 C27 C26 119.9(9) . . ?
C28 C27 H27 120.0 . . ?
C26 C27 H27 120.0 . . ?
C25 C26 C27 120.3(8) . . ?
C25 C26 H26 119.9 . . ?
C27 C26 H26 119.9 . . ?
C18 N4 C14 118.5(9) . . ?
C18 N4 Ag1 126.9(8) . 2_645 ?
C14 N4 Ag1 114.5(6) . 2_645 ?
C36 N8 C32 116.0(10) . . ?
C36 N8 Ag2 129.6(9) . 2_755 ?
C32 N8 Ag2 113.9(7) . 2_755 ?
N4 C18 C17 122.6(11) . . ?
N4 C18 H18 118.7 . . ?
C17 C18 H18 118.7 . . ?
N8 C36 C35 123.9(13) . . ?
N8 C36 H36 118.1 . . ?
C35 C36 H36 118.1 . . ?
C16 C17 C18 119.2(10) . . ?
C16 C17 H17 120.4 . . ?
C18 C17 H17 120.4 . . ?
C34 C35 C36 120.0(12) . . ?
C34 C35 H35 120.0 . . ?
C36 C35 H35 120.0 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb1 F1 1.849(7) . ?
Sb1 F5 1.862(8) . ?
Sb1 F3 1.866(6) . ?
Sb1 F4 1.876(7) . ?
Sb1 F6 1.880(7) . ?
Sb1 F2 1.883(8) . ?
Sb2 F11 1.860(7) . ?
Sb2 F7 1.860(7) . ?
Sb2 F12 1.872(8) . ?
Sb2 F10 1.877(6) . ?
Sb2 F9 1.880(7) . ?
Sb2 F8 1.885(6) . ?
Ag1 N2 2.266(8) . ?
Ag1 N4 2.298(9) 2_655 ?
Ag1 N3 2.354(8) 2_655 ?
Ag1 N1 2.392(8) . ?
Ag2 N8 2.269(10) 2_745 ?
Ag2 N6 2.303(8) . ?
Ag2 N5 2.351(8) . ?
Ag2 N7 2.363(8) 2_745 ?
N1 C1 1.338(13) . ?
N1 C5 1.362(12) . ?
N2 C6 1.280(12) . ?
N2 C7 1.435(11) . ?
N3 C13 1.267(12) . ?
N3 C10 1.425(11) . ?
N3 Ag1 2.354(8) 2_645 ?
N5 C19 1.325(12) . ?
N5 C23 1.358(12) . ?
N6 C24 1.278(12) . ?
N6 C25 1.412(11) . ?
C25 C26 1.381(13) . ?
C25 C30 1.403(13) . ?
N7 C31 1.269(12) . ?
N7 C28 1.421(12) . ?
N7 Ag2 2.363(8) 2_755 ?
C14 N4 1.357(13) . ?
C14 C15 1.404(15) . ?
C14 C13 1.460(13) . ?
C16 C15 1.377(15) . ?
C16 C17 1.387(18) . ?
C16 H16 0.9500 . ?
C1 C2 1.404(15) . ?
C1 H1 0.9500 . ?
C2 C3 1.378(14) . ?
C2 H2 0.9500 . ?
C3 C4 1.377(13) . ?
C3 H3 0.9500 . ?
C4 C5 1.402(14) . ?
C4 H4 0.9500 . ?
C5 C6 1.447(13) . ?
C6 H6 0.9500 . ?
C7 C8 1.389(13) . ?
C7 C12 1.391(14) . ?
C8 C9 1.384(12) . ?
C8 H8 0.9500 . ?
C9 C10 1.392(13) . ?
C9 H9 0.9500 . ?
C10 C11 1.393(13) . ?
C11 C12 1.367(12) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 H13 0.9500 . ?
C15 H15 0.9500 . ?
C32 N8 1.378(15) . ?
C32 C33 1.409(14) . ?
