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#$Date: 2022-11-16 01:33:27 +0200 (Wed, 16 Nov 2022) $
#$Revision: 279300 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/58/7245832.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7245832
loop_
_publ_author_name
'Gugin, Nikita Y.'
'Virovets, Alexander V.'
'Peresypkina, Eugenia'
'Davydova, Elena I.'
'Timoshkin, Alexey Y.'
_publ_section_title
;
 Coordination polymers and molecular complexes of group 13 metal halides
 with bis-pyridylethane: comparison with rigid N-containing ligands
;
_journal_name_full               CrystEngComm
_journal_paper_doi               10.1039/D2CE01063A
_journal_year                    2022
_chemical_formula_moiety         '(C24 H24 Al Cl2 N4), (Al Cl4)'
_chemical_formula_sum            'C24 H24 Al2 Cl6 N4'
_chemical_formula_weight         635.13
_chemical_properties_physical    Air-sensitive,Moisture-sensitive
_space_group_crystal_system      trigonal
_space_group_IT_number           154
_space_group_name_Hall           'P 32 2"'
_space_group_name_H-M_alt        'P 32 2 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2022-09-14 deposited with the CCDC.	2022-10-20 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            3
_cell_length_a                   10.04888(13)
_cell_length_b                   10.04888(13)
_cell_length_c                   24.9760(5)
_cell_measurement_reflns_used    5417
_cell_measurement_temperature    90(2)
_cell_measurement_theta_max      73.9890
_cell_measurement_theta_min      5.2800
_cell_volume                     2184.18(6)
_computing_cell_refinement       'CrysAlisPro 1.171.40.14a (Rigaku OD, 2018)'
_computing_data_collection       'CrysAlisPro 1.171.40.14a (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.40.14a (Rigaku OD, 2018)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    SHELXT
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      90(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 4.2047
_diffrn_detector_type            TitanS2
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Rigaku Oxford Diffraction SuperNova'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0309
_diffrn_reflns_av_unetI/netI     0.0285
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            9216
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.982
_diffrn_reflns_theta_full        67.500
_diffrn_reflns_theta_max         74.162
_diffrn_reflns_theta_min         5.082
_diffrn_source_type              'microfocus SuperNova source'
_exptl_absorpt_coefficient_mu    6.146
_exptl_absorpt_correction_T_max  0.796
_exptl_absorpt_correction_T_min  0.561
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.40.14a (Rigaku Oxford Diffraction, 2018)
Numerical absorption correction based on gaussian integration over
			a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.449
_exptl_crystal_description       'prism with broken vertices'
_exptl_crystal_F_000             972
_exptl_crystal_size_max          0.156
_exptl_crystal_size_mid          0.098
_exptl_crystal_size_min          0.079
_refine_diff_density_max         0.294
_refine_diff_density_min         -0.174
_refine_diff_density_rms         0.037
_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.23(2)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.003
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     286
_refine_ls_number_reflns         2922
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.003
_refine_ls_R_factor_all          0.0336
_refine_ls_R_factor_gt           0.0299
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0499P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0742
_refine_ls_wR_factor_ref         0.0755
_reflns_Friedel_coverage         0.696
_reflns_Friedel_fraction_full    0.999
_reflns_Friedel_fraction_max     0.971
_reflns_number_gt                2644
_reflns_number_total             2922
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2ce01063a2.cif
_cod_data_source_block           ayt73
_cod_original_cell_volume        2184.18(7)
_cod_database_code               7245832
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.447
_shelx_estimated_absorpt_t_max   0.642
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z+2/3'
'-x+y, -x, z+1/3'
'y, x, -z'
'x-y, -y, -z+1/3'
'-x, -x+y, -z+2/3'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cl1 Cl 0.29706(9) 0.44853(9) 0.07420(2) 0.04173(18) Uani 1 1 d . . . . .
Al1 Al 0.36941(13) 0.36941(13) 0.000000 0.0328(2) Uani 1 2 d S T P . .
