#------------------------------------------------------------------------------
#$Date: 2019-11-08 01:33:54 +0200 (Fri, 08 Nov 2019) $
#$Revision: 224517 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/05/7700557.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7700557
loop_
_publ_author_name
'Naito, Toshio'
'Watanabe, Naoki'
'Sakamoto, Yuuka'
'Miyaji, Yuuko'
'Shirahata, Takashi'
'Misaki, Yohji'
'Kitou, Shunsuke'
'Sawa, Hiroshi'
_publ_section_title
;
 A molecular crystal with an unprecedentedly long-lived photoexcited
 state.
;
_journal_issue                   34
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12858
_journal_page_last               12866
_journal_paper_doi               10.1039/c9dt02377a
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C24 H12 Au2 N2 S20'
_chemical_formula_sum            'C24 H12 Au2 N2 S20'
_chemical_formula_weight         1363.51
_chemical_name_systematic        BPY[Au(dmit)2]2
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_update_record
;
2017-11-09 deposited with the CCDC.    2019-07-04 downloaded from the CCDC.
;
_cell_angle_alpha                90.0000
_cell_angle_beta                 100.412(2)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   11.2396(3)
_cell_length_b                   14.3805(3)
_cell_length_c                   23.5196(5)
_cell_measurement_reflns_used    27641
_cell_measurement_temperature    240
_cell_measurement_theta_max      31.26
_cell_measurement_theta_min      2.21
_cell_volume                     3738.90(15)
_computing_cell_refinement       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_molecular_graphics    'CrystalStructure 4.2.5'
_computing_publication_material  'CrystalStructure 4.2.5 (Rigaku, 2017)'
_computing_structure_refinement  'SHELXL Version 2017/1 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT Version 2014/4 (Sheldrick, 2014)'
_diffrn_ambient_temperature      240
_diffrn_detector_area_resol_mean 28.626
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Rigaku Saturn724'
_diffrn_measurement_method       ω
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0677
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            62258
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.000
_diffrn_reflns_theta_min         1.667
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    9.010
_exptl_absorpt_correction_T_max  0.835
_exptl_absorpt_correction_T_min  0.357
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    2.422
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2592.00
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: CH3CN'
_exptl_crystal_size_max          0.190
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.020
_refine_diff_density_max         1.30
_refine_diff_density_min         -1.17
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     443
_refine_ls_number_reflns         9003
_refine_ls_number_restraints     18
_refine_ls_R_factor_all          0.0473
_refine_ls_R_factor_gt           0.0362
_refine_ls_shift/su_max          0.003
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.0287P)²+8.6982P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0755
_refine_ls_wR_factor_ref         0.0807
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7597
_reflns_number_total             9003
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            c9dt02377a2.cif
_cod_data_source_block           240K_dark
_cod_depositor_comments
'Adding full bibliography for 7700531--7700563.cif.'
_cod_database_code               7700557
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 +X,+Y,+Z
2 -X,1/2+Y,1/2-Z
3 -X,-Y,-Z
4 +X,-1/2-Y,-1/2+Z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au2 Au 0.49384(8) 0.35224(8) 0.74219(4) 0.0229(2) Uani 0.897(13) 1 d . U P A 1
Au3 Au 0.4984(9) 0.378(3) 0.7486(6) 0.053(3) Uani 0.103(13) 1 d . U P A 2
Au1 Au 0.99228(2) 0.37225(2) 0.75248(2) 0.02382(7) Uani 1 1 d . . . . .
S1 S 0.8185(2) 0.38663(18) 1.03256(8) 0.0755(7) Uani 1 1 d . . . . .
S2 S 0.90742(14) 0.48038(12) 0.93546(6) 0.0431(4) Uani 1 1 d . . . . .
S3 S 0.88711(14) 0.28065(12) 0.93480(6) 0.0455(4) Uani 1 1 d . . . . .
S4 S 0.98871(13) 0.48881(9) 0.82041(6) 0.0343(3) Uani 1 1 d . . . . .
S5 S 0.96090(14) 0.25897(10) 0.81879(6) 0.0359(3) Uani 1 1 d . . . . .
S6 S 1.02393(13) 0.48612(10) 0.68698(6) 0.0358(3) Uani 1 1 d . . . . .
S7 S 0.99497(12) 0.25689(9) 0.68363(6) 0.0314(3) Uani 1 1 d . . . . .
S8 S 1.09220(14) 0.46786(12) 0.56989(6) 0.0424(4) Uani 1 1 d . . . . .
S9 S 1.07317(14) 0.26805(12) 0.56766(6) 0.0424(4) Uani 1 1 d . . . . .
