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#$Date: 2024-09-06 03:17:00 +0300 (Fri, 06 Sep 2024) $
#$Revision: 294520 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/89/7248967.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7248967
loop_
_publ_author_name
'Prętka, Dominika'
'Marcinkowski, Dawid'
'Siwiak, Agnieszka'
'Kubicki, Maciej'
'Consiglio, Giuseppe'
'Patroniak, Violetta'
'Gorczyński, Adam'
_publ_section_title
;
 Crystal engineering of monometallic lanthanide(iii) supramolecular
 systems within the N3-tridentate hydrazone Schiff-base ligand
;
_journal_issue                   31
_journal_name_full               CrystEngComm
_journal_page_first              4167
_journal_page_last               4180
_journal_paper_doi               10.1039/D4CE00450G
_journal_volume                  26
_journal_year                    2024
_chemical_formula_moiety         'C11 H15 Eu N8 O10, C H4 O'
_chemical_formula_sum            'C12 H19 Eu N8 O11'
_chemical_formula_weight         603.31
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2016-01-10 deposited with the CCDC.	2024-07-03 downloaded from the CCDC.
;
_cell_angle_alpha                98.188(6)
_cell_angle_beta                 97.531(4)
_cell_angle_gamma                100.576(5)
_cell_formula_units_Z            2
_cell_length_a                   8.1426(4)
_cell_length_b                   10.4679(8)
_cell_length_c                   12.4743(7)
_cell_measurement_reflns_used    3575
_cell_measurement_temperature    120(1)
_cell_measurement_theta_max      27.8100
_cell_measurement_theta_min      3.3990
_cell_volume                     1020.95(11)
_computing_cell_refinement       'CrysAlis Pro (Agilent Technologies (2011))'
_computing_data_collection       'CrysAlis Pro (Agilent Technologies (2011))'
_computing_data_reduction        'CrysAlis Pro (Agilent Technologies (2011))'
_computing_molecular_graphics    'Mercury (MacRae et al., 2009)'
_computing_publication_material  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SIR92 (Altomare et al., 1993)'
_diffrn_ambient_temperature      120(1)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.1544
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.840
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Eos'
_diffrn_measurement_method       ω-scan
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_unetI/netI     0.0405
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.840
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            4237
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.840
_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         28.255
_diffrn_reflns_theta_min         2.837
_exptl_absorpt_coefficient_mu    3.144
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.70610
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.963
_exptl_crystal_description       plate
_exptl_crystal_F_000             596
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.05
_refine_diff_density_max         2.474
_refine_diff_density_min         -1.892
_refine_diff_density_rms         0.146
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.074
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     293
_refine_ls_number_reflns         4237
_refine_ls_number_restraints     7
_refine_ls_restrained_S_all      1.081
_refine_ls_R_factor_all          0.0391
_refine_ls_R_factor_gt           0.0353
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0277P)²+5.0296P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0807
_refine_ls_wR_factor_ref         0.0828
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3940
_reflns_number_total             4237
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d4ce00450g2.cif
_cod_data_source_block           16
_cod_depositor_comments
'Adding full bibliography for 7248946--7248974.cif.'
_cod_database_code               7248967
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.30069(3) 0.76876(2) 0.28936(2) 0.01533(8) Uani 1 1 d . . . . .
N1A N 0.0470(5) 0.6946(4) 0.3818(3) 0.0174(8) Uani 1 1 d . . . . .
C2A C -0.0139(6) 0.7834(5) 0.4464(4) 0.0212(10) Uani 1 1 d . . . . .
H2A H 0.0434 0.8731 0.4583 0.025 Uiso 1 1 calc R U . . .
C3A C -0.1531(6) 0.7525(5) 0.4958(4) 0.0230(11) Uani 1 1 d . . . . .
H3A H -0.1931 0.8188 0.5391 0.028 Uiso 1 1 calc R U . . .
