#------------------------------------------------------------------------------
#$Date: 2019-11-08 01:35:42 +0200 (Fri, 08 Nov 2019) $
#$Revision: 224523 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/06/7700650.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7700650
loop_
_publ_author_name
'Li, Qipeng'
'Peng, Yan'
'Qian, Jinjie'
'Yan, Tong'
'Du, Lin'
'Zhao, Qihua'
_publ_section_title
;
 A family of planar hexanuclear CoLn clusters with lucanidae-like
 arrangement and single-molecule magnet behavior.
;
_journal_issue                   34
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12880
_journal_page_last               12887
_journal_paper_doi               10.1039/c9dt02103e
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety
'C64 H82 Co4 Eu2 N18 O18, 2(C2 H3 O2),20[H2O]'
_chemical_formula_sum            'C68 H88 Co4 Eu2 N18 O22'
_chemical_formula_weight         2049.20
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_date             2019-07-19
_audit_creation_method
;
Olex2 1.2-beta
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2019-07-22 deposited with the CCDC.    2019-07-24 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 124.311(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   32.415(10)
_cell_length_b                   15.275(4)
_cell_length_c                   24.178(7)
_cell_measurement_reflns_used    10660
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.4624
_cell_measurement_theta_min      2.9113
_cell_volume                     9888(5)
_computing_cell_refinement       'Saint+ ver. V8.34A (Bruker AXS)'
_computing_data_collection       'Saint+ ver. V8.34A (Bruker AXS)'
_computing_data_reduction        'Saint+ ver. V8.34A (Bruker AXS)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXL (Sheldrick, 2015)'
_diffrn_ambient_temperature      173.15
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0276
_diffrn_reflns_av_unetI/netI     0.0312
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       41
_diffrn_reflns_limit_h_min       -42
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            37095
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.457
_diffrn_reflns_theta_min         2.667
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    1.972
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.8921
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            Red
_exptl_crystal_density_diffrn    1.376
_exptl_crystal_description       Prism
_exptl_crystal_F_000             4128
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.25
_refine_diff_density_max         1.837
_refine_diff_density_min         -1.101
_refine_diff_density_rms         0.108
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.152
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     514
_refine_ls_number_reflns         11259
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.152
_refine_ls_R_factor_all          0.0588
_refine_ls_R_factor_gt           0.0462
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0768P)²+20.3855P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1355
_refine_ls_wR_factor_ref         0.1502
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9057
_reflns_number_total             11259
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9dt02103e2.cif
_cod_data_source_block           4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 7700649--7700652.cif.
;
_cod_original_cell_volume        9889(5)
_cod_database_code               7700650
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.446
_shelx_estimated_absorpt_t_min   0.531
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups, All O(H,H) groups
2.a Riding coordinates:
 O7(H7C,H7D)
2.b Secondary CH2 refined with riding coordinates:
 C1(H1A,H1B), C7(H7A,H7B), C14(H14A,H14B), C15(H15A,H15B), C16(H16A,H16B),
 C17(H17A,H17B), C23(H23A,H23B), C30(H30A,H30B), C31(H31A,H31B), C32(H32A,H32B)
2.c Me refined with riding coordinates:
 C34(H34A,H34B,H34C)
2.d Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C6(H6), C9(H9), C10(H10), C11(H11), C12(H12),
 C19(H19), C20(H20), C21(H21), C22(H22), C25(H25), C26(H26), C27(H27), C28(H28)
2.e Tetrahedral OH refined with riding coordinates:
 O3(H3A), O6(H6A), O8(H8)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_disorder_assembly
_atom_site_disorder_group
Co1 Co 0.31584(2) 0.65859(4) 0.87487(3) 0.04667(16) Uani 1 1 d . . .
Co2 Co 0.46331(2) 0.37427(4) 1.04467(3) 0.04169(14) Uani 1 1 d . . .
Eu1 Eu 0.43545(2) 0.56264(2) 0.95668(2) 0.04032(9) Uani 1 1 d . . .
C1 C 0.2439(2) 0.7810(4) 0.7861(3) 0.0669(14) Uani 1 1 d . . .
H1A H 0.231453 0.838748 0.789164 0.080 Uiso 1 1 calc R . .
H1B H 0.237003 0.775523 0.740786 0.080 Uiso 1 1 calc R . .
C2 C 0.21741(19) 0.7099(4) 0.7968(3) 0.0601(13) Uani 1 1 d . . .
