#------------------------------------------------------------------------------
#$Date: 2024-07-05 18:36:34 +0300 (Fri, 05 Jul 2024) $
#$Revision: 292985 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/85/7248529.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7248529
loop_
_publ_author_name
'Guan, Ming-Xue'
'Li, Hui-Zi'
'Li, Shangda'
'Yang, Han-Jiang'
'Wang, Fei'
'Zhang, Jian'
_publ_section_title
;
 Syntheses, crystal structures and properties of a series of isostructural
 lanthanide organic frameworks
;
_journal_issue                   21
_journal_name_full               CrystEngComm
_journal_page_first              2770
_journal_page_last               2774
_journal_paper_doi               10.1039/D4CE00292J
_journal_volume                  26
_journal_year                    2024
_chemical_formula_moiety         'C24 H22 Eu O11, H2 O'
_chemical_formula_sum            'C24 H24 Eu O12'
_chemical_formula_weight         656.39
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_date             2023-06-08
_audit_creation_method
;
Olex2 1.5
(compiled 2023.03.06 svn.rbb2c1857 for OlexSys, GUI svn.r6748)
;
_audit_update_record
;
2023-10-25 deposited with the CCDC.	2024-04-08 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 111.900(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   17.2995(3)
_cell_length_b                   9.31930(10)
_cell_length_c                   15.4902(2)
_cell_measurement_reflns_used    11447
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      60.2200
_cell_measurement_theta_min      4.7730
_cell_volume                     2317.10(6)
_computing_cell_refinement       'CrysAlisPro 1.171.42.84a (Rigaku OD, 2023)'
_computing_data_collection       'CrysAlisPro 1.171.42.84a (Rigaku OD, 2023)'
_computing_data_reduction        'CrysAlisPro 1.171.42.84a (Rigaku OD, 2023)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/1 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     20.00 108.00   0.50    0.71    --   76.59-125.00   0.00  176
  2  ω     42.00  68.00   0.50    0.71    --   76.59-108.00  19.00   52
  3  ω     -4.00  38.00   0.50    0.18    --   -0.78 -99.00 -90.00   84
  4  ω     -2.00  26.00   0.50    0.18    --   -0.78 -99.00 -60.00   56
  5  ω     10.00  36.00   0.50    0.18    --   -0.78 -99.00-150.00   52
  6  ω     10.00  36.00   0.50    0.18    --   -0.78 -99.00-180.00   52
  7  ω     -8.00  17.00   0.50    0.18    --   -0.78 -99.00 -30.00   50
  8  ω      5.00  36.00   0.50    0.18    --   -0.78 -99.00 120.00   62
  9  ω     88.00 140.00   0.50    0.71    --   76.59 108.00 116.00  104
 10  ω   -106.00  -8.00   0.50    0.71    --  -78.15 108.00 116.00  196
 11  ω    -82.00 -25.00   0.50    0.71    --  -78.15  57.00 120.00  114
 12  ω    -55.00 -12.00   0.50    0.71    --  -78.15  38.00 120.00   86
 13  ω    -36.00 -10.00   0.50    0.71    --  -78.15  38.00 -90.00   52
 14  ω    -70.00 -42.00   0.50    0.71    --  -78.15  38.00 -90.00   56
 15  ω    -71.00 -30.00   0.50    0.71    --  -78.15  38.00-120.00   82
 16  ω   -144.00 -91.00   0.50    0.71    --  -78.15 -99.00  90.00  106
 17  ω   -150.00 -88.00   0.50    0.71    --  -78.15 -99.00  60.00  124
 18  ω   -143.00-118.00   0.50    0.71    --  -78.15-108.00  19.00   50
 19  ω   -147.00 -89.00   0.50    0.71    --  -78.15-125.00 -90.00  116
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'ROD, Synergy Custom system, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0199007000
_diffrn_orient_matrix_UB_12      0.0504954000
_diffrn_orient_matrix_UB_13      0.0699777000
_diffrn_orient_matrix_UB_21      -0.0113979000
_diffrn_orient_matrix_UB_22      0.1308759000