N1 N 0.5821(3) 0.4444(3) 0.03355(9) 0.0380(5) Uani 1 1 d . . . . .
N2 N 1.2862(3) 1.1557(3) 0.03427(9) 0.0409(6) Uani 1 1 d . . . . .
C1 C 0.5979(4) 0.4125(4) 0.08497(12) 0.0450(7) Uani 1 1 d . . . . .
H1 H 0.508077 0.356057 0.106071 0.054 Uiso 1 1 calc R U . . .
C2 C 0.7386(5) 0.4582(4) 0.10796(15) 0.0566(9) Uani 1 1 d . . . . .
H2 H 0.743803 0.430503 0.143951 0.068 Uiso 1 1 calc R U . . .
C3 C 0.8728(4) 0.5442(4) 0.07919(17) 0.0633(11) Uani 1 1 d . . . . .
C4 C 0.8558(4) 0.5793(4) 0.02683(16) 0.0574(9) Uani 1 1 d . . . . .
H4 H 0.944422 0.639840 0.005578 0.069 Uiso 1 1 calc R U . . .
C5 C 0.7127(4) 0.5277(4) 0.00540(14) 0.0453(7) Uani 1 1 d . . . . .
H5 H 0.705119 0.551686 -0.030863 0.054 Uiso 1 1 calc R U . . .
C6A C 1.0356(6) 0.5858(7) 0.0950(3) 0.0417(12) Uani 0.62 1 d . . P A 1
H6AA H 1.096854 0.596940 0.062555 0.050 Uiso 0.62 1 calc R U P A 1
H6AB H 1.032777 0.503211 0.117458 0.050 Uiso 0.62 1 calc R U P A 1
C7A C 1.1101(5) 0.7384(6) 0.12656(19) 0.0423(10) Uani 0.62 1 d . . P A 1
H7AA H 1.035764 0.733766 0.153561 0.051 Uiso 0.62 1 calc R U P A 1
H7AB H 1.200779 0.749076 0.146013 0.051 Uiso 0.62 1 calc R U P A 1
C8A C 1.1595(8) 0.8777(8) 0.0926(2) 0.0366(13) Uani 0.62 1 d . . P A 1
C9A C 1.0855(8) 0.9606(11) 0.0926(3) 0.0413(18) Uani 0.62 1 d . . P A 1
H9A H 0.991617 0.924712 0.111541 0.050 Uiso 0.62 1 calc R U P A 1
C10A C 1.1520(12) 1.1030(13) 0.0636(5) 0.034(2) Uani 0.62 1 d . . P A 1
H10A H 1.102734 1.162727 0.064517 0.041 Uiso 0.62 1 calc R U P A 1
C11A C 1.3387(13) 1.0640(17) 0.0297(6) 0.050(3) Uani 0.62 1 d . . P A 1
H11A H 1.417812 1.088609 0.004188 0.060 Uiso 0.62 1 calc R U P A 1
C12A C 1.2878(10) 0.9306(10) 0.0595(3) 0.0447(16) Uani 0.62 1 d . . P A 1
H12A H 1.340958 0.874794 0.057381 0.054 Uiso 0.62 1 calc R U P A 1
C6B C 1.0051(10) 0.6113(10) 0.1213(4) 0.0420(18) Uani 0.38 1 d . . P A 2
H6BA H 0.992587 0.680951 0.146161 0.050 Uiso 0.38 1 calc R U P A 2
H6BB H 1.003922 0.527261 0.142401 0.050 Uiso 0.38 1 calc R U P A 2
C7B C 1.1518(10) 0.6968(9) 0.0915(3) 0.0456(18) Uani 0.38 1 d . . P A 2
H7BA H 1.145799 0.635661 0.059557 0.055 Uiso 0.38 1 calc R U P A 2
H7BB H 1.235196 0.703538 0.114506 0.055 Uiso 0.38 1 calc R U P A 2
C8B C 1.1975(15) 0.8597(11) 0.0729(5) 0.0317(19) Uani 0.38 1 d . . P A 2
C9B C 1.1197(14) 0.9359(14) 0.0806(5) 0.036(2) Uani 0.38 1 d . . P A 2
H9B H 1.028114 0.887531 0.101248 0.043 Uiso 0.38 1 calc R U P A 2
C10B C 1.163(3) 1.070(2) 0.0614(11) 0.051(6) Uani 0.38 1 d . . P A 2
H10B H 1.096610 1.110086 0.067843 0.061 Uiso 0.38 1 calc R U P A 2
C11B C 1.385(2) 1.0895(19) 0.0300(9) 0.035(4) Uani 0.38 1 d . U P A 2
H11B H 1.486486 1.151163 0.016408 0.043 Uiso 0.38 1 calc R U P A 2
C12B C 1.3371(16) 0.9383(15) 0.0452(4) 0.043(3) Uani 0.38 1 d . . P A 2
H12B H 1.396235 0.891010 0.037100 0.051 Uiso 0.38 1 calc R U P A 2
Al2 Al 0.7217(2) 0.0218(3) 0.15464(6) 0.0364(5) Uani 0.5 1 d . . P . .