C3 C 0.1665(2) 0.7115(5) 0.7670(3) 0.0753(17) Uani 1 1 d . . .
H3 H 0.147385 0.760535 0.741042 0.090 Uiso 1 1 calc R . .
C4 C 0.1437(2) 0.6421(5) 0.7751(3) 0.0823(19) Uani 1 1 d . . .
H4 H 0.108614 0.642090 0.754389 0.099 Uiso 1 1 calc R . .
C5 C 0.1726(2) 0.5720(4) 0.8141(3) 0.0726(16) Uani 1 1 d . . .
H5 H 0.157383 0.522492 0.819435 0.087 Uiso 1 1 calc R . .
C6 C 0.2231(2) 0.5746(4) 0.8446(3) 0.0657(14) Uani 1 1 d . . .
H6 H 0.242837 0.527478 0.872894 0.079 Uiso 1 1 calc R . .
C7 C 0.3153(2) 0.8384(4) 0.8939(3) 0.0656(14) Uani 1 1 d . . .
H7A H 0.292385 0.889160 0.876860 0.079 Uiso 1 1 calc R . .
H7B H 0.349377 0.860045 0.911284 0.079 Uiso 1 1 calc R . .
C8 C 0.3150(2) 0.7950(4) 0.9491(3) 0.0594(12) Uani 1 1 d . . .
C9 C 0.3112(3) 0.8391(5) 0.9955(3) 0.0815(18) Uani 1 1 d . . .
H9 H 0.306537 0.900729 0.992541 0.098 Uiso 1 1 calc R . .
C10 C 0.3141(3) 0.7925(6) 1.0461(3) 0.091(2) Uani 1 1 d . . .
H10 H 0.312866 0.822317 1.079660 0.109 Uiso 1 1 calc R . .
C11 C 0.3187(3) 0.7040(6) 1.0486(3) 0.086(2) Uani 1 1 d . . .
H11 H 0.320154 0.671417 1.083084 0.103 Uiso 1 1 calc R . .
C12 C 0.3214(2) 0.6617(4) 0.9994(3) 0.0652(14) Uani 1 1 d . . .
H12 H 0.324016 0.599699 1.000168 0.078 Uiso 1 1 calc R . .
C13 C 0.3317(2) 0.7763(4) 0.8103(3) 0.0575(12) Uani 1 1 d . . .
C14 C 0.3128(2) 0.6969(4) 0.7626(3) 0.0645(14) Uani 1 1 d . . .
H14A H 0.280352 0.711340 0.720684 0.077 Uiso 1 1 calc R . .
H14B H 0.336904 0.682857 0.751149 0.077 Uiso 1 1 calc R . .
C15 C 0.38441(18) 0.7551(4) 0.8696(3) 0.0589(12) Uani 1 1 d . . .
H15A H 0.405005 0.736359 0.853339 0.071 Uiso 1 1 calc R . .
H15B H 0.399883 0.808140 0.897530 0.071 Uiso 1 1 calc R . .
C16 C 0.3277(2) 0.8598(4) 0.7731(3) 0.0729(16) Uani 1 1 d . . .
H16A H 0.346776 0.851941 0.752784 0.087 Uiso 1 1 calc R . .
H16B H 0.292269 0.869232 0.736250 0.087 Uiso 1 1 calc R . .
C17 C 0.4488(3) 0.1986(4) 1.0643(3) 0.0744(16) Uani 1 1 d . . .
H17A H 0.461364 0.149962 1.050571 0.089 Uiso 1 1 calc R . .
H17B H 0.422753 0.174750 1.069491 0.089 Uiso 1 1 calc R . .
C18 C 0.4909(2) 0.2347(3) 1.1302(3) 0.0587(12) Uani 1 1 d . . .
C19 C 0.5174(3) 0.1831(4) 1.1869(3) 0.0746(16) Uani 1 1 d . . .
H19 H 0.510037 0.122559 1.184965 0.090 Uiso 1 1 calc R . .
C20 C 0.5543(3) 0.2207(5) 1.2457(3) 0.085(2) Uani 1 1 d . . .
H20 H 0.573129 0.185847 1.284915 0.102 Uiso 1 1 calc R . .
C21 C 0.5642(2) 0.3090(5) 1.2484(3) 0.0728(16) Uani 1 1 d . . .
