#------------------------------------------------------------------------------
#$Date: 2022-06-22 01:34:22 +0300 (Wed, 22 Jun 2022) $
#$Revision: 276137 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/50/7245093.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7245093
loop_
_publ_author_name
'Araškov, Jovana B.'
'Višnjevac, Aleksandar'
'Popović, Jasminka'
'Blagojević, Vladimir'
'Fernandes, Henrique S.'
'Sousa, Sérgio F.'
'Novaković, Irena'
'Padrón, José M.'
'Holló, Berta Barta'
'Monge, Miguel'
'Rodríguez-Castillo, María'
'López-de-Luzuriaga, José M.'
'Filipović, Nenad R.'
'Todorović, Tamara R.'
_publ_section_title
;
 Zn(ii) complexes with thiazolyl--hydrazones: structure, intermolecular
 interactions, photophysical properties, computational study and
 anticancer activity
;
_journal_name_full               CrystEngComm
_journal_paper_doi               10.1039/D2CE00443G
_journal_year                    2022
_chemical_formula_moiety         'C30  H24  N8  S2  Zn1, 2(N1 O3), O1'
_chemical_formula_sum            'C30 H24 N10 O7 S2 Zn'
_chemical_formula_weight         766.08
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   direct
_audit_creation_date             2017-02-22T14:56:17-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_audit_update_record
;
2021-12-26 deposited with the CCDC.	2022-06-06 downloaded from the CCDC.
;
_cell_angle_alpha                108.799(4)
_cell_angle_beta                 94.313(3)
_cell_angle_gamma                115.023(4)
_cell_formula_units_Z            2
_cell_length_a                   10.9908(5)
_cell_length_b                   12.5765(5)
_cell_length_c                   14.2015(6)
_cell_measurement_reflns_used    6561
_cell_measurement_temperature    110
_cell_measurement_theta_max      72.9972
_cell_measurement_theta_min      3.3894
_cell_measurement_wavelength     1.54184
_cell_volume                     1631.88(15)
_computing_cell_refinement
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.36.20 (release 27-06-2012 CrysAlis171 .NET)
        (compiled Jul 11 2012,15:38:31)
;
_computing_data_collection
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.36.20 (release 27-06-2012 CrysAlis171 .NET)
        (compiled Jul 11 2012,15:38:31)
;
_computing_data_reduction
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.36.20 (release 27-06-2012 CrysAlis171 .NET)
        (compiled Jul 11 2012,15:38:31)
;
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 2012)'
_computing_publication_material  'WinGX publication routines (Farrugia, 2012)'
_computing_structure_refinement  'SHELXL-2016/4 (Sheldrick, 2016)'
_computing_structure_solution    'SIR-2014 (Burla et al., 2014)'
_diffrn_ambient_temperature      110
_diffrn_detector_area_resol_mean 10.4323
_diffrn_measured_fraction_theta_full 0.972
_diffrn_measured_fraction_theta_max 0.936
_diffrn_measurement_device_type  'Xcalibur, Ruby, Nova'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.1169816
_diffrn_orient_matrix_UB_12      -0.1387565
_diffrn_orient_matrix_UB_13      -0.0403492
_diffrn_orient_matrix_UB_21      0.1077127
_diffrn_orient_matrix_UB_22      -0.0481229
_diffrn_orient_matrix_UB_23      -0.014731
_diffrn_orient_matrix_UB_31      0.0138003
_diffrn_orient_matrix_UB_32      0.0045418
_diffrn_orient_matrix_UB_33      0.1101646
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54179
_diffrn_reflns_av_R_equivalents  0.0306
_diffrn_reflns_av_unetI/netI     0.0508
_diffrn_reflns_Laue_measured_fraction_full 0.972
_diffrn_reflns_Laue_measured_fraction_max 0.936
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            10699
_diffrn_reflns_point_group_measured_fraction_full 0.972
_diffrn_reflns_point_group_measured_fraction_max 0.936
_diffrn_reflns_theta_full        67.68
_diffrn_reflns_theta_max         73.147
_diffrn_reflns_theta_min         3.392
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.794
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.63256
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.36.20 (release 27-06-2012 CrysAlis171 .NET)
        (compiled Jul 11 2012,15:38:31)
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.559
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       stick
_exptl_crystal_F_000             784
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.98
_refine_diff_density_min         -0.622
_refine_diff_density_rms         0.102
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.095
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     451
_refine_ls_number_reflns         6127
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.094
_refine_ls_R_factor_all          0.0585
_refine_ls_R_factor_gt           0.0548
_refine_ls_shift/su_max          0
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0869P)²+2.8074P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.154
_refine_ls_wR_factor_ref         0.1585
_reflns_Friedel_coverage         0
_reflns_number_gt                5610
_reflns_number_total             6127
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2ce00443g2.cif
_cod_data_source_block           jat1cn
_cod_original_cell_volume        1631.88(13)
_cod_original_formula_sum        'C30 H24 N10 O7 S2 Zn1'
_cod_database_code               7245093
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Zn1 Zn 0.02568(4) 0.38372(4) 0.72675(3) 0.01797(15) Uani 1 1 d . . . . .
