#------------------------------------------------------------------------------
#$Date: 2024-07-05 21:07:19 +0300 (Fri, 05 Jul 2024) $
#$Revision: 293288 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/88/7248825.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7248825
loop_
_publ_author_name
'Deree, Yinon'
'Bogoslavsky, Benny'
'Schapiro, Igor'
'Gidron, Ori'
_publ_section_title
;
 The photochemistry and photophysics of benzoyl-carbazole.
;
_journal_issue                   26
_journal_name_full               'Physical chemistry chemical physics : PCCP'
_journal_page_first              18048
_journal_page_last               18053
_journal_paper_doi               10.1039/d4cp01781a
_journal_volume                  26
_journal_year                    2024
_chemical_formula_moiety         'C19 H7 F4 N O'
_chemical_formula_sum            'C19 H7 F4 N O'
_chemical_formula_weight         341.26
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2022-09-08
_audit_creation_method
;
Olex2 1.5
(compiled 2021.12.09 svn.r5202d8cf for OlexSys, GUI svn.r6439)
;
_audit_update_record
;
2024-04-30 deposited with the CCDC.	2024-06-07 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 93.668(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   6.9645(3)
_cell_length_b                   13.1363(6)
_cell_length_c                   14.5331(6)
_cell_measurement_reflns_used    3177
_cell_measurement_temperature    100.00(11)
_cell_measurement_theta_max      32.2740
_cell_measurement_theta_min      3.0930
_cell_volume                     1326.88(10)
_computing_cell_refinement       'CrysAlisPro 1.171.42.67a (Rigaku OD, 2022)'
_computing_data_collection       'CrysAlisPro 1.171.42.67a (Rigaku OD, 2022)'
_computing_data_reduction        'CrysAlisPro 1.171.42.67a (Rigaku OD, 2022)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/4 (Sheldrick, 2014)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.00(11)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.803
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -63.00  27.00   0.50  420.00    --    6.81 -77.00  90.00  180
  2  ω    -56.00   5.00   0.50  420.00    --    6.81 -19.00 150.00  122
  3  ω    -20.00  19.00   0.50  420.00    --   -7.90 -99.00 150.00   78
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type
'XtaLAB Synergy, Single source at offset/far, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0001587000
_diffrn_orient_matrix_UB_12      -0.0083545000
_diffrn_orient_matrix_UB_13      -0.0482154000
_diffrn_orient_matrix_UB_21      -0.0183201000
_diffrn_orient_matrix_UB_22      -0.0524859000
_diffrn_orient_matrix_UB_23      0.0068726000
_diffrn_orient_matrix_UB_31      -0.1003917000
_diffrn_orient_matrix_UB_32      0.0095160000
_diffrn_orient_matrix_UB_33      -0.0045145000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0372
_diffrn_reflns_av_unetI/netI     0.0535
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.803
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            8943
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.803
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         32.028
_diffrn_reflns_theta_min         3.101
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'PhotonJet (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    0.145
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.788
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.42.67a (Rigaku Oxford Diffraction, 2022)
Numerical absorption correction based on gaussian integration over
a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.708
_exptl_crystal_description       needle
_exptl_crystal_F_000             688
_exptl_crystal_size_max          0.322
_exptl_crystal_size_mid          0.058
_exptl_crystal_size_min          0.038
_refine_diff_density_max         0.525
_refine_diff_density_min         -0.302
_refine_diff_density_rms         0.082
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.038
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     226
_refine_ls_number_reflns         3721
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.038
_refine_ls_R_factor_all          0.1142
_refine_ls_R_factor_gt           0.0720
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0908P)²+0.5290P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1617
_refine_ls_wR_factor_ref         0.1806
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2439
_reflns_number_total             3721
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d4cp01781a2.cif
_cod_data_source_block           origi93
_cod_depositor_comments          'Adding full bibliography for 7248825.cif.'
_cod_database_code               7248825
_shelx_shelxl_version_number     2018/3
_chemical_oxdiff_formula         'C19 H20 N O F4'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.995
_shelx_estimated_absorpt_t_min   0.955
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C8(H8), C9(H9), C10(H10), C11(H11)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 2.008
_oxdiff_exptl_absorpt_empirical_full_min 0.464
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
F1 F 0.5753(2) 0.45879(11) 0.24788(9) 0.0277(4) Uani 1 1 d . . . . .
F2 F 0.5455(2) 0.25870(12) 0.25895(12) 0.0393(4) Uani 1 1 d . . . . .
F3 F 0.6450(2) 0.15992(11) 0.41871(13) 0.0418(5) Uani 1 1 d . . . . .
