#------------------------------------------------------------------------------
#$Date: 2022-02-04 04:15:01 +0200 (Fri, 04 Feb 2022) $
#$Revision: 272543 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/43/7244336.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7244336
loop_
_publ_author_name
'Karmakar, Himadri'
'Anga, Srinivas'
'Panda, Tarun K.'
'Chandrasekhar, Vadapalli'
_publ_section_title
;
 Aluminium alkyl complexes supported by imino-phosphanamide ligand as
 precursors for catalytic guanylation reactions of carbodiimides
;
_journal_issue                   8
_journal_name_full               'RSC Advances'
_journal_page_first              4501
_journal_page_last               4509
_journal_paper_doi               10.1039/D2RA00242F
_journal_volume                  12
_journal_year                    2022
_chemical_formula_moiety         '0.25(C29 H43 N4 P), 0.13(C4 H8)'
_chemical_formula_sum            'C7.75 H11.75 N P0.25'
_chemical_formula_weight         126.67
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_audit_creation_date             2021-09-16
_audit_creation_method
;
Olex2 1.3-ac4
(compiled 2019.04.23 svn.r3594 for Rigaku Oxford Diffraction, GUI svn.r5739)
;
_audit_update_record
;
2021-11-24 deposited with the CCDC.	2022-01-17 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 100.693(5)
_cell_angle_gamma                90
_cell_formula_units_Z            16
_cell_length_a                   10.4218(5)
_cell_length_b                   14.9253(7)
_cell_length_c                   20.5378(9)
_cell_measurement_reflns_used    8453
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.3390
_cell_measurement_theta_min      2.9100
_cell_volume                     3139.2(3)
_computing_cell_refinement       'CrysAlisPro 1.171.39.29d (Rigaku OD, 2017)'
_computing_data_collection       'CrysAlisPro 1.171.39.29d (Rigaku OD, 2017)'
_computing_data_reduction        'CrysAlisPro 1.171.39.29d (Rigaku OD, 2017)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector                 'CCD plate'
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.883
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     53.00  91.00   0.50   64.79    --    7.10  77.00-150.00   76
  2  ω    -11.00  21.00   0.50   64.79    --   -7.50 -57.00-180.00   64
  3  ω    -36.00  20.00   0.50   64.79    --   -7.50  57.00   0.00  112
  4  ω    -64.00 -38.00   0.50   64.79    --   -7.50 -57.00-180.00   52
  5  ω    -54.00   8.00   0.50   64.79    --   -7.50 -82.00-180.00  124
  6  ω    -95.00  26.00   0.50   64.79    --   -7.50  19.00 150.00  242
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB AFC12 (RINC): Kappa single'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0114925000
_diffrn_orient_matrix_UB_12      -0.0113422000
_diffrn_orient_matrix_UB_13      0.0319560000
_diffrn_orient_matrix_UB_21      -0.0044820000
_diffrn_orient_matrix_UB_22      0.0461409000
_diffrn_orient_matrix_UB_23      0.0075385000
_diffrn_orient_matrix_UB_31      -0.0681720000
_diffrn_orient_matrix_UB_32      -0.0010694000
_diffrn_orient_matrix_UB_33      -0.0125114000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0552
_diffrn_reflns_av_unetI/netI     0.0504
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.883
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            28830
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.883
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.981
_diffrn_reflns_theta_min         2.729
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_source_type              'Enhance (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    0.111
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.71528
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.29d (Rigaku Oxford Diffraction, 2017)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.072
_exptl_crystal_description       block
_exptl_crystal_F_000             1104
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.089
_refine_diff_density_min         -0.390
_refine_diff_density_rms         0.082
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     338
_refine_ls_number_reflns         7361
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.045
_refine_ls_R_factor_all          0.1174
_refine_ls_R_factor_gt           0.0899
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1605P)²+1.7995P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2664
_refine_ls_wR_factor_ref         0.2856
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5144
_reflns_number_total             7361
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2ra00242f2.cif
_cod_data_source_block           1c
_cod_database_code               7244336
_shelx_shelxl_version_number     2018/3
_chemical_oxdiff_formula         CHNP
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_reflns_odcompleteness_completeness 99.64
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All N(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C7(H7), C10(H10)
2.b Secondary CH2 refined with riding coordinates:
 C00Z(H00A,H00B), C010(H01A,H01B)
2.c Aromatic/amide H refined with riding coordinates:
 C3(H3), C5(H5), C14(H14), C4(H4), C15(H15), C29(H29), C25(H25), C27(H27),
 C28(H28), C26(H26)
2.d Idealised Me refined as rotating group:
 C19(H19A,H19B,H19C), C17(H17A,H17B,H17C), C21(H21A,H21B,H21C), C22(H22A,H22B,
 H22C), C18(H18A,H18B,H18C), C9(H9A,H9B,H9C), C23(H23A,H23B,H23C), C8(H8A,H8B,
 H8C), C12(H12A,H12B,H12C), C11(H11A,H11B,H11C)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.662
_oxdiff_exptl_absorpt_empirical_full_min 0.667
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P 0.70303(7) 0.32640(5) 0.30211(3) 0.0434(2) Uani 1 1 d . . . . .