S1 S 0.31065(9) 0.77508(8) 0.73993(7) 0.0296(2) Uani 1 1 d . . . . .
S2 S -0.30767(8) 0.47037(7) 0.84275(6) 0.02331(19) Uani 1 1 d . . . . .
N1 N 0.0628(3) 0.2684(2) 0.8033(2) 0.0190(5) Uani 1 1 d . . . . .
N2 N 0.2443(3) 0.4627(3) 0.7743(2) 0.0239(6) Uani 1 1 d . . . . .
N3 N 0.3208(3) 0.5695(3) 0.7578(3) 0.0297(7) Uani 1 1 d . . . . .
H3A H 0.408981 0.602336 0.765072 0.036 Uiso 1 1 calc R U . . .
N4 N 0.1073(3) 0.5507(3) 0.6926(2) 0.0236(6) Uani 1 1 d . . . . .
N5 N 0.0096(3) 0.2437(3) 0.5762(2) 0.0276(6) Uani 1 1 d . . . . .
N6 N -0.1871(3) 0.2485(2) 0.6655(2) 0.0212(5) Uani 1 1 d . . . . .
N7 N -0.2746(3) 0.2738(3) 0.7191(2) 0.0242(6) Uani 1 1 d . . . . .
H7A H -0.360148 0.219295 0.707558 0.029 Uiso 1 1 calc R U . . .
N8 N -0.0784(3) 0.4641(2) 0.8272(2) 0.0176(5) Uani 1 1 d . . . . .
C1 C 0.1966(3) 0.2939(3) 0.8249(3) 0.0223(6) Uani 1 1 d . . . . .
C2 C 0.2378(4) 0.2199(3) 0.8593(3) 0.0284(7) Uani 1 1 d . . . . .
H2 H 0.330655 0.239929 0.873818 0.034 Uiso 1 1 calc R U . . .
C3 C 0.1370(4) 0.1150(3) 0.8714(3) 0.0274(7) Uani 1 1 d . . . . .
H3 H 0.161493 0.063049 0.893393 0.033 Uiso 1 1 calc R U . . .
C4 C 0.0007(4) 0.0890(3) 0.8507(2) 0.0248(7) Uani 1 1 d . . . . .
H4 H -0.067987 0.019844 0.859088 0.03 Uiso 1 1 calc R U . . .
C5 C -0.0327(3) 0.1683(3) 0.8167(2) 0.0222(6) Uani 1 1 d . . . . .
H5 H -0.124778 0.150876 0.803027 0.027 Uiso 1 1 calc R U . . .
C6 C 0.2969(3) 0.4061(3) 0.8101(3) 0.0270(7) Uani 1 1 d . . . . .
H6 H 0.391775 0.433991 0.825662 0.032 Uiso 1 1 calc R U . . .
C7 C 0.2420(4) 0.6197(3) 0.7281(3) 0.0271(7) Uani 1 1 d . . . . .
C8 C 0.1455(4) 0.7461(3) 0.6934(3) 0.0298(8) Uani 1 1 d . . . . .
H8 H 0.124194 0.806412 0.683305 0.036 Uiso 1 1 calc R U . . .
