#------------------------------------------------------------------------------
#$Date: 2021-09-06 13:12:28 +0300 (Mon, 06 Sep 2021) $
#$Revision: 268628 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/32/7243241.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7243241
loop_
_publ_author_name
'Chuang, Po-Min'
'Wu, Jing-Yun'
_publ_section_title
;
 A highly stable Zn coordination polymer exhibiting pH-dependent
 fluorescence and as a visually ratiometric and on--off fluorescent sensor
;
_journal_issue                   30
_journal_name_full               CrystEngComm
_journal_page_first              5226
_journal_page_last               5240
_journal_paper_doi               10.1039/D1CE00705J
_journal_volume                  23
_journal_year                    2021
_chemical_formula_sum            'C40 H29 N3 O9 Zn2'
_chemical_formula_weight         826.40
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2020-03-19 deposited with the CCDC.	2021-07-06 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 107.575(7)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   25.237(6)
_cell_length_b                   19.307(4)
_cell_length_c                   15.041(3)
_cell_measurement_reflns_used    9924
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      26.3
_cell_measurement_theta_min      2.81
_cell_volume                     6987(3)
_computing_cell_refinement       'Bruker D8 Venture'
_computing_data_collection       'Bruker D8 Venture'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.966
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0605
_diffrn_reflns_av_unetI/netI     0.0482
_diffrn_reflns_Laue_measured_fraction_full 0.976
_diffrn_reflns_Laue_measured_fraction_max 0.966
_diffrn_reflns_limit_h_max       31
_diffrn_reflns_limit_h_min       -31
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            44085
_diffrn_reflns_point_group_measured_fraction_full 0.976
_diffrn_reflns_point_group_measured_fraction_max 0.966
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.582
_diffrn_reflns_theta_min         2.808
_exptl_absorpt_coefficient_mu    1.437
_exptl_absorpt_correction_T_max  0.9281
_exptl_absorpt_correction_T_min  0.743
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.571
_exptl_crystal_description       prism
_exptl_crystal_F_000             3376
_exptl_crystal_size_max          0.6
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.09
_refine_diff_density_max         1.704
_refine_diff_density_min         -0.922
_refine_diff_density_rms         0.155
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.090
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     505
_refine_ls_number_reflns         7044
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.090
_refine_ls_R_factor_all          0.1413
_refine_ls_R_factor_gt           0.0992
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0763P)²+225.8547P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2651
_refine_ls_wR_factor_ref         0.2911
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4765
_reflns_number_total             7044
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1ce00705j2.cif
_cod_data_source_block           shelx
_cod_depositor_comments          'Adding full bibliography for 7243241.cif.'
_cod_original_cell_volume        6987(2)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7243241
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.0503(4) 0.6790(5) 0.4343(8) 0.047(2) Uani 1 1 d . . . . .
C2 C 0.1027(5) 0.6962(5) 0.4938(10) 0.063(3) Uani 1 1 d . . . . .
H2 H 0.1131 0.7433 0.5068 0.075 Uiso 1 1 calc R U . . .
C3 C 0.1397(4) 0.6431(5) 0.5338(8) 0.052(3) Uani 1 1 d . . . . .
H3 H 0.1756 0.6548 0.5737 0.063 Uiso 1 1 calc R U . . .
C4 C 0.1254(4) 0.5724(5) 0.5169(7) 0.038(2) Uani 1 1 d . . . . .
C5 C 0.0720(3) 0.5568(4) 0.4582(6) 0.0322(19) Uani 1 1 d . . . . .
H5 H 0.0610 0.5098 0.4462 0.039 Uiso 1 1 calc R U . . .
C6 C 0.0352(4) 0.6091(4) 0.4175(7) 0.035(2) Uani 1 1 d . . . . .
C7 C -0.0203(3) 0.6088(5) 0.3522(7) 0.036(2) Uani 1 1 d . . . . .
C8 C -0.0561(3) 0.5569(5) 0.3090(6) 0.0333(19) Uani 1 1 d . . . . .
H8 H -0.0457 0.5098 0.3211 0.040 Uiso 1 1 calc R U . . .
C9 C -0.1086(3) 0.5741(5) 0.2465(7) 0.037(2) Uani 1 1 d . . . . .
