#------------------------------------------------------------------------------
#$Date: 2019-11-07 22:18:09 +0200 (Thu, 07 Nov 2019) $
#$Revision: 223749 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/03/7700316.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7700316
loop_
_publ_author_name
'Feng, Zhijun'
'Huang, Zeming'
'Wang, Shaowu'
'Wei, Yun'
'Zhou, Shuangliu'
'Zhu, Xiancui'
_publ_section_title
;
 Synthesis and characterization of 2-t-butylimino-functionalized indolyl
 rare-earth metal amido complexes for the catalytic addition of terminal
 alkynes to carbodiimides: the dimeric complexes with the alkynide species
 in the μ-η¹:η² bonding modes.
;
_journal_issue                   29
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11094
_journal_page_last               11102
_journal_paper_doi               10.1039/c9dt01582e
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C25 H51 Dy N4 Si4'
_chemical_formula_sum            'C25 H51 Dy N4 Si4'
_chemical_formula_weight         682.55
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_date             2019-02-10
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2019-02-10 deposited with the CCDC.    2019-06-18 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 108.947(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   18.233(3)
_cell_length_b                   11.728(2)
_cell_length_c                   17.281(3)
_cell_measurement_reflns_used    9595
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.098
_cell_measurement_theta_min      2.237
_cell_volume                     3495.1(10)
_computing_cell_refinement       'SAINT v7.34A (Bruker, 200?)'
_computing_data_collection       'SAINT v7.34A (Bruker, 200?)'
_computing_data_reduction        'SAINT v7.34A (Bruker, 200?)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293.15
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0660
_diffrn_reflns_av_unetI/netI     0.0625
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.988
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            28487
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.988
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.656
_diffrn_reflns_theta_min         2.100
_exptl_absorpt_coefficient_mu    2.293
_exptl_absorpt_correction_T_max  0.7548
_exptl_absorpt_correction_T_min  0.399494
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'SADABS-2004/1 (Bruker,2004) was used for absorption correction. R(int) was 0.1333 before and 0.0617 after correction. The Ratio of minimum to maximum transmission is 0.3995. The λ/2 correction factor is 0.0015.'
_exptl_crystal_colour            'clear light yellow'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.297
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1404
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.13
_refine_diff_density_max         3.194
_refine_diff_density_min         -2.020
_refine_diff_density_rms         0.139
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.005
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     322
_refine_ls_number_reflns         8052
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.005
_refine_ls_R_factor_all          0.0875
_refine_ls_R_factor_gt           0.0530
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0905P)²+1.7492P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1324
_refine_ls_wR_factor_ref         0.1586
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5563
_reflns_number_total             8052
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9dt01582e2.cif
_cod_data_source_block           111213b
_cod_depositor_comments
'Adding full bibliography for 7700314--7700321.cif.'
_cod_original_cell_volume        3495.2(11)
_cod_database_code               7700316
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.755
_shelx_estimated_absorpt_t_min   0.710
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C2(H2), C4(H4), C5(H5), C6(H6), C7(H7), C9(H9)
2.b Idealised Me refined as rotating group:
 C11(H11A,H11B,H11C), C12(H12A,H12B,H12C), C13(H13A,H13B,H13C), C14(H14A,H14B,
 H14C), C15(H15A,H15B,H15C), C16(H16A,H16B,H16C), C17(H17A,H17B,H17C), C18(H18A,
 H18B,H18C), C19(H19A,H19B,H19C), C20(H20A,H20B,H20C), C21(H21A,H21B,H21C),
 C22(H22A,H22B,H22C), C23(H23A,H23B,H23C), C24(H24A,H24B,H24C), C25(H25A,H25B,
 H25C)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
C1 C 0.9392(4) 0.5165(5) 0.3493(4) 0.0508(14) Uani 1 1 d .
C2 C 1.0034(4) 0.4707(5) 0.4066(4) 0.0615(17) Uani 1 1 d .
H2 H 1.049158 0.508515 0.434577 0.074 Uiso 1 1 calc R
C3 C 0.9864(4) 0.3558(5) 0.4145(4) 0.0553(15) Uani 1 1 d .
C4 C 1.0267(4) 0.2640(6) 0.4628(5) 0.071(2) Uani 1 1 d .