C9 C 0.0502(4) 0.6239(3) 0.6731(3) 0.0263(7) Uani 1 1 d . . . . .
C10 C -0.1012(4) 0.5648(3) 0.6326(3) 0.0273(7) Uani 1 1 d . . . . .
C11 C -0.1745(4) 0.4392(4) 0.5595(3) 0.0318(8) Uani 1 1 d . . . . .
H11 H -0.127375 0.393558 0.535885 0.038 Uiso 1 1 calc R U . . .
C12 C -0.3160(5) 0.3827(4) 0.5224(3) 0.0390(9) Uani 1 1 d . . . . .
H12 H -0.364245 0.298959 0.474411 0.047 Uiso 1 1 calc R U . . .
C13 C -0.3865(5) 0.4518(5) 0.5572(3) 0.0431(10) Uani 1 1 d . . . . .
H13 H -0.481948 0.41389 0.532246 0.052 Uiso 1 1 calc R U . . .
C14 C -0.3156(5) 0.5754(4) 0.6281(3) 0.0396(9) Uani 1 1 d . . . . .
H14 H -0.36317 0.621028 0.650487 0.048 Uiso 1 1 calc R U . . .
C15 C -0.1733(4) 0.6327(4) 0.6666(3) 0.0332(8) Uani 1 1 d . . . . .
H15 H -0.126013 0.716291 0.714923 0.04 Uiso 1 1 calc R U . . .
C16 C -0.1179(4) 0.1398(3) 0.5347(3) 0.0294(8) Uani 1 1 d . . . . .
C17 C -0.1428(5) 0.0347(4) 0.4478(3) 0.0415(10) Uani 1 1 d . . . . .
H17 H -0.230409 -0.035958 0.421295 0.05 Uiso 1 1 calc R U . . .
C18 C -0.0378(6) 0.0360(5) 0.4018(3) 0.0510(13) Uani 1 1 d . . . . .
H18 H -0.052881 -0.034295 0.344466 0.061 Uiso 1 1 calc R U . . .
C19 C 0.0904(7) 0.1422(5) 0.4411(4) 0.0542(15) Uani 1 1 d . . . . .
H19 H 0.162302 0.145716 0.409409 0.065 Uiso 1 1 calc R U . . .
C20 C 0.1111(5) 0.2452(4) 0.5295(3) 0.0382(9) Uani 1 1 d . . . . .
H20 H 0.198108 0.316686 0.55655 0.046 Uiso 1 1 calc R U . . .
C21 C -0.2261(4) 0.1465(3) 0.5861(3) 0.0275(7) Uani 1 1 d . . . . .
H21 H -0.317033 0.081077 0.562681 0.033 Uiso 1 1 calc R U . . .
C22 C -0.2137(3) 0.3952(3) 0.7941(2) 0.0192(6) Uani 1 1 d . . . . .
C23 C -0.1538(3) 0.6055(3) 0.9135(3) 0.0222(6) Uani 1 1 d . . . . .
H23 H -0.147019 0.681572 0.958132 0.027 Uiso 1 1 calc R U . . .
C24 C -0.0438(3) 0.5863(3) 0.8955(2) 0.0188(6) Uani 1 1 d . . . . .
C25 C 0.1028(3) 0.6832(3) 0.9429(2) 0.0197(6) Uani 1 1 d . . . . .
C26 C 0.2008(3) 0.6506(3) 0.9738(3) 0.0239(7) Uani 1 1 d . . . . .
H26 H 0.174666 0.566099 0.963009 0.029 Uiso 1 1 calc R U . . .
C27 C 0.3376(4) 0.7440(4) 1.0207(3) 0.0312(8) Uani 1 1 d . . . . .
H27 H 0.403011 0.721601 1.040268 0.037 Uiso 1 1 calc R U . . .
C28 C 0.3768(4) 0.8705(3) 1.0385(3) 0.0321(8) Uani 1 1 d . . . . .
H28 H 0.468053 0.932896 1.07053 0.038 Uiso 1 1 calc R U . . .
C29 C 0.2799(4) 0.9038(3) 1.0084(3) 0.0307(8) Uani 1 1 d . . . . .
H29 H 0.306158 0.988557 1.020334 0.037 Uiso 1 1 calc R U . . .