H21 H 0.589580 0.335740 1.289254 0.087 Uiso 1 1 calc R . .
C22 C 0.5364(2) 0.3574(4) 1.1903(2) 0.0583(12) Uani 1 1 d . . .
H22 H 0.542444 0.418487 1.191807 0.070 Uiso 1 1 calc R . .
C23 C 0.3728(2) 0.2866(4) 0.9867(3) 0.0654(14) Uani 1 1 d . . .
H23A H 0.353890 0.306989 0.939653 0.078 Uiso 1 1 calc R . .
H23B H 0.356515 0.233070 0.988766 0.078 Uiso 1 1 calc R . .
C24 C 0.3732(2) 0.3557(4) 1.0302(3) 0.0600(13) Uani 1 1 d . . .
C25 C 0.3345(2) 0.3681(5) 1.0380(4) 0.0811(19) Uani 1 1 d . . .
H25 H 0.305969 0.331018 1.015565 0.097 Uiso 1 1 calc R . .
C26 C 0.3377(3) 0.4344(5) 1.0784(4) 0.082(2) Uani 1 1 d . . .
H26 H 0.310881 0.445365 1.082881 0.098 Uiso 1 1 calc R . .
C27 C 0.3799(2) 0.4847(4) 1.1121(3) 0.0674(14) Uani 1 1 d . . .
H27 H 0.383061 0.529511 1.141497 0.081 Uiso 1 1 calc R . .
C28 C 0.4179(2) 0.4701(4) 1.1034(3) 0.0559(11) Uani 1 1 d . . .
H28 H 0.447310 0.504663 1.127400 0.067 Uiso 1 1 calc R . .
C29 C 0.43323(18) 0.2533(3) 0.9541(2) 0.0488(11) Uani 1 1 d . . .
C30 C 0.4895(2) 0.2509(3) 0.9885(3) 0.0579(12) Uani 1 1 d . . .
H30A H 0.503953 0.198794 1.017746 0.069 Uiso 1 1 calc R . .
H30B H 0.497734 0.248384 0.954805 0.069 Uiso 1 1 calc R . .
C31 C 0.41381(19) 0.3384(3) 0.9123(2) 0.0520(11) Uani 1 1 d . . .
H31A H 0.431197 0.348078 0.889808 0.062 Uiso 1 1 calc R . .
H31B H 0.377606 0.332946 0.877365 0.062 Uiso 1 1 calc R . .
C32 C 0.4075(2) 0.1706(4) 0.9123(3) 0.0675(15) Uani 1 1 d . . .
H32A H 0.416170 0.162100 0.879492 0.081 Uiso 1 1 calc R . .
H32B H 0.418895 0.118664 0.941922 0.081 Uiso 1 1 calc R . .
C33 C 0.4391(2) 0.3926(4) 0.7818(3) 0.0579(12) Uani 1 1 d . . .
C34 C 0.4396(3) 0.3232(5) 0.7394(4) 0.092(2) Uani 1 1 d . . .
H34A H 0.405487 0.312854 0.700421 0.138 Uiso 1 1 calc R . .
H34B H 0.460621 0.341776 0.724214 0.138 Uiso 1 1 calc R . .
H34C H 0.453038 0.269106 0.765414 0.138 Uiso 1 1 calc R . .
N1 N 0.24577(15) 0.6417(3) 0.8361(2) 0.0550(10) Uani 1 1 d . . .
N2 N 0.32020(15) 0.7070(3) 0.95171(19) 0.0548(10) Uani 1 1 d . . .
N3 N 0.29942(15) 0.7752(3) 0.83803(19) 0.0515(9) Uani 1 1 d . . .
N4 N 0.50135(16) 0.3208(3) 1.1319(2) 0.0514(9) Uani 1 1 d . . .
N5 N 0.41383(15) 0.4079(3) 1.0614(2) 0.0502(9) Uani 1 1 d . . .
N6 N 0.42631(16) 0.2669(3) 1.0111(2) 0.0528(9) Uani 1 1 d . . .
N7 N 0.34119(15) 0.5440(3) 0.91660(19) 0.0507(9) Uani 1 1 d . . .
N8 N 0.31922(16) 0.4803(3) 0.8807(2) 0.0608(11) Uani 1 1 d . . .
N9 N 0.3008(2) 0.4202(4) 0.8503(4) 0.096(2) Uani 1 1 d . . .
