#------------------------------------------------------------------------------
#$Date: 2021-06-05 21:10:29 +0300 (Sat, 05 Jun 2021) $
#$Revision: 265955 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/26/7242606.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7242606
loop_
_publ_author_name
'Ruan, Zhong-Yu'
'Lu, Yong-Fang'
'Lv, Xi'
'Wu, Jian-Zhong'
'Ou, Yong-Cong'
'Cai, Yue-Peng'
_publ_section_title
;
 Synthesis of a Eu complex based on benzonitrile hydrolysis as the first
 luminescent probe for clinafloxacin
;
_journal_issue                   19
_journal_name_full               CrystEngComm
_journal_page_first              3602
_journal_page_last               3608
_journal_paper_doi               10.1039/D1CE00315A
_journal_volume                  23
_journal_year                    2021
_chemical_formula_sum            'C80 H54 Eu2 N8 O12'
_chemical_formula_weight         1623.29
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2021-02-24 deposited with the CCDC.	2021-04-05 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 103.757(4)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   13.6055(5)
_cell_length_b                   21.8372(8)
_cell_length_c                   11.3040(4)
_cell_measurement_reflns_used    7613
_cell_measurement_temperature    150.00(10)
_cell_measurement_theta_max      29.0720
_cell_measurement_theta_min      2.6260
_cell_volume                     3262.1(2)
_computing_cell_refinement       'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)'
_computing_molecular_graphics    'ORTEP-3 (Farrugia, 2012)'
_computing_publication_material  'PLATON (Spek, 2020)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXL-2018/3 (Sheldrick, 2018)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      150.00(10)
_diffrn_detector_area_resol_mean 5.2684
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'SuperNova (Mo) X-ray Source'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0332
_diffrn_reflns_av_unetI/netI     0.0459
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            16165
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.500
_diffrn_reflns_theta_min         2.076
_diffrn_source                   'micro-focus sealed X-ray tube'
_exptl_absorpt_coefficient_mu    1.980
_exptl_absorpt_correction_T_max  0.854
_exptl_absorpt_correction_T_min  0.789
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.43f (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.653
_exptl_crystal_description       block
_exptl_crystal_F_000             1624
_exptl_crystal_size_max          0.120
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.080
_refine_diff_density_max         1.620
_refine_diff_density_min         -0.489
_refine_diff_density_rms         0.097
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.077
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     460
_refine_ls_number_reflns         6077
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.077
_refine_ls_R_factor_all          0.0395
_refine_ls_R_factor_gt           0.0314
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0194P)²+2.8044P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0606
_refine_ls_wR_factor_ref         0.0642
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5268
_reflns_number_total             6077
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1ce00315a1.cif
_cod_data_source_block           shelx
_cod_depositor_comments          'Adding full bibliography for 7242606.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7242606
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.797
_shelx_estimated_absorpt_t_max   0.858
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.3611(3) 0.10275(17) 0.3179(3) 0.0235(9) Uani 1 1 d . . . . .
H1 H 0.426637 0.112398 0.313097 0.028 Uiso 1 1 calc R U . . .
C2 C 0.3242(3) 0.12977(17) 0.4105(3) 0.0248(9) Uani 1 1 d . . . . .
H2 H 0.364252 0.156557 0.465460 0.030 Uiso 1 1 calc R U . . .
C3 C 0.2285(3) 0.11630(16) 0.4189(3) 0.0217(8) Uani 1 1 d . . . . .
H3 H 0.202458 0.134001 0.479737 0.026 Uiso 1 1 calc R U . . .
C4 C 0.1699(3) 0.07598(15) 0.3362(3) 0.0167(8) Uani 1 1 d . . . . .
C5 C 0.2132(2) 0.05006(15) 0.2461(3) 0.0154(7) Uani 1 1 d . . . . .
C6 C 0.1588(2) 0.00479(15) 0.1618(3) 0.0152(7) Uani 1 1 d . . . . .