F4 F 0.7683(2) 0.26191(11) 0.56898(12) 0.0356(4) Uani 1 1 d . . . . .
O1 O 0.6277(2) 0.63369(13) 0.33036(10) 0.0217(4) Uani 1 1 d . . . . .
N1 N 0.7558(2) 0.63609(13) 0.47780(11) 0.0129(4) Uani 1 1 d . . . . .
C1 C 0.8060(3) 0.58636(17) 0.56043(13) 0.0146(4) Uani 1 1 d . . . . .
C2 C 0.8001(3) 0.48211(18) 0.57249(15) 0.0179(5) Uani 1 1 d . . . . .
C3 C 0.8553(3) 0.4479(2) 0.66287(16) 0.0250(5) Uani 1 1 d . . . . .
H3 H 0.856772 0.377118 0.676175 0.030 Uiso 1 1 calc R U . . .
C4 C 0.9076(3) 0.5179(2) 0.73249(16) 0.0287(6) Uani 1 1 d . . . . .
H4 H 0.945112 0.492841 0.792293 0.034 Uiso 1 1 calc R U . . .
C5 C 0.9072(3) 0.6221(2) 0.71805(15) 0.0245(6) Uani 1 1 d . . . . .
H5 H 0.940244 0.667927 0.767106 0.029 Uiso 1 1 calc R U . . .
C6 C 0.8568(3) 0.65791(18) 0.62927(14) 0.0167(5) Uani 1 1 d . . . . .
C7 C 0.8354(3) 0.75737(18) 0.58693(14) 0.0167(5) Uani 1 1 d . . . . .
C8 C 0.8638(3) 0.85663(19) 0.62057(16) 0.0217(5) Uani 1 1 d . . . . .
H8 H 0.907753 0.868334 0.682899 0.026 Uiso 1 1 calc R U . . .
C9 C 0.8261(3) 0.93698(19) 0.56081(17) 0.0250(5) Uani 1 1 d . . . . .
H9 H 0.842315 1.004666 0.582967 0.030 Uiso 1 1 calc R U . . .
C10 C 0.7647(3) 0.92102(18) 0.46865(17) 0.0235(5) Uani 1 1 d . . . . .
H10 H 0.740371 0.977959 0.429311 0.028 Uiso 1 1 calc R U . . .
C11 C 0.7383(3) 0.82309(17) 0.43335(15) 0.0192(5) Uani 1 1 d . . . . .
H11 H 0.698637 0.812018 0.370387 0.023 Uiso 1 1 calc R U . . .
C12 C 0.7724(3) 0.74247(16) 0.49365(14) 0.0140(4) Uani 1 1 d . . . . .
C13 C 0.6849(3) 0.58660(17) 0.39867(14) 0.0148(4) Uani 1 1 d . . . . .
C14 C 0.6829(3) 0.47306(17) 0.40750(15) 0.0166(4) Uani 1 1 d . . . . .
C15 C 0.7354(3) 0.42188(17) 0.49141(15) 0.0176(5) Uani 1 1 d . . . . .
C16 C 0.6220(3) 0.41589(18) 0.32961(16) 0.0212(5) Uani 1 1 d . . . . .
C17 C 0.6083(3) 0.3113(2) 0.33366(18) 0.0275(6) Uani 1 1 d . . . . .
C18 C 0.6578(3) 0.26152(18) 0.4149(2) 0.0284(6) Uani 1 1 d . . . . .
C19 C 0.7211(3) 0.31602(19) 0.49179(18) 0.0256(5) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
0 2 20 0.0337
-9 4 5 0.1402
10 -3 -1 0.1614
0 -2 -20 0.0207
0 18 -3 0.0249
0 15 11 0.0264
0 -15 -12 0.0151
0 -18 -4 0.0095
0 -14 14 0.0154
-1 14 -13 0.0219
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 N1 C12 107.98(17) . . ?
C13 N1 C1 123.57(19) . . ?
C13 N1 C12 128.17(18) . . ?
N1 C1 C6 109.8(2) . . ?
C2 C1 N1 124.5(2) . . ?
C2 C1 C6 125.6(2) . . ?
C1 C2 C3 115.0(2) . . ?
C1 C2 C15 116.31(19) . . ?
C3 C2 C15 128.7(2) . . ?
C2 C3 H3 119.8 . . ?
C4 C3 C2 120.3(2) . . ?
C4 C3 H3 119.8 . . ?
C3 C4 H4 118.6 . . ?
C5 C4 C3 122.8(2) . . ?
C5 C4 H4 118.6 . . ?