C10 C -0.1215(4) 0.6438(5) 0.2275(8) 0.044(2) Uani 1 1 d . . . . .
H10 H -0.1557 0.6555 0.1824 0.053 Uiso 1 1 calc R U . . .
C11 C -0.0862(4) 0.6970(5) 0.2721(8) 0.051(3) Uani 1 1 d . . . . .
H11 H -0.0966 0.7442 0.2606 0.062 Uiso 1 1 calc R U . . .
C12 C -0.0352(4) 0.6786(5) 0.3338(7) 0.041(2) Uani 1 1 d . . . . .
C13 C 0.1905(3) 0.3999(5) 0.6002(6) 0.034(2) Uani 1 1 d . . . . .
H13 H 0.1782 0.3541 0.6064 0.041 Uiso 1 1 calc R U . . .
C14 C 0.1515(3) 0.4507(5) 0.5666(6) 0.035(2) Uani 1 1 d . . . . .
H14 H 0.1132 0.4390 0.5507 0.042 Uiso 1 1 calc R U . . .
C15 C 0.1663(3) 0.5182(5) 0.5551(6) 0.034(2) Uani 1 1 d . . . . .
C16 C 0.2242(4) 0.5303(5) 0.5807(8) 0.051(3) Uani 1 1 d . . . . .
H16 H 0.2379 0.5753 0.5745 0.061 Uiso 1 1 calc R U . . .
C17 C 0.2604(4) 0.4768(5) 0.6145(8) 0.049(3) Uani 1 1 d . . . . .
H17 H 0.2991 0.4866 0.6317 0.058 Uiso 1 1 calc R U . . .
C18 C -0.1683(4) 0.3995(5) 0.1671(8) 0.048(3) Uani 1 1 d . . . . .
H18 H -0.1549 0.3545 0.1597 0.058 Uiso 1 1 calc R U . . .
C19 C -0.1310(4) 0.4525(5) 0.1972(7) 0.045(2) Uani 1 1 d . . . . .
H19 H -0.0924 0.4425 0.2127 0.055 Uiso 1 1 calc R U . . .
C20 C -0.1471(3) 0.5189(5) 0.2057(6) 0.0320(19) Uani 1 1 d . . . . .
C21 C -0.2057(3) 0.5291(5) 0.1783(7) 0.039(2) Uani 1 1 d . . . . .
H21 H -0.2205 0.5742 0.1797 0.047 Uiso 1 1 calc R U . . .
C22 C -0.2406(4) 0.4742(5) 0.1501(7) 0.041(2) Uani 1 1 d . . . . .
H22 H -0.2795 0.4829 0.1311 0.050 Uiso 1 1 calc R U . . .
C23 C 0.4607(5) 0.3570(8) 0.8388(12) 0.083(5) Uani 1 1 d . . . . .
C24 C 0.4925(6) 0.4136(9) 0.865(2) 0.176(13) Uani 1 1 d . . . . .
H24 H 0.4762 0.4576 0.8456 0.211 Uiso 1 1 calc R U . . .
C25 C 0.5483(6) 0.4111(9) 0.919(2) 0.166(12) Uani 1 1 d . . . . .
H25 H 0.5684 0.4527 0.9392 0.199 Uiso 1 1 calc R U . . .
C26 C 0.5730(5) 0.3500(8) 0.9404(12) 0.090(5) Uani 1 1 d . . . . .
C27 C 0.5442(4) 0.2875(6) 0.9147(8) 0.055(3) Uani 1 1 d . . . . .
C28 C 0.4854(4) 0.2901(7) 0.8610(8) 0.056(3) Uani 1 1 d . . . . .
C29 C 0.4575(5) 0.2277(7) 0.8360(9) 0.067(3) Uani 1 1 d . . . . .
H29 H 0.4194 0.2288 0.8006 0.081 Uiso 1 1 calc R U . . .
C30 C 0.4820(7) 0.1661(9) 0.8597(13) 0.100(6) Uani 1 1 d . . . . .
H30 H 0.4615 0.1245 0.8420 0.121 Uiso 1 1 calc R U . . .
C31 C 0.5384(7) 0.1639(7) 0.9109(11) 0.093(5) Uani 1 1 d . . . . .