C7 C 0.1570(3) -0.06173(15) 0.0018(3) 0.0186(8) Uani 1 1 d . . . . .
H7 H 0.187345 -0.076488 -0.058008 0.022 Uiso 1 1 calc R U . . .
C8 C 0.0649(2) -0.08691(15) 0.0101(3) 0.0175(8) Uani 1 1 d . . . . .
H8 H 0.036396 -0.119195 -0.040159 0.021 Uiso 1 1 calc R U . . .
C9 C 0.0172(3) -0.06325(16) 0.0934(3) 0.0195(8) Uani 1 1 d . . . . .
H9 H -0.045233 -0.078689 0.098881 0.023 Uiso 1 1 calc R U . . .
C10 C 0.0623(2) -0.01587(15) 0.1705(3) 0.0149(7) Uani 1 1 d . . . . .
C11 C 0.0192(2) 0.01400(15) 0.2579(3) 0.0156(7) Uani 1 1 d . . . . .
C12 C 0.0681(2) 0.05760(15) 0.3377(3) 0.0152(7) Uani 1 1 d . . . . .
C13 C -0.0763(3) 0.04553(15) 0.3777(3) 0.0156(8) Uani 1 1 d . . . . .
C14 C -0.1642(3) 0.04853(15) 0.4323(3) 0.0165(8) Uani 1 1 d . . . . .
C15 C -0.2524(3) 0.01565(16) 0.3819(3) 0.0191(8) Uani 1 1 d . . . . .
H15 H -0.257172 -0.006842 0.310852 0.023 Uiso 1 1 calc R U . . .
C16 C -0.3330(3) 0.01656(17) 0.4378(3) 0.0220(8) Uani 1 1 d . . . . .
H16 H -0.391772 -0.005122 0.403661 0.026 Uiso 1 1 calc R U . . .
C17 C -0.3264(3) 0.04931(16) 0.5431(3) 0.0222(8) Uani 1 1 d . . . . .
H17 H -0.379744 0.048961 0.581462 0.027 Uiso 1 1 calc R U . . .
C18 C -0.2398(3) 0.08287(17) 0.5918(3) 0.0245(9) Uani 1 1 d . . . . .
H18 H -0.235969 0.105793 0.662097 0.029 Uiso 1 1 calc R U . . .
C19 C -0.1593(3) 0.08264(16) 0.5371(3) 0.0205(8) Uani 1 1 d . . . . .
H19 H -0.101577 0.105393 0.570624 0.025 Uiso 1 1 calc R U . . .
C20 C 0.4888(3) -0.08100(15) 0.1707(3) 0.0166(8) Uani 1 1 d . . . . .
C21 C 0.5165(3) -0.14219(15) 0.2284(3) 0.0180(8) Uani 1 1 d . . . . .
C22 C 0.5907(3) -0.17833(18) 0.1983(4) 0.0387(11) Uani 1 1 d . . . . .
H22 H 0.622214 -0.165235 0.138211 0.046 Uiso 1 1 calc R U . . .
C23 C 0.6184(3) -0.23342(19) 0.2561(5) 0.0498(14) Uani 1 1 d . . . . .
H23 H 0.668879 -0.256839 0.235364 0.060 Uiso 1 1 calc R U . . .
C24 C 0.5722(3) -0.25411(17) 0.3444(4) 0.0346(10) Uani 1 1 d . . . . .
H24 H 0.591990 -0.290834 0.384664 0.042 Uiso 1 1 calc R U . . .
C25 C 0.4964(3) -0.21970(16) 0.3718(4) 0.0267(9) Uani 1 1 d . . . . .
H25 H 0.463582 -0.233791 0.429853 0.032 Uiso 1 1 calc R U . . .
C26 C 0.4682(3) -0.16460(16) 0.3148(3) 0.0228(8) Uani 1 1 d . . . . .
H26 H 0.416230 -0.142096 0.334326 0.027 Uiso 1 1 calc R U . . .
