#------------------------------------------------------------------------------
#$Date: 2021-09-06 13:28:17 +0300 (Mon, 06 Sep 2021) $
#$Revision: 268668 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/30/7243098.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7243098
loop_
_publ_author_name
'Tseng, Tien-Wen'
'Luo, Tzuoo-Tsair'
'Tseng, Kuo-Yang'
'Hong, Yu-Xian'
'Huang, Guang-Cheng'
_publ_section_title
;
 Bent-bis(triazolyl)-based coordination polymers tuned by dicarboxylate
 ligands: syntheses, structures and properties
;
_journal_issue                   31
_journal_name_full               CrystEngComm
_journal_page_first              5293
_journal_page_last               5305
_journal_paper_doi               10.1039/D1CE00780G
_journal_volume                  23
_journal_year                    2021
_chemical_formula_sum            'C24 H17 N7 O8 Zn'
_chemical_formula_weight         596.81
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2021-06-12 deposited with the CCDC.	2021-06-22 downloaded from the CCDC.
;
_cell_angle_alpha                98.331(2)
_cell_angle_beta                 98.781(2)
_cell_angle_gamma                103.468(2)
_cell_formula_units_Z            2
_cell_length_a                   7.2333(5)
_cell_length_b                   9.6810(7)
_cell_length_c                   17.5939(12)
_cell_measurement_reflns_used    9728
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.11
_cell_measurement_theta_min      2.5
_cell_volume                     1163.04(14)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0642
_diffrn_reflns_av_unetI/netI     0.0457
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            30702
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.172
_diffrn_reflns_theta_min         2.202
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    1.125
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.9554
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
;
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.704
_exptl_crystal_description       prism
_exptl_crystal_F_000             608
_exptl_crystal_size_max          0.340
_exptl_crystal_size_mid          0.260
_exptl_crystal_size_min          0.260
_refine_diff_density_max         1.684
_refine_diff_density_min         -0.612
_refine_diff_density_rms         0.078
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     367
_refine_ls_number_reflns         5172
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.034
_refine_ls_R_factor_all          0.0489
_refine_ls_R_factor_gt           0.0368
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0495P)²+0.5790P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0893
_refine_ls_wR_factor_ref         0.0962
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4373
_reflns_number_total             5172
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1ce00780g2.cif
_cod_data_source_block           shelx_CCDC5
_cod_depositor_comments
'Adding full bibliography for 7243093--7243099.cif.'
_cod_database_code               7243098
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.701
_shelx_estimated_absorpt_t_max   0.759
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Zn1 Zn 0.24759(4) 0.19604(3) 0.95353(2) 0.01217(9) Uani 1 1 d . . . . .
C1 C 0.0544(3) 0.5324(2) 0.87994(13) 0.0112(5) Uani 1 1 d . . . . .
C2 C 0.0996(3) 0.6825(2) 0.90171(13) 0.0118(5) Uani 1 1 d . . . . .
H2 H 0.169461 0.727174 0.951557 0.014 Uiso 1 1 calc R U . . .
C3 C 0.0406(3) 0.7659(2) 0.84928(13) 0.0117(5) Uani 1 1 d . . . . .
C4 C -0.0659(3) 0.6997(2) 0.77466(13) 0.0120(5) Uani 1 1 d . . . . .
H4 H -0.104844 0.754380 0.738986 0.014 Uiso 1 1 calc R U . . .
C5 C -0.1118(3) 0.5507(2) 0.75525(13) 0.0121(5) Uani 1 1 d . . . . .
C6 C -0.0529(3) 0.4656(2) 0.80593(14) 0.0125(5) Uani 1 1 d . . . . .
H6 H -0.084620 0.365547 0.790725 0.015 Uiso 1 1 calc R U . . .
C7 C 0.1338(3) 0.4425(2) 0.93361(13) 0.0120(5) Uani 1 1 d . . . . .
C8 C 0.0968(3) 0.9290(2) 0.87077(14) 0.0123(5) Uani 1 1 d . . . . .
C9 C 0.6194(3) 0.4227(2) 1.26042(13) 0.0118(5) Uani 1 1 d . . . . .
C10 C 0.7081(3) 0.3649(3) 1.31937(14) 0.0161(5) Uani 1 1 d . . . . .
H10 H 0.700371 0.266461 1.311940 0.019 Uiso 1 1 calc R U . . .