H31 H 0.5557 0.1202 0.9283 0.112 Uiso 1 1 calc R U . . .
C32 C 0.5692(5) 0.2224(7) 0.9366(8) 0.067(4) Uani 1 1 d . . . . .
H32 H 0.6077 0.2192 0.9693 0.080 Uiso 1 1 calc R U . . .
C33 C 0.3995(6) 0.3662(9) 0.7859(12) 0.090(5) Uani 1 1 d . . . . .
C34 C 0.6348(5) 0.3483(7) 0.9987(13) 0.076(4) Uani 1 1 d . . . . .
C35 C 0.2456(4) 0.2533(5) 0.9047(7) 0.042(2) Uani 1 1 d . . . . .
C36 C 0.2134(6) 0.2032(7) 0.9342(7) 0.066(4) Uani 1 1 d . . . . .
C37 C 0.2189(5) 0.1997(6) 1.0333(7) 0.053(3) Uani 1 1 d . . . . .
C38 C 0.1769(7) 0.1439(9) 1.0608(14) 0.034(4) Uani 0.5 1 d . . P . .
H38 H 0.1767 0.1411 1.1237 0.041 Uiso 0.5 1 calc R U P . .
C39 C 0.1401(8) 0.0987(10) 0.9916(16) 0.047(5) Uani 0.5 1 d . . P . .
H39 H 0.1217 0.0624 1.0133 0.057 Uiso 0.5 1 calc R U P . .
C40 C 0.1306(7) 0.1050(8) 0.9008(13) 0.036(4) Uani 0.5 1 d . . P . .
H40 H 0.1021 0.0793 0.8576 0.043 Uiso 0.5 1 calc R U P . .
C41 C 0.1655(7) 0.1525(9) 0.8701(12) 0.033(4) Uani 0.5 1 d . . P . .
H41 H 0.1599 0.1545 0.8048 0.039 Uiso 0.5 1 calc R U P . .
C42 C 0.2447(4) 0.2534(5) 0.8041(6) 0.037(2) Uani 1 1 d . . . . .
N1 N 0.0073(3) 0.7198(4) 0.3843(7) 0.053(2) Uani 1 1 d . . . . .
H101 H 0.0089 0.7623 0.3855 0.064 Uiso 1 1 d R U . . .
N2 N 0.2453(3) 0.4123(4) 0.6247(5) 0.0361(18) Uani 1 1 d . . . . .
N3 N -0.2238(3) 0.4097(4) 0.1475(5) 0.0352(17) Uani 1 1 d . . . . .
O1 O 0.2693(3) 0.2486(4) 0.5987(5) 0.0482(17) Uani 1 1 d . . . . .
H102 H 0.2889 0.2361 0.5576 0.072 Uiso 1 1 d R U . . .
O2 O 0.3730(3) 0.3194(7) 0.7453(7) 0.094(4) Uani 1 1 d . . . . .
O3 O 0.3796(4) 0.4256(7) 0.7824(12) 0.149(7) Uani 1 1 d . . . . .
O4 O 0.6719(4) 0.3621(7) 0.9537(7) 0.102(4) Uani 1 1 d . . . . .
O5 O 0.6471(4) 0.3413(9) 1.0774(9) 0.138(7) Uani 1 1 d . . . . .
O6 O 0.2549(3) 0.3075(4) 0.7701(5) 0.0468(17) Uani 1 1 d . . . . .
O7 O 0.2324(3) 0.1970(4) 0.7619(5) 0.0472(17) Uani 1 1 d . . . . .
O8 O 0.9997(7) 0.8673(6) 0.3473(15) 0.177(8) Uani 1 1 d . . . . .
O9 O 0.9026(7) 0.9349(9) 0.3147(18) 0.205(10) Uani 1 1 d . . . . .
Zn1 Zn 0.22819(4) 0.17637(6) 0.63204(8) 0.0425(3) Uani 1 1 d . . . . .
Zn2 Zn 0.29660(4) 0.33162(6) 0.67129(8) 0.0435(4) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C2 131.2(9) . . ?
N1 C1 C6 109.1(8) . . ?
C2 C1 C6 119.7(9) . . ?
C3 C2 C1 119.0(9) . . ?