Cl2A Cl 0.7341(6) -0.1811(6) 0.1690(3) 0.0611(13) Uani 0.25 1 d . . P B -1
Cl3A Cl 0.512(2) 0.010(3) 0.1572(11) 0.090(7) Uani 0.25 1 d . . P B -1
Cl4A Cl 0.885(2) 0.2031(17) 0.2028(7) 0.067(5) Uani 0.25 1 d . . P B -1
Cl5A Cl 0.7763(9) 0.1018(11) 0.0744(3) 0.060(2) Uani 0.25 1 d . . P B -1
Cl2B Cl 0.6892(14) -0.2073(12) 0.1416(6) 0.054(3) Uani 0.25 1 d . . P B -2
Cl3B Cl 0.5026(9) -0.0186(13) 0.1784(8) 0.056(4) Uani 0.25 1 d . . P B -2
Cl4B Cl 0.8962(9) 0.1469(11) 0.2096(5) 0.085(3) Uani 0.25 1 d . . P B -2
Cl5B Cl 0.7832(12) 0.1369(10) 0.0801(4) 0.064(3) Uani 0.25 1 d . . P B -2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Al Al 0.2130 0.2455 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
6 -5 -4 0.0337
-3 6 2 0.0720
2 4 -1 0.0323
-4 -3 2 0.0689
-6 1 4 0.0923
6 -4 6 0.0502
5 -3 10 0.0528
2 -6 5 0.0591
4 -4 -12 0.0387
-2 6 7 0.0602
-3 -2 8 0.0583
0 0 -16 0.0422
-1 -5 -5 0.0582
-2 2 -15 0.0501
0 -2 14 0.0382
1 4 9 0.0377
0 1 16 0.0337
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Al1 N1 90.65(15) . 4 ?
N1 Al1 N2 177.79(11) . 4_445 ?
N1 Al1 N2 91.06(10) 4 4_445 ?
N1 Al1 N2 91.06(10) . 1_445 ?
N1 Al1 N2 177.79(11) 4 1_445 ?
N2 Al1 N2 87.27(16) 4_445 1_445 ?
N1 Al1 Cl1 89.73(7) . . ?
N1 Al1 Cl1 89.07(7) 4 . ?
N2 Al1 Cl1 91.71(7) 4_445 . ?
N2 Al1 Cl1 89.53(7) 1_445 . ?
N1 Al1 Cl1 89.07(7) . 4 ?
N1 Al1 Cl1 89.72(7) 4 4 ?
N2 Al1 Cl1 89.53(7) 4_445 4 ?
N2 Al1 Cl1 91.71(7) 1_445 4 ?
Cl1 Al1 Cl1 178.29(8) . 4 ?
C5 N1 C1 116.7(3) . . ?
C5 N1 Al1 121.7(2) . . ?
C1 N1 Al1 121.6(2) . . ?
C11A N2 C10A 116.5(8) . . ?
C10B N2 C11B 112.4(11) . . ?