C4 C5 H5 121.0 . . ?
C4 C5 C6 118.1(2) . . ?
C6 C5 H5 121.0 . . ?
C1 C6 C7 106.70(18) . . ?
C5 C6 C1 118.1(2) . . ?
C5 C6 C7 135.2(2) . . ?
C8 C7 C6 133.1(2) . . ?
C8 C7 C12 119.5(2) . . ?
C12 C7 C6 107.48(19) . . ?
C7 C8 H8 120.8 . . ?
C9 C8 C7 118.3(2) . . ?
C9 C8 H8 120.8 . . ?
C8 C9 H9 119.2 . . ?
C8 C9 C10 121.5(2) . . ?
C10 C9 H9 119.2 . . ?
C9 C10 H10 119.4 . . ?
C11 C10 C9 121.2(2) . . ?
C11 C10 H10 119.4 . . ?
C10 C11 H11 121.3 . . ?
C12 C11 C10 117.4(2) . . ?
C12 C11 H11 121.3 . . ?
C7 C12 N1 108.01(18) . . ?
C11 C12 N1 129.87(19) . . ?
C11 C12 C7 122.1(2) . . ?
O1 C13 N1 121.4(2) . . ?
O1 C13 C14 124.94(19) . . ?
N1 C13 C14 113.68(18) . . ?
C15 C14 C13 122.8(2) . . ?
C16 C14 C13 118.0(2) . . ?
C16 C14 C15 119.2(2) . . ?
C14 C15 C2 118.9(2) . . ?
C19 C15 C2 123.6(2) . . ?
C19 C15 C14 117.5(2) . . ?
F1 C16 C14 122.4(2) . . ?
F1 C16 C17 116.4(2) . . ?
C17 C16 C14 121.2(2) . . ?
F2 C17 C16 120.0(3) . . ?
F2 C17 C18 120.2(2) . . ?
C18 C17 C16 119.8(2) . . ?
F3 C18 C17 119.8(2) . . ?
F3 C18 C19 120.2(3) . . ?
C17 C18 C19 120.0(2) . . ?
F4 C19 C15 121.0(2) . . ?
F4 C19 C18 116.7(2) . . ?
C18 C19 C15 122.3(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
F1 C16 1.336(3) . ?
F2 C17 1.337(3) . ?
F3 C18 1.339(3) . ?
F4 C19 1.351(3) . ?
O1 C13 1.215(3) . ?
N1 C1 1.392(3) . ?
N1 C12 1.420(3) . ?
N1 C13 1.384(3) . ?
C1 C2 1.382(3) . ?
C1 C6 1.402(3) . ?
C2 C3 1.418(3) . ?
C2 C15 1.466(3) . ?
C3 H3 0.9500 . ?
C3 C4 1.398(4) . ?
C4 H4 0.9500 . ?
C4 C5 1.385(4) . ?
C5 H5 0.9500 . ?
C5 C6 1.397(3) . ?
C6 C7 1.448(3) . ?
C7 C8 1.402(3) . ?
C7 C12 1.412(3) . ?
C8 H8 0.9500 . ?
C8 C9 1.381(4) . ?
C9 H9 0.9500 . ?
C9 C10 1.395(3) . ?
C10 H10 0.9500 . ?
C10 C11 1.393(3) . ?
C11 H11 0.9500 . ?
C11 C12 1.385(3) . ?
C13 C14 1.497(3) . ?
C14 C15 1.420(3) . ?
C14 C16 1.401(3) . ?
C15 C19 1.394(3) . ?
C16 C17 1.378(3) . ?
C17 C18 1.374(4) . ?
C18 C19 1.376(4) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
F1 C16 C17 F2 -1.9(3) . . . . ?
F1 C16 C17 C18 178.66(19) . . . . ?
F2 C17 C18 F3 0.8(3) . . . . ?
F2 C17 C18 C19 -179.6(2) . . . . ?
F3 C18 C19 F4 0.1(3) . . . . ?
F3 C18 C19 C15 -179.5(2) . . . . ?
O1 C13 C14 C15 -174.2(2) . . . . ?
O1 C13 C14 C16 4.3(3) . . . . ?
N1 C1 C2 C3 -179.25(18) . . . . ?
N1 C1 C2 C15 -0.1(3) . . . . ?
N1 C1 C6 C5 178.43(18) . . . . ?
N1 C1 C6 C7 0.4(2) . . . . ?
N1 C13 C14 C15 4.4(3) . . . . ?
N1 C13 C14 C16 -177.08(17) . . . . ?
C1 N1 C12 C7 0.6(2) . . . . ?