_diffrn_orient_matrix_UB_23      -0.0384220000
_diffrn_orient_matrix_UB_31      -0.0802244000
_diffrn_orient_matrix_UB_32      -0.0311140000
_diffrn_orient_matrix_UB_33      -0.0480888000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Ga K\a'
_diffrn_radiation_wavelength     1.3405
_diffrn_reflns_av_R_equivalents  0.0434
_diffrn_reflns_av_unetI/netI     0.0401
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            16036
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        53.543
_diffrn_reflns_theta_max         55.832
_diffrn_reflns_theta_min         2.393
_diffrn_source                   'micro-focus metaljet'
_exptl_absorpt_coefficient_mu    14.516
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.25029
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.42.84a (Rigaku Oxford Diffraction, 2023)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.882
_exptl_crystal_description       block
_exptl_crystal_F_000             1308
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_refine_diff_density_max         1.495
_refine_diff_density_min         -0.956
_refine_diff_density_rms         0.127
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.121
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     342
_refine_ls_number_reflns         4553
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.121
_refine_ls_R_factor_all          0.0397
_refine_ls_R_factor_gt           0.0337
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0391P)²+5.8338P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0873
_refine_ls_wR_factor_ref         0.0899
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3952
_reflns_number_total             4553
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d4ce00292j2.cif
_cod_data_source_block           gm-36-4_auto
_cod_depositor_comments
'Adding full bibliography for 7248523--7248531.cif.'
_cod_database_code               7248529
_shelx_shelxl_version_number     2018/1
_chemical_oxdiff_formula         'Eu C H O N '
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.159
_shelx_estimated_absorpt_t_min   0.159
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H) groups, All O(H,H) groups
2. Restrained distances
 H12A-H11B_$1
 2.1 with sigma of 0.02
3.a Free rotating group:
 O12(H12A,H12B)
3.b Rotating group:
 O10(H10A,H10B), O11(H11A,H11B)
3.c Ternary CH refined with riding coordinates:
 C15(H15), C16(H16), C24(H24)
3.d Aromatic/amide H refined with riding coordinates:
 C13(H13), C21(H21), C12(H12), C10(H10), C9(H9A), C19(H19), C5(H5A), C18(H18),
 C6(H6A), C3(H3), C2(H2), C22(H22)
3.e Idealised tetrahedral OH refined as rotating group:
 O9(H9), O6(H6), O5(H5)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 3.527
_oxdiff_exptl_absorpt_empirical_full_min 0.480
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.49774(2) 0.87381(2) 0.33720(2) 0.01708(9) Uani 1 1 d . . . . .
O8 O 0.58987(19) 0.5529(4) 0.2489(2) 0.0301(8) Uani 1 1 d . . . . .
O7 O 0.60322(19) 0.7107(4) 0.3604(2) 0.0294(8) Uani 1 1 d . . . . .
O9 O 0.9962(2) 0.3118(4) 0.5252(3) 0.0313(8) Uani 1 1 d . . . . .
H9 H 0.994745 0.273459 0.572226 0.047 Uiso 1 1 calc R U . . .
O6 O -0.0074(2) 0.8099(4) 0.3020(3) 0.0292(7) Uani 1 1 d . . . . .
H6 H -0.006071 0.776672 0.253517 0.044 Uiso 1 1 calc R U . . .
O5 O 0.0021(2) 1.1848(4) 0.3624(3) 0.0304(8) Uani 1 1 d . . . . .
H5 H 0.004253 1.221910 0.411224 0.046 Uiso 1 1 calc R U . . .
O10 O 0.5498(2) 0.7686(4) 0.5003(3) 0.0376(9) Uani 1 1 d . . . . .
H10A H 0.532538 0.681792 0.498555 0.056 Uiso 1 1 d R U . . .
H10B H 0.527199 0.813183 0.533475 0.056 Uiso 1 1 d R U . . .