H4 H 1.076682 0.274220 0.498823 0.085 Uiso 1 1 calc R
C5 C 0.9912(4) 0.1599(6) 0.4559(5) 0.075(2) Uani 1 1 d .
H5 H 1.017101 0.099395 0.488124 0.090 Uiso 1 1 calc R
C6 C 0.9173(5) 0.1437(6) 0.4017(5) 0.076(2) Uani 1 1 d .
H6 H 0.895149 0.071588 0.397662 0.091 Uiso 1 1 calc R
C7 C 0.8747(4) 0.2308(5) 0.3528(5) 0.0676(18) Uani 1 1 d .
H7 H 0.824858 0.218657 0.316853 0.081 Uiso 1 1 calc R
C8 C 0.9104(3) 0.3377(5) 0.3605(3) 0.0475(13) Uani 1 1 d .
C9 C 0.9282(4) 0.6337(5) 0.3220(4) 0.0579(16) Uani 1 1 d .
H9 H 0.968224 0.685362 0.344326 0.069 Uiso 1 1 calc R
C10 C 0.8607(4) 0.7939(5) 0.2475(4) 0.0643(17) Uani 1 1 d .
C11 C 0.9372(5) 0.8551(7) 0.2694(6) 0.107(3) Uani 1 1 d .
H11A H 0.962276 0.852050 0.327500 0.160 Uiso 1 1 calc GR
H11B H 0.928594 0.933202 0.252193 0.160 Uiso 1 1 calc GR
H11C H 0.969481 0.819111 0.242344 0.160 Uiso 1 1 calc GR
C12 C 0.8132(6) 0.8477(6) 0.2969(6) 0.102(3) Uani 1 1 d .
H12A H 0.762666 0.813374 0.281252 0.153 Uiso 1 1 calc GR
H12B H 0.808034 0.928140 0.286164 0.153 Uiso 1 1 calc GR
H12C H 0.839100 0.835297 0.354235 0.153 Uiso 1 1 calc GR
C13 C 0.8181(7) 0.8035(8) 0.1574(6) 0.131(5) Uani 1 1 d .
H13A H 0.846484 0.763922 0.127563 0.197 Uiso 1 1 calc GR
H13B H 0.813226 0.882445 0.141813 0.197 Uiso 1 1 calc GR
H13C H 0.767508 0.770379 0.145216 0.197 Uiso 1 1 calc GR
C14 C 0.7731(6) 0.5231(9) 0.4357(6) 0.109(4) Uani 1 1 d .
H14A H 0.774554 0.446038 0.417619 0.164 Uiso 1 1 calc GR
H14B H 0.776123 0.523177 0.492226 0.164 Uiso 1 1 calc GR
H14C H 0.816212 0.564795 0.429598 0.164 Uiso 1 1 calc GR
C15 C 0.6845(9) 0.7384(10) 0.4147(7) 0.163(6) Uani 1 1 d .
H15A H 0.730792 0.775696 0.412825 0.245 Uiso 1 1 calc GR
H15B H 0.684910 0.734575 0.470279 0.245 Uiso 1 1 calc GR
H15C H 0.639955 0.780736 0.382523 0.245 Uiso 1 1 calc GR
C16 C 0.6006(7) 0.5181(10) 0.3948(7) 0.125(4) Uani 1 1 d .
H16A H 0.552156 0.552460 0.363851 0.188 Uiso 1 1 calc GR
H16B H 0.607443 0.524071 0.452176 0.188 Uiso 1 1 calc GR
H16C H 0.600481 0.439246 0.380027 0.188 Uiso 1 1 calc GR
C17 C 0.5756(6) 0.7897(8) 0.1949(7) 0.122(4) Uani 1 1 d .
H17A H 0.558335 0.803818 0.240947 0.183 Uiso 1 1 calc GR
H17B H 0.535411 0.810788 0.145437 0.183 Uiso 1 1 calc GR
H17C H 0.621239 0.833924 0.200275 0.183 Uiso 1 1 calc GR
C18 C 0.5056(5) 0.5561(10) 0.1745(6) 0.105(3) Uani 1 1 d .