O1 O 0.30692(12) 0.6233(2) 0.79330(16) 0.0537(8) Uani 1 1 d . . .
O2 O 0.38298(12) 0.6875(2) 0.90873(16) 0.0494(7) Uani 1 1 d . . .
O3 O 0.3453(2) 0.9342(3) 0.8134(3) 0.0983(17) Uani 1 1 d . . .
H3A H 0.342375 0.977789 0.790292 0.147 Uiso 1 1 calc R . .
O4 O 0.50900(11) 0.3287(2) 1.02710(16) 0.0466(7) Uani 1 1 d . . .
O5 O 0.42245(12) 0.4102(2) 0.95449(14) 0.0448(7) Uani 1 1 d . . .
O6 O 0.3537(2) 0.1807(4) 0.8776(3) 0.1119(19) Uani 1 1 d . . .
H6A H 0.339374 0.135455 0.854973 0.168 Uiso 1 1 calc R . .
O7 O 0.39046(13) 0.5371(3) 0.84023(16) 0.0574(8) Uani 1 1 d . . .
H7C H 0.408451 0.507982 0.831452 0.086 Uiso 1 1 d R . .
H7D H 0.382881 0.586032 0.820011 0.086 Uiso 1 1 d R . .
O8 O 0.44048(13) 0.6406(2) 1.04792(17) 0.0578(8) Uani 1 1 d . . .
H8 H 0.465340 0.622734 1.084638 0.087 Uiso 1 1 calc R . .
O9 O 0.49882(10) 0.48385(19) 1.06032(14) 0.0415(6) Uani 1 1 d . A 1
O10 O 0.39742(17) 0.4273(3) 0.7612(2) 0.0828(14) Uani 1 1 d . . .
O11 O 0.47997(15) 0.4147(3) 0.8344(2) 0.0702(10) Uani 1 1 d . B 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Co1 Eu1 147.11(14) . .
N1 Co1 N2 86.94(18) . .
N1 Co1 N3 87.48(18) . .
N1 Co1 N7 99.72(19) . .
N2 Co1 Eu1 99.13(12) . .
N2 Co1 N7 93.74(18) . .
N3 Co1 Eu1 124.95(13) . .
N3 Co1 N2 86.67(18) . .
N3 Co1 N7 172.80(18) . .
N7 Co1 Eu1 47.88(12) . .
O1 Co1 Eu1 86.58(10) . .
O1 Co1 N1 90.50(16) . .
O1 Co1 N2 172.93(17) . .
O1 Co1 N3 86.63(16) . .
O1 Co1 N7 93.19(16) . .
O2 Co1 Eu1 39.02(10) . .
O2 Co1 N1 173.76(17) . .
O2 Co1 N2 92.97(16) . .
O2 Co1 N3 86.29(16) . .
O2 Co1 N7 86.51(16) . .
O2 Co1 O1 88.86(15) . .
Eu1 Co2 Eu1 70.955(16) . 5_667
N4 Co2 Eu1 145.96(13) . .
N4 Co2 Eu1 95.95(12) . 5_667
N4 Co2 N5 88.74(17) . .
N4 Co2 O9 102.04(16) . .
N5 Co2 Eu1 146.82(13) . 5_667
N5 Co2 Eu1 86.95(13) . .
N5 Co2 O9 101.56(15) . .
N6 Co2 Eu1 125.36(13) . .
N6 Co2 Eu1 127.42(13) . 5_667
N6 Co2 N4 87.84(18) . .
N6 Co2 N5 85.47(18) . .
N6 Co2 O9 167.89(15) . .
O4 Co2 Eu1 97.89(10) . .
O4 Co2 Eu1 39.42(9) . 5_667
O4 Co2 N4 89.46(16) . .
O4 Co2 N5 173.70(16) . .
O4 Co2 N6 88.43(16) . .
O4 Co2 O9 84.71(13) . .
O5 Co2 Eu1 87.69(10) . 5_667
O5 Co2 Eu1 42.36(10) . .
O5 Co2 N4 171.68(16) . .
O5 Co2 N5 92.30(16) . .
O5 Co2 N6 84.01(16) . .
O5 Co2 O4 88.62(14) . .
O5 Co2 O9 85.85(13) . .
O9 Co2 Eu1 45.32(9) . 5_667
O9 Co2 Eu1 46.31(9) . .