C1 N1 C12 C11 180.0(2) . . . . ?
C1 N1 C13 O1 173.71(19) . . . . ?
C1 N1 C13 C14 -5.0(3) . . . . ?
C1 C2 C3 C4 1.0(3) . . . . ?
C1 C2 C15 C14 -0.4(3) . . . . ?
C1 C2 C15 C19 179.99(19) . . . . ?
C1 C6 C7 C8 179.7(2) . . . . ?
C1 C6 C7 C12 0.0(2) . . . . ?
C2 C1 C6 C5 0.4(3) . . . . ?
C2 C1 C6 C7 -177.64(19) . . . . ?
C2 C3 C4 C5 0.5(4) . . . . ?
C2 C15 C19 F4 -0.3(3) . . . . ?
C2 C15 C19 C18 179.2(2) . . . . ?
C3 C2 C15 C14 178.6(2) . . . . ?
C3 C2 C15 C19 -1.0(4) . . . . ?
C3 C4 C5 C6 -1.7(3) . . . . ?
C4 C5 C6 C1 1.2(3) . . . . ?
C4 C5 C6 C7 178.5(2) . . . . ?
C5 C6 C7 C8 2.1(4) . . . . ?
C5 C6 C7 C12 -177.6(2) . . . . ?
C6 C1 C2 C3 -1.5(3) . . . . ?
C6 C1 C2 C15 177.66(19) . . . . ?
C6 C7 C8 C9 -178.8(2) . . . . ?
C6 C7 C12 N1 -0.4(2) . . . . ?
C6 C7 C12 C11 -179.80(19) . . . . ?
C7 C8 C9 C10 -1.2(3) . . . . ?
C8 C7 C12 N1 179.92(18) . . . . ?
C8 C7 C12 C11 0.5(3) . . . . ?
C8 C9 C10 C11 0.2(4) . . . . ?
C9 C10 C11 C12 1.1(3) . . . . ?
C10 C11 C12 N1 179.3(2) . . . . ?
C10 C11 C12 C7 -1.4(3) . . . . ?
C12 N1 C1 C2 177.44(19) . . . . ?
C12 N1 C1 C6 -0.6(2) . . . . ?
C12 N1 C13 O1 0.6(3) . . . . ?
C12 N1 C13 C14 -178.08(18) . . . . ?
C12 C7 C8 C9 0.8(3) . . . . ?
C13 N1 C1 C2 3.1(3) . . . . ?
C13 N1 C1 C6 -174.95(18) . . . . ?
C13 N1 C12 C7 174.58(18) . . . . ?
C13 N1 C12 C11 -6.0(4) . . . . ?
C13 C14 C15 C2 -1.9(3) . . . . ?
C13 C14 C15 C19 177.77(19) . . . . ?
C13 C14 C16 F1 3.2(3) . . . . ?
C13 C14 C16 C17 -177.11(19) . . . . ?
C14 C15 C19 F4 -179.96(18) . . . . ?
C14 C15 C19 C18 -0.4(3) . . . . ?
C14 C16 C17 F2 178.41(19) . . . . ?
C14 C16 C17 C18 -1.0(3) . . . . ?
C15 C2 C3 C4 -178.0(2) . . . . ?
C15 C14 C16 F1 -178.23(19) . . . . ?
C15 C14 C16 C17 1.5(3) . . . . ?
C16 C14 C15 C2 179.63(19) . . . . ?
C16 C14 C15 C19 -0.7(3) . . . . ?
C16 C17 C18 F3 -179.8(2) . . . . ?
C16 C17 C18 C19 -0.1(3) . . . . ?
C17 C18 C19 F4 -179.6(2) . . . . ?
C17 C18 C19 C15 0.9(3) . . . . ?
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
-0.2368 2.2461 20.3207 -0.9986 0.0261 -0.0466
-9.4471 3.8174 4.9357 -0.2714 0.0066 0.9625
9.6466 -3.4538 -0.8682 0.0722 -0.0014 -0.9974
-0.1023 -2.1253 -20.2960 0.9963 -0.0261 0.0817
-0.2938 18.3518 -2.6496 -0.0256 -0.9760 0.2161
-0.3825 15.3368 11.4922 -0.6823 -0.7190 0.1325
0.2130 -15.3125 -11.5278 0.6838 0.7206 -0.1151
0.3018 -18.2242 -3.6427 0.3279 0.9260 -0.1873
0.4198 -13.6093 13.7801 -0.5506 0.8013 -0.2339
-1.4325 13.5472 -13.4256 0.5339 -0.7771 0.3333