C27 C 0.2315(3) 0.11357(15) -0.0910(3) 0.0161(8) Uani 1 1 d . . . . .
C28 C 0.1646(2) 0.16086(15) -0.1651(3) 0.0172(8) Uani 1 1 d . . . . .
C29 C 0.1228(3) 0.15084(16) -0.2881(3) 0.0211(8) Uani 1 1 d . . . . .
H29 H 0.136567 0.114641 -0.324370 0.025 Uiso 1 1 calc R U . . .
C30 C 0.0605(3) 0.19468(18) -0.3571(4) 0.0304(10) Uani 1 1 d . . . . .
H30 H 0.033043 0.187995 -0.439569 0.036 Uiso 1 1 calc R U . . .
C31 C 0.0394(3) 0.24795(18) -0.3032(4) 0.0314(10) Uani 1 1 d . . . . .
H31 H -0.002114 0.277330 -0.349637 0.038 Uiso 1 1 calc R U . . .
C32 C 0.0797(3) 0.25815(17) -0.1804(4) 0.0327(10) Uani 1 1 d . . . . .
H32 H 0.064020 0.293928 -0.144171 0.039 Uiso 1 1 calc R U . . .
C33 C 0.1433(3) 0.21503(16) -0.1114(4) 0.0238(9) Uani 1 1 d . . . . .
H33 H 0.171693 0.222320 -0.029285 0.029 Uiso 1 1 calc R U . . .
C34 C 0.3972(2) -0.09142(15) -0.1456(3) 0.0147(7) Uani 1 1 d . . . . .
C35 C 0.3434(2) -0.14658(15) -0.2084(3) 0.0162(8) Uani 1 1 d . . . . .
C36 C 0.2771(3) -0.17918(16) -0.1555(4) 0.0254(9) Uani 1 1 d . . . . .
H36 H 0.265979 -0.166418 -0.081242 0.030 Uiso 1 1 calc R U . . .
C37 C 0.2270(3) -0.23087(17) -0.2128(4) 0.0350(11) Uani 1 1 d . . . . .
H37 H 0.183673 -0.252909 -0.176372 0.042 Uiso 1 1 calc R U . . .
C38 C 0.2423(3) -0.24906(18) -0.3240(4) 0.0387(11) Uani 1 1 d . . . . .
H38 H 0.208497 -0.283164 -0.363151 0.046 Uiso 1 1 calc R U . . .
C39 C 0.3073(3) -0.21682(17) -0.3769(4) 0.0316(10) Uani 1 1 d . . . . .
H39 H 0.316603 -0.228877 -0.452429 0.038 Uiso 1 1 calc R U . . .
C40 C 0.3591(3) -0.16659(16) -0.3187(3) 0.0230(8) Uani 1 1 d . . . . .
H40 H 0.404828 -0.146058 -0.353932 0.028 Uiso 1 1 calc R U . . .
N1 N 0.3088(2) 0.06433(12) 0.2368(3) 0.0160(6) Uani 1 1 d . . . . .
N2 N 0.2040(2) -0.01742(12) 0.0755(2) 0.0150(6) Uani 1 1 d . . . . .
N3 N 0.0090(2) 0.07736(13) 0.4135(3) 0.0187(7) Uani 1 1 d . . . . .
N4 N -0.0737(2) 0.00729(13) 0.2833(3) 0.0165(6) Uani 1 1 d . . . . .
H4 H -0.121531 -0.016595 0.246474 0.020 Uiso 1 1 calc R U . . .
O1 O 0.41635(18) -0.05243(10) 0.1960(2) 0.0213(6) Uani 1 1 d . . . . .
O2 O 0.53793(17) -0.05941(10) 0.0972(2) 0.0197(6) Uani 1 1 d . . . . .
O3 O 0.28696(17) 0.12718(10) 0.0116(2) 0.0188(5) Uani 1 1 d . . . . .
O4 O 0.23248(17) 0.05918(10) -0.1328(2) 0.0178(5) Uani 1 1 d . . . . .