S10 S 1.1517(2) 0.36550(16) 0.46917(8) 0.0679(6) Uani 1 1 d . . . . .
S11 S 0.3181(2) 0.34467(17) 1.02193(8) 0.0734(6) Uani 1 1 d . . . . .
S12 S 0.25731(14) 0.35811(12) 0.89487(7) 0.0429(4) Uani 1 1 d . . . . .
S13 S 0.50675(14) 0.32842(13) 0.94865(7) 0.0495(4) Uani 1 1 d . . . . .
S14 S 0.31008(12) 0.35931(10) 0.77407(6) 0.0346(3) Uani 1 1 d . . . . .
S15 S 0.59715(12) 0.32207(11) 0.83542(6) 0.0368(3) Uani 1 1 d . . . . .
S16 S 0.39154(12) 0.37263(11) 0.64825(6) 0.0369(3) Uani 1 1 d . . . . .
S17 S 0.67952(12) 0.35808(11) 0.71313(6) 0.0359(3) Uani 1 1 d . . . . .
S18 S 0.49010(13) 0.38412(12) 0.53716(6) 0.0417(4) Uani 1 1 d . . . . .
S19 S 0.73929(12) 0.36992(11) 0.59391(6) 0.0377(3) Uani 1 1 d . . . . .
S20 S 0.68516(16) 0.39092(13) 0.46704(7) 0.0508(4) Uani 1 1 d . . . . .
N1 N 0.6805(4) 0.6176(3) 0.7489(2) 0.0325(10) Uani 1 1 d . . . . .
N2 N 0.5072(4) 0.5860(3) 0.8191(2) 0.0415(12) Uani 1 1 d . . . . .
C1 C 0.8653(5) 0.3835(5) 0.9701(3) 0.0472(17) Uani 1 1 d . . . . .
C2 C 0.9430(4) 0.4235(4) 0.8754(2) 0.0283(11) Uani 1 1 d . . . . .
C3 C 0.9336(5) 0.3305(4) 0.8753(2) 0.0311(12) Uani 1 1 d . . . . .
C4 C 1.0512(4) 0.4157(4) 0.6302(2) 0.0301(12) Uani 1 1 d . . . . .
C5 C 1.0411(4) 0.3226(4) 0.6292(2) 0.0297(11) Uani 1 1 d . . . . .
C6 C 1.1089(6) 0.3668(5) 0.5327(3) 0.0455(16) Uani 1 1 d . . . . .
C7 C 0.3592(6) 0.3446(4) 0.9586(3) 0.0441(15) Uani 1 1 d . . . . .
C8 C 0.3614(5) 0.3485(4) 0.8483(2) 0.0306(12) Uani 1 1 d . . . . .
C9 C 0.4767(5) 0.3347(4) 0.8732(2) 0.0318(12) Uani 1 1 d . . . . .
C10 C 0.5151(5) 0.3724(4) 0.6123(2) 0.0301(12) Uani 1 1 d . . . . .
C11 C 0.6318(5) 0.3664(4) 0.6383(2) 0.0293(11) Uani 1 1 d . . . . .
C12 C 0.6395(5) 0.3824(4) 0.5292(3) 0.0358(13) Uani 1 1 d . . . . .
C13 C 0.4288(6) 0.5855(5) 0.8561(3) 0.0563(19) Uani 1 1 d . . . . .
H13 H 0.457124 0.575143 0.895701 0.068 Uiso 1 1 calc R U . . .
C14 C 0.3082(6) 0.5998(5) 0.8363(3) 0.0581(19) Uani 1 1 d . . . . .
H14 H 0.253540 0.600186 0.862259 0.070 Uiso 1 1 calc R U . . .
C15 C 0.2679(6) 0.6135(4) 0.7789(3) 0.0495(16) Uani 1 1 d . . . . .
H15 H 0.185057 0.622869 0.764736 0.059 Uiso 1 1 calc R U . . .
C16 C 0.3498(5) 0.6136(4) 0.7414(3) 0.0397(14) Uani 1 1 d . . . . .
H16 H 0.321894 0.622759 0.701634 0.048 Uiso 1 1 calc R U . . .
C17 C 0.4707(5) 0.6004(4) 0.7614(2) 0.0337(12) Uani 1 1 d . . . . .
C18 C 0.5628(5) 0.6033(3) 0.7248(2) 0.0312(12) Uani 1 1 d . . . . .
C19 C 0.5338(5) 0.5948(4) 0.6651(2) 0.0385(13) Uani 1 1 d . . . . .
H19 H 0.453024 0.585399 0.646961 0.046 Uiso 1 1 calc R U . . .