C4A C -0.2341(6) 0.6201(6) 0.4802(4) 0.0235(11) Uani 1 1 d . . . . .
H4A H -0.3288 0.5944 0.5152 0.028 Uiso 1 1 calc R U . . .
C5A C -0.1771(6) 0.5282(5) 0.4150(4) 0.0207(10) Uani 1 1 d . . . . .
H5A H -0.2314 0.4378 0.4037 0.025 Uiso 1 1 calc R U . . .
C6A C -0.0367(5) 0.5687(5) 0.3645(4) 0.0150(9) Uani 1 1 d . . . . .
N7A N 0.0236(5) 0.4776(4) 0.2954(3) 0.0178(8) Uani 1 1 d . . . . .
C71A C -0.0607(6) 0.3404(5) 0.2633(4) 0.0201(10) Uani 1 1 d . . . . .
H71C H -0.0460 0.3085 0.1881 0.030 Uiso 1 1 calc R U . . .
H71B H -0.1816 0.3317 0.2669 0.030 Uiso 1 1 calc R U . . .
H71A H -0.0115 0.2880 0.3131 0.030 Uiso 1 1 calc R U . . .
N8A N 0.1777(5) 0.5219(4) 0.2668(3) 0.0166(8) Uani 1 1 d . . . . .
C9A C 0.2586(6) 0.4391(5) 0.2218(4) 0.0172(9) Uani 1 1 d . . . . .
H9A H 0.2148 0.3466 0.2074 0.021 Uiso 1 1 calc R U . . .
C10A C 0.4207(6) 0.4965(5) 0.1949(4) 0.0185(10) Uani 1 1 d . . . . .
N11A N 0.5177(5) 0.4287(4) 0.1378(3) 0.0202(9) Uani 1 1 d . . . . .
C11A C 0.4795(7) 0.2874(5) 0.0948(5) 0.0290(12) Uani 1 1 d . . . . .
H11C H 0.4929 0.2383 0.1556 0.043 Uiso 1 1 calc R U . . .
H11B H 0.5573 0.2677 0.0440 0.043 Uiso 1 1 calc R U . . .
H11A H 0.3627 0.2612 0.0559 0.043 Uiso 1 1 calc R U . . .
C12A C 0.6578(6) 0.5190(5) 0.1279(4) 0.0232(11) Uani 1 1 d . . . . .
H12A H 0.7491 0.5017 0.0917 0.028 Uiso 1 1 calc R U . . .
C13A C 0.6408(6) 0.6374(5) 0.1794(4) 0.0229(11) Uani 1 1 d . . . . .
H13A H 0.7204 0.7178 0.1859 0.028 Uiso 1 1 calc R U . . .
N14A N 0.4924(5) 0.6243(4) 0.2206(3) 0.0184(8) Uani 1 1 d . . . . .
N1B N 0.2298(6) 1.0190(5) 0.2347(4) 0.0320(11) Uani 1 1 d . . . . .
O11B O 0.1991(5) 0.9776(4) 0.3228(3) 0.0341(9) Uani 1 1 d . . . . .
O12B O 0.3110(5) 0.9548(4) 0.1752(3) 0.0267(8) Uani 1 1 d . . . . .
O13B O 0.1803(7) 1.1159(5) 0.2087(5) 0.0576(14) Uani 1 1 d . . . . .
N1C N 0.0733(5) 0.6939(5) 0.0750(3) 0.0258(10) Uani 1 1 d . . . . .
O11C O 0.0270(4) 0.7416(4) 0.1640(3) 0.0245(8) Uani 1 1 d . . . . .
O12C O 0.2262(4) 0.6815(4) 0.0838(3) 0.0229(7) Uani 1 1 d . . . . .
O13C O -0.0247(5) 0.6608(5) -0.0107(3) 0.0446(12) Uani 1 1 d . . . . .