O1 O 0.3987(2) 0.9295(4) 0.4052(2) 0.0345(8) Uani 1 1 d . . . . .
O4 O -0.4112(2) 0.9895(4) 0.2735(3) 0.0389(9) Uani 1 1 d . . . . .
O2 O 0.42776(18) 0.9397(4) 0.5574(2) 0.0255(7) Uani 1 1 d . . . . .
O3 O -0.4160(2) 1.1636(4) 0.1742(3) 0.0343(9) Uani 1 1 d . . . . .
O12 O 0.4067(3) 0.5420(6) 0.4986(3) 0.0610(13) Uani 1 1 d G . . . .
H12A H 0.379694 0.611938 0.508837 0.092 Uiso 1 1 d DG U . . .
H12B H 0.417623 0.568127 0.451879 0.092 Uiso 1 1 d G U . . .
C23 C 0.6295(3) 0.6102(5) 0.3253(3) 0.0214(9) Uani 1 1 d . . . . .
O11 O 0.4462(3) 0.8014(5) 0.1729(3) 0.0484(11) Uani 1 1 d . . . . .
H11A H 0.454450 0.700778 0.163417 0.073 Uiso 1 1 d R U . . .
H11B H 0.476062 0.842833 0.136705 0.073 Uiso 1 1 d R U . . .
C17 C 0.8829(3) 0.4858(5) 0.4775(3) 0.0227(10) Uani 1 1 d . . . . .
C13 C -0.1662(3) 0.8884(5) 0.3053(4) 0.0260(10) Uani 1 1 d . . . . .
H13 H -0.139147 0.809560 0.340382 0.031 Uiso 1 1 calc R U . . .
C21 C 0.7537(3) 0.4530(5) 0.3470(3) 0.0257(10) Uani 1 1 d . . . . .
H21 H 0.722655 0.405210 0.292285 0.031 Uiso 1 1 calc R U . . .
C15 C 0.0232(3) 1.0373(5) 0.3778(3) 0.0224(9) Uani 1 1 d . . . . .
H15 H 0.007997 1.003546 0.429251 0.027 Uiso 1 1 calc R U . . .
C12 C -0.2496(3) 0.9145(5) 0.2911(4) 0.0265(10) Uani 1 1 d . . . . .
H12 H -0.277808 0.852409 0.316138 0.032 Uiso 1 1 calc R U . . .
C1 C 0.1155(3) 1.0132(5) 0.4032(3) 0.0232(10) Uani 1 1 d . . . . .
C20 C 0.7171(3) 0.5593(5) 0.3806(3) 0.0208(9) Uani 1 1 d . . . . .
C14 C -0.3796(3) 1.0632(5) 0.2285(3) 0.0230(10) Uani 1 1 d . . . . .
C10 C -0.2481(3) 1.1225(5) 0.2018(4) 0.0251(10) Uani 1 1 d . . . . .
H10 H -0.275101 1.201450 0.166857 0.030 Uiso 1 1 calc R U . . .
C7 C 0.3778(3) 0.9453(5) 0.4733(3) 0.0206(9) Uani 1 1 d . . . . .
C16 C -0.0311(3) 0.9577(5) 0.2884(3) 0.0209(9) Uani 1 1 d . . . . .
H16 H -0.018330 0.994996 0.236085 0.025 Uiso 1 1 calc R U . . .
C8 C -0.1235(3) 0.9789(5) 0.2677(3) 0.0211(9) Uani 1 1 d . . . . .
C9 C -0.1652(3) 1.0960(5) 0.2153(3) 0.0248(10) Uani 1 1 d . . . . .
H9A H -0.137426 1.157146 0.189123 0.030 Uiso 1 1 calc R U . . .
C19 C 0.7623(3) 0.6247(5) 0.4652(3) 0.0256(10) Uani 1 1 d . . . . .
H19 H 0.737482 0.693978 0.489576 0.031 Uiso 1 1 calc R U . . .