H18A H 0.511038 0.479569 0.157386 0.158 Uiso 1 1 calc GR
H18B H 0.464541 0.593740 0.132936 0.158 Uiso 1 1 calc GR
H18C H 0.493522 0.554251 0.224564 0.158 Uiso 1 1 calc GR
C19 C 0.6244(5) 0.6138(8) 0.0935(4) 0.088(3) Uani 1 1 d .
H19A H 0.664165 0.666899 0.092655 0.132 Uiso 1 1 calc GR
H19B H 0.579235 0.626310 0.046607 0.132 Uiso 1 1 calc GR
H19C H 0.642785 0.537368 0.092123 0.132 Uiso 1 1 calc GR
C20 C 0.6444(5) 0.2760(8) 0.2519(5) 0.092(3) Uani 1 1 d .
H20A H 0.691826 0.292129 0.295198 0.138 Uiso 1 1 calc GR
H20B H 0.622397 0.206559 0.263899 0.138 Uiso 1 1 calc GR
H20C H 0.608541 0.337515 0.247352 0.138 Uiso 1 1 calc GR
C21 C 0.5717(5) 0.2729(8) 0.0687(6) 0.099(3) Uani 1 1 d .
H21A H 0.551850 0.348936 0.067498 0.148 Uiso 1 1 calc GR
H21B H 0.534942 0.219536 0.076951 0.148 Uiso 1 1 calc GR
H21C H 0.579974 0.256759 0.017734 0.148 Uiso 1 1 calc GR
C22 C 0.6984(6) 0.1091(7) 0.1505(7) 0.110(3) Uani 1 1 d .
H22A H 0.707161 0.095866 0.099374 0.165 Uiso 1 1 calc GR
H22B H 0.659363 0.057550 0.155650 0.165 Uiso 1 1 calc GR
H22C H 0.745716 0.096904 0.194732 0.165 Uiso 1 1 calc GR
C23 C 0.8395(6) 0.4936(6) 0.0968(6) 0.088(3) Uani 1 1 d .
H23A H 0.804820 0.557065 0.090774 0.132 Uiso 1 1 calc GR
H23B H 0.865305 0.498840 0.056498 0.132 Uiso 1 1 calc GR
H23C H 0.877310 0.494908 0.150493 0.132 Uiso 1 1 calc GR
C24 C 0.7207(5) 0.3523(10) -0.0264(5) 0.111(4) Uani 1 1 d .
H24A H 0.691447 0.282660 -0.036603 0.167 Uiso 1 1 calc GR
H24B H 0.752577 0.355669 -0.060970 0.167 Uiso 1 1 calc GR
H24C H 0.685838 0.416069 -0.037861 0.167 Uiso 1 1 calc GR
C25 C 0.8553(5) 0.2390(8) 0.0994(7) 0.104(3) Uani 1 1 d .
H25A H 0.885818 0.236154 0.156249 0.157 Uiso 1 1 calc GR
H25B H 0.888570 0.252299 0.067182 0.157 Uiso 1 1 calc GR
H25C H 0.828618 0.167810 0.083552 0.157 Uiso 1 1 calc GR
Dy1 Dy 0.76753(2) 0.51171(2) 0.23026(2) 0.04602(12) Uani 1 1 d .
N1 N 0.8804(3) 0.4374(4) 0.3198(3) 0.0513(12) Uani 1 1 d .
N2 N 0.8670(3) 0.6689(4) 0.2693(3) 0.0503(11) Uani 1 1 d .
N3 N 0.6749(3) 0.5882(4) 0.2720(3) 0.0548(12) Uani 1 1 d .
N4 N 0.7325(3) 0.3594(4) 0.1503(3) 0.0492(11) Uani 1 1 d .
Si1 Si 0.68039(13) 0.5922(2) 0.37281(13) 0.0714(6) Uani 1 1 d .
Si2 Si 0.59825(12) 0.63523(18) 0.19111(14) 0.0696(5) Uani 1 1 d .
Si3 Si 0.66493(12) 0.26011(16) 0.15378(13) 0.0637(5) Uani 1 1 d .