N4 N 0.4194(2) 0.33603(16) 0.17570(11) 0.0446(5) Uani 1 1 d . . . . .
N3 N 0.4381(2) 0.18941(16) 0.18375(12) 0.0470(6) Uani 1 1 d . . . . .
N2 N 0.5695(2) 0.27059(17) 0.26971(11) 0.0458(6) Uani 1 1 d . . . . .
N1 N 0.8133(2) 0.24155(17) 0.32851(13) 0.0480(6) Uani 1 1 d . . . . .
H1 H 0.797(3) 0.208(2) 0.3695(17) 0.058 Uiso 1 1 d R . . . .
C2 C 0.9892(3) 0.2555(2) 0.26536(15) 0.0497(7) Uani 1 1 d . . . . .
C1 C 0.9483(3) 0.25104(18) 0.32706(14) 0.0438(6) Uani 1 1 d . . . . .
C13 C 0.4875(2) 0.26826(18) 0.21420(13) 0.0404(6) Uani 1 1 d . . . . .
C6 C 1.0399(3) 0.2533(2) 0.38609(16) 0.0512(7) Uani 1 1 d . . . . .
C7 C 0.8946(3) 0.2518(2) 0.19967(15) 0.0540(7) Uani 1 1 d . . . . .
H7 H 0.806698 0.243081 0.209210 0.065 Uiso 1 1 calc R . . . .
C3 C 1.1219(3) 0.2632(3) 0.26513(19) 0.0638(9) Uani 1 1 d . . . . .
H3 H 1.149941 0.267474 0.224825 0.077 Uiso 1 1 calc R . . . .
C24 C 0.6627(3) 0.3568(2) 0.38319(14) 0.0484(7) Uani 1 1 d . . . . .
C5 C 1.1726(3) 0.2597(3) 0.38236(18) 0.0651(9) Uani 1 1 d . . . . .
H5 H 1.234685 0.260572 0.421250 0.078 Uiso 1 1 calc R . . . .
C14 C 0.3320(3) 0.2975(2) 0.12426(15) 0.0559(8) Uani 1 1 d . . . . .
H14 H 0.274945 0.328295 0.091698 0.067 Uiso 1 1 calc R . . . .
C20 C 0.4783(3) 0.0974(2) 0.20825(16) 0.0553(7) Uani 1 1 d . . . . .
C16 C 0.4305(3) 0.4349(2) 0.18755(16) 0.0550(7) Uani 1 1 d . . . . .
C4 C 1.2126(3) 0.2646(3) 0.3228(2) 0.0736(11) Uani 1 1 d . . . . .
H4 H 1.300997 0.268966 0.321274 0.088 Uiso 1 1 calc R . . . .
C15 C 0.3438(3) 0.2089(2) 0.12941(15) 0.0566(8) Uani 1 1 d . . . . .
H15 H 0.296338 0.167212 0.101025 0.068 Uiso 1 1 calc R . . . .
C10 C 0.9994(4) 0.2474(2) 0.45347(16) 0.0623(9) Uani 1 1 d . . . . .
H10 H 0.908054 0.266666 0.447541 0.075 Uiso 1 1 calc R . . . .
C19 C 0.4073(4) 0.4546(3) 0.25710(19) 0.0736(10) Uani 1 1 d . . . . .
H19A H 0.327221 0.426921 0.263222 0.110 Uiso 1 1 calc GR . . . .
H19B H 0.401508 0.518211 0.262936 0.110 Uiso 1 1 calc GR . . . .
H19C H 0.478404 0.431175 0.289032 0.110 Uiso 1 1 calc GR . . . .
C17 C 0.5614(4) 0.4685(3) 0.1753(2) 0.0762(11) Uani 1 1 d . . . . .
H17A H 0.630464 0.437808 0.204181 0.114 Uiso 1 1 calc GR . . . .
H17B H 0.568281 0.531695 0.183845 0.114 Uiso 1 1 calc GR . . . .
H17C H 0.568235 0.457211 0.130022 0.114 Uiso 1 1 calc GR . . . .
C21 C 0.6237(3) 0.0859(2) 0.2112(2) 0.0721(10) Uani 1 1 d . . . . .
H21A H 0.644222 0.098423 0.168420 0.108 Uiso 1 1 calc GR . . . .
