#------------------------------------------------------------------------------
#$Date: 2025-01-19 03:53:24 +0200 (Sun, 19 Jan 2025) $
#$Revision: 297380 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/97/7249795.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7249795
loop_
_publ_author_name
'Sobczak, Paulina'
'Sierański, Tomasz'
'Świątkowski, Marcin'
'Trzęsowska-Kruszyńska, Agata'
'Kolińska, Jolanta'
_publ_section_title
;
 Unraveling the structure--property relationships in fluorescent
 phenylhydrazones: the role of substituents and molecular interactions
;
_journal_issue                   3
_journal_name_full               'RSC Advances'
_journal_page_first              1514
_journal_page_last               1526
_journal_paper_doi               10.1039/D4RA07856J
_journal_volume                  15
_journal_year                    2025
_chemical_formula_moiety         'C14 H13 N3 O3'
_chemical_formula_sum            'C14 H13 N3 O3'
_chemical_formula_weight         271.27
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_audit_creation_date             2023-12-07
_audit_creation_method
;
Olex2 1.5-ac5-024
(compiled 2022.04.12 svn.rca3783a0 for Rigaku Oxford Diffraction, GUI svn.r6498)
;
_audit_update_record
;
2024-04-23 deposited with the CCDC.	2025-01-10 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 114.076(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   14.3070(3)
_cell_length_b                   7.29090(10)
_cell_length_c                   13.4037(2)
_cell_measurement_reflns_used    9894
_cell_measurement_temperature    99.9(5)
_cell_measurement_theta_max      79.3820
_cell_measurement_theta_min      6.5940
_cell_volume                     1276.52(4)
_computing_cell_refinement       'CrysAlisPro 1.171.42.68a (Rigaku OD, 2022)'
_computing_data_collection       'CrysAlisPro 1.171.42.68a (Rigaku OD, 2022)'
_computing_data_reduction        'CrysAlisPro 1.171.42.68a (Rigaku OD, 2022)'
_computing_molecular_graphics    'Olex2 1.5-ac5-024 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5-ac5-024 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      99.9(5)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 5.8140
_diffrn_detector_type            'Pilatus 300K'
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.913
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     38.00  66.00   0.50    0.50    --  110.00 -57.00-180.00   56
  2  ω     38.00  66.00   0.50    0.50    --  110.00 -57.00 -60.00   56
  3  ω     38.00  66.00   0.50    0.50    --  110.00 -57.00   0.00   56
  4  ω     38.00  66.00   0.50    0.50    --  110.00 -57.00 -30.00   56
  5  ω     38.00  66.00   0.50    0.50    --  110.00 -57.00  30.00   56
  6  ω     38.00  66.00   0.50    0.50    --  110.00 -57.00 120.00   56
  7  ω     38.00  66.00   0.50    0.50    --  110.00 -57.00 150.00   56
  8  ω     26.00 114.00   0.50    0.20    --   49.12  77.00 -90.00  176
  9  ω     26.00 114.00   0.50    0.20    --   49.12  77.00-180.00  176
 10  ω     94.00 178.00   0.50    0.50    --  110.00  57.00 -90.00  168
 11  ω     26.00 114.00   0.50    0.20    --   49.12  77.00  90.00  176
 12  ω    -26.00  27.00   0.50    0.20    --  -49.12  19.00 -60.00  106
 13  ω    -43.00  26.00   0.50    0.20    --  -49.12  38.00-150.00  138
 14  ω     60.00 122.00   0.50    0.20    --   49.12-178.00  60.00  124
 15  ω    -43.00  26.00   0.50    0.20    --  -49.12  38.00  90.00  138
 16  ω    -26.00  27.00   0.50    0.20    --  -49.12  19.00   0.00  106
 17  ω    -26.00  27.00   0.50    0.20    --  -49.12  19.00 -30.00  106
 18  ω    -43.00 -13.00   0.50    0.50    --  -88.50  38.00 -90.00   60
 19  ω    -43.00 -13.00   0.50    0.50    --  -88.50  38.00-180.00   60
 20  ω    -43.00 -13.00   0.50    0.50    --  -88.50  38.00-120.00   60
 21  ω    -43.00 -13.00   0.50    0.50    --  -88.50  38.00 -60.00   60
 22  ω    -43.00 -13.00   0.50    0.50    --  -88.50  38.00 120.00   60
 23  ω    -43.00 -13.00   0.50    0.50    --  -88.50  38.00  30.00   60
 24  ω   -164.00 -75.00   0.50    0.50    --  -88.50 -19.00 -30.00  178
 25  ω   -160.00 -73.00   0.50    0.50    --  -88.50 -57.00  30.00  174
 26  ω   -160.00 -73.00   0.50    0.50    --  -88.50 -57.00  60.00  174