Co1 Eu1 Eu1 175.611(15) . 5_667
Co1 Eu1 H7C 86.7 . .
Co1 Eu1 H7D 62.1 . .
Co2 Eu1 Co1 121.680(18) . .
Co2 Eu1 Co1 129.15(2) 5_667 .
Co2 Eu1 Co2 109.045(16) . 5_667
Co2 Eu1 Eu1 55.154(14) . 5_667
Co2 Eu1 Eu1 53.89(2) 5_667 5_667
Co2 Eu1 H7C 103.8 . .
Co2 Eu1 H7C 77.8 5_667 .
Co2 Eu1 H7D 129.0 . .
Co2 Eu1 H7D 84.3 5_667 .
Eu1 Eu1 H7C 91.2 5_667 .
Eu1 Eu1 H7D 116.8 5_667 .
N7 Eu1 Co1 33.20(9) . .
N7 Eu1 Co2 159.55(9) . 5_667
N7 Eu1 Co2 89.00(9) . .
N7 Eu1 Eu1 143.00(9) . 5_667
N7 Eu1 H7C 88.8 . .
N7 Eu1 H7D 76.7 . .
O2 Eu1 Co1 30.14(8) . .
O2 Eu1 Co2 101.24(8) . 5_667
O2 Eu1 Co2 148.50(8) . .
O2 Eu1 Eu1 153.89(8) . 5_667
O2 Eu1 N7 63.08(12) . .
O2 Eu1 H7C 90.6 . .
O2 Eu1 H7D 61.5 . .
O2 Eu1 O8 73.32(12) . .
O2 Eu1 O9 147.13(11) . .
O2 Eu1 O9 126.29(11) . 5_667
O4 Eu1 Co1 107.54(8) 5_667 .
O4 Eu1 Co2 31.22(8) 5_667 5_667
O4 Eu1 Co2 126.64(8) 5_667 .
O4 Eu1 Eu1 76.56(8) 5_667 5_667
O4 Eu1 N7 140.00(12) 5_667 .
O4 Eu1 O2 77.40(11) 5_667 .
O4 Eu1 O5 145.38(11) 5_667 .
O4 Eu1 O7 102.65(13) 5_667 .
O4 Eu1 H7C 97.9 5_667 .
O4 Eu1 H7D 90.4 5_667 .
O4 Eu1 O8 81.20(12) 5_667 .
O4 Eu1 O9 64.91(10) 5_667 5_667
O4 Eu1 O9 93.13(10) 5_667 .
O5 Eu1 Co1 105.74(8) . .
O5 Eu1 Co2 115.81(8) . 5_667
O5 Eu1 Co2 32.52(7) . .
O5 Eu1 Eu1 69.96(8) . 5_667
O5 Eu1 N7 74.42(12) . .
O5 Eu1 O2 135.27(11) . .
O5 Eu1 H7C 74.7 . .
O5 Eu1 H7D 96.8 . .
O5 Eu1 O8 115.05(12) . .
O5 Eu1 O9 65.14(10) . .
O5 Eu1 O9 82.73(10) . 5_667
O7 Eu1 Co1 69.84(9) . .
O7 Eu1 Co2 89.21(9) . 5_667
O7 Eu1 Co2 112.07(10) . .
O7 Eu1 Eu1 108.01(9) . 5_667
O7 Eu1 N7 74.72(12) . .
O7 Eu1 O2 76.10(12) . .
O7 Eu1 O5 80.10(12) . .
O7 Eu1 H7C 16.8 . .
O7 Eu1 H7D 17.0 . .
O7 Eu1 O8 147.51(12) . .
O7 Eu1 O9 136.72(11) . .
O7 Eu1 O9 76.52(11) . 5_667
H7C Eu1 H7D 29.1 . .
O8 Eu1 Co1 78.20(8) . .
O8 Eu1 Co2 89.34(9) . .
O8 Eu1 Co2 107.17(9) . 5_667
O8 Eu1 Eu1 104.27(8) . 5_667
O8 Eu1 N7 81.85(12) . .
O8 Eu1 H7C 163.7 . .
O8 Eu1 H7D 134.8 . .
O8 Eu1 O9 74.15(11) . .
O8 Eu1 O9 131.58(11) . 5_667
O9 Eu1 Co1 142.96(7) 5_667 .
O9 Eu1 Co1 142.28(7) . .
O9 Eu1 Co2 84.91(7) 5_667 .
