#------------------------------------------------------------------------------
#$Date: 2021-05-05 11:48:18 +0300 (Wed, 05 May 2021) $
#$Revision: 264908 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/25/7242571.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7242571
loop_
_publ_author_name
'Shen, Qingbo'
'Gómez-García, Carlos J.'
'Sun, Wenlong'
'Lai, Xiaoyong'
'Pang, Haijun'
'Ma, Huiyuan'
_publ_section_title
;
 Improving the photocatalytic H2 evolution activity of Keggin
 polyoxometalates anchoring copper-azole complexes
;
_journal_issue                   8
_journal_name_full               'Green Chemistry'
_journal_page_first              3104
_journal_page_last               3114
_journal_paper_doi               10.1039/D1GC00692D
_journal_volume                  23
_journal_year                    2021
_chemical_formula_sum            'C32 H46 Cu2 Ge N12 O48 W12'
_chemical_formula_weight         3772.57
_space_group_IT_number           8
_space_group_name_Hall           'C -2y'
_space_group_name_H-M_alt        'C 1 m 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'C 1 m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2020-08-16 deposited with the CCDC.	2021-03-26 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 109.9510(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   12.5419(5)
_cell_length_b                   22.4521(9)
_cell_length_c                   11.6246(5)
_cell_measurement_reflns_used    9902
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.34
_cell_measurement_theta_min      3.08
_cell_volume                     3076.9(2)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0544
_diffrn_reflns_av_sigmaI/netI    0.0692
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            22556
_diffrn_reflns_theta_full        28.38
_diffrn_reflns_theta_max         28.38
_diffrn_reflns_theta_min         3.08
_exptl_absorpt_coefficient_mu    23.593
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    3.972
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3256.3
_refine_diff_density_max         6.782
_refine_diff_density_min         -2.548
_refine_diff_density_rms         0.438
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.03(3)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     441
_refine_ls_number_reflns         7802
_refine_ls_number_restraints     120
_refine_ls_restrained_S_all      1.042
_refine_ls_R_factor_all          0.0774
_refine_ls_R_factor_gt           0.0579
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0688P)²+182.8526P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1378
_refine_ls_wR_factor_ref         0.1487
_reflns_number_gt                6397
_reflns_number_total             7802
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            d1gc00692d2.cif
_cod_data_source_block           mcm
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7242571--7242572.cif.
;
_cod_original_sg_symbol_H-M      'Cm   '
_cod_database_code               7242571
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x, -y, z'
'x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 0.8535(3) 0.67454(10) 1.0195(3) 0.0272(5) Uani 1 1 d . . .
Ge Ge 0.8552(3) 0.5000 0.5293(3) 0.0082(4) Uani 1 2 d S . .
W1 W 0.88118(9) 0.58015(5) 0.79254(9) 0.0314(3) Uani 1 1 d . . .
W2 W 0.81830(8) 0.57511(4) 0.25380(7) 0.0237(2) Uani 1 1 d . . .
W3 W 1.12241(12) 0.5000 0.76635(12) 0.0229(3) Uani 1 2 d S . .
W4 W 0.84976(10) 0.65794(3) 0.53686(10) 0.0240(2) Uani 1 1 d . . .
W5 W 1.09450(7) 0.57617(4) 0.50557(8) 0.0235(2) Uani 1 1 d . . .
W6 W 0.62488(8) 0.58211(4) 0.56064(8) 0.0240(2) Uani 1 1 d . . .
W7 W 0.59334(12) 0.5000 0.27896(12) 0.0226(3) Uani 1 2 d S . .
O1 O 1.1765(16) 0.5591(7) 0.6755(15) 0.032(4) Uani 1 1 d . . .
OW1 O 1.407(3) 0.5000 0.686(3) 0.048(7) Uani 1 2 d SU . .
O2 O 0.9768(12) 0.5709(6) 0.3538(13) 0.024(3) Uani 1 1 d DU . .
OW2 O 1.335(2) 0.5000 0.379(3) 0.063(10) Uani 1 2 d SD . .