 27  ω    -87.00 -19.00   0.50    0.50    --  -88.50 125.00 150.00  136
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, Pilatus 300K'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0829292000
_diffrn_orient_matrix_UB_12      0.1486489000
_diffrn_orient_matrix_UB_13      0.0480558000
_diffrn_orient_matrix_UB_21      0.0167015000
_diffrn_orient_matrix_UB_22      0.0010267000
_diffrn_orient_matrix_UB_23      -0.1064961000
_diffrn_orient_matrix_UB_31      -0.0821892000
_diffrn_orient_matrix_UB_32      0.1501638000
_diffrn_orient_matrix_UB_33      -0.0468824000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0220
_diffrn_reflns_av_unetI/netI     0.0144
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.913
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            12901
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.913
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         79.438
_diffrn_reflns_theta_min         6.620
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'PhotonJet (Cu) X-ray Source'
_exptl_absorpt_coefficient_mu    0.845
_exptl_absorpt_correction_T_max  0.940
_exptl_absorpt_correction_T_min  0.849
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.42.68a (Rigaku Oxford Diffraction, 2022)
Analytical numeric absorption correction using a multifaceted crystal
model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            red
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    1.412
_exptl_crystal_description       prism
_exptl_crystal_F_000             568
_exptl_crystal_size_max          0.287
_exptl_crystal_size_mid          0.195
_exptl_crystal_size_min          0.102
_refine_diff_density_max         0.160
_refine_diff_density_min         -0.304
_refine_diff_density_rms         0.059
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.076
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     185
_refine_ls_number_reflns         2536
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.076
_refine_ls_R_factor_all          0.0344
_refine_ls_R_factor_gt           0.0328
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0512P)²+0.3545P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0900
_refine_ls_wR_factor_ref         0.0912
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2361
_reflns_number_total             2536
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d4ra07856j2.cif
_cod_data_source_block           ps_dok63_no3
_cod_database_code               7249795
_shelx_shelxl_version_number     2018/3
_chemical_oxdiff_formula         'C14 H13 N3 O3'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.919
_shelx_estimated_absorpt_t_min   0.793
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All N(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C7(H7), C10(H10), C3(H3), C11(H11), C14(H14), C6(H6), C13(H13), C8(H8), C4(H4)
2.b Idealised Me refined as rotating group:
 C1(H1A,H1B,H1C)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.985
_oxdiff_exptl_absorpt_empirical_full_min 0.651
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O1 O 0.92284(5) 0.42324(10) 0.04466(5) 0.01785(18) Uani 1 1 d . . . . .
O2 O 0.40017(6) 0.86730(12) 0.58207(7) 0.0269(2) Uani 1 1 d . . . . .
O3 O 0.45259(6) 0.68863(12) 0.72348(7) 0.0288(2) Uani 1 1 d . . . . .
N1 N 0.87051(7) 0.44465(13) 0.43365(7) 0.0184(2) Uani 1 1 d . . . . .
H1 H 0.9083(10) 0.3692(19) 0.4836(11) 0.022 Uiso 1 1 d . U . . .
N2 N 0.78656(6) 0.51399(12) 0.44295(7) 0.0167(2) Uani 1 1 d . . . . .
N3 N 0.45926(7) 0.75151(12) 0.64157(7) 0.0199(2) Uani 1 1 d . . . . .
C5 C 0.87759(8) 0.44235(13) 0.33259(8) 0.0158(2) Uani 1 1 d . . . . .
C7 C 0.97750(7) 0.35792(14) 0.23136(8) 0.0165(2) Uani 1 1 d . . . . .
H7 H 1.036811 0.303050 0.229042 0.020 Uiso 1 1 calc R U . . .
C9 C 0.69473(7) 0.55112(13) 0.55706(8) 0.0158(2) Uani 1 1 d . . . . .
C10 C 0.62006(8) 0.67020(14) 0.48630(8) 0.0166(2) Uani 1 1 d . . . . .
H10 H 0.622150 0.704572 0.418872 0.020 Uiso 1 1 calc R U . . .
C3 C 0.81566(8) 0.51230(14) 0.14015(8) 0.0176(2) Uani 1 1 d . . . . .
H3 H 0.764433 0.562506 0.075587 0.021 Uiso 1 1 calc R U . . .
C2 C 0.90325(8) 0.43499(13) 0.13716(8) 0.0155(2) Uani 1 1 d . . . . .