O5 O 0.35173(17) -0.06006(10) -0.0814(2) 0.0178(5) Uani 1 1 d . . . . .
O6 O 0.48425(16) -0.07951(10) -0.1615(2) 0.0177(5) Uani 1 1 d . . . . .
Eu1 Eu 0.37324(2) 0.02713(2) 0.04758(2) 0.01304(6) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0030 0.0020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0060 0.0030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0110 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1580 3.6680 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C2 124.0(3) . . ?
C3 C2 C1 118.9(3) . . ?
C2 C3 C4 119.7(3) . . ?
C3 C4 C5 118.0(3) . . ?
C3 C4 C12 124.5(3) . . ?
C5 C4 C12 117.5(3) . . ?
N1 C5 C4 122.2(3) . . ?
N1 C5 C6 116.9(3) . . ?
C4 C5 C6 120.9(3) . . ?
N2 C6 C10 121.4(3) . . ?
N2 C6 C5 117.9(3) . . ?
C10 C6 C5 120.7(3) . . ?
N2 C7 C8 123.4(3) . . ?
C9 C8 C7 118.6(3) . . ?
C8 C9 C10 120.0(3) . . ?
C9 C10 C6 118.1(3) . . ?
C9 C10 C11 125.5(3) . . ?
C6 C10 C11 116.4(3) . . ?
N4 C11 C12 105.4(3) . . ?
N4 C11 C10 130.6(3) . . ?
C12 C11 C10 124.0(3) . . ?
C11 C12 N3 111.3(3) . . ?
C11 C12 C4 120.2(3) . . ?
N3 C12 C4 128.5(3) . . ?
N3 C13 N4 112.1(3) . . ?
N3 C13 C14 125.9(3) . . ?
N4 C13 C14 122.0(3) . . ?
C19 C14 C15 119.1(3) . . ?
C19 C14 C13 120.2(3) . . ?
C15 C14 C13 120.7(3) . . ?
C16 C15 C14 120.0(3) . . ?
C17 C16 C15 120.4(3) . . ?
C16 C17 C18 119.6(3) . . ?
C19 C18 C17 120.7(3) . . ?
C18 C19 C14 120.1(3) . . ?
O1 C20 O2 121.8(3) . . ?
O1 C20 C21 118.3(3) . . ?
O2 C20 C21 119.9(3) . . ?
O1 C20 Eu1 50.17(17) . . ?
O2 C20 Eu1 72.76(18) . . ?
C21 C20 Eu1 163.4(2) . . ?
C22 C21 C26 117.8(3) . . ?
C22 C21 C20 121.6(3) . . ?
C26 C21 C20 120.6(3) . . ?
C23 C22 C21 120.9(4) . . ?
C24 C23 C22 120.7(4) . . ?
C25 C24 C23 118.8(4) . . ?
C24 C25 C26 121.0(4) . . ?
C25 C26 C21 120.8(3) . . ?
O3 C27 O4 120.2(3) . . ?
O3 C27 C28 120.3(3) . . ?
O4 C27 C28 119.5(3) . . ?
O3 C27 Eu1 58.48(17) . . ?
O4 C27 Eu1 61.85(17) . . ?
C28 C27 Eu1 175.7(2) . . ?
C29 C28 C33 119.5(3) . . ?
C29 C28 C27 120.1(3) . . ?
C33 C28 C27 120.3(3) . . ?
C28 C29 C30 120.2(3) . . ?
C31 C30 C29 119.9(4) . . ?
C30 C31 C32 120.4(4) . . ?
C31 C32 C33 120.0(4) . . ?
C32 C33 C28 119.9(4) . . ?
O5 C34 O6 125.0(3) . . ?
O5 C34 C35 117.2(3) . . ?
O6 C34 C35 117.8(3) . . ?
C40 C35 C36 118.7(3) . . ?
C40 C35 C34 121.1(3) . . ?
C36 C35 C34 120.2(3) . . ?