C11 C 0.8083(3) 0.4549(3) 1.38927(14) 0.0168(5) Uani 1 1 d . . . . .
H11 H 0.868396 0.417558 1.429101 0.020 Uiso 1 1 calc R U . . .
C12 C 0.8178(3) 0.6003(3) 1.39914(14) 0.0149(5) Uani 1 1 d . . . . .
C13 C 0.7307(4) 0.6582(3) 1.34017(14) 0.0170(5) Uani 1 1 d . . . . .
H13 H 0.739788 0.756776 1.347583 0.020 Uiso 1 1 calc R U . . .
C14 C 0.6306(3) 0.5693(3) 1.27048(14) 0.0161(5) Uani 1 1 d . . . . .
H14 H 0.571298 0.607231 1.230711 0.019 Uiso 1 1 calc R U . . .
C15 C 0.4419(3) 0.3578(2) 1.12077(13) 0.0121(5) Uani 1 1 d . . . . .
H15 H 0.449172 0.450228 1.110470 0.014 Uiso 1 1 calc R U . . .
C16 C 0.3846(4) 0.1316(3) 1.11148(14) 0.0161(5) Uani 1 1 d . . . . .
H16 H 0.340389 0.033319 1.090307 0.019 Uiso 1 1 calc R U . . .
C17 C 0.6877(3) 0.9346(2) 1.61880(14) 0.0153(5) Uani 1 1 d . . . . .
C18 C 0.5635(4) 0.8293(3) 1.55928(14) 0.0177(5) Uani 1 1 d . . . . .
H18 H 0.430107 0.813727 1.554764 0.021 Uiso 1 1 calc R U . . .
C19 C 0.6378(4) 0.7471(3) 1.50637(14) 0.0178(5) Uani 1 1 d . . . . .
H19 H 0.555114 0.675606 1.466614 0.021 Uiso 1 1 calc R U . . .
C20 C 0.8362(3) 0.7728(3) 1.51359(13) 0.0143(5) Uani 1 1 d . . . . .
C21 C 0.9614(4) 0.8826(3) 1.57106(14) 0.0186(5) Uani 1 1 d . . . . .
H21 H 1.094643 0.901617 1.574054 0.022 Uiso 1 1 calc R U . . .
C22 C 0.8860(4) 0.9631(3) 1.62358(15) 0.0200(5) Uani 1 1 d . . . . .
H22 H 0.968680 1.036606 1.662284 0.024 Uiso 1 1 calc R U . . .
C23 C 0.7007(4) 1.0861(2) 1.74877(14) 0.0155(5) Uani 1 1 d . . . . .
H23 H 0.832529 1.104794 1.768803 0.019 Uiso 1 1 calc R U . . .
C24 C 0.4040(4) 1.0740(3) 1.73445(14) 0.0176(5) Uani 1 1 d . . . . .
H24 H 0.285852 1.085025 1.745348 0.021 Uiso 1 1 calc R U . . .
N1 N 0.3580(3) 0.2358(2) 1.06999(11) 0.0129(4) Uani 1 1 d . . . . .
N2 N 0.5143(3) 0.3277(2) 1.18884(11) 0.0114(4) Uani 1 1 d . . . . .
N3 N 0.4776(3) 0.1814(2) 1.18378(12) 0.0171(4) Uani 1 1 d . . . . .
N4 N 0.5740(3) 1.1304(2) 1.78644(12) 0.0169(4) Uani 1 1 d . . . . .
N5 N 0.6109(3) 1.0100(2) 1.67734(12) 0.0156(4) Uani 1 1 d . . . . .
N6 N 0.4208(3) 1.0020(2) 1.66687(12) 0.0199(5) Uani 1 1 d . . . . .
N7 N -0.2186(3) 0.4784(2) 0.67551(12) 0.0150(4) Uani 1 1 d . . . . .
O1 O 0.0767(2) 0.30510(17) 0.90960(10) 0.0165(4) Uani 1 1 d . . . . .
O2 O 0.2533(2) 0.50202(17) 0.99457(9) 0.0166(4) Uani 1 1 d . . . . .
O3 O 0.1797(2) 0.98458(17) 0.94182(10) 0.0189(4) Uani 1 1 d . . . . .
O4 O 0.0629(2) 1.00098(17) 0.82026(10) 0.0177(4) Uani 1 1 d . . . . .