Si4 Si 0.78302(11) 0.35700(18) 0.08217(12) 0.0634(5) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C2 C1 C9 127.0(6)
C2 C1 N1 112.3(5)
N1 C1 C9 120.6(5)
C1 C2 H2 126.8
C1 C2 C3 106.4(5)
C3 C2 H2 126.8
C2 C3 C4 134.6(6)
C2 C3 C8 106.4(5)
C8 C3 C4 119.0(6)
C3 C4 H4 120.4
C5 C4 C3 119.2(6)
C5 C4 H4 120.4
C4 C5 H5 119.7
C4 C5 C6 120.7(6)
C6 C5 H5 119.7
C5 C6 H6 118.6
C5 C6 C7 122.7(7)
C7 C6 H6 118.6
C6 C7 H7 121.7
C6 C7 C8 116.7(6)
C8 C7 H7 121.7
C7 C8 C3 121.6(5)
N1 C8 C3 110.5(5)
N1 C8 C7 127.8(6)
C1 C9 H9 118.5
N2 C9 C1 122.9(6)
N2 C9 H9 118.5
C11 C10 C12 108.0(7)
C11 C10 N2 114.4(6)
C13 C10 C11 110.5(8)
C13 C10 C12 110.5(8)
C13 C10 N2 107.7(6)
N2 C10 C12 105.8(6)
C10 C11 H11A 109.5
C10 C11 H11B 109.5
C10 C11 H11C 109.5
H11A C11 H11B 109.5
H11A C11 H11C 109.5
H11B C11 H11C 109.5
C10 C12 H12A 109.5
C10 C12 H12B 109.5
C10 C12 H12C 109.5
H12A C12 H12B 109.5
H12A C12 H12C 109.5
H12B C12 H12C 109.5
C10 C13 H13A 109.5
C10 C13 H13B 109.5
C10 C13 H13C 109.5
H13A C13 H13B 109.5
H13A C13 H13C 109.5
H13B C13 H13C 109.5
H14A C14 H14B 109.5
H14A C14 H14C 109.5
H14B C14 H14C 109.5
Si1 C14 H14A 109.5
Si1 C14 H14B 109.5
Si1 C14 H14C 109.5
H15A C15 H15B 109.5
H15A C15 H15C 109.5
H15B C15 H15C 109.5
Si1 C15 H15A 109.5
Si1 C15 H15B 109.5
Si1 C15 H15C 109.5
H16A C16 H16B 109.5
H16A C16 H16C 109.5
H16B C16 H16C 109.5
Si1 C16 H16A 109.5
Si1 C16 H16B 109.5
Si1 C16 H16C 109.5
H17A C17 H17B 109.5
H17A C17 H17C 109.5
H17B C17 H17C 109.5
Si2 C17 H17A 109.5
Si2 C17 H17B 109.5
Si2 C17 H17C 109.5
H18A C18 H18B 109.5
H18A C18 H18C 109.5
H18B C18 H18C 109.5
Si2 C18 H18A 109.5
Si2 C18 H18B 109.5
Si2 C18 H18C 109.5
H19A C19 H19B 109.5
H19A C19 H19C 109.5
H19B C19 H19C 109.5
Si2 C19 H19A 109.5
Si2 C19 H19B 109.5
Si2 C19 H19C 109.5
H20A C20 H20B 109.5
H20A C20 H20C 109.5
H20B C20 H20C 109.5
Si3 C20 H20A 109.5
Si3 C20 H20B 109.5
Si3 C20 H20C 109.5
H21A C21 H21B 109.5
H21A C21 H21C 109.5
H21B C21 H21C 109.5
Si3 C21 H21A 109.5
Si3 C21 H21B 109.5
Si3 C21 H21C 109.5
H22A C22 H22B 109.5
H22A C22 H22C 109.5
H22B C22 H22C 109.5
Si3 C22 H22A 109.5
Si3 C22 H22B 109.5
Si3 C22 H22C 109.5