C35 C36 C37 120.6(4) . . ?
C38 C37 C36 119.6(4) . . ?
C39 C38 C37 120.1(4) . . ?
C38 C39 C40 120.5(4) . . ?
C39 C40 C35 120.6(4) . . ?
C1 N1 C5 117.3(3) . . ?
C1 N1 Eu1 122.2(2) . . ?
C5 N1 Eu1 120.0(2) . . ?
C7 N2 C6 118.3(3) . . ?
C7 N2 Eu1 120.3(2) . . ?
C6 N2 Eu1 121.4(2) . . ?
C13 N3 C12 104.1(3) . . ?
C13 N4 C11 107.2(3) . . ?
C20 O1 Eu1 106.0(2) . . ?
C20 O2 Eu1 175.3(2) . 3_655 ?
C20 O2 Eu1 82.27(19) . . ?
Eu1 O2 Eu1 99.89(8) 3_655 . ?
C27 O3 Eu1 95.7(2) . . ?
C27 O4 Eu1 91.8(2) . . ?
C34 O5 Eu1 141.5(2) . . ?
C34 O6 Eu1 134.3(2) . 3_655 ?
O6 Eu1 O2 75.12(8) 3_655 3_655 ?
O6 Eu1 O5 133.72(8) 3_655 . ?
O2 Eu1 O5 79.78(8) 3_655 . ?
O6 Eu1 O1 86.36(8) 3_655 . ?
O2 Eu1 O1 128.54(8) 3_655 . ?
O5 Eu1 O1 79.73(8) . . ?
O6 Eu1 O3 87.57(8) 3_655 . ?
O2 Eu1 O3 85.60(8) 3_655 . ?
O5 Eu1 O3 128.66(8) . . ?
O1 Eu1 O3 141.92(8) . . ?
O6 Eu1 O4 132.13(8) 3_655 . ?
O2 Eu1 O4 76.94(8) 3_655 . ?
O5 Eu1 O4 76.64(7) . . ?
O1 Eu1 O4 140.89(8) . . ?
O3 Eu1 O4 52.10(7) . . ?
O6 Eu1 N2 139.24(8) 3_655 . ?
O2 Eu1 N2 144.46(8) 3_655 . ?
O5 Eu1 N2 77.87(8) . . ?
O1 Eu1 N2 73.62(8) . . ?
O3 Eu1 N2 87.17(8) . . ?
O4 Eu1 N2 71.24(8) . . ?
O6 Eu1 N1 78.18(8) 3_655 . ?
O2 Eu1 N1 142.86(8) 3_655 . ?
O5 Eu1 N1 137.06(8) . . ?
O1 Eu1 N1 74.14(8) . . ?
O3 Eu1 N1 67.82(8) . . ?
O4 Eu1 N1 103.55(8) . . ?
N2 Eu1 N1 62.47(8) . . ?
O6 Eu1 C27 109.68(9) 3_655 . ?
O2 Eu1 C27 79.30(9) 3_655 . ?
O5 Eu1 C27 102.89(9) . . ?
O1 Eu1 C27 151.53(8) . . ?
O3 Eu1 C27 25.78(8) . . ?
O4 Eu1 C27 26.36(8) . . ?
N2 Eu1 C27 79.20(9) . . ?
N1 Eu1 C27 86.00(9) . . ?
O6 Eu1 O2 73.20(7) 3_655 . ?
O2 Eu1 O2 80.11(8) 3_655 . ?
O5 Eu1 O2 64.54(7) . . ?
O1 Eu1 O2 48.48(7) . . ?
O3 Eu1 O2 158.40(7) . . ?
O4 Eu1 O2 137.68(7) . . ?
N2 Eu1 O2 113.77(7) . . ?
N1 Eu1 O2 116.04(8) . . ?
C27 Eu1 O2 157.55(8) . . ?
O6 Eu1 C20 81.69(8) 3_655 . ?
O2 Eu1 C20 105.01(9) 3_655 . ?