O5 O -0.2722(3) 0.55389(19) 0.63101(10) 0.0232(4) Uani 1 1 d . . . . .
O6 O -0.2476(3) 0.34690(18) 0.65802(10) 0.0212(4) Uani 1 1 d . . . . .
O7 O 0.9260(2) 0.68848(18) 1.46858(9) 0.0181(4) Uani 1 1 d . . . . .
O8 O 0.4920(3) 0.2690(2) 0.91508(11) 0.0226(4) Uani 1 1 d D . . . .
H8A H 0.542(3) 0.228(3) 0.8831(12) 0.034 Uiso 1 1 d D U . . .
H8B H 0.583(2) 0.327(2) 0.9456(12) 0.034 Uiso 1 1 d D U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Zn1 O3 124.37(7) . 1_545 ?
O1 Zn1 O8 103.12(8) . . ?
O3 Zn1 O8 111.29(8) 1_545 . ?
O1 Zn1 N1 121.07(7) . . ?
O3 Zn1 N1 95.48(7) 1_545 . ?
O8 Zn1 N1 99.00(8) . . ?
C6 C1 C2 119.7(2) . . ?
C6 C1 C7 119.5(2) . . ?
C2 C1 C7 120.7(2) . . ?
C3 C2 C1 120.4(2) . . ?
C3 C2 H2 119.8 . . ?
C1 C2 H2 119.8 . . ?
C2 C3 C4 120.2(2) . . ?
C2 C3 C8 120.9(2) . . ?
C4 C3 C8 118.8(2) . . ?
C5 C4 C3 118.1(2) . . ?
C5 C4 H4 121.0 . . ?
C3 C4 H4 121.0 . . ?
C4 C5 C6 122.8(2) . . ?
C4 C5 N7 119.1(2) . . ?
C6 C5 N7 118.1(2) . . ?
C5 C6 C1 118.8(2) . . ?
C5 C6 H6 120.6 . . ?
C1 C6 H6 120.6 . . ?
O2 C7 O1 124.0(2) . . ?
O2 C7 C1 120.3(2) . . ?
O1 C7 C1 115.7(2) . . ?
O4 C8 O3 123.7(2) . . ?
O4 C8 C3 119.6(2) . . ?
O3 C8 C3 116.7(2) . . ?
C14 C9 C10 120.9(2) . . ?
C14 C9 N2 120.3(2) . . ?
C10 C9 N2 118.8(2) . . ?
C11 C10 C9 119.5(2) . . ?
C11 C10 H10 120.2 . . ?
C9 C10 H10 120.2 . . ?
C12 C11 C10 119.3(2) . . ?
C12 C11 H11 120.3 . . ?
C10 C11 H11 120.3 . . ?
C11 C12 C13 121.2(2) . . ?
C11 C12 O7 117.8(2) . . ?
C13 C12 O7 120.9(2) . . ?
C14 C13 C12 119.9(2) . . ?
C14 C13 H13 120.1 . . ?
C12 C13 H13 120.1 . . ?
C13 C14 C9 119.2(2) . . ?
C13 C14 H14 120.4 . . ?
C9 C14 H14 120.4 . . ?
N1 C15 N2 109.6(2) . . ?
N1 C15 H15 125.2 . . ?
N2 C15 H15 125.2 . . ?
N3 C16 N1 114.2(2) . . ?
N3 C16 H16 122.9 . . ?
N1 C16 H16 122.9 . . ?
C22 C17 C18 120.2(2) . . ?
C22 C17 N5 119.9(2) . . ?
C18 C17 N5 119.9(2) . . ?
C17 C18 C19 120.1(2) . . ?
C17 C18 H18 120.0 . . ?
C19 C18 H18 120.0 . . ?
C20 C19 C18 119.1(2) . . ?
C20 C19 H19 120.5 . . ?
C18 C19 H19 120.5 . . ?
C19 C20 O7 123.8(2) . . ?
C19 C20 C21 121.0(2) . . ?
O7 C20 C21 115.1(2) . . ?
C22 C21 C20 119.4(2) . . ?
C22 C21 H21 120.3 . . ?
C20 C21 H21 120.3 . . ?
C21 C22 C17 120.1(2) . . ?
C21 C22 H22 119.9 . . ?
C17 C22 H22 119.9 . . ?
N4 C23 N5 110.0(2) . . ?