OW3 O 0.643(2) 0.5000 0.913(2) 0.066(10) Uani 1 2 d S . .
O3 O 0.8018(13) 0.6258(6) 0.3742(13) 0.023(3) Uani 1 1 d . . .
O4 O 0.862(2) 0.7314(6) 0.5198(19) 0.035(4) Uani 1 1 d . . .
OW4 O 1.0285(17) 0.5000 0.2417(19) 0.039(11) Uani 0.50 2 d SPDU . .
O5 O 0.9978(14) 0.6270(7) 0.5545(15) 0.026(3) Uani 1 1 d . . .
O6 O 1.0030(17) 0.5000 0.5651(18) 0.021(4) Uani 1 2 d SU . .
O7 O 1.2361(17) 0.5000 0.911(2) 0.029(5) Uani 1 2 d SU . .
O8 O 1.0235(12) 0.5589(6) 0.7905(13) 0.020(3) Uani 1 1 d . . .
O9 O 0.845(2) 0.5000 0.812(2) 0.033(5) Uani 1 2 d S . .
O10 O 0.4593(19) 0.5000 0.184(2) 0.027(5) Uani 1 2 d SU . .
O11 O 0.7143(13) 0.5950(7) 0.7335(12) 0.025(3) Uani 1 1 d . . .
O12 O 0.9058(18) 0.6102(8) 0.9371(17) 0.039(4) Uani 1 1 d U . .
O13 O 0.8148(18) 0.6221(8) 0.1395(16) 0.037(4) Uani 1 1 d . . .
O14 O 0.5039(19) 0.6124(10) 0.5667(19) 0.047(5) Uani 1 1 d . . .
O15 O 0.8333(16) 0.5000 0.176(2) 0.034(6) Uani 1 2 d SD . .
O16 O 1.1931(19) 0.6203(10) 0.478(2) 0.050(6) Uani 1 1 d . . .
O17 O 0.8894(13) 0.6553(6) 0.7096(14) 0.027(3) Uani 1 1 d . . .
O18 O 0.6918(14) 0.6533(8) 0.5257(12) 0.031(4) Uani 1 1 d . . .
O19 O 0.5927(15) 0.5582(7) 0.4006(14) 0.029(4) Uani 1 1 d . . .
O20 O 0.611(2) 0.5000 0.597(2) 0.022(5) Uani 0.90 2 d SP . .
O21 O 0.6647(16) 0.5612(7) 0.2144(18) 0.039(5) Uani 1 1 d . . .
O22 O 0.7893(18) 0.5000 0.3744(17) 0.020(4) Uani 1 2 d S . .
O23 O 0.8158(12) 0.5618(5) 0.5905(12) 0.018(3) Uani 1 1 d U . .
O24 O 1.144(2) 0.5000 0.4648(19) 0.059(9) Uani 1 2 d SD . .
N1 N 0.7339(8) 0.7264(4) 0.9165(8) 0.018(4) Uani 1 1 d G . .
N2 N 0.992(2) 0.7208(9) 1.1274(17) 0.032(5) Uani 1 1 d . . .
N3 N 0.6962(10) 0.7149(5) 0.7934(10) 0.035(5) Uani 1 1 d GU . .
H3B H 0.7035 0.6818 0.7596 0.042 Uiso 1 1 calc R . .
N4 N 1.0289(16) 0.7081(7) 1.2432(16) 0.048(6) Uani 1 1 d . . .
H4B H 1.0239 0.6731 1.2713 0.057 Uiso 1 1 calc R . .
N5 N 0.7908(16) 0.8708(7) 1.2713(16) 0.079(10) Uani 1 1 d RU . .
N6 N 0.9316(16) 0.8688(7) 0.7804(16) 0.074(9) Uani 1 1 d RU . .
C1 C 0.6511(9) 0.8081(5) 0.8195(9) 0.027(5) Uani 1 1 d GU . .
H1A H 0.6229 0.8467 0.8039 0.032 Uiso 1 1 calc R . .