N1D N 0.4149(5) 0.7741(4) 0.5270(3) 0.0230(9) Uani 1 1 d . . . . .
O11D O 0.3713(4) 0.8751(3) 0.4933(3) 0.0238(8) Uani 1 1 d . . . . .
O12D O 0.4070(4) 0.6758(4) 0.4544(3) 0.0221(7) Uani 1 1 d . . . . .
O13D O 0.4587(5) 0.7738(4) 0.6246(3) 0.0364(10) Uani 1 1 d . . . . .
O1E O 0.5800(4) 0.9108(4) 0.3363(3) 0.0251(8) Uani 1 1 d . . . . .
H2E H 0.6410 0.9403 0.2946 0.030 Uiso 1 1 d R U . . .
H1E H 0.5938 0.9638 0.3839 0.030 Uiso 1 1 d R U . . .
O1F O 0.7900(16) 1.0026(10) 0.2123(8) 0.171(5) Uani 1 1 d D U . . .
H1F H 0.8945 1.0192 0.2357 0.205 Uiso 1 1 calc R U . . .
C1F C 0.7623(18) 1.0046(12) 0.0971(9) 0.147(7) Uani 1 1 d D . . . .
H1F3 H 0.7612 1.0949 0.0850 0.221 Uiso 1 1 calc R U . . .
H1F2 H 0.6533 0.9470 0.0635 0.221 Uiso 1 1 calc R U . . .
H1F1 H 0.8533 0.9732 0.0639 0.221 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1E Eu1 O11B 84.30(13) . . ?
O1E Eu1 O11C 140.78(13) . . ?
O11B Eu1 O11C 72.33(13) . . ?
O1E Eu1 N14A 76.25(12) . . ?
O11B Eu1 N14A 154.91(13) . . ?
O11C Eu1 N14A 113.99(12) . . ?
O1E Eu1 O12D 81.89(12) . . ?
O11B Eu1 O12D 117.56(12) . . ?
O11C Eu1 O12D 136.78(11) . . ?
N14A Eu1 O12D 75.57(12) . . ?
O1E Eu1 N1A 138.85(12) . . ?
O11B Eu1 N1A 79.70(13) . . ?
O11C Eu1 N1A 67.96(12) . . ?
N14A Eu1 N1A 125.39(13) . . ?
O12D Eu1 N1A 72.69(12) . . ?
O1E Eu1 O12C 111.46(11) . . ?
O11B Eu1 O12C 107.07(13) . . ?
O11C Eu1 O12C 50.60(11) . . ?
N14A Eu1 O12C 66.83(12) . . ?
O12D Eu1 O12C 134.62(11) . . ?
N1A Eu1 O12C 109.45(12) . . ?
O1E Eu1 N8A 136.50(12) . . ?
O11B Eu1 N8A 137.48(13) . . ?
O11C Eu1 N8A 77.09(12) . . ?
N14A Eu1 N8A 65.94(12) . . ?
O12D Eu1 N8A 68.87(12) . . ?
N1A Eu1 N8A 61.59(12) . . ?
O12C Eu1 N8A 73.09(12) . . ?
O1E Eu1 O12B 71.51(12) . . ?
O11B Eu1 O12B 50.71(12) . . ?
O11C Eu1 O12B 69.30(12) . . ?
N14A Eu1 O12B 107.10(12) . . ?
O12D Eu1 O12B 151.39(12) . . ?
N1A Eu1 O12B 121.87(12) . . ?
O12C Eu1 O12B 67.62(12) . . ?
N8A Eu1 O12B 138.98(12) . . ?
O1E Eu1 O11D 67.42(12) . . ?
O11B Eu1 O11D 68.40(13) . . ?
O11C Eu1 O11D 127.21(11) . . ?
N14A Eu1 O11D 116.66(12) . . ?
O12D Eu1 O11D 50.07(11) . . ?
N1A Eu1 O11D 71.45(12) . . ?