O9 Eu1 Co2 83.92(7) . 5_667
O9 Eu1 Co2 33.72(7) 5_667 5_667
O9 Eu1 Co2 34.55(7) . .
O9 Eu1 Eu1 37.26(7) . 5_667
O9 Eu1 Eu1 37.06(7) 5_667 5_667
O9 Eu1 N7 145.77(11) 5_667 .
O9 Eu1 N7 116.44(11) . .
O9 Eu1 H7C 122.1 . .
O9 Eu1 H7C 60.3 5_667 .
O9 Eu1 H7D 151.0 . .
O9 Eu1 H7D 81.2 5_667 .
O9 Eu1 O9 74.32(11) . 5_667
H1A C1 H1B 108.1 . .
C2 C1 H1A 109.6 . .
C2 C1 H1B 109.6 . .
C2 C1 N3 110.2(4) . .
N3 C1 H1A 109.6 . .
N3 C1 H1B 109.6 . .
C3 C2 C1 122.2(5) . .
N1 C2 C1 116.7(5) . .
N1 C2 C3 121.1(6) . .
C2 C3 H3 120.1 . .
C4 C3 C2 119.8(6) . .
C4 C3 H3 120.1 . .
C3 C4 H4 120.5 . .
C3 C4 C5 118.9(6) . .
C5 C4 H4 120.5 . .
C4 C5 H5 120.3 . .
C6 C5 C4 119.3(6) . .
C6 C5 H5 120.3 . .
C5 C6 H6 118.9 . .
N1 C6 C5 122.2(6) . .
N1 C6 H6 118.9 . .
H7A C7 H7B 108.1 . .
C8 C7 H7A 109.6 . .
C8 C7 H7B 109.6 . .
N3 C7 H7A 109.6 . .
N3 C7 H7B 109.6 . .
N3 C7 C8 110.3(5) . .
C9 C8 C7 124.1(6) . .
N2 C8 C7 114.7(5) . .
N2 C8 C9 121.1(6) . .
C8 C9 H9 120.6 . .
C8 C9 C10 118.8(7) . .
C10 C9 H9 120.6 . .
C9 C10 H10 119.8 . .
C11 C10 C9 120.3(6) . .
C11 C10 H10 119.8 . .
C10 C11 H11 120.6 . .
C10 C11 C12 118.8(6) . .
C12 C11 H11 120.6 . .
C11 C12 H12 119.6 . .
N2 C12 C11 120.8(6) . .
N2 C12 H12 119.6 . .
C15 C13 C14 107.4(4) . .
C15 C13 C16 114.3(5) . .
C15 C13 N3 105.4(4) . .
C16 C13 C14 110.6(5) . .
C16 C13 N3 114.7(4) . .
N3 C13 C14 103.7(4) . .
C13 C14 H14A 109.6 . .
C13 C14 H14B 109.6 . .
H14A C14 H14B 108.1 . .
O1 C14 C13 110.3(4) . .
O1 C14 H14A 109.6 . .
O1 C14 H14B 109.6 . .
C13 C15 H15A 109.7 . .
C13 C15 H15B 109.7 . .
H15A C15 H15B 108.2 . .
O2 C15 C13 110.0(4) . .
O2 C15 H15A 109.7 . .
O2 C15 H15B 109.7 . .
C13 C16 H16A 108.8 . .
C13 C16 H16B 108.8 . .
H16A C16 H16B 107.7 . .
O3 C16 C13 113.9(5) . .
O3 C16 H16A 108.8 . .
O3 C16 H16B 108.8 . .
H17A C17 H17B 108.0 . .
C18 C17 H17A 109.3 . .
C18 C17 H17B 109.3 . .
N6 C17 H17A 109.3 . .
N6 C17 H17B 109.3 . .
N6 C17 C18 111.6(5) . .
C19 C18 C17 121.8(5) . .
N4 C18 C17 116.8(5) . .
N4 C18 C19 121.3(6) . .
C18 C19 H19 120.6 . .
C20 C19 C18 118.9(6) . .
C20 C19 H19 120.6 . .
C19 C20 H20 119.8 . .
C19 C20 C21 120.3(6) . .
C21 C20 H20 119.8 . .
C20 C21 H21 120.9 . .
C20 C21 C22 118.3(6) . .
C22 C21 H21 120.9 . .
C21 C22 H22 119.0 . .