C2 C 0.7285(8) 0.8130(4) 1.0478(8) 0.031(6) Uani 1 1 d R . .
C3 C 0.7242(12) 0.8748(5) 1.0527(11) 0.070(11) Uani 1 1 d R . .
H3A H 0.7013 0.8969 0.9808 0.084 Uiso 1 1 d R . .
C4 C 0.7542(15) 0.9035(6) 1.1651(14) 0.067(10) Uani 1 1 d RU . .
H4A H 0.7501 0.9447 1.1684 0.081 Uiso 1 1 d R . .
C5 C 0.7927(13) 0.8087(7) 1.2677(12) 0.053(9) Uani 1 1 d R . .
H5A H 0.8143 0.7866 1.3397 0.064 Uiso 1 1 d R . .
C6 C 0.7627(10) 0.7800(5) 1.1553(9) 0.025(5) Uani 1 1 d RU . .
H6A H 0.7655 0.7387 1.1520 0.031 Uiso 1 1 d R . .
C7 C 1.0141(12) 0.7788(8) 1.1175(13) 0.028(5) Uani 1 1 d GU . .
C8 C 1.076(3) 0.7550(13) 1.316(3) 0.049(7) Uani 1 1 d U . .
H8A H 1.1116 0.7552 1.4001 0.058 Uiso 1 1 calc R . .
C9 C 1.0600(11) 0.8042(6) 1.2336(12) 0.060(10) Uani 1 1 d . . .
H9A H 1.0764 0.8441 1.2532 0.071 Uiso 1 1 calc R . .
C10 C 0.9822(11) 0.8086(6) 0.9989(12) 0.031(6) Uani 1 1 d R . .
C11 C 0.9605(11) 0.7777(6) 0.8896(12) 0.042(7) Uani 1 1 d R . .
H11A H 0.9637 0.7363 0.8900 0.050 Uiso 1 1 d R . .
C12 C 0.9341(11) 0.8086(6) 0.7799(12) 0.054(8) Uani 1 1 d R . .
H12A H 0.9190 0.7881 0.7065 0.065 Uiso 1 1 d R . .
C13 C 0.9509(11) 0.9014(6) 0.8886(12) 0.089(13) Uani 1 1 d RU . .
H13A H 0.9470 0.9428 0.8871 0.107 Uiso 1 1 d R . .
C14 C 0.9774(11) 0.8705(6) 0.9983(12) 0.064(10) Uani 1 1 d RU . .
H14A H 0.9918 0.8911 1.0714 0.076 Uiso 1 1 d R . .
C15 C 0.7060(7) 0.7841(3) 0.9327(7) 0.020(4) Uani 1 1 d G . .
C16 C 0.6451(10) 0.7654(6) 0.7334(11) 0.040(6) Uani 1 1 d GU . .
H16A H 0.6120 0.7698 0.6491 0.048 Uiso 0.47 1 calc PR . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
V V 0.3005 0.5294 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Cu1 O12 117.0(7) . . ?
N1 Cu1 O13 117.3(7) . 1_556 ?
O12 Cu1 O13 96.2(7) . 1_556 ?
N1 Cu1 N2 112.7(6) . . ?
O12 Cu1 N2 108.6(9) . . ?
O13 Cu1 N2 103.1(8) 1_556 . ?
O22 Ge O23 109.5(6) . 2_565 ?
O22 Ge O23 109.5(6) . . ?
O23 Ge O23 108.7(9) 2_565 . ?
O22 Ge O6 110.0(10) . . ?
O23 Ge O6 109.5(6) 2_565 . ?
O23 Ge O6 109.5(6) . . ?
O12 W1 O8 104.9(8) . . ?
O12 W1 O9 103.0(10) . . ?
O8 W1 O9 91.6(9) . . ?
O12 W1 O17 96.8(8) . . ?
O8 W1 O17 90.1(7) . . ?
O9 W1 O17 158.8(9) . . ?
O12 W1 O11 95.0(8) . . ?