C12 C 0.54185(7) 0.68460(14) 0.61276(8) 0.0169(2) Uani 1 1 d . . . . .
C11 C 0.54341(8) 0.73804(14) 0.51386(8) 0.0172(2) Uani 1 1 d . . . . .
H11 H 0.492987 0.819277 0.466297 0.021 Uiso 1 1 calc R U . . .
C14 C 0.68996(8) 0.49963(14) 0.65561(8) 0.0175(2) Uani 1 1 d . . . . .
H14 H 0.739799 0.417730 0.703385 0.021 Uiso 1 1 calc R U . . .
C6 C 0.96467(8) 0.36150(14) 0.32828(8) 0.0169(2) Uani 1 1 d . . . . .
H6 H 1.015299 0.308715 0.392338 0.020 Uiso 1 1 calc R U . . .
C13 C 0.61385(8) 0.56614(14) 0.68446(8) 0.0181(2) Uani 1 1 d . . . . .
H13 H 0.610988 0.531633 0.751504 0.022 Uiso 1 1 calc R U . . .
C8 C 0.77838(8) 0.47859(14) 0.53326(8) 0.0169(2) Uani 1 1 d . . . . .
H8 H 0.828385 0.402914 0.585921 0.020 Uiso 1 1 calc R U . . .
C4 C 0.80289(8) 0.51626(14) 0.23792(8) 0.0175(2) Uani 1 1 d . . . . .
H4 H 0.743057 0.569528 0.239855 0.021 Uiso 1 1 calc R U . . .
C1 C 0.84877(8) 0.50257(15) -0.05358(8) 0.0201(2) Uani 1 1 d . . . . .
H1A H 0.872858 0.491776 -0.112087 0.030 Uiso 1 1 calc R U . . .
H1B H 0.839368 0.632335 -0.040971 0.030 Uiso 1 1 calc R U . . .
H1C H 0.783428 0.437845 -0.074878 0.030 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
1 -3 5 0.0696
-8 1 6 0.0797
3 2 -8 0.0846
7 0 -8 0.1175
7 -3 -2 0.1370
1 -5 -1 0.0423
2 4 2 0.0763
-7 0 -3 0.0963
-3 -4 -3 0.0481
3 -3 -7 0.0652
0 -1 -8 0.0665
-2 2 7 0.0345
3 4 0 0.0727
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 O1 C1 117.08(8) . . ?
N2 N1 H1 117.7(9) . . ?
N2 N1 C5 120.70(8) . . ?
C5 N1 H1 118.2(9) . . ?
C8 N2 N1 115.80(9) . . ?
O2 N3 C12 118.13(9) . . ?
O3 N3 O2 123.50(9) . . ?
O3 N3 C12 118.37(9) . . ?
N1 C5 C6 117.51(9) . . ?
C4 C5 N1 123.11(9) . . ?
C4 C5 C6 119.37(9) . . ?
C2 C7 H7 120.1 . . ?
C6 C7 H7 120.1 . . ?
C6 C7 C2 119.90(9) . . ?
C10 C9 C8 122.90(9) . . ?
C14 C9 C10 119.12(9) . . ?
C14 C9 C8 117.98(9) . . ?
C9 C10 H10 119.7 . . ?
C11 C10 C9 120.57(9) . . ?
C11 C10 H10 119.7 . . ?
C2 C3 H3 120.0 . . ?
C2 C3 C4 120.04(9) . . ?
C4 C3 H3 120.0 . . ?
O1 C2 C7 115.43(9) . . ?
O1 C2 C3 124.53(9) . . ?
C3 C2 C7 120.02(9) . . ?
C11 C12 N3 119.03(9) . . ?
C13 C12 N3 118.33(9) . . ?
C13 C12 C11 122.61(9) . . ?
C10 C11 C12 118.50(9) . . ?
C10 C11 H11 120.8 . . ?
C12 C11 H11 120.8 . . ?
C9 C14 H14 119.5 . . ?
C13 C14 C9 121.07(9) . . ?
C13 C14 H14 119.5 . . ?
C5 C6 H6 119.8 . . ?
C7 C6 C5 120.49(9) . . ?
C7 C6 H6 119.8 . . ?
C12 C13 H13 120.9 . . ?
C14 C13 C12 118.13(9) . . ?
C14 C13 H13 120.9 . . ?
N2 C8 C9 122.01(9) . . ?
N2 C8 H8 119.0 . . ?
C9 C8 H8 119.0 . . ?
C5 C4 C3 120.16(9) . . ?
C5 C4 H4 119.9 . . ?
C3 C4 H4 119.9 . . ?