H23A C23 H23B 109.5
H23A C23 H23C 109.5
H23B C23 H23C 109.5
Si4 C23 H23A 109.5
Si4 C23 H23B 109.5
Si4 C23 H23C 109.5
H24A C24 H24B 109.5
H24A C24 H24C 109.5
H24B C24 H24C 109.5
Si4 C24 H24A 109.5
Si4 C24 H24B 109.5
Si4 C24 H24C 109.5
H25A C25 H25B 109.5
H25A C25 H25C 109.5
H25B C25 H25C 109.5
Si4 C25 H25A 109.5
Si4 C25 H25B 109.5
Si4 C25 H25C 109.5
N1 Dy1 N2 71.91(16)
N1 Dy1 Si2 151.80(13)
N2 Dy1 Si2 106.23(12)
N3 Dy1 N1 122.65(18)
N3 Dy1 N2 100.01(18)
N3 Dy1 Si2 29.15(13)
N4 Dy1 N1 97.31(16)
N4 Dy1 N2 142.33(17)
N4 Dy1 N3 115.45(19)
N4 Dy1 Si2 99.53(12)
C1 N1 Dy1 114.2(4)
C8 N1 C1 104.3(5)
C8 N1 Dy1 141.3(4)
C9 N2 C10 118.5(5)
C9 N2 Dy1 110.2(4)
C10 N2 Dy1 130.9(4)
Si1 N3 Dy1 122.7(3)
Si1 N3 Si2 125.7(3)
Si2 N3 Dy1 111.6(3)
Si3 N4 Dy1 126.2(3)
Si3 N4 Si4 124.5(3)
Si4 N4 Dy1 109.3(2)
C15 Si1 C14 105.0(6)
C16 Si1 C14 107.6(5)
C16 Si1 C15 106.9(6)
N3 Si1 C14 108.8(4)
N3 Si1 C15 113.8(4)
N3 Si1 C16 114.2(4)
C17 Si2 C18 106.8(5)
C17 Si2 C19 106.3(5)
C17 Si2 Dy1 128.9(4)
C18 Si2 C19 105.7(4)
C18 Si2 Dy1 123.9(3)
C19 Si2 Dy1 68.7(2)
N3 Si2 C17 114.5(4)
N3 Si2 C18 115.0(4)
N3 Si2 C19 107.9(3)
N3 Si2 Dy1 39.29(17)
C20 Si3 C22 106.6(5)
C21 Si3 C20 108.1(4)
C21 Si3 C22 105.9(4)
N4 Si3 C20 108.9(3)
N4 Si3 C21 113.7(3)
N4 Si3 C22 113.3(4)
C24 Si4 C23 106.9(5)
C24 Si4 C25 108.0(5)
C25 Si4 C23 106.5(4)
N4 Si4 C23 106.7(3)
N4 Si4 C24 114.0(3)
N4 Si4 C25 114.3(4)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
C1 C2 1.374(9)
C1 C9 1.445(8)
C1 N1 1.384(8)
C2 H2 0.9300
C2 C3 1.399(8)
C3 C4 1.413(8)
C3 C8 1.413(8)
C4 H4 0.9300
C4 C5 1.369(10)
C5 H5 0.9300
C5 C6 1.382(10)
C6 H6 0.9300
C6 C7 1.391(9)
C7 H7 0.9300
C7 C8 1.399(8)
C8 N1 1.383(7)
C9 H9 0.9300
C9 N2 1.260(7)
C10 C11 1.503(10)
C10 C12 1.536(11)
C10 C13 1.502(10)
C10 N2 1.508(7)
C11 H11A 0.9600
C11 H11B 0.9600
C11 H11C 0.9600
C12 H12A 0.9600
C12 H12B 0.9600
C12 H12C 0.9600
C13 H13A 0.9600
C13 H13B 0.9600
C13 H13C 0.9600
C14 H14A 0.9600
C14 H14B 0.9600
C14 H14C 0.9600
C14 Si1 1.871(10)
C15 H15A 0.9600
C15 H15B 0.9600
C15 H15C 0.9600
C15 Si1 1.854(10)
C16 H16A 0.9600
C16 H16B 0.9600
C16 H16C 0.9600
C16 Si1 1.837(11)