C11A N2 Al1 128.1(6) . 1_665 ?
C10B N2 Al1 131.9(8) . 1_665 ?
C10A N2 Al1 115.3(5) . 1_665 ?
C11B N2 Al1 115.7(7) . 1_665 ?
N1 C1 C2 122.7(3) . . ?
N1 C1 H1 118.6 . . ?
C2 C1 H1 118.6 . . ?
C1 C2 C3 120.7(3) . . ?
C1 C2 H2 119.7 . . ?
C3 C2 H2 119.7 . . ?
C2 C3 C4 116.3(3) . . ?
C2 C3 C6A 127.8(4) . . ?
C4 C3 C6A 115.2(4) . . ?
C2 C3 C6B 105.9(5) . . ?
C4 C3 C6B 135.5(4) . . ?
C5 C4 C3 120.7(4) . . ?
C5 C4 H4 119.6 . . ?
C3 C4 H4 119.6 . . ?
N1 C5 C4 122.9(3) . . ?
N1 C5 H5 118.6 . . ?
C4 C5 H5 118.6 . . ?
C3 C6A C7A 109.0(4) . . ?
C3 C6A H6AA 109.9 . . ?
C7A C6A H6AA 109.9 . . ?
C3 C6A H6AB 109.9 . . ?
C7A C6A H6AB 109.9 . . ?
H6AA C6A H6AB 108.3 . . ?
C8A C7A C6A 114.2(5) . . ?
C8A C7A H7AA 108.7 . . ?
C6A C7A H7AA 108.7 . . ?
C8A C7A H7AB 108.7 . . ?
C6A C7A H7AB 108.7 . . ?
H7AA C7A H7AB 107.6 . . ?
C9A C8A C12A 116.8(6) . . ?
C9A C8A C7A 122.9(6) . . ?
C12A C8A C7A 120.3(7) . . ?
C8A C9A C10A 118.8(6) . . ?
C8A C9A H9A 120.6 . . ?
C10A C9A H9A 120.6 . . ?
N2 C10A C9A 121.8(8) . . ?
N2 C10A H10A 119.1 . . ?
C9A C10A H10A 119.1 . . ?
N2 C11A C12A 124.3(11) . . ?
N2 C11A H11A 117.8 . . ?
C12A C11A H11A 117.8 . . ?
C11A C12A C8A 120.7(8) . . ?
C11A C12A H12A 119.7 . . ?
C8A C12A H12A 119.7 . . ?
C7B C6B C3 107.3(7) . . ?
C7B C6B H6BA 110.3 . . ?
C3 C6B H6BA 110.3 . . ?
C7B C6B H6BB 110.3 . . ?
C3 C6B H6BB 110.3 . . ?
H6BA C6B H6BB 108.5 . . ?
C6B C7B C8B 116.8(9) . . ?
C6B C7B H7BA 108.1 . . ?
C8B C7B H7BA 108.1 . . ?
C6B C7B H7BB 108.1 . . ?
C8B C7B H7BB 108.1 . . ?
H7BA C7B H7BB 107.3 . . ?
C9B C8B C12B 116.7(9) . . ?
C9B C8B C7B 127.7(12) . . ?
C12B C8B C7B 115.6(11) . . ?
C10B C9B C8B 123.6(16) . . ?
C10B C9B H9B 118.2 . . ?
C8B C9B H9B 118.2 . . ?
C9B C10B N2 127.2(17) . . ?
C9B C10B H10B 116.4 . . ?
N2 C10B H10B 116.4 . . ?
C12B C11B N2 122.3(14) . . ?
C12B C11B H11B 118.9 . . ?
N2 C11B H11B 118.9 . . ?
C11B C12B C8B 116.9(11) . . ?
C11B C12B H12B 121.5 . . ?
C8B C12B H12B 121.5 . . ?
Al2 Al2 Cl3A 87.0(7) 5 . ?
Al2 Al2 Cl4B 73.8(5) 5 . ?
Al2 Al2 Cl3B 71.0(4) 5 . ?