O1 C1 H1A 109.5 . . ?
O1 C1 H1B 109.5 . . ?
O1 C1 H1C 109.5 . . ?
H1A C1 H1B 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O1 C2 1.3808(12) . ?
O1 C1 1.4328(12) . ?
O2 N3 1.2302(12) . ?
O3 N3 1.2289(12) . ?
N1 H1 0.865(14) . ?
N1 N2 1.3549(12) . ?
N1 C5 1.3991(13) . ?
N2 C8 1.2889(13) . ?
N3 C12 1.4683(13) . ?
C5 C6 1.4006(14) . ?
C5 C4 1.3915(14) . ?
C7 H7 0.9500 . ?
C7 C2 1.3944(14) . ?
C7 C6 1.3844(14) . ?
C9 C10 1.4028(14) . ?
C9 C14 1.4015(14) . ?
C9 C8 1.4578(14) . ?
C10 H10 0.9500 . ?
C10 C11 1.3836(14) . ?
C3 H3 0.9500 . ?
C3 C2 1.3895(14) . ?
C3 C4 1.3953(14) . ?
C12 C11 1.3905(14) . ?
C12 C13 1.3867(15) . ?
C11 H11 0.9500 . ?
C14 H14 0.9500 . ?
C14 C13 1.3834(15) . ?
C6 H6 0.9500 . ?
C13 H13 0.9500 . ?
C8 H8 0.9500 . ?
C4 H4 0.9500 . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O2 N3 C12 C11 -7.19(14) . . . . ?
O2 N3 C12 C13 174.53(9) . . . . ?
O3 N3 C12 C11 172.58(9) . . . . ?
O3 N3 C12 C13 -5.70(14) . . . . ?
N1 N2 C8 C9 177.09(9) . . . . ?
N1 C5 C6 C7 -178.69(9) . . . . ?
N1 C5 C4 C3 178.84(9) . . . . ?
N2 N1 C5 C6 -177.34(9) . . . . ?
N2 N1 C5 C4 2.77(15) . . . . ?
N3 C12 C11 C10 -178.30(9) . . . . ?
N3 C12 C13 C14 178.32(9) . . . . ?
C5 N1 N2 C8 167.20(9) . . . . ?
C9 C10 C11 C12 -0.38(15) . . . . ?
C9 C14 C13 C12 0.37(15) . . . . ?
C10 C9 C14 C13 -0.83(15) . . . . ?
C10 C9 C8 N2 -2.84(16) . . . . ?
C2 C7 C6 C5 -0.11(15) . . . . ?
C2 C3 C4 C5 -0.20(15) . . . . ?
C11 C12 C13 C14 0.10(15) . . . . ?
C14 C9 C10 C11 0.83(15) . . . . ?
C14 C9 C8 N2 177.63(9) . . . . ?
C6 C5 C4 C3 -1.05(15) . . . . ?
C6 C7 C2 O1 -179.55(9) . . . . ?
C6 C7 C2 C3 -1.15(15) . . . . ?
C13 C12 C11 C10 -0.10(15) . . . . ?
C8 C9 C10 C11 -178.69(9) . . . . ?
C8 C9 C14 C13 178.71(9) . . . . ?
C4 C5 C6 C7 1.21(15) . . . . ?
C4 C3 C2 O1 179.56(9) . . . . ?
C4 C3 C2 C7 1.31(15) . . . . ?
C1 O1 C2 C7 -179.38(9) . . . . ?
C1 O1 C2 C3 2.30(14) . . . . ?
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
1.1053 -3.2278 5.3081 -0.1331 -0.5501 -0.8244
-8.2316 1.4840 5.8554 -0.1807 -0.7595 0.6249
3.1899 2.1483 -7.7494 0.2115 0.8808 0.4237
6.6156 0.4683 -8.0483 0.2315 0.9681 -0.0961
7.2907 -2.8950 -2.0053 0.0779 0.3324 -0.9399
0.8676 -4.6627 -1.4754 -0.6921 0.1668 -0.7023
2.1733 4.1664 2.4471 0.9172 -0.2200 0.3323
-6.9868 0.4066 -2.5170 -0.6399 0.1518 0.7533
-3.2739 -3.7488 -2.7066 -0.9588 0.2297 -0.1670
2.6029 -2.8276 -6.9646 -0.5392 0.7823 -0.3120
-0.0892 -1.2323 -7.6353 -0.5575 0.8104 0.1802
-1.6267 2.2877 7.4360 0.5625 -0.8167 0.1286
2.8177 4.4780 -0.1866 0.8904 0.0715 0.4496