C24 C 0.9755(3) 0.4593(5) 0.5249(3) 0.0219(9) Uani 1 1 d . . . . .
H24 H 0.993736 0.493112 0.589354 0.026 Uiso 1 1 calc R U . . .
C11 C -0.2907(3) 1.0327(5) 0.2397(3) 0.0214(9) Uani 1 1 d . . . . .
C5 C 0.2474(3) 0.9186(6) 0.5079(4) 0.0301(11) Uani 1 1 d . . . . .
H5A H 0.277897 0.870031 0.562505 0.036 Uiso 1 1 calc R U . . .
C18 C 0.8439(3) 0.5862(5) 0.5123(3) 0.0266(10) Uani 1 1 d . . . . .
H18 H 0.873597 0.629056 0.569302 0.032 Uiso 1 1 calc R U . . .
C4 C 0.2864(3) 0.9703(5) 0.4518(3) 0.0217(9) Uani 1 1 d . . . . .
C6 C 0.1617(3) 0.9391(6) 0.4829(4) 0.0295(11) Uani 1 1 d . . . . .
H6A H 0.135359 0.902198 0.520539 0.035 Uiso 1 1 calc R U . . .
C3 C 0.2406(3) 1.0450(6) 0.3709(3) 0.0287(11) Uani 1 1 d . . . . .
H3 H 0.266846 1.080287 0.332700 0.034 Uiso 1 1 calc R U . . .
C2 C 0.1559(3) 1.0667(6) 0.3475(4) 0.0291(11) Uani 1 1 d . . . . .
H2 H 0.125789 1.117751 0.293906 0.035 Uiso 1 1 calc R U . . .
C22 C 0.8365(3) 0.4170(5) 0.3942(4) 0.0280(11) Uani 1 1 d . . . . .
H22 H 0.861277 0.346794 0.370423 0.034 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0137 0.0067 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -2.6997 10.5010 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0389 0.0241 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O8 Eu1 O10 139.86(13) 2_655 . ?
O8 Eu1 O1 70.90(13) 2_655 . ?
O8 Eu1 O4 80.11(12) 2_655 1_655 ?
O8 Eu1 O2 86.57(12) 2_655 3_676 ?
O8 Eu1 O3 107.89(13) 2_655 2_545 ?
O8 Eu1 O11 72.20(13) 2_655 . ?
O7 Eu1 O8 151.47(13) . 2_655 ?
O7 Eu1 O10 67.85(12) . . ?
O7 Eu1 O1 137.39(13) . . ?
O7 Eu1 O4 75.96(13) . 1_655 ?
O7 Eu1 O2 100.30(11) . 3_676 ?
O7 Eu1 O3 83.24(12) . 2_545 ?
O7 Eu1 O11 86.59(13) . . ?
O1 Eu1 O10 72.00(12) . . ?
O1 Eu1 O4 140.74(14) . 1_655 ?
O1 Eu1 O2 80.43(12) . 3_676 ?
O1 Eu1 O3 72.95(13) . 2_545 ?
O1 Eu1 O11 118.39(14) . . ?
O4 Eu1 O10 122.52(13) 1_655 . ?
O4 Eu1 O2 71.77(13) 1_655 3_676 ?
O4 Eu1 O11 74.81(15) 1_655 . ?
O2 Eu1 O10 72.66(12) 3_676 . ?
O2 Eu1 O11 142.93(13) 3_676 . ?
O3 Eu1 O10 74.77(13) 2_545 . ?
O3 Eu1 O4 143.11(14) 2_545 1_655 ?
O3 Eu1 O2 142.89(12) 2_545 3_676 ?
O3 Eu1 O11 73.82(14) 2_545 . ?
O11 Eu1 O10 141.37(14) . . ?
C23 O8 Eu1 150.1(3) . 2_645 ?
C23 O7 Eu1 145.5(3) . . ?
C24 O9 H9 109.5 . . ?
C16 O6 H6 109.5 . . ?
C15 O5 H5 109.5 . . ?