C32 C31 1.464(15) . ?
C19 C20 1.390(14) . ?
C19 H19 0.9500 . ?
C20 C21 1.368(15) . ?
C20 H20 0.9500 . ?
C21 C22 1.418(13) . ?
C21 H21 0.9500 . ?
C22 C23 1.392(13) . ?
C22 H22 0.9500 . ?
C23 C24 1.466(13) . ?
C24 H24 0.9500 . ?
C30 C29 1.365(13) . ?
C30 H30 0.9500 . ?
C29 C28 1.411(12) . ?
C29 H29 0.9500 . ?
C28 C27 1.376(13) . ?
C31 H31 0.9500 . ?
C33 C34 1.401(16) . ?
C33 H33 0.9500 . ?
C34 C35 1.34(2) . ?
C34 H34 0.9500 . ?
C27 C26 1.398(13) . ?
C27 H27 0.9500 . ?
C26 H26 0.9500 . ?
N4 C18 1.328(12) . ?
N4 Ag1 2.298(9) 2_645 ?
N8 C36 1.336(14) . ?
N8 Ag2 2.269(10) 2_755 ?
C18 C17 1.405(16) . ?
C18 H18 0.9500 . ?
C36 C35 1.385(17) . ?
C36 H36 0.9500 . ?
C17 H17 0.9500 . ?
C35 H35 0.9500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C24 N6 C25 C26 -155.4(9) . . . . ?
Ag2 N6 C25 C26 26.7(11) . . . . ?
C24 N6 C25 C30 26.1(14) . . . . ?
Ag2 N6 C25 C30 -151.8(7) . . . . ?
C5 N1 C1 C2 -5.2(15) . . . . ?
Ag1 N1 C1 C2 172.4(8) . . . . ?
N1 C1 C2 C3 3.7(16) . . . . ?
C1 C2 C3 C4 -0.9(15) . . . . ?
C2 C3 C4 C5 0.0(15) . . . . ?
C1 N1 C5 C4 4.1(14) . . . . ?
Ag1 N1 C5 C4 -174.0(7) . . . . ?
C1 N1 C5 C6 -177.3(9) . . . . ?
Ag1 N1 C5 C6 4.7(10) . . . . ?
C3 C4 C5 N1 -1.5(14) . . . . ?
C3 C4 C5 C6 179.9(9) . . . . ?
C7 N2 C6 C5 178.3(8) . . . . ?
Ag1 N2 C6 C5 -1.8(11) . . . . ?
N1 C5 C6 N2 -2.2(13) . . . . ?
C4 C5 C6 N2 176.4(9) . . . . ?
C6 N2 C7 C8 147.8(8) . . . . ?
Ag1 N2 C7 C8 -32.2(10) . . . . ?
C6 N2 C7 C12 -36.7(12) . . . . ?
Ag1 N2 C7 C12 143.4(7) . . . . ?
C12 C7 C8 C9 1.7(13) . . . . ?
N2 C7 C8 C9 177.4(8) . . . . ?
C7 C8 C9 C10 -0.2(13) . . . . ?
C8 C9 C10 C11 -1.3(13) . . . . ?
C8 C9 C10 N3 -177.6(8) . . . . ?
C13 N3 C10 C9 -146.6(9) . . . . ?
Ag1 N3 C10 C9 40.4(10) 2_645 . . . ?
C13 N3 C10 C11 37.1(13) . . . . ?
Ag1 N3 C10 C11 -135.9(8) 2_645 . . . ?
C9 C10 C11 C12 1.4(14) . . . . ?
N3 C10 C11 C12 177.5(9) . . . . ?
C10 C11 C12 C7 0.1(14) . . . . ?
C8 C7 C12 C11 -1.6(14) . . . . ?
N2 C7 C12 C11 -177.1(8) . . . . ?
C10 N3 C13 C14 -177.7(8) . . . . ?