C20 C 0.6243(6) 0.6004(4) 0.6324(3) 0.0442(15) Uani 1 1 d . . . . .
H20 H 0.605180 0.594537 0.591939 0.053 Uiso 1 1 calc R U . . .
C21 C 0.7417(6) 0.6143(4) 0.6590(3) 0.0462(16) Uani 1 1 d . . . . .
H21 H 0.803688 0.618262 0.637079 0.055 Uiso 1 1 calc R U . . .
C22 C 0.7674(5) 0.6225(4) 0.7175(3) 0.0399(14) Uani 1 1 d . . . . .
H22 H 0.847841 0.631696 0.736041 0.048 Uiso 1 1 calc R U . . .
C23 C 0.7119(5) 0.6311(4) 0.8117(2) 0.0409(14) Uani 1 1 d . . . . .
H23A H 0.696361 0.695666 0.821430 0.049 Uiso 1 1 calc R U . . .
H23B H 0.798046 0.618070 0.824986 0.049 Uiso 1 1 calc R U . . .
C24 C 0.6375(5) 0.5670(4) 0.8406(2) 0.0451(15) Uani 1 1 d . . . . .
H24A H 0.656014 0.502386 0.832363 0.054 Uiso 1 1 calc R U . . .
H24B H 0.656355 0.576298 0.882566 0.054 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Table 6.1.1.4)
;
Au Au -2.0133 8.8022
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
N N 0.0061 0.0033
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
S S 0.1246 0.1234
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
S17 Au2 S16 91.86(6)
S17 Au2 S14 175.13(9)
S16 Au2 S14 89.16(6)
S17 Au2 S15 87.82(6)
S16 Au2 S15 176.50(8)
S14 Au2 S15 91.45(6)
S15 Au3 S14 92.6(4)
S15 Au3 S17 87.8(4)
S14 Au3 S17 165.1(19)
S15 Au3 S16 157.4(19)
S14 Au3 S16 86.2(5)
S17 Au3 S16 87.7(5)
S6 Au1 S4 88.34(5)
S6 Au1 S7 91.05(5)
S4 Au1 S7 179.31(5)
S6 Au1 S5 179.52(5)
S4 Au1 S5 91.18(5)
S7 Au1 S5 89.42(5)
C1 S2 C2 97.3(3)
C1 S3 C3 97.1(3)
C2 S4 Au1 99.47(18)
C3 S5 Au1 99.55(19)
C4 S6 Au1 99.67(19)
C5 S7 Au1 99.69(18)
C6 S8 C4 96.9(3)
C6 S9 C5 97.3(3)
C7 S12 C8 97.0(3)
C7 S13 C9 96.7(3)
C8 S14 Au3 96.7(4)
C8 S14 Au2 99.60(18)
C9 S15 Au3 97.0(4)
C9 S15 Au2 99.10(18)
C10 S16 Au2 99.22(19)
C10 S16 Au3 99.9(3)
C11 S17 Au2 99.84(18)
C11 S17 Au3 102.7(3)
C12 S18 C10 97.3(3)
C12 S19 C11 97.0(3)
C22 N1 C18 122.4(5)
C22 N1 C23 119.0(5)
C18 N1 C23 118.6(5)
C13 N2 C17 122.1(6)
C13 N2 C24 119.9(5)
C17 N2 C24 117.9(5)
S1 C1 S2 123.9(4)
S1 C1 S3 123.1(4)
S2 C1 S3 112.8(3)
C3 C2 S2 116.1(4)
C3 C2 S4 124.6(4)
S2 C2 S4 119.3(3)
C2 C3 S3 116.5(4)
C2 C3 S5 124.2(4)
S3 C3 S5 119.3(3)
C5 C4 S8 116.7(4)
C5 C4 S6 124.4(4)
S8 C4 S6 118.9(3)
C4 C5 S9 115.7(4)
C4 C5 S7 124.2(4)
S9 C5 S7 120.0(3)
S10 C6 S8 123.1(4)
S10 C6 S9 123.6(4)
S8 C6 S9 113.3(3)
S11 C7 S12 122.6(4)
S11 C7 S13 123.9(4)
S12 C7 S13 113.5(3)
C9 C8 S14 124.8(4)
C9 C8 S12 116.3(4)