Eu1 O10 H10A 110.0 . . ?
Eu1 O10 H10B 109.6 . . ?
H10A O10 H10B 104.0 . . ?
C7 O1 Eu1 152.4(3) . . ?
C14 O4 Eu1 166.5(3) . 1_455 ?
C7 O2 Eu1 131.0(3) . 3_676 ?
C14 O3 Eu1 142.7(3) . 2 ?
H12A O12 H12B 104.5 . . ?
O8 C23 O7 125.0(4) . . ?
O8 C23 C20 118.9(4) . . ?
O7 C23 C20 116.0(4) . . ?
Eu1 O11 H11A 114.0 . . ?
Eu1 O11 H11B 115.0 . . ?
H11A O11 H11B 99.0 . . ?
C18 C17 C24 120.4(4) . . ?
C18 C17 C22 118.6(4) . . ?
C22 C17 C24 120.8(4) . . ?
C12 C13 H13 119.7 . . ?
C8 C13 H13 119.7 . . ?
C8 C13 C12 120.6(4) . . ?
C20 C21 H21 119.8 . . ?
C20 C21 C22 120.3(4) . . ?
C22 C21 H21 119.8 . . ?
O5 C15 H15 108.5 . . ?
O5 C15 C1 111.6(4) . . ?
O5 C15 C16 106.4(4) . . ?
C1 C15 H15 108.5 . . ?
C1 C15 C16 113.1(4) . . ?
C16 C15 H15 108.5 . . ?
C13 C12 H12 119.8 . . ?
C11 C12 C13 120.4(4) . . ?
C11 C12 H12 119.8 . . ?
C6 C1 C15 120.7(4) . . ?
C6 C1 C2 118.6(4) . . ?
C2 C1 C15 120.8(4) . . ?
C21 C20 C23 121.1(4) . . ?
C21 C20 C19 119.6(4) . . ?
C19 C20 C23 119.2(4) . . ?
O4 C14 O3 124.8(4) . . ?
O4 C14 C11 118.4(4) . . ?
O3 C14 C11 116.8(4) . . ?
C9 C10 H10 119.6 . . ?
C11 C10 H10 119.6 . . ?
C11 C10 C9 120.8(4) . . ?
O1 C7 O2 124.2(4) . . ?
O1 C7 C4 116.3(4) . . ?
O2 C7 C4 119.4(4) . . ?
O6 C16 C15 106.7(4) . . ?
O6 C16 H16 108.8 . . ?
O6 C16 C8 112.1(4) . . ?
C15 C16 H16 108.8 . . ?
C8 C16 C15 111.5(4) . . ?
C8 C16 H16 108.8 . . ?
C13 C8 C16 121.0(4) . . ?
C13 C8 C9 118.8(4) . . ?
C9 C8 C16 120.0(4) . . ?
C10 C9 H9A 119.8 . . ?
C8 C9 C10 120.5(4) . . ?
C8 C9 H9A 119.8 . . ?
C20 C19 H19 120.3 . . ?
C18 C19 C20 119.4(4) . . ?
C18 C19 H19 120.3 . . ?
O9 C24 C17 112.4(4) . . ?
O9 C24 C24 107.0(4) . 3_766 ?
O9 C24 H24 108.8 . . ?
C17 C24 C24 110.9(5) . 3_766 ?
C17 C24 H24 108.8 . . ?
C24 C24 H24 108.8 3_766 . ?
C12 C11 C14 119.8(4) . . ?
C10 C11 C12 118.9(4) . . ?
C10 C11 C14 121.3(4) . . ?
C4 C5 H5A 120.1 . . ?
C4 C5 C6 119.8(5) . . ?
C6 C5 H5A 120.1 . . ?
C17 C18 H18 119.1 . . ?
C19 C18 C17 121.8(5) . . ?
C19 C18 H18 119.1 . . ?
C5 C4 C7 121.9(4) . . ?
C5 C4 C3 119.8(4) . . ?
C3 C4 C7 118.3(4) . . ?