C30 C 0.1432(4) 0.8105(3) 0.9603(3) 0.0249(7) Uani 1 1 d . . . . .
H30 H 0.078528 0.833107 0.939703 0.03 Uiso 1 1 calc R U . . .
O1 O 0.5897(3) 0.7780(3) 0.8014(2) 0.0397(6) Uani 1 1 d . . . . .
O2 O 0.5995(3) 0.6756(2) 0.8956(2) 0.0329(6) Uani 1 1 d . . . . .
O3 O 0.7881(3) 0.8302(2) 0.8939(2) 0.0327(6) Uani 1 1 d . . . . .
N9 N 0.6611(3) 0.7623(3) 0.8643(2) 0.0263(6) Uani 1 1 d . . . . .
O4 O 0.3514(3) 0.0280(3) 0.7691(3) 0.0450(7) Uani 1 1 d . . . . .
O5 O 0.4647(3) 0.0125(3) 0.6516(3) 0.0491(8) Uani 1 1 d . . . . .
O6 O 0.4518(3) 0.1866(3) 0.7242(3) 0.0482(8) Uani 1 1 d . . . . .
N10 N 0.4214(3) 0.0721(3) 0.7178(3) 0.0372(8) Uani 1 1 d . . . . .
O7 O 0.3392(3) 0.0807(4) 0.3237(3) 0.0562(9) Uani 1 1 d . U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn -1.5491 0.6778 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Zn1 N5 89.39(10) . . ?
N2 Zn1 N1 73.63(10) . . ?
N2 Zn1 N4 75.45(11) . . ?
N2 Zn1 N5 93.52(11) . . ?
N2 Zn1 N8 118.69(11) . . ?
N4 Zn1 N1 148.53(11) . . ?
N4 Zn1 N5 98.27(11) . . ?
N4 Zn1 N8 88.84(10) . . ?
N6 Zn1 N1 92.06(10) . . ?
N6 Zn1 N2 160.97(10) . . ?
N6 Zn1 N4 119.40(11) . . ?
N6 Zn1 N5 73.44(11) . . ?
N6 Zn1 N8 75.66(10) . . ?
N8 Zn1 N1 100.82(9) . . ?
N8 Zn1 N5 147.74(11) . . ?
C7 S1 C8 88.46(17) . . ?
C22 S2 C23 88.55(15) . . ?
C1 N1 Zn1 114.0(2) . . ?
C5 N1 Zn1 127.1(2) . . ?
C5 N1 C1 118.2(3) . . ?
N3 N2 Zn1 115.9(2) . . ?
C6 N2 Zn1 120.4(2) . . ?
C6 N2 N3 123.5(3) . . ?
N2 N3 C7 112.9(3) . . ?
C7 N4 Zn1 112.6(2) . . ?
C7 N4 C9 110.2(3) . . ?
C9 N4 Zn1 133.2(2) . . ?
C16 N5 Zn1 113.3(2) . . ?
C20 N5 Zn1 127.9(3) . . ?
C20 N5 C16 118.5(3) . . ?
N7 N6 Zn1 115.9(2) . . ?
C21 N6 Zn1 120.7(2) . . ?
C21 N6 N7 123.3(3) . . ?
N6 N7 C22 113.4(2) . . ?
C22 N8 Zn1 111.5(2) . . ?
C22 N8 C24 109.9(3) . . ?
C24 N8 Zn1 134.4(2) . . ?
N1 C1 C2 122.7(3) . . ?
N1 C1 C6 115.7(3) . . ?
C2 C1 C6 121.7(3) . . ?
C1 C2 C3 118.5(3) . . ?
C4 C3 C2 119.4(3) . . ?
C3 C4 C5 118.8(3) . . ?
N1 C5 C4 122.5(3) . . ?
N2 C6 C1 115.2(3) . . ?
N3 C7 S1 123.1(3) . . ?
N4 C7 S1 116.0(3) . . ?
N4 C7 N3 120.9(3) . . ?
C9 C8 S1 111.4(3) . . ?
N4 C9 C10 119.4(3) . . ?
C8 C9 N4 113.8(3) . . ?