O12C Eu1 O11D 175.30(11) . . ?
N8A Eu1 O11D 111.00(12) . . ?
O12B Eu1 O11D 107.89(11) . . ?
O1E Eu1 N1B 78.49(13) . . ?
O11B Eu1 N1B 25.47(13) . . ?
O11C Eu1 N1B 66.80(13) . . ?
N14A Eu1 N1B 132.08(13) . . ?
O12D Eu1 N1B 139.20(13) . . ?
N1A Eu1 N1B 100.15(13) . . ?
O12C Eu1 N1B 86.04(13) . . ?
N8A Eu1 N1B 143.74(13) . . ?
O12B Eu1 N1B 25.37(12) . . ?
O11D Eu1 N1B 89.27(13) . . ?
O1E Eu1 N1C 129.17(12) . . ?
O11B Eu1 N1C 89.87(14) . . ?
O11C Eu1 N1C 25.40(11) . . ?
N14A Eu1 N1C 90.27(13) . . ?
O12D Eu1 N1C 142.15(12) . . ?
N1A Eu1 N1C 88.65(12) . . ?
O12C Eu1 N1C 25.20(11) . . ?
N8A Eu1 N1C 73.30(13) . . ?
O12B Eu1 N1C 66.20(12) . . ?
O11D Eu1 N1C 152.45(12) . . ?
N1B Eu1 N1C 75.35(14) . . ?
C6A N1A C2A 117.2(4) . . ?
C6A N1A Eu1 122.3(3) . . ?
C2A N1A Eu1 120.5(3) . . ?
N1A C2A C3A 124.2(5) . . ?
N1A C2A H2A 117.9 . . ?
C3A C2A H2A 117.9 . . ?
C2A C3A C4A 117.6(5) . . ?
C2A C3A H3A 121.2 . . ?
C4A C3A H3A 121.2 . . ?
C5A C4A C3A 119.8(5) . . ?
C5A C4A H4A 120.1 . . ?
C3A C4A H4A 120.1 . . ?
C4A C5A C6A 119.0(5) . . ?
C4A C5A H5A 120.5 . . ?
C6A C5A H5A 120.5 . . ?
N1A C6A N7A 117.2(4) . . ?
N1A C6A C5A 122.2(4) . . ?
N7A C6A C5A 120.7(4) . . ?
N8A N7A C6A 115.9(4) . . ?
N8A N7A C71A 120.6(4) . . ?
C6A N7A C71A 123.2(4) . . ?
N7A C71A H71C 109.5 . . ?
N7A C71A H71B 109.5 . . ?
H71C C71A H71B 109.5 . . ?
N7A C71A H71A 109.5 . . ?
H71C C71A H71A 109.5 . . ?
H71B C71A H71A 109.5 . . ?
C9A N8A N7A 120.1(4) . . ?
C9A N8A Eu1 119.0(3) . . ?
N7A N8A Eu1 120.8(3) . . ?
N8A C9A C10A 115.5(4) . . ?
N8A C9A H9A 122.2 . . ?
C10A C9A H9A 122.2 . . ?
N14A C10A N11A 110.9(4) . . ?
N14A C10A C9A 124.2(4) . . ?
N11A C10A C9A 124.8(4) . . ?
C10A N11A C12A 106.6(4) . . ?
C10A N11A C11A 126.6(4) . . ?
C12A N11A C11A 126.8(4) . . ?
N11A C11A H11C 109.5 . . ?
N11A C11A H11B 109.5 . . ?
H11C C11A H11B 109.5 . . ?
N11A C11A H11A 109.5 . . ?
H11C C11A H11A 109.5 . . ?
H11B C11A H11A 109.5 . . ?
C13A C12A N11A 106.8(4) . . ?
C13A C12A H12A 126.6 . . ?
N11A C12A H12A 126.6 . . ?
C12A C13A N14A 110.0(5) . . ?