O5 Eu1 C20 68.08(9) . . ?
O1 Eu1 C20 23.81(8) . . ?
O3 Eu1 C20 162.29(8) . . ?
O4 Eu1 C20 143.45(8) . . ?
N2 Eu1 C20 91.79(9) . . ?
N1 Eu1 C20 96.07(9) . . ?
C27 Eu1 C20 168.61(9) . . ?
O2 Eu1 C20 24.97(8) . . ?
O6 Eu1 Eu1 69.06(5) 3_655 3_655 ?
O2 Eu1 Eu1 44.83(6) 3_655 3_655 ?
O5 Eu1 Eu1 65.69(5) . 3_655 ?
O1 Eu1 Eu1 83.73(5) . 3_655 ?
O3 Eu1 Eu1 128.34(5) . 3_655 ?
O4 Eu1 Eu1 113.37(5) . 3_655 ?
N2 Eu1 Eu1 139.95(6) . 3_655 ?
N1 Eu1 Eu1 141.40(6) . 3_655 ?
C27 Eu1 Eu1 123.54(6) . 3_655 ?
O2 Eu1 Eu1 35.28(5) . 3_655 ?
C20 Eu1 Eu1 60.20(6) . 3_655 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.319(4) . ?
C1 C2 1.395(5) . ?
C2 C3 1.359(5) . ?
C3 C4 1.389(5) . ?
C4 C5 1.411(5) . ?
C4 C12 1.446(5) . ?
C5 N1 1.366(4) . ?
C5 C6 1.448(5) . ?
C6 N2 1.360(4) . ?
C6 C10 1.414(4) . ?
C7 N2 1.336(4) . ?
C7 C8 1.391(5) . ?
C8 C9 1.366(5) . ?
C9 C10 1.397(5) . ?
C10 C11 1.422(5) . ?
C11 N4 1.369(4) . ?
C11 C12 1.370(5) . ?
C12 N3 1.377(4) . ?
C13 N3 1.330(4) . ?
C13 N4 1.362(4) . ?
C13 C14 1.473(5) . ?
C14 C19 1.388(5) . ?
C14 C15 1.399(5) . ?
C15 C16 1.390(5) . ?
C16 C17 1.373(5) . ?
C17 C18 1.385(5) . ?
C18 C19 1.380(5) . ?
C20 O1 1.256(4) . ?
C20 O2 1.274(4) . ?
C20 C21 1.495(5) . ?
C20 Eu1 2.991(3) . ?
C21 C22 1.386(5) . ?
C21 C26 1.389(5) . ?
C22 C23 1.378(6) . ?
C23 C24 1.376(6) . ?
C24 C25 1.369(5) . ?
C25 C26 1.376(5) . ?
C27 O3 1.259(4) . ?
C27 O4 1.280(4) . ?
C27 C28 1.495(5) . ?
C27 Eu1 2.881(3) . ?
C28 C29 1.389(5) . ?
C28 C33 1.391(5) . ?
C29 C30 1.389(5) . ?
C30 C31 1.374(5) . ?
C31 C32 1.384(6) . ?
C32 C33 1.387(5) . ?
C34 O5 1.262(4) . ?
C34 O6 1.266(4) . ?
C34 C35 1.498(5) . ?
C35 C40 1.385(5) . ?
C35 C36 1.391(5) . ?
C36 C37 1.396(5) . ?
C37 C38 1.380(6) . ?
C38 C39 1.374(6) . ?
C39 C40 1.383(5) . ?
N1 Eu1 2.626(3) . ?
N2 Eu1 2.587(3) . ?
O1 Eu1 2.389(2) . ?
O2 Eu1 2.361(2) 3_655 ?
O2 Eu1 2.882(2) . ?
O3 Eu1 2.468(2) . ?
O4 Eu1 2.541(2) . ?
O5 Eu1 2.373(2) . ?
O6 Eu1 2.353(2) 3_655 ?
Eu1 Eu1 4.0276(3) 3_655 ?