Ag1 N3 C13 C14 -4.1(11) 2_645 . . . ?
N4 C14 C13 N3 4.8(14) . . . . ?
C15 C14 C13 N3 -176.9(9) . . . . ?
C17 C16 C15 C14 0.5(16) . . . . ?
N4 C14 C15 C16 -2.2(16) . . . . ?
C13 C14 C15 C16 179.7(10) . . . . ?
C23 N5 C19 C20 3.1(14) . . . . ?
Ag2 N5 C19 C20 -173.3(7) . . . . ?
N5 C19 C20 C21 -0.3(16) . . . . ?
C19 C20 C21 C22 -1.3(15) . . . . ?
C20 C21 C22 C23 0.2(14) . . . . ?
C19 N5 C23 C22 -4.3(14) . . . . ?
Ag2 N5 C23 C22 172.5(7) . . . . ?
C19 N5 C23 C24 177.9(9) . . . . ?
Ag2 N5 C23 C24 -5.2(10) . . . . ?
C21 C22 C23 N5 2.7(14) . . . . ?
C21 C22 C23 C24 -179.7(9) . . . . ?
C25 N6 C24 C23 -179.1(8) . . . . ?
Ag2 N6 C24 C23 -1.1(11) . . . . ?
N5 C23 C24 N6 4.4(13) . . . . ?
C22 C23 C24 N6 -173.4(9) . . . . ?
C26 C25 C30 C29 -1.8(14) . . . . ?
N6 C25 C30 C29 176.7(8) . . . . ?
C25 C30 C29 C28 1.3(14) . . . . ?
C30 C29 C28 C27 -1.8(14) . . . . ?
C30 C29 C28 N7 -177.4(8) . . . . ?
C31 N7 C28 C27 159.4(9) . . . . ?
Ag2 N7 C28 C27 -32.0(11) 2_755 . . . ?
C31 N7 C28 C29 -24.9(14) . . . . ?
Ag2 N7 C28 C29 143.6(7) 2_755 . . . ?
C28 N7 C31 C32 178.8(9) . . . . ?
Ag2 N7 C31 C32 9.0(12) 2_755 . . . ?
N8 C32 C31 N7 -9.1(15) . . . . ?
C33 C32 C31 N7 170.7(10) . . . . ?
N8 C32 C33 C34 2.8(17) . . . . ?
C31 C32 C33 C34 -176.9(10) . . . . ?
C32 C33 C34 C35 -1.2(18) . . . . ?
C29 C28 C27 C26 2.8(14) . . . . ?
N7 C28 C27 C26 178.6(8) . . . . ?
C30 C25 C26 C27 2.8(14) . . . . ?
N6 C25 C26 C27 -175.9(8) . . . . ?
C28 C27 C26 C25 -3.3(14) . . . . ?
C15 C14 N4 C18 2.7(14) . . . . ?
C13 C14 N4 C18 -179.1(9) . . . . ?
C15 C14 N4 Ag1 179.0(8) . . . 2_645 ?
C13 C14 N4 Ag1 -2.8(11) . . . 2_645 ?
C33 C32 N8 C36 -3.6(16) . . . . ?
C31 C32 N8 C36 176.2(10) . . . . ?
C33 C32 N8 Ag2 -176.1(9) . . . 2_755 ?
C31 C32 N8 Ag2 3.7(12) . . . 2_755 ?
C14 N4 C18 C17 -1.6(15) . . . . ?
Ag1 N4 C18 C17 -177.4(8) 2_645 . . . ?
C32 N8 C36 C35 2.9(17) . . . . ?
Ag2 N8 C36 C35 174.0(9) 2_755 . . . ?
C15 C16 C17 C18 0.6(16) . . . . ?
N4 C18 C17 C16 -0.1(16) . . . . ?
C33 C34 C35 C36 0.5(19) . . . . ?
N8 C36 C35 C34 -1.5(19) . . . . ?
