#------------------------------------------------------------------------------
#$Date: 2025-01-19 03:53:24 +0200 (Sun, 19 Jan 2025) $
#$Revision: 297380 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/97/7249794.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7249794
loop_
_publ_author_name
'Sobczak, Paulina'
'Sierański, Tomasz'
'Świątkowski, Marcin'
'Trzęsowska-Kruszyńska, Agata'
'Kolińska, Jolanta'
_publ_section_title
;
 Unraveling the structure--property relationships in fluorescent
 phenylhydrazones: the role of substituents and molecular interactions
;
_journal_issue                   3
_journal_name_full               'RSC Advances'
_journal_page_first              1514
_journal_page_last               1526
_journal_paper_doi               10.1039/D4RA07856J
_journal_volume                  15
_journal_year                    2025
_chemical_formula_moiety         'C14 H14 N2 O2'
_chemical_formula_sum            'C14 H14 N2 O2'
_chemical_formula_weight         242.27
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_audit_creation_date             2023-12-07
_audit_creation_method
;
Olex2 1.5-ac5-024
(compiled 2022.04.12 svn.rca3783a0 for Rigaku Oxford Diffraction, GUI svn.r6498)
;
_audit_update_record
;
2024-04-23 deposited with the CCDC.	2025-01-10 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 95.511(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   26.7493(5)
_cell_length_b                   5.80660(10)
_cell_length_c                   7.7294(2)
_cell_measurement_reflns_used    7990
_cell_measurement_temperature    99.9(5)
_cell_measurement_theta_max      78.8700
_cell_measurement_theta_min      4.9560
_cell_volume                     1195.00(4)
_computing_cell_refinement       'CrysAlisPro 1.171.42.96a (Rigaku OD, 2023)'
_computing_data_collection       'CrysAlisPro 1.171.42.96a (Rigaku OD, 2023)'
_computing_data_reduction        'CrysAlisPro 1.171.42.96a (Rigaku OD, 2023)'
_computing_molecular_graphics    'Olex2 1.5-ac5-024 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5-ac5-024 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      99.9(5)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 5.8140
_diffrn_detector_type            'Pilatus 300K'
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.932
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω   -119.00 -72.00   0.50    0.20    --  -48.87-126.00 -82.00   94
  2  ω   -120.00 -33.00   0.50    0.20    --  -48.87 -57.00 -60.00  174
  3  ω    -26.00  27.00   0.50    0.20    --  -48.87  19.00 -60.00  106
  4  ω    -26.00  27.00   0.50    0.20    --  -48.87  19.00 -90.00  106
  5  ω    -27.00  26.00   0.50    0.20    --   48.87 -19.00  90.00  106
  6  ω    -27.00  26.00   0.50    0.20    --   48.87 -19.00 -60.00  106
  7  ω    -43.00 -13.00   0.50    0.60    --  -88.50  38.00  90.00   60
  8  ω    -43.00 -13.00   0.50    0.60    --  -88.50  38.00   0.00   60
  9  ω    -66.00 -17.00   0.50    0.60    --  -88.50  57.00 -90.00   98
 10  ω    -43.00 -13.00   0.50    0.60    --  -88.50  38.00 120.00   60
 11  ω    -43.00 -13.00   0.50    0.60    --  -88.50  38.00 150.00   60
 12  ω   -164.00 -75.00   0.50    0.60    --  -88.50 -38.00 -30.00  178
 13  ω    -43.00 -13.00   0.50    0.60    --  -88.50  38.00 -30.00   60
 14  ω   -105.00 -22.00   0.50    0.60    --  -88.50  77.00 120.00  166
 15  ω    -43.00 -13.00   0.50    0.60    --  -88.50  38.00 -60.00   60
 16  ω    -43.00 -13.00   0.50    0.60    --  -88.50  38.00  60.00   60
 17  ω     38.00  66.00   0.50    0.60    --  110.00 -57.00 -90.00   56
 18  ω     38.00  66.00   0.50    0.60    --  110.00 -57.00 -60.00   56
 19  ω     38.00  66.00   0.50    0.60    --  110.00 -57.00  90.00   56
 20  ω     38.00  66.00   0.50    0.60    --  110.00 -57.00 -30.00   56
 21  ω     38.00  66.00   0.50    0.60    --  110.00 -57.00-120.00   56
 22  ω     45.00 105.00   0.50    0.60    --  110.00 -77.00-150.00  120
 23  ω     97.00 178.00   0.50    0.60    --  110.00  19.00-120.00  162
 24  ω     41.00 106.00   0.50    0.60    --  110.00 -99.00-150.00  130
 25  ω   -114.00 -25.00   0.50    0.20    --  -48.87 -77.00 150.00  178
 26  ω   -114.00 -25.00   0.50    0.20    --  -48.87 -77.00-120.00  178