C12A C13A H13A 125.0 . . ?
N14A C13A H13A 125.0 . . ?
C10A N14A C13A 105.7(4) . . ?
C10A N14A Eu1 114.3(3) . . ?
C13A N14A Eu1 138.4(3) . . ?
O13B N1B O12B 121.8(5) . . ?
O13B N1B O11B 121.3(5) . . ?
O12B N1B O11B 116.9(4) . . ?
O13B N1B Eu1 172.3(4) . . ?
O12B N1B Eu1 60.7(3) . . ?
O11B N1B Eu1 56.7(2) . . ?
N1B O11B Eu1 97.9(3) . . ?
N1B O12B Eu1 93.9(3) . . ?
O13C N1C O12C 122.9(5) . . ?
O13C N1C O11C 121.6(4) . . ?
O12C N1C O11C 115.4(4) . . ?
O13C N1C Eu1 177.4(4) . . ?
O12C N1C Eu1 58.9(2) . . ?
O11C N1C Eu1 56.5(2) . . ?
N1C O11C Eu1 98.1(3) . . ?
N1C O12C Eu1 95.9(3) . . ?
O13D N1D O12D 122.4(5) . . ?
O13D N1D O11D 121.4(4) . . ?
O12D N1D O11D 116.2(4) . . ?
O13D N1D Eu1 178.5(3) . . ?
O12D N1D Eu1 56.8(2) . . ?
O11D N1D Eu1 59.4(2) . . ?
N1D O11D Eu1 95.2(3) . . ?
N1D O12D Eu1 98.5(3) . . ?
Eu1 O1E H2E 128.0 . . ?
Eu1 O1E H1E 117.0 . . ?
H2E O1E H1E 104.9 . . ?
C1F O1F H1F 109.5 . . ?
O1F C1F H1F3 109.5 . . ?
O1F C1F H1F2 109.5 . . ?
H1F3 C1F H1F2 109.5 . . ?
O1F C1F H1F1 109.5 . . ?
H1F3 C1F H1F1 109.5 . . ?
H1F2 C1F H1F1 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1E 2.426(3) . ?
Eu1 O11B 2.476(4) . ?
Eu1 O11C 2.494(3) . ?
Eu1 N14A 2.511(4) . ?
Eu1 O12D 2.519(3) . ?
Eu1 N1A 2.547(4) . ?
Eu1 O12C 2.549(3) . ?
Eu1 N8A 2.555(4) . ?
Eu1 O12B 2.567(4) . ?
Eu1 O11D 2.572(3) . ?
Eu1 N1B 2.936(5) . ?
Eu1 N1C 2.961(4) . ?
N1A C6A 1.341(6) . ?
N1A C2A 1.349(6) . ?
C2A C3A 1.369(7) . ?
C2A H2A 0.9500 . ?
C3A C4A 1.396(8) . ?
C3A H3A 0.9500 . ?
C4A C5A 1.358(7) . ?
C4A H4A 0.9500 . ?
C5A C6A 1.404(6) . ?
C5A H5A 0.9500 . ?
C6A N7A 1.393(6) . ?
N7A N8A 1.366(5) . ?
N7A C71A 1.448(6) . ?
C71A H71C 0.9800 . ?
C71A H71B 0.9800 . ?
C71A H71A 0.9800 . ?
N8A C9A 1.292(6) . ?
C9A C10A 1.448(6) . ?
C9A H9A 0.9500 . ?
C10A N14A 1.333(6) . ?
C10A N11A 1.358(6) . ?
N11A C12A 1.373(7) . ?
N11A C11A 1.461(7) . ?
C11A H11C 0.9800 . ?
C11A H11B 0.9800 . ?
C11A H11A 0.9800 . ?
C12A C13A 1.351(7) . ?
C12A H12A 0.9500 . ?
C13A N14A 1.367(6) . ?
C13A H13A 0.9500 . ?