C2 C3 C4 122.0(9) . . ?
C5 C4 C3 117.7(8) . . ?
C5 C4 C15 121.6(8) . . ?
C3 C4 C15 120.6(8) . . ?
C6 C5 C4 120.6(8) . . ?
C5 C6 C1 120.9(8) . . ?
C5 C6 C7 132.8(8) . . ?
C1 C6 C7 106.3(8) . . ?
C8 C7 C12 120.5(8) . . ?
C8 C7 C6 133.5(8) . . ?
C12 C7 C6 106.0(8) . . ?
C7 C8 C9 119.7(8) . . ?
C10 C9 C8 118.5(9) . . ?
C10 C9 C20 122.6(8) . . ?
C8 C9 C20 118.9(8) . . ?
C11 C10 C9 122.5(9) . . ?
C12 C11 C10 117.6(9) . . ?
N1 C12 C11 129.6(9) . . ?
N1 C12 C7 109.3(8) . . ?
C11 C12 C7 121.1(9) . . ?
N2 C13 C14 122.6(8) . . ?
C13 C14 C15 121.9(8) . . ?
C14 C15 C16 114.8(8) . . ?
C14 C15 C4 122.6(7) . . ?
C16 C15 C4 122.6(8) . . ?
C17 C16 C15 119.6(9) . . ?
N2 C17 C16 124.6(8) . . ?
N3 C18 C19 121.6(9) . . ?
C20 C19 C18 122.6(9) . . ?
C19 C20 C21 114.5(8) . . ?
C19 C20 C9 123.5(8) . . ?
C21 C20 C9 121.8(8) . . ?
C22 C21 C20 120.1(9) . . ?
N3 C22 C21 124.1(8) . . ?
C24 C23 C28 119.1(12) . . ?
C24 C23 C33 118.8(13) . . ?
C28 C23 C33 122.1(13) . . ?
C23 C24 C25 123.4(15) . . ?
C26 C25 C24 119.3(16) . . ?
C25 C26 C27 122.0(12) . . ?
C25 C26 C34 118.7(13) . . ?
C27 C26 C34 119.3(12) . . ?
C32 C27 C26 123.2(10) . . ?
C32 C27 C28 118.1(11) . . ?
C26 C27 C28 118.7(11) . . ?
C29 C28 C23 124.8(11) . . ?
C29 C28 C27 117.9(11) . . ?
C23 C28 C27 117.3(11) . . ?
C30 C29 C28 122.9(12) . . ?
C29 C30 C31 119.0(14) . . ?
C32 C31 C30 122.0(13) . . ?
C31 C32 C27 120.1(11) . . ?
O2 C33 O3 121.6(13) . . ?
O2 C33 C23 120.7(15) . . ?
O3 C33 C23 117.6(15) . . ?
O5 C34 O4 122.4(12) . . ?
O5 C34 C26 120.5(15) . . ?
O4 C34 C26 116.8(16) . . ?
C37 C35 C36 122.8(9) 7_557 . ?
C37 C35 C42 118.5(9) 7_557 . ?
C36 C35 C42 118.6(10) . . ?
C35 C36 C37 117.8(13) . . ?
C35 C36 C41 128.2(10) . . ?
C37 C36 C41 113.7(12) . . ?
C35 C37 C36 119.4(12) 7_557 . ?
C35 C37 C38 125.6(10) 7_557 . ?
C36 C37 C38 114.7(13) . . ?
C39 C38 C37 122.2(15) . . ?
C40 C39 C38 124.1(18) . . ?
C39 C40 C41 116.9(16) . . ?
C40 C41 C36 127.6(14) . . ?
O6 C42 O7 125.6(9) . . ?
O6 C42 C35 118.7(9) . . ?
O7 C42 C35 115.7(9) . . ?
C12 N1 C1 109.3(8) . . ?
C17 N2 C13 116.5(8) . . ?
C17 N2 Zn2 126.1(6) . . ?
C13 N2 Zn2 117.4(6) . . ?
C22 N3 C18 116.8(8) . . ?
C22 N3 Zn1 126.2(6) . 8_455 ?
C18 N3 Zn1 116.6(6) . 8_455 ?
Zn1 O1 Zn2 126.0(4) . . ?