N4 C22 C21 122.0(6) . .
N4 C22 H22 119.0 . .
H23A C23 H23B 108.4 . .
C24 C23 H23A 110.0 . .
C24 C23 H23B 110.0 . .
C24 C23 N6 108.4(4) . .
N6 C23 H23A 110.0 . .
N6 C23 H23B 110.0 . .
C25 C24 C23 123.2(5) . .
N5 C24 C23 115.6(5) . .
N5 C24 C25 121.2(5) . .
C24 C25 H25 120.4 . .
C26 C25 C24 119.2(6) . .
C26 C25 H25 120.4 . .
C25 C26 H26 120.3 . .
C27 C26 C25 119.3(6) . .
C27 C26 H26 120.3 . .
C26 C27 H27 120.1 . .
C26 C27 C28 119.8(6) . .
C28 C27 H27 120.1 . .
C27 C28 H28 119.5 . .
N5 C28 C27 121.0(5) . .
N5 C28 H28 119.5 . .
C30 C29 C31 107.3(4) . .
C30 C29 C32 112.3(4) . .
C30 C29 N6 104.5(4) . .
C32 C29 C31 113.0(4) . .
N6 C29 C31 105.2(4) . .
N6 C29 C32 113.7(4) . .
C29 C30 H30A 110.3 . .
C29 C30 H30B 110.3 . .
H30A C30 H30B 108.6 . .
O4 C30 C29 106.9(4) . .
O4 C30 H30A 110.3 . .
O4 C30 H30B 110.3 . .
C29 C31 H31A 109.7 . .
C29 C31 H31B 109.7 . .
H31A C31 H31B 108.2 . .
O5 C31 C29 109.7(4) . .
O5 C31 H31A 109.7 . .
O5 C31 H31B 109.7 . .
C29 C32 H32A 109.9 . .
C29 C32 H32B 109.9 . .
H32A C32 H32B 108.3 . .
O6 C32 C29 108.9(5) . .
O6 C32 H32A 109.9 . .
O6 C32 H32B 109.9 . .
O10 C33 C34 117.1(5) . .
O11 C33 C34 118.3(5) . .
O11 C33 O10 124.6(5) . .
C33 C34 H34A 109.5 . .
C33 C34 H34B 109.5 . .
C33 C34 H34C 109.5 . .
H34A C34 H34B 109.5 . .
H34A C34 H34C 109.5 . .
H34B C34 H34C 109.5 . .
C2 N1 Co1 112.6(4) . .
C6 N1 Co1 128.7(4) . .
C6 N1 C2 118.6(5) . .
C8 N2 Co1 113.4(3) . .
C12 N2 Co1 126.0(4) . .
C12 N2 C8 120.0(5) . .
C1 N3 Co1 109.2(3) . .
C1 N3 C13 115.1(4) . .
C7 N3 Co1 108.3(3) . .
C7 N3 C1 110.9(4) . .
C7 N3 C13 114.5(4) . .
C13 N3 Co1 97.7(3) . .
C18 N4 Co2 112.6(3) . .
C22 N4 Co2 128.2(4) . .
C22 N4 C18 119.1(5) . .
C24 N5 Co2 112.9(3) . .
C28 N5 Co2 127.5(4) . .
C28 N5 C24 119.4(5) . .
C17 N6 Co2 110.4(3) . .
C17 N6 C23 111.8(4) . .
C17 N6 C29 115.7(4) . .
C23 N6 Co2 107.5(3) . .
C23 N6 C29 113.1(4) . .
C29 N6 Co2 97.0(3) . .
Co1 N7 Eu1 98.92(17) . .
N8 N7 Co1 115.9(3) . .
N8 N7 Eu1 115.7(3) . .
N9 N8 N7 177.0(6) . .
C14 O1 Co1 109.3(3) . .
Co1 O2 Eu1 110.84(15) . .
C15 O2 Co1 110.0(3) . .
C15 O2 Eu1 128.8(3) . .
C16 O3 H3A 109.5 . .
Co2 O4 Eu1 109.36(14) . 5_667
C30 O4 Co2 110.0(3) . .
C30 O4 Eu1 136.6(3) . 5_667
Co2 O5 Eu1 105.12(13) . .
C31 O5 Co2 109.5(3) . .
C31 O5 Eu1 137.8(3) . .
C32 O6 H6A 109.5 . .
Eu1 O7 H7C 109.6 . .