N4 C23 H23 125.0 . . ?
N5 C23 H23 125.0 . . ?
N6 C24 N4 114.3(2) . . ?
N6 C24 H24 122.8 . . ?
N4 C24 H24 122.8 . . ?
C15 N1 C16 103.50(19) . . ?
C15 N1 Zn1 131.99(16) . . ?
C16 N1 Zn1 123.95(15) . . ?
C15 N2 N3 109.90(18) . . ?
C15 N2 C9 130.2(2) . . ?
N3 N2 C9 119.94(18) . . ?
C16 N3 N2 102.78(19) . . ?
C23 N4 C24 102.8(2) . . ?
N6 N5 C23 110.08(19) . . ?
N6 N5 C17 120.4(2) . . ?
C23 N5 C17 129.3(2) . . ?
C24 N6 N5 102.8(2) . . ?
O6 N7 O5 124.1(2) . . ?
O6 N7 C5 117.97(19) . . ?
O5 N7 C5 117.90(19) . . ?
C7 O1 Zn1 115.13(14) . . ?
C8 O3 Zn1 108.75(14) . 1_565 ?
C12 O7 C20 118.47(18) . . ?
Zn1 O8 H8A 129.9(19) . . ?
Zn1 O8 H8B 118.6(18) . . ?
H8A O8 H8B 104.5(5) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Zn1 O1 1.9476(16) . ?
Zn1 O3 1.9629(16) 1_545 ?
Zn1 O8 2.0007(18) . ?
Zn1 N1 2.0280(19) . ?
C1 C6 1.389(3) . ?
C1 C2 1.394(3) . ?
C1 C7 1.511(3) . ?
C2 C3 1.393(3) . ?
C2 H2 0.9300 . ?
C3 C4 1.395(3) . ?
C3 C8 1.510(3) . ?
C4 C5 1.381(3) . ?
C4 H4 0.9300 . ?
C5 C6 1.384(3) . ?
C5 N7 1.479(3) . ?
C6 H6 0.9300 . ?
C7 O2 1.239(3) . ?
C7 O1 1.283(3) . ?
C8 O4 1.236(3) . ?
C8 O3 1.280(3) . ?
C9 C14 1.386(3) . ?
C9 C10 1.390(3) . ?
C9 N2 1.434(3) . ?
C10 C11 1.386(3) . ?
C10 H10 0.9300 . ?
C11 C12 1.377(3) . ?
C11 H11 0.9300 . ?
C12 C13 1.386(3) . ?
C12 O7 1.389(3) . ?
C13 C14 1.379(3) . ?
C13 H13 0.9300 . ?
C14 H14 0.9300 . ?
C15 N1 1.325(3) . ?
C15 N2 1.332(3) . ?
C15 H15 0.9300 . ?
C16 N3 1.309(3) . ?
C16 N1 1.360(3) . ?
C16 H16 0.9300 . ?
C17 C22 1.383(3) . ?
C17 C18 1.386(3) . ?
C17 N5 1.431(3) . ?
C18 C19 1.388(3) . ?
C18 H18 0.9300 . ?
C19 C20 1.381(3) . ?
C19 H19 0.9300 . ?
C20 O7 1.390(3) . ?
C20 C21 1.390(3) . ?
C21 C22 1.378(3) . ?
C21 H21 0.9300 . ?
C22 H22 0.9300 . ?
C23 N4 1.323(3) . ?
C23 N5 1.343(3) . ?
C23 H23 0.9300 . ?
C24 N6 1.326(3) . ?
C24 N4 1.359(3) . ?
C24 H24 0.9300 . ?
N2 N3 1.366(3) . ?
N5 N6 1.341(3) . ?
N7 O6 1.225(3) . ?
N7 O5 1.226(3) . ?
O8 H8A 0.819(2) . ?
O8 H8B 0.819(2) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 -1.1(3) . . . . ?
C7 C1 C2 C3 174.2(2) . . . . ?
C1 C2 C3 C4 0.6(3) . . . . ?
C1 C2 C3 C8 -177.0(2) . . . . ?
C2 C3 C4 C5 0.7(3) . . . . ?
C8 C3 C4 C5 178.4(2) . . . . ?
C3 C4 C5 C6 -1.5(3) . . . . ?
C3 C4 C5 N7 -177.85(19) . . . . ?
C4 C5 C6 C1 1.0(3) . . . . ?