C17 H17A 0.9600
C17 H17B 0.9600
C17 H17C 0.9600
C17 Si2 1.864(9)
C18 H18A 0.9600
C18 H18B 0.9600
C18 H18C 0.9600
C18 Si2 1.866(9)
C19 H19A 0.9600
C19 H19B 0.9600
C19 H19C 0.9600
C19 Si2 1.913(8)
C20 H20A 0.9600
C20 H20B 0.9600
C20 H20C 0.9600
C20 Si3 1.861(9)
C21 H21A 0.9600
C21 H21B 0.9600
C21 H21C 0.9600
C21 Si3 1.858(8)
C22 H22A 0.9600
C22 H22B 0.9600
C22 H22C 0.9600
C22 Si3 1.880(9)
C23 H23A 0.9600
C23 H23B 0.9600
C23 H23C 0.9600
C23 Si4 1.877(8)
C24 H24A 0.9600
C24 H24B 0.9600
C24 H24C 0.9600
C24 Si4 1.852(8)
C25 H25A 0.9600
C25 H25B 0.9600
C25 H25C 0.9600
C25 Si4 1.867(8)
Dy1 N1 2.306(5)
Dy1 N2 2.520(5)
Dy1 N3 2.230(5)
Dy1 N4 2.221(4)
Dy1 Si2 3.2751(19)
N3 Si1 1.712(5)
N3 Si2 1.715(5)
N4 Si3 1.710(5)
N4 Si4 1.715(5)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C1 C2 C3 C4 -179.2(8)
C1 C2 C3 C8 -0.4(8)
C1 C9 N2 C10 177.8(6)
C1 C9 N2 Dy1 4.5(8)
C2 C1 C9 N2 -179.5(7)
C2 C1 N1 C8 -0.6(8)
C2 C1 N1 Dy1 175.8(5)
C2 C3 C4 C5 178.8(8)
C2 C3 C8 C7 -180.0(6)
C2 C3 C8 N1 0.0(8)
C3 C4 C5 C6 0.9(12)
C3 C8 N1 C1 0.4(7)
C3 C8 N1 Dy1 -174.4(5)
C4 C3 C8 C7 -0.9(10)
C4 C3 C8 N1 179.0(6)
C4 C5 C6 C7 -1.2(13)
C5 C6 C7 C8 0.4(12)
C6 C7 C8 C3 0.6(11)
C6 C7 C8 N1 -179.3(7)
C7 C8 N1 C1 -179.7(7)
C7 C8 N1 Dy1 5.5(11)
C8 C3 C4 C5 0.1(11)
C9 C1 C2 C3 178.2(7)
C9 C1 N1 C8 -178.4(6)
C9 C1 N1 Dy1 -2.0(8)
C11 C10 N2 C9 19.8(9)
C11 C10 N2 Dy1 -168.5(6)
C12 C10 N2 C9 -98.9(7)
C12 C10 N2 Dy1 72.8(7)
C13 C10 N2 C9 142.9(8)
C13 C10 N2 Dy1 -45.4(9)
Dy1 N3 Si1 C14 -0.3(5)
Dy1 N3 Si1 C15 116.4(6)
Dy1 N3 Si1 C16 -120.5(5)
Dy1 N3 Si2 C17 -122.1(5)
Dy1 N3 Si2 C18 113.6(4)
Dy1 N3 Si2 C19 -4.0(4)
Dy1 N4 Si3 C20 -15.3(5)
Dy1 N4 Si3 C21 105.3(4)
Dy1 N4 Si3 C22 -133.7(4)
Dy1 N4 Si4 C23 -5.9(4)
Dy1 N4 Si4 C24 -123.7(4)
Dy1 N4 Si4 C25 111.5(4)
N1 C1 C2 C3 0.6(9)
N1 C1 C9 N2 -2.1(11)
Si1 N3 Si2 C17 60.5(6)
Si1 N3 Si2 C18 -63.7(6)
Si1 N3 Si2 C19 178.6(4)
Si1 N3 Si2 Dy1 -177.4(6)
Si2 N3 Si1 C14 176.7(5)
Si2 N3 Si1 C15 -66.5(7)
Si2 N3 Si1 C16 56.5(6)
Si3 N4 Si4 C23 173.2(4)
Si3 N4 Si4 C24 55.5(5)
Si3 N4 Si4 C25 -69.4(5)
Si4 N4 Si3 C20 165.7(4)
Si4 N4 Si3 C21 -73.7(5)
Si4 N4 Si3 C22 47.3(5)