S14 C8 S12 118.9(3)
C8 C9 S13 116.6(4)
C8 C9 S15 124.6(4)
S13 C9 S15 118.8(3)
C11 C10 S18 115.6(4)
C11 C10 S16 124.9(4)
S18 C10 S16 119.5(3)
C10 C11 S19 116.8(4)
C10 C11 S17 124.0(4)
S19 C11 S17 119.2(3)
S20 C12 S18 124.4(4)
S20 C12 S19 122.4(3)
S18 C12 S19 113.3(3)
N2 C13 C14 120.3(6)
N2 C13 H13 119.8
C14 C13 H13 119.8
C15 C14 C13 119.4(6)
C15 C14 H14 120.3
C13 C14 H14 120.3
C14 C15 C16 119.5(6)
C14 C15 H15 120.2
C16 C15 H15 120.2
C17 C16 C15 120.9(6)
C17 C16 H16 119.5
C15 C16 H16 119.5
N2 C17 C16 117.7(5)
N2 C17 C18 118.3(5)
C16 C17 C18 123.9(5)
N1 C18 C19 117.9(5)
N1 C18 C17 120.0(5)
C19 C18 C17 122.1(5)
C20 C19 C18 119.7(6)
C20 C19 H19 120.2
C18 C19 H19 120.2
C21 C20 C19 119.9(6)
C21 C20 H20 120.0
C19 C20 H20 120.0
C22 C21 C20 119.1(6)
C22 C21 H21 120.5
C20 C21 H21 120.5
N1 C22 C21 121.0(6)
N1 C22 H22 119.5
C21 C22 H22 119.5
N1 C23 C24 109.0(5)
N1 C23 H23A 109.9
C24 C23 H23A 109.9
N1 C23 H23B 109.9
C24 C23 H23B 109.9
H23A C23 H23B 108.3
N2 C24 C23 109.4(5)
N2 C24 H24A 109.8
C23 C24 H24A 109.8
N2 C24 H24B 109.8
C23 C24 H24B 109.8
H24A C24 H24B 108.3
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Au2 S17 2.3119(16)
Au2 S16 2.3175(17)
Au2 S14 2.3235(16)
Au2 S15 2.3291(16)
Au3 S15 2.288(9)
Au3 S14 2.318(10)
Au3 S17 2.353(11)
Au3 S16 2.448(16)
Au1 S6 2.3193(14)
Au1 S4 2.3210(13)
Au1 S7 2.3222(13)
Au1 S5 2.3258(14)
S1 C1 1.648(6)
S2 C1 1.723(7)
S2 C2 1.742(5)
S3 C1 1.735(7)
S3 C3 1.736(5)
S4 C2 1.748(5)
S5 C3 1.750(6)
S6 C4 1.747(5)
S7 C5 1.744(5)
S8 C6 1.724(7)
S8 C4 1.738(5)
S9 C6 1.725(7)
S9 C5 1.739(5)
S10 C6 1.649(6)
S11 C7 1.637(6)
S12 C7 1.725(7)
S12 C8 1.746(5)
S13 C7 1.732(6)
S13 C9 1.748(5)
S14 C8 1.744(5)
S15 C9 1.758(5)
S16 C10 1.752(5)
S17 C11 1.749(5)
S18 C12 1.723(6)
S18 C10 1.746(5)
S19 C12 1.730(6)
S19 C11 1.735(5)
S20 C12 1.639(6)
N1 C22 1.327(7)
N1 C18 1.358(7)
N1 C23 1.469(7)
N2 C13 1.346(7)
N2 C17 1.361(7)
N2 C24 1.485(7)
C2 C3 1.341(8)
C4 C5 1.344(8)
C8 C9 1.337(7)
C10 C11 1.346(7)
C13 C14 1.367(9)
C13 H13 0.9400
C14 C15 1.359(10)
C14 H14 0.9400
C15 C16 1.385(9)
C15 H15 0.9400
C16 C17 1.369(8)
C16 H16 0.9400
C17 C18 1.461(8)
C18 C19 1.389(7)
C19 C20 1.385(8)
C19 H19 0.9400
C20 C21 1.369(9)
C20 H20 0.9400
C21 C22 1.359(8)
C21 H21 0.9400
C22 H22 0.9400
C23 C24 1.489(8)
C23 H23A 0.9800
C23 H23B 0.9800
C24 H24A 0.9800
C24 H24B 0.9800
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C2 S2 C1 S1 -179.8(4)