O8 W1 O11 159.9(6) . . ?
O9 W1 O11 86.2(9) . . ?
O17 W1 O11 85.0(6) . . ?
O12 W1 O23 164.5(7) . . ?
O8 W1 O23 87.1(6) . . ?
O9 W1 O23 86.1(8) . . ?
O17 W1 O23 72.9(5) . . ?
O11 W1 O23 72.8(5) . . ?
O13 W2 O21 99.5(9) . . ?
O13 W2 O3 103.3(7) . . ?
O21 W2 O3 85.2(8) . . ?
O13 W2 O2 104.5(9) . . ?
O21 W2 O2 155.8(7) . . ?
O3 W2 O2 86.2(6) . . ?
O13 W2 O15 99.1(9) . . ?
O21 W2 O15 89.8(8) . . ?
O3 W2 O15 157.6(8) . . ?
O2 W2 O15 89.7(8) . . ?
O13 W2 O22 166.5(8) . . ?
O21 W2 O22 70.1(7) . . ?
O3 W2 O22 84.8(6) . . ?
O2 W2 O22 86.7(7) . . ?
O15 W2 O22 73.0(7) . . ?
O7 W3 O8 102.3(7) . . ?
O7 W3 O8 102.3(7) . 2_565 ?
O8 W3 O8 88.3(9) . 2_565 ?
O7 W3 O1 101.2(8) . 2_565 ?
O8 W3 O1 156.5(7) . 2_565 ?
O8 W3 O1 88.4(7) 2_565 2_565 ?
O7 W3 O1 101.2(8) . . ?
O8 W3 O1 88.4(7) . . ?
O8 W3 O1 156.5(7) 2_565 . ?
O1 W3 O1 85.4(9) 2_565 . ?
O7 W3 O6 169.3(9) . . ?
O8 W3 O6 85.3(6) . . ?
O8 W3 O6 85.3(6) 2_565 . ?
O1 W3 O6 71.2(6) 2_565 . ?
O1 W3 O6 71.2(6) . . ?
O4 W4 O17 98.9(9) . . ?
O4 W4 O3 105.3(8) . . ?
O17 W4 O3 155.7(7) . . ?
O4 W4 O5 104.0(9) . . ?
O17 W4 O5 88.9(7) . . ?
O3 W4 O5 86.3(6) . . ?
O4 W4 O18 100.3(10) . . ?
O17 W4 O18 87.8(6) . . ?
O3 W4 O18 86.8(6) . . ?
O5 W4 O18 155.7(7) . . ?
O4 W4 O23 168.1(9) . . ?
O17 W4 O23 72.1(5) . . ?
O3 W4 O23 83.7(5) . . ?
O5 W4 O23 84.0(6) . . ?
O18 W4 O23 72.1(6) . . ?
O16 W5 O2 104.5(9) . . ?
O16 W5 O5 106.7(9) . . ?
O2 W5 O5 86.6(6) . . ?
O16 W5 O1 98.0(10) . . ?
O2 W5 O1 157.4(7) . . ?
O5 W5 O1 89.1(7) . . ?
O16 W5 O24 99.0(9) . . ?
O2 W5 O24 85.9(9) . . ?
O5 W5 O24 154.3(8) . . ?
O1 W5 O24 88.4(8) . . ?
O16 W5 O6 164.4(10) . . ?
O2 W5 O6 85.6(7) . . ?
O5 W5 O6 85.5(6) . . ?
O1 W5 O6 71.9(7) . . ?
O24 W5 O6 69.5(7) . . ?
O14 W6 O19 105.6(9) . . ?
O14 W6 O18 97.9(10) . . ?
O19 W6 O18 89.4(6) . . ?
O14 W6 O20 103.0(11) . . ?
O19 W6 O20 86.5(8) . . ?
O18 W6 O20 159.0(9) . . ?
O14 W6 O11 96.1(9) . . ?
O19 W6 O11 158.3(7) . . ?
O18 W6 O11 87.4(6) . . ?
O20 W6 O11 88.8(9) . . ?