N7 C5 C6 C1 177.40(19) . . . . ?
C2 C1 C6 C5 0.3(3) . . . . ?
C7 C1 C6 C5 -175.1(2) . . . . ?
C6 C1 C7 O2 169.1(2) . . . . ?
C2 C1 C7 O2 -6.3(3) . . . . ?
C6 C1 C7 O1 -7.6(3) . . . . ?
C2 C1 C7 O1 177.0(2) . . . . ?
C2 C3 C8 O4 171.4(2) . . . . ?
C4 C3 C8 O4 -6.3(3) . . . . ?
C2 C3 C8 O3 -8.2(3) . . . . ?
C4 C3 C8 O3 174.2(2) . . . . ?
C14 C9 C10 C11 0.3(4) . . . . ?
N2 C9 C10 C11 -179.2(2) . . . . ?
C9 C10 C11 C12 0.1(4) . . . . ?
C10 C11 C12 C13 -0.6(4) . . . . ?
C10 C11 C12 O7 -177.4(2) . . . . ?
C11 C12 C13 C14 0.7(4) . . . . ?
O7 C12 C13 C14 177.4(2) . . . . ?
C12 C13 C14 C9 -0.3(4) . . . . ?
C10 C9 C14 C13 -0.3(4) . . . . ?
N2 C9 C14 C13 179.3(2) . . . . ?
C22 C17 C18 C19 3.1(4) . . . . ?
N5 C17 C18 C19 -174.3(2) . . . . ?
C17 C18 C19 C20 -0.6(4) . . . . ?
C18 C19 C20 O7 173.8(2) . . . . ?
C18 C19 C20 C21 -2.3(4) . . . . ?
C19 C20 C21 C22 2.6(4) . . . . ?
O7 C20 C21 C22 -173.8(2) . . . . ?
C20 C21 C22 C17 -0.1(4) . . . . ?
C18 C17 C22 C21 -2.7(4) . . . . ?
N5 C17 C22 C21 174.7(2) . . . . ?
N2 C15 N1 C16 -0.1(3) . . . . ?
N2 C15 N1 Zn1 -171.50(15) . . . . ?
N3 C16 N1 C15 0.3(3) . . . . ?
N3 C16 N1 Zn1 172.63(16) . . . . ?
N1 C15 N2 N3 -0.2(3) . . . . ?
N1 C15 N2 C9 179.0(2) . . . . ?
C14 C9 N2 C15 11.3(4) . . . . ?
C10 C9 N2 C15 -169.2(2) . . . . ?
C14 C9 N2 N3 -169.6(2) . . . . ?
C10 C9 N2 N3 10.0(3) . . . . ?
N1 C16 N3 N2 -0.4(3) . . . . ?
C15 N2 N3 C16 0.3(2) . . . . ?
C9 N2 N3 C16 -179.0(2) . . . . ?
N5 C23 N4 C24 1.3(3) . . . . ?
N6 C24 N4 C23 -1.9(3) . . . . ?
N4 C23 N5 N6 -0.5(3) . . . . ?
N4 C23 N5 C17 -175.8(2) . . . . ?
C22 C17 N5 N6 168.8(2) . . . . ?
C18 C17 N5 N6 -13.7(3) . . . . ?
C22 C17 N5 C23 -16.3(4) . . . . ?
C18 C17 N5 C23 161.1(2) . . . . ?
N4 C24 N6 N5 1.6(3) . . . . ?
C23 N5 N6 C24 -0.7(3) . . . . ?
C17 N5 N6 C24 175.1(2) . . . . ?
C4 C5 N7 O6 175.7(2) . . . . ?
C6 C5 N7 O6 -0.9(3) . . . . ?
C4 C5 N7 O5 -4.2(3) . . . . ?
C6 C5 N7 O5 179.3(2) . . . . ?
O2 C7 O1 Zn1 -20.0(3) . . . . ?
C1 C7 O1 Zn1 156.61(15) . . . . ?
O4 C8 O3 Zn1 -1.9(3) . . . 1_565 ?
C3 C8 O3 Zn1 177.58(15) . . . 1_565 ?
C11 C12 O7 C20 -124.5(2) . . . . ?
C13 C12 O7 C20 58.8(3) . . . . ?
C19 C20 O7 C12 18.7(3) . . . . ?
C21 C20 O7 C12 -165.0(2) . . . . ?