H21B H 0.648428 0.025531 0.223734 0.108 Uiso 1 1 calc GR . . . .
H21C H 0.670468 0.126667 0.243237 0.108 Uiso 1 1 calc GR . . . .
C29 C 0.7253(4) 0.4292(3) 0.41703(18) 0.0757(11) Uani 1 1 d . . . . .
H29 H 0.787028 0.461080 0.399015 0.091 Uiso 1 1 calc R . . . .
C25 C 0.5726(4) 0.3120(3) 0.41211(19) 0.0778(12) Uani 1 1 d . . . . .
H25 H 0.528033 0.263347 0.390322 0.093 Uiso 1 1 calc R . . . .
C22 C 0.4412(4) 0.0840(3) 0.2758(2) 0.0772(11) Uani 1 1 d . . . . .
H22A H 0.490467 0.124532 0.307134 0.116 Uiso 1 1 calc GR . . . .
H22B H 0.460069 0.023411 0.290256 0.116 Uiso 1 1 calc GR . . . .
H22C H 0.349628 0.095472 0.272692 0.116 Uiso 1 1 calc GR . . . .
C18 C 0.3241(4) 0.4822(3) 0.1379(2) 0.0774(11) Uani 1 1 d . . . . .
H18A H 0.338019 0.471225 0.093654 0.116 Uiso 1 1 calc GR . . . .
H18B H 0.327518 0.545435 0.146429 0.116 Uiso 1 1 calc GR . . . .
H18C H 0.240018 0.459448 0.142438 0.116 Uiso 1 1 calc GR . . . .
C27 C 0.6075(4) 0.4102(3) 0.50572(19) 0.0819(12) Uani 1 1 d . . . . .
H27 H 0.587997 0.428488 0.546064 0.098 Uiso 1 1 calc R . . . .
C28 C 0.6965(6) 0.4549(3) 0.4783(2) 0.0924(14) Uani 1 1 d . . . . .
H28 H 0.739646 0.503722 0.500506 0.111 Uiso 1 1 calc R . . . .
C9 C 0.9244(5) 0.1724(3) 0.1576(2) 0.0832(12) Uani 1 1 d . . . . .
H9A H 1.008002 0.181069 0.145320 0.125 Uiso 1 1 calc GR . . . .
H9B H 0.858248 0.168385 0.118353 0.125 Uiso 1 1 calc GR . . . .
H9C H 0.925478 0.118119 0.182720 0.125 Uiso 1 1 calc GR . . . .
C23 C 0.4060(5) 0.0288(3) 0.1606(2) 0.0859(12) Uani 1 1 d . . . . .
H23A H 0.313630 0.037245 0.156932 0.129 Uiso 1 1 calc GR . . . .
H23B H 0.429331 -0.030399 0.176852 0.129 Uiso 1 1 calc GR . . . .
H23C H 0.429307 0.036218 0.117835 0.129 Uiso 1 1 calc GR . . . .
C8 C 0.8944(5) 0.3387(3) 0.1619(2) 0.0862(12) Uani 1 1 d . . . . .
H8A H 0.878689 0.387752 0.189650 0.129 Uiso 1 1 calc GR . . . .
H8B H 0.826828 0.337000 0.123144 0.129 Uiso 1 1 calc GR . . . .
H8C H 0.977490 0.346654 0.148879 0.129 Uiso 1 1 calc GR . . . .
C26 C 0.5469(4) 0.3381(4) 0.4735(2) 0.0958(16) Uani 1 1 d . . . . .
H26 H 0.487372 0.305689 0.492679 0.115 Uiso 1 1 calc R . . . .
C12 C 1.0049(7) 0.1519(4) 0.4772(3) 0.137(3) Uani 1 1 d . . . . .
H12A H 0.953428 0.114833 0.444052 0.206 Uiso 1 1 calc GR . . . .
H12B H 0.970892 0.148380 0.517503 0.206 Uiso 1 1 calc GR . . . .
H12C H 1.093772 0.131520 0.485232 0.206 Uiso 1 1 calc GR . . . .
C11 C 1.0775(6) 0.3078(6) 0.5050(3) 0.154(3) Uani 1 1 d . . . . .
H11A H 1.168202 0.292000 0.510905 0.231 Uiso 1 1 calc GR . . . .
H11B H 1.047691 0.300869 0.546185 0.231 Uiso 1 1 calc GR . . . .
H11C H 1.066248 0.368937 0.490540 0.231 Uiso 1 1 calc GR . . . .
C00Z C 0.1003(9) 0.5370(10) -0.0123(5) 0.227(7) Uani 1 1 d . . . . .
H00A H 0.186074 0.532674 0.015534 0.273 Uiso 1 1 calc R . . . .
H00B H 0.102686 0.573748 -0.051014 0.273 Uiso 1 1 calc R . . . .