C33 O2 Zn2 121.1(11) . . ?
C34 O4 Zn2 145.1(10) . 2_656 ?
C34 O5 Zn1 112.0(11) . 8_556 ?
C42 O6 Zn2 133.9(7) . . ?
C42 O7 Zn1 127.7(6) . . ?
O1 Zn1 O7 104.1(3) . . ?
O1 Zn1 O5 126.4(6) . 8_455 ?
O7 Zn1 O5 100.7(4) . 8_455 ?
O1 Zn1 N3 106.2(3) . 8_556 ?
O7 Zn1 N3 101.6(3) . 8_556 ?
O5 Zn1 N3 114.2(5) 8_455 8_556 ?
O2 Zn2 O1 110.3(4) . . ?
O2 Zn2 N2 136.3(4) . . ?
O1 Zn2 N2 111.1(3) . . ?
O2 Zn2 O6 100.9(4) . . ?
O1 Zn2 O6 92.6(3) . . ?
N2 Zn2 O6 90.6(3) . . ?
O2 Zn2 O4 88.4(4) . 2_656 ?
O1 Zn2 O4 84.5(4) . 2_656 ?
N2 Zn2 O4 82.2(4) . 2_656 ?
O6 Zn2 O4 170.6(3) . 2_656 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.367(13) . ?
C1 C2 1.395(15) . ?
C1 C6 1.405(13) . ?
C2 C3 1.394(15) . ?
C3 C4 1.415(13) . ?
C4 C5 1.404(11) . ?
C4 C15 1.460(12) . ?
C5 C6 1.385(12) . ?
C6 C7 1.447(12) . ?
C7 C8 1.374(12) . ?
C7 C12 1.405(12) . ?
C8 C9 1.413(11) . ?
C9 C10 1.394(13) . ?
C9 C20 1.447(13) . ?
C10 C11 1.392(15) . ?
C11 C12 1.387(13) . ?
C12 N1 1.365(12) . ?
C13 N2 1.340(10) . ?
C13 C14 1.374(12) . ?
C14 C15 1.382(13) . ?
C15 C16 1.412(12) . ?
C16 C17 1.372(14) . ?
C17 N2 1.325(12) . ?
C18 N3 1.356(12) . ?
C18 C19 1.371(13) . ?
C19 C20 1.364(13) . ?
C20 C21 1.423(12) . ?
C21 C22 1.361(14) . ?
C22 N3 1.321(12) . ?
C23 C24 1.34(2) . ?
C23 C28 1.430(18) . ?
C23 C33 1.519(16) . ?
C24 C25 1.40(2) . ?
C25 C26 1.33(2) . ?
C26 C27 1.401(18) . ?
C26 C34 1.541(16) . ?
C27 C32 1.401(16) . ?
C27 C28 1.460(14) . ?
C28 C29 1.388(17) . ?
C29 C30 1.34(2) . ?
C30 C31 1.40(2) . ?
C31 C32 1.360(19) . ?
C33 O2 1.180(18) . ?
C33 O3 1.247(19) . ?
C34 O5 1.138(19) . ?
C34 O4 1.339(19) . ?
C35 C37 1.411(16) 7_557 ?
C35 C36 1.417(17) . ?
C35 C42 1.507(13) . ?
C36 C37 1.456(14) . ?
C36 C41 1.63(2) . ?
C37 C35 1.411(16) 7_557 ?
C37 C38 1.65(2) . ?
C38 C39 1.46(3) . ?
C39 C40 1.32(3) . ?
C40 C41 1.44(3) . ?
C42 O6 1.224(11) . ?
C42 O7 1.251(12) . ?
N2 Zn2 2.011(7) . ?
N3 Zn1 2.028(8) 8_455 ?
O1 Zn1 1.894(7) . ?
O1 Zn2 1.945(7) . ?
O2 Zn2 1.928(8) . ?
O4 Zn2 2.326(11) 2_656 ?
O5 Zn1 1.990(10) 8_556 ?
O6 Zn2 2.116(7) . ?
O7 Zn1 1.965(7) . ?
Zn1 O5 1.990(10) 8_455 ?
Zn1 N3 2.028(8) 8_556 ?
Zn2 O4 2.326(11) 2_656 ?