C1 C6 C5 121.1(4) . . ?
C1 C6 H6A 119.4 . . ?
C5 C6 H6A 119.4 . . ?
C4 C3 H3 120.0 . . ?
C2 C3 C4 119.9(4) . . ?
C2 C3 H3 120.0 . . ?
C1 C2 H2 119.6 . . ?
C3 C2 C1 120.8(4) . . ?
C3 C2 H2 119.6 . . ?
C17 C22 H22 120.0 . . ?
C21 C22 C17 120.1(4) . . ?
C21 C22 H22 120.0 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O8 2.313(3) 2_655 ?
Eu1 O7 2.298(3) . ?
Eu1 O10 2.541(4) . ?
Eu1 O1 2.379(3) . ?
Eu1 O4 2.403(3) 1_655 ?
Eu1 O2 2.404(3) 3_676 ?
Eu1 O3 2.383(4) 2_545 ?
Eu1 O11 2.457(4) . ?
O8 C23 1.245(6) . ?
O7 C23 1.250(6) . ?
O9 H9 0.8200 . ?
O9 C24 1.420(6) . ?
O6 H6 0.8200 . ?
O6 C16 1.430(6) . ?
O5 H5 0.8200 . ?
O5 C15 1.419(6) . ?
O10 H10A 0.8599 . ?
O10 H10B 0.8602 . ?
O1 C7 1.246(6) . ?
O4 C14 1.241(6) . ?
O2 C7 1.267(5) . ?
O3 C14 1.259(6) . ?
O12 H12A 0.8502 . ?
O12 H12B 0.8502 . ?
C23 C20 1.512(6) . ?
O11 H11A 0.9680 . ?
O11 H11B 0.9730 . ?
C17 C24 1.513(6) . ?
C17 C18 1.375(7) . ?
C17 C22 1.395(7) . ?
C13 H13 0.9300 . ?
C13 C12 1.397(6) . ?
C13 C8 1.385(6) . ?
C21 H21 0.9300 . ?
C21 C20 1.378(6) . ?
C21 C22 1.385(6) . ?
C15 H15 0.9800 . ?
C15 C1 1.513(6) . ?
C15 C16 1.542(7) . ?
C12 H12 0.9300 . ?
C12 C11 1.389(6) . ?
C1 C6 1.379(7) . ?
C1 C2 1.389(7) . ?
C20 C19 1.391(7) . ?
C14 C11 1.509(6) . ?
C10 H10 0.9300 . ?
C10 C9 1.392(6) . ?
C10 C11 1.383(6) . ?
C7 C4 1.506(6) . ?
C16 H16 0.9800 . ?
C16 C8 1.522(6) . ?
C8 C9 1.390(6) . ?
C9 H9A 0.9300 . ?
C19 H19 0.9300 . ?
C19 C18 1.373(7) . ?
C24 C24 1.543(9) 3_766 ?
C24 H24 0.9800 . ?
C5 H5A 0.9300 . ?
C5 C4 1.371(7) . ?
C5 C6 1.400(6) . ?
C18 H18 0.9300 . ?
C4 C3 1.393(7) . ?
C6 H6A 0.9300 . ?
C3 H3 0.9300 . ?
C3 C2 1.387(6) . ?
C2 H2 0.9300 . ?
C22 H22 0.9300 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O8 C23 O7 -93.8(7) 2_645 . . . ?
Eu1 O8 C23 C20 87.8(7) 2_645 . . . ?
Eu1 O7 C23 O8 -6.7(9) . . . . ?
Eu1 O7 C23 C20 171.8(4) . . . . ?
Eu1 O1 C7 O2 6.7(11) . . . . ?
Eu1 O1 C7 C4 -172.4(5) . . . . ?
Eu1 O4 C14 O3 11(2) 1_455 . . . ?
Eu1 O4 C14 C11 -169.3(14) 1_455 . . . ?
Eu1 O2 C7 O1 93.7(5) 3_676 . . . ?