C010 C -0.0233(18) 0.5665(7) 0.0306(4) 0.267(8) Uani 1 1 d . . . . .
H01A H -0.075486 0.616914 0.011202 0.320 Uiso 1 1 calc R . . . .
H01B H 0.007736 0.575924 0.077616 0.320 Uiso 1 1 calc R . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 P1 N1 102.63(12) . . ?
N2 P1 C24 99.86(13) . . ?
N1 P1 C24 98.45(13) . . ?
C13 N4 C16 127.4(2) . . ?
C14 N4 C13 108.9(2) . . ?
C14 N4 C16 123.6(2) . . ?
C13 N3 C20 124.8(2) . . ?
C15 N3 C13 109.7(2) . . ?
C15 N3 C20 125.5(3) . . ?
C13 N2 P1 137.6(2) . . ?
C1 N1 P1 121.6(2) . . ?
C1 C2 C7 122.8(3) . . ?
C3 C2 C1 118.3(3) . . ?
C3 C2 C7 118.9(3) . . ?
C2 C1 N1 119.3(3) . . ?
C6 C1 N1 120.3(3) . . ?
C6 C1 C2 120.4(3) . . ?
N3 C13 N4 104.6(2) . . ?
N2 C13 N4 131.6(3) . . ?
N2 C13 N3 123.4(2) . . ?
C1 C6 C5 118.4(3) . . ?
C1 C6 C10 121.8(3) . . ?
C5 C6 C10 119.8(3) . . ?
C2 C7 C9 111.3(3) . . ?
C8 C7 C2 111.3(3) . . ?
C8 C7 C9 110.8(3) . . ?
C4 C3 C2 121.7(3) . . ?
C29 C24 P1 118.7(3) . . ?
C25 C24 P1 123.9(3) . . ?
C25 C24 C29 117.4(3) . . ?
C4 C5 C6 121.3(3) . . ?
C15 C14 N4 108.3(3) . . ?
N3 C20 C21 109.4(3) . . ?
N3 C20 C22 108.9(3) . . ?
N3 C20 C23 109.1(3) . . ?
C21 C20 C22 111.8(3) . . ?
C21 C20 C23 108.9(3) . . ?
C23 C20 C22 108.7(3) . . ?
N4 C16 C19 108.8(3) . . ?
N4 C16 C17 110.1(3) . . ?
N4 C16 C18 108.7(3) . . ?
C19 C16 C18 108.3(3) . . ?
C17 C16 C19 113.4(3) . . ?
C17 C16 C18 107.4(3) . . ?
C5 C4 C3 119.8(3) . . ?
C14 C15 N3 108.5(3) . . ?
C12 C10 C6 110.5(3) . . ?
C12 C10 C11 110.9(5) . . ?
C11 C10 C6 113.4(4) . . ?
C24 C29 C28 120.4(4) . . ?
C24 C25 C26 121.1(4) . . ?
C28 C27 C26 118.9(4) . . ?
C27 C28 C29 121.3(4) . . ?
C27 C26 C25 120.9(4) . . ?
C010 C00Z C010 88.8(6) . 3_565 ?
C00Z C010 C00Z 91.2(6) . 3_565 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 N2 1.652(2) . ?
P1 N1 1.729(2) . ?
P1 C24 1.848(3) . ?
N4 C13 1.394(3) . ?
N4 C14 1.385(4) . ?
N4 C16 1.496(4) . ?
N3 C13 1.386(4) . ?
N3 C20 1.496(4) . ?
N3 C15 1.374(4) . ?
N2 C13 1.292(3) . ?
N1 C1 1.420(4) . ?
C2 C1 1.411(4) . ?
C2 C7 1.517(4) . ?
C2 C3 1.388(5) . ?
C1 C6 1.397(4) . ?
C6 C5 1.402(5) . ?
C6 C10 1.523(5) . ?
C7 C9 1.532(5) . ?
C7 C8 1.511(5) . ?
C3 C4 1.371(5) . ?
C24 C29 1.381(5) . ?
C24 C25 1.375(5) . ?
C5 C4 1.366(5) . ?
C14 C15 1.331(5) . ?
C20 C21 1.514(5) . ?
C20 C22 1.521(5) . ?
C20 C23 1.516(5) . ?
C16 C19 1.521(5) . ?
C16 C17 1.517(5) . ?
C16 C18 1.533(5) . ?
C10 C12 1.504(7) . ?
C10 C11 1.508(6) . ?
C29 C28 1.400(6) . ?
C25 C26 1.392(6) . ?
C27 C28 1.348(7) . ?
C27 C26 1.356(7) . ?
C00Z C010 1.747(15) . ?
C00Z C010 1.748(13) 3_565 ?