 27  ω   -114.00 -25.00   0.50    0.20    --  -48.87 -77.00  30.00  178
 28  ω     62.00  87.00   0.50    0.20    --   48.87 178.00 -90.00   50
 29  ω     25.00 114.00   0.50    0.20    --   48.87  77.00  90.00  178
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, Pilatus 300K'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0416635000
_diffrn_orient_matrix_UB_12      -0.0568027000
_diffrn_orient_matrix_UB_13      -0.1176969000
_diffrn_orient_matrix_UB_21      -0.0399277000
_diffrn_orient_matrix_UB_22      -0.0847538000
_diffrn_orient_matrix_UB_23      -0.1426883000
_diffrn_orient_matrix_UB_31      -0.0041601000
_diffrn_orient_matrix_UB_32      0.2448912000
_diffrn_orient_matrix_UB_33      -0.0767636000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0265
_diffrn_reflns_av_unetI/netI     0.0189
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.932
_diffrn_reflns_limit_h_max       32
_diffrn_reflns_limit_h_min       -32
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -5
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_number            12265
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.932
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         79.447
_diffrn_reflns_theta_min         4.983
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'PhotonJet (Cu) X-ray Source'
_exptl_absorpt_coefficient_mu    0.744
_exptl_absorpt_correction_T_max  0.956
_exptl_absorpt_correction_T_min  0.889
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.42.96a (Rigaku Oxford Diffraction, 2023)
Analytical numeric absorption correction using a multifaceted crystal
model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.347
_exptl_crystal_description       prism
_exptl_crystal_F_000             512
_exptl_crystal_size_max          0.176
_exptl_crystal_size_mid          0.126
_exptl_crystal_size_min          0.054
_refine_diff_density_max         0.276
_refine_diff_density_min         -0.262
_refine_diff_density_rms         0.058
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.198
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     170
_refine_ls_number_reflns         2425
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.198
_refine_ls_R_factor_all          0.0511
_refine_ls_R_factor_gt           0.0478
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0258P)²+1.8792P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1290
_refine_ls_wR_factor_ref         0.1303
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2211
_reflns_number_total             2425
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d4ra07856j2.cif
_cod_data_source_block           ps_dok59
_cod_database_code               7249794
_shelx_shelxl_version_number     2018/3
_chemical_oxdiff_formula         'C14 H14 N2 O2'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.961
_shelx_estimated_absorpt_t_min   0.880
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All N(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C8(H8), C3(H3), C6(H6), C4(H4), C14(H14), C7(H7), C11(H11), C13(H13), C12(H12)
2.b Idealised Me refined as rotating group:
 C1(H1A,H1B,H1C)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
- Detector area scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.500
_oxdiff_exptl_absorpt_empirical_full_min 0.757
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O2 O 0.19865(6) -0.1283(3) 0.6295(2) 0.0220(3) Uani 1 1 d . . . . .
H2 H 0.2191(10) -0.006(5) 0.667(4) 0.033 Uiso 1 1 d . U . . .
O1 O 0.44523(5) 0.5420(3) 0.59985(19) 0.0207(3) Uani 1 1 d . . . . .
N2 N 0.22136(6) 0.2848(3) 0.7553(2) 0.0184(4) Uani 1 1 d . . . . .
N1 N 0.25270(7) 0.4591(3) 0.8116(2) 0.0197(4) Uani 1 1 d . . . . .
H1 H 0.2381(9) 0.587(5) 0.846(3) 0.024 Uiso 1 1 d . U . . .
C10 C 0.14977(8) -0.0730(4) 0.6479(3) 0.0190(4) Uani 1 1 d . . . . .
C5 C 0.30085(8) 0.4777(4) 0.7539(3) 0.0178(4) Uani 1 1 d . . . . .
C8 C 0.17435(8) 0.3117(4) 0.7767(3) 0.0185(4) Uani 1 1 d . . . . .
H8 H 0.163900 0.449672 0.828585 0.022 Uiso 1 1 calc R U . . .
C3 C 0.36998(8) 0.3355(4) 0.6069(3) 0.0195(4) Uani 1 1 d . . . . .
H3 H 0.384058 0.220041 0.539240 0.023 Uiso 1 1 calc R U . . .
C9 C 0.13708(8) 0.1372(4) 0.7240(3) 0.0182(4) Uani 1 1 d . . . . .