Cl4B Al2 Cl3B 114.4(6) . . ?
Al2 Al2 Cl5B 175.9(5) 5 . ?
Cl4B Al2 Cl5B 108.8(4) . . ?
Cl3B Al2 Cl5B 110.1(5) . . ?
Al2 Al2 Cl4A 85.3(6) 5 . ?
Cl3A Al2 Cl4A 111.5(9) . . ?
Al2 Al2 Cl5A 166.3(5) 5 . ?
Cl3A Al2 Cl5A 96.6(7) . . ?
Cl4A Al2 Cl5A 105.5(6) . . ?
Al2 Al2 Cl2A 54.3(3) 5 . ?
Cl3A Al2 Cl2A 119.2(6) . . ?
Cl4A Al2 Cl2A 109.6(5) . . ?
Cl5A Al2 Cl2A 113.1(3) . . ?
Al2 Al2 Cl2B 68.8(5) 5 . ?
Cl4B Al2 Cl2B 111.8(5) . . ?
Cl3B Al2 Cl2B 104.3(5) . . ?
Cl5B Al2 Cl2B 107.1(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cl1 Al1 2.2744(6) . ?
Al1 N1 2.056(3) . ?
Al1 N1 2.056(3) 4 ?
Al1 N2 2.061(3) 4_445 ?
Al1 N2 2.061(3) 1_445 ?
N1 C5 1.348(4) . ?
N1 C1 1.352(4) . ?
N2 C11A 1.275(15) . ?
N2 C10B 1.29(3) . ?
N2 C10A 1.386(11) . ?
N2 C11B 1.452(17) . ?
C1 C2 1.375(5) . ?
C1 H1 0.9500 . ?
C2 C3 1.384(6) . ?
C2 H2 0.9500 . ?
C3 C4 1.387(5) . ?
C3 C6A 1.524(6) . ?
C3 C6B 1.559(9) . ?
C4 C5 1.371(5) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6A C7A 1.544(8) . ?
C6A H6AA 0.9900 . ?
C6A H6AB 0.9900 . ?
C7A C8A 1.494(9) . ?
C7A H7AA 0.9900 . ?
C7A H7AB 0.9900 . ?
C8A C9A 1.367(10) . ?
C8A C12A 1.392(8) . ?
C9A C10A 1.437(16) . ?
C9A H9A 0.9500 . ?
C10A H10A 0.9500 . ?
C11A C12A 1.389(18) . ?
C11A H11A 0.9500 . ?
C12A H12A 0.9500 . ?
C6B C7B 1.483(13) . ?
C6B H6BA 0.9900 . ?
C6B H6BB 0.9900 . ?
C7B C8B 1.534(11) . ?
C7B H7BA 0.9900 . ?
C7B H7BB 0.9900 . ?
C8B C9B 1.355(15) . ?
C8B C12B 1.401(15) . ?
C9B C10B 1.28(3) . ?
C9B H9B 0.9500 . ?
C10B H10B 0.9500 . ?
C11B C12B 1.40(2) . ?
C11B H11B 0.9500 . ?
C12B H12B 0.9500 . ?
Al2 Al2 0.711(3) 5 ?
Al2 Cl3A 2.048(15) . ?
Al2 Cl4B 2.082(8) . ?
Al2 Cl3B 2.114(11) . ?
Al2 Cl5B 2.115(10) . ?
Al2 Cl4A 2.116(14) . ?
Al2 Cl5A 2.127(9) . ?
Al2 Cl2A 2.135(5) . ?
Al2 Cl2B 2.182(12) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
C4 H4 Cl5A^a 0.95 2.49 3.395(9) 159.1 4_655 yes
C4 H4 Cl5B^b 0.95 2.76 3.676(10) 162.9 4_655 yes
C10A^a H10A^a Cl1 0.95 2.55 3.031(11) 111.4 1_665 yes
C11B^b H11B^b N1 0.95 2.64 3.096(17) 110.1 1_665 yes
C11A^a H11A^a Cl1 0.95 2.77 3.294(15) 115.6 4_665 yes