O14 W6 O23 163.9(9) . . ?
O19 W6 O23 87.3(6) . . ?
O18 W6 O23 72.2(6) . . ?
O20 W6 O23 87.0(8) . . ?
O11 W6 O23 71.3(6) . . ?
O10 W7 O21 103.8(8) . 2_565 ?
O10 W7 O21 103.8(8) . . ?
O21 W7 O21 91.1(10) 2_565 . ?
O10 W7 O19 103.3(7) . . ?
O21 W7 O19 152.7(8) 2_565 . ?
O21 W7 O19 85.4(7) . . ?
O10 W7 O19 103.3(8) . 2_565 ?
O21 W7 O19 85.4(7) 2_565 2_565 ?
O21 W7 O19 152.7(8) . 2_565 ?
O19 W7 O19 85.4(9) . 2_565 ?
O10 W7 O22 168.1(9) . . ?
O21 W7 O22 68.3(6) 2_565 . ?
O21 W7 O22 68.3(6) . . ?
O19 W7 O22 85.3(6) . . ?
O19 W7 O22 85.3(6) 2_565 . ?
W5 O1 W3 121.7(9) . . ?
W5 O2 W2 151.6(8) . . ?
W2 O3 W4 152.8(9) . . ?
W5 O5 W4 151.7(9) . . ?
Ge O6 W5 121.7(6) . 2_565 ?
Ge O6 W5 121.7(6) . . ?
W5 O6 W5 96.4(7) 2_565 . ?
Ge O6 W3 120.5(10) . . ?
W5 O6 W3 95.0(6) 2_565 . ?
W5 O6 W3 95.0(6) . . ?
W1 O8 W3 149.4(8) . . ?
W1 O9 W1 144.7(14) . 2_565 ?
W6 O11 W1 119.6(7) . . ?
W1 O12 Cu1 141.0(12) . . ?
W2 O13 Cu1 165.4(13) . 1_554 ?
W2 O15 W2 119.6(12) . 2_565 ?
W4 O17 W1 120.5(7) . . ?
W6 O18 W4 122.8(9) . . ?
W6 O19 W7 152.0(9) . . ?
W6 O20 W6 148.8(12) 2_565 . ?
W2 O21 W7 127.4(9) . . ?
Ge O22 W2 121.5(7) . 2_565 ?
Ge O22 W2 121.5(7) . . ?
W2 O22 W2 94.3(6) 2_565 . ?
Ge O22 W7 123.8(10) . . ?
W2 O22 W7 94.0(6) 2_565 . ?
W2 O22 W7 94.0(6) . . ?
Ge O23 W1 122.0(7) . . ?
Ge O23 W4 122.5(7) . . ?
W1 O23 W4 94.3(5) . . ?
Ge O23 W6 121.5(7) . . ?
W1 O23 W6 96.3(5) . . ?
W4 O23 W6 92.9(5) . . ?
W5 O24 W5 124.6(11) 2_565 . ?
N3 N1 C15 108.0 . . ?
N3 N1 Cu1 116.5(4) . . ?
C15 N1 Cu1 131.1(4) . . ?
N4 N2 C7 107.0(16) . . ?
N4 N2 Cu1 117.0(15) . . ?
C7 N2 Cu1 126.7(14) . . ?
C16 N3 N1 108.1 . . ?
N2 N4 C8 113.5(19) . . ?
C4 N5 C5 120.7(16) . . ?
C12 N6 C13 122.0(16) . . ?
C16 C1 C15 108.0 . . ?
C3 C2 C6 120.0 . . ?
C3 C2 C15 119.7 . . ?
C6 C2 C15 120.2 . . ?
C2 C3 C4 120.0 . . ?
N5 C4 C3 119.9(9) . . ?
C6 C5 N5 119.3(10) . . ?
C5 C6 C2 120.0 . . ?
N2 C7 C9 109.9(15) . . ?
N2 C7 C10 121.7(13) . . ?
C9 C7 C10 128.1(16) . . ?