C2 S2 C1 S3 4.3(4)
C3 S3 C1 S1 179.8(4)
C3 S3 C1 S2 -4.3(4)
C1 S2 C2 C3 -2.8(5)
C1 S2 C2 S4 177.7(3)
Au1 S4 C2 C3 8.1(5)
Au1 S4 C2 S2 -172.3(3)
S2 C2 C3 S3 0.1(6)
S4 C2 C3 S3 179.7(3)
S2 C2 C3 S5 178.3(3)
S4 C2 C3 S5 -2.1(7)
C1 S3 C3 C2 2.6(5)
C1 S3 C3 S5 -175.7(3)
Au1 S5 C3 C2 -5.3(5)
Au1 S5 C3 S3 172.9(3)
C6 S8 C4 C5 -2.3(5)
C6 S8 C4 S6 178.6(3)
Au1 S6 C4 C5 5.6(5)
Au1 S6 C4 S8 -175.3(3)
S8 C4 C5 S9 1.0(6)
S6 C4 C5 S9 -180.0(3)
S8 C4 C5 S7 -177.2(3)
S6 C4 C5 S7 1.9(7)
C6 S9 C5 C4 0.9(5)
C6 S9 C5 S7 179.1(3)
Au1 S7 C5 C4 -8.1(5)
Au1 S7 C5 S9 173.8(3)
C4 S8 C6 S10 -178.7(4)
C4 S8 C6 S9 2.8(4)
C5 S9 C6 S10 179.1(4)
C5 S9 C6 S8 -2.4(4)
C8 S12 C7 S11 -178.8(4)
C8 S12 C7 S13 -0.2(4)
C9 S13 C7 S11 178.7(4)
C9 S13 C7 S12 0.2(4)
Au3 S14 C8 C9 -13.1(11)
Au2 S14 C8 C9 -3.4(5)
Au3 S14 C8 S12 165.8(10)
Au2 S14 C8 S12 175.4(3)
C7 S12 C8 C9 0.2(5)
C7 S12 C8 S14 -178.7(4)
S14 C8 C9 S13 178.8(3)
S12 C8 C9 S13 -0.1(6)
S14 C8 C9 S15 -1.6(8)
S12 C8 C9 S15 179.5(3)
C7 S13 C9 C8 0.0(5)
C7 S13 C9 S15 -179.7(3)
Au3 S15 C9 C8 15.4(11)
Au2 S15 C9 C8 5.6(5)
Au3 S15 C9 S13 -165.0(10)
Au2 S15 C9 S13 -174.8(3)
C12 S18 C10 C11 0.1(5)
C12 S18 C10 S16 178.3(3)
Au2 S16 C10 C11 -3.0(5)
Au3 S16 C10 C11 6.3(10)
Au2 S16 C10 S18 179.1(3)
Au3 S16 C10 S18 -171.7(9)
S18 C10 C11 S19 -0.7(6)
S16 C10 C11 S19 -178.7(3)
S18 C10 C11 S17 177.9(3)
S16 C10 C11 S17 -0.1(7)
C12 S19 C11 C10 0.8(5)
C12 S19 C11 S17 -177.8(3)
Au2 S17 C11 C10 3.2(5)
Au3 S17 C11 C10 -6.4(11)
Au2 S17 C11 S19 -178.3(3)
Au3 S17 C11 S19 172.1(10)
C10 S18 C12 S20 -179.9(4)
C10 S18 C12 S19 0.4(4)
C11 S19 C12 S20 179.6(4)
C11 S19 C12 S18 -0.7(4)
C17 N2 C13 C14 -0.2(10)
C24 N2 C13 C14 -177.8(6)
N2 C13 C14 C15 0.8(11)
C13 C14 C15 C16 -0.6(11)
C14 C15 C16 C17 -0.3(10)
C13 N2 C17 C16 -0.7(9)
C24 N2 C17 C16 177.0(5)
C13 N2 C17 C18 177.7(5)
C24 N2 C17 C18 -4.6(8)
C15 C16 C17 N2 0.9(9)
C15 C16 C17 C18 -177.4(5)
C22 N1 C18 C19 -0.8(8)
C23 N1 C18 C19 177.2(5)
C22 N1 C18 C17 -178.8(5)
C23 N1 C18 C17 -0.8(7)
N2 C17 C18 N1 -18.1(8)
C16 C17 C18 N1 160.2(5)
N2 C17 C18 C19 164.0(5)
C16 C17 C18 C19 -17.7(8)
N1 C18 C19 C20 0.5(8)
C17 C18 C19 C20 178.4(5)
C18 C19 C20 C21 -0.2(9)
C19 C20 C21 C22 0.1(9)
C18 N1 C22 C21 0.8(9)
C23 N1 C22 C21 -177.2(5)
C20 C21 C22 N1 -0.4(9)
C22 N1 C23 C24 -142.9(5)
C18 N1 C23 C24 39.1(7)
C13 N2 C24 C23 -139.5(6)
C17 N2 C24 C23 42.8(7)
N1 C23 C24 N2 -58.3(6)