N1B O13B 1.228(6) . ?
N1B O12B 1.261(6) . ?
N1B O11B 1.275(6) . ?
N1C O13C 1.212(6) . ?
N1C O12C 1.267(5) . ?
N1C O11C 1.283(5) . ?
N1D O13D 1.224(5) . ?
N1D O12D 1.256(5) . ?
N1D O11D 1.283(6) . ?
O1E H2E 0.8178 . ?
O1E H1E 0.7343 . ?
O1F C1F 1.428(5) . ?
O1F H1F 0.8400 . ?
C1F H1F3 0.9800 . ?
C1F H1F2 0.9800 . ?
C1F H1F1 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6A N1A C2A C3A 0.9(7) . . . . ?
Eu1 N1A C2A C3A 177.6(4) . . . . ?
N1A C2A C3A C4A 1.6(8) . . . . ?
C2A C3A C4A C5A -2.1(7) . . . . ?
C3A C4A C5A C6A 0.1(7) . . . . ?
C2A N1A C6A N7A 178.4(4) . . . . ?
Eu1 N1A C6A N7A 1.8(5) . . . . ?
C2A N1A C6A C5A -3.0(6) . . . . ?
Eu1 N1A C6A C5A -179.6(3) . . . . ?
C4A C5A C6A N1A 2.5(7) . . . . ?
C4A C5A C6A N7A -178.9(4) . . . . ?
N1A C6A N7A N8A 10.3(6) . . . . ?
C5A C6A N7A N8A -168.3(4) . . . . ?
N1A C6A N7A C71A -175.6(4) . . . . ?
C5A C6A N7A C71A 5.8(7) . . . . ?
C6A N7A N8A C9A 166.3(4) . . . . ?
C71A N7A N8A C9A -8.0(6) . . . . ?
C6A N7A N8A Eu1 -17.8(5) . . . . ?
C71A N7A N8A Eu1 167.9(3) . . . . ?
N7A N8A C9A C10A -179.9(4) . . . . ?
Eu1 N8A C9A C10A 4.1(5) . . . . ?
N8A C9A C10A N14A 5.0(7) . . . . ?
N8A C9A C10A N11A -173.2(4) . . . . ?
N14A C10A N11A C12A 0.3(5) . . . . ?
C9A C10A N11A C12A 178.6(4) . . . . ?
N14A C10A N11A C11A -179.3(5) . . . . ?
C9A C10A N11A C11A -0.9(8) . . . . ?
C10A N11A C12A C13A 0.3(5) . . . . ?
C11A N11A C12A C13A 179.8(5) . . . . ?
N11A C12A C13A N14A -0.7(6) . . . . ?
N11A C10A N14A C13A -0.7(5) . . . . ?
C9A C10A N14A C13A -179.1(5) . . . . ?
N11A C10A N14A Eu1 167.4(3) . . . . ?
C9A C10A N14A Eu1 -11.0(6) . . . . ?
C12A C13A N14A C10A 0.8(6) . . . . ?
C12A C13A N14A Eu1 -162.6(4) . . . . ?
O13B N1B O11B Eu1 171.2(5) . . . . ?
O12B N1B O11B Eu1 -7.8(5) . . . . ?
O13B N1B O12B Eu1 -171.6(5) . . . . ?
O11B N1B O12B Eu1 7.4(5) . . . . ?
O13C N1C O11C Eu1 177.8(5) . . . . ?
O12C N1C O11C Eu1 -0.7(5) . . . . ?
O13C N1C O12C Eu1 -177.8(5) . . . . ?
O11C N1C O12C Eu1 0.6(4) . . . . ?
O13D N1D O11D Eu1 -178.5(4) . . . . ?
O12D N1D O11D Eu1 0.4(4) . . . . ?
O13D N1D O12D Eu1 178.4(4) . . . . ?
O11D N1D O12D Eu1 -0.4(4) . . . . ?