C6 C 0.32887(8) 0.6725(4) 0.8043(3) 0.0194(4) Uani 1 1 d . . . . .
H6 H 0.314876 0.787758 0.872368 0.023 Uiso 1 1 calc R U . . .
C2 C 0.39795(8) 0.5309(4) 0.6571(3) 0.0180(4) Uani 1 1 d . . . . .
C4 C 0.32164(8) 0.3085(4) 0.6553(3) 0.0189(4) Uani 1 1 d . . . . .
H4 H 0.302774 0.174741 0.621039 0.023 Uiso 1 1 calc R U . . .
C14 C 0.08629(8) 0.1792(4) 0.7431(3) 0.0204(4) Uani 1 1 d . . . . .
H14 H 0.077069 0.318394 0.796387 0.024 Uiso 1 1 calc R U . . .
C7 C 0.37740(8) 0.6995(4) 0.7554(3) 0.0195(4) Uani 1 1 d . . . . .
H7 H 0.396297 0.833309 0.789391 0.023 Uiso 1 1 calc R U . . .
C11 C 0.11254(8) -0.2285(4) 0.5879(3) 0.0218(5) Uani 1 1 d . . . . .
H11 H 0.121346 -0.368012 0.534135 0.026 Uiso 1 1 calc R U . . .
C13 C 0.04932(8) 0.0230(4) 0.6864(3) 0.0231(5) Uani 1 1 d . . . . .
H13 H 0.015154 0.053982 0.701787 0.028 Uiso 1 1 calc R U . . .
C12 C 0.06252(8) -0.1801(4) 0.6064(3) 0.0230(5) Uani 1 1 d . . . . .
H12 H 0.037155 -0.286082 0.564247 0.028 Uiso 1 1 calc R U . . .
C1 C 0.47434(8) 0.7417(4) 0.6482(3) 0.0247(5) Uani 1 1 d . . . . .
H1A H 0.457604 0.878360 0.595635 0.037 Uiso 1 1 calc R U . . .
H1B H 0.507737 0.726478 0.607262 0.037 Uiso 1 1 calc R U . . .
H1C H 0.477684 0.757517 0.775056 0.037 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
7 1 4 0.0522
5 3 2 0.0568
-15 2 2 0.0383
15 0 -3 0.0477
-15 -1 3 0.0484
-10 3 0 0.0608
4 3 -2 0.0842
12 -3 -1 0.0693
-1 -3 2 0.0985
-7 0 -4 0.0383
-7 -2 -3 0.0535
6 -1 4 0.0672
17 0 0 0.0352
-17 0 0 0.0171
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C10 O2 H2 109.2(17) . . ?
C2 O1 C1 116.57(17) . . ?
C8 N2 N1 116.55(18) . . ?
N2 N1 H1 116.1(16) . . ?
N2 N1 C5 120.76(18) . . ?
C5 N1 H1 118.1(17) . . ?
O2 C10 C9 121.16(19) . . ?
O2 C10 C11 118.31(19) . . ?
C11 C10 C9 120.53(19) . . ?
C6 C5 N1 117.31(19) . . ?
C6 C5 C4 119.62(19) . . ?
C4 C5 N1 123.04(19) . . ?
N2 C8 H8 119.0 . . ?
N2 C8 C9 122.0(2) . . ?
C9 C8 H8 119.0 . . ?
C2 C3 H3 119.8 . . ?
C4 C3 H3 119.8 . . ?
C4 C3 C2 120.4(2) . . ?
C10 C9 C8 122.31(19) . . ?
C14 C9 C10 117.97(19) . . ?
C14 C9 C8 119.69(19) . . ?
C5 C6 H6 119.8 . . ?
C5 C6 C7 120.4(2) . . ?
C7 C6 H6 119.8 . . ?
O1 C2 C3 115.61(19) . . ?
O1 C2 C7 124.53(19) . . ?
C7 C2 C3 119.85(19) . . ?
C5 C4 H4 120.0 . . ?
C3 C4 C5 119.94(19) . . ?
C3 C4 H4 120.0 . . ?
C9 C14 H14 119.2 . . ?
C13 C14 C9 121.6(2) . . ?
C13 C14 H14 119.2 . . ?
C6 C7 H7 120.1 . . ?
C2 C7 C6 119.8(2) . . ?
C2 C7 H7 120.1 . . ?
C10 C11 H11 120.0 . . ?
C12 C11 C10 120.0(2) . . ?
C12 C11 H11 120.0 . . ?
C14 C13 H13 120.2 . . ?
C14 C13 C12 119.5(2) . . ?