Eu1 O2 C7 C4 -87.3(5) 3_676 . . . ?
Eu1 O3 C14 O4 48.2(9) 2 . . . ?
Eu1 O3 C14 C11 -131.1(4) 2 . . . ?
O8 C23 C20 C21 1.1(7) . . . . ?
O8 C23 C20 C19 178.8(4) . . . . ?
O7 C23 C20 C21 -177.4(4) . . . . ?
O7 C23 C20 C19 0.2(6) . . . . ?
O6 C16 C8 C13 31.9(6) . . . . ?
O6 C16 C8 C9 -152.5(4) . . . . ?
O5 C15 C1 C6 126.4(5) . . . . ?
O5 C15 C1 C2 -52.8(6) . . . . ?
O5 C15 C16 O6 177.5(3) . . . . ?
O5 C15 C16 C8 -59.8(5) . . . . ?
O1 C7 C4 C5 145.7(5) . . . . ?
O1 C7 C4 C3 -32.6(7) . . . . ?
O4 C14 C11 C12 7.1(7) . . . . ?
O4 C14 C11 C10 -171.2(5) . . . . ?
O2 C7 C4 C5 -33.4(7) . . . . ?
O2 C7 C4 C3 148.3(5) . . . . ?
O3 C14 C11 C12 -173.5(5) . . . . ?
O3 C14 C11 C10 8.2(7) . . . . ?
C23 C20 C19 C18 -175.3(4) . . . . ?
C13 C12 C11 C14 -177.3(5) . . . . ?
C13 C12 C11 C10 1.0(8) . . . . ?
C13 C8 C9 C10 0.6(7) . . . . ?
C21 C20 C19 C18 2.4(7) . . . . ?
C15 C1 C6 C5 -178.8(5) . . . . ?
C15 C1 C2 C3 179.8(5) . . . . ?
C15 C16 C8 C13 -87.7(5) . . . . ?
C15 C16 C8 C9 88.0(5) . . . . ?
C12 C13 C8 C16 175.6(5) . . . . ?
C12 C13 C8 C9 -0.1(7) . . . . ?
C1 C15 C16 O6 54.6(5) . . . . ?
C1 C15 C16 C8 177.3(4) . . . . ?
C20 C21 C22 C17 1.6(8) . . . . ?
C20 C19 C18 C17 1.0(8) . . . . ?
C7 C4 C3 C2 178.3(5) . . . . ?
C16 C15 C1 C6 -113.6(5) . . . . ?
C16 C15 C1 C2 67.2(6) . . . . ?
C16 C8 C9 C10 -175.1(4) . . . . ?
C8 C13 C12 C11 -0.7(8) . . . . ?
C9 C10 C11 C12 -0.5(7) . . . . ?
C9 C10 C11 C14 177.8(5) . . . . ?
C24 C17 C18 C19 172.3(5) . . . . ?
C24 C17 C22 C21 -173.6(5) . . . . ?
C11 C10 C9 C8 -0.3(8) . . . . ?
C5 C4 C3 C2 0.0(8) . . . . ?
C18 C17 C24 O9 141.5(5) . . . . ?
C18 C17 C24 C24 -98.7(6) . . . 3_766 ?
C18 C17 C22 C21 1.8(8) . . . . ?
C4 C5 C6 C1 -1.3(8) . . . . ?
C4 C3 C2 C1 -0.8(8) . . . . ?
C6 C1 C2 C3 0.6(8) . . . . ?
C6 C5 C4 C7 -177.2(5) . . . . ?
C6 C5 C4 C3 1.1(8) . . . . ?
C2 C1 C6 C5 0.4(8) . . . . ?
C22 C17 C24 O9 -43.1(6) . . . . ?
C22 C17 C24 C24 76.6(6) . . . 3_766 ?
C22 C17 C18 C19 -3.2(8) . . . . ?
C22 C21 C20 C23 173.9(5) . . . . ?
C22 C21 C20 C19 -3.7(7) . . . . ?