C8 C9 C10 126.8(3) . . ?
C11 C10 C9 120.1(3) . . ?
C15 C10 C9 120.8(3) . . ?
C15 C10 C11 119.0(4) . . ?
C12 C11 C10 120.6(4) . . ?
C11 C12 C13 119.7(4) . . ?
C14 C13 C12 120.3(4) . . ?
C13 C14 C15 120.4(4) . . ?
C14 C15 C10 120.0(4) . . ?
N5 C16 C17 121.5(4) . . ?
N5 C16 C21 115.9(3) . . ?
C17 C16 C21 122.6(4) . . ?
C18 C17 C16 119.6(5) . . ?
C17 C18 C19 119.4(4) . . ?
C18 C19 C20 119.0(4) . . ?
N5 C20 C19 122.0(5) . . ?
N6 C21 C16 115.3(3) . . ?
N7 C22 S2 122.5(2) . . ?
N8 C22 S2 115.9(2) . . ?
N8 C22 N7 121.4(3) . . ?
C24 C23 S2 111.1(2) . . ?
N8 C24 C25 120.6(3) . . ?
C23 C24 N8 114.6(3) . . ?
C23 C24 C25 124.8(3) . . ?
C26 C25 C24 121.1(3) . . ?
C26 C25 C30 119.3(3) . . ?
C30 C25 C24 119.5(3) . . ?
C27 C26 C25 120.1(3) . . ?
C26 C27 C28 120.2(3) . . ?
C29 C28 C27 120.0(3) . . ?
C28 C29 C30 120.1(3) . . ?
C29 C30 C25 120.2(3) . . ?
O2 N9 O1 118.2(3) . . ?
O3 N9 O1 120.8(3) . . ?
O3 N9 O2 121.0(3) . . ?
O4 N10 O5 124.2(4) . . ?
O4 N10 O6 120.1(3) . . ?
O5 N10 O6 115.6(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
N1 Zn1 2.214(3) . ?
N2 Zn1 2.126(3) . ?
N2 N3 1.357(4) . ?
N4 Zn1 2.140(3) . ?
N5 Zn1 2.226(3) . ?
N6 Zn1 2.120(3) . ?
N6 N7 1.349(4) . ?
N8 Zn1 2.159(2) . ?
C1 N1 1.353(4) . ?
C1 C2 1.387(5) . ?
C1 C6 1.470(4) . ?
C2 C3 1.392(5) . ?
C3 C4 1.377(5) . ?
C4 C5 1.399(5) . ?
C5 N1 1.338(4) . ?
C6 N2 1.279(4) . ?
C7 S1 1.714(3) . ?
C7 N3 1.381(5) . ?
C7 N4 1.311(5) . ?
C8 S1 1.723(4) . ?
C9 N4 1.394(4) . ?
C9 C8 1.360(5) . ?
C9 C10 1.479(5) . ?
C10 C11 1.401(5) . ?
C10 C15 1.398(5) . ?
C11 C12 1.379(6) . ?
C12 C13 1.396(6) . ?
C13 C14 1.374(7) . ?
C14 C15 1.388(6) . ?
C16 N5 1.360(5) . ?
C16 C17 1.391(5) . ?
C16 C21 1.459(5) . ?
C18 C17 1.365(7) . ?
C19 C18 1.375(8) . ?
C20 N5 1.336(5) . ?
C20 C19 1.402(6) . ?
C21 N6 1.277(4) . ?
C22 S2 1.717(3) . ?
C22 N7 1.376(4) . ?
C22 N8 1.314(4) . ?
C23 S2 1.724(3) . ?
C23 C24 1.356(4) . ?
C24 N8 1.391(4) . ?
C24 C25 1.477(4) . ?
C25 C26 1.392(5) . ?
C25 C30 1.396(4) . ?
C26 C27 1.391(5) . ?
C27 C28 1.388(5) . ?
C28 C29 1.383(6) . ?
C29 C30 1.392(5) . ?
N9 O1 1.262(4) . ?
N9 O2 1.257(4) . ?
N9 O3 1.236(4) . ?
N10 O4 1.189(5) . ?
N10 O5 1.260(5) . ?
N10 O6 1.303(4) . ?