C12 C13 H13 120.2 . . ?
C11 C12 C13 120.4(2) . . ?
C11 C12 H12 119.8 . . ?
C13 C12 H12 119.8 . . ?
O1 C1 H1A 109.5 . . ?
O1 C1 H1B 109.5 . . ?
O1 C1 H1C 109.5 . . ?
H1A C1 H1B 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O2 H2 0.93(3) . ?
O2 C10 1.367(3) . ?
O1 C2 1.381(2) . ?
O1 C1 1.427(3) . ?
N2 N1 1.359(2) . ?
N2 C8 1.293(3) . ?
N1 H1 0.89(3) . ?
N1 C5 1.407(3) . ?
C10 C9 1.410(3) . ?
C10 C11 1.391(3) . ?
C5 C6 1.392(3) . ?
C5 C4 1.392(3) . ?
C8 H8 0.9500 . ?
C8 C9 1.452(3) . ?
C3 H3 0.9500 . ?
C3 C2 1.394(3) . ?
C3 C4 1.389(3) . ?
C9 C14 1.402(3) . ?
C6 H6 0.9500 . ?
C6 C7 1.395(3) . ?
C2 C7 1.385(3) . ?
C4 H4 0.9500 . ?
C14 H14 0.9500 . ?
C14 C13 1.382(3) . ?
C7 H7 0.9500 . ?
C11 H11 0.9500 . ?
C11 C12 1.388(3) . ?
C13 H13 0.9500 . ?
C13 C12 1.393(3) . ?
C12 H12 0.9500 . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O2 C10 C9 C8 3.9(3) . . . . ?
O2 C10 C9 C14 -178.19(18) . . . . ?
O2 C10 C11 C12 179.10(19) . . . . ?
O1 C2 C7 C6 179.05(19) . . . . ?
N2 N1 C5 C6 174.05(18) . . . . ?
N2 N1 C5 C4 -8.1(3) . . . . ?
N2 C8 C9 C10 0.7(3) . . . . ?
N2 C8 C9 C14 -177.17(19) . . . . ?
N1 N2 C8 C9 -179.30(18) . . . . ?
N1 C5 C6 C7 178.42(19) . . . . ?
N1 C5 C4 C3 -178.19(19) . . . . ?
C10 C9 C14 C13 -1.3(3) . . . . ?
C10 C11 C12 C13 -0.6(3) . . . . ?
C5 C6 C7 C2 -0.4(3) . . . . ?
C8 N2 N1 C5 -162.61(19) . . . . ?
C8 C9 C14 C13 176.6(2) . . . . ?
C3 C2 C7 C6 0.3(3) . . . . ?
C9 C10 C11 C12 -1.6(3) . . . . ?
C9 C14 C13 C12 -0.7(3) . . . . ?
C6 C5 C4 C3 -0.4(3) . . . . ?
C2 C3 C4 C5 0.2(3) . . . . ?
C4 C5 C6 C7 0.5(3) . . . . ?
C4 C3 C2 O1 -179.05(18) . . . . ?
C4 C3 C2 C7 -0.2(3) . . . . ?
C14 C13 C12 C11 1.7(3) . . . . ?
C11 C10 C9 C8 -175.38(19) . . . . ?
C11 C10 C9 C14 2.5(3) . . . . ?
C1 O1 C2 C3 179.38(18) . . . . ?
C1 O1 C2 C7 0.6(3) . . . . ?
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
7.3709 0.6708 4.2288 -0.2287 -0.9546 -0.1910
5.4944 3.2029 1.9553 -0.1831 -0.7698 0.6114
-14.6981 1.8180 1.5349 -0.8963 0.2138 0.3885
15.1494 0.3016 -2.8277 0.9469 -0.2270 0.2279
-14.5450 -0.7175 2.9600 -0.9136 0.2192 -0.3424
-10.3822 3.0176 0.0916 -0.6147 0.1457 0.7751
3.7168 3.2105 -2.4898 0.2655 -0.0652 0.9619
12.1197 -2.6929 -0.5820 0.7264 -0.1726 -0.6652
-1.0796 -3.4075 2.1405 -0.1034 0.0265 -0.9943
-7.0624 0.0989 -4.3639 0.2138 0.8963 0.3886
-6.7177 -2.4801 -3.0411 0.2189 0.9123 -0.3460
5.9083 -1.3293 4.1882 -0.1713 -0.7208 -0.6716
17.3016 0.1802 -0.1291 0.7258 -0.6877 -0.0179
-17.3033 -0.0809 0.0752 -0.7252 0.6870 0.0464