Eu1 O7 H7D 108.9 . .
H7C O7 H7D 109.5 . .
Eu1 O8 H8 109.5 . .
Co2 O9 Eu1 100.96(12) . 5_667
Co2 O9 Eu1 99.15(11) . .
Eu1 O9 Eu1 105.68(11) . 5_667
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Co1 N1 1.924(4) .
Co1 N2 1.930(4) .
Co1 N3 1.927(4) .
Co1 N7 1.955(4) .
Co1 O1 1.903(3) .
Co1 O2 1.895(3) .
Co2 N4 1.924(4) .
Co2 N5 1.933(4) .
Co2 N6 1.921(4) .
Co2 O4 1.889(3) .
Co2 O5 1.885(3) .
Co2 O9 1.944(3) .
Eu1 N7 2.649(4) .
Eu1 O2 2.377(3) .
Eu1 O4 2.314(3) 5_667
Eu1 O5 2.362(3) .
Eu1 O7 2.362(3) .
Eu1 H7C 2.7646 .
Eu1 H7D 2.7572 .
Eu1 O8 2.430(4) .
Eu1 O9 2.490(3) 5_667
Eu1 O9 2.479(3) .
C1 H1A 0.9900 .
C1 H1B 0.9900 .
C1 C2 1.494(8) .
C1 N3 1.508(7) .
C2 C3 1.379(8) .
C2 N1 1.360(7) .
C3 H3 0.9500 .
C3 C4 1.368(10) .
C4 H4 0.9500 .
C4 C5 1.384(10) .
C5 H5 0.9500 .
C5 C6 1.366(8) .
C6 H6 0.9500 .
C6 N1 1.344(7) .
C7 H7A 0.9900 .
C7 H7B 0.9900 .
C7 C8 1.497(8) .
C7 N3 1.495(7) .
C8 C9 1.372(8) .
C8 N2 1.351(7) .
C9 H9 0.9500 .
C9 C10 1.373(10) .
C10 H10 0.9500 .
C10 C11 1.358(11) .
C11 H11 0.9500 .
C11 C12 1.396(8) .
C12 H12 0.9500 .
C12 N2 1.328(7) .
C13 C14 1.543(8) .
C13 C15 1.523(7) .
C13 C16 1.524(7) .
C13 N3 1.528(7) .
C14 H14A 0.9900 .
C14 H14B 0.9900 .
C14 O1 1.416(6) .
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C15 O2 1.419(6) .
C16 H16A 0.9900 .
C16 H16B 0.9900 .
C16 O3 1.392(9) .
C17 H17A 0.9900 .
C17 H17B 0.9900 .
C17 C18 1.502(8) .
C17 N6 1.488(7) .
C18 C19 1.383(8) .
C18 N4 1.353(7) .
C19 H19 0.9500 .
C19 C20 1.365(10) .
C20 H20 0.9500 .
C20 C21 1.380(10) .
C21 H21 0.9500 .
C21 C22 1.381(8) .
C22 H22 0.9500 .
C22 N4 1.338(7) .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C23 C24 1.485(8) .
C23 N6 1.514(7) .
C24 C25 1.383(8) .
C24 N5 1.350(6) .
C25 H25 0.9500 .
C25 C26 1.370(9) .
C26 H26 0.9500 .
C26 C27 1.367(9) .
C27 H27 0.9500 .
C27 C28 1.379(8) .
C28 H28 0.9500 .
C28 N5 1.341(7) .
C29 C30 1.521(7) .
C29 C31 1.546(7) .
C29 C32 1.537(7) .
C29 N6 1.530(6) .
C30 H30A 0.9900 .
C30 H30B 0.9900 .
C30 O4 1.420(5) .
C31 H31A 0.9900 .
C31 H31B 0.9900 .
C31 O5 1.414(6) .
C32 H32A 0.9900 .
C32 H32B 0.9900 .
C32 O6 1.454(8) .
C33 C34 1.482(8) .
C33 O10 1.262(7) .
C33 O11 1.261(6) .
C34 H34A 0.9800 .
C34 H34B 0.9800 .
C34 H34C 0.9800 .
N7 N8 1.230(6) .
N8 N9 1.116(7) .
O3 H3A 0.8400 .
O6 H6A 0.8400 .
O7 H7C 0.8501 .
O7 H7D 0.8499 .
O8 H8 0.8400 .