N4 C8 C9 105(2) . . ?
C7 C9 C8 104.4(17) . . ?
C11 C10 C14 120.0 . . ?
C11 C10 C7 122.7(8) . . ?
C14 C10 C7 117.3(8) . . ?
C12 C11 C10 120.0 . . ?
N6 C12 C11 119.6(9) . . ?
C14 C13 N6 118.4(8) . . ?
C13 C14 C10 120.0 . . ?
C1 C15 N1 108.0 . . ?
C1 C15 C2 126.5 . . ?
N1 C15 C2 125.5 . . ?
N3 C16 C1 108.0 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu1 N1 1.953(10) . ?
Cu1 O12 1.965(16) . ?
Cu1 O13 2.007(17) 1_556 ?
Cu1 N2 2.04(2) . ?
Ge O22 1.71(2) . ?
Ge O23 1.707(13) 2_565 ?
Ge O23 1.707(13) . ?
Ge O6 1.76(2) . ?
W1 O12 1.738(17) . ?
W1 O8 1.855(14) . ?
W1 O9 1.888(8) . ?
W1 O17 1.963(15) . ?
W1 O11 1.995(16) . ?
W1 O23 2.246(13) . ?
W2 O13 1.686(17) . ?
W2 O21 1.848(19) . ?
W2 O3 1.868(14) . ?
W2 O2 1.932(15) . ?
W2 O15 1.951(12) . ?
W2 O22 2.300(12) . ?
W3 O7 1.79(2) . ?
W3 O8 1.899(13) . ?
W3 O8 1.899(13) 2_565 ?
W3 O1 1.957(15) 2_565 ?
W3 O1 1.957(16) . ?
W3 O6 2.31(2) . ?
W4 O4 1.675(14) . ?
W4 O17 1.898(15) . ?
W4 O3 1.919(14) . ?
W4 O5 1.927(16) . ?
W4 O18 1.944(17) . ?
W4 O23 2.327(12) . ?
W5 O16 1.697(17) . ?
W5 O2 1.878(15) . ?
W5 O5 1.889(15) . ?
W5 O1 1.928(17) . ?
W5 O24 1.932(10) . ?
W5 O6 2.294(13) . ?
W6 O14 1.686(19) . ?
W6 O19 1.843(16) . ?
W6 O18 1.913(16) . ?
W6 O20 1.914(6) . ?
W6 O11 1.960(14) . ?
W6 O23 2.344(14) . ?
W7 O10 1.67(2) . ?
W7 O21 1.927(16) 2_565 ?
W7 O21 1.927(16) . ?
W7 O19 1.928(16) . ?
W7 O19 1.928(16) 2_565 ?
W7 O22 2.33(2) . ?
O6 W5 2.294(13) 2_565 ?
O9 W1 1.888(7) 2_565 ?
O13 Cu1 2.007(17) 1_554 ?
O15 W2 1.951(12) 2_565 ?
O20 W6 1.914(6) 2_565 ?
O22 W2 2.300(12) 2_565 ?
O24 W5 1.932(10) 2_565 ?
N1 N3 1.370(4) . ?
N1 C15 1.371(4) . ?
N2 N4 1.30(2) . ?
N2 C7 1.35(3) . ?
N3 C16 1.370(4) . ?
N4 C8 1.35(3) . ?
N5 C4 1.37(2) . ?
N5 C5 1.40(2) . ?
N6 C12 1.35(2) . ?
N6 C13 1.40(2) . ?
C1 C16 1.370(4) . ?
C1 C15 1.370(4) . ?
C2 C3 1.389(4) . ?
C2 C6 1.389(4) . ?
C2 C15 1.426(5) . ?
C3 C4 1.389(4) . ?
C5 C6 1.388(4) . ?
C7 C9 1.396(17) . ?
C7 C10 1.46(2) . ?
C8 C9 1.43(3) . ?
C10 C11 1.3901 . ?
C10 C14 1.3901 . ?
C11 C12 1.3899 . ?
C13 C14 1.3900 . ?
